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Geochemical characteristics of silty clays from the Brusartsi Formation 布鲁萨特西地层淤泥质粘土的地球化学特征
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.279
Metodi Karadjov, D. Karastanev, Boriana Tchakalova
This study investigated the geochemical characteristics of Pliocene clay sediments from the Brusartsi Formation, situated in the area of the town of Kozloduy, North Bulgaria). The main objective of the study is to characterize the Brusartsi clays as a natural barrier against pollutant and radionuclide migration. Based on mineralogical and geochemical analyses, new results are obtained concerning the mineral composition, cation exchange capacity (CEC), specific surface area, etc., for the Brusartsi Formation.
本研究调查了位于保加利亚北部科兹洛杜伊镇地区的布鲁萨特西地层上新世粘土沉积物的地球化学特征。)这项研究的主要目的是确定布鲁萨特西粘土作为防止污染物和放射性核素迁移的天然屏障的特征。根据矿物学和地球化学分析,获得了 Brusartsi 地层的矿物成分、阳离子交换容量(CEC)、比表面积等方面的新结果。
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引用次数: 0
Preliminary data on the mineral chemistry of garnet from the skarn alteration associated with the Elatsite porphyry-copper gold deposit, Bulgaria 关于保加利亚 Elatsite 斑岩铜金矿床相关矽卡岩蚀变中石榴石矿物化学的初步数据
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.31
H. Georgieva, R. Nedialkov, Elitsa Stefanova, Georgi Milenkov, Ivan Krumov, Neven Georgiev
The skarn alteration is poorly preserved at the Elatsite, restricted to the hornfelses from the East, Southeast and Southern part of the deposit. The rocks are defined as exoskarns, with a mineral composition including garnets, epidote, pyroxene, amphiboles, carbonates, prehnite, quartz, sulphides. The newly formed minerals occur in poorly preserved layers. The garnet grains are subhedral with inclusions of epidote and quartz, while some of them are corrode with carbonate and zeolites formed in the fractures. The garnets are grossular-andradite type, with higher values for HREE over LREE, and low values for Rb, Sr, Ba, Pb and U. The skarn formation is related with the intrusion of the magma which causes the heating of the metamorphic rocks (rich in carbonate material – chlorite-sericite-carbonite, sericite-carbonate schists, etc.) from the low-grade metamorphic rocks. The Fe+3–Al+3 exchanges in the cores of the garnets indicate their formation from fluids with high oxygen fugacity.
埃拉茨岩的矽卡岩蚀变保存较差,仅限于矿床东部、东南部和南部的角闪岩。这些岩石被定义为外矽卡岩,矿物成分包括石榴石、闪石、辉石、闪石、碳酸盐、辉绿岩、石英、硫化物。新形成的矿物分布在保存较差的地层中。石榴石晶粒为亚方形,内含闪石和石英,其中一些晶粒被裂缝中形成的碳酸盐和沸石腐蚀。矽卡岩的形成与岩浆的侵入有关,岩浆的侵入导致变质岩(富含碳酸盐物质--绿泥石-绢云母-碳酸盐片岩、绢云母-碳酸盐片岩等)从低级变质岩中加热。石榴石内核中的 Fe+3-Al+3 交换表明它们是由高富氧流体形成的。
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引用次数: 0
Coexisting nickel diarsenide polymorphs in the five-element mineralization of the Bihor metallogenetic district, Apuseni Mountains, Romania 罗马尼亚阿普塞尼山脉比霍尔成矿带五元素矿化中并存的二砷化镍多晶体
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.51
G. Săbău, George Dincă, Andra-Elena Filiuță
The three known polymorphs of nickel diarsenide were found to coexist in apparent equilibrium in the five-element mineralizations of the Bihor Metallogenetic District. It is the first identification of pararammelsbergite and krutovite in Romania, and the locality joins a very limited list of occurrences where all three NiAs2 polymorphs coexist. Both phases newly identified in Romania are easily distinguishable from rammelsbergite by their optical properties and display consistent compositional differences manifested in stoichiometry and degree of isomorphic substitution. The NiAs2 polymorphs coexist with nickeline and skutterudite and apparently predate cobaltite-gersdorffite in a mesothermal depositional sequence characterized by initial separation of Ni and Co in metal-poorer arsenides, followed by continuous decrease of arsenic activity, increase in sulfur activity, modal increase of nickeline and Co enrichment in the gersdorffite-cobaltite series.
在比霍尔金属成因区的五元素矿化物中,发现了三种已知的二砷化镍多晶体以明显的平衡状态共存。这是在罗马尼亚首次发现pararammelsbergite和krutovite,该矿区也是所有三种NiAs2多晶体共存的极少数矿点之一。在罗马尼亚新发现的这两种物相都很容易通过光学特性与雷姆贝里石区分开来,并在化学计量和同构取代程度上显示出一致的成分差异。NiAs2 多晶体与镍线石和矽卡岩共存,在中温沉积序列中明显早于钴铁-格氏钴铁矿,其特征是金属-贫砷化物中的镍和钴最初分离,随后砷活性持续降低,硫活性增加,镍线石模态增加,格氏钴铁矿-钴铁矿系列中的钴富集。
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引用次数: 0
Morphometric analysis of the drainage network in the Parvenetska river basin, the Western Rhodopes Mountains 西罗多佩山脉帕尔文涅茨卡河流域排水网络形态计量分析
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.341
Dimitar Krenchev
The aim of this study is to analyze selected morphometric properties of drainage network in the Parvenetska river basin, the northwestern Rhodope Mountains. In this regard, the watershed of the main river was divided into seven sub-basins. For each of them, the following linear and areal morphometric parameters were considered: area and shape of the catchment, slopes, drainage network length, drainage density, stream frequency, bifurcation ratio, Meltonʼs index, hypsometric integral, etc. The morphometric analysis can be used for creating of hydrological and geomorphological models for natural hazards and for better planning of sustainable use of water resources in the area.
本研究的目的是分析罗多彼山脉西北部帕尔文涅茨卡河流域排水网络的部分形态特征。为此,主河流域被划分为七个子流域。每个子流域都考虑了以下线性和区域形态参数:流域面积和形状、坡度、排水管网长度、排水密度、河流频率、分叉率、梅尔顿指数、湿度积分等。形态分析可用于创建自然灾害水文和地貌模型,以及更好地规划该地区水资源的可持续利用。
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引用次数: 0
Genetic modeling and prospecting criteria: An example of syngenetic vs. epigenetic ore formation 遗传建模和勘探标准:合成遗传与表观遗传矿石形成的实例
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.207
Z. Damyanov
The paper presents the importance of mineral deposit modeling, based on the elucidation of key elements of its origin, for the development of reliable criteria for prospecting of new deposits and orebodies of this type. On the example of the Kremikovtsi carbonate-hosted IF-barite-polymetallic deposit, it is shown that the adoption of a well-grounded syngenetic or epigenetic concept for its origin is crucial for successful prospecting activity. Based on the developed model for a sedimentary-exhalative (SEDEX) origin of the deposit (i.e. syngenetic to the carbonate host), the key factors controlling ore formation are specified, and an optimal strategy for future prospecting in the region is proposed.
本文介绍了在阐明矿床起源关键因素的基础上建立矿床模型的重要性,以便为勘探新矿床和此类矿体制定可靠的标准。以克雷米科夫茨碳酸盐岩包裹的 IF 重晶石多金属矿床为例,说明了采用有充分依据的系统遗传学或表观遗传学概念来确定矿床起源对于成功开展勘探活动至关重要。根据所开发的沉积-喷出(SEDEX)矿床起源模型(即与碳酸盐母岩的共生),明确了控制矿石形成的关键因素,并提出了该地区未来勘探的最佳战略。
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引用次数: 0
Carboniferous sills and related metasomatic activity in the area of Asaritsa Peak, West Stara Planina Mountain 西斯塔拉普兰纳山阿萨里萨峰地区的石炭纪山体及相关的变质活动
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.85
Stoyan Georgiev, Elitsa Stefanova, A. Hikov, I. Peytcheva, V. Sachanski, Milen Stavrev
Two diorite to monzodiorite sills are recently found among the Silurian sedimentary succession near to Asaritsa peak, West Stara Planina Mountain. Several levels with diagenetic metalliferous nodules occur within shale interval in the sediments. The magmatic rocks are affected by strong propylitic to sericitic alteration (chlorite, sericite, albite and quartz) and only relicts of the rock-forming minerals (feldspar, biotite and clinopyroxene) are observed. The bodies are crosscut by thin quartz veins and disseminated pyrite is observed. The chondrite normalized spidergrams show patterns similar to orogenic rocks, with very high peaks of Th and U and depletion in Sr and Ti. The zircon U-Pb geochronology reveals that the magmatic crystallization is during the Carboniferous period – 326.4±3.2 Ма, with low content of xenocryst most probably from the sedimentary basement. The magmatic activity coincides with the Variscan orogeny formed during the late Paleozoic and most probabaly is related to the evolution of the alkaline Buhovo-Seslavtsi Pluton which is situated just to the south, at a direct proximity. The different composition of the pyrite from the sills and the diagenetic nodules from the sediments is most probably due to their different genesis. While the alterations of the nodules can be attributed to metasomatic processes related to the magmatic activity.
最近在西斯塔拉普兰纳山阿萨里萨峰附近的志留纪沉积演替中发现了两块闪长岩至单斜闪长岩岩屑。在沉积物的页岩层中,有几层带有成岩金属结核。岩浆岩受到强烈的阳起石-绢云母蚀变(绿泥石、绢云母、白云石和石英)的影响,只能观察到岩石形成矿物(长石、生物橄榄石和鳞片辉石)的遗迹。岩体被细石英脉横切,并观察到黄铁矿散布。软玉归一化spidergrams显示出与造山岩类似的模式,Th和U的峰值非常高,Sr和Ti的峰值很低。锆石U-Pb地质年代学显示,岩浆结晶发生在石炭纪--326.4±3.2 Ма,氙晶含量较低,很可能来自沉积基底。岩浆活动与古生代晚期形成的瓦里斯坎造山运动相吻合,很可能与碱性布霍沃-塞斯拉夫齐岩浆岩的演化有关,该岩浆岩就位于南面,距离很近。岩屑中的黄铁矿和沉积物中的成岩结核成分不同,很可能是由于它们的成因不同。结核的蚀变可能是与岩浆活动有关的成岩过程造成的。
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引用次数: 0
Petrography and geochemistry of Cretaceous bauxites from Jajce, Bosnia and Herzegovina 波斯尼亚和黑塞哥维那亚伊采白垩纪铝土矿的岩石学和地球化学研究
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.77
Šime Bilić, I. Peytcheva, Stoyan Georgiev, A. Hikov, Ivica Pavičić, Gordana Deljak, F. Šumanovac, Marko Holma
The study presents petrographic and compositional data of Late Cretaceous bauxite deposits in the area of Jajce, Bosnia and Herzegovina. Results indicate that bauxites exhibit ooidic to pisodic textures enclosed within a pelitomorfic matrix. Most of the deposits are boehmitic but in some localities, a considerable quantity of diaspore is identified. Hematite is the dominant Fe-mineral, while kaolinite, goethite and calcite are minor. The accessory minerals are represented by anatase, rutile and zircon. Al2O3 content ranges between 54.32–61.05 wt % and is negatively correlated to Fe2O3. Rare earth elements (REE) show variable concentrations, reaching up to 1353 ppm. The chondrite normalized patterns reveal negative Eu anomaly in all and positive Ce anomaly in almost all samples. Ce anomaly shows negative correlation with REE. Bauxites from the Jajce area represent valuable mineral resource with potentially valuable quantities of REE and Sc. Mineralogy and geochemical signature indicate a complex petrogenetic history.
本研究介绍了波斯尼亚和黑塞哥维那亚伊采地区晚白垩世铝土矿床的岩石学和成分数据。研究结果表明,铝土矿呈现出鲕状至雉状纹理,并被包裹在鲕状基质中。大部分矿床为铁铝土矿,但在一些地方也发现了相当数量的透辉石。铁矿石是主要的铁矿物,而高岭石、鹅卵石和方解石则是次要矿物。附属矿物有锐钛矿、金红石和锆石。Al2O3 含量介于 54.32-61.05 wt % 之间,与 Fe2O3 呈负相关。稀土元素(REE)含量不一,最高可达 1353 ppm。软玉归一化模式显示,所有样本的 Eu 异常均为负值,几乎所有样本的 Ce 异常均为正值。铈异常与 REE 呈负相关。Jajce 地区的铝土矿是宝贵的矿产资源,可能含有大量有价值的 REE 和 Sc。矿物学和地球化学特征显示了复杂的成岩历史。
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引用次数: 0
Efficient benchtop acid digestion of organic-rich sediments for ICP-MS analyses: testing analytical procedures on NIST 2702 standard reference material 用于 ICP-MS 分析的富含有机物沉积物的高效台式酸消化:在 NIST 2702 标准参考材料上测试分析程序
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.73
Lora Bidzhova, Emiliya D. Raeva, Gatien L. F. Morin, Svetoslav V. Georgiev
Trace element abundances in organic-rich sediments are widely used in various fields of the geosciences, yet few contributions discuss the effectiveness of low-cost benchtop acid digestion techniques for such samples. Here, we tested three different sample preparation methods (acid digestion in closed and open vessels, and fusion) on twelve powder aliquots of organic-rich sediment, standard reference material NIST 2702. Comparison of newly obtained ICP-MS and LA-ICP-MS results with their respective certificate values, facilitates the assessment of digestion efficiency and the effects of vessel size, acid mixture, and other parameters on the recoveries of 29 trace elements. Our results show that benchtop digestion of organic-rich sediment in closed 7 mL PFA vessels using HF+HNO3+HClO4 mixture is more efficient compared with open vessel digestion treated with the same acid mixture (± HCl), with closed or open vessel digestions without HClO4, and with LA-ICP-MS measurements on fused glass discs.
富含有机物的沉积物中的痕量元素丰度被广泛应用于地球科学的各个领域,但很少有人讨论低成本的台式酸消解技术对这类样品的有效性。在此,我们对 12 份富含有机沉积物的粉末等分样品(标准参考材料 NIST 2702)测试了三种不同的样品制备方法(在封闭和开放容器中进行酸消解以及熔融)。将新获得的 ICP-MS 和 LA-ICP-MS 结果与各自的证书值进行比较,有助于评估消化效率以及容器大小、酸混合物和其他参数对 29 种微量元素回收率的影响。我们的结果表明,使用 HF+HNO3+HClO4 混合物在封闭的 7 mL PFA 容器中对富含有机物的沉积物进行台式消解,与使用相同酸混合物(± HCl)处理的开放式容器消解、不使用 HClO4 的封闭式或开放式容器消解以及在熔融玻璃圆盘上进行 LA-ICP-MS 测量相比,效率更高。
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引用次数: 0
A contribution to the understanding of the discharge dynamics and water balance of the karst spring Gornji Dušnik (Suva Planina) 有助于了解岩溶泉 Gornji Dušnik(苏瓦普兰纳)的排放动态和水平衡
Pub Date : 2023-12-01 DOI: 10.52215//rev.bgs.2023.84.3.315
Aleksandar Tanasković, Vesna Ristić Vakanjac, D. Polomcic, Jelena M. Močević
A sufficiently long time-series of daily discharges is needed to assess the discharge dynamics and calculate the water balance equation parameters of a spring (river source). The paper assumes that a catchment is gauged if a time-series of observations of at least 30 years is available, which is a rare case in Serbia. One-year monitoring is often set up to verify the reserves of a water source or spring intended for capture. Monitoring ceases after the final report is produced. The paper aims to show potential problems if there are no sufficiently long time-series and if no detailed hydrogeological investigations have been undertaken. The Gornji Dušnik Spring is used as an example. That spring drains the western parts of Suva Planina Mountain. It was captured many years ago to provide public water supply to the town of Gadžin Han and the nearby villages of Donji Dušnik and Gornji Dušnik.
要评估泉水(河流源头)的排水动态并计算其水平衡方程参数,需要足够长的日排水时间序列。本文假定,如果有至少 30 年的观测时间序列,就可以对集水区进行测量,但在塞尔维亚这种情况很少见。通常会进行为期一年的监测,以核实水源或泉水的储备情况。监测工作在最终报告编制完成后停止。本文旨在说明,如果没有足够长的时间序列,如果没有进行详细的水文地质调查,可能会出现的问题。本文以 Gornji Dušnik 泉水为例。该泉水流经苏瓦普兰纳山西部。多年前取水是为了向 Gadžin Han 镇及附近的 Donji Dušnik 和 Gornji Dušnik 村提供公共供水。
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引用次数: 0
History of the development of the hydrodynamic model of the open pit mine “Drmno”, Serbia 塞尔维亚 "Drmno "露天矿流体力学模型的发展历程
Pub Date : 2023-12-01 DOI: 10.52215/rev.bgs.2023.84.3.307
D. Polomcic, Jelena Ratković, Vesna Ristić Vakanjac
With the creation of a hydrodynamic model, the need for it usually ceases until some next moment when the model needs to be updated and used for the set task for the necessary project documentation or dedicated studies. It is relatively rare that almost every year the model is improved and used for forecast calculations. The paper presents the basic characteristics and development of the hydrodynamic model of the open pit mine “Drmno” for 25 years. This open pit mine is the second-largest mine in Serbia. At the time the model was made (1998), it was the largest and most complex model that was made in the former Yugoslavia. Also, advanced model calibration techniques were used for the first time in Serbia
随着水动力模型的建立,对模型的需求通常会停止,直到下一刻需要更新模型并将其用 于必要的项目文件或专门研究的既定任务。几乎每年都对模型进行改进并用于预测计算的情况比较少见。本文介绍了露天矿 "Drmno "水动力模型的基本特征和 25 年来的发展情况。该露天矿是塞尔维亚第二大矿山。在制作模型时(1998 年),它是前南斯拉夫最大、最复杂的模型。此外,在塞尔维亚首次使用了先进的模型校准技术
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引用次数: 0
期刊
Review of the Bulgarian Geological Society
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