G. Reyes-Castellanos, A. Cruz-Ramírez, V. Gutiérrez-Pérez, J. Rivera-Salinas, R. Sánchez-Álvarado, E. Colin-García
An initial assessment of the gray cast irons production by injecting an inoculant with a conveying gas into a molten iron bath was evaluated at a laboratory scale. A numerical simulation was carried out to determine the hydrodynamic behavior between the inoculant particles injected into the molten iron. It was determined that an optimal interaction between the particles with the molten iron occurred at a lance depth of 7 cm and for the particle sizes fine (211 to 297 ?m) and medium (421 to 590 ?m), and the residence time was of 0.38 and 0.4 s, respectively. The melting time was calculated at 0.0008 and 0.003 s for the particle sizes fine and medium, respectively. After the injection, the FeSi of the inoculant melted quickly, releasing the elements of the inoculant which interacted with the molten iron and formed oxides and sulfides creating nucleating sites during solidification. The injection technique allowed obtaining a type-A graphite distribution for the fine and medium particle sizes. The number of eutectic cells increased when the inoculant particle size decreased despite of the low graphitisers elements and manganese contents used in the gray cast iron manufacturing.
{"title":"Experimental assessment of the gray cast iron production by inoculant injection","authors":"G. Reyes-Castellanos, A. Cruz-Ramírez, V. Gutiérrez-Pérez, J. Rivera-Salinas, R. Sánchez-Álvarado, E. Colin-García","doi":"10.2298/jmmb200414035r","DOIUrl":"https://doi.org/10.2298/jmmb200414035r","url":null,"abstract":"An initial assessment of the gray cast irons production by injecting an inoculant with a conveying gas into a molten iron bath was evaluated at a laboratory scale. A numerical simulation was carried out to determine the hydrodynamic behavior between the inoculant particles injected into the molten iron. It was determined that an optimal interaction between the particles with the molten iron occurred at a lance depth of 7 cm and for the particle sizes fine (211 to 297 ?m) and medium (421 to 590 ?m), and the residence time was of 0.38 and 0.4 s, respectively. The melting time was calculated at 0.0008 and 0.003 s for the particle sizes fine and medium, respectively. After the injection, the FeSi of the inoculant melted quickly, releasing the elements of the inoculant which interacted with the molten iron and formed oxides and sulfides creating nucleating sites during solidification. The injection technique allowed obtaining a type-A graphite distribution for the fine and medium particle sizes. The number of eutectic cells increased when the inoculant particle size decreased despite of the low graphitisers elements and manganese contents used in the gray cast iron manufacturing.","PeriodicalId":51090,"journal":{"name":"Journal of Mining and Metallurgy Section B-Metallurgy","volume":"202 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77002427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Q. Gao, J. Wang, Yong Du, S. Shang, Zi-kui Liu, Y. J. Liu
Atomic structure, diffusivity and viscosity of Al1-xMgx (x=0, 0.0039, 0.1172, 0.9180, 0.9961, 1)melts at 875, 1000, 1125, and 1250K were investigated by the ab initio molecular dynamics (AIMD) simulations. The simulated results are compared with available experimental and calculated data in the literature with reasonable agreements. Considering the results of pair correlation function g(r), it can be observed that Mg atoms in Al0.8828Mg0.1172 melt aggregate more obviously at 1000 and 1250K. For Al0.0820Mg0.9180, Al atom segregation is more obvious at 875 and 1000K. The tracer diffusion coefficients of Al or Mg in Al1-xMgx (x=0.1172, 0.9180) melts, and interdiffusion coefficients of Al0.8828Mg0.1172 and Al0.0820Mg0.9180 melts are all close to the self-diffusion coefficients of Al or Mg. With the increasing temperature, the diffusivity increases linearly. In dilute melts, the tracer diffusion coefficients of solute atom and the interdiffusion coefficients increase nonlinearly with the increasing temperature. For Al0.8828Mg0.1172 and Al0.0820Mg0.9180 melts, the viscosities ? are comparatively higher than pure melts. The viscosities of all melts decrease with the increasing temperature, then increase at 1250K. The results obtained in the present work provide an insight into the design of Al and Mg alloys.
{"title":"Atomic structure, diffusivity and viscosity of Al1-xMgx melts from ab initio molecular dynamics simulations","authors":"Q. Gao, J. Wang, Yong Du, S. Shang, Zi-kui Liu, Y. J. Liu","doi":"10.2298/jmmb200807037g","DOIUrl":"https://doi.org/10.2298/jmmb200807037g","url":null,"abstract":"Atomic structure, diffusivity and viscosity of Al1-xMgx (x=0, 0.0039, 0.1172, 0.9180, 0.9961, 1)melts at 875, 1000, 1125, and 1250K were investigated by the ab initio molecular dynamics (AIMD) simulations. The simulated results are compared with available experimental and calculated data in the literature with reasonable agreements. Considering the results of pair correlation function g(r), it can be observed that Mg atoms in Al0.8828Mg0.1172 melt aggregate more obviously at 1000 and 1250K. For Al0.0820Mg0.9180, Al atom segregation is more obvious at 875 and 1000K. The tracer diffusion coefficients of Al or Mg in Al1-xMgx (x=0.1172, 0.9180) melts, and interdiffusion coefficients of Al0.8828Mg0.1172 and Al0.0820Mg0.9180 melts are all close to the self-diffusion coefficients of Al or Mg. With the increasing temperature, the diffusivity increases linearly. In dilute melts, the tracer diffusion coefficients of solute atom and the interdiffusion coefficients increase nonlinearly with the increasing temperature. For Al0.8828Mg0.1172 and Al0.0820Mg0.9180 melts, the viscosities ? are comparatively higher than pure melts. The viscosities of all melts decrease with the increasing temperature, then increase at 1250K. The results obtained in the present work provide an insight into the design of Al and Mg alloys.","PeriodicalId":51090,"journal":{"name":"Journal of Mining and Metallurgy Section B-Metallurgy","volume":"11 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84933464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Comprehensive utilization of stainless-steel slag (SSS) is restrained due to the risk of Cr6+ leaching. Based on the studying the microstructure of synthetic slag (SS) containing Cr2O3with XRD, SEM-EDS?and Image pro, the effect of binary basicity on the chromium occurrence in SSS was investigated. The results indicated that the binary basicity had a significant impact on the properties of spinel crystals. There was a positive correlation between the calcium content in spinel crystals and the SS basicity. The size of spinel crystals varied from large to small and the precipitation occurrence changed with the basicity increase. Furthermore, the chromium occurrences changed with basicity. The chromium was produced in spinel crystals at lower basicity, but as the basicity increased to 3.0, the chromium precipitated as calcium chromate. In view of the relationship between the chromium leaching behavior and its occurrence, increasing basicity raised the Cr6+ leaching.
{"title":"Effect of binary basicity on chromium occurrence in stainless steel slag","authors":"Q. Zeng, J. Li, G. Ma, Hy Y. Zhu","doi":"10.2298/jmmb210304043z","DOIUrl":"https://doi.org/10.2298/jmmb210304043z","url":null,"abstract":"Comprehensive utilization of stainless-steel slag (SSS) is restrained due to the risk of Cr6+ leaching. Based on the studying the microstructure of synthetic slag (SS) containing Cr2O3with XRD, SEM-EDS?and Image pro, the effect of binary basicity on the chromium occurrence in SSS was investigated. The results indicated that the binary basicity had a significant impact on the properties of spinel crystals. There was a positive correlation between the calcium content in spinel crystals and the SS basicity. The size of spinel crystals varied from large to small and the precipitation occurrence changed with the basicity increase. Furthermore, the chromium occurrences changed with basicity. The chromium was produced in spinel crystals at lower basicity, but as the basicity increased to 3.0, the chromium precipitated as calcium chromate. In view of the relationship between the chromium leaching behavior and its occurrence, increasing basicity raised the Cr6+ leaching.","PeriodicalId":51090,"journal":{"name":"Journal of Mining and Metallurgy Section B-Metallurgy","volume":"34 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89383263","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Amdur, E. Selivanov, S. Fedorov, V. Pavlov, S. Krasikov
Copper-nickel sulfide ores are one of the main sources of platinum. One of the ways to extract precious metals from such ores involves melting of a concentrate in electric ore smelting furnaces, where the melt is divided into matte and slag. Platinum is generally concentrated in matte; however, some its part remains in the slag, thus leading to metal losses. In order to reduce platinum losses, the forms of platinum in these phases should be studied. It was found that during the melting of this ore, iron, nickel, and copper are reduced. The mineral composition of matte has been studied. Platinum in matte is present in the form of intermetallics with Fe and Ni. The PtFe intermetallic is a dispersed needle formation with a length of 20 to 500 ?m and a thickness of up to 10 ?m. The size effect is revealed: the content of platinum in the PtFe intermetallic decreases with decreasing the thickness of needle formations. The decreases in the content of platinum in dispersed needle formations can be explained by an increase in the thermodynamic activity and changing properties of the dispersed substance and a corresponding increase in solubility. It was found that matte drops, together with their associated platinum-containing particles of no more than 5-7 ?m in size, were carried into the slag by gas bubbles using flotation. The conditions for the rise of a matte drop, together with a bubble in the slag, consist in the fact that the adhesive force of the drop with the bubble and the buoyancy force acting on the bubble must be greater than the gravity of the drop.
{"title":"Behavior of platinum in the system of the matte-slag in the processing of copper-nickel ores","authors":"A. Amdur, E. Selivanov, S. Fedorov, V. Pavlov, S. Krasikov","doi":"10.2298/JMMB200312016A","DOIUrl":"https://doi.org/10.2298/JMMB200312016A","url":null,"abstract":"Copper-nickel sulfide ores are one of the main sources of platinum. One of the ways to extract precious metals from such ores involves melting of a concentrate in electric ore smelting furnaces, where the melt is divided into matte and slag. Platinum is generally concentrated in matte; however, some its part remains in the slag, thus leading to metal losses. In order to reduce platinum losses, the forms of platinum in these phases should be studied. It was found that during the melting of this ore, iron, nickel, and copper are reduced. The mineral composition of matte has been studied. Platinum in matte is present in the form of intermetallics with Fe and Ni. The PtFe intermetallic is a dispersed needle formation with a length of 20 to 500 ?m and a thickness of up to 10 ?m. The size effect is revealed: the content of platinum in the PtFe intermetallic decreases with decreasing the thickness of needle formations. The decreases in the content of platinum in dispersed needle formations can be explained by an increase in the thermodynamic activity and changing properties of the dispersed substance and a corresponding increase in solubility. It was found that matte drops, together with their associated platinum-containing particles of no more than 5-7 ?m in size, were carried into the slag by gas bubbles using flotation. The conditions for the rise of a matte drop, together with a bubble in the slag, consist in the fact that the adhesive force of the drop with the bubble and the buoyancy force acting on the bubble must be greater than the gravity of the drop.","PeriodicalId":51090,"journal":{"name":"Journal of Mining and Metallurgy Section B-Metallurgy","volume":"36 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76720798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Using a reduced pressure during the smelting and refining of alloys removes dissolved gasses, as well as impurities with a high vapor pressure. When smelting is carried out in vacuum induction furnaces, the intensification of the discussed processes is achieved by intensive mixing of the bath, as well as an enhanced mass exchange surface (liquid metal surface) due to the formation of a meniscus. This is due to the electromagnetic field applied to the liquid metal. This study reports the removal of arsenic from blister copper via refining in an induction vacuum furnace in the temperature range of 1423-1523 K, at operating pressures from 8 to 1333 Pa. The overall mass transfer coefficient kAs determined from the experimental data ranged from 9.99?10-7 to 1.65?10-5 ms-1. Arsenic elimination was largely controlled by mass transfer in the gas phase. The kinetic analysis indicated that the arsenic evaporation rate was controlled by the combination of both liquid and gas-phase mass transfer only at a pressure of 8 Pa.
{"title":"Removal of arsenic from liquid blister copper during remelting in an induction vacuum furnace","authors":"J. Łabaj, L. Blacha, A. Smalcerz, B. Chmiela","doi":"10.2298/jmmb210108033l","DOIUrl":"https://doi.org/10.2298/jmmb210108033l","url":null,"abstract":"Using a reduced pressure during the smelting and refining of alloys removes dissolved gasses, as well as impurities with a high vapor pressure. When smelting is carried out in vacuum induction furnaces, the intensification of the discussed processes is achieved by intensive mixing of the bath, as well as an enhanced mass exchange surface (liquid metal surface) due to the formation of a meniscus. This is due to the electromagnetic field applied to the liquid metal. This study reports the removal of arsenic from blister copper via refining in an induction vacuum furnace in the temperature range of 1423-1523 K, at operating pressures from 8 to 1333 Pa. The overall mass transfer coefficient kAs determined from the experimental data ranged from 9.99?10-7 to 1.65?10-5 ms-1. Arsenic elimination was largely controlled by mass transfer in the gas phase. The kinetic analysis indicated that the arsenic evaporation rate was controlled by the combination of both liquid and gas-phase mass transfer only at a pressure of 8 Pa.","PeriodicalId":51090,"journal":{"name":"Journal of Mining and Metallurgy Section B-Metallurgy","volume":"12 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87421426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. Wei, Xiaoyong Zhou, Fengkun Li, M. Li, Shuqin Li, Pingze Zhang
To improve the wear resistance of ?-TiAl alloy, Ta alloy layer was prepared on surface by double glow plasma surface alloying technique. The tribology behavior of Ta alloy layer against Si3N4 at 25?, 350? and 500? were comparatively studied. The results showed that Ta alloy layer comprised a deposition layer and a diffusion layer. The deposition layer played a role in protection as a soft film. With the increase of temperature, the wear mechanism of ?-TiAl changed from abrasive wear to coexistence of abrasive wear and oxidation wear. Ta alloy layer?s wear mechanism changed from adhesive wear to coexistence of adhesive wear and oxidation wear. Surface Ta alloying process significantly reduced the wear volume, the specific wear rate and the friction coefficient of ?-TiAl and improved the wear resistance properties of ?-TiAl.
{"title":"Effects of plasma surface Ta alloying on the tribology behavior of γ-TiAl","authors":"D. Wei, Xiaoyong Zhou, Fengkun Li, M. Li, Shuqin Li, Pingze Zhang","doi":"10.2298/JMMB200617002W","DOIUrl":"https://doi.org/10.2298/JMMB200617002W","url":null,"abstract":"To improve the wear resistance of ?-TiAl alloy, Ta alloy layer was prepared on surface by double glow plasma surface alloying technique. The tribology behavior of Ta alloy layer against Si3N4 at 25?, 350? and 500? were comparatively studied. The results showed that Ta alloy layer comprised a deposition layer and a diffusion layer. The deposition layer played a role in protection as a soft film. With the increase of temperature, the wear mechanism of ?-TiAl changed from abrasive wear to coexistence of abrasive wear and oxidation wear. Ta alloy layer?s wear mechanism changed from adhesive wear to coexistence of adhesive wear and oxidation wear. Surface Ta alloying process significantly reduced the wear volume, the specific wear rate and the friction coefficient of ?-TiAl and improved the wear resistance properties of ?-TiAl.","PeriodicalId":51090,"journal":{"name":"Journal of Mining and Metallurgy Section B-Metallurgy","volume":"3 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88259423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Slag viscosity is essential in high-temperature metallurgical processes. However, a slag viscosity model is difficult to exactly interpret as it has a strong nonlinear relation with its composition and temperature. In this paper, genetic programming (GP) was employed to derive a CaO-SiO2-Al2O3slag viscosity equation. The equation was automatically described as a simple algebraic equation with the basicity and content of Al2O3and temperature. The average relative error between the values obtained by the equation and the experimental data used for its derivation was as low as 17.1%. Computer simulations were performed to evaluate the accuracy of the derived viscosity equation and were then compared with many experimental viscosities and calculated values of other researchers. Slag compositions and temperatures for simulation calculations were the experimental data which were not used for deriving aviscosity equation. Our results showed that the viscosity equation was relatively exact. The viscosities of CaO-SiO2-Al2O3system slag could be simply and expediently predicted with in the wide range of compositions and temperatures by using the derived viscosity equation.
{"title":"Derivation of CaO-SiO2-Al2O3system slag viscosity equation by GP","authors":"Shen Ri, Junghwa Ra, K. Ryom, U.-D. Kim","doi":"10.2298/JMMB190919027R","DOIUrl":"https://doi.org/10.2298/JMMB190919027R","url":null,"abstract":"Slag viscosity is essential in high-temperature metallurgical processes. However, a slag viscosity model is difficult to exactly interpret as it has a strong nonlinear relation with its composition and temperature. In this paper, genetic programming (GP) was employed to derive a CaO-SiO2-Al2O3slag viscosity equation. The equation was automatically described as a simple algebraic equation with the basicity and content of Al2O3and temperature. The average relative error between the values obtained by the equation and the experimental data used for its derivation was as low as 17.1%. Computer simulations were performed to evaluate the accuracy of the derived viscosity equation and were then compared with many experimental viscosities and calculated values of other researchers. Slag compositions and temperatures for simulation calculations were the experimental data which were not used for deriving aviscosity equation. Our results showed that the viscosity equation was relatively exact. The viscosities of CaO-SiO2-Al2O3system slag could be simply and expediently predicted with in the wide range of compositions and temperatures by using the derived viscosity equation.","PeriodicalId":51090,"journal":{"name":"Journal of Mining and Metallurgy Section B-Metallurgy","volume":"164 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86742761","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mechanical soft reduction (MSR) is an effective method for elimination of the centerline segregation and porosity of the continuous casting steel slab, and the reduction amount is a key parameter that determines whether the MSR could be applied successfully. In the present work, a 2D heat transfer model was developed for predicting the non-uniform solidification of the wide-thick slab. The measured shell thickness by nail shooting experiment and the measured slab surface temperature by infrared camera were applied to validate the 2D heat transfer model. A new calculation method of theoretical reduction amount that could consider the influence of non-uniform solidification of the wide-thick slab was then derived. Based on the predicted temperature field by the 2D heat transfer model and the newly-proposed calculation method, the required theoretical reduction amount and reduction gradient/rate for the wide-thick slab were calculated and discussed. The difference between the newly-proposed method and the previous method, the influence of the casting speed and slab thickness on the required theoretical reduction amount and reduction gradient/rate were also investigated.
{"title":"A new method for determination of the theoretical reduction amount for wide-thick slab during the mechanical reduction process","authors":"C. Wu, J. Zeng, G.-R. Wu, X. Xie, M. Zhang","doi":"10.2298/JMMB200622010W","DOIUrl":"https://doi.org/10.2298/JMMB200622010W","url":null,"abstract":"Mechanical soft reduction (MSR) is an effective method for elimination of the centerline segregation and porosity of the continuous casting steel slab, and the reduction amount is a key parameter that determines whether the MSR could be applied successfully. In the present work, a 2D heat transfer model was developed for predicting the non-uniform solidification of the wide-thick slab. The measured shell thickness by nail shooting experiment and the measured slab surface temperature by infrared camera were applied to validate the 2D heat transfer model. A new calculation method of theoretical reduction amount that could consider the influence of non-uniform solidification of the wide-thick slab was then derived. Based on the predicted temperature field by the 2D heat transfer model and the newly-proposed calculation method, the required theoretical reduction amount and reduction gradient/rate for the wide-thick slab were calculated and discussed. The difference between the newly-proposed method and the previous method, the influence of the casting speed and slab thickness on the required theoretical reduction amount and reduction gradient/rate were also investigated.","PeriodicalId":51090,"journal":{"name":"Journal of Mining and Metallurgy Section B-Metallurgy","volume":"17 1","pages":"125-136"},"PeriodicalIF":1.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88766554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
W. Gierlotka, W. Gasior, A. Dębski, Miłosz Zabrocki
The binary In - Li system is a promising Li-ion battery anode material as well as a part of the important ternary Ge - In - Li system. The thermodynamic descriptions of metallic systems are widely used to retrieve information necessary for alloy applications. In this work, a thermodynamic model of a binary indium - lithium system prepared by the Calphad approach is proposed. The liquid phase was described by an associate model, and the solid phases determined by the ab-initio calculation were included in thermodynamic modeling. The obtained set of self-consistent thermodynamic parameters well reproduces the available experimental data and enables further calculations of multi-component systems. A good agreement between the calculations and the available experimental data was found. The proposed model can be used for further descriptions of ternary systems.
二元In - Li体系是锂离子电池极具发展前景的负极材料，也是重要的三元Ge - In - Li体系的组成部分。金属系统的热力学描述被广泛用于检索合金应用所需的信息。本文提出了用calphhad法制备二元铟锂体系的热力学模型。液相由关联模型描述，固相由从头算法确定纳入热力学模型。所得到的自洽热力学参数集很好地再现了现有的实验数据，为进一步计算多组分系统提供了可能。计算结果与实验数据吻合较好。所提出的模型可用于进一步描述三元体系。
{"title":"Thermodynamic modelling of the binary indium-lithium system, a promising li-ion battery material","authors":"W. Gierlotka, W. Gasior, A. Dębski, Miłosz Zabrocki","doi":"10.2298/jmmb210205041g","DOIUrl":"https://doi.org/10.2298/jmmb210205041g","url":null,"abstract":"The binary In - Li system is a promising Li-ion battery anode material as well as a part of the important ternary Ge - In - Li system. The thermodynamic descriptions of metallic systems are widely used to retrieve information necessary for alloy applications. In this work, a thermodynamic model of a binary indium - lithium system prepared by the Calphad approach is proposed. The liquid phase was described by an associate model, and the solid phases determined by the ab-initio calculation were included in thermodynamic modeling. The obtained set of self-consistent thermodynamic parameters well reproduces the available experimental data and enables further calculations of multi-component systems. A good agreement between the calculations and the available experimental data was found. The proposed model can be used for further descriptions of ternary systems.","PeriodicalId":51090,"journal":{"name":"Journal of Mining and Metallurgy Section B-Metallurgy","volume":"25 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74612522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The present work represents a comparative study on the impurities removal from pig iron melt by addition of partially reduced highly fluxed direct reduced iron (DRI) to make steel in a 2 kg capacity electric arc furnace (EAF). Three types of fluxed DRI (30, 50, 80% Reduction (%R) with similar basicity-8) were used to maintain different level of oxidizing potential on the bath for studying the kinetic behaviour of impurities removal from melt. Results showed that the rate of removal of impurities (i.e. C, Si, Mn, P, S etc.) was increased initially up to 5 minutes of reaction time then decreased afterwards. Phosphorus (~64%), sulfur (~16%) and carbon (~94%) were removed simultaneously up to 25 minutes of reaction time using 30%R fluxed DRI. Similarly, phosphorus (~33%), sulfur (~50%) and carbon (~62%) were removed simultaneously using 50%R fluxed DRI while highly reduced (80%R) flux DRI removed sulfur (~58%), carbon (~56%) with a small fraction of phosphorus (~18%) from pig iron. It was observed in all the cases that silicon (>99%) and manganese (>80%) were removed. From the present study, it can be concluded that ~30%R DRI is favorable for effective phosphorus removal whereas ~80%R is favorable for sulfur removal. The significant removal of impurities could be achieved by charging ~50%R fluxed DRI in the pig iron melt.
{"title":"Effect of partially reduced highly fluxed DRI pellets on impurities removal during steelmaking using a laboratory scale EAF","authors":"R. K. Dishwar, O. P. Sinha","doi":"10.2298/jmmb210319050d","DOIUrl":"https://doi.org/10.2298/jmmb210319050d","url":null,"abstract":"The present work represents a comparative study on the impurities removal from pig iron melt by addition of partially reduced highly fluxed direct reduced iron (DRI) to make steel in a 2 kg capacity electric arc furnace (EAF). Three types of fluxed DRI (30, 50, 80% Reduction (%R) with similar basicity-8) were used to maintain different level of oxidizing potential on the bath for studying the kinetic behaviour of impurities removal from melt. Results showed that the rate of removal of impurities (i.e. C, Si, Mn, P, S etc.) was increased initially up to 5 minutes of reaction time then decreased afterwards. Phosphorus (~64%), sulfur (~16%) and carbon (~94%) were removed simultaneously up to 25 minutes of reaction time using 30%R fluxed DRI. Similarly, phosphorus (~33%), sulfur (~50%) and carbon (~62%) were removed simultaneously using 50%R fluxed DRI while highly reduced (80%R) flux DRI removed sulfur (~58%), carbon (~56%) with a small fraction of phosphorus (~18%) from pig iron. It was observed in all the cases that silicon (>99%) and manganese (>80%) were removed. From the present study, it can be concluded that ~30%R DRI is favorable for effective phosphorus removal whereas ~80%R is favorable for sulfur removal. The significant removal of impurities could be achieved by charging ~50%R fluxed DRI in the pig iron melt.","PeriodicalId":51090,"journal":{"name":"Journal of Mining and Metallurgy Section B-Metallurgy","volume":"42 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89108997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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