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Insight on the reduction of copper content in slags produced from the Ausmelt Converting Process 关于降低奥斯梅尔特转炉生产的炉渣中铜含量的见解
IF 1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.2298/JMMB201016013Y
H. Yuan, B. Cai, Xiaocong Song, Ding Tang, B. Yang
The reduction of copper content in converting slag using process control is significant to copper smelter. In this study, the slags produced from the Ausmelt Converting Process for copper matte have been analyzed using X-ray diffraction and chemical analysis. Thermodynamic calculation and effects of various conditions including the lance submerging depth in molten bath, the molten bath temperature, the addition of copper matte, and airflow rate were carried out to lower the content in the slag. Thermodynamic analysis indicates that the decrease of copper content was achieved by reducing Fe3O4, CuFe2O4and Cu2O in the slag, decreasing the magnetism of slag and lowering the viscosity of slag, which is feasible at the operating temperature of the molten bath. Experiments show that the optimal combination of operating conditions were found to be the addition of copper matte between 5000 -7000 kg/h, a lance airflow rate of 13000-14000 Nm3/h and a lance submergence depth into the molten bath of 700-900 mm, in which the copper content in the slag can be effectively reduced from 22.74 wt. % to 7.70 wt. %.This study provides a theoretical support and technical guidance for promoting the utilization of slags from the Ausmelt Converting Process.
利用过程控制降低转炉渣中铜的含量对铜冶炼厂具有重要意义。本文采用x射线衍射和化学分析的方法对铜锍奥斯梅尔特转化过程中产生的炉渣进行了分析。通过热力学计算,分析了钢枪在熔池中浸入深度、熔池温度、铜锍的加入、气流速率等条件对降低渣中含量的影响。热力学分析表明,通过降低炉渣中的Fe3O4、cufe2o4和Cu2O,降低炉渣磁性,降低炉渣粘度来降低铜含量,在熔浴操作温度下是可行的。试验结果表明,最佳操作条件组合为:铜锍添加量为5000 ~ 7000 kg/h,喷枪气流速率为13000 ~ 14000 Nm3/h,喷枪浸入熔池深度为700 ~ 900 mm,可有效地将渣中铜含量从22.74 wt. %降低到7.70 wt. %。本研究为促进奥斯梅尔特炉渣资源化利用提供了理论支持和技术指导。
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引用次数: 1
Solubility of CO2 in molten Li2Co3-LiCl CO2在熔融Li2Co3-LiCl中的溶解度
IF 1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.2298/JMMB200426024H
Xianwei Hu, W.-T. Deng, Zhongning Shi, Liu Aimin, Jiang-yu Yu, Z.-W. Wang
Solubility of CO2 in molten Li2CO3-LiCl was measured by using a pressure differential method and the enthalpy change of the solution was calculated on that basis. The relationships between the solubility and the enthalpy change, and the temperature and the composition of the melts were discussed. The results showed that when the temperature was 873-923K and the Li2CO3content was 10-50 mol%, the solubility of CO2 increased with decreasing temperature and/or increasing Li2CO3 content.The maximum solubility was 3.965 ? 10?7gCO2/gmelt at 873Kwhen the content of Li2CO3 was 50 mol%. The solution of CO2was exothermic. With increasing temperature and Li2CO3content,more enthalpy was needed for CO2 solution.
采用压差法测定CO2在熔融Li2CO3-LiCl中的溶解度,并在此基础上计算溶液的焓变。讨论了熔体的溶解度与焓变、温度和组成之间的关系。结果表明:当温度为873 ~ 923k, Li2CO3含量为10 ~ 50 mol%时,CO2的溶解度随温度的降低和Li2CO3含量的增加而增加;最大溶解度为3.965 ?10 ?当Li2CO3的含量为50 mol%时,在873k下熔化7gCO2/g。二氧化碳的溶液是放热的。随着温度的升高和li2co3含量的增加,CO2溶液所需焓增大。
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引用次数: 0
Study on the kinetics of gas-solid based synergistic reduction of limonite carbon-containing pellets 褐铁矿含碳球团气固协同还原动力学研究
IF 1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.2298/JMMB200510017G
Gao Guofeng, Zhou Xiaolei, Zhe Shi, L.-P. Liu
The gas-solid-based synergistic reduction of pellets is an innovative and effective method for iron ore smelting. With the development and utilization of iron resources, ore reserves have been greatly depleted; therefore, as a lean mineral resource, the comprehensive utilization of limonite has become increasingly important. To study the reduction kinetics of pellets in depth, this study used coke and reducing gases (CO and H2) to study the reduction characteristics and changes occurring in carbon-containing limonite pellets. The results showed that the total weight loss percentage of pellets gradually increased with the temperature. The C/O molar ratio had a greater effect on the total weight loss percentage of pellets in a N2atmosphere, but it had no significant effect in CO or H2atmospheres. The maximum reaction rate increased with increasing temperature. The reduction reaction was the most difficult to proceed in the N2atmosphere, and the reaction was most likely to occur in the CO atmosphere. The analysis of pellets by EPMA and XRD found that the pellets reduced in the N2atmosphere had the lowest porosity, and the pellets reduced in the H2atmosphere had the highest porosity, which is more conducive to gas diffusion. Some of the unreduced Si, Al, Mn, Ca, and Fe in the pellets reduced in the N2atmosphere precipitated in the form of oxides, but when a reducing gas (CO, H2) was introduced, precipitation did not occur.
气固协同还原球团法是一种创新而有效的铁矿冶炼方法。随着铁矿资源的开发利用,铁矿石储量已大大枯竭;因此,褐铁矿作为一种贫矿资源,其综合利用变得越来越重要。为了深入研究球团的还原动力学,本研究采用焦炭和还原性气体(CO和H2)研究了含碳褐铁矿球团的还原特性和变化。结果表明,随着温度的升高,球团的总失重率逐渐升高。在n2气氛下,C/O摩尔比对球团总失重率的影响较大,而在CO和h2o2气氛下对球团总失重率的影响不显著。最大反应速率随温度升高而增大。还原反应在n2气氛中最难进行,在CO气氛中最容易发生。通过EPMA和XRD对球团进行分析发现,在n2气氛下还原的球团孔隙率最低,在h2o2气氛下还原的球团孔隙率最高,更有利于气体扩散。在n2气氛中还原的球团中,部分未还原的Si、Al、Mn、Ca和Fe以氧化物的形式析出,但当引入还原性气体(CO、H2)时,不发生析出。
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引用次数: 1
Recovery of zinc from zinc oxide dust containing multiple metal elements by carbothermal reduction 碳热还原法从含多种金属元素的氧化锌粉尘中回收锌
IF 1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.2298/jmmb201102049l
F.-G. Lei, Li Minting, C. Wei, Deng Zhigan, Li Xingbin, Gang Fan
A carbothermal reduction process simulating EAF process is used to handle the zinc oxide dust, and the zinc in the dust can be extracted and recovered efficiently. The crude zinc and lead-tin alloy were obtained finally. The effects of temperature, holding time, and reductant dosage on zincvolatilization rate were investigated, and the ?Pelletizing -Calcination-Carbothermic reduction? experiment was conducted. The resultsfound the optimal reduction condition was as follows: the temperature of 1300?C, reductant dosage of 14.04% and holding time of 120 min. After the calcination at 900?C for 120 min, the removal rates of fluorine, chlorine and sulfur in the dust were 98.18%, 96.38% and 28.58% respectively, and the volatilization rate of zinc was 99.83% in reduction process. The zinc content of the crude zinc was 68.48%.
采用模拟电弧炉工艺的碳热还原法处理氧化锌粉尘,可有效地提取和回收粉尘中的锌。最后得到粗锌和铅锡合金。考察了温度、保温时间和还原剂用量对锌挥发速率的影响,并对球团-煅烧-碳热还原过程进行了研究。进行了实验。结果发现,最佳还原条件为:温度为1300℃;C,还原剂用量为14.04%,保温时间为120 min。还原过程中氟、氯和硫的去除率分别为98.18%、96.38%和28.58%,锌的挥发率为99.83%。粗锌的锌含量为68.48%。
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引用次数: 0
Magnesium extraction of ferronickel slag processed by alkali fusion and hydrochloric acid leaching 碱熔-盐酸浸出法处理镍铁渣的提镁
IF 1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.2298/JMMB200224018P
A. Prasetyo, A. Khaerul, W. Mayangsari, E. Febriana, A. Maksum, J. Andinie, F. Firdiyono, J. Soedarsono
A research using ferronickel slag, the by-product of ferronickel production, as raw material for magnesium extraction has been carried out. It is essential to upgrade the value of ferronickel slag instead of used directly for reclamation materials. Moreover, accumulation due to increasing ferronickel demand as well as environmental contamination due to various potencially toxic elements contained in the ferronickel slag could be prevented. The general objective of this study is to utilize the ferronickel slag for magnesium materials. The specific objective is to determine the optimum conditions of magnesium extraction in the process of alkali fusion followed by hydrochloric acid leaching. A novel method for magnesium extraction from ferronickel slag was carried out through reducing silica content followed by acid leaching method. Alkali fusion of the mixture of ferronickel slag and Na2CO3 at 1000 ?C for 60 minutes followed by water leaching at 100 ?C for 60 minutes with solid to liquid percentage of 20 % were carried out to separate the silica. The leaching residue resulted from water leaching was then leached using hydrochloric aid solution to extract magnesium. The leaching temperature and time as well as the hycrochloric acid concentration were varied in the acid leaching process. Alkali fusion process proved can be generated the sodium silicate that can be separated in the water leaching to the leached solution. Meanwhile, the leaching residue was leached using hydrochloric acid to extract the magnesium. The highest magnesium extraction percentage is 82.67% that resulted from an optimum acid leaching condition with temperature of 80 ?C for 30 minutes using 2M HCl solution. Based on the kinetics study, the activation energy (Ea) for the leaching reaction of magnesium at atmospheric pressure between 32?C to 80?C is 9.44 kJ/mol and affected by diffusion and chemical reactions.
以镍铁生产副产物镍铁渣为原料进行了提镁研究。提高镍铁渣的利用价值,而不是直接作为回收材料。此外,还可以防止镍铁渣中各种潜在有毒元素对环境的污染。本研究的总体目标是利用镍铁渣制备镁材料。具体目的是确定碱熔后盐酸浸出工艺中提取镁的最佳条件。采用酸浸法先降低氧化硅含量,再从镍铁渣中提取镁。将镍铁渣与Na2CO3的混合物在1000℃下碱熔60分钟,然后在100℃下以固液比20%的比例水浸60分钟,分离出二氧化硅。然后用盐酸助浸液对水浸渣进行浸出,提取镁。酸浸过程中,浸出温度、浸出时间和盐酸浓度都发生了变化。经证明,碱熔工艺可产生水玻璃,水玻璃可在浸出液中分离出来。同时,对浸出渣进行盐酸浸出,提取镁。最佳酸浸条件为:温度为80℃,盐酸浓度为2M,酸浸时间为30 min,镁的提取率为82.67%。在动力学研究的基础上,得到了常压下32?摄氏到八十度?C为9.44 kJ/mol,受扩散和化学反应的影响。
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引用次数: 2
Thermodynamic behavior of dissolved oxygen and hydrogen in pure vanadium 纯钒中溶解氧和氢的热力学行为
IF 1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.2298/jmmb210108037z
D. Zhong, Guishang Pei, J. Xiang, C. Pan, W. Gu, X. Lv
The mechanism governing the deoxidation of vanadium metal is regarded as fundamental knowledge; however, it has not been elucidated in existing literature. In this paper, the thermodynamic data of V-H-O systems were summarized, and the Gibbs free energies of the main compounds were calculated. Consequently, the deoxidation limits of different reductants in a V-O system were evaluated, namely: Si, Al, and Mg. It was observed that Si cannot remove an O content of less than 7.27 wt% from V. However, Al was the stronger reducing agent; it could remove O contents of up to 0.01 and 0.1 wt% at 800 and 1050 ?C, respectively. Nevertheless, Mg exhibited the best reducing properties as it could remove less than 0.01 wt% of O at 1100 ?C. The addition of H2 renders the V-O solid solution unstable to a certain extent, thereby indicating that H2 facilitates deoxygenation. Furthermore, the results obtained by analyzing the equilibrium conditions were in accordance with the results of the deoxidation limit in the V-O system. In other words, this study demonstrates that the oxygen in vanadium can be effectively controlled by changing the reductant dosage and temperature.
钒金属的脱氧机理被认为是基本知识;然而,在现有文献中尚未得到阐明。本文总结了V-H-O体系的热力学数据,并计算了主要化合物的吉布斯自由能。因此,不同的还原剂在一个V-O系统的脱氧极限进行了评估,即:Si, Al和Mg。结果表明,Si对v中O的去除率低于7.27 wt%,而Al是较强的还原剂;在800℃和1050℃下,O的去除率分别高达0.01 wt%和0.1 wt%。然而,Mg表现出最好的还原性能,在1100℃时,它可以去除少于0.01 wt%的O。H2的加入使V-O固溶体在一定程度上变得不稳定,说明H2有利于脱氧。平衡条件分析结果与V-O体系脱氧极限分析结果吻合较好。也就是说,本研究表明,通过改变还原剂的用量和温度,可以有效地控制钒中的氧。
{"title":"Thermodynamic behavior of dissolved oxygen and hydrogen in pure vanadium","authors":"D. Zhong, Guishang Pei, J. Xiang, C. Pan, W. Gu, X. Lv","doi":"10.2298/jmmb210108037z","DOIUrl":"https://doi.org/10.2298/jmmb210108037z","url":null,"abstract":"The mechanism governing the deoxidation of vanadium metal is regarded as fundamental knowledge; however, it has not been elucidated in existing literature. In this paper, the thermodynamic data of V-H-O systems were summarized, and the Gibbs free energies of the main compounds were calculated. Consequently, the deoxidation limits of different reductants in a V-O system were evaluated, namely: Si, Al, and Mg. It was observed that Si cannot remove an O content of less than 7.27 wt% from V. However, Al was the stronger reducing agent; it could remove O contents of up to 0.01 and 0.1 wt% at 800 and 1050 ?C, respectively. Nevertheless, Mg exhibited the best reducing properties as it could remove less than 0.01 wt% of O at 1100 ?C. The addition of H2 renders the V-O solid solution unstable to a certain extent, thereby indicating that H2 facilitates deoxygenation. Furthermore, the results obtained by analyzing the equilibrium conditions were in accordance with the results of the deoxidation limit in the V-O system. In other words, this study demonstrates that the oxygen in vanadium can be effectively controlled by changing the reductant dosage and temperature.","PeriodicalId":51090,"journal":{"name":"Journal of Mining and Metallurgy Section B-Metallurgy","volume":"9 1","pages":""},"PeriodicalIF":1.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87938755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The application of citric acid solutions for selective removal of zinc from steelmaking dust 柠檬酸溶液在炼钢粉尘中选择性脱除锌的应用
IF 1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.2298/JMMB200630012G
Krzysztof Gargul, P. Handzlik, P. Palimąka, A. Pawlik
Steelmaking dust is one of the wastes which are produced by ironworks. This kind of waste is a byproduct made mainly in electric arc furnace. Zinc content in dust is different and depends on the charge processed in the furnace. The basic technology used for recycling steelmaking dust is Waelz process however it requires a large amount of reducer and generates a lot of waste which need to be stored. First stage in this study was to analyze if steelmaking dust is safe to be exposed for atmospheric conditions. To verify this subject the dust exposed for two kinds of leaching, in standards of TCLP and EN-12457-2. The amount of extracted elements was too large that's why steelmaking dust must be treated as dangerous waste. Leaching in citric acid solutions was divided in four series. The first one was set to determine the time and temperature for most selective zinc leaching. Next series optimized three leaching parameters which were: citric acid concentration, liquid to solid phase ratio (l/s), and the stirring speed. Performed experiments showed the optimal conditions for selective leaching: temperature of 50 ?C, leaching time of 60 minutes, citric acid concentration of 0.5 mol/dm3, l/s ratio of 10, and stirring speed of 250 rpm.
炼钢粉尘是炼铁企业产生的废弃物之一。这种废料主要是电弧炉产生的副产品。粉尘中的锌含量不同,取决于炉内处理的炉料。回收炼钢粉尘的基本技术是Waelz法,但它需要大量的减速机,产生大量的废物,需要储存。本研究的第一阶段是分析炼钢粉尘在大气条件下暴露是否安全。为了验证这一课题,在TCLP和EN-12457-2的标准中,暴露于两种浸出的粉尘。提取的元素量太大,这就是为什么炼钢粉尘必须作为危险废物处理。在柠檬酸溶液中浸出分为四个系列。第一个是用来确定大多数选择性锌浸出的时间和温度。接着对柠檬酸浓度、液固比(l/s)和搅拌速度三个浸出参数进行了优化。实验结果表明,选择性浸出的最佳条件为:温度50℃,浸出时间60 min,柠檬酸浓度0.5 mol/dm3, l/s比为10,搅拌转速250 rpm。
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引用次数: 1
Reduction behavior of iron in the red mud 赤泥中铁的还原行为
IF 1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.2298/jmmb210227039e
S. Eray, E. Keskinkilic, Y. Topkaya, A. Geveci
Red mud or bauxite residue contains significant quantities of industrial metals such as Fe, Al and Ti, and rare earths such as Sc, Ce, and La. The authors performed a laboratory-scale project work dealing with stepwise recovery of valuable elements from two bauxite residues, namely Iranian red mud (IRM) and Turkish red mud (TRM). In the first stage, it was tried to recover iron which is present in large quantities in red mud. Two different methods have been investigated for this purpose: 1) solid state reduction followed by wet magnetic separation, 2) smelting. In the scope of this paper, some results of pyrometallurgical part of this project are presented. According to solid-state reduction experiments, it was found that more excess coal was needed for IRM (35%) than TRM (15%) to maximize iron reduction. Temperature had significant effect on the reduction process and metallization increased from about 70% to about 95% when the temperature was raised from 1000 to 1200?C. Metallization degree was reported to be slightly higher for IRM (96.2%) than TRM (94.1%). The results demonstrated that a high degree of iron metallization can be achieved regardless of the chemical and mineralogical composition of the bauxite residue sample.
赤泥或铝土矿渣含有大量的工业金属,如铁、铝和钛,以及稀土,如Sc、Ce和La。作者进行了一个实验室规模的项目工作,处理从两种铝土矿残留物,即伊朗赤泥(IRM)和土耳其赤泥(TRM)中逐步回收有价元素。在第一阶段,试图回收大量存在于赤泥中的铁。为此研究了两种不同的方法:1)固态还原,然后是湿式磁选,2)熔炼。在本文的范围内,介绍了该项目火法冶炼部分的一些成果。通过固态还原实验发现,为了最大限度地还原铁,IRM(35%)比TRM(15%)需要更多的多余煤。温度对还原过程有显著影响,当温度从1000℃升高到1200℃时,金属化率从70%左右提高到95%左右。金属化程度IRM(96.2%)略高于TRM(94.1%)。结果表明,无论铝土矿渣样品的化学和矿物组成如何,都可以实现高程度的铁金属化。
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引用次数: 0
Erratum to: Atomic mobility in titanium grade 5 (Ti6Al4V) 5级钛(Ti6Al4V)原子迁移率勘误
IF 1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.2298/jmmb2102295e
E. Editorial
This erratum concerns a correction in the author name and affiliation of the original article [1] on page 65 and 77.

Link to the corrected article 10.2298/JMMB180620030G
此勘误涉及第65页和第77页原始文章[1]的作者姓名和隶属关系的更正。链接到更正文章10.2298/JMMB180620030G
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引用次数: 0
Effect of casting and rolling process parameters on solidification welding line of magnesium alloy 铸造和轧制工艺参数对镁合金凝固焊接线的影响
IF 1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2021-01-01 DOI: 10.2298/jmmb210305042h
Z. Huang, Hongyu Lai, H.-B. Zhou, H. Guo
Process of horizontal twin roll casting magnesium alloy was analyzed by numerical simulation. Taking solidification welding line in cast rolling area as research object, the characteristic change of solidification welding line caused by casting rolling temperature, casting rolling speed and roll heat transfer capacity and its influence on the forming process of casting rolling area were analyzed. The results show that increasing casting temperature, casting speed or reducing heat transfer capacity of roll can make solidification welding line shift to exit of casting rolling zone. Increasing casting temperature and casting speed will increase difference between middle and edge of the solidification welding line along casting direction. And heat distribution of whole slab is more uniform. However, effect of improving heat transfer capacity of roll is completely opposite. According to this, optimum process parameters of casting and rolling magnesium alloy with plate thickness of 6 mm are put forward to reduce probability of edge crack.
采用数值模拟方法对镁合金水平双辊铸造工艺进行了分析。以铸轧区凝固焊缝为研究对象,分析了铸轧温度、铸轧速度和轧辊换热能力对凝固焊缝特性的影响及其对铸轧区成形过程的影响。结果表明,提高浇注温度、提高浇注速度或降低轧辊的换热能力均可使凝固焊接线向铸件轧制区出口移动。提高浇注温度和浇注速度会增大凝固焊缝沿浇注方向的中边缘差。整个板的热分布更加均匀。而提高轧辊换热能力的效果则完全相反。在此基础上,提出了板厚为6 mm的镁合金铸造和轧制的最佳工艺参数,以降低边缘裂纹的发生概率。
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引用次数: 1
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Journal of Mining and Metallurgy Section B-Metallurgy
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