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Does phosphite accelerate the phosphorus cycle in freshwater ecosystems? 亚硝酸盐会加速淡水生态系统中的磷循环吗?
IF 8.2 2区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-09-20 DOI: 10.1016/j.wroa.2025.100417
Wenqiang Zhang , Songjie Han , Baoqing Shan , Quan Zhou
Phosphite is supposed to an essential compound for the origin of early life, and exist as the main form of phosphorus (P) in the P cycle of ancient anoxic marine environments. Recent researches have discovered the presence of phosphite in contemporary aquatic ecosystems, considering its utilization by microorganisms via assimilatory and dissimilatory phosphite oxidation, as well as the indirect photooxidization to orthophosphate by ultraviolet light, which indicate the potential contribution of phosphite for P cycle in modern earth. Given its high solubility, phosphite is believed to expedite P transformations in freshwater aquatic environments, particularly in lacustrine systems. Compared to oceans, these systems have shallower waters, which favor the rapid transport of released phosphite from reducing sediments to surface water. This is especially significant if the sediment is a major production site for phosphite, indicating that its role in the P cycle might have been previously understated.
亚磷酸盐被认为是早期生命起源所必需的化合物,在古代缺氧海洋环境的磷循环中以磷的主要形式存在。近年来的研究发现,现代水生生态系统中存在亚磷酸盐,考虑到其被微生物通过同化和异化亚磷酸盐氧化利用,以及被紫外光间接光氧化为正磷酸盐,这表明亚磷酸盐对现代地球磷循环的潜在贡献。鉴于其高溶解度,亚磷酸盐被认为可以加速淡水水生环境中磷的转化,特别是在湖泊系统中。与海洋相比,这些系统的水域较浅,有利于亚硝酸酯从还原性沉积物快速运输到地表水。如果沉积物是亚磷酸盐的主要生产场所,这一点尤为重要,这表明它在P循环中的作用以前可能被低估了。
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引用次数: 0
Flow configuration shapes microbiome assembly and function in full-scale drinking water BAC filters 流动配置形状微生物组组装和功能在全尺寸饮用水BAC过滤器
IF 8.2 2区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-09-17 DOI: 10.1016/j.wroa.2025.100411
Hong Wang , Kaiyang Jiang , Jinhao Yang , Yuxing Hu , Min Rui , Yueyi Wang , Yinyin Ye
To address the challenges of traditional down-flow biological activated carbon (BAC) filters, up-flow filters have been increasingly applied in drinking water treatment plants (DWTPs), yet their microbial characteristics and underlying assembly mechanisms are not fully explored. This study presents the first comprehensive comparison of bacterial and eukaryotic communities, functional traits, ecological interactions and assembly mechanisms in up-flow and down-flow BAC filters across 18 full-scale DWTPs spanning diverse geographic and operational contexts in China. Despite site-specific variability, distinct bacterial and eukaryotic community structures were observed between the two configurations (ANOSIM, R=0.345-0.353, P < 0.05), highlighting the strong influence of filter design on microbiomes. Functional gene profiling revealed significant enrichment of high-abundance pathways related to carbon, sulfur, and nitrogen metabolism in up-flow filters (P<0.05), indicating elevated biogeochemical activity. HAllA and network analyses revealed the pivotal role of eukaryotes in structuring microbial interactions and uncovered distinct cross-domain interaction patterns between filter types. Community assembly analysis showed deterministic processes dominated BAC microbiomes, with significantly stronger homogeneous selection in up-flow systems (P < 0.05). Together, these findings provide new ecological insights into BAC filter microbiomes and support the broader adoption of up-flow designs to enhance treatment performance and microbial stability in full-scale DWTPs.
为了解决传统的下流式生物活性炭(BAC)过滤器的挑战,上流式过滤器在饮用水处理厂(dwtp)中得到越来越多的应用,但其微生物特性和潜在的组装机制尚未得到充分的探讨。本研究首次全面比较了中国18个不同地理和操作环境的全规模dwtp上、下流式BAC过滤器中的细菌和真核生物群落、功能特征、生态相互作用和组装机制。尽管存在位点特异性差异,但在两种配置之间观察到不同的细菌和真核生物群落结构(ANOSIM, R=0.345-0.353, P < 0.05),突出了过滤器设计对微生物组的强烈影响。功能基因谱分析显示,上流式过滤器中碳、硫和氮代谢相关的高丰度途径显著富集(P<0.05),表明生物地球化学活性升高。HAllA和网络分析揭示了真核生物在构建微生物相互作用中的关键作用,并揭示了过滤器类型之间不同的跨域相互作用模式。群落组装分析显示,确定性过程主导BAC微生物组,在上游系统中具有显著更强的均匀选择(P < 0.05)。总之,这些发现为BAC过滤器微生物群提供了新的生态学见解,并支持更广泛地采用向上流设计来提高全尺寸dwtp的处理性能和微生物稳定性。
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引用次数: 0
Low-cost, data-efficient, on-device soft sensors for sewer flow monitoring—learning from adjacent water level sensors 用于下水道流量监测的低成本、数据高效、设备软传感器——从相邻的水位传感器中学习
IF 8.2 2区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-09-16 DOI: 10.1016/j.wroa.2025.100415
Ruozhou Lin , Wenchong Tian , Ruihong Qiu , Lihan Hu , Zhiguo Yuan
Flow measurements are critical for sewer monitoring, but direct measurements with flow meters are often expensive due to high sensor costs and frequent sensor maintenance. Soft sensors that derive flow rates from water depth measurements are a more cost-effective approach; however, the training of such sensors still requires extensive direct flow measurements. In this paper, we propose on-device soft flow sensors based on water depth measurements at two adjacent manholes, rather than a single manhole, to reduce the demand for flow data for training. Three model structures, namely the Saint-Venant equations (SVE), a multilayer perceptron (MLP), and a physics-informed neural network (PINN), are used to implement soft sensors for two real-life pipes and one simulated pipe. In all cases, the SVE- and MLP-based soft sensors reliably estimate flow rates with a low computational load that can be implemented on a Raspberry Pi 5 that powers a water level sensor. In contrast, the PINN-based soft sensor failed due to its high computational demand. The SVE-based sensor requires much less flow data for training, while the MLP-based soft sensor delivers more accurate flow estimates but requires more flow data. Both sensors are robust against noise and bias associated with the water depth and flow rate measurements, suitable for real-life applications. The SVE-based sensor is preferrable when scarce flow data are available.
流量测量对于下水道监测至关重要,但由于传感器成本高且传感器维护频繁,使用流量计进行直接测量通常非常昂贵。从水深测量中获得流量的软传感器是一种更具成本效益的方法;然而,这种传感器的训练仍然需要大量的直接流量测量。在本文中,我们提出了基于两个相邻人孔的水深测量的设备上软流量传感器,而不是单个人孔,以减少对训练流量数据的需求。三种模型结构,即Saint-Venant方程(SVE),多层感知器(MLP)和物理信息神经网络(PINN),用于实现两个现实管道和一个模拟管道的软传感器。在所有情况下,基于SVE和mlp的软传感器以低计算负荷可靠地估计流量,可以在为水位传感器供电的树莓派5上实现。相比之下,基于pup的软传感器由于计算量大而失败。基于sve的传感器需要更少的流量数据进行训练,而基于mlp的软传感器提供更准确的流量估计,但需要更多的流量数据。这两种传感器都能抵抗与水深和流量测量相关的噪声和偏差,适用于实际应用。当流量数据稀缺时,基于sve的传感器是首选。
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引用次数: 0
Beyond the Curve Number methodology: Power law-based calibration and a nonparametric approach for enhancing urban runoff estimation 超越曲线数方法:基于幂律的校准和增强城市径流估算的非参数方法
IF 8.2 2区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-09-16 DOI: 10.1016/j.wroa.2025.100414
Yu Jian Cheong , Lloyd Ling , Ren Jie Chin , Steven Lim , Yu Heng Cheong , Zulkifli Yusop
This study presents a statistically grounded reformulation of the Natural Resources Conservation Service (NRCS) Curve Number (CN) rainfall-runoff model by replacing the conventional linear initial abstraction (Ia) to retention (S) relationship (Ia = λS, where λ is initial abstraction ratio) with a power law-based formulation (Ia = SL, where L is gradient of log-log graph) in order to restore mathematical correctness. A nonparametric bias-corrected and accelerated (BCa) bootstrap framework was employed to test the NRCS universal λ = 0.20 assumption, revealing its statistical invalidity (derived optimum λ value at 99 % BCa confidence interval: 0.032 - 0.079) for the urban Malaysian catchment studied. The proposed model achieved higher theoretical coherence and improved runoff estimate accuracy while preserving model parsimony. Importantly, it accommodates full rainfall-runoff datasets and dynamically captures catchment saturation-dependent retention behavior, addressing limitations of the conventional CN practices. The newly developed parsimonious two-parameter (S, L) runoff estimation model ensures practical adaptability by enabling catchment specific calibration without resorting to arbitrary CN selection. This study bridges traditional hydrology with modern statistical rigor, offering a scalable, data-driven alternative to conventional CN practices. The findings support a paradigm shift in runoff modelling by demonstrating the potential of nonparametric methods to refine legacy hydrological models and better capture real world nonlinearity and variability under changing climatic conditions.
本研究提出了基于统计的自然资源保护局(NRCS)曲线数(CN)降雨径流模型的重新表述,将传统的线性初始抽象(Ia)与保留(S)关系(Ia = λS,其中λ为初始抽象比)替换为基于幂律的表述(Ia = SL,其中L为对数-对数图的梯度),以恢复数学上的准确性。采用非参数偏差校正和加速(BCa)自举框架对NRCS普遍λ = 0.20假设进行了检验,揭示了其在马来西亚城市流域的统计不有效性(在99% BCa置信区间:0.032 - 0.079时推导出最佳λ值)。该模型在保持模型简洁性的同时,提高了径流估计的精度和理论一致性。重要的是,它适应完整的降雨径流数据集,并动态捕获集水区饱和度相关的保留行为,解决了传统CN实践的局限性。新开发的简约双参数(S, L)径流估算模型通过实现流域特定校准而无需任意选择CN,从而确保了实际适应性。这项研究将传统的水文学与现代严谨的统计联系起来,为传统的CN实践提供了一个可扩展的、数据驱动的替代方案。研究结果通过展示非参数方法在改进传统水文模型和更好地捕捉现实世界的非线性和气候条件变化下的可变性方面的潜力,支持径流建模的范式转变。
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引用次数: 0
Phytoplankton-induced nitrification suppression limits sediment nitrogen removal via nitrate diffusion in shallow illuminated eutrophic lake 浮游植物诱导的硝化抑制限制了浅层富营养化湖泊中硝酸盐扩散对沉积物氮的去除
IF 8.2 2区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-09-14 DOI: 10.1016/j.wroa.2025.100413
Rong Zhao , Min Xu , Lili Han , Moyang Li , Ehui Tan , Shiheng Tang , Hui Shen , Wenhao Su , Zhiwen Fu , Shan Sun , Silin Ni , Xindong Ma , Zhenzhen Zheng , Shuh-Ji Kao
Widespread shallow lakes/ponds receive substantial anthropogenic reactive nitrogen (N) inputs to be vulnerable components of global aquatic ecosystems. However, the mechanisms governing N retention in these systems remain inadequately explored. We combined 15N tracer-labeling techniques and molecular analysis to quantify N transformation networks, including ammonium (NH4+) uptake, remineralization, nitrate (NO3) uptake and nitrification in water column versus sedimentary N removal capacity in a tropical shallow lake (<1 m depth) in southern China. High-resolution diel monitoring (every 2 h over 36 h) revealed pronounced diel fluctuations in NH4+, driven by daytime phytoplankton uptake (up to 8.5 µM h−1) and NH4+ regeneration from particulate organic nitrogen (PN) (up to 12.3 µM h−1) in diel rhythms. In contrast, NO3 remained stable, with negligible uptake by phytoplankton or production via nitrification. The reciprocal transfer between NH4+ and PN formed a closed N cycle loop. Nitrification was nearly absent despite ample NH4+ availability at night, as evidenced by low nitrifier gene abundances (amo A = 0 copies/mL, amo B ≤ 8 × 103 copies/mL), suggesting competitive exclusion by phytoplankton. This suppression of nitrification restricted NO3 supply to sediments and likely limited denitrification particularly contributed from the overlying water diffusion, though measured denitrification rates indicated strong potential under elevated NO3 conditions. This study elucidated the pivotal role of diel N cycling and ecological niche competition in driving N retention and self-purification capacity in eutrophic well-lit shallow systems.
广泛分布的浅湖/池塘接收大量人为活性氮(N)输入,成为全球水生生态系统的脆弱组成部分。然而,在这些系统中控制氮保留的机制仍然没有得到充分的探索。我们结合15N示踪标记技术和分子分析来量化中国南方一个热带浅湖(<;1 m深度)的N转化网络,包括水柱中铵态氮(NH4+)吸收、再矿化、硝态氮(NO3−)吸收和硝化作用与沉积N去除能力。高分辨率日报社监测(在36小时内每2小时)显示,日报社中NH4+的显著波动是由白天浮游植物的吸收(高达8.5 μ M h- 1)和颗粒有机氮(PN)的NH4+再生(高达12.3 μ M h- 1)驱动的。相比之下,NO3−保持稳定,浮游植物的吸收或通过硝化作用产生的NO3−可以忽略不计。NH4+和PN之间的相互转移形成了一个闭合的N环。尽管夜间NH4+可用性充足,但硝化作用几乎不存在,这可以通过低氮化物基因丰度(amo A = 0拷贝/mL, amo B≤8 × 103拷贝/mL)来证明,这表明浮游植物的竞争性排斥。这种抑制硝化作用限制了沉积物的NO3−供应,并可能限制了反硝化作用,特别是由上覆水扩散所贡献的反硝化作用,尽管测量的反硝化速率表明在NO3−升高的条件下具有很强的潜力。本研究阐明了富营养化光照良好的浅层生态系统中氮循环和生态位竞争在驱动氮保持和自净化能力中的关键作用。
{"title":"Phytoplankton-induced nitrification suppression limits sediment nitrogen removal via nitrate diffusion in shallow illuminated eutrophic lake","authors":"Rong Zhao ,&nbsp;Min Xu ,&nbsp;Lili Han ,&nbsp;Moyang Li ,&nbsp;Ehui Tan ,&nbsp;Shiheng Tang ,&nbsp;Hui Shen ,&nbsp;Wenhao Su ,&nbsp;Zhiwen Fu ,&nbsp;Shan Sun ,&nbsp;Silin Ni ,&nbsp;Xindong Ma ,&nbsp;Zhenzhen Zheng ,&nbsp;Shuh-Ji Kao","doi":"10.1016/j.wroa.2025.100413","DOIUrl":"10.1016/j.wroa.2025.100413","url":null,"abstract":"<div><div>Widespread shallow lakes/ponds receive substantial anthropogenic reactive nitrogen (N) inputs to be vulnerable components of global aquatic ecosystems. However, the mechanisms governing N retention in these systems remain inadequately explored. We combined <sup>15</sup>N tracer-labeling techniques and molecular analysis to quantify N transformation networks, including ammonium (NH<sub>4</sub><sup>+</sup>) uptake, remineralization, nitrate (NO<sub>3</sub><sup>−</sup>) uptake and nitrification in water column versus sedimentary N removal capacity in a tropical shallow lake (&lt;1 m depth) in southern China. High-resolution diel monitoring (every 2 h over 36 h) revealed pronounced diel fluctuations in NH<sub>4</sub><sup>+</sup>, driven by daytime phytoplankton uptake (up to 8.5 µM h<sup>−1</sup>) and NH<sub>4</sub><sup>+</sup> regeneration from particulate organic nitrogen (PN) (up to 12.3 µM h<sup>−1</sup>) in diel rhythms. In contrast, NO<sub>3</sub><sup>−</sup> remained stable, with negligible uptake by phytoplankton or production via nitrification. The reciprocal transfer between NH<sub>4</sub><sup>+</sup> and PN formed a closed N cycle loop. Nitrification was nearly absent despite ample NH<sub>4</sub><sup>+</sup> availability at night, as evidenced by low nitrifier gene abundances (<em>amo A</em> = 0 copies/mL, <em>amo B</em> ≤ 8 × 10<sup>3</sup> copies/mL), suggesting competitive exclusion by phytoplankton. This suppression of nitrification restricted NO<sub>3</sub><sup>−</sup> supply to sediments and likely limited denitrification particularly contributed from the overlying water diffusion, though measured denitrification rates indicated strong potential under elevated NO<sub>3</sub><sup>−</sup> conditions. This study elucidated the pivotal role of diel N cycling and ecological niche competition in driving N retention and self-purification capacity in eutrophic well-lit shallow systems.</div></div>","PeriodicalId":52198,"journal":{"name":"Water Research X","volume":"29 ","pages":"Article 100413"},"PeriodicalIF":8.2,"publicationDate":"2025-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145095093","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Shark-inspired riblet design and optimization for drag reduction in drinking water distribution pipes across varying flow rates 鲨鱼启发的波纹设计和优化,减少了不同流速下饮用水分配管道的阻力
IF 8.2 2区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-09-14 DOI: 10.1016/j.wroa.2025.100412
Mirvahid Mohammadpour Chehrghani , Jamal Seyyed Monfared Zanjani , Doekle Yntema , David Matthews , Matthijn de Rooij
Drinking water distribution systems (DWDS) experience significant energy losses due to turbulence-induced drag. While shark-inspired riblet surfaces have been shown to reduce drag in controlled conditions, their effectiveness in DWDS remains uncertain, particularly under the dynamic flow variations. This experimental study explores biomimetic riblet designs as a potential solution for drag reduction in such environments. Two riblet configurations were evaluated: one designed after the shortfin mako shark (MSI), with smaller, tightly spaced riblets, and another based on the blacktip shark (BSI), with larger, widely spaced riblets. Riblet structures were 3D-printed and tested in a water flow loop system. The results show that although MSI and BSI achieved similar maximum drag reduction of approximately 6 % near a nondimensional spacing of s⁺ ≈ 14.5, their performance differed significantly versus Reynolds numbers. The MSI design sustained drag reduction over a wider range (2500 < Re < 20,000), while the BSI design was effective only within 2500 < Re < 8500. However, beyond these ranges, both designs began to experience drag increase. In addition, a comparison of geometric descriptors revealed that the square root of the groove cross-sectional area (lg+), provided the most consistent predictor for optimal riblet performance in pipe flow. However, the mean optimal value of lg+ was approximately 8.45, which is lower than the reference value of 10.7 reported for channel flows. This deviation likely results from confinement and curvature effects in pipe geometries, which modify vortex–riblet interactions compared to planar flows. These findings highlight the need to tailor riblet design to pipe-specific conditions and show that combining geometric and flow parameters improves performance evaluation in DWDS.
由于湍流引起的阻力,饮用水分配系统(DWDS)经历了巨大的能量损失。虽然鲨鱼纹表面在受控条件下可以减少阻力,但其在DWDS中的有效性仍然不确定,特别是在动态流动变化的情况下。这项实验研究探索了仿生波纹设计作为在这种环境中减少阻力的潜在解决方案。评估了两种肋骨配置:一种是根据短鳍鲭鲨(MSI)设计的,具有较小的,紧密间隔的肋骨,另一种是根据黑鳍鲨(BSI)设计的,具有较大的,广泛间隔的肋骨。波纹结构是3d打印的,并在水流循环系统中进行了测试。结果表明,尽管MSI和BSI在s +≈14.5的无量纲间距附近实现了相似的最大减阻约6%,但它们的性能与雷诺数有显著差异。MSI设计在更大的范围内(2500 < Re < 20,000)持续减少阻力,而BSI设计仅在2500 <; Re <; 8500范围内有效。然而,超过这个范围,两种设计都开始经历阻力增加。此外,几何描述符的比较表明,槽横截面积的平方根(lg+)提供了最一致的预测器,用于管道流动中最佳的波纹性能。然而,lg+的平均最优值约为8.45,低于通道流的参考值10.7。这种偏差可能是由于管道几何形状的限制和曲率效应造成的,与平面流动相比,它们改变了涡纹相互作用。这些发现强调了针对管道特定条件定制纹管设计的必要性,并表明结合几何参数和流动参数可以改善DWDS的性能评估。
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引用次数: 0
Bioremediation of agricultural nitrate pollution – challenges and opportunities 农业硝酸盐污染的生物修复——挑战与机遇
IF 8.2 2区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-09-13 DOI: 10.1016/j.wroa.2025.100410
Hao Wang , Satoshi Ishii
Agriculture is the major cause of nitrogen pollution worldwide, leading to eutrophication in the surrounding and downstream rivers, lakes, and oceans. Nitrogen runs out from the field mostly in the form of nitrate where subsurface drainage is installed, which is common in areas with poorly drained soils such as the U.S. Midwest and northern Europe. Nitrate contamination in groundwater wells can also cause human diseases, and therefore, is a serious public health concern. Agricultural drainage displays distinct characteristics from municipal wastewater and animal manure, which include high nitrate, low ammonium, and low organic carbon concentrations as well as low temperature. The remediation technologies also need to be deployable in rural settings, low cost, and have minimum impacts on agricultural production. In this review article, we first summarize the challenges associated with agricultural nitrate pollution. We also briefly summarize microbial nitrogen transforming reactions that are potentially useful for nitrate bioremediation. We then critically evaluate currently available nitrate remediation technologies. Because bioremediation is much less expensive than physical and chemical treatments, we mostly focus on bioremediation technologies, including wetlands, denitrification bioreactors, saturated riparian buffers, controlled drainage, and controlled drainage ditches. Current bioremediation technologies exhibit substantial variability in performance when implemented at field scale. This review discusses recent advances and emerging strategies to enhance nitrate removal under challenging field conditions, including bioaugmentation, biostimulation, and other novel technologies. Looking forward, the effective management of agricultural subsurface drainage will likely depend on the integration of multiple conservation practices to achieve targeted nitrate reduction goals.
农业是全球氮污染的主要原因,导致周围和下游河流、湖泊和海洋的富营养化。在地下排水系统安装的地方,氮主要以硝酸盐的形式从农田中流失,这在美国中西部和北欧等排水土壤较差的地区很常见。地下水井中的硝酸盐污染也会引起人类疾病,因此是一个严重的公共卫生问题。城市污水和动物粪便的农业排水具有高硝酸盐、低铵、低有机碳浓度和低温的明显特征。补救技术还需要在农村环境中部署,成本低,对农业生产的影响最小。在这篇综述文章中,我们首先总结了与农业硝酸盐污染相关的挑战。我们还简要总结了微生物氮转化反应对硝酸盐生物修复的潜在作用。然后,我们批判性地评估目前可用的硝酸盐修复技术。由于生物修复比物理和化学处理要便宜得多,我们主要关注生物修复技术,包括湿地、反硝化生物反应器、饱和河岸缓冲层、控制排水和控制排水沟。目前的生物修复技术在实地实施时表现出很大的性能差异。这篇综述讨论了在具有挑战性的野外条件下提高硝酸盐去除的最新进展和新兴策略,包括生物增强、生物刺激和其他新技术。展望未来,农业地下排水的有效管理可能取决于多种保护措施的整合,以实现有针对性的硝酸盐减少目标。
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引用次数: 0
Multi-scale variance partitioning reveals hidden regional connectivity in groundwater contamination: Implications for drinking water security 多尺度方差划分揭示地下水污染的区域连通性:对饮用水安全的影响
IF 8.2 2区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-09-13 DOI: 10.1016/j.wroa.2025.100409
Acme Afrin Jahan , Do Hwan Jeong , Jae Uk Youn , Tae Kwon Lee , MoonSu Kim
Rural communities dependent on groundwater face increasing contamination risks, yet large-scale assessments of actual drinking water sources remain rare. This study pioneers a novel geostatistical framework to quantify contamination patterns using 2349 groundwater wells that serve as primary drinking water sources for populations in unsupplied areas of Chungcheongnam-do, South Korea. Our integrated analysis revealed that NO₃⁻-N is the most pressing concern with 16.1 % of wells exceeding the national drinking water standard. Our analysis revealed unprecedented spatial contamination architecture. Nitrate demonstrated spatial coherence extending 62 km, vastly exceeding the <20 km ranges observed for trace elements. Variance partitioning quantified that neighboring wells contribute 38–40 % to nitrate variability at any location, indicating substantial hydraulic interconnection across the regional aquifer system. Local Indicators of Spatial Association identified six agricultural townships as contamination hotspots where mean nitrate concentrations reach 64.7 mg L⁻¹—over six times the safe drinking water limit. These hotspots exhibited 68 % cropland coverage compared to 33 % in non-hotspot areas. These findings transform understanding of groundwater contamination from local to regional phenomena, necessitating watershed-scale management rather than well-by-well remediation to protect rural drinking water supplies.
依赖地下水的农村社区面临越来越大的污染风险,但对实际饮用水源的大规模评估仍然很少。本研究开创了一个新的地质统计学框架,利用2349口地下水井作为韩国忠清南道无水地区人口的主要饮用水源,对污染模式进行量化。我们的综合分析显示,NO₃⁻-N是最紧迫的问题,16.1%的水井超过了国家饮用水标准。我们的分析揭示了前所未有的空间污染结构。硝酸盐表现出62公里的空间相干性,大大超过了微量元素的20公里范围。方差划分量化了相邻井在任何位置对硝酸盐变异的贡献为38 - 40%,表明整个区域含水层系统存在大量的水力互连。地方空间关联指标确定了6个农业乡镇为污染热点,平均硝酸盐浓度达到64.7 mg L -毒血症-超过安全饮用水限量的6倍。这些热点地区的耕地覆盖率为68%,而非热点地区的耕地覆盖率为33%。这些发现将对地下水污染的认识从局部现象转变为区域现象,需要流域尺度的管理,而不是逐井修复,以保护农村饮用水供应。
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引用次数: 0
Long-term multivariate water quality forecasting for sustainable aquaculture management 水产养殖可持续管理的长期多元水质预测
IF 8.2 2区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-09-10 DOI: 10.1016/j.wroa.2025.100402
Xiaodong Ji , Lu Liu , Bentao Duan , Ying Li , Haoran Xing , Bin Wang , Dashe Li
Accurate water quality prediction is essential for intelligent aquaculture management, enabling timely intervention, risk mitigation, and sustainable resource use. Key parameters such as dissolved oxygen, chlorophyll-a, and pH are influenced by complex spatiotemporal dynamics, making long-term forecasting particularly challenging in high-density aquaculture systems. Traditional methods struggle to balance local details and global trends, while circadian rhythms, feeding cycles, and seasonal shifts cause dynamic dependencies and distribution drift. To address these issues, we propose a novel deep learning framework with three core components: (1) a multi-scale decomposition module with time–frequency enhancement, which removes cross-scale redundancy, suppresses noise, and integrates local–global features via hierarchical decomposition and feature reorganization; (2) an adaptive sequence perception attention mechanism based on graph learning, which captures dynamic variable dependencies and models spatiotemporal interactions, including environmental coupling and aquaculture disturbances; and (3) a GRU-MoE network with a dynamic expert selection strategy that adjusts to data characteristics, mitigating distribution drift caused by human interventions like feeding and oxygenation. Extensive experiments on four real-world water quality datasets show the proposed method outperforms six deep learning baselines, achieving an average MAE reduction of 53.17%, RMSE reduction of 51.68%, R2 improvement of 0.4945, and KGE improvement of 0.1979. Furthermore, Kolmogorov–Smirnov test results confirm the model’s ability to recover real data distributions and their temporal evolution. This high-precision long-term prediction method enhances aquaculture system resilience, reduces risks from water quality fluctuations, and provides a robust foundation for informed decision-making and sustainable aquaculture management.
准确的水质预测对智能水产养殖管理至关重要,有助于及时干预、减轻风险和可持续利用资源。溶解氧、叶绿素-a和pH等关键参数受复杂的时空动态影响,使得高密度水产养殖系统的长期预测尤其具有挑战性。传统方法难以平衡局部细节和全球趋势,而昼夜节律、喂养周期和季节变化导致动态依赖和分布漂移。为了解决这些问题,我们提出了一个新的深度学习框架,该框架包含三个核心组件:(1)具有时频增强的多尺度分解模块,该模块通过分层分解和特征重组去除跨尺度冗余,抑制噪声,并集成局部-全局特征;(2)基于图学习的自适应序列感知注意机制,该机制捕获动态变量依赖,并对包括环境耦合和水产养殖干扰在内的时空相互作用进行建模;(3)具有动态专家选择策略的GRU-MoE网络,该策略可根据数据特征进行调整,减轻人为干预(如喂养和氧合)造成的分布漂移。在4个真实水质数据集上进行的大量实验表明,该方法优于6条深度学习基线,平均MAE降低53.17%,RMSE降低51.68%,R2提高0.4945,KGE提高0.1979。此外,Kolmogorov-Smirnov检验结果证实了该模型恢复真实数据分布及其时间演变的能力。这种高精度的长期预测方法增强了水产养殖系统的复原力,降低了水质波动带来的风险,并为知情决策和可持续水产养殖管理提供了坚实的基础。
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引用次数: 0
Identification of characteristic factors for water quality indicators and development of a wastewater source signature system for receiving rivers 确定水质指标的特征因素和开发污水来源特征系统的接收河流
IF 8.2 2区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-09-08 DOI: 10.1016/j.wroa.2025.100408
Rui Bian , Ting Su , Xiaofeng Cao , Jianfeng Peng , Weixiao Qi , Jiuhui Qu
Wastewater treatment plant (WWTP) discharge has become a focal point in watershed management, and its aggregate impacts on receiving rivers have been preliminarily elucidated. However, the characteristic water quality patterns in receiving rivers under the influence of different WWTP discharges (domestic, mixed, and industrial) remain unclear. To address this gap, water quality indicators were analysed in samples collected upstream and downstream of the outfall during different water periods and characteristic factors were identified. A threshold system for identifying the characteristic water quality patterns was established based on indicator concentration ratios, and the threshold ranges for source-type water quality signature ratios were determined. The characteristic patterns were validated by selecting three characteristic section types (different regions, double outfalls, and long distances). The results showed that the concentrations of most indicators at the downstream of outfalls were 5 % − 70 % higher than those at the upstream, and the water quality index quantified downstream deterioration (0.46 − 0.69). Furthermore, anions and metallic elements were identified as the characteristic factors. Based on these analyses, threshold ranges for source-type water quality signature ratio were determined: domestic (< 6.22), mixed (6.22 − 9.86), and industrial (> 9.86). Validation across the other characteristic sections confirmed that the results were within the threshold ranges. The strength of the indicator interaction by industrial wastewater discharge exceeded that of other wastewaters, thereby elucidating the differential characteristics mechanisms. This study provides a novel methodological framework for watershed water quality characterization, and the established threshold system holds significant practical value for aquatic environment management.
污水处理厂排放已成为流域管理中的一个重点问题,其对受水河流的总体影响已初步阐明。然而,在不同污水排放(生活、混合和工业)影响下,接收河流的特征水质模式尚不清楚。为了解决这一差距,在不同的水期,对排水口上游和下游收集的样本进行了水质指标分析,并确定了特征因素。建立了基于指标浓度比识别水质特征模式的阈值体系,确定了源型水质特征比的阈值范围。通过选择不同区域、双出口和长距离3种特征断面类型,对特征模式进行了验证。结果表明:水口下游大部分指标的浓度比上游高5% ~ 70%,水质指数量化了下游的恶化程度(0.46 ~ 0.69)。此外,阴离子和金属元素被确定为特征因素。基于这些分析,确定了水源型水质特征比的阈值范围:生活(< 6.22)、混合(> 9.86)和工业(> 9.86)。跨其他特征部分的验证确认结果在阈值范围内。工业废水排放的指标相互作用强度超过其他废水,从而阐明了差异特征机制。本研究为流域水质表征提供了一种新的方法框架,所建立的阈值体系对水环境管理具有重要的实用价值。
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Water Research X
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