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Efficiency of FeSO4.7H2O as a Coagulant on Chromium Hexavalent Removal Using Coagulation-Flocculation Process: Optimization Using Response Surface Methodology 混凝-絮凝工艺中FeSO4.7H2O混凝去除六价铬的效率:响应面法优化
Pub Date : 2023-10-29 DOI: 10.33795/jtkl.v7i2.3560
Andi Baso Pangeran, Moh. Azhar Afandy, Fikrah Dian Indrawati Sawali
Response Surface Methodology-Central Composite Design (RSM-CCD) is widely employed in the process of optimizing the applications of coagulants for wastewater treatment. The experiment aims to evaluate the effect of the FeSO4.7H2O concentration and settling time on removing the chromium hexavalent (Cr (VI)) from wastewater by coagulation-flocculation using RSM-CCD. This experiment was carried out based on the results of the model and optimization using the RSM-CCD to obtain the removal efficiency of Cr (VI) as well as determine the influence of the concentration of FeSO4.7H2O (X1) and settling time (X2). The RSM-CCD experimental design uses a two-factor and two-level design with 13 experimental runs and 5 center points. Inter-variable regression coefficients are also produced with the elimination of Cr (VI). The ANOVA test results showed a fairly significant figure for the assembled model. The model validation results show that the proposed model is compatible with the experimental results. RSM optimization shows optimum conditions based on experimental FeSO4.7H2O coagulant concentration variables and coagulation time at 150 mg/L coagulant concentration and 60 minutes of time, and the prediction results based on RSM-CCD optimization using Design Expert show the most optimum condition at 165,562 mg/L coagulant concentrations and 60,527 minutes of time.
响应面法-中心复合设计(RSM-CCD)在优化混凝剂在废水处理中的应用中得到了广泛的应用。本实验旨在评价FeSO4.7H2O浓度和沉淀时间对混凝-絮凝法去除废水中六价铬(Cr (VI))的影响。本实验以模型结果为基础,利用RSM-CCD进行优化,得到了Cr (VI)的去除率,并确定了FeSO4.7H2O浓度(X1)和沉淀时间(X2)的影响。RSM-CCD实验设计采用双因素双水平设计,13个实验运行,5个中心点。消除Cr (VI)后,还产生了变量间回归系数。方差分析检验结果显示,组装模型的数据相当显著。模型验证结果表明,所提模型与实验结果吻合较好。基于实验FeSO4.7H2O混凝剂浓度变量和混凝时间的RSM优化结果为混凝剂浓度为150 mg/L、混凝时间为60 min,基于Design Expert的RSM- ccd优化预测结果为混凝剂浓度为165,562 mg/L、混凝时间为60,527 min时的最优条件。
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引用次数: 0
The Potential of Cassava Peel Waste as a Material of Biodegradable Plastic using Calcium Silicate Filler 木薯皮废弃物作为硅酸钙填料生物降解塑料的潜力
Pub Date : 2023-10-29 DOI: 10.33795/jtkl.v7i2.1721
None Noor Isnaini Azkiya, None S. Sigit Udjiana, None Arya Rizqy Irangga, None Anatasya Tania Febiyanti
Biodegradable plastics are plastics that can be degraded and decomposed quickly by microorganisms in the soil. In this study, biodegradable plastic was made with starch from cassava peel waste, sorbitol as a plasticizer, and calcium silicate as a filler. This research was conducted to determine the effect of the amount of filler and the amount of plasticizer on biodegradation properties, tensile and elongation strength, and water absorption properties. The variables used in the plasticizer are 30%, 40%, and 50% (w/w) of the weight of cassava peel starch. While the variables used for filler are 1%, 3%, 5%, and 7% (w/w) of the weight of cassava peel starch. The results of the study showed that the highest biodegradation test results were 81.7% with 7% calcium silicate filler variables and 50% plasticizer sorbitol, tensile strength test obtained the highest value of 0.767 MPa on 3% calcium silicate filler variables and 30% sorbitol, elongation test with the highest value on the filler variable calcium silicate 7% and sorbitol 30% that is equal to 5.20% and the water adsorption test obtained the smallest value is 10.33% on the filler variable calcium silicate 1% and sorbitol 30%. The biodegradable plastic as a result of this research has met the standards for degradation ability based on the ASTM 6400 standard but has not met the standards for tensile strength, elongation, and water adsorption.
可生物降解塑料是指可以被土壤中的微生物迅速降解和分解的塑料。以木薯皮废料为原料,以山梨醇为增塑剂,硅酸钙为填料,制备了生物可降解塑料。研究了填料用量和增塑剂用量对生物降解性能、拉伸伸长率和吸水性能的影响。增塑剂中使用的变量为木薯皮淀粉重量的30%、40%和50% (w/w)。而用于填料的变量为木薯皮淀粉重量的1%,3%,5%和7% (w/w)。研究结果表明:7%硅酸钙填料变量和50%增塑剂山梨醇的生物降解试验结果最高为81.7%,3%硅酸钙填料变量和30%山梨醇的拉伸强度试验结果最高为0.767 MPa;伸长率试验中,在硅酸钙含量为7%、山梨醇含量为30%时达到最大值,等于5.20%;吸水率试验中,在硅酸钙含量为1%、山梨醇含量为30%时达到最小值,为10.33%。本研究所得的生物降解塑料在降解能力方面达到ASTM 6400标准,但在抗拉强度、伸长率和吸水率方面仍未达到标准。
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引用次数: 0
Restaurant Liquid Waste Treatment into Clean Water Using Graded Filter-Ultrafiltration Membrane Polyethersulfone (PES) Method 用分级过滤-超滤膜聚醚砜(PES)法处理饭店废液成清水
Pub Date : 2023-10-29 DOI: 10.33795/jtkl.v7i2.1691
Intan Fadhilah, Abd Mujahid Hamdan, Fachrul Razi
Restaurant liquid waste contains elevated pollutant levels and is commonly discharged directly into the environment, leading to adverse impacts on ecosystems and aquatic life. The traditional methods for processing such wastewater often involve extensive land usage and complicated operations, posing challenges for effective treatment. Therefore, there is a need for a more practical technology to manage restaurant liquid waste, and one promising approach is the utilization of membrane technology for wastewater treatment. In this study, the researchers employed a combination process of multilevel filters with downflow flow and PES membrane ultrafiltration to treat the restaurant liquid waste. The multilevel filter comprised several layers of filter media, including silica sand, activated carbon, zeolite, and gravel, with specific thicknesses on a PVC pipe. For the PES membrane, two different concentrations were tested: 15% and 20% PES. To evaluate the efficiency of the treatment process, pollutant parameters such as pH, TSS (Total Suspended Solids), COD (Chemical Oxygen Demand), and turbidity were measured. The results indicated significant pollutant reduction: pH levels could reach 6.9, TSS degradation achieved up to 98.37%, COD degradation up to 88.14%, and turbidity degradation up to 97.03%. Based on the outcomes, the most effective treatment for converting restaurant wastewater into clean water involved the combined use of multilevel filters and a 20% PES membrane ultrafiltration system.
餐馆的废液含有高浓度的污染物,通常直接排放到环境中,对生态系统和水生生物造成不利影响。传统的废水处理方法往往占用大量土地,操作复杂,对有效处理提出了挑战。因此,需要一种更实用的技术来管理餐厅废液,而利用膜技术进行废水处理是一种很有前途的方法。本研究采用多级下流式过滤器与PES膜超滤组合工艺处理餐厅废液。多层过滤器由多层过滤介质组成,包括硅砂、活性炭、沸石和砾石,在PVC管上具有特定的厚度。对于PES膜,测试了两种不同浓度的PES: 15%和20%。为了评估处理过程的效率,测量了污染物参数,如pH、TSS(总悬浮固体)、COD(化学需氧量)和浊度。结果表明:pH值可达6.9,TSS降解率达98.37%,COD降解率达88.14%,浊度降解率达97.03%。根据结果,将餐厅废水转化为清洁水的最有效处理方法是多级过滤器和20% PES膜超滤系统的联合使用。
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引用次数: 0
Characterization of Bioethanol from Tuber of Porang Waste Fermented with Saccharomyces cerevisiae Enzyme: Effect of Fermentation Time and Yeast Ratio 酿酒酵母酵素发酵茯苓块茎生物乙醇的特性研究:发酵时间和酵母比的影响
Pub Date : 2023-10-29 DOI: 10.33795/jtkl.v7i2.3199
Rina Ridara, Muhammad Muhammad, Adi Setiawan, Shafira Riskina, Siti Nurjannah
The production of bioethanol from non-plant lignocellulosic materials has reached a commercial scale and is advocated as a possible solution for the decarbonization of the transport sector. Porang pulp tubers can be converted into bioethanol because they have abundant potential due to their high glucomannan content. The purpose of this study was to determine the effect of fermentation time and the ratio of yeast addition on bioethanol production. The methods used are hydrolysis, fermentation and distillation methods. The hydrolysis process used 5% (v/v) HCl catalyst, the fermentation process with 6 gr sample powder tuber of waste used Saccharomyces cerevisiae bacteria with varying ratios of 2.5, 4 and 6.5 g and variations in fermentation time for 2, 4 and 6 days at 38-40˚C. The results showed that the duration of fermentation had a significant effect on the yield of bioethanol, where microorganisms have the opportunity to break down more glucose to produce bioethanol. While the ratio of the addition of yeast added to the fermentation process, the greater the ratio of the addition of yeast, the greater the bioethanol produced. Where the addition of 6.5 grams of yeast and 6 days of fermentation time, resulted in a yield of 9.889%, a bioethanol concentration of 37.599%, a refractive index of 1.3642 and a density of 1.04 g/ml.
从非植物木质纤维素材料中生产生物乙醇已达到商业规模,并被提倡作为运输部门脱碳的可能解决方案。Porang果肉块茎中葡甘露聚糖含量高,具有丰富的转化潜力。本研究的目的是确定发酵时间和酵母添加比例对生物乙醇产量的影响。所用的方法有水解、发酵和蒸馏法。水解过程采用5% (v/v) HCl催化剂,发酵过程采用6 g废粉块茎样品,发酵过程采用酵母菌,发酵时间分别为2.5、4和6.5 g,发酵时间为2、4和6 d,温度为38-40℃。结果表明,发酵时间对生物乙醇的产量有显著影响,微生物有机会分解更多的葡萄糖来生产生物乙醇。而在发酵过程中添加酵母的比例,酵母的添加比例越大,产生的生物乙醇越多。其中,添加6.5 g酵母,发酵时间为6 d,产率为9.889%,生物乙醇浓度为37.599%,折射率为1.3642,密度为1.04 g/ml。
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引用次数: 0
Making Charcoal from Nipah (Nypa fruticans) Frond Waste as an Adsorbent to Extend the Shelf Life of Fresh Bread 利用尼帕果叶废料制作木炭作为吸附剂以延长新鲜面包的保质期
Pub Date : 2023-10-29 DOI: 10.33795/jtkl.v7i2.3643
Ayu Nur Sabila, Theresia Evila Purwanti Sri Rahayu, Oto Prasadi
Fresh bread has high potential for creating food waste that increases every year, because of its relatively short shelf life of 3-4 days after leaving the baking process. One way to extend the shelf life of bread is by using charcoal. Nipah fronds contain lignin elements that are good for charcoal. This study aims to determine the characteristics of charcoal from nipah fronds, the effectiveness of charcoal's ability to extend the shelf life of fresh bread, the effect of burning time, particle size and adsorbent mass on the storage time of fresh bread, the effect of the ratio of nipah frond adsorbent to commercial silica gel on the storage time compared to quality requirements of fresh bread of SNI 01-3840-1995 2013. Charcoal characterization includes quality tests based on SNI No. 06-3730-1995 on technical charcoal, namely water content and iodine absorption parameters and also Scanning Electron Microscopy (SEM) test. Based on the results of the study, charcoal from nipah frond waste has characteristics of water content that have met the quality standards of SNI 06-3730-1995 and in iodine absorbency only samples with pyrolysis time of 4 hours that have met the quality standards of SNI 06-3730-1995. Giving variations in charcoal burning time, mass and particle size of adsorbent powder affects the shelf life and quality requirements of fresh bread. Adsorbent packaging using teabags and silica gel paper can extend the shelf life of fresh bread up to 27 hours compared to those without adsorbent.
新鲜面包的保质期相对较短,烘焙后只有3-4天,因此很有可能造成每年都在增加的食物浪费。延长面包保质期的一种方法是使用木炭。尼帕叶含有木质素元素,对木炭有益。本研究旨在确定尼帕叶木炭的特性,木炭延长新鲜面包保质期的有效性,燃烧时间,颗粒大小和吸附剂质量对新鲜面包储存时间的影响,尼帕叶吸附剂与商业硅胶的比例对储存时间的影响,并与SNI 01-3840-1995 2013新鲜面包的质量要求进行比较。木炭表征包括基于SNI No. 06-3730-1995对技术木炭的质量测试,即含水量和碘吸收参数,以及扫描电子显微镜(SEM)测试。研究结果表明,尼帕叶废炭的含水率符合SNI 06-3730-1995的质量标准,只有热解时间为4小时的样品吸碘性符合SNI 06-3730-1995的质量标准。活性炭燃烧时间、吸附剂粉末的质量和粒度的变化会影响新鲜面包的保质期和质量要求。与不使用吸附剂的包装相比,使用茶袋和硅胶纸的吸附剂包装可将新鲜面包的保质期延长27小时。
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引用次数: 0
Evaluation and Management of B3 Waste Sludge via the Sludge Oil Recovery (SOR) Program at PT. X Plaju 基于油泥回收(SOR)项目的B3废污泥评价与管理
Pub Date : 2023-10-29 DOI: 10.33795/jtkl.v7i2.3851
Widya Reza Nurdiasna, Iva Yenis Septiariva, I Wayan Koko Suryawan, Mega Mutiara Sari, Nova Ulhasanah
With the ever-increasing need for waste management solutions, PT. X Plaju is one of the entities that contribute to B3 waste production, a waste type characterized by its explosive, flammable, reactive, corrosive, and toxic properties. This research centers on the evaluation and management of B3 waste sludge, particularly at PT. X Plaju. The institution implements two licensed B3 waste control programs: the Sludge Oil Recovery (SOR) and used lubricant utilization programs. The SOR program, which focuses on recovering components from oil deposits or sludge, operates under the recovery principle. This study showcases the importance of the oil component in the oil sludge, emphasizing that it must constitute more than 20% of the total volume to be deemed suitable for refinery production. Our findings highlighted a water content of 28.32% within the waste oil sludge. Additionally, the ultimate analysis showcased carbon, hydrogen, and nitrogen compositions of 85.99%, 13.42%, and 0.21%, respectively, while the density was measured at 0.85 gr/cc. This research offers insights into the waste management practices of PT. X Plaju, emphasizing the potential of the SOR program in managing B3 waste effectively.
随着对废物管理解决方案的需求日益增长,PT. X Plaju是产生B3废物的实体之一,这是一种具有爆炸性,可燃性,反应性,腐蚀性和毒性的废物类型。本研究的重点是B3废污泥的评价和管理,特别是在X厂。该机构实施了两个获得许可的B3废物控制计划:污泥油回收(SOR)和废润滑油利用计划。SOR项目侧重于从石油沉积物或污泥中回收成分,在回收原则下运作。这项研究显示了油泥中油成分的重要性,强调它必须占总量的20%以上才能被认为适合炼油厂生产。我们的研究结果突出了废油污泥中28.32%的含水量。此外,最终分析显示,碳、氢和氮的组成分别为85.99%、13.42%和0.21%,而密度为0.85 gr/cc。这项研究为PT. X Plaju的废物管理实践提供了见解,强调了SOR项目在有效管理B3废物方面的潜力。
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引用次数: 0
Simulation of Furfural and Levulinic Acid Production from Lignocellulosic Biomass 木质纤维素生物质生产糠醛和乙酰丙酸的模拟
Pub Date : 2023-10-29 DOI: 10.33795/jtkl.v7i2.4141
Jabosar Ronggur Hamonangan Panjaitan
Furfural and levulinic acid are chemicals that can be produced from lignocellulosic biomass. In this research, mass balance simulation of furfural and levulinic acid production at scale of 100 tons of biomass/year was examined. This research using various models of kinetic reaction and biomass to solvent ratio from lignocellulosic biomass raw materials consisting of cellulose, hemicellulose, lignin, ash, and water composition of 35%, 30%, 25%, 3%, and 7%. The kinetic models used in this research were separate kinetic models and simultaneous model (model-3). The separate kinetic models were divided into two models which separate kinetic model 1 (model-1) and separate kinetic model 2 (model-2). SuperPro Designer 9.0 software was used to calculate mass balance simulation. From the research, it was found that variations in kinetic reaction model affected furfural and levulinic acid production. Higher biomass to solvent ratio produced higher furfural and levulinic acid production. The highest furfural produced from simulation process was kinetic reaction model-2 with a biomass to solvent ratio of 1:30 and 0.67 liter furfural/hour. While the highest levulinic acid produced from the simulation process was kinetic reaction model-1 with a biomass to solvent ratio of 1:30 and 2.37 liter levulinic acid/hour.
糠醛和乙酰丙酸是可以从木质纤维素生物质中产生的化学物质。本研究对100吨生物质/年生产糠醛和乙酰丙酸的质量平衡模拟进行了研究。本研究采用多种动力学反应模型和生物质与溶剂的比例,从木质纤维素生物质原料中提取由纤维素、半纤维素、木质素、灰分和水组成的35%、30%、25%、3%和7%。本研究采用的动力学模型为分离动力学模型和同时动力学模型(模型3)。将分离动力学模型分为分离动力学模型1(模型1)和分离动力学模型2(模型2)两个模型。采用SuperPro Designer 9.0软件进行质量平衡模拟计算。研究发现,反应动力学模型的变化影响了糠醛和乙酰丙酸的生成。较高的生物质与溶剂比产生较高的糠醛和乙酰丙酸产量。在生物质与溶剂比为1:30、糠醛含量为0.67 l/h的动力学反应模式-2下,模拟过程中糠醛产量最高。而模拟过程中乙酰丙酸产量最高的是动力学反应模型-1,生物质与溶剂比为1:30,乙酰丙酸/小时为2.37升。
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引用次数: 0
Application of Sequencing Batch Biofilm Reactor (SBBR) Using Microalgae Chorella sp. to Removal Nutrient in Grey Water 微藻测序间歇式生物膜反应器(SBBR)在污水处理中的应用
Pub Date : 2023-04-30 DOI: 10.33795/jtkl.v7i1.338
S. Elystia, Rika Kristin, D. Andrio
Grey water contains organic matter that is directly disposed to the environment without any treatment previously, will cause pollution and impacting life in the water. Treatment that can be done is using microorganisms. One of its kind is the microalgae Chlorella sp. which utilizes organic matter as a source of nutrients for its growth. In this study, the Kaldness 1 (K1) bio carrier was added as a medium for attaching microorganisms using the Sequencing Batch Biofilm Reactor (SBBR) process. The research objectives were (1) to know the maximum number of Chlorella sp. both attached and suspended in the Sequencing Batch Biofilm Reactor (SBBR), (2) to obtain the best cycle time and stabilization time in the removal of COD, Ammonia, and MLSS in grey water. The research was conducted by varying the stabilization time (1.5; 2 and 2.5 hours) in each cycle for four cycles with a constant variation of charging time 30 minutes, reaction 120 minutes, 45 minutes, separation 45 minutes, and carried out with four cycles, stirring speed at 60 rpm, the concentration of algae suspension in SBBR was 25% and the volume of Kaldness K1 medium was 20%. The results showed the number of microalgae cells Chlorella sp. was suspended and attached to 1.85 x 106 and 1.46 x 106 cells/ml. The best removal of COD, ammonia, and MLSS was found in the stabilization time variation of 1.5 hours in 4 cycles with a removal efficiency of 84% and 76%, respectively, and an increase in the concentration of suspended and attached MLSS by 4780 mg/l and 4720 mg/l. It can be concluded that the faster stabilization time, the more removal efficient will be.
灰水含有有机物,未经任何处理就直接排放到环境中,会造成污染并影响水中的生命。可以进行的治疗是使用微生物。其中一种是微藻小球藻,它利用有机物作为生长的营养来源。在本研究中,使用序批式生物膜反应器(SBBR)工艺添加Kaledness 1(K1)生物载体作为附着微生物的培养基。研究目的是(1)了解序批式生物膜反应器(SBBR)中附着和悬浮的小球藻的最大数量。(2)获得去除灰水中COD、氨和MLSS的最佳循环时间和稳定时间。该研究通过在四个循环中改变每个循环中的稳定时间(1.5;2和2.5小时)进行,充电时间30分钟、反应120分钟、45分钟、分离45分钟不变,并进行四个循环,搅拌速度为60rpm,SBBR中藻类悬浮液的浓度为25%,Kaledness K1培养基的体积为20%。结果表明,小球藻悬浮并附着的微藻细胞数分别为1.85×106和1.46×106个/ml。对COD、氨和MLSS的最佳去除是在4个循环中稳定时间变化1.5小时,去除效率分别为84%和76%,悬浮和附着的MLSS浓度分别增加4780mg/l和4720mg/l。可以得出的结论是,稳定时间越快,去除效率就越高。
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引用次数: 0
OPTIMALISASI PENAMBAHAN ANTIOKSIDAN DALAM DEMULSIFIER BERBASIS ACRYLATE PADA PROSES PENYIMPANAN BIOSOLAR 以氯气储存过程为基础的消化性消氧化
Pub Date : 2023-04-30 DOI: 10.33005/jurnal_tekkim.v17i2.3790
Oksil Venriza, M. W. Prastio, R. Rahmadani
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引用次数: 0
KARAKTERISTIK ALIRAN TAYLOR SISTEM GAS-LIQUID DALAM MICROCHANNEL BERPENAMPANG LINGKARAN
Pub Date : 2023-04-30 DOI: 10.33005/jurnal_tekkim.v17i2.3788
Aloisiyus Yuli Widianto
Miniaturization performs better than conventional equipment since it can generate a high specific surface (A/V) for mass and heat transfer between phases. The current studies aimed at characterizing the two-phase flow pattern (air-methanol) with a circular cross-sectional area of silicone, determining bubble length in the inlet and outlet section by using the three configurations of microchannel; finding the effect of gas and liquid velocity as well as the pressure drop throughout the channel to the bubble dimensions formed. The experiments were conducted by visualizing a gas-liquid flow pattern (Taylor) and measuring the bubble length within a channel of 1 mm ID. As a flow pattern target in this work, Taylor has a uniform shape, dimension, and constant velocity during observations. An increase in the ratio of linear velocity (UG/UL) brings on an increase in bubble length throughout the channel from the inlet to the outlet section. The bubble length outlet is longer than the inlet section due to the effect of increasing pressure drop (ΔP) and is sometimes caused by the bubble coalescence phenomena. The wettability on the inner wall of the microchannel strongly determined the flow pattern type and the length of bubbles
小型化性能优于传统设备,因为它可以产生高比表面积(a /V),用于相之间的质量和热量传递。目前的研究旨在表征有机硅圆形横截面积下的两相流(空气-甲醇),通过使用三种配置的微通道确定入口和出口截面的气泡长度;发现气液速度以及整个通道的压降对形成气泡尺寸的影响。实验通过可视化气液流动模式(Taylor)和测量1毫米内径通道内的气泡长度来进行。作为本研究的流型靶,Taylor在观测过程中具有均匀的形状、尺寸和恒定的速度。线速度比(UG/UL)的增加会导致从入口到出口段整个通道的气泡长度增加。由于压降增大(ΔP)的影响,出口气泡长度比进口截面长,有时由气泡合并现象引起。微通道内壁的润湿性在很大程度上决定了气泡的流型类型和长度
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引用次数: 0
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