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Comparison of Relationship between Solubilization and Methane Productivity on Anaerobic Digestion of Pre-treated Waste Activated Sludge 预处理废活性污泥厌氧消化溶解性与甲烷生产率关系的比较
Pub Date : 2022-02-28 DOI: 10.4491/ksee.2022.44.2.33
Byung-Kyu Ahn, Tae-Hoon Kim, Hyojeon Kim, Seoktae Kang, Yeo-Myeong Yun
Objectives : Various pre-treatment methods have been applied to waste activated sludge(WAS) to improve the efficiency of anaerobic digestion(AD) by enhancing hydrolysis. The objective of this study was to find out the relationship between increased solubilization and AD efficiency in response to the application of different pretreatment methods(Acid+Heat and Alkali+Heat) to WAS.Methods : Acid+Heat(pH 2+130℃) and Alkali+Heat(pH 10+130℃) pretreatment processes were performed by adding HCl and KOH, respectively. A biochemical methane potential(BMP) test was subsequently conducted to determine the AD efficiency of pretreated WAS. Finally, the physicochemical characteristics in the effluent of AD of WAS, done by excitation-emission matrix(EEM) and size exclusion chromatography(SEC), were analyzed to investigate the degree of changed intermediates during microbial degradation of organic compounds.Results : Both Acid+Heat and Alkali+Heat pretreatments resulted in similar solubilization of WAS, reaching 34.1 and 36.3%, respectively. Meanwhile, it was found that the CH4 yield obtained from the Alkali+Heat pretreated sample was lower than the sample of Acid+Heat. The results of EEM analysis showed that the Alkali+Heat pretreated WAS had a higher portion of less biodegradable organic compounds with high- molecular weight in the soluble sample than that of the Alkali+Heat pretreated sample.Conclusion : This study was conducted to clarify the relationship by comparing the hydrolysis rate and AD efficiency according to the application of Acid+Heat and Alkali+Heat pretreatment. It was found that the amount of methane generated could vary depending on the properties of the dissolved substances in response to different pretreatment approaches.
目的:将各种预处理方法应用于废活性污泥(WAS),通过增强水解作用来提高厌氧消化(AD)的效率。本研究的目的是找出不同预处理方法(酸+热和碱+热)对was的增溶作用和AD效率之间的关系。随后进行生化甲烷电位(BMP)测试以确定预处理was的AD效率。最后,通过激发发射矩阵(EEM)和尺寸排阻色谱(SEC)对WAS AD废水的理化特性进行了分析,以考察微生物降解有机化合物过程中中间体的变化程度。结果:酸+热和碱+热预处理对WAS的增溶作用相似,分别达到34.1%和36.3%。同时,发现碱+热预处理样品获得的CH4产率低于酸+热处理样品。EEM分析结果表明,碱+热预处理的WAS在可溶性样品中的高分子量不易生物降解的有机化合物比例高于碱+热处理样品。结论:本研究通过比较酸+热和碱+热预处理的水解速率和AD效率来阐明两者之间的关系。研究发现,在不同的预处理方法下,产生的甲烷量可能因溶解物质的性质而异。
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引用次数: 2
A Study on Changes in Air Pollutant Generation Trends after Integrated Permit in Coal-fired Power Plants 燃煤电厂综合许可后大气污染物产生趋势变化研究
Pub Date : 2022-02-28 DOI: 10.4491/ksee.2022.44.2.41
H. Hwang, J. Seo, JongBeom Khan, Sunkyung Lee, Hyeonsoo Park, Younglan Kim
Objectives : The Environmental Pollution Facility Act was implemented to effectively reduce pollutants that could be generated in the business establishment, centering on emission facilities, from the Media Act, which had been managed in the aspect of follow-up management. Accordingly, the change in the generation of air pollutants after the integrated permit in coal-fired power plants was examined.Methods : Air pollutant emission standards were analyzed for business establishment that use coal, a solid fuel, as fuel among power plants that have completed integrated permits.Results and Discussion : The standards suggested by the Act on the Integrated Control of Pollutant-Discharging Facilities have numerically higher values than the existing Clean Air Conservation Act Standards, but there is a limit to evaluating only with simple standards because permit standards are given through emission impact analysis. As a result of a comparison through the emission impact analysis, it was found that 10 plants were given stricter permit standards for sulfur oxides and nitrogen oxides by 22% and for dust by 10% at 8 business establishment.Conclusion : The level of pollution on the surrounding location status is evaluated, and permission standards are granted. It was confirmed that the emission impact analysis method under the Act On The Integrated Control of Pollutant-Discharging Facilities can be applied as a more strictly manageable means than the existing standards under the Clean Air Conservation Act.
目的:实施《环境污染设施法》,有效减少以排放设施为中心的企业机构可能产生的污染物,从《媒介法》开始,在后续管理方面进行管理。据此,考察了燃煤电厂综合许可后大气污染物产生量的变化。方法:对已完成综合许可的电厂中以固体燃料煤为燃料的企业进行大气污染物排放标准分析。结果与讨论:《排污设施综合治理法》建议的标准数值高于现行的《清洁空气保护法》标准,但由于是通过排放影响分析给出许可标准,因此仅用简单标准进行评价存在局限性。通过排放影响分析对比发现,10家工厂的硫氧化物和氮氧化物的许可标准提高了22%,8家企业的粉尘的许可标准提高了10%。结论:评价了周边区位状况的污染程度,并给出了许可标准。与现行的《清洁空气保护法》标准相比,《排污设施综合治理法》规定的排放影响分析方法可以作为更严格的管理手段得到证实。
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引用次数: 0
Biomass Based Bioenergy: Technologies and Impact on Environmental Sustainability 生物质生物能源:技术及其对环境可持续性的影响
Pub Date : 2022-01-31 DOI: 10.4491/ksee.2022.44.1.1
I. Mehrez, S. Shobana, Georgeio Semaan, Sang‐Hyoun Kim, Gopalakrishnan Kumar
Biomass based bioenergy has many advantages evidently as their available quantity and renewability, when compared to the petro-derived traditional fossil fuels. Thereby, such bioenergy occupies a vital role defensively to the global energy requirement as well as guarantee energy supply. On the other hand, it should be considered that the development of biomass based energy may lead to some serious environmental issues and those are only based on the published data. Such adverse environmental alterations, mainly erosion of soil organic carbon, greenhouse gas emissions, lessening of water quantity and quality, have mainly been based on type of biomass source utilized, location of the land, and management practices. Consequently, more attention should be paid towards environmental protection, while implementing the production of biomass based bioenergy. In this study, various types of biomass, its conversion technology, advantages and disadvantages and its environmental issues of bioenergy production in terms of adverse impact on water, air and soil along with protection measures have been discussed.
与石油衍生的传统化石燃料相比,生物质生物能源具有明显的可用量和可再生性优势。因此,这种生物能源在满足全球能源需求和保障能源供应方面发挥着至关重要的作用。另一方面,应该考虑到,基于生物质的能源的发展可能会导致一些严重的环境问题,而这些问题只是基于已公布的数据。这种不利的环境变化,主要是土壤有机碳的侵蚀、温室气体排放、水量和水质的降低,主要是基于所利用的生物量来源类型、土地位置和管理实践。因此,在实施生物质生物能源生产的同时,应更加重视环境保护。在本研究中,讨论了各种类型的生物质、其转化技术、生物能源生产的优缺点及其对水、空气和土壤的不利影响方面的环境问题以及保护措施。
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引用次数: 3
Effect of Ultrasonic Pretreatment of Sewage Sludge on the Performance of Bioelectrochemical Anaerobic Digester 污泥超声预处理对电化学厌氧沼池性能的影响
Pub Date : 2022-01-31 DOI: 10.4491/ksee.2022.44.1.13
Donghwan Lee, Jinwon Kim, Hwijin Seo, Yongtae Ahn
Objectives : This study examined the effect of ultrasonic pretreatment on primary sewage sludge (raw sludge) solubilization and its subsequent microbial electrolysis cells (MECs) operation performance.Methods : To compare the effect of ultrasound on raw sludge solubilization, ultrasonic pretreatment was conducted at 1~4 W/mL energy density for 5~30 min. In MECs operation, raw sludge was used as a control group, and ultrasound pretreated sludge was used as an experimental group. For comparing MECs performance, biogas production, and organic matter removal were analyzed.Results and Discussion : The optimal experimental condition for ultrasonic pretreatment were 30 min of sonication time at 3 W/mL. In methane production, MEC with ultrasound pretreatment (MEC 3W) produced 243 mL/L more methane than that of unpretreated MEC (MEC) by 4,970 mL/L at 1, 3 cycles. In the modified Gompertz model analysis, the lag phase of MEC 3W was 0.46 days, which was 0.12 days longer than MEC. The maximum methane production rate of MEC 3W by 938.5 mL/L/day was also higher than MEC. MEC 3W showed a 1.8% higher TS removal rate, 2.4% VS removal rate than MEC. COD removal rate also improved by 2.0% when ultrasound pretreatment was applied. The methane yield of MEC with ultrasound pretreatment (377.4 mL/g VSin.) was 0.4% higher than that of MEC without pretreatment.Conclusion Ultrasonic pretreatment of sewage sludge improved the methane production and organic removal in microbial electrolysis cells. It is necessary to find the optimal operating conditions to obtain the maximize the performance.
目的:研究超声波预处理对初级污泥(原污泥)溶解及其后续微生物电解池(MECs)运行性能的影响。方法:为了比较超声对原污泥溶解的影响,在1~4W/mL能量密度下进行超声预处理5~30min。在MECs操作中,原污泥作为对照组,超声预处理污泥作为实验组。为了比较MECs的性能,分析了沼气的产生和有机物的去除。结果与讨论:超声预处理的最佳实验条件为超声处理时间为30min,超声处理浓度为3W/mL。在甲烷生产中,超声预处理的MEC(MEC 3W)在1、3个循环中产生的甲烷比未经预处理的MEC(MEC)多243mL/L,多4970mL/L。在改进的Gompertz模型分析中,MEC 3W的滞后期为0.46天,比MEC长0.12天。MEC 3W的最大甲烷生成速率为938.5mL/L/天,也高于MEC。MEC 3W的TS去除率比MEC高1.8%,VS去除率为2.4%。超声波预处理对COD的去除率也提高了2.0%。超声预处理的MEC的甲烷产率(377.4mL/g VSin)比未预处理的高0.4%。结论超声波预处理污泥提高了微生物电解槽的甲烷生成和有机物去除率。为了获得最大的性能,必须找到最佳的操作条件。
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引用次数: 0
Evaluation of Accelerated Mineral Carbonation Efficiency Using Industrial By-products and Estimation of Its Domestic Carbon Dioxide Reduction Potential 工业副产品加速矿物碳化效率评价及其国内二氧化碳减排潜力估算
Pub Date : 2022-01-31 DOI: 10.4491/ksee.2022.44.1.21
Sangmin Lee, Seong Min Yeon, Sokhee P. Jung
Objectives : Cement Kiln Dust (CKD), a cement industrial by-product, was used in this study to improve the effectiveness of CO2 removal and increase the production of precipitate calcium carbonate (PCC) in the accelerated mineral carbonation process, differentiating injection flow rate of alkaline agent into the process. Further, CKD, slag, waste cement powder (WC), coal fly ash (CFA) which are mainly used for mineral carbonation, were also compared for their total CO2 removal capability by the year.Methods : The morphology and composition of CKD were analyzed using FE-SEM, EDS and XRD to evaluate its applicability to mineral carbonation, and CKD extract and 1N NaOH were added into the reactor with the flow rate range of 1.1 to 3.0 mL/min for longer reaction time. And DTA was carried out for purity analysis of PCC. Last, for annual CO2 removal potential evaluation, CKD, slag, WC and CFA was compared based on the result from this and previous researches.Results : Result showed that 1N NaOH injection at flow rate of 1.1, 2.0, 3.0 mL/min accelerated the CO2 removal by the 61.7, 77.2, 41.5% and 48.2, 52.2, 54.3 g of PCC was generated respectively. The annual amount of industrial by-product in Korea is 26,664,893 tons/year, 8,000,000 tons/year, 2,531,750 ~ 7,595,250 tons/year and 884,854 tons/year, respectively, in order of Slag, CFA, CKD, waste concrete fine powder (WC). Thus, the annual removal of CO2 could be estimated in order of CKD > Slag > CFA > WC.Conclusion CKD is a fine powder form with a high specific surface area, high calcium content, and high alkalinity. Therefore, CKD is superior to waste concrete or slag in mineral carbonation in removing CO2 and generating PCC. Considering the annual amount of CO2 removal when applying industrial by-products to the CCUS process, CKD and slag are considered the most economical mineral carbonation materials.
目的:利用水泥工业副产物水泥窑尘(CKD),在加速矿物碳化过程中提高CO2脱除效果,增加沉淀碳酸钙(PCC)的产量,并对碱性剂注入过程的流量进行区分。此外,还比较了主要用于矿物碳酸化的CKD、矿渣、废水泥粉(WC)、粉煤灰(CFA)的年度总CO2去除能力。方法:采用FE-SEM、EDS、XRD分析CKD的形貌和组成,评价其在矿物碳酸化中的适用性,并在反应器中加入CKD提取物和1N NaOH,流速为1.1 ~ 3.0 mL/min,延长反应时间。采用DTA法对PCC进行纯度分析。最后,在本研究结果和前人研究结果的基础上,对CKD、矿渣、WC和CFA进行了年度CO2去除潜力评价。结果:结果表明,1N NaOH在1.1、2.0、3.0 mL/min流速下对CO2的去除率分别提高61.7、77.2、41.5%,PCC的产出量分别提高48.2、52.2、54.3 g。韩国工业副产物年产生量依次为:矿渣、CFA、CKD、废混凝土细粉(WC),分别为266664893吨/年、800万吨/年、2531750 ~ 7595250吨/年、884854吨/年。因此,CO2的年去除率可以按CKD b>渣b> CFA > WC进行估算。结论CKD为细粉末状,具有高比表面积、高钙含量、高碱度等特点。因此,在去除CO2和生成PCC方面,CKD优于矿物碳化中的废混凝土或矿渣。考虑到工业副产物在CCUS工艺中的年CO2脱除量,CKD和矿渣被认为是最经济的矿物碳化材料。
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引用次数: 1
Characteristics of Cesium Adsorption by Alginate Bead Adsorbent with Layer-by-Layer Synthesis of Prussian Blue 逐层合成普鲁士蓝海藻酸盐珠状吸附剂对铯的吸附特性
Pub Date : 2021-12-31 DOI: 10.4491/ksee.2021.43.12.731
Bokseong Kim, Sung-Won Kang
Objectives : The purpose of this study was to develop an adsorbent to which Prussian blue (PB) is stably immobilized to remove radioactive cesium (Cs).Methods : Prussian blue-Alginate (PA) bead and Prussian blue-Alginate with Layer-by-layer synthesis (PAL) bead were synthesized by immobilizing PB respectively.Results and Discussion : As a results of XRD and FT-IR analysis, PB was successfuuly immobilized in alginate bead and PA, PAL bead. SEM (EDS) and TG analysis data were confirmed that the PB content of the PAL bead to which the LBL synthesis method was applied was improved by 6.31%. It was confirmed that the Cs adsorption capacity was improved through the LBL assembly process. The maximum adsorption amount (qm) of PA bead was 25.783 mg/g, and PAL bead was mg/g. In addition, as a result of UV-vis analysis of washing water after synthesis of PA bead and PAL bead, it was confirmed that the PB desorption of the PAL bead was lower indicating that the stability was also improved by LBL synthesis.Conclusions : We developed an adsorbent which prussianblue immobilized on alginate bead for selective removal cesium in aqueous solution. PB was immobilized by LBL synthesis method qm of PAL beads was 28.294 mg/g. It was expected to applied effectively and stably to radioactive cesium contaminated water.
目的:研制一种能稳定固定普鲁士蓝(PB)去除放射性铯(Cs)的吸附剂。结果与讨论:XRD和FT-IR分析结果表明,PB成功地固定在海藻酸盐珠和PA、PAL珠中。SEM(EDS)和TG分析数据证实,采用LBL合成方法的PAL珠的PB含量提高了6.31%。证实了通过LBL组装工艺提高了Cs的吸附能力。PA珠的最大吸附量(qm)为25.783mg/g,PAL珠为mg/g。此外,作为PA珠和PAL珠合成后洗涤水的UV-vis分析的结果,证实PAL珠的PB解吸较低,表明LBL合成也提高了稳定性。结论:我们研制了一种固定在藻酸盐珠上的选择性去除水溶液中铯的吸附剂。用LBL合成法固定化PB,PAL珠的qm为28.294mg/g。有望在放射性铯污染水中得到有效、稳定的应用。
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引用次数: 0
Plant Growth Promoting Microorganism Selection and Activity Test for Reforestation of Topsoil Restoration Site 植物生长促进微生物的选择及表层土壤复垦地造林活性试验
Pub Date : 2021-12-31 DOI: 10.4491/ksee.2021.43.12.719
Ji Seul Kim, Jun Ho Kim, Eun Young Lee
Objectives : This study was conducted to investigate the applicability of plant growth promoting microorganisms during restoration through re-vegetation of damaged topsoil.Methods : As the vegetation to be applied to the restoration site, Weigela subsessilis, Spiraea prunifolia, Pine densiflora, Pennisetum alopecuroides were selected. An attempt was made to isolate plant growth promoting microorganisms from the root zone of plants of the same species inhabiting domestic park sites and hiking trails. Plant growth promoting activities such as phosphate solubilization ability, siderophore production ability, IAA production ability, and ACC deaminase production ability were examined, and the species to be finally applied was selected and then identified. Among the strains whose plant growth promoting activity was confirmed, Arthrobacter sp. 1B2 and Paraburkholderia terrae 1P2 were applied to the genitalia and pine, respectively, and a pot experiment was conducted to confirm the activity.Results and Discussion : Forty-five strains were isolated from Weigela subsessilis, Spiraea prunifolia, Pine densiflora, Pennisetum alopecuroides and the IAA-producing ability and ACC deaminase-producing ability were confirmed for 16 strains whose phosphate solubilizing ability and siderophore-producing ability were confirmed. After selecting and identifying strains with excellent plant growth promoting ability, strains such as Cupriavidus sp, Arthrobacter sp., Pseudomonas fluorescens, Pseudomonas sp., Paraburkholderia terrae were obtained. Among them, Arthrobacter sp. 1B2 and Paraburkholderia terrae 1P2 strains were applied to genitalia and pine, respectively, and it was confirmed that plant growth was promoted.Conclusions : Bioassay experiments and field applications using plant growth promoting microorganisms have been mainly studied for herbaceous species (Grandaceae, corn, oats, etc.). However, in this study, the applied plants are shrubs class, which do not significantly grow in length, targeting damaged areas with high subsoil content, which are poor in environment and insufficient in organic and inorganic matter. Therefore, it is meaningful in that the activity of plant growth promoting microorganisms focused on absorption of inorganic substances, such as phosphate solubilization activity and siderophore ability, was investigated and the activity was confirmed by performing a bioassay.
目的:本研究旨在探讨促进植物生长的微生物在受损表土恢复过程中的适用性。方法:选择薇葛拉、绣线菊、赤松、狼牙草为恢复区植被。试图从居住在国内公园和徒步小径的同类植物的根区中分离出促进植物生长的微生物。考察了植物的促生长活性,如磷酸盐溶解能力、铁载体产生能力、IAA产生能力和ACC脱氨酶产生能力,并筛选和鉴定了最终应用的物种。在已证实具有植物生长促进活性的菌株中,将节杆菌1B2和对地拟伯克霍尔德菌1P2分别应用于生殖器和松树,并进行盆栽实验以证实其活性。结果与讨论:从魏格拉、绣线菊、赤松、苦叶狼尾草中分离得到45株菌株,其中16株菌株的IAA产生能力和ACC脱氨酶产生能力得到了证实,其溶磷能力和铁载体产生能力得到证实。经过筛选鉴定,获得了Cupriavidus sp、Arthrobacter sp.、Pseudomonas fluorescens、Pseudodomonas sp.、Paraburkholderia terrae等具有良好促生长能力的菌株。其中,节杆菌1B2和地形副伯克霍尔德菌1P2菌株分别应用于生殖器和松树,证实了植物生长得到了促进。结论:利用植物生长促进微生物进行的生物测定实验和田间应用主要针对草本物种(Grandaceae、玉米、燕麦等)。然而,在本研究中,应用植物为灌木类,其长度不显著,针对底土含量高的受损区域,其环境较差,有机物和无机物不足。因此,研究以吸收无机物质为重点的植物生长促进微生物的活性,如磷酸盐增溶活性和铁载体能力,并通过生物测定证实其活性,是有意义的。
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引用次数: 0
Qualitative Evaluation of Factors Inducing Environmental Pollution of the Sandy Beaches of Jeju Island Using Styrene Oligomers 苯乙烯低聚物对济州岛沙质海滩环境污染因素的定性评价
Pub Date : 2021-12-31 DOI: 10.4491/ksee.2021.43.12.700
B. Kwon, Jea-Jun Ko, Jeong-Hun Park
Objectives : Plastic pollution is a very important environmental issue in Korea as well as abroad. The objective of this study is to evaluate the internal and external factors that cause pollution of the coastal environment of Jeju Island using styrene oligomers (SOs) originated from polystyrene (PS) plastic.Methods : In order to achieve the above objective, this study is conducted to quantitatively measure the concentration of 12 individual SOs chemicals, through gas chromatography/mass spectroscopy (GC/MS) analyzing seawater and beach sand samples around sandy beaches in Jeju Island. This study evaluates the degree of environmental pollution according to internal or external factors of the sandy beach by using the physicochemical characteristic that SOs species are adsorbed on the surface of sand particles.Results and Discussion : The average concentration of SOs in the beach sand of Jeju Island ranges from a minimum of 9.80 ng/g to a maximum of 13.62 ng/g, and the average concentration of SOs in seawater is relatively low with a constant 0.05 to 0.11 µg/L. Although the concentration distribution of SOs species differs considerably depending on the sample collected, the concentration of SOs decreases in the order of styrene trimers (7 isomers) > styrene dimers (4 isomers) > styrene monomer. As a result of monitoring, the concentration of SOs at the sandy beaches of Jeju Island is much higher in the beach sand than in the seawater. This result means that the major beaches of Jeju Island can be polluted mainly by internal factors (e.g. population density, number of travelers according to population movement, and so on), because SOs species are adsorbed on the surface of the sand particles and their mobility is limited.Conclusions : This study shows that the sandy beaches of Jeju Island are mainly polluted by internal factors. It is thought that the pollution degree of the sandy beaches is the highest in the order of Gwakji Beach < Samyang Beach, Hamdeok Beach, Pyoseon Beach < Ihoteho Beach, Sagye Beach < Seopjikoji Beach, Gimnyeong Beach, and Hyeopjae Beach. This study is expected to contribute to the evaluation of the causes of plastic pollution in the coastal environment of Jeju Island.
目标:塑料污染在韩国和国外都是一个非常重要的环境问题。本研究的目的是评估使用源自聚苯乙烯(PS)塑料的苯乙烯低聚物(SO)污染济州岛沿海环境的内部和外部因素。方法:为了达到上述目的,本研究通过气相色谱/质谱(GC/MS)分析济州岛沙滩周围的海水和沙滩沙样品,定量测定了12种SOs化学物质的浓度。本研究利用硫物种吸附在沙粒表面的物理化学特征,根据沙滩的内部或外部因素来评估环境污染程度。结果与讨论:济州岛沙滩砂中SOs的平均浓度从最小9.80纳克/克到最大13.62纳克/克不等,海水中SOs平均浓度相对较低,恒定值为0.05至0.11µg/L。尽管SOs物种的浓度分布因所收集的样品而异,但SOs的浓度按苯乙烯三聚体(7种异构体)>苯乙烯二聚体(4种异构物)>苯乙烯单体的顺序降低。监测结果显示,济州岛沙滩的SOs浓度在沙滩砂中远高于海水。这一结果意味着济州岛的主要海滩可能主要受到内部因素的污染(如人口密度、根据人口流动的旅行者数量等),因为SOs物种吸附在沙粒表面,其流动性有限。结论:济州岛沙滩污染主要受内部因素影响。据认为,沙质海滩的污染程度最高,依次为Gwakji海滩<Samyang海滩、Hamdeok海滩、Pyoseon海滩<Ihoteho海滩、Sagye海滩<Seopjikoji海滩、Gimnyeong海滩和Hyeopjae海滩。这项研究有望有助于评估济州岛沿海环境中塑料污染的原因。
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引用次数: 2
The Current State of Management and Disposal of Wastes Related to COVID-19 : A review 与COVID-19有关的废物管理和处置现状:综述
Pub Date : 2021-12-31 DOI: 10.4491/ksee.2021.43.12.739
Jeong-ki Yoon, Young-Nae Yoon, S. Yun, Wontae Lee
Objectives : This paper summarizes effective waste management and disposal methods for plastic and medical wastes during the prolonged COVID-19 pandemic.Methods : We reviewed the literatures reporting and identifying the current status and characteristics of wastes related to COVID-19, and the management and treatment guidelines for those wastes. We also investigated various technologies for waste treatment and disposal, and assessed the current status and future direction of the technologies in Korea.Results and Discussion : In the first half of 2020 in Korea, the amount of plastic waste produced had increased by 15.6% year-on-year, and medical waste production also increased significantly from 0.6 ton in January 2020 to 2,928 ton in August 2021. All of the infectious wastes are currently being incinerated in Korea, but there are concerns on air pollutant emissions and insufficient treatment facilities. Municipal solid waste also suffers from a lack of landfill capacity and low price competitiveness in the recycling industry.Conclusions : Policy and system need to be improved to reduce the infectious waste generation from the sources, and treatment and disposal technologies for produced wastes also need to be developed. Furthermore, hospitals and health care facilities should establish their own waste reducing systems which may include chemical treatment and sterilization units.
目的:总结新冠肺炎大流行期间塑料和医疗废物的有效管理和处置方法。方法:回顾文献报道,明确新型冠状病毒相关废弃物的现状和特征,以及相关废弃物的管理和处理指南。我们还调查了各种废物处理和处置技术,并评估了韩国技术的现状和未来方向。结果与讨论:2020年上半年,韩国塑料废弃物产生量同比增长15.6%,医疗废弃物产生量也从2020年1月的0.6吨大幅增长至2021年8月的2928吨。目前,所有的传染性废物都在国内进行焚烧处理,但有人担心会排放大气污染物,而且处理设施不足。城市固体废物还面临填埋能力不足和回收行业价格竞争力低下的问题。结论:需要完善政策和制度,从源头上减少传染性废物的产生,并开发生产废物的处理和处置技术。此外,医院和保健设施应建立自己的减少废物系统,其中可包括化学处理和灭菌装置。
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引用次数: 5
Development of Inorganic Impregnated Phase Change Material(PCM) in the Pores of Activated Carbon 活性炭孔隙中无机浸渍相变材料(PCM)的研制
Pub Date : 2021-12-31 DOI: 10.4491/ksee.2021.43.12.709
Soyoung Baek, Y. Ghaffari, Jiyeol Bae, K. Kim
Objectives : Recently, energy-related research has shifted from developing alternative energy to the efficient management technology of the produced energy. As an alternative, research on phase change materials (PCMs) capable of absorbing and releasing heat as an energy medium has been conducted. This study developed a more efficient heat storage medium using activated carbon as a medium for the phase change material. At the same time, we developed a method for efficiently impregnating the phase change material into the activated carbon pores.Methods : The activated carbon used in this experiment was charcoal powder activated carbon (250-350 mesh) and granular activated carbon. The inorganic phase change materials used in the experiment was manganese nitrate hexahydrate. The method for impregnating the phase change material was pressurization method and dilution method. The heat absorption / emission capacity of the developed material was examined within the range of 10℃ to 50℃.Results and Discussion : The Scanning electron microscope (SEM) and Transmission electron microscopy energy-dispersive X-ray spectroscopy (TEM-EDX) analysis showed that the phase change material was filled in the pore of activated carbon. When the phase change material is filled by the pressurized method, the material properties of manganese nitrate hexahydrate are reflected, resulting in absorption and release of heat at each phase change temperature. As a result of experiments for the selection of the optimum solvent in the phase change material filling study using the dilution method, when ethanol was used as the solvent, the heat absorption was clearly observed even after the phase change material was loaded. As a result of selecting the optimal dilution ratio, the ratio of ethanol was determined to be 1:1 as the dilution ratio with the lowest amount of floating activated carbon. The optimal solvent removal method experimental results show that the heat absorption/release section occurred when the ethanol was removed by evaporation at 85℃ temperature.Conclusions : 1) Both the pressurization method and the dilution method are filling methods in which inorganic phase change materials can be immobilized inside activated carbon, and heat absorption and release characteristics are maintained even after loading. 2) The heat absorption release was maintained for ethanol and the optimal dilution ratio was 1:1. 3) In case of the dilute solvent removal method, the heat absorption/release capacity was maintained when the solvent was removed using only the vaporization method.
目的:近年来,能源相关研究已从开发替代能源转向生产能源的高效管理技术。作为一种替代方案,已经对能够吸收和释放热量作为能量介质的相变材料(PCM)进行了研究。本研究开发了一种更有效的储热介质,使用活性炭作为相变材料的介质。同时,我们开发了一种将相变材料有效地浸渍到活性炭孔隙中的方法。方法:本实验所用活性炭为炭粉活性炭(250-350目)和颗粒状活性炭。实验中使用的无机相变材料是六水合硝酸锰。浸渍相变材料的方法有加压法和稀释法。结果与讨论:扫描电子显微镜(SEM)和透射电子显微镜(TEM-EDX)分析表明,相变材料填充在活性炭的孔隙中。当通过加压方法填充相变材料时,六水合硝酸锰的材料性质得到了反映,导致在每个相变温度下热量的吸收和释放。作为在使用稀释法的相变材料填充研究中选择最佳溶剂的实验的结果,当使用乙醇作为溶剂时,即使在加载相变材料之后也能清楚地观察到热吸收。作为选择最佳稀释比的结果,确定乙醇的比例为1:1作为具有最低量的浮动活性炭的稀释比。最佳溶剂去除方法实验结果表明,当乙醇在85℃下蒸发去除时,会出现吸热/放热段。结论:1)加压法和稀释法都是将无机相变材料固定在活性炭内的填充方法,即使在负载后也能保持吸热和放热特性。2) 乙醇保持吸热释放,最佳稀释比为1:1。3) 在稀释溶剂去除方法的情况下,当仅使用蒸发方法去除溶剂时,保持热吸收/释放能力。
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