首页 > 最新文献

daehanhwangyeonggonghaghoeji最新文献

英文 中文
Analysis of Changes and Statistical Characteristics in PM-2.5 based on the Seasonal Management Data 基于季节管理数据的pm2.5变化及统计特征分析
Pub Date : 2022-08-31 DOI: 10.4491/ksee.2022.44.8.276
Hyunjun Ahn, Dongju Kim, Okgil Kim, Jae-Bum Lee, Daegyun Lee
Objectives : This study aims to identify the changes and statistical characteristics of the observed concentration data of fine particles (PM-2.5), one of the air environment indicators, and to analyze the variability of observation data in South Korea based on the statistical significance of the observation data.Methods : We analyzed the changes and characteristics of daily average PM-2.5 observations based on descriptive statistics (the basic statistical and frequency analysis), and inference statistics (analysis of variance and post-hoc analysis) from December to March for the period 2015 to 2021.Results and Discussion : Through ANOVA analysis and post-hoc analysis, it was confirmed that there was a statistically significant difference in the observed PM-2.5 as of the winter of 2019. Before 2019, the frequency of observed data greater 30 µg/m3 was relatively more than after 2019, and on the contrary, the frequency of observed data less than 20 µg/m3 was smaller than after 2019. After 2019, the frequency of high-concentration observations greater than 50 µg/m3 was insignificant, and on the contrary, the frequency of observations less than 20 µg/m3 was more than before 2019. As a result, It’s an average difference of 7.5 µg/m3 between before and after 2019, and it was reduced by about 24% compared to the average before 2019. Meanwhile, as a result of examining the weather influence (wind direction and wind speed) to analyze the causes of the observed data differences before and after 2019, no significant differences were identified between the two periods due to the influence of meteorological conditions.Conclusion : The observed concentration of PM-2.5 data set in South Korea showed variability as of the winter season of 2019 at the significance level of 5%. The variability could be more attributed to anthropogenic activities and socio-environmental changes such as COVID-19 rather than natural environmental factors such as meteorological factors. In order to more effectively manage air quality, it is necessary to identify social changes and their flows, and at the same time conduct continuous and systematic research such as data expansion and analysis technique development.
目的:本研究旨在识别空气环境指标之一的细颗粒物(PM-2.5)观测浓度数据的变化和统计特征,并基于观测数据的统计显著性分析韩国观测数据的变异性。方法:采用描述性统计方法(基础统计和频次分析)和推理统计方法(方差分析和事后分析)对2015 - 2021年12月至3月pm2.5日均值观测值的变化特征进行分析。结果与讨论:通过方差分析和事后分析证实,截至2019年冬季,两地pm2.5观测值存在统计学差异。在2019年之前,大于30µg/m3的观测数据频率相对高于2019年之后,反之,小于20µg/m3的观测数据频率相对低于2019年之后。2019年之后,大于50µg/m3的高浓度观测频率不显著,相反,小于20µg/m3的观测频率较2019年之前有所增加。因此,2019年前后的平均差异为7.5µg/m3,与2019年之前的平均值相比降低了约24%。同时,通过考察天气影响(风向、风速)对2019年前后观测数据差异的原因进行分析,发现由于气象条件的影响,两个时间段之间没有明显差异。结论:韩国观测到的pm2.5浓度数据集在2019年冬季呈现变异性,显著性水平为5%。这种变异性可能更多地归因于人为活动和COVID-19等社会环境变化,而不是气象因素等自然环境因素。为了更有效地管理空气质量,有必要识别社会变化及其流向,同时进行数据扩展和分析技术开发等持续系统的研究。
{"title":"Analysis of Changes and Statistical Characteristics in PM-2.5 based on the Seasonal Management Data","authors":"Hyunjun Ahn, Dongju Kim, Okgil Kim, Jae-Bum Lee, Daegyun Lee","doi":"10.4491/ksee.2022.44.8.276","DOIUrl":"https://doi.org/10.4491/ksee.2022.44.8.276","url":null,"abstract":"Objectives : This study aims to identify the changes and statistical characteristics of the observed concentration data of fine particles (PM-2.5), one of the air environment indicators, and to analyze the variability of observation data in South Korea based on the statistical significance of the observation data.Methods : We analyzed the changes and characteristics of daily average PM-2.5 observations based on descriptive statistics (the basic statistical and frequency analysis), and inference statistics (analysis of variance and post-hoc analysis) from December to March for the period 2015 to 2021.Results and Discussion : Through ANOVA analysis and post-hoc analysis, it was confirmed that there was a statistically significant difference in the observed PM-2.5 as of the winter of 2019. Before 2019, the frequency of observed data greater 30 µg/m3 was relatively more than after 2019, and on the contrary, the frequency of observed data less than 20 µg/m3 was smaller than after 2019. After 2019, the frequency of high-concentration observations greater than 50 µg/m3 was insignificant, and on the contrary, the frequency of observations less than 20 µg/m3 was more than before 2019. As a result, It’s an average difference of 7.5 µg/m3 between before and after 2019, and it was reduced by about 24% compared to the average before 2019. Meanwhile, as a result of examining the weather influence (wind direction and wind speed) to analyze the causes of the observed data differences before and after 2019, no significant differences were identified between the two periods due to the influence of meteorological conditions.Conclusion : The observed concentration of PM-2.5 data set in South Korea showed variability as of the winter season of 2019 at the significance level of 5%. The variability could be more attributed to anthropogenic activities and socio-environmental changes such as COVID-19 rather than natural environmental factors such as meteorological factors. In order to more effectively manage air quality, it is necessary to identify social changes and their flows, and at the same time conduct continuous and systematic research such as data expansion and analysis technique development.","PeriodicalId":52756,"journal":{"name":"daehanhwangyeonggonghaghoeji","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44643485","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation on applying Condensate from Food Waste Dry Process as External Carbon Source to Biological Denitrification Process 食品垃圾干法冷凝液作为外碳源应用于生物脱氮工艺的评价
Pub Date : 2022-07-31 DOI: 10.4491/ksee.2022.44.7.235
J. Jeung, Tae Young Kim, Yu Kyung Kim, Jea-Jun Song, S. Chang, W. Chung
Objectives:In this study, the applicability of dry condensate generated from food waste dry feed conversion process was evaluated as an external carbon source to increase the efficiency of the biological denitrification process.Methods:The experiment was carried out in the form of a batch test, and dry condensate was injected into each reactor according to the COD and T/N ratio (C/N ratio). Then, the reactor was operated under anoxic conditions for 5 hours, and nitrate nitrogen was analyzed at intervals of 1 hour.Results and Discussion:The dry condensate from food waste showed a low nitrogen content (T-N 220 mg/L) compared to a high organic matter content (TCOD 21,863 mg/L), and was analyzed to satisfy the conditions of an external carbon source in the denitrification process. And as a result of the experiment, it was found that the nitrate nitrogen removal efficiency was up to 76% after 5 hours at a C/N ratio 7.50:1, which was significantly increased compared to the control which was without condensed water (removal efficiency 4%). Moreover, the removal efficiency of 28% was exhibited even at the C/N ratio 0.95:1, which exhibited the lowest efficiency. In addition, as a result of calculating the specific denitrification rate (SDNR) for each C/N ratio, 7.50:1 was found to be as 0.0726 mg NO3-/mg VSS/d, which was significantly increased than that of control as 0.0038mg NO3-/mg VSS/d.Conclusion:Based on these results, it is judged that it is possible to utilize the dried condensate of food waste as an external carbon source in the denitrification process.
目的:本研究对食物垃圾干饲料转化过程产生的干凝结水作为提高生物脱氮效率的外部碳源的适用性进行了评价。方法:采用间歇式试验的方式,按COD和T/N比(C/N比)向各反应器注入干凝析液。然后在缺氧条件下运行5小时,每隔1小时对硝态氮进行分析。结果与讨论:厨余干冷凝物的氮含量较低(T-N为220 mg/L),有机物含量较高(TCOD为21863 mg/L),可以满足反硝化过程中外部碳源的条件。实验结果表明,在C/N比为7.50:1的条件下,处理5 h后硝酸盐氮的去除率可达76%,较不加冷凝水的对照(去除率4%)有显著提高。当C/N为0.95:1时,其去除率最低,为28%。此外,通过计算各C/N比下的比反硝化速率(SDNR),得到7.50:1的比反硝化速率为0.0726 mg NO3-/mg VSS/d,显著高于对照的0.0038mg NO3-/mg VSS/d。结论:基于以上结果,判断在反硝化过程中,可利用餐厨垃圾的干燥冷凝水作为外部碳源。
{"title":"Evaluation on applying Condensate from Food Waste Dry Process as External Carbon Source to Biological Denitrification Process","authors":"J. Jeung, Tae Young Kim, Yu Kyung Kim, Jea-Jun Song, S. Chang, W. Chung","doi":"10.4491/ksee.2022.44.7.235","DOIUrl":"https://doi.org/10.4491/ksee.2022.44.7.235","url":null,"abstract":"Objectives:In this study, the applicability of dry condensate generated from food waste dry feed conversion process was evaluated as an external carbon source to increase the efficiency of the biological denitrification process.Methods:The experiment was carried out in the form of a batch test, and dry condensate was injected into each reactor according to the COD and T/N ratio (C/N ratio). Then, the reactor was operated under anoxic conditions for 5 hours, and nitrate nitrogen was analyzed at intervals of 1 hour.Results and Discussion:The dry condensate from food waste showed a low nitrogen content (T-N 220 mg/L) compared to a high organic matter content (TCOD 21,863 mg/L), and was analyzed to satisfy the conditions of an external carbon source in the denitrification process. And as a result of the experiment, it was found that the nitrate nitrogen removal efficiency was up to 76% after 5 hours at a C/N ratio 7.50:1, which was significantly increased compared to the control which was without condensed water (removal efficiency 4%). Moreover, the removal efficiency of 28% was exhibited even at the C/N ratio 0.95:1, which exhibited the lowest efficiency. In addition, as a result of calculating the specific denitrification rate (SDNR) for each C/N ratio, 7.50:1 was found to be as 0.0726 mg NO3-/mg VSS/d, which was significantly increased than that of control as 0.0038mg NO3-/mg VSS/d.Conclusion:Based on these results, it is judged that it is possible to utilize the dried condensate of food waste as an external carbon source in the denitrification process.","PeriodicalId":52756,"journal":{"name":"daehanhwangyeonggonghaghoeji","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47502520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Carbon Dioxide and Particulate Matter Generation Analysis and Policy Suggestions in Drive-thru Service System 免下车服务系统中二氧化碳和颗粒物生成分析及政策建议
Pub Date : 2022-07-31 DOI: 10.4491/ksee.2022.44.7.242
Junbeum Kim, Soon-Bark Kwon, Jaeryeong Song
Objectives:Recently, during two-three years of the COVID-19 pandemic, the drive-thru service system has been one of the most actively used non-face-to-face systems to reduce the risk of infection. The business of coffee shops and fast-food restaurants using drive-thru service systems keeps growing. However, carbon dioxide and particulate matter problems in idle running, including traffic congestion and pedestrian safety issue, were brought up in the drive-thru service systems. In this study, carbon dioxide and particulate matter generation were calculated. Also, we proposed existing problems, improvements, and policy issues.Methods:We calculated the carbon dioxide and particulate matter generation in the idle running of vehicles in drive-thru service using several assumptions, the number of vehicles, the idle running time, and emission factors.Results and Discussion:We provided the carbon dioxide and particulate matter generation in the drive-thru service system. Also, we proposed and explained the existing problems, improvements, and policy issues; employees’ respiratory health problems, installation of particulate matter reduction and monitoring system, “Idle Stop & GO” and eco mode use, Performance of environmental improvement charge, single-use cup & product and collection issue.Conclusion:More accurate calculations and studies are needed using more good data such as the number of vehicles, the idle running time, and emission factors. More active policy applications should be considered with revealed problems and proposed improvements in this study.
目标:最近,在2019冠状病毒病大流行的两三年里,免下车服务系统是减少感染风险最积极使用的非面对面服务系统之一。使用“得来速”服务系统的咖啡店和快餐店的业务不断增长。但是,在“得来速”服务系统中,出现了交通堵塞、行人安全等空转过程中的二氧化碳和颗粒物问题。在本研究中,计算了二氧化碳和颗粒物的产生。同时提出了存在的问题、改进措施和政策问题。方法:采用车辆数量、车辆怠速运行时间和排放因子等假设条件,计算了车辆怠速运行过程中产生的二氧化碳和颗粒物。结果与讨论:我们提供了汽车通道服务系统中二氧化碳和颗粒物的产生。提出并说明存在的问题、需要改进的地方和政策问题;员工的呼吸健康问题,颗粒物减少和监测系统的安装,“怠速走走”和生态模式的使用,环境改善收费的绩效,一次性杯子和产品以及收集问题。结论:车辆数量、怠速运行时间、排放因子等数据需要更准确的计算和研究。本研究应考虑更积极的政策应用,并提出改进建议。
{"title":"Carbon Dioxide and Particulate Matter Generation Analysis and Policy Suggestions in Drive-thru Service System","authors":"Junbeum Kim, Soon-Bark Kwon, Jaeryeong Song","doi":"10.4491/ksee.2022.44.7.242","DOIUrl":"https://doi.org/10.4491/ksee.2022.44.7.242","url":null,"abstract":"Objectives:Recently, during two-three years of the COVID-19 pandemic, the drive-thru service system has been one of the most actively used non-face-to-face systems to reduce the risk of infection. The business of coffee shops and fast-food restaurants using drive-thru service systems keeps growing. However, carbon dioxide and particulate matter problems in idle running, including traffic congestion and pedestrian safety issue, were brought up in the drive-thru service systems. In this study, carbon dioxide and particulate matter generation were calculated. Also, we proposed existing problems, improvements, and policy issues.Methods:We calculated the carbon dioxide and particulate matter generation in the idle running of vehicles in drive-thru service using several assumptions, the number of vehicles, the idle running time, and emission factors.Results and Discussion:We provided the carbon dioxide and particulate matter generation in the drive-thru service system. Also, we proposed and explained the existing problems, improvements, and policy issues; employees’ respiratory health problems, installation of particulate matter reduction and monitoring system, “Idle Stop & GO” and eco mode use, Performance of environmental improvement charge, single-use cup & product and collection issue.Conclusion:More accurate calculations and studies are needed using more good data such as the number of vehicles, the idle running time, and emission factors. More active policy applications should be considered with revealed problems and proposed improvements in this study.","PeriodicalId":52756,"journal":{"name":"daehanhwangyeonggonghaghoeji","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43052512","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of Individual and Mixture Toxicity of Heavy Metals using Semi-continuous Type Sulfur Oxidizing Bacteria (SOB) Bioreactor 用半连续型硫氧化菌(SOB)生物反应器评价重金属的个体和混合物毒性
Pub Date : 2022-07-31 DOI: 10.4491/ksee.2022.44.7.225
Seung-Ha Kim, Heonseop Eom, Woochang Kang, Sang-Eun Oh
Objectives:In this research, individual toxicity evaluation of heavy metals (Hg2+, Cr6+, Cd2+) was performed using a semi-continuous type bioreactor based on changes in the activity of sulfur oxidizing bacteria(SOB), and the purpose is to evaluate the toxic interaction of heavy metals through mixture toxicity evaluation and prediction modeling based on individual toxicity evaluation.Methods:SOB were separated into a reactor, and then the culture medium and heavy metal influent were automatically injected at 1-hour intervals under the optimized conditions. Heavy metal mixture influent for composite toxicity evaluation was produced and tested based on the individual EC50 value of each heavy metal based on the change in electrical conductivity(EC). Based on the results of the mixture toxicity evaluation, the CA, IA, and CI models are implemented, and after comparison with the actual experimental values, similarity with the model was verified through the MDR index. And the type of interaction (synergism, antagonism) was evaluated by CI value.Results and Discussion:In case of individual toxicity evaluation experiments, the individual EC50 of each heavy metal was derived at Hg2+ 0.71mg/L, Cr6+ 1.02 mg/L, and Cd2+ 8.82 mg/L in the order of strong toxicity. As a result of performing a combined toxicity evaluation based on individual EC50 values, it was judged that the combination of Hg2++Cd2+ showed a strong similarity with the IA model and no toxic interaction was developed, but all the remaining combinations were with the CI model. A similar relationship was shown and the existence of toxic interactions could be determined. As a result of analyzing the CI value, synergistic effects appeared in all combinations in which the interaction existed, and based on this result, it was possible to determine that Cr6+ is a factor that induces the toxic interaction. Conclusion:This study allowed a real-time toxicity monitoring system for SOB to verify sensitive toxicity detection for functional and non-essential metals. In addition, most heavy metal combinations generate synergistic effects during toxic interactions, and additional research on heavy metals and organic pollutants other than heavy metals used in this study will result in a more systematic ecotoxicity monitoring system.
目的:本研究基于硫氧化菌(SOB)活性变化,利用半连续式生物反应器对重金属(Hg2+、Cr6+、Cd2+)进行个体毒性评价,目的是通过基于个体毒性评价的混合毒性评价和预测建模,评价重金属的毒性相互作用。方法:将SOB分离到反应器中,在优化的条件下,每隔1 h自动注入培养基和重金属进水。根据电导率(EC)的变化,根据每种重金属的单独EC50值,制作并测试了用于复合毒性评价的重金属混合物进水。根据混合物毒性评价结果,分别建立了CA、IA和CI模型,并与实际实验值进行比较,通过MDR指数验证与模型的相似性。并用CI值评价相互作用类型(增效、拮抗)。结果与讨论:在个体毒性评价实验中,各重金属的个体EC50按强毒性顺序分别为Hg2+ 0.71mg/L、Cr6+ 1.02 mg/L、Cd2+ 8.82 mg/L。基于个体EC50值进行联合毒性评价,判断Hg2++Cd2+组合与IA模型具有很强的相似性,未发生毒性相互作用,其余组合均与CI模型具有毒性相互作用。结果也显示出类似的关系,可以确定是否存在毒性相互作用。通过CI值分析,所有存在相互作用的组合均出现协同效应,由此可以确定Cr6+是诱导毒性相互作用的因子。结论:本研究为SOB提供了一个实时毒性监测系统,以验证对功能金属和非必需金属的敏感毒性检测。此外,大多数重金属组合在毒性相互作用中产生协同效应,除了本研究中使用的重金属外,对重金属和有机污染物的进一步研究将导致更系统的生态毒性监测系统。
{"title":"Evaluation of Individual and Mixture Toxicity of Heavy Metals using Semi-continuous Type Sulfur Oxidizing Bacteria (SOB) Bioreactor","authors":"Seung-Ha Kim, Heonseop Eom, Woochang Kang, Sang-Eun Oh","doi":"10.4491/ksee.2022.44.7.225","DOIUrl":"https://doi.org/10.4491/ksee.2022.44.7.225","url":null,"abstract":"Objectives:In this research, individual toxicity evaluation of heavy metals (Hg2+, Cr6+, Cd2+) was performed using a semi-continuous type bioreactor based on changes in the activity of sulfur oxidizing bacteria(SOB), and the purpose is to evaluate the toxic interaction of heavy metals through mixture toxicity evaluation and prediction modeling based on individual toxicity evaluation.Methods:SOB were separated into a reactor, and then the culture medium and heavy metal influent were automatically injected at 1-hour intervals under the optimized conditions. Heavy metal mixture influent for composite toxicity evaluation was produced and tested based on the individual EC50 value of each heavy metal based on the change in electrical conductivity(EC). Based on the results of the mixture toxicity evaluation, the CA, IA, and CI models are implemented, and after comparison with the actual experimental values, similarity with the model was verified through the MDR index. And the type of interaction (synergism, antagonism) was evaluated by CI value.Results and Discussion:In case of individual toxicity evaluation experiments, the individual EC50 of each heavy metal was derived at Hg2+ 0.71mg/L, Cr6+ 1.02 mg/L, and Cd2+ 8.82 mg/L in the order of strong toxicity. As a result of performing a combined toxicity evaluation based on individual EC50 values, it was judged that the combination of Hg2++Cd2+ showed a strong similarity with the IA model and no toxic interaction was developed, but all the remaining combinations were with the CI model. A similar relationship was shown and the existence of toxic interactions could be determined. As a result of analyzing the CI value, synergistic effects appeared in all combinations in which the interaction existed, and based on this result, it was possible to determine that Cr6+ is a factor that induces the toxic interaction. Conclusion:This study allowed a real-time toxicity monitoring system for SOB to verify sensitive toxicity detection for functional and non-essential metals. In addition, most heavy metal combinations generate synergistic effects during toxic interactions, and additional research on heavy metals and organic pollutants other than heavy metals used in this study will result in a more systematic ecotoxicity monitoring system.","PeriodicalId":52756,"journal":{"name":"daehanhwangyeonggonghaghoeji","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45468766","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Hydrogen Production of Clean Energy by Partial Oxidation of Methane over M(1)-Ni(5)/SBA-15 (M = Tb, Pr, Eu, and Dy) Catalysts 甲烷在M(1)-Ni(5)/SBA-15(M=Tb、Pr、Eu和Dy)催化剂上部分氧化制备清洁能源的氢气
Pub Date : 2022-07-31 DOI: 10.4491/ksee.2022.44.7.217
H. Seo
Objectives : In order to solve the environmental problem that is the cause of the global greenhouse effect, We want to evaluate the effects of 1wt% of lanthanum (Tb, Pr, Eu, and Dy) as a promoter added to Ni(5)/SBA-15 catalyst by performing the partial oxidation of methane, the main component of natural gas, to hydrogen over M(1)-Ni(5)/SBA-15 (M = Tb, Pr, Eu and Dy) catalyst and to identify the active site of the catalyst by means of instrumentation such as XPS, FETEM, and EDS.Methods : The catalytic activities of the partial oxidation of methane (POM) to hydrogen as a clean energy over M(1)-Ni(5)/SBA-15 (M = Tb, Pr, Eu, and Dy) catalysts are investigated using a fixed bed flow reactor under atmospheric pressure. The active sites of the catalyst are verified through instrumental analysis with XPS, FETEM, and EDS.Results and Discussion : The XPS results show that when 1wt% of Eu is added to the Ni(5)/SBA-15 catalyst, the atomic percent of Ni2p3/2 is increased from 0.12% to 0.15%, and the oxygen atomic number including lattice oxygen and oxygen vacancies is increased 1.32 times compared to that of the Ni(5)/SBA-15 catalyst. Further, the O1s characteristic peak is chemically shifted toward the lower binding energy. The FETEM images show that the nanoparticles of Ni and Eu are uniformly distributed on the surface of a reduced Eu(1)-Ni(5)/SBA-15 catalyst. The EDS mappings of Eu, Ni, O, and Si are confirmed. It is believed that the activity of the catalyst was improved by increasing the dispersion of nanoparticles of Ni0 on the surface of the catalyst due to the increased mobility of oxygen by creating oxygen vacancies. Methane conversion of Ni(5)/SBA-15 catalyst was deactivated rapidly after the reaction time of 12h whereas M(1)-Ni(5)/SBA-15 (M = Tb, Pr, Eu, and Dy) catalyst showed constant and stable catalyst activity until 12h ~ 50h. It is also considered to be the case that the sintering of Ni particles is prevented by the strong metal support interaction (SMSI) effect between Eu3+, Ni2+, and the SBA-15 carrier, and the stability of the catalyst is thereby maintained. The hydrogen yield of catalyst was in the order of Eu(1)-Ni(5)/SBA-15(57.2%, 25h) >> Dy(1)-Ni(5)/SBA-15 (49%, 14h) > Pr(1)-Ni(5)/SBA-15 (43.1%, 29h) > Tb(1)-Ni(5)/SBA-15 (42.8%, 25h).Conclusion : The Ni(5)/SBA-15 catalyst was showed that the conversion of methane was rapidly reduced after a reaction time of 12h, while when 1wt% of lanthanum (Tb, Pr, Eu and Dy) as a promoter was added to the Ni(5)/SBA-15 catalyst, the conversion of methane and yields of hydrogen were showed constant and stable catalytic activity in the reaction time of 12h to 50h. It is believed that the conversion of methane was improved by increasing the dispersion of nanoparticles of Ni0 on the surface of the catalyst due to the increased mobility of oxygen by creating oxygen vacancies. Moreover, sintering of Ni0 nanoparticles on the surface of M(1)-Ni(5)/SBA-15 (M = Tb, Pr, Eu, Dy) catalyst is prevented by strong m
目的:为了解决导致全球温室效应的环境问题,我们想评估1wt%的镧(Tb、Pr、Eu和Dy)作为促进剂添加到Ni(5)/SBA-15催化剂中,通过对天然气的主要成分甲烷进行部分氧化,在M(1)-Ni(5)/SBA-15(M=Tb、Pr、Eu和Dy)催化剂上转化为氢气,方法:在常压下,使用固定床流动反应器研究了M(1)-Ni(5)/SBA-15(M=Tb,Pr,Eu和Dy)催化剂上甲烷(POM)部分氧化为清洁能源氢气的催化活性。通过XPS、FETEM和EDS的仪器分析验证了催化剂的活性位点。结果与讨论:XPS结果表明,当向Ni(5)/SBA-15催化剂中加入1wt%的Eu时,Ni2p3/2的原子百分比从0.12%增加到0.15%,与Ni(5)/SBA-15催化剂相比,包括晶格氧和氧空位的氧原子序数增加了1.32倍。此外,O1s特征峰向较低的结合能发生化学位移。FETEM图像显示,Ni和Eu的纳米颗粒均匀分布在还原的Eu(1)-Ni(5)/SBA-15催化剂表面。证实了Eu、Ni、O和Si的EDS图谱。据信,由于通过产生氧空位增加了氧的迁移率,因此通过增加Ni0纳米颗粒在催化剂表面上的分散度来提高催化剂的活性。Ni(5)/SBA-15催化剂的甲烷转化在反应12h后迅速失活,而M(1)-Ni(5)/STBA-15(M=Tb、Pr、Eu和Dy)催化剂在反应12h~50h前表现出稳定的催化剂活性。还认为,通过Eu3+、Ni2+和SBA-15载体之间的强金属-载体相互作用(SMSI)效应来防止Ni颗粒的烧结,从而保持催化剂的稳定性。催化剂的氢气产率依次为Eu(1)-Ni(5)/SBA-15(57.2%,25h)>>Dy(1,当在Ni(5)/SBA-15催化剂中加入1wt%的镧(Tb、Pr、Eu和Dy)作为助催化剂时,在12h至50h的反应时间内,甲烷的转化率和氢气的产率显示出稳定的催化活性。据信,甲烷的转化率是通过增加Ni0纳米颗粒在催化剂表面的分散来提高的,这是由于通过产生氧空位增加了氧的迁移率。此外,强金属-载体相互作用(SMSI)效应阻止了Ni0纳米颗粒在M(1)-Ni(5)/SBA-15(M=Tb,Pr,Eu,Dy)催化剂表面的烧结。
{"title":"Hydrogen Production of Clean Energy by Partial Oxidation of Methane over M(1)-Ni(5)/SBA-15 (M = Tb, Pr, Eu, and Dy) Catalysts","authors":"H. Seo","doi":"10.4491/ksee.2022.44.7.217","DOIUrl":"https://doi.org/10.4491/ksee.2022.44.7.217","url":null,"abstract":"Objectives : In order to solve the environmental problem that is the cause of the global greenhouse effect, We want to evaluate the effects of 1wt% of lanthanum (Tb, Pr, Eu, and Dy) as a promoter added to Ni(5)/SBA-15 catalyst by performing the partial oxidation of methane, the main component of natural gas, to hydrogen over M(1)-Ni(5)/SBA-15 (M = Tb, Pr, Eu and Dy) catalyst and to identify the active site of the catalyst by means of instrumentation such as XPS, FETEM, and EDS.Methods : The catalytic activities of the partial oxidation of methane (POM) to hydrogen as a clean energy over M(1)-Ni(5)/SBA-15 (M = Tb, Pr, Eu, and Dy) catalysts are investigated using a fixed bed flow reactor under atmospheric pressure. The active sites of the catalyst are verified through instrumental analysis with XPS, FETEM, and EDS.Results and Discussion : The XPS results show that when 1wt% of Eu is added to the Ni(5)/SBA-15 catalyst, the atomic percent of Ni2p3/2 is increased from 0.12% to 0.15%, and the oxygen atomic number including lattice oxygen and oxygen vacancies is increased 1.32 times compared to that of the Ni(5)/SBA-15 catalyst. Further, the O1s characteristic peak is chemically shifted toward the lower binding energy. The FETEM images show that the nanoparticles of Ni and Eu are uniformly distributed on the surface of a reduced Eu(1)-Ni(5)/SBA-15 catalyst. The EDS mappings of Eu, Ni, O, and Si are confirmed. It is believed that the activity of the catalyst was improved by increasing the dispersion of nanoparticles of Ni0 on the surface of the catalyst due to the increased mobility of oxygen by creating oxygen vacancies. Methane conversion of Ni(5)/SBA-15 catalyst was deactivated rapidly after the reaction time of 12h whereas M(1)-Ni(5)/SBA-15 (M = Tb, Pr, Eu, and Dy) catalyst showed constant and stable catalyst activity until 12h ~ 50h. It is also considered to be the case that the sintering of Ni particles is prevented by the strong metal support interaction (SMSI) effect between Eu3+, Ni2+, and the SBA-15 carrier, and the stability of the catalyst is thereby maintained. The hydrogen yield of catalyst was in the order of Eu(1)-Ni(5)/SBA-15(57.2%, 25h) >> Dy(1)-Ni(5)/SBA-15 (49%, 14h) > Pr(1)-Ni(5)/SBA-15 (43.1%, 29h) > Tb(1)-Ni(5)/SBA-15 (42.8%, 25h).Conclusion : The Ni(5)/SBA-15 catalyst was showed that the conversion of methane was rapidly reduced after a reaction time of 12h, while when 1wt% of lanthanum (Tb, Pr, Eu and Dy) as a promoter was added to the Ni(5)/SBA-15 catalyst, the conversion of methane and yields of hydrogen were showed constant and stable catalytic activity in the reaction time of 12h to 50h. It is believed that the conversion of methane was improved by increasing the dispersion of nanoparticles of Ni0 on the surface of the catalyst due to the increased mobility of oxygen by creating oxygen vacancies. Moreover, sintering of Ni0 nanoparticles on the surface of M(1)-Ni(5)/SBA-15 (M = Tb, Pr, Eu, Dy) catalyst is prevented by strong m","PeriodicalId":52756,"journal":{"name":"daehanhwangyeonggonghaghoeji","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49457852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption of Levofloxacin on Microplastics in Aqueous Solution 微塑料对左氧氟沙星的吸附研究
Pub Date : 2022-06-30 DOI: 10.4491/ksee.2022.44.6.195
Jooyoung Lee, Jeong-Ann Park
Objectives : Recently, microplastics (MPs) is observed at surface water in worldwide because of massive use of plastics. Since MPs have a large specific surface area, they could provide adsorption sites to water contaminants such as Levofloxacin (LVF). LVF is one of widely used antibiotics and is detected in surface water. Therefore, the aim of this study is to evaluate adsorption trend of LVF on polypropylene (PP) and polyethylene(PE) microplastics in aqueous solution.Methods : For kinetic adsorption experiment, 0.02 g of PP and PE MPs were placed in glass vials and mixed with LVF solution (10 mg/L) for 1-48 hours. And the experimental data was fitted to pseudo-first order and pseudo-second order. For isotherm adsorption experiment, initial LVF concentrations were varied from 1 to 25 mg/L for 24 hours and the results were applied to Langmuir and Freundlich models. The Thermodynamic adsorption experiment was conducted in the temperature range of 298-318 K. Each cations (Na+, Ca2+, Cu2+, Cr3+, Pb3+) and LVF solution were both reacted with the MPs to determine effect of LVF adsorption when cations were coexistence.Results and Discussion : Based on the FT-IR analysis, it was confirmed that the prepared PP and PE MPs were consisted of the respective single polymer. The kinetic experiment results showed that LVF adsorption on PP and PE MPs reached equilibrium at 24 hours with adsorption capacities of PP (0.748 mg/g) and PE (0.801 mg/g) MPs, respectively. Kinetic data of PP MPs was well fitted to the pseudo-first order (R2=0.986) model, while the data of PE MPs was described well by the pseudo-second order (R2=0.992) model. The results of the isotherm experiments were explained well by the Freundlich model (R2>0.97), indicating that multilayer adsorption occurred in both MPs. The thermodynamic experiments showed that LVF adsorptions on each MPs were exothermic reaction and physical adsorption process. Cations can inhibit the adsorption of LVF to the MPs.Conclusion : This study shows that LVF could be adsorbed to PP and PE MPs in aqueous solution and its adsorption capacity can be changed according to the various factors: characteristics of polymer, reaction time, initial concentration of LVF, temperature, and coexistence of cations.
目的:近年来,由于塑料的大量使用,在世界各地的地表水中发现了微塑料(MPs)。由于MPs具有较大的比表面积,它们可以为左氧氟沙星(LVF)等水污染物提供吸附位点。LVF是应用广泛的抗生素之一,在地表水中检测到。因此,本研究的目的是评价LVF在水溶液中对聚丙烯(PP)和聚乙烯(PE)微塑料的吸附趋势。方法:取0.02 g PP和PE MPs分别装于玻璃瓶中,与LVF溶液(10 mg/L)混合1 ~ 48 h,进行动力学吸附实验。对实验数据进行了拟一阶和拟二阶拟合。等温吸附实验中,初始LVF浓度在1 ~ 25 mg/L范围内变化24小时,并将结果应用于Langmuir和Freundlich模型。热力学吸附实验在298 ~ 318 K的温度范围内进行。将各阳离子(Na+、Ca2+、Cu2+、Cr3+、Pb3+)和LVF溶液与MPs反应,考察阳离子共存时对LVF的吸附效果。结果与讨论:通过FT-IR分析,证实所制备的PP和PE MPs均由各自的单体聚合物组成。动力学实验结果表明,LVF对PP和PE MPs的吸附在24 h达到平衡,吸附量分别为PP (0.748 mg/g)和PE (0.801 mg/g) MPs。PP MPs的动力学数据符合拟一阶模型(R2=0.986), PE MPs的动力学数据符合拟二阶模型(R2=0.992)。等温线实验结果可以用Freundlich模型(R2>0.97)很好地解释,表明两种MPs都发生了多层吸附。热力学实验表明,LVF在各MPs上的吸附均为放热反应和物理吸附过程。阳离子可以抑制LVF对MPs的吸附。结论:本研究表明,LVF在水溶液中可以吸附在PP和PE MPs上,其吸附量可根据聚合物特性、反应时间、LVF初始浓度、温度、阳离子共存等因素而改变。
{"title":"Adsorption of Levofloxacin on Microplastics in Aqueous Solution","authors":"Jooyoung Lee, Jeong-Ann Park","doi":"10.4491/ksee.2022.44.6.195","DOIUrl":"https://doi.org/10.4491/ksee.2022.44.6.195","url":null,"abstract":"Objectives : Recently, microplastics (MPs) is observed at surface water in worldwide because of massive use of plastics. Since MPs have a large specific surface area, they could provide adsorption sites to water contaminants such as Levofloxacin (LVF). LVF is one of widely used antibiotics and is detected in surface water. Therefore, the aim of this study is to evaluate adsorption trend of LVF on polypropylene (PP) and polyethylene(PE) microplastics in aqueous solution.Methods : For kinetic adsorption experiment, 0.02 g of PP and PE MPs were placed in glass vials and mixed with LVF solution (10 mg/L) for 1-48 hours. And the experimental data was fitted to pseudo-first order and pseudo-second order. For isotherm adsorption experiment, initial LVF concentrations were varied from 1 to 25 mg/L for 24 hours and the results were applied to Langmuir and Freundlich models. The Thermodynamic adsorption experiment was conducted in the temperature range of 298-318 K. Each cations (Na+, Ca2+, Cu2+, Cr3+, Pb3+) and LVF solution were both reacted with the MPs to determine effect of LVF adsorption when cations were coexistence.Results and Discussion : Based on the FT-IR analysis, it was confirmed that the prepared PP and PE MPs were consisted of the respective single polymer. The kinetic experiment results showed that LVF adsorption on PP and PE MPs reached equilibrium at 24 hours with adsorption capacities of PP (0.748 mg/g) and PE (0.801 mg/g) MPs, respectively. Kinetic data of PP MPs was well fitted to the pseudo-first order (R2=0.986) model, while the data of PE MPs was described well by the pseudo-second order (R2=0.992) model. The results of the isotherm experiments were explained well by the Freundlich model (R2>0.97), indicating that multilayer adsorption occurred in both MPs. The thermodynamic experiments showed that LVF adsorptions on each MPs were exothermic reaction and physical adsorption process. Cations can inhibit the adsorption of LVF to the MPs.Conclusion : This study shows that LVF could be adsorbed to PP and PE MPs in aqueous solution and its adsorption capacity can be changed according to the various factors: characteristics of polymer, reaction time, initial concentration of LVF, temperature, and coexistence of cations.","PeriodicalId":52756,"journal":{"name":"daehanhwangyeonggonghaghoeji","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42501618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption-enhanced sonophotocatalytic removal of tetracycline from water using ceria-zirconia (x)CeO2-(1-x)ZrO2 binary oxide nanocatalyst 二氧化铈-氧化锆(x)CeO2-(1-x)ZrO2二元氧化物纳米催化剂吸附增强声光催化去除水中四环素
Pub Date : 2022-06-30 DOI: 10.4491/ksee.2022.44.6.203
Gyuri Kim, Yeonji Yea, Sejoon Park, Seong-Rye Byeon, Seungbeom Seo, Jun-Sung Cho, C. Park
Objectives : Tetracycline (TC) antibiotics have a risk of causing gastrointestinal and hepatic disorders and, in rare cases, photosensitivity and deposition in bone tissue.Methods : Therefore, it is urgent to develop a technology that can completely remove TC remaining in the water. In this study, a new type of sonophotocatalytic decomposition system that can efficiently decompose TC, a water-based recalcitrant trace pollutant, was proposed.Results and Discussion : As a sonophotocatalyst, xCeO2-(1-x)ZrO2 (x = 0, 0.25, 0.5, 0.75, and 1) binary nanocomposites were synthesized by hydrothermal methods, followed by X-ray diffraction, Fourier-transform infrared spectroscopy, field emission scanning electron microscope, UV-Vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller surface area techniques. Interestingly, the 0.75CeO2-0.25ZrO2 (CZ0.75) nanocomposite had low adsorption and removal ability of TC in the absence of light, but due to the synergistic effect of the material and the advanced treatment system, the remaining TC was removed by 89.2% under sonophoto irradiation for 60 min. For CZ0.75, the effect of operating factors such as initial pH of solution, catalyst dosage, reaction time, initial TC concentration, and ultrasonic intensity was studied and the mechanism was analyzed.Conclusion : In addition, through LC-MS analysis, intermediate products obtained in the TC degradation process using the CZ0.75 catalyst and the TC degradation pathway were identified.
目的:四环素(TC)抗生素有引起胃肠道和肝脏疾病的风险,在极少数情况下,光敏性和骨组织沉积。方法:因此,开发一种能够完全去除水中残留TC的技术迫在眉睫。本研究提出了一种新型的声光催化分解体系,该体系可以有效地分解水基难降解性微量污染物TC。结果与讨论:采用水热法合成了xCeO2-(1-x)ZrO2 (x = 0、0.25、0.5、0.75和1)二元纳米复合材料,并采用x射线衍射、傅里叶变换红外光谱、场发射扫描电镜、紫外-可见漫反射光谱、x射线光电子能谱、Brunauer-Emmett-Teller表面积等技术进行了表征。有趣的是,0.75CeO2-0.25ZrO2 (CZ0.75)纳米复合材料在无光条件下对TC的吸附和去除能力较低,但由于材料与深度处理系统的协同作用,在声光照射60 min后,剩余TC的去除率达到89.2%。对CZ0.75进行了溶液初始pH、催化剂用量、反应时间、初始TC浓度、超声强度等操作因素的影响,并分析了其机理。结论:此外,通过LC-MS分析,确定了使用CZ0.75催化剂降解TC过程中获得的中间产物和TC降解途径。
{"title":"Adsorption-enhanced sonophotocatalytic removal of tetracycline from water using ceria-zirconia (x)CeO2-(1-x)ZrO2 binary oxide nanocatalyst","authors":"Gyuri Kim, Yeonji Yea, Sejoon Park, Seong-Rye Byeon, Seungbeom Seo, Jun-Sung Cho, C. Park","doi":"10.4491/ksee.2022.44.6.203","DOIUrl":"https://doi.org/10.4491/ksee.2022.44.6.203","url":null,"abstract":"Objectives : Tetracycline (TC) antibiotics have a risk of causing gastrointestinal and hepatic disorders and, in rare cases, photosensitivity and deposition in bone tissue.Methods : Therefore, it is urgent to develop a technology that can completely remove TC remaining in the water. In this study, a new type of sonophotocatalytic decomposition system that can efficiently decompose TC, a water-based recalcitrant trace pollutant, was proposed.Results and Discussion : As a sonophotocatalyst, xCeO2-(1-x)ZrO2 (x = 0, 0.25, 0.5, 0.75, and 1) binary nanocomposites were synthesized by hydrothermal methods, followed by X-ray diffraction, Fourier-transform infrared spectroscopy, field emission scanning electron microscope, UV-Vis diffuse reflectance spectroscopy, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller surface area techniques. Interestingly, the 0.75CeO2-0.25ZrO2 (CZ0.75) nanocomposite had low adsorption and removal ability of TC in the absence of light, but due to the synergistic effect of the material and the advanced treatment system, the remaining TC was removed by 89.2% under sonophoto irradiation for 60 min. For CZ0.75, the effect of operating factors such as initial pH of solution, catalyst dosage, reaction time, initial TC concentration, and ultrasonic intensity was studied and the mechanism was analyzed.Conclusion : In addition, through LC-MS analysis, intermediate products obtained in the TC degradation process using the CZ0.75 catalyst and the TC degradation pathway were identified.","PeriodicalId":52756,"journal":{"name":"daehanhwangyeonggonghaghoeji","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45588991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A study on the Treatment of Hydrofluoric Acid Wastewater from Semiconductor Manufacturing Processes and the Possibility of Reuse of reclaimed water 半导体生产过程中氢氟酸废水的处理及中水回用可能性研究
Pub Date : 2022-06-30 DOI: 10.4491/ksee.2022.44.6.189
Sujeong Lee, I. Han
Objectives : By eliminating fluorine and other ions through precipitation of fluoride and UF, RO membrane filtration using the hydrofluoric acid wastewater generated from the semiconductor production processes, this study aimed to investigate the possibility of the reuse of the reclaimed wastewater for the processes.Methods : For the experiment, firstly, the 2-stage precipitation of fluoride was done using Ca(OH)2 and PAC and it aimed to judge whether the water quality standards for reuse by each market were satisfied by eliminating colloidal particles and then other metal ions through the UF and RO membrane filtration.Results and Discussion : About 93 % of F- was removed through the 1st and 2nd precipitation. It can be also removed ammonium, phosphate ions, through the UF membrane filtration, about 95 % of particulate matter was removed and finally, the water quality for reuse was satisfied through RO filtration.Conclusion : This study found that the fluorine wastewater generated from the semiconductor production processes can be reused by precipitation and filtration methods without going through the existing complicated treatment methods. In the future, through such treatment procedures, it is expected to be able to secure the reuse of the reclaimed wastewater in the process.
目的:利用半导体生产过程中产生的氢氟酸废水,通过沉淀氟化物和UF去除氟和其他离子,RO膜过滤,本研究旨在探讨回收废水再利用的可能性。方法:实验首先采用Ca(OH)2和PAC两阶段沉淀氟化物,通过UF和RO膜过滤去除胶体颗粒和其他金属离子,判断是否满足各市场的回用水质标准。结果与讨论:第一次和第二次降水去除了约93%的F-。它还可以去除铵、磷离子,通过超滤膜过滤,去除了约95%的颗粒物,最终通过RO过滤,达到了满意的回用水质。结论:本研究发现,半导体生产过程中产生的含氟废水可以通过沉淀法和过滤法进行回用,而不需要经过现有的复杂处理方法。未来,通过这种处理程序,有望确保回收废水在该过程中的再利用。
{"title":"A study on the Treatment of Hydrofluoric Acid Wastewater from Semiconductor Manufacturing Processes and the Possibility of Reuse of reclaimed water","authors":"Sujeong Lee, I. Han","doi":"10.4491/ksee.2022.44.6.189","DOIUrl":"https://doi.org/10.4491/ksee.2022.44.6.189","url":null,"abstract":"Objectives : By eliminating fluorine and other ions through precipitation of fluoride and UF, RO membrane filtration using the hydrofluoric acid wastewater generated from the semiconductor production processes, this study aimed to investigate the possibility of the reuse of the reclaimed wastewater for the processes.Methods : For the experiment, firstly, the 2-stage precipitation of fluoride was done using Ca(OH)2 and PAC and it aimed to judge whether the water quality standards for reuse by each market were satisfied by eliminating colloidal particles and then other metal ions through the UF and RO membrane filtration.Results and Discussion : About 93 % of F- was removed through the 1st and 2nd precipitation. It can be also removed ammonium, phosphate ions, through the UF membrane filtration, about 95 % of particulate matter was removed and finally, the water quality for reuse was satisfied through RO filtration.Conclusion : This study found that the fluorine wastewater generated from the semiconductor production processes can be reused by precipitation and filtration methods without going through the existing complicated treatment methods. In the future, through such treatment procedures, it is expected to be able to secure the reuse of the reclaimed wastewater in the process.","PeriodicalId":52756,"journal":{"name":"daehanhwangyeonggonghaghoeji","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41611455","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Study on the Distribution of Air Pollutants in Petrochemical Industrial Complex On Summer 石油化工园区夏季大气污染物分布研究
Pub Date : 2022-05-31 DOI: 10.4491/ksee.2022.44.5.161
J. H. Jeong, I. Kim, E. H. Oh, J. R. Lee, H. Kim
Objectives : Using a mobile laboratory equipped with Proton Transfer Reaction-Time of Flight/Mass Spectrometry (PTR-ToF-MS), we investigate the degree of air pollution level in the petrochemical industrial complex by investigating the distribution characteristics of air pollutants and tracking emission sources.Methods : The research area within the petrochemical industrial complex was measured three times each at dawn, day, night, and the distribution of VOCs at each time was investigated and presented as a pollution map. In the emission source tracking, hot spot (high-concentration) wes found by mobile monitoring, and the emission source was closely tracked by stationary monitoring.Results and Discussion : Acetaldehyde measured in the petrochemical industrial complex was confirmed to have the highest 3 to 5 degrees by direct olfactory method. In most instances the highest concentration was at dawn, potentially due to stagnant pollutants caused by temperature reversal. It was observed that the probability of finding an hot spot was higher during dawn and that it was significantly affected by the wind direction and speed at the time of measurement. When tracking the emission sources, appropriate areas of concern for contamination were selected on the basis of the stationary monitoring results, which were obtained from areas showing high concentrations after mobile monitoring.Conclusion : As a result of the investigation of the distribution characteristics and emission sources of air pollutants in the petrochemical industrial complex, we found that acetaldehyde was the major pollutant and presented an efficient method to search for areas of concern for air pollution. Through these results, it is expected that emission sources can be managed more efficiently.
目的:利用配备质子转移反应飞行时间/质谱(PTR-ToF-MS)的移动实验室,通过调查空气污染物的分布特征和跟踪排放源,了解石化工业园区的空气污染程度。方法:对石化工业园区内的研究区域分别在黎明、白天和夜间进行3次测量,并对每次测量的VOCs分布情况进行调查,以污染图的形式呈现。在排放源跟踪中,移动监测发现热点(高浓度),静止监测密切跟踪排放源。结果与讨论:用直接嗅法测定的乙醛在石化工业综合体中具有最高的3 ~ 5度。在大多数情况下,浓度最高的时候是黎明时分,这可能是由于温度逆转导致污染物停滞不前。我们观察到,在黎明发现热点的可能性较高,并且受测量时风向和风速的显著影响。在跟踪排放源时,根据固定监测结果,选择适当的污染关注区域,这些区域是在移动监测后高浓度区域获得的。结论:通过对石化工业综合体大气污染物的分布特征和排放源的调查,发现乙醛是主要污染物,为寻找大气污染的关注区域提供了一种有效的方法。通过这些结果,预计可以更有效地管理排放源。
{"title":"A Study on the Distribution of Air Pollutants in Petrochemical Industrial Complex On Summer","authors":"J. H. Jeong, I. Kim, E. H. Oh, J. R. Lee, H. Kim","doi":"10.4491/ksee.2022.44.5.161","DOIUrl":"https://doi.org/10.4491/ksee.2022.44.5.161","url":null,"abstract":"Objectives : Using a mobile laboratory equipped with Proton Transfer Reaction-Time of Flight/Mass Spectrometry (PTR-ToF-MS), we investigate the degree of air pollution level in the petrochemical industrial complex by investigating the distribution characteristics of air pollutants and tracking emission sources.Methods : The research area within the petrochemical industrial complex was measured three times each at dawn, day, night, and the distribution of VOCs at each time was investigated and presented as a pollution map. In the emission source tracking, hot spot (high-concentration) wes found by mobile monitoring, and the emission source was closely tracked by stationary monitoring.Results and Discussion : Acetaldehyde measured in the petrochemical industrial complex was confirmed to have the highest 3 to 5 degrees by direct olfactory method. In most instances the highest concentration was at dawn, potentially due to stagnant pollutants caused by temperature reversal. It was observed that the probability of finding an hot spot was higher during dawn and that it was significantly affected by the wind direction and speed at the time of measurement. When tracking the emission sources, appropriate areas of concern for contamination were selected on the basis of the stationary monitoring results, which were obtained from areas showing high concentrations after mobile monitoring.Conclusion : As a result of the investigation of the distribution characteristics and emission sources of air pollutants in the petrochemical industrial complex, we found that acetaldehyde was the major pollutant and presented an efficient method to search for areas of concern for air pollution. Through these results, it is expected that emission sources can be managed more efficiently.","PeriodicalId":52756,"journal":{"name":"daehanhwangyeonggonghaghoeji","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48186739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characteristics of Organic Compounds in PM2.5 at Seosan: Comparison of Organic Compounds in PM2.5 at Seoul 瑞山地区PM2.5中有机化合物的特征:与首尔地区PM2.5中有机化合物的比较
Pub Date : 2022-05-31 DOI: 10.4491/ksee.2022.44.5.150
Y. Lee, Zihui Teng, Ki Ae Kim, Kwang-Yul Lee, S. Park, J. Lee
Objectives : In this study, we analyzed 56 individual organic compounds in PM2.5 in Seosan, where the large complex emission sources are closely located, to characterize organic compounds distributions in this site.Methods : The sampling of PM2.5 in Seoul was also simultaneously carried out to compare the concentrations and distributions of organic compounds in PM2.5 measured in Seosan.Results and Discussion : The overall concentration of organic compounds (OCs) in Seosan was 383±165 ng/m3 , which was twice as high as the concentration in Seoul (189±67 ng/m3 ). PAHs and levoglucosan concentrations were higher in Seosan than in Seoul, attributing mostly to emissions from fossil fuel combustion and biomass burning. The ratio of Levoglucosan/Mannosan(Levo/Manno) and Levo/K+ plot showed that the type of biomass in the biomass burning at two areas might be different. In addition, the concentrations of 1,3,5-triphenylbenzne and tere-phthalic acid, which are indicators of plastic burning, in Seosan were 2~9 times higher than Seoul, respectively.Conclusion : It suggests that open burning of solid fuels such as biomass and plastic garbage was a key contributor to rising organic aerosol concentrations in Seosan.
目的:本研究分析了大型复杂排放源密集的瑞山地区PM2.5中的56种有机化合物,以表征该地区的有机化合物分布。方法:同时对首尔市的PM2.5进行采样,比较瑞山市PM2.5中有机化合物的浓度和分布。结果与讨论:瑞山市的有机化合物(OCs)总浓度为383±165 ng/m3,是首尔市(189±67 ng/m3)的两倍。西山的多环芳烃和左旋葡聚糖浓度高于首尔,这主要是由于化石燃料燃烧和生物质燃烧产生的排放。左旋葡聚糖/甘露聚糖比值(Levo/Manno)和Levo/K+图表明,两个地区燃烧的生物质类型可能不同。另外,作为塑料燃烧指标的1,3,5-三苯基苯和对邻苯二甲酸的浓度分别比汉城高出2~9倍。结论:露天燃烧生物质和塑料垃圾等固体燃料是导致瑞山地区有机气溶胶浓度上升的主要原因。
{"title":"Characteristics of Organic Compounds in PM2.5 at Seosan: Comparison of Organic Compounds in PM2.5 at Seoul","authors":"Y. Lee, Zihui Teng, Ki Ae Kim, Kwang-Yul Lee, S. Park, J. Lee","doi":"10.4491/ksee.2022.44.5.150","DOIUrl":"https://doi.org/10.4491/ksee.2022.44.5.150","url":null,"abstract":"Objectives : In this study, we analyzed 56 individual organic compounds in PM2.5 in Seosan, where the large complex emission sources are closely located, to characterize organic compounds distributions in this site.Methods : The sampling of PM2.5 in Seoul was also simultaneously carried out to compare the concentrations and distributions of organic compounds in PM2.5 measured in Seosan.Results and Discussion : The overall concentration of organic compounds (OCs) in Seosan was 383±165 ng/m3 , which was twice as high as the concentration in Seoul (189±67 ng/m3 ). PAHs and levoglucosan concentrations were higher in Seosan than in Seoul, attributing mostly to emissions from fossil fuel combustion and biomass burning. The ratio of Levoglucosan/Mannosan(Levo/Manno) and Levo/K+ plot showed that the type of biomass in the biomass burning at two areas might be different. In addition, the concentrations of 1,3,5-triphenylbenzne and tere-phthalic acid, which are indicators of plastic burning, in Seosan were 2~9 times higher than Seoul, respectively.Conclusion : It suggests that open burning of solid fuels such as biomass and plastic garbage was a key contributor to rising organic aerosol concentrations in Seosan.","PeriodicalId":52756,"journal":{"name":"daehanhwangyeonggonghaghoeji","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42136194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
期刊
daehanhwangyeonggonghaghoeji
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1