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Hazard Analysis of Trace Metals in Muscle of Sarotherodon Melanotheron and Chrysichthys Nigrodigitatus from Okulu River, Rivers State, Nigeria 尼日利亚里弗斯州奥库卢河黑脊龙和黑脊龙肌肉中微量金属的危害分析
Q4 Engineering Pub Date : 2021-09-10 DOI: 10.18502/jehsd.v6i3.7242
A. Aigberua, Sylvester Chibueze Izah, Glory Richard
Introduction: An instance of fish deaths in marine waters surrounding some communities in Bonny and Andoni Local Government Areas in Rivers State was reported in March-April 2020. This study investigated trace metals hazard in muscle of Tilapia (Sarotherodon melanotheron) and Silver Catfish (Chrysichthys nigrodigitatus) from Okulu River, Rivers State, Nigeria. Materials and Methods: Tissues of 24 samples of Sarotherodon melanotheron and Chrysichthys nigrodigitatus obtained from the river were analyzed using atomic adsorption spectrophotometer, and the health risk was estimated based on estimated daily intake (EDI), target hazard quotient (THQ), and total target hazard quotient (TTHQ). Results: The concentration (mg/kg) of iron, zinc, manganese, copper, cadmium, lead, and chromium in both species ranged 4.00 – 197.30, 9.20 – 35.30, 0.20 – 5.00, 0.00 – 73.10, 0.00 – 1.30, 0.00 – 54.70, and 0.00 – 0.50, respectively. The EDI of trace metals resulting from the consumption of both fish species was higher than the permissible tolerance intake (PTI) mg/day/60kg body weight. The THQ and TTHQ were < 1, indicating that the consumption of this food fish portends no known health concern. However, the carcinogenic risks exceeded the threshold level of 10-6 - 10-4, thus, reflecting carcinogenic tendency. Based on the results obtained, it must be ensured that the effluents discharged into open water bodies meet the recommended limits. Conclusion: There is a need to create awareness among consumers of food fish in the study area. There should be periodic monitoring of trace metals in surface waters and its food fish population to forestall potential health impact on humans.
简介:2020年3月至4月,据报道,里弗斯州邦尼和安多尼地方政府区一些社区周围海域发生鱼类死亡事件。本研究调查了尼日利亚里弗斯州奥库卢河罗非鱼(Sarotherodon melanotheron)和银鲶鱼(Chrysichthys nigrodigitatus)肌肉中微量金属的危害。材料与方法:采用原子吸收分光光度计对从河流中采集的24份黑脊龙和黑脊龙标本的组织进行分析,并根据估计日摄入量(EDI)、目标危险商(THQ)和总目标危险商数(TTHQ)估计健康风险。结果:两个物种的铁、锌、锰、铜、镉、铅和铬的浓度(mg/kg)分别为4.00–197.30、9.20–35.30、0.20–5.00、0.00–73.10、0.00–1.30、0.00–54.70和0.00–0.50。食用这两种鱼类产生的微量金属的EDI高于容许耐受摄入量(PTI)mg/天/60kg体重。THQ和TTHQ<1,表明食用这种食用鱼预示着没有已知的健康问题。然而,致癌风险超过了10-6-10-4的阈值水平,从而反映了致癌倾向。根据所获得的结果,必须确保排入开放水体的污水达到建议的限值。结论:有必要提高研究地区食用鱼消费者的意识。应定期监测地表水及其食用鱼种群中的微量金属,以防止对人类健康的潜在影响。
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引用次数: 4
Association between Exposure to Pesticides and Cognitive Function in Greenhouse Workers (Case Study: Ahmadabad Village of Yazd Province) 农药暴露与温室工人认知功能的关系(以亚兹德省艾哈迈达巴德村为例)
Q4 Engineering Pub Date : 2021-09-10 DOI: 10.18502/jehsd.v6i3.7246
Moslem Akhoundzardeini, M. Z. Sakhvidi, F. Teimouri, M. Mokhtari
Introduction: Exposure to pesticides in greenhouse workers is associated with several health outcomes, such as cognitive impairment. This study aimed to investigate the association between exposure to pesticides and cognitive function in Yazd city greenhouse workers and those living in the proximity of the greenhouses. Materials and Methods: In this study, three groups of participants were selected, including the greenhouse workers, the residents in the proximity of the greenhouses, and the control group. A semi-quantitative assessment of pesticide exposure was used to calculate the subjects’ cumulative pesticide exposure as a proxy for long-term exposure to pesticides. Blood level of acetylcholinesterase (AChE) activity was measured as a biomarker of effect. Frontal Assessment Battery (FAB), and Mini–mental State Examination (MMSE) were used to assess cognitive functions (including memory, executive functions, attention, visual, and verbal functions). Results: Mean cholinesterase activity in the greenhouse workers (average = 7009.3 U/L) was lower than the two other groups.  The results of the cognitive function score for both FAB and MMSE tests did not show a significant difference between the direct exposure and indirect exposure groups, although the cognitive function score in the pesticide applicators was lower than the two other study groups (e.g. for FAB score: 13.89, 14.55, and 15.4 for the greenhouse workers, the residents in the proximity of greenhouses, and the control group). The results also showed that in the direct exposure group, those with lower levels of cholinesterase activity also had a lower cognitive function. Conclusion: The findings indicated that there is a potential link between impaired cognitive function and exposure to pesticides in the greenhouse workers.
导言:温室工人接触农药与若干健康结果有关,如认知障碍。本研究旨在调查亚兹德市温室工人和居住在温室附近的人接触农药与认知功能之间的关系。材料与方法:本研究选取了三组参与者,分别是温室工人、温室附近居民和对照组。使用农药暴露的半定量评估来计算受试者的累积农药暴露量,作为长期农药暴露量的代表。测定血中乙酰胆碱酯酶(AChE)活性水平作为疗效的生物标志物。使用前额评估电池(FAB)和迷你精神状态检查(MMSE)评估认知功能(包括记忆、执行功能、注意力、视觉和语言功能)。结果:温室工人平均胆碱酯酶活性(平均值= 7009.3 U/L)低于其他两组。FAB和MMSE测试的认知功能得分结果在直接暴露组和间接暴露组之间没有显着差异,尽管农药施药者的认知功能得分低于其他两个研究组(例如,温室工人、温室附近居民和对照组的FAB得分分别为13.89、14.55和15.4)。结果还表明,在直接接触组中,胆碱酯酶活性水平较低的人认知功能也较低。结论:研究结果表明,温室工人的认知功能受损与农药暴露之间存在潜在的联系。
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引用次数: 2
Mg-Al–layered Double Hydroxide as Promising Sustainable Nanoadsorbent for Application in Water/Wastewater Treatment Processes; Diethyl Phthalate Removal Mg-Al层状双氢氧化物作为一种有前途的可持续纳米吸附剂在水/废水处理过程中的应用;邻苯二甲酸二乙酯的去除
Q4 Engineering Pub Date : 2021-09-10 DOI: 10.18502/jehsd.v6i3.7244
M. Dolatabadi, A. Ghorbanian, Saeid Ahmadzadeh
Introduction: Since phthalate esters and their derivatives have the potential to disrupt proper endocrine function, these compounds are considered as one of the most important groups of endocrine-disrupting chemicals. The presence of these compounds in various aquatic environments has caused main concerns about human and animal health and causes problems in the environment. Materials and Methods: The treatment process was carried out in a glass reactor containing 200 mL polluted water at room temperature. The Mg-Al layered double hydroxides (Mg-Al-LDH) were successfully synthesized and were applied as adsorbents for the removal of Diethyl Phthalate (DEP) from polluted water. The kinetics and isotherm of the process were investigated to determine the exact mechanism of DEP removal from the water medium. Results: The Mg-Al-LDH was a surface area of 673 (m2 g-1), a total pore of 0.716 (cm3 g-1), and microspore volumes of 0.627 (cm3 g-1), and a pore diameter of 8.64 nm. The maximum DEP removal efficiency of 96.7% was obtained at the DEP concentration of 10 mg L-1, Mg-Al-LDH dosage of 0.50 g L-1, and the reaction time of 30 min. The second-order kinetic model well depicted the kinetics of DEP adsorption (R2 = 0. 99). The Langmuir isotherm model best described the data by predicting the maximum adsorption capacity (qm) of 95.6 mg g-1 and R2 of 0.99. Conclusion: All the results demonstrate that the Mg-Al-LDH is an efficient, safe, and efficient adsorbent in water and wastewater treatment.
引言:由于邻苯二甲酸酯及其衍生物有可能破坏正常的内分泌功能,这些化合物被认为是最重要的内分泌干扰化学物质之一。这些化合物在各种水生环境中的存在引起了人们对人类和动物健康的主要关注,并导致环境问题。材料和方法:处理过程在含有200mL污染水的玻璃反应器中在室温下进行。成功合成了Mg-Al层状双氢氧化物(Mg-Al-LDH),并将其用作去除污染水中邻苯二甲酸二乙酯(DEP)的吸附剂。研究了该过程的动力学和等温线,以确定从水介质中去除DEP的确切机理。结果:Mg-Al LDH的表面积为673(m2g-1),总孔为0.716(cm3g-1),小孢子体积为0.627(cm3g-1),孔径为8.64nm。当DEP浓度为10mg L-1,mg-Al-LDH用量为0.50g L-1,反应时间为30min时,DEP的最大去除率为96.7%。99)。Langmuir等温线模型通过预测95.6 mg g-1的最大吸附容量(qm)和0.99的R2来最好地描述数据。结论:Mg-Al-LDH是一种高效、安全、高效的水、废水吸附剂。
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引用次数: 2
Zataria Multiflora Essential Oil Loaded with Starch Nanoparticles to Protect Strawberries against Botrytis Cinerea Zataria Multiflora精油负载淀粉纳米粒子保护草莓免受番茄红霉菌感染
Q4 Engineering Pub Date : 2021-09-10 DOI: 10.18502/jehsd.v6i3.7245
Maryam Mobininejad, E. K. Sadrabad, S. Hekmatimoghaddam, A. Jebali, A. Fallah, F. Mohajeri
Introduction: The post-harvest damage to fruits is estimated to be about 10-30% of the total products, which reaches up to 30-50% in some perishable fruits. About 25 species of fungi and bacteria including Botrytis spp. and in particular Botrytis cinerea are known to contaminate fruits, vegetables and ornamental greenhouse plants. The aim of this study was to investigate the antifungal activity of different concentrations of Zataria multiflora essential oil (ZEO) against B. cinerea. Materials and Methods: The ZEO was extracted through steam distillation and analyzed by gas chromatography-mass spectrometry. The strawberries packages were exposed to ZEO with different concentrations (0, 200, 400, 600, and 800 ppm) and satarch nanoparticles. The exposed fruits were kept for 24 days at two temperatures of 20°C and 4°C. Results: The ZEO decreased mycelium growth even when only 200 ppm of it was added to each container. The response was dose-dependent, so that the 800 ppm dose of ZEO showed complete inhibitory effect. The minimum inhibitory concentration (MIC) and minimum fungicidal concentration (MFC) values for ZEO against B. cinerea were 200 µg/mL and 500 µg/mL, respectively. Additionally, ZEO preserved the sensory characteristics. Conclusion: The ZEO may be effectively used in packaging of strawberry to increase its shelf life by inhibition of B. cinerea.
摘后对水果的损害估计约占产品总量的10-30%,某些易腐水果可达30-50%。大约有25种真菌和细菌,包括葡萄孢杆菌,特别是葡萄孢杆菌,已知会污染水果、蔬菜和观赏温室植物。研究了不同浓度的扎扎草精油(ZEO)对灰霉病菌的抑菌活性。材料与方法:采用水蒸气蒸馏法提取ZEO,气相色谱-质谱联用分析。草莓包装暴露于不同浓度的ZEO(0、200、400、600和800 ppm)和satarch纳米颗粒。暴露后的果实在20℃和4℃两种温度下保存24 d。结果:即使在每个容器中只添加200 ppm的ZEO,也会降低菌丝的生长。反应呈剂量依赖性,800 ppm的ZEO表现出完全抑制作用。ZEO对灰绿杆菌的最小抑菌浓度(MIC)为200µg/mL,最小杀真菌浓度(MFC)为500µg/mL。此外,ZEO保留了感官特征。结论:ZEO可有效地应用于草莓包装中,通过抑菌来延长草莓的保质期。
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引用次数: 0
Epidemiological Pattern of Poisoning in Children under the Age of 15 Admitted to the Referral Teaching Hospitals of Yazd and Taft Cities (2014-2019) 亚兹德市和塔夫脱市转诊教学医院收治15岁以下儿童中毒流行病学分析(2014-2019年)
Q4 Engineering Pub Date : 2021-09-10 DOI: 10.18502/jehsd.v6i3.7243
M. Momayyezi, Parisa Peigan, H. Fallahzadeh
Introduction: Understanding the epidemiological pattern and causes of poisoning is the first step to prevent and reduce complications and mortality due to poisoning in children. Given that no study has been conducted on this subject in Yazd, this study aimed to determine the epidemiology pattern of poisoning in children admitted to the referral teaching hospitals in Yazd and Taft cities during 2014-2019. Materials and Methods: This descriptive cross-sectional study was conducted on 238 children under the age of 15 who have been admitted to Shahid Sadoughi hospital in Yazd and Shahid Beheshti hospital in Taft city during 2014-2019. The data were analyzed by SPSS version 20.0 using descriptive statistics, Pearson correlation, and Chi-square. In all the statistical analyses, a P-value of less than 0.05 was considered significant. Results: The results showed that the frequency of poisonings was higher in girls (58%), in summer (31.1%), and in urban areas (82.8%). Most cases of poisoning aged less than 15 years (75.1%). The main cause of poisoning in children was drug poisoning (60.5%), followed by cleansing products (10.1%). The most common clinical manifestations included neurological signs (33.6%). During 2014-2019, the frequency of drugs and pesticide poisonings decreased; while poisoning due to drug-opioids and cleansing products increased (P = 0.04). Also, 3 deaths occurred due to poisoning during this period. Conclusion: The higher prevalence of drug and cleansing products poisoning in children under the age of 15 indicates involuntary poisoning in this group. Therefore, proper storage of these substances and more parental care can reduce poisonings in children.
前言:了解中毒的流行病学模式和原因是预防和减少儿童中毒并发症和死亡率的第一步。鉴于亚兹德尚未开展这方面的研究,本研究旨在确定2014-2019年亚兹德和塔夫脱市转诊教学医院收治儿童中毒的流行病学模式。材料与方法:本描述性横断面研究对2014-2019年期间在亚兹德Shahid Sadoughi医院和塔夫特市Shahid Beheshti医院住院的238名15岁以下儿童进行了研究。数据分析采用SPSS 20.0版本,采用描述性统计、Pearson相关和卡方分析。在所有的统计分析中,p值小于0.05被认为是显著的。结果:中毒发生率以女童(58%)、夏季(31.1%)和城区(82.8%)较高。15岁以下中毒最多(75.1%)。儿童中毒的主要原因是药物中毒(60.5%),其次是清洁用品中毒(10.1%)。最常见的临床表现为神经系统症状(33.6%)。2014-2019年期间,药物和农药中毒发生率下降;阿片类药物和清洁用品引起的中毒增加(P = 0.04)。此外,在此期间有3人因中毒死亡。结论:15岁以下儿童药物和清洁用品中毒发生率较高,表明该群体存在非自愿中毒。因此,适当储存这些物质和父母更多的照顾可以减少儿童中毒。
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引用次数: 0
In Vitro Activity of Disinfectants against Mold Fungi Isolated from Different Environments of the Children’s Medical Center Hospital, Tehran, Iran 伊朗德黑兰儿童医疗中心医院不同环境中分离的霉菌消毒剂的体外活性
Q4 Engineering Pub Date : 2021-06-10 DOI: 10.18502/jehsd.v6i2.6537
Sedighe Karimpour Roshan, H. Godini, S. Ansari, Arezoo Charsizadeh, M. Norouzi
Introduction: Fungal aerosols cause life-threatening infections in patients hospitalized in critical wards. Antiseptics and disinfectants have broad-spectrum antimicrobial activity against the living tissue and inert surfaces microorganisms; hence, they have an essential role in controlling and preventing nosocomial infections. This study aimed to evaluate in vitro antifungal activity of benzalkonium chloride (BAC), chlorhexidine digluconate (CHX), and sodium hypochlorite (SH) against isolated fungal aerosols from the hospital environment. Materials and Methods: The susceptibility tests were performed on fungal aerosols isolated from various wards of Children’s Medical Center, based on broth microdilution antifungal susceptibility testing of filamentous fungi approved by the Clinical and Laboratory Standards Institute (CLSI) M38-A2 document. The isolates included Aspergillus (Aspergillus flavus (n = 14), Aspergillus niger complex (n = 12), Penicillium spp. (n = 14), and Cladosporium spp. (n = 14). Results: The geometric means (GM) of the Minimum Inhibitory Concentrations (MICs) of the biocides across all isolates were as follows: BAC, 3.56 µg/ml, CHX, 9.45 µg/ml, and SH, 810.35 µg/ml. The highest range of MICs was found for SH (50-12800 µg/ml), while the lowest range was for BAC (1-16 µg/ml) against all fungal isolates. Generally, BAC showed the highest in vitro activity among disinfectants tested. The lowest MIC50 and MIC90 values were 4 and 8 µg/ml for BAC, followed by 16 and 32 µg/ml for CHX, and 800 and 6400 µg/ml for SH, respectively. Conclusion: The findings showed that BAC was an effective disinfectant, which can  prevent resistant species and fungal pathogens and be used an alternative to other disinfectants and antiseptics.
真菌气溶胶在危重病房住院的患者中引起危及生命的感染。防腐剂和消毒剂对活组织和惰性表面微生物具有广谱抗菌活性;因此,它们在控制和预防医院感染方面具有重要作用。本研究旨在评价苯扎氯铵(BAC)、二光酸氯己定(CHX)和次氯酸钠(SH)对医院环境中分离的真菌气溶胶的体外抗真菌活性。材料与方法:采用临床与实验室标准协会(CLSI) M38-A2文件批准的丝状真菌微汤稀释抗真菌药敏试验,对儿童医疗中心各病房分离的真菌气雾剂进行药敏试验。分离株包括黄曲霉(Aspergillus flavus) 14株、黑曲霉复合体(Aspergillus niger complex) 12株、青霉(Penicillium spp) 14株、枝孢霉(Cladosporium spp) 14株。结果:各菌株的最小抑菌浓度几何平均值(GM)分别为:BAC为3.56µg/ml, CHX为9.45µg/ml, SH为810.35µg/ml。所有真菌分离株的mic最高范围为SH(50 ~ 12800µg/ml),最低范围为BAC(1 ~ 16µg/ml)。总体而言,BAC在所有消毒剂中显示出最高的体外活性。BAC的MIC50和MIC90值最低,分别为4和8µg/ml, CHX最低,分别为16和32µg/ml, SH最低,分别为800和6400µg/ml。结论:BAC是一种有效的消毒剂,对耐药菌种和真菌病原菌有一定的预防作用,可作为其他消毒剂和防腐剂的替代品。
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引用次数: 1
Assessment of Emergency Response Preparedness in Power Plant Using FEMA Method (Case Study: South Isfahan Power Plant) 基于FEMA方法的电厂应急准备评估(以南伊斯法罕电厂为例)
Q4 Engineering Pub Date : 2021-06-10 DOI: 10.18502/jehsd.v6i2.6540
Alireza Kazemian Talkhooncheh, Afarin Akhavan, G. Halvani
Introduction: The aim of this study was to identify all activities to be sufficiently prepared for emergencies in the power plant industries using the method of the Federal Crisis Management Organization in the south Isfahan power plant. Materials and Methods: In this research, a checklist tool of 117 questions in 9 sections based on the FEMA method has been used. Checklists were localized. To check the face and content validity of the checklists, the opinions of three technical experts were used, and to check the reliability of the research subjects, the test-retest test was used, and to measure the reliability of the checklists, Cronbach's alpha coefficient was used with an emphasis on internal correlation. The obtained alpha coefficient was 0.76. Data were analyzed using SPSS software. Results: The results showed that the power plant preparedness for general emergencies is 77.5%, winter storms and extreme cold 80%, storm 73.33%, overheating 70%, chemical storage 88.57%, earthquake 65%, Fire and explosion is 87%, flood 63.33%, and lightning 92%. The highest level of preparedness with 92% was related to the lightning checklist and the lowest level of readiness with 63.33% was related to floods. Conclusion: In general, despite the differences in the readiness of the power plant against various accidents, the average level of preparedness for all accidents is higher than average. However, a number of appropriate measures must be taken in each area and the level of preparedness must be increased in cases such as fires and explosions.
引言:本研究的目的是利用联邦危机管理组织在伊斯法罕南部发电厂的方法,确定发电厂行业中为紧急情况做好充分准备的所有活动。材料和方法:在本研究中,使用了一个基于FEMA方法的9节117个问题的检查表工具。检查表已本地化。为了检查检查表的表面和内容的有效性,使用了三位技术专家的意见,为了检查研究对象的可靠性,使用了重测测试,并使用了Cronbachα系数来衡量检查表的可靠性,强调了内部相关性。所获得的α系数为0.76。使用SPSS软件对数据进行分析。结果:电厂对一般突发事件的准备率为77.5%,冬季风暴和极寒的准备率80%,风暴73.33%,过热70%,化学品储存88.57%,地震65%,火灾爆炸87%,洪水63.33%,雷电92%。最高级别的准备程度(92%)与雷电检查表有关,最低级别的准备水平(63.33%)与洪水有关。结论:总的来说,尽管发电厂对各种事故的准备程度存在差异,但对所有事故的平均准备水平都高于平均水平。然而,必须在每个地区采取一些适当措施,并在火灾和爆炸等情况下提高准备水平。
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引用次数: 0
Investigation of Electrocoagulation Process for Efficient Removal of Bisphenol A from the Aqueous Environment: Promising Treatment Strategy 电絮凝法高效去除水环境中双酚A的研究:有前途的处理策略
Q4 Engineering Pub Date : 2021-06-10 DOI: 10.18502/jehsd.v6i2.6539
M. Dolatabadi, Roya Malekahmadi, A. Ghorbanian, Saeid Ahmadzadeh
Introduction: Endocrine disruptive compounds as a class of organic contaminants in the aquatic environment received severe attention in the last decades. The release of bisphenol A (BPA) as a hazardous organic chemical into the environment has caused high health and environmental concerns. Therefore, its removal from aquatic environments is strongly recommended. The present study deals with BPA removal efficiency from an aqueous environment using the electrocoagulation process (ECP). Materials and Methods: The effects of parameters including BPA concentration (1-10 mg L-1), current density (3-15 mA cm-2), pH (4-10), and reaction time (5-30 min) on the treatment process were investigated. Response surface methodology (RSM) was employed for optimization of the ECP. The significance of the developed model was investigated by the obtained F-value and P-value. Results: The maximum BPA removal of 98.2% was attained at pH of 8.5, BPA concentration of 3.25 mg L-1, the current density of 12.0 mA cm-2, and reaction time of 23 min. The significance of the developed model was confirmed by the high F-value of 46.69 and the very low P-value of < 0.0001. Furthermore, the electrical energy consumption of the process was found to be 0.308 kWh m-3 in the optimum condition. Conclusion: The obtained experimental results revealed that the co-precipitation and the adsorption process through the electrostatic interactions as the main removal mechanisms controlled the treatment process.
引言:内分泌破坏性化合物作为水生环境中的一类有机污染物,在过去几十年中受到了广泛关注。双酚A(BPA)作为一种危险的有机化学品释放到环境中引起了人们对健康和环境的高度关注。因此,强烈建议将其从水生环境中清除。本研究涉及使用电凝聚工艺(ECP)从水性环境中去除BPA的效率。材料和方法:研究了BPA浓度(1-10mg L-1)、电流密度(3-15mA cm-2)、pH(4-10)和反应时间(5-30min)等参数对处理过程的影响。采用响应面法对ECP进行了优化。通过所获得的F值和P值来研究所开发的模型的意义。结果:当pH为8.5,BPA浓度为3.25mg L-1,电流密度为12.0mA cm-2,反应时间为23min时,BPA的最大去除率为98.2%。46.69的高F值和<0.0001的极低P值证实了该模型的重要性。此外,在最佳条件下,该工艺的电能消耗为0.308kWhm-3。结论:实验结果表明,共沉淀和静电相互作用吸附过程是控制处理过程的主要去除机制。
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引用次数: 4
Carcinogenic and Non-Carcinogenic Risk Assessment of Heavy Metals in Water Resources of North East of Iran in 2018 2018年伊朗东北部水资源中重金属致癌和非致癌风险评估
Q4 Engineering Pub Date : 2021-06-10 DOI: 10.18502/jehsd.v6i2.6543
M. Sadeghi, M. Noroozi
Introduction: Contamination of water with heavy metals has turned into a health concern, particularly in the developing countries. In this study, concentration of heavy metals and associated carcinogenic and non- carcinogenic risk was investigated in water samples collected from Gonbad-e Kavus, a high-risk area for cancer. Materials and Methods: Samples were collected from Gorgan River, Golestan reservoir and wells around villages with high prevalence in 2018. Samples were analysed through inductively coupled plasma mass spectrometry. After determining the concentration of heavy metals in water samples from different sources, health risk assessment was carried out according to the Environmental Protection Agency.  Results: Arsenic in samples 6-9 was higher than 10 µg/L, calcium and magnesium in sample 5 was higher than 200 mg/L and 150 mg/L respectively, and sodium in all samples was higher than 50 mg/L.  According to the findings, these concentrations were higher than the maximum allowed limit in most water samples. Hazard quotient (HQ) in samples 8 and 9 were associated with arsenic and health risk in sample 1 was related to antimony. Furthermore, since all samples contained high amounts of lithium, water from this area better should not be consumed by children older than one year. Conclusion: Given the high rate of arsenic contamination, consumption of water in the study area could be health threatening for all individuals and is not recommended for children. This highlights the need for taking immediate actions to review the water treatment process and ensure safety of the drinking water in this area.
引言:重金属对水的污染已成为一个健康问题,特别是在发展中国家。在本研究中,对癌症高风险地区Gonbad-e Kavus采集的水样中重金属浓度及其相关的致癌和非致癌风险进行了调查。材料和方法:从2018年高发病率的Gorgan河、Golestan水库和村庄周围的水井中采集样本。样品通过电感耦合等离子体质谱法进行分析。在确定了不同来源的水样中重金属的浓度后,根据环境保护局的规定进行了健康风险评估。结果:样品6-9中砷含量高于10µg/L,样品5中钙和镁含量分别高于200 mg/L和150 mg/L,所有样品中钠含量均高于50 mg/L。根据研究结果,这些浓度高于大多数水样的最大允许限值。样品8和9中的危险商(HQ)与砷有关,样品1中的健康风险与锑有关。此外,由于所有样本都含有大量锂,因此一岁以上的儿童不应饮用该地区的水。结论:鉴于砷污染率很高,研究区域的用水可能会威胁所有人的健康,不建议儿童饮用。这突出表明需要立即采取行动审查水处理过程,并确保该地区饮用水的安全。
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引用次数: 3
Functionalization of Synthesized Nanoporous Silica and Its Application in Malachite Green Removal from Contaminated Water 纳米多孔二氧化硅的功能化及其在污染水中孔雀绿去除中的应用
Q4 Engineering Pub Date : 2021-06-10 DOI: 10.18502/jehsd.v6i2.6542
Bahman Hasan-Zadeh, R. Rahmanian, M. Salmani, M. Salmani
Introduction: Nanoporous silica has received growing interest for its unique application potential in pollutant removal. Therefore, the development of a simple technique is required to synthesize and functionalize the nanoporous materials for industrial application. Materials and Methods: The synthesis of nanoporous silica was investigated by the template sol-gel method, and it functionalized as an adsorbent for adsorption of malachite green. The morphology and structure of the prepared and functionalized nanoporous silica were studied using X-ray diffraction, Fourier transform infrared spectroscopy (FT-IR), and nitrogen adsorption-desorption technique. Subsequently, the effective parameters such as solution pH, contact time, and initial concentration on the adsorption process were optimized by adsorption tests. Results: The results showed that high-order nanoporous silica had been produced with an average diameter of 20.12 nm and average pore volume of 1.04 cm3.g−1. It was found that the optimum parameters of pH, initial concentration and contact time for malachite green adsorption on nanoporous silica were 6.5, 10 mg.l-1, and 60 min, respectively. The experimental data confirmed the Freundlich model (R2 = 0.995) and the obtained kinetic data followed the pseudo-first-order equation. The maximum adsorption capacity calculated by Langmuir isotherm was found to be 116.3 mg.g-1. Conclusion: The high adsorption capacity showed that the acid-functionalized nanoporous silica adsorbent can be used as an adequate adsorbent to remove malachite green from aquatic environments. The large surface area can be suggested that the silica nanoporous will have potential application prospects as the adsorbent.
引言:纳米多孔二氧化硅因其在污染物去除方面的独特应用潜力而受到越来越多的关注。因此,需要开发一种简单的技术来合成和功能化纳米多孔材料,用于工业应用。材料与方法:采用模板溶胶-凝胶法合成纳米多孔二氧化硅,并将其功能化为吸附孔雀石绿的吸附剂。利用X射线衍射、傅立叶变换红外光谱(FT-IR)和氮吸附-解吸技术研究了制备和功能化的纳米多孔二氧化硅的形貌和结构。随后,通过吸附试验优化了溶液pH、接触时间和初始浓度等对吸附过程的有效参数。结果:制备了平均孔径为20.12nm、平均孔体积为1.04cm3/g−1的高阶纳米多孔二氧化硅。研究发现,纳米多孔二氧化硅吸附孔雀石绿的最佳pH值、初始浓度和接触时间分别为6.5、10mg.l-1和60min。实验数据证实了Freundlich模型(R2=0.995),所获得的动力学数据遵循伪一阶方程。通过Langmuir等温线计算的最大吸附容量为116.3mg.g-1。结论:酸性功能化纳米多孔二氧化硅吸附剂具有较高的吸附性能,可作为去除水体中孔雀石绿的有效吸附剂。大的表面积表明二氧化硅纳米多孔吸附剂具有潜在的应用前景。
{"title":"Functionalization of Synthesized Nanoporous Silica and Its Application in Malachite Green Removal from Contaminated Water","authors":"Bahman Hasan-Zadeh, R. Rahmanian, M. Salmani, M. Salmani","doi":"10.18502/jehsd.v6i2.6542","DOIUrl":"https://doi.org/10.18502/jehsd.v6i2.6542","url":null,"abstract":"Introduction: Nanoporous silica has received growing interest for its unique application potential in pollutant removal. Therefore, the development of a simple technique is required to synthesize and functionalize the nanoporous materials for industrial application. \u0000Materials and Methods: The synthesis of nanoporous silica was investigated by the template sol-gel method, and it functionalized as an adsorbent for adsorption of malachite green. The morphology and structure of the prepared and functionalized nanoporous silica were studied using X-ray diffraction, Fourier transform infrared spectroscopy (FT-IR), and nitrogen adsorption-desorption technique. Subsequently, the effective parameters such as solution pH, contact time, and initial concentration on the adsorption process were optimized by adsorption tests. \u0000Results: The results showed that high-order nanoporous silica had been produced with an average diameter of 20.12 nm and average pore volume of 1.04 cm3.g−1. It was found that the optimum parameters of pH, initial concentration and contact time for malachite green adsorption on nanoporous silica were 6.5, 10 mg.l-1, and 60 min, respectively. The experimental data confirmed the Freundlich model (R2 = 0.995) and the obtained kinetic data followed the pseudo-first-order equation. The maximum adsorption capacity calculated by Langmuir isotherm was found to be 116.3 mg.g-1. \u0000Conclusion: The high adsorption capacity showed that the acid-functionalized nanoporous silica adsorbent can be used as an adequate adsorbent to remove malachite green from aquatic environments. The large surface area can be suggested that the silica nanoporous will have potential application prospects as the adsorbent.","PeriodicalId":53380,"journal":{"name":"Journal of Environmental Health and Sustainable Development","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47816016","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
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Journal of Environmental Health and Sustainable Development
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