Pub Date : 2024-06-21DOI: 10.1007/s40789-024-00703-y
Wei Zhao, Huzi Dong, Junchen Ren, Yuan Yuan, Kai Wang, Fei Wang
The ability to predict gas emissions accurately is pivotal in managing gas control and ensuring safe mining operations. Existing internationally acknowledged gas control and prediction software does not cater to the specific conditions in Chinese coal mines. Hence, this paper introduces an object-oriented programming method to design a software tool for calculating the total gas emission quantity using the MATLAB application program designer runtime environment. The software incorporates an algorithm, data structure, framework, and module functions, all of which enable seamless integration and visualization of gas emission calculation software. This software tool mitigates the inefficiencies and inaccuracies associated with manual, different-source forecast methods. Based on the field data of the Hulonggou Coal Mine in Shanxi province, this technical software was used to predict the gas emission of the mine. The research results show that the predicted value of the technical software is close to the actual measured value. The differing estimates of the working face and coal mine output primarily account for the deviation between the tool's predicted gas emission value and the field-measured value. The underlying design logic of this technical software determines that it has good adaptability to mines with clear mining technology parameters and gas geological parameters. This study provides a valuable method for researchers and engineers seeking to improve gas emission calculation efficiency.
{"title":"A software for calculating coal mine gas emission quantity based on the different-source forecast method","authors":"Wei Zhao, Huzi Dong, Junchen Ren, Yuan Yuan, Kai Wang, Fei Wang","doi":"10.1007/s40789-024-00703-y","DOIUrl":"https://doi.org/10.1007/s40789-024-00703-y","url":null,"abstract":"<p>The ability to predict gas emissions accurately is pivotal in managing gas control and ensuring safe mining operations. Existing internationally acknowledged gas control and prediction software does not cater to the specific conditions in Chinese coal mines. Hence, this paper introduces an object-oriented programming method to design a software tool for calculating the total gas emission quantity using the MATLAB application program designer runtime environment. The software incorporates an algorithm, data structure, framework, and module functions, all of which enable seamless integration and visualization of gas emission calculation software. This software tool mitigates the inefficiencies and inaccuracies associated with manual, different-source forecast methods. Based on the field data of the Hulonggou Coal Mine in Shanxi province, this technical software was used to predict the gas emission of the mine. The research results show that the predicted value of the technical software is close to the actual measured value. The differing estimates of the working face and coal mine output primarily account for the deviation between the tool's predicted gas emission value and the field-measured value. The underlying design logic of this technical software determines that it has good adaptability to mines with clear mining technology parameters and gas geological parameters. This study provides a valuable method for researchers and engineers seeking to improve gas emission calculation efficiency.</p>","PeriodicalId":53469,"journal":{"name":"International Journal of Coal Science & Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141529144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-20DOI: 10.1007/s40789-024-00701-0
Shouqing Lu, Jiang Shi, Lei Jiao, Yankun Ma, Wei Li, Zhanyou Sa, Jie Liu, Taibiao Bei, Shengcheng Wang
Coal bed methane (CBM), the high-quality and efficient fuel, has caught the interest of many nations as they strive for environmentally friendly development. Therefore, the efficient exploitation and utilization of CBM has become one of the international focal research problems. A significant factor affecting the mining of CBM is coal permeability. To better capture the changes that occur during the extraction of CBM, the internal swelling coefficient of matrix (ISCM) has been gradually in permeability introduced into the permeability models, and such models have become an important type of the development of permeability models. The goal is to find out more precisely the evolution mechanism of the ISCM and its influence on the permeability models. In this paper, the selection of coal structure, determination of boundary conditions and influencing factors of permeability for were first analyzed. Then, according to the research process of ISCM, the permeability models including the ISCM were reviewed and divided into four phases: proposal phase, development phase, evaluation phase and display of internal structure phase. On the basis of the ISCM values in the current coal permeability models, the primary influencing factors and evolutionary laws of the ISCM are explored. The results obtained provide guidance for future theoretical refinement of permeability models with the ISCM.
{"title":"A review of coal permeability models including the internal swelling coefficient of matrix","authors":"Shouqing Lu, Jiang Shi, Lei Jiao, Yankun Ma, Wei Li, Zhanyou Sa, Jie Liu, Taibiao Bei, Shengcheng Wang","doi":"10.1007/s40789-024-00701-0","DOIUrl":"https://doi.org/10.1007/s40789-024-00701-0","url":null,"abstract":"<p>Coal bed methane (CBM), the high-quality and efficient fuel, has caught the interest of many nations as they strive for environmentally friendly development. Therefore, the efficient exploitation and utilization of CBM has become one of the international focal research problems. A significant factor affecting the mining of CBM is coal permeability. To better capture the changes that occur during the extraction of CBM, the internal swelling coefficient of matrix (ISCM) has been gradually in permeability introduced into the permeability models, and such models have become an important type of the development of permeability models. The goal is to find out more precisely the evolution mechanism of the ISCM and its influence on the permeability models. In this paper, the selection of coal structure, determination of boundary conditions and influencing factors of permeability for were first analyzed. Then, according to the research process of ISCM, the permeability models including the ISCM were reviewed and divided into four phases: proposal phase, development phase, evaluation phase and display of internal structure phase. On the basis of the ISCM values in the current coal permeability models, the primary influencing factors and evolutionary laws of the ISCM are explored. The results obtained provide guidance for future theoretical refinement of permeability models with the ISCM.</p>","PeriodicalId":53469,"journal":{"name":"International Journal of Coal Science & Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141505084","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Special attention was drawn to the heavy metals contained in coal, due to it will cause harm to the environment during coal processing and utilization. The sequential chemical extraction of Shanxi coal (SX coal) and Wulanchabu coal (WLCB coal) was carried out to investigate the distribution of arsenic (As) in coals. Two raw coals were pyrolyzed at 300–900 °C in horizontal tubular furnace to investigate release behavior of As during pyrolysis process. The results showed that As in SX coal mainly existed in aluminosilicate-bound state (40.25%) and disulfide-bound state (32.51%), followed by carbonate-bound state and organic-bound state. The As in WLCB coal mainly existed in aluminosilicate-bound state (62.50%), followed by disulfide-bound state (19.10%). The As contents of water-soluble, ion-exchange and residue states in the two coals were less than others. The modes of occurrence of As had great influence on its volatilization behavior. As in organic part was easy to volatilize at low temperature. Sulfide-bound state would escape with the decomposition of pyrite. Because SX coal contained higher organic state and sulfide-bound state, the volatilization rate of As was higher than WLCB coal at any temperature, and the difference was more obvious at low temperature. In addition, FactSage simulation value was basically consistent with the experimental value.
由于煤炭在加工和利用过程中会对环境造成危害,因此煤炭中含有的重金属引起了人们的特别关注。研究人员对山西煤(SX 煤)和乌兰察布煤(WLCB 煤)进行了连续化学萃取,以调查煤中砷(As)的分布情况。在水平管式炉中,两种原煤在 300-900 °C 的温度下进行热解,以研究热解过程中砷的释放行为。结果表明,SX 煤中的砷主要以铝硅酸盐结合态(40.25%)和二硫化物结合态(32.51%)存在,其次是碳酸盐结合态和有机结合态。WLCB煤中的As主要以铝硅酸盐结合态存在(62.50%),其次是二硫化物结合态(19.10%)。两种煤中水溶态、离子交换态和残留态的 As 含量均较低。砷的存在方式对其挥发行为有很大影响。有机态的 As 在低温下容易挥发。硫化物结合态会随着黄铁矿的分解而逸出。由于 SX 煤含有较高的有机态和硫化物结合态,因此在任何温度下,As 的挥发率都高于 WLCB 煤,在低温下差异更为明显。此外,FactSage 模拟值与实验值基本一致。
{"title":"The release and migration mechanism of arsenic during pyrolysis process of Chinese coals","authors":"Meijie Sun, Lingmei Zhou, Jiali Zhong, Yingjie Zhao, Hao Zheng, Beibei Qu, Maolin Ma","doi":"10.1007/s40789-024-00715-8","DOIUrl":"https://doi.org/10.1007/s40789-024-00715-8","url":null,"abstract":"<p>Special attention was drawn to the heavy metals contained in coal, due to it will cause harm to the environment during coal processing and utilization. The sequential chemical extraction of Shanxi coal (SX coal) and Wulanchabu coal (WLCB coal) was carried out to investigate the distribution of arsenic (As) in coals. Two raw coals were pyrolyzed at 300–900 °C in horizontal tubular furnace to investigate release behavior of As during pyrolysis process. The results showed that As in SX coal mainly existed in aluminosilicate-bound state (40.25%) and disulfide-bound state (32.51%), followed by carbonate-bound state and organic-bound state. The As in WLCB coal mainly existed in aluminosilicate-bound state (62.50%), followed by disulfide-bound state (19.10%). The As contents of water-soluble, ion-exchange and residue states in the two coals were less than others. The modes of occurrence of As had great influence on its volatilization behavior. As in organic part was easy to volatilize at low temperature. Sulfide-bound state would escape with the decomposition of pyrite. Because SX coal contained higher organic state and sulfide-bound state, the volatilization rate of As was higher than WLCB coal at any temperature, and the difference was more obvious at low temperature. In addition, FactSage simulation value was basically consistent with the experimental value.</p>","PeriodicalId":53469,"journal":{"name":"International Journal of Coal Science & Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141505085","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-04DOI: 10.1007/s40789-024-00690-0
Lanre Asiwaju, Khairul Azlan Mustapha, Wan Hasiah Abdullah, Say Gee Sia, Mohammed Hail Hakimi
Forty Tertiary coals from Mukah-Balingian and Merit-Pila coalfields of the Sarawak Basin, Malaysia were investigated using bulk and molecular geochemical techniques such as proximate analysis, gas chromatography-mass spectrometry, elemental analyser, isotope ratio mass spectrometry, and inductively coupled plasma mass spectrometry to reconstruct their paleovegetation, paleoclimate, and environments of deposition. In addition, principal component analysis (PCA) of selected geochemical parameters was carried out to determine the controlling influences on the petroleum potential of the humic coals. δ13C values and the abundance of terpenoids imply the predominant contribution of angiosperms to the paleoflora. Bimetal proxies (Sr/Ba, Sr/Cu, and C-value), and δD values are generally suggestive of a warm and humid climate during the accumulation of the paleopeats. However, n-alkane proxies (Pwax, Paq, n-C23/n-C29, etc.) and polycyclic aromatic hydrocarbons (PAHs) distribution suggest that Balingian coals accumulated under relatively drier and strongly seasonal paleoclimate in the Late Pliocene. When compared with published global average abundances, the investigated coals are mostly depleted in major oxides and trace elements, suggesting peat accumulation in freshwater-influenced environments. Nonetheless, higher (> 0.5 wt%) total sulfur content in some Mukah-Balingian coals suggests some degree of epigenetic marine influence. Furthermore, the low to moderately-high ash contents of the Sarawak Basin coals indicate the presence of ombrotrophic and rheotrophic peat deposits. PCA result of selected geochemical proxies suggests that source input, paleoflora, and marine incursions are not major controlling influences on the petroleum potential. However, climatic, and depositional conditions appear to slightly influence the petroleum potential of the studied humic coals.
{"title":"Geochemistry of Cenozoic coals from Sarawak Basin, Malaysia: implications for paleoclimate, depositional conditions, and controls on petroleum potential","authors":"Lanre Asiwaju, Khairul Azlan Mustapha, Wan Hasiah Abdullah, Say Gee Sia, Mohammed Hail Hakimi","doi":"10.1007/s40789-024-00690-0","DOIUrl":"https://doi.org/10.1007/s40789-024-00690-0","url":null,"abstract":"<p>Forty Tertiary coals from Mukah-Balingian and Merit-Pila coalfields of the Sarawak Basin, Malaysia were investigated using bulk and molecular geochemical techniques such as proximate analysis, gas chromatography-mass spectrometry, elemental analyser, isotope ratio mass spectrometry, and inductively coupled plasma mass spectrometry to reconstruct their paleovegetation, paleoclimate, and environments of deposition. In addition, principal component analysis (PCA) of selected geochemical parameters was carried out to determine the controlling influences on the petroleum potential of the humic coals. δ<sup>13</sup>C values and the abundance of terpenoids imply the predominant contribution of angiosperms to the paleoflora. Bimetal proxies (Sr/Ba, Sr/Cu, and C-value), and δD values are generally suggestive of a warm and humid climate during the accumulation of the paleopeats. However, <i>n</i>-alkane proxies (<i>P</i><sub>wax</sub>, <i>P</i><sub>aq</sub>, <i>n</i>-C<sub>23</sub>/<i>n</i>-C<sub>29</sub>, etc.) and polycyclic aromatic hydrocarbons (PAHs) distribution suggest that Balingian coals accumulated under relatively drier and strongly seasonal paleoclimate in the Late Pliocene. When compared with published global average abundances, the investigated coals are mostly depleted in major oxides and trace elements, suggesting peat accumulation in freshwater-influenced environments. Nonetheless, higher (> 0.5 wt%) total sulfur content in some Mukah-Balingian coals suggests some degree of epigenetic marine influence. Furthermore, the low to moderately-high ash contents of the Sarawak Basin coals indicate the presence of ombrotrophic and rheotrophic peat deposits. PCA result of selected geochemical proxies suggests that source input, paleoflora, and marine incursions are not major controlling influences on the petroleum potential. However, climatic, and depositional conditions appear to slightly influence the petroleum potential of the studied humic coals.</p>","PeriodicalId":53469,"journal":{"name":"International Journal of Coal Science & Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141258692","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study employs similar simulation testing and discrete element simulation coupling to analyze the failure and deformation processes of a model coal seam's roof. The caving area of the overburden rock is divided into three zones: the delamination fracture zone, broken fracture zone, and compaction zone. The caving and fracture zones' heights are approximately 110 m above the coal seam, with a maximum subsidence of 11 m. The delamination fracture zone's porosity range is between 0.2 and 0.3, while the remainder of the roof predominantly exhibits a porosity of less than 0.1. In addition, the numerical model's stress analysis revealed that the overburden rock's displacement zone forms an 'arch-beam' structure starting from 160 m, with the maximum and minimum stress values decreasing as the distance of advancement increases. In the stress beam interval of the overburden rock, the maximum value changes periodically as the advancement distance increases. Based on a comparative analysis between observable data from on-site work and numerical simulation results, the stress data from the numerical simulation are essentially consistent with the actual results detected on-site, indicating the validity of the numerical simulation results.
{"title":"Failure characteristics and fracture mechanism of overburden rock induced by mining: A case study in China","authors":"Jiawei Li, Meng Zhang, Changxiang Wang, Changlong Liao, Baoliang Zhang","doi":"10.1007/s40789-024-00693-x","DOIUrl":"https://doi.org/10.1007/s40789-024-00693-x","url":null,"abstract":"<p>This study employs similar simulation testing and discrete element simulation coupling to analyze the failure and deformation processes of a model coal seam's roof. The caving area of the overburden rock is divided into three zones: the delamination fracture zone, broken fracture zone, and compaction zone. The caving and fracture zones' heights are approximately 110 m above the coal seam, with a maximum subsidence of 11 m. The delamination fracture zone's porosity range is between 0.2 and 0.3, while the remainder of the roof predominantly exhibits a porosity of less than 0.1. In addition, the numerical model's stress analysis revealed that the overburden rock's displacement zone forms an 'arch-beam' structure starting from 160 m, with the maximum and minimum stress values decreasing as the distance of advancement increases. In the stress beam interval of the overburden rock, the maximum value changes periodically as the advancement distance increases. Based on a comparative analysis between observable data from on-site work and numerical simulation results, the stress data from the numerical simulation are essentially consistent with the actual results detected on-site, indicating the validity of the numerical simulation results.</p>","PeriodicalId":53469,"journal":{"name":"International Journal of Coal Science & Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141191334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-31DOI: 10.1007/s40789-024-00697-7
Li’nan Huang, Danyang Li, Lei Jiang, Zhiqiang Li, Dong Tian, Kongzhai Li
The challenges posed by energy and environmental issues have forced mankind to explore and utilize unconventional energy sources. It is imperative to convert the abundant coalbed gas (CBG) into high value-added products, i.e., selective and efficient conversion of methane from CBG. Methane activation, known as the “holy grail”, poses a challenge to the design and development of catalysts. The structural complexity of the active metal on the carrier is of particular concern. In this work, we have studied the nucleation growth of small Co clusters (up to Co6) on the surface of CeO2(110) using density functional theory, from which a stable loaded Co/CeO2(110) structure was selected to investigate the methane activation mechanism. Despite the relatively small size of the selected Co clusters, the obtained Cox/CeO2(110) exhibits interesting properties. The optimized Co5/CeO2(110) structure was selected as the optimal structure to study the activation mechanism of methane due to its competitive electronic structure, adsorption energy and binding energy. The energy barriers for the stepwise dissociation of methane to form CH3*, CH2*, CH*, and C* radical fragments are 0.44, 0.55, 0.31, and 1.20 eV, respectively, indicating that CH* dissociative dehydrogenation is the rate-determining step for the system under investigation here. This fundamental study of metal-support interactions based on Co growth on the CeO2(110) surface contributes to the understanding of the essence of Co/CeO2 catalysts with promising catalytic behavior. It provides theoretical guidance for better designing the optimal Co/CeO2 catalyst for tailored catalytic reactions.
{"title":"Screening the optimal Cox/CeO2(110) (x = 1–6) catalyst for methane activation in coalbed gas","authors":"Li’nan Huang, Danyang Li, Lei Jiang, Zhiqiang Li, Dong Tian, Kongzhai Li","doi":"10.1007/s40789-024-00697-7","DOIUrl":"https://doi.org/10.1007/s40789-024-00697-7","url":null,"abstract":"<p>The challenges posed by energy and environmental issues have forced mankind to explore and utilize unconventional energy sources. It is imperative to convert the abundant coalbed gas (CBG) into high value-added products, i.e., selective and efficient conversion of methane from CBG. Methane activation, known as the “holy grail”, poses a challenge to the design and development of catalysts. The structural complexity of the active metal on the carrier is of particular concern. In this work, we have studied the nucleation growth of small Co clusters (up to Co<sub>6</sub>) on the surface of CeO<sub>2</sub>(110) using density functional theory, from which a stable loaded Co/CeO<sub>2</sub>(110) structure was selected to investigate the methane activation mechanism. Despite the relatively small size of the selected Co clusters, the obtained Co<sub><i>x</i></sub>/CeO<sub>2</sub>(110) exhibits interesting properties. The optimized Co<sub>5</sub>/CeO<sub>2</sub>(110) structure was selected as the optimal structure to study the activation mechanism of methane due to its competitive electronic structure, adsorption energy and binding energy. The energy barriers for the stepwise dissociation of methane to form CH<sub>3</sub>*, CH<sub>2</sub>*, CH*, and C* radical fragments are 0.44, 0.55, 0.31, and 1.20 eV, respectively, indicating that CH* dissociative dehydrogenation is the rate-determining step for the system under investigation here. This fundamental study of metal-support interactions based on Co growth on the CeO<sub>2</sub>(110) surface contributes to the understanding of the essence of Co/CeO<sub>2</sub> catalysts with promising catalytic behavior. It provides theoretical guidance for better designing the optimal Co/CeO<sub>2</sub> catalyst for tailored catalytic reactions.</p>","PeriodicalId":53469,"journal":{"name":"International Journal of Coal Science & Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141191335","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The enhanced coalbed methane recovery using CO2 injection (CO2-ECBM) is widely proposed as a way of achieving the energy transition and reducing atmospheric CO2 in areas such as the Lorrain basin in France, where heavy industry is responsible for huge CO2 emissions and coal mines have been closed for more than a decade. This paper deals with the feasibility of extracting methane from the Lorraine basin using CO2-ECBM by comparing data from sorption isotherms, thermogravimetric analyses and breakthrough curves for two coal samples. One is bituminous (Box 18), from Folschviller (France) and is compared with another sub-bituminous (TH01) from La Houve (France), which is used as a reference because it was identified as a good candidate for CO2-ECBM in a previous research program. The quantities of adsorbed gases (CO2/CH4) obtained by sorption isotherms, thermogravimetry and CO2 breakthrough curves showed that Box 18 adsorbs more CO2 and CH4 than TH01 due to its higher porosity and good affinity for gases (CO2/CH4). Tόth model fits the experimental CH4 and CO2 adsorption isotherms better, reflecting the fact that the adsorption surface of the coals studied is heterogeneous. Adsorption enthalpies obtained by calorimetry indicated physisorption for gas-coal interactions, with higher values for CO2 than for CH4. Thermogravimetric analyses and breakthrough curves carried out at up to 50% relative humidity showed that the adsorption capacity of CO2 decreases with increasing temperature and the presence of water, respectively. The compilation of these experimental data explained the adsorption process of the studied coals and revealed their advantages for CO2-ECBM.
在法国洛林盆地等重工业排放大量二氧化碳且煤矿已关闭十多年的地区,利用二氧化碳注入强化煤层甲烷回收(CO2-ECBM)被广泛认为是实现能源转型和减少大气中二氧化碳的一种方法。本文通过比较两种煤炭样本的吸附等温线、热重分析和突破曲线数据,探讨了利用 CO2-ECBM 从洛林盆地提取甲烷的可行性。其中一个是来自法国 Folschviller 的烟煤(方框 18),与另一个来自法国 La Houve 的亚烟煤(TH01)进行了比较。通过吸附等温线、热重仪和二氧化碳突破曲线获得的气体(CO2/CH4)吸附量表明,Box 18 比 TH01 吸附更多的 CO2 和 CH4,因为它的孔隙率更高,对气体(CO2/CH4)的亲和力更好。Tόth模型更适合实验中的CH4和CO2吸附等温线,反映了所研究煤炭的吸附表面是异质的这一事实。通过量热法获得的吸附焓表明气体与煤之间存在物理吸附作用,二氧化碳的吸附焓值高于 CH4。在相对湿度高达 50%的条件下进行的热重分析和突破曲线显示,二氧化碳的吸附能力分别随着温度的升高和水的存在而降低。这些实验数据的汇编解释了所研究煤炭的吸附过程,并揭示了它们在 CO2-ECBM 方面的优势。
{"title":"Comparative study on different coals from the Lorraine basin (France) by sorption isotherms, thermogravimetric analysis and breakthrough curves for CO2-ECBM recovery","authors":"Franck Amoih, Gisèle Finqueneisel, Thierry Zimny, Sandrine Bourrelly, Odile Barres, Dragan Grgic","doi":"10.1007/s40789-024-00696-8","DOIUrl":"https://doi.org/10.1007/s40789-024-00696-8","url":null,"abstract":"<p>The enhanced coalbed methane recovery using CO<sub>2</sub> injection (CO<sub>2</sub>-ECBM) is widely proposed as a way of achieving the energy transition and reducing atmospheric CO<sub>2</sub> in areas such as the Lorrain basin in France, where heavy industry is responsible for huge CO<sub>2</sub> emissions and coal mines have been closed for more than a decade. This paper deals with the feasibility of extracting methane from the Lorraine basin using CO<sub>2</sub>-ECBM by comparing data from sorption isotherms, thermogravimetric analyses and breakthrough curves for two coal samples. One is bituminous (Box 18), from Folschviller (France) and is compared with another sub-bituminous (TH01) from La Houve (France), which is used as a reference because it was identified as a good candidate for CO<sub>2</sub>-ECBM in a previous research program. The quantities of adsorbed gases (CO<sub>2</sub>/CH<sub>4</sub>) obtained by sorption isotherms, thermogravimetry and CO<sub>2</sub> breakthrough curves showed that Box 18 adsorbs more CO<sub>2</sub> and CH<sub>4</sub> than TH01 due to its higher porosity and good affinity for gases (CO<sub>2</sub>/CH<sub>4</sub>). Tόth model fits the experimental CH<sub>4</sub> and CO<sub>2</sub> adsorption isotherms better, reflecting the fact that the adsorption surface of the coals studied is heterogeneous. Adsorption enthalpies obtained by calorimetry indicated physisorption for gas-coal interactions, with higher values for CO<sub>2</sub> than for CH<sub>4</sub>. Thermogravimetric analyses and breakthrough curves carried out at up to 50% relative humidity showed that the adsorption capacity of CO<sub>2</sub> decreases with increasing temperature and the presence of water, respectively. The compilation of these experimental data explained the adsorption process of the studied coals and revealed their advantages for CO<sub>2</sub>-ECBM.</p>","PeriodicalId":53469,"journal":{"name":"International Journal of Coal Science & Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-05-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141191829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-30DOI: 10.1007/s40789-024-00695-9
Haiyang Wang, Desheng Zhou, Yi Zou, Peng Zheng
The flow of fluid through the porous matrix of a reservoir rock applies a seepage force to the solid rock matrix. Although the seepage force exerted by fluid flow through the porous matrix of a reservoir rock has a notable influence on rock deformation and failure, its effect on hydraulic fracture (HF) propagation remains ambiguous. Therefore, in this study, we improved a traditional fluid–solid coupling method by incorporating the role of seepage force during the fracturing fluid seepage, using the discrete element method. First, we validated the simulation results of the improved method by comparing them with an analytical solution of the seepage force and published experimental results. Next, we conducted numerical simulations in both homogeneous and heterogeneous sandstone formations to investigate the influence of seepage force on HF propagation. Our results indicate that fluid viscosity has a greater impact on the magnitude and extent of seepage force compared to injection rate, and that lower viscosity and injection rate correspond to shorter hydraulic fracture lengths. Furthermore, seepage force influences the direction of HF propagation, causing HFs to deflect towards the side of the reservoir with weaker cementation and higher permeability.
{"title":"Effect mechanism of seepage force on the hydraulic fracture propagation","authors":"Haiyang Wang, Desheng Zhou, Yi Zou, Peng Zheng","doi":"10.1007/s40789-024-00695-9","DOIUrl":"https://doi.org/10.1007/s40789-024-00695-9","url":null,"abstract":"<p>The flow of fluid through the porous matrix of a reservoir rock applies a seepage force to the solid rock matrix. Although the seepage force exerted by fluid flow through the porous matrix of a reservoir rock has a notable influence on rock deformation and failure, its effect on hydraulic fracture (HF) propagation remains ambiguous. Therefore, in this study, we improved a traditional fluid–solid coupling method by incorporating the role of seepage force during the fracturing fluid seepage, using the discrete element method. First, we validated the simulation results of the improved method by comparing them with an analytical solution of the seepage force and published experimental results. Next, we conducted numerical simulations in both homogeneous and heterogeneous sandstone formations to investigate the influence of seepage force on HF propagation. Our results indicate that fluid viscosity has a greater impact on the magnitude and extent of seepage force compared to injection rate, and that lower viscosity and injection rate correspond to shorter hydraulic fracture lengths. Furthermore, seepage force influences the direction of HF propagation, causing HFs to deflect towards the side of the reservoir with weaker cementation and higher permeability.</p>","PeriodicalId":53469,"journal":{"name":"International Journal of Coal Science & Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141191336","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-29DOI: 10.1007/s40789-024-00681-1
Yuxue Wei, Zhiyuan Fu, Yingzi Meng, Chun Li, Fu Yin, Xue Wang, Chenghua Zhang, Lisheng Guo, Song Sun
Adsorption coupled with photocatalytic degradation is proposed to fulfill the removal and thorough elimination of organic dyes. Herein, we report a facile hydrothermal synthesis of MIL-100(Fe)/GO photocatalysts. The adsorption and photocatalytic degradation process of methylene blue (MB) on MIL‐100(Fe)/GO composites were systematically studied from performance and kinetic perspectives. A possible adsorption‐photocatalytic degradation mechanism is proposed. The optimized 1M8G composite achieves 95% MB removal (60.8 mg/g) in 210 min and displays well recyclability over ten cycles. The obtained MB adsorption and degradation results are well fitted onto Langmuir isotherm and pseudo‐second order kinetic model. This study shed light on the design of MOFs based composites for water treatment.
{"title":"Photocatalytic degradation of methylene blue over MIL-100(Fe)/GO composites: a performance and kinetic study","authors":"Yuxue Wei, Zhiyuan Fu, Yingzi Meng, Chun Li, Fu Yin, Xue Wang, Chenghua Zhang, Lisheng Guo, Song Sun","doi":"10.1007/s40789-024-00681-1","DOIUrl":"https://doi.org/10.1007/s40789-024-00681-1","url":null,"abstract":"<p>Adsorption coupled with photocatalytic degradation is proposed to fulfill the removal and thorough elimination of organic dyes. Herein, we report a facile hydrothermal synthesis of MIL-100(Fe)/GO photocatalysts. The adsorption and photocatalytic degradation process of methylene blue (MB) on MIL‐100(Fe)/GO composites were systematically studied from performance and kinetic perspectives. A possible adsorption‐photocatalytic degradation mechanism is proposed. The optimized 1M8G composite achieves 95% MB removal (60.8 mg/g) in 210 min and displays well recyclability over ten cycles. The obtained MB adsorption and degradation results are well fitted onto Langmuir isotherm and pseudo‐second order kinetic model. This study shed light on the design of MOFs based composites for water treatment.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>","PeriodicalId":53469,"journal":{"name":"International Journal of Coal Science & Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141165470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-14DOI: 10.1007/s40789-024-00680-2
Chaojun Fan, Hao Sun, Sheng Li, Lei Yang, Bin Xiao, Zhenhua Yang, Mingkun Luo, Xiaofeng Jiang, Lijun Zhou
With the continuous increase of mining in depth, the gas extraction faces the challenges of low permeability, great ground stress, high temperature and large gas pressure in coal seam. The controllable shock wave (CSW), as a new method for enhancing permeability of coal seam to improve gas extraction, features in the advantages of high efficiency, eco-friendly, and low cost. In order to better utilize the CSW into gas extraction in coal mine, the mechanism and feasibility of CSW enhanced extraction need to be studied. In this paper, the basic principles, the experimental tests, the mathematical models, and the on-site tests of CSW fracturing coal seams are reviewed, thereby its future research directions are provided. Based on the different media between electrodes, the CSW can be divided into three categories: hydraulic effect, wire explosion and excitation of energetic materials by detonating wire. During the process of propagation and attenuation of the high-energy shock wave in coal, the shock wave and bubble pulsation work together to produce an enhanced permeability effect on the coal seam. The stronger the strength of the CSW is, the more cracks created in the coal is, and the greater the length, width and area of the cracks being. The repeated shock on the coal seam is conducive to the formation of complex network fracture system as well as the reduction of coal seam strength, but excessive shock frequency will also damage the coal structure, resulting in the limited effect of the enhanced gas extraction. Under the influence of ground stress, the crack propagation in coal seam will be restrained. The difference of horizontal principal stress has a significant impact on the shape, propagation direction and connectivity of the CSW induced cracks. The permeability enhancement effect of CSW is affected by the breakage degree of coal seam. The shock wave is absorbed by the broken coal, which may hinder the propagation of CSW, resulting in a poor effect of permeability enhancement. When arranging two adjacent boreholes for CSW permeability enhancement test, the spacing of boreholes should not be too close, which may lead to negative pressure mutual pulling in the early stage of drainage. At present, the accurate method for effectively predicting the CSW permeability enhanced range should be further investigated.
{"title":"Research advances in enhanced coal seam gas extraction by controllable shock wave fracturing","authors":"Chaojun Fan, Hao Sun, Sheng Li, Lei Yang, Bin Xiao, Zhenhua Yang, Mingkun Luo, Xiaofeng Jiang, Lijun Zhou","doi":"10.1007/s40789-024-00680-2","DOIUrl":"https://doi.org/10.1007/s40789-024-00680-2","url":null,"abstract":"<p>With the continuous increase of mining in depth, the gas extraction faces the challenges of low permeability, great ground stress, high temperature and large gas pressure in coal seam. The controllable shock wave (CSW), as a new method for enhancing permeability of coal seam to improve gas extraction, features in the advantages of high efficiency, eco-friendly, and low cost. In order to better utilize the CSW into gas extraction in coal mine, the mechanism and feasibility of CSW enhanced extraction need to be studied. In this paper, the basic principles, the experimental tests, the mathematical models, and the on-site tests of CSW fracturing coal seams are reviewed, thereby its future research directions are provided. Based on the different media between electrodes, the CSW can be divided into three categories: hydraulic effect, wire explosion and excitation of energetic materials by detonating wire. During the process of propagation and attenuation of the high-energy shock wave in coal, the shock wave and bubble pulsation work together to produce an enhanced permeability effect on the coal seam. The stronger the strength of the CSW is, the more cracks created in the coal is, and the greater the length, width and area of the cracks being. The repeated shock on the coal seam is conducive to the formation of complex network fracture system as well as the reduction of coal seam strength, but excessive shock frequency will also damage the coal structure, resulting in the limited effect of the enhanced gas extraction. Under the influence of ground stress, the crack propagation in coal seam will be restrained. The difference of horizontal principal stress has a significant impact on the shape, propagation direction and connectivity of the CSW induced cracks. The permeability enhancement effect of CSW is affected by the breakage degree of coal seam. The shock wave is absorbed by the broken coal, which may hinder the propagation of CSW, resulting in a poor effect of permeability enhancement. When arranging two adjacent boreholes for CSW permeability enhancement test, the spacing of boreholes should not be too close, which may lead to negative pressure mutual pulling in the early stage of drainage. At present, the accurate method for effectively predicting the CSW permeability enhanced range should be further investigated.</p>","PeriodicalId":53469,"journal":{"name":"International Journal of Coal Science & Technology","volume":null,"pages":null},"PeriodicalIF":8.3,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140930378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}