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Effect of CO2 dilution on laminar burning velocities, combustion characteristics and NOx emissions of CH4/air mixtures CO2稀释对CH4/空气混合物层流燃烧速度、燃烧特性和NOx排放的影响
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-11-13 DOI: 10.1007/s40789-023-00655-9
Wenlong Dong, Longkai Xiang, Jian Gao, Bingbing Qiu, Huaqiang Chu
Abstract The laminar combustion characteristics of CH 4 /air premixed flames with CO 2 addition are systemically studied. Experimental measurements and numerical simulations of the laminar burning velocity (LBV) are performed in CH 4 /CO 2 /Air flames with various CO 2 doping ratio under equivalence ratios of 1.0–1.4. GRI 3.0 mech and Aramco mech are employed for predicting LBV, adiabatic flame temperature (AFT), important intermediate radicals (CH 3 , H, OH, O) and NO x emissions (NO, NO 2 , N 2 O), as well as the sensitivity analysis is also conducted. The detail analysis of experiment and simulation reveals that as the CO 2 addition increases from 0% to 40%, the LBVs and AFTs decrease monotonously. Under the same CO 2 doping ratio, the LBVs and AFTs increase first and then decrease with the increase of equivalence ratio, and the maximum of LBV is reached at equivalence ratio of 1.05. The mole fraction tendency of important intermediates and NO x with equivalence ratio and CO 2 doping ratio are similar to the LBVs and AFTs. Reaction H + O 2 ⇔ O + OH is found to be responsible for the promotion of the generation of important intermediates and NO x under the equivalence ratios and CO 2 addition through sensitivity analysis. The sensitivity coefficients of elementary reactions that the increasing of CO 2 doping ratio promotes or inhibits formation of intermediate radicals and NO x decreases. Graphical abstract
系统研究了添加co2的ch4 /空气预混火焰的层流燃烧特性。在当量比为1.0 ~ 1.4的条件下,对不同co2掺杂比的ch4 / co2 /Air火焰层流燃烧速度(LBV)进行了实验测量和数值模拟。采用GRI 3.0模型和Aramco模型对LBV、绝热火焰温度(AFT)、重要中间自由基(CH 3、H、OH、O)和nox排放量(NO、NO 2、n2o)进行预测,并进行敏感性分析。实验和模拟的详细分析表明,随着co2添加量从0%增加到40%,LBVs和AFTs单调降低。在相同CO 2掺杂比下,随着等效比的增大,LBV和aft先增大后减小,在等效比为1.05时达到最大值。等效比和CO 2掺杂比下,重要中间体和NO x的摩尔分数趋势与LBVs和AFTs相似。通过敏感性分析,发现反应H + o2⇔O + OH促进了重要中间体和NO x在等比值和CO 2加入下的生成。随着CO 2掺杂比例的增加,促进或抑制中间自由基和NO x生成的元素反应敏感性系数减小。图形抽象
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引用次数: 0
Simulation study of hydrogen sulfide removal in underground gas storage converted from the multilayered sour gas field 多层含硫气田改造地下储气库硫化氢脱除模拟研究
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-11-04 DOI: 10.1007/s40789-023-00631-3
Yi Yang, Longxin Li, Xia Wang, Nan Qin, Ruihan Zhang, Yulong Zhao, Ye Tian
Abstract A simulation study was carried out to investigate the temporal evolution of H 2 S in the Huangcaoxia underground gas storage (UGS), which is converted from a depleted sulfur-containing gas field. Based on the rock and fluid properties of the Huangcaoxia gas field, a multilayered model was built. The upper layer Jia-2 contains a high concentration of H 2 S (27.2 g/m 3 ), and the lower layer Jia-1 contains a low concentration of H 2 S (14.0 mg/m 3 ). There is also a low-permeability interlayer between Jia-1 and Jia-2. The multi-component fluid characterizations for Jia-1 and Jia-2 were implemented separately using the Peng-Robinson equation of state in order to perform the compositional simulation. The H 2 S concentration gradually increased in a single cycle and peaked at the end of the production season. The peak H 2 S concentration in each cycle showed a decreasing trend when the recovery factor (RF) of the gas field was lower than 70%. When the RF was above 70%, the peak H 2 S concentration increased first and then decreased. A higher reservoir RF, a higher maximum working pressure, and a higher working gas ratio will lead to a higher H 2 S removal efficiency. Similar to developing multi-layered petroleum fields, the operation of multilayered gas storage can also be divided into multi-layer commingled operation and independent operation for different layers. When the two layers are combined to build the storage, the sweet gas produced from Jia-1 can spontaneously mix with the sour gas produced from Jia-2 within the wellbore, which can significantly reduce the overall H 2 S concentration in the wellstream. When the working gas volume is set constant, the allocation ratio between the two layers has little effect on the H 2 S removal. After nine cycles, the produced gas’s H 2 S concentration can be lowered to 20 mg/m 3 . Our study recommends combining the Jia-2 and Jia-1 layers to build the Huangcaoxia underground gas storage. This plan can quickly reduce the H 2 S concentration of the produced gas to 20 mg/m 3 , thus meeting the gas export standards as well as the HSE (Health, Safety, and Environment) requirements in the field. This study helps the engineers understand the H 2 S removal for sulfur-containing UGS as well as provides technical guidelines for converting other multilayered sour gas fields into underground storage sites.
摘要以含硫枯竭气田改造的黄草峡地下储气库(UGS)为研究对象,研究了地下储气库中硫化氢的演化规律。根据黄草峡气田的岩石和流体性质,建立了多层模型。上层Jia-2含有高浓度的h2s (27.2 g/m 3),下层Jia-1含有低浓度的h2s (14.0 mg/m 3)。甲1层和甲2层之间也存在低渗夹层。利用Peng-Robinson状态方程分别对佳1号和佳2号进行多组分流体表征,进行组分模拟。h2s浓度在单周期内逐渐升高,在生产季末达到峰值。当气田采收率(RF)低于70%时,各循环的峰值h2s浓度呈下降趋势。当RF大于70%时,峰值h2s浓度先升高后降低。较高的储层RF、较高的最大工作压力和较高的工作气比将导致较高的h2s去除效率。与开发多层油田类似,多层储气库的作业也可分为多层混合作业和分层独立作业。当两层组合建造储气库时,甲-1产的含硫气可以在井筒内与甲-2产的含硫气自发混合,从而显著降低井流中整体h2s浓度。当工作气量一定时,两层分配比例对h2s去除率影响不大。经过9次循环后,产气的h2s浓度可降至20 mg/ m3。研究建议将甲2层与甲1层结合建设黄草峡地下储气库。该方案可将采出气体的h2s浓度快速降低至20 mg/ m3,从而满足天然气出口标准以及该领域的HSE(健康、安全与环境)要求。该研究有助于工程师了解含硫UGS的h2s去除,并为其他多层含硫气田转化为地下储存场所提供技术指导。
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引用次数: 0
Building 3D CityGML models of mining industrial structures using integrated UAV and TLS point clouds 利用集成无人机和TLS点云构建矿业产业结构的三维CityGML模型
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-10-30 DOI: 10.1007/s40789-023-00645-x
Canh Le Van, Cuong Xuan Cao, Anh Ngoc Nguyen, Chung Van Pham, Long Quoc Nguyen
Abstract Mining industrial areas with anthropogenic engineering structures are one of the most distinctive features of the real world. 3D models of the real world have been increasingly popular with numerous applications, such as digital twins and smart factory management. In this study, 3D models of mining engineering structures were built based on the CityGML standard. For collecting spatial data, the two most popular geospatial technologies, namely UAV-SfM and TLS were employed. The accuracy of the UAV survey was at the centimeter level, and it satisfied the absolute positional accuracy requirement of creating all levels of detail (LoD) according to the CityGML standard. Therefore, the UAV-SfM point cloud dataset was used to build LoD 2 models. In addition, the comparison between the UAV-SfM and TLS sub-clouds of facades and roofs indicates that the UAV-SfM and TLS point clouds of these objects are highly consistent, therefore, point clouds with a higher level of detail and accuracy provided by the integration of UAV-SfM and TLS were used to build LoD 3 models. The resulting 3D CityGML models include 39 buildings at LoD 2, and two mine shafts with hoistrooms, headframes, and sheave wheels at LoD 3.
具有人为工程结构的矿业工业区是现实世界最显著的特征之一。现实世界的3D模型在许多应用中越来越受欢迎,例如数字双胞胎和智能工厂管理。本研究基于CityGML标准建立了矿山工程构筑物的三维模型。为了收集空间数据,采用了两种最流行的地理空间技术,即UAV-SfM和TLS。无人机测量精度为厘米级,满足CityGML标准创建各级细节(LoD)的绝对位置精度要求。因此,采用UAV-SfM点云数据集构建LoD 2模型。此外,通过对正立面和屋顶的无人机- sfm和TLS子云的对比发现,这些目标的无人机- sfm和TLS点云高度一致,因此,使用无人机- sfm和TLS集成提供的更高细节和精度的点云来构建LoD 3模型。由此产生的3D CityGML模型包括位于LoD 2的39座建筑物,以及位于LoD 3的带有吊装室、井架和滑轮的两个矿井。
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引用次数: 0
Experimental study on the slip evolution of planar fractures subjected to cyclic normal stress 循环正应力作用下平面裂缝滑移演化的实验研究
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-10-27 DOI: 10.1007/s40789-023-00654-w
Kang Tao, Wengang Dang, Xian Liao, Xingling Li
Abstract The frictional rupture mechanisms of rock discontinuities considering the dynamic load disturbance still remain unclear. This paper investigates the transitional behaviors of slip events happened on a planar granite fracture under cyclic normal stress with different oscillation amplitudes. The experimental results show that the activations of fast slips always correlate with unloading of normal stress. Besides, the intensive normal stress oscillation can weaken the shear strength which is recoverable when the normal stress return to constant. The rupture patterns are quantified by stress drop, slip length and slip velocity. With the effect of small oscillation amplitudes, the slip events show chaotic shapes, compared to the regular and predictable style under constant normal stress. When the amplitude is large enough, the big and small slip events emerge alternately, showing a compound slip style. Large amplitude of the cyclic normal stress also widens the interval differences of the slip events. This work provides experimental supports for a convincible link between the dynamic stress disturbance and the slip behavior of rock fractures.
考虑动荷载扰动的岩体结构面摩擦破裂机制尚不清楚。本文研究了在不同振荡幅值的循环正应力作用下,平面花岗岩断裂上发生滑动事件的过渡行为。实验结果表明,快滑块的激活总是与法向应力的卸载有关。此外,剧烈的法向应力振荡会削弱抗剪强度,当法向应力恢复到恒定时,抗剪强度可恢复。破裂模式通过应力降、滑移长度和滑移速度来量化。在较小的振荡幅值的作用下,滑移事件呈现出混乱的形状,而在恒定的正应力下,滑移事件呈现出规则和可预测的形式。当振幅足够大时,大小滑动事件交替出现,表现为复合滑动类型。大的循环正应力幅值也扩大了滑移事件的间隔差。这一工作为在动应力扰动与岩石裂隙滑移行为之间建立可信的联系提供了实验支持。
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引用次数: 0
Time-shift effect of spontaneous combustion characteristics and microstructure difference of dry-soaked coal 干浸煤自燃特性的时移效应及微观结构差异
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-10-27 DOI: 10.1007/s40789-023-00616-2
Yikang Liu, Haiyan Wang, Huiyong Niu, Tao Wang, Zhiwen Chen, Yuqi Chen, Qingjie Qi
Abstract The physical and chemical properties of the air-dried residual coal after soaking in the goaf will change, resulting in an increase in its spontaneous combustion tendency. This study aimed to look into the features and mechanism of soaked-dried coal's spontaneous combustion. Five samples of coal were dried to various degrees, and the weight loss features during thermal processing were examined. Based on this, the pore structure and chemical structure characteristics of the coal samples with the highest tendency to spontaneous combustion were quantitatively examined, and the mechanism by which soaking-drying affected the spontaneous combustion heating process of the remaining coal in goaf was investigated in turn. The results show that T 1 decreases with the increase of drying time, T 2 –T 6 shows a fluctuating change, and the ignition activation energy of 36-S-Coal is smaller than that of other coal samples. The pore type of 36-S-Coal changes from a one-end closed impermeable pore to an open pore, and the pore group area is large. During the 36 h drying process, the internal channels of the coal were dredged, and a large number of gravels and minerals were precipitated from the pores with the air flow. A large number of gravels were around the pores to form a surface structure that was easy to adsorb various gases. Furthermore, infrared spectroscopy was used to analyze the two coal samples. It was found that soaking and drying did not change the functional group types of coal samples, but the fatty chain degree of 36-S-Coal was reduced to 1.56. It shows that the aliphatic chain structure of coal is changed after 36 h of drying after 30 days of soaking, which leads to the continuous shedding of aliphatic chain branches of residual coal, and the skeleton of coal is looser, which makes the low-temperature oxidation reaction of 36-S-Coal easier. Based on the above results, the coal-oxygen composite mechanism of water-immersed-dried coal is obtained, and it is considered that the key to the spontaneous combustion oxidation process of coal is to provide oxygen atoms and accelerate the formation of peroxides.
风干残煤在采空区浸泡后,其物理化学性质会发生变化,导致其自燃倾向增加。本研究旨在探讨湿干煤自燃特性及其机理。对5个煤样进行了不同程度的干燥,考察了其在热加工过程中的失重特征。在此基础上,定量考察了最易自燃煤样的孔隙结构和化学结构特征,并依次研究了浸湿干燥对采空区剩余煤自燃加热过程的影响机理。结果表明:t1随干燥时间的延长而减小,t2 -T - 6呈波动变化,36- s煤的点火活化能小于其他煤样。36- s煤孔隙类型由一端封闭不透水孔隙转变为开放孔隙,孔隙群面积较大。在36 h的干燥过程中,煤的内部通道被疏浚,大量的砾石和矿物随气流从孔隙中析出。孔隙周围有大量的砾石,形成易于吸附各种气体的表面结构。利用红外光谱对两种煤样进行了分析。结果发现,浸泡干燥对煤样官能团类型没有影响,但36- s煤的脂肪链度降低到1.56。结果表明,煤的脂肪链结构在浸泡30天后干燥36 h后发生了变化,导致残余煤的脂肪链分支不断脱落,煤骨架更加疏松,有利于36- s煤的低温氧化反应。基于以上结果,得出了水浸-干燥煤的煤氧复合机理,认为煤自燃氧化过程的关键是提供氧原子,加速过氧化物的形成。
{"title":"Time-shift effect of spontaneous combustion characteristics and microstructure difference of dry-soaked coal","authors":"Yikang Liu, Haiyan Wang, Huiyong Niu, Tao Wang, Zhiwen Chen, Yuqi Chen, Qingjie Qi","doi":"10.1007/s40789-023-00616-2","DOIUrl":"https://doi.org/10.1007/s40789-023-00616-2","url":null,"abstract":"Abstract The physical and chemical properties of the air-dried residual coal after soaking in the goaf will change, resulting in an increase in its spontaneous combustion tendency. This study aimed to look into the features and mechanism of soaked-dried coal's spontaneous combustion. Five samples of coal were dried to various degrees, and the weight loss features during thermal processing were examined. Based on this, the pore structure and chemical structure characteristics of the coal samples with the highest tendency to spontaneous combustion were quantitatively examined, and the mechanism by which soaking-drying affected the spontaneous combustion heating process of the remaining coal in goaf was investigated in turn. The results show that T 1 decreases with the increase of drying time, T 2 –T 6 shows a fluctuating change, and the ignition activation energy of 36-S-Coal is smaller than that of other coal samples. The pore type of 36-S-Coal changes from a one-end closed impermeable pore to an open pore, and the pore group area is large. During the 36 h drying process, the internal channels of the coal were dredged, and a large number of gravels and minerals were precipitated from the pores with the air flow. A large number of gravels were around the pores to form a surface structure that was easy to adsorb various gases. Furthermore, infrared spectroscopy was used to analyze the two coal samples. It was found that soaking and drying did not change the functional group types of coal samples, but the fatty chain degree of 36-S-Coal was reduced to 1.56. It shows that the aliphatic chain structure of coal is changed after 36 h of drying after 30 days of soaking, which leads to the continuous shedding of aliphatic chain branches of residual coal, and the skeleton of coal is looser, which makes the low-temperature oxidation reaction of 36-S-Coal easier. Based on the above results, the coal-oxygen composite mechanism of water-immersed-dried coal is obtained, and it is considered that the key to the spontaneous combustion oxidation process of coal is to provide oxygen atoms and accelerate the formation of peroxides.","PeriodicalId":53469,"journal":{"name":"International Journal of Coal Science & Technology","volume":"14 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136264059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of nanosized magnesia on the hydration of borehole-sealing cements prepared using different methods 纳米氧化镁对不同方法制备的封井水泥水化性能的影响
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-10-26 DOI: 10.1007/s40789-023-00605-5
Quanle Zou, Jinfei Zhan, Xin Wang, Zhen Huang
Abstract Gas drainage is an effective technology for gas control in coal mines. A high borehole-sealing quality is the fundamental precondition for efficient gas drainage. The expansibilities of cement pastes used in borehole-sealing processes are critical for the borehole-sealing effect. Nanosized magnesia expansive agents are used to improve the expansibilities of cement pastes and improve the borehole-sealing effect. Nuclear magnetic resonance spectrometry and scanning electron microscopy were adopted to study the effects of nanosized magnesia on the hydration of borehole-sealing cements used with different preparation methods. The results showed that an increase in the mass fraction of the nanosized magnesia promoted cement hydration, and the mass fraction was positively correlated with the promotion effect. The use of different preparation methods did not change the water-phase distribution in the cement. When using the wet-mixing preparation method, nanosized magnesia promoted the induction, acceleration, and deceleration periods of hydration; when using the dry-mixing preparation method, the nanosized magnesia promoted the induction period of cement hydration, and the promotion effect was less obvious than that seen when using the wet-mixing method. When using the wet-mixing preparation method, the nanosized magnesia was uniformly dispersed, thus enlarging the surface area of the reaction, which provided more nucleation sites for the hydration products of the cement and therefore accelerated the hydration reaction. When using the dry-mixing preparation method, the nanosized magnesia powders were dispersed nonuniformly and aggregated. Under these conditions, only a few nanosized magnesia particles on the surfaces of the aggregated clusters took part in hydration, so only a small number of nucleation sites were provided for the hydration products of cement. This led to inconsistent hydration of cement pastes prepared using the dry-mixing method. The surface porosity of the cement prepared with the wet-mixing preparation method first decreased and then increased with increases in the mass fraction of the nanosized magnesia. The cement surface exhibited compact hydration products and few pores, and the surface was relatively smooth. In comparison, the surface porosity of the cement prepared using the dry-mixing method fluctuated with increasing mass fraction of the nanosized magnesia, resulting in a rough cement surface and microfractures on some surfaces. The two preparation methods both reduced the surface porosity of the cement. The wet-mixing preparation was more effective and consistent in improving the compactness of the cement than the dry-mixing preparation. These results provide important guidance on the addition of nanosized magnesia in borehole-sealing engineering and the selection of cement preparation methods, and they also lay a solid foundation for realizing safe and efficient gas drainage.
瓦斯抽放是煤矿瓦斯治理的一项有效技术。高封井质量是有效抽采瓦斯的基本前提。封井过程中使用的水泥浆的膨胀性对封井效果至关重要。采用纳米氧化镁膨胀剂改善水泥浆的膨胀性,改善封井效果。采用核磁共振谱和扫描电镜研究了纳米氧化镁对不同制备方法封井水泥水化性能的影响。结果表明,纳米氧化镁质量分数的增加促进了水泥水化,且质量分数与水化效果呈正相关。不同制备方法的使用没有改变水泥中水相的分布。采用湿法混合制备时,纳米氧化镁促进了水化的诱导期、加速期和减速期;采用干法制备时,纳米氧化镁能促进水泥水化诱导期,但促进效果不如湿法制备时明显。采用湿混合制备方法时,纳米氧化镁分散均匀,扩大了反应表面积,为水泥水化产物提供了更多的成核位点,从而加速了水化反应。采用干法制备时,纳米氧化镁粉分散不均匀,存在团聚现象。在此条件下,仅聚集团簇表面的少量纳米级氧化镁颗粒参与水化,因此仅为水泥水化产物提供了少量的成核位点。这导致使用干拌法制备的水泥浆体水化不一致。随着纳米氧化镁质量分数的增加,湿拌法制备的水泥表面孔隙率先减小后增大。水泥表面水化产物致密,孔隙少,表面相对光滑。相比之下,采用干混法制备的水泥的表面孔隙率随纳米氧化镁质量分数的增加而波动,导致水泥表面粗糙,部分表面出现微裂缝。两种制备方法均降低了水泥的表面孔隙率。湿拌法比干拌法在改善水泥密实度方面更有效、更一致。研究结果为井眼密封工程中纳米氧化镁的添加和水泥制备方法的选择提供了重要指导,为实现瓦斯安全高效抽放奠定了坚实基础。
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引用次数: 0
Spoil characterisation using UAV-based optical remote sensing in coal mine dumps 基于无人机光学遥感的煤矿排土场矸石特征分析
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-10-26 DOI: 10.1007/s40789-023-00622-4
Sureka Thiruchittampalam, Sarvesh Kumar Singh, Bikram Pratap Banerjee, Nancy F. Glenn, Simit Raval
Abstract The structural integrity of mine dumps is crucial for mining operations to avoid adverse impacts on the triple bottom-line. Routine temporal assessments of coal mine dumps are a compliant requirement to ensure design reconciliation as spoil offloading continues over time. Generally, the conventional in-situ coal spoil characterisation is inefficient, laborious, hazardous, and prone to experts' observation biases. To this end, this study explores a novel approach to develop automated coal spoil characterisation using unmanned aerial vehicle (UAV) based optical remote sensing. The textural and spectral properties of the high-resolution UAV images were utilised to derive lithology and geotechnical parameters (i.e., fabric structure and relative density/consistency) in the proposed workflow. The raw images were converted to an orthomosaic using structure from motion aided processing. Then, structural descriptors were computed per pixel to enhance feature modalities of the spoil materials. Finally, machine learning algorithms were employed with ground truth from experts as training and testing data to characterise spoil rapidly with minimal human intervention. The characterisation accuracies achieved from the proposed approach manifest a digital solution to address the limitations in the conventional characterisation approach.
摘要矿山排土场的结构完整性是矿山生产中避免对三重底线产生不利影响的关键。煤矿排土场的常规时间评估是一项合规要求,以确保随着时间的推移,随着矸石的卸载继续进行设计协调。一般来说,传统的煤矸石原位表征方法效率低、费力、危险,而且容易受到专家观察偏差的影响。为此,本研究探索了一种利用基于无人机(UAV)的光学遥感技术开发自动化煤矸石表征的新方法。在提出的工作流程中,利用高分辨率无人机图像的纹理和光谱特性来推导岩性和岩土参数(即织物结构和相对密度/一致性)。使用运动辅助处理的结构将原始图像转换为正交图像。然后,计算每像素的结构描述符以增强废土材料的特征模态。最后,机器学习算法与专家的真实情况一起作为训练和测试数据,在最少的人为干预下快速表征破坏。从所提出的方法中获得的表征精度表明了一种数字解决方案,以解决传统表征方法中的局限性。
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引用次数: 0
Stability analysis of a slope containing water-sensitive mudstone considering different rainfall conditions at an open-pit mine 考虑不同降雨条件的露天矿含水敏泥岩边坡稳定性分析
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-10-06 DOI: 10.1007/s40789-023-00619-z
Guoyu Yang, Yanlong Chen, Xuanyu Liu, Ri Yang, Yafei Zhang, Jialong Zhang
Abstract Mudstone, as a typical soft rock with wide distribution, has been endangering the slopes containing mudstone by its water-sensitivity of swelling and weakening strength when encountering water. To comprehensively understand the water-sensitivity of mudstone and reveal its influence on slope stability, we took the working slope containing water-sensitive mudstone of Shengli No.1 open-pit coal mine in Xilinhot, Inner Mongolia, China, as an example. Mudstone samples taken from the working slope were remodeled and saturated, and then triaxial tested to obtain the effective cohesion and effective internal friction angle. The filter paper method was used to obtain the soil–water characteristic curve of unsaturated mudstone. The pore structure of mudstone samples with different water contents were analyzed using the mercury intrusion porosimetry tests combined with the fractal dimension. The total pore content of the mudstone sample with lower water content is greater than that of the mudstone sample with higher water content. The mesopores are more in the mudstone sample with lower water content, while the small pores are more in the mudstone sample with higher water content. The variation of water content will change the complexity of mudstone pore structure. The higher the water content, the simpler the mudstone pore structure and the smoother the pore surface. Numerical calculations were conducted on the stability of the working slope under different rainfall conditions. The effective saturation on the mudstone layer surface changed and the plastic strain all occurred on the mudstone steps under different rainfall conditions. The key to preventing landslide of the slope containing water-sensitive mudstone in Shengli No.1 open-pit coal mine is to control the deformation and sliding of the mudstone layer.
泥岩作为一种典型的分布较广的软岩,其遇水膨胀、强度减弱的水敏性已对含泥岩边坡造成危害。为全面了解泥岩的水敏性,揭示其对边坡稳定性的影响,以内蒙古锡林浩特胜利一号露天煤矿含水敏性泥岩的工作边坡为例。对工作边坡泥岩进行重塑和饱和,然后进行三轴试验,得到有效黏聚力和有效内摩擦角。采用滤纸法获得了非饱和泥岩的土-水特征曲线。采用压汞孔隙测量法结合分形维数对不同含水率泥岩样品的孔隙结构进行了分析。低含水率泥岩样品的总孔隙含量大于高含水率泥岩样品。低含水率泥岩样品中介孔多,高含水率泥岩样品中小孔多。含水率的变化会改变泥岩孔隙结构的复杂性。含水率越高,泥岩孔隙结构越简单,孔隙表面越光滑。对不同降雨条件下工作边坡的稳定性进行了数值计算。不同降雨条件下,泥岩层表面有效饱和度发生变化,泥岩台阶均发生塑性应变。胜利一号露天矿含水敏泥岩边坡防治滑坡的关键是控制泥岩层的变形和滑动。
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引用次数: 0
Environmental performance assessments of different methods of coal preparation for use in small-capacity boilers: experiment and theory 小容量锅炉不同选煤方法的环境性能评价:实验与理论
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-10-05 DOI: 10.1007/s40789-023-00623-3
A. N. Kozlov, E. P. Maysyuk, I. Yu. Ivanova
Abstract The purpose of this article is to receive environmental assessments of combustion of different types of coal fuel depending on the preparation (unscreened, size-graded, briquetted and heat-treated) in automated boilers and boilers with manual loading. The assessments were made on the basis of data obtained from experimental methods of coal preparation and calculated methods of determining the amount of pollutant and greenhouse gas emissions, as well as the mass of ash and slag waste. The main pollutants from coal combustion are calculated: particulate matter, benz(a)pyrene, nitrogen oxides, sulfur dioxide, carbon monoxide. Of the greenhouse gases carbon dioxide is calculated. As a result of conducted research it is shown that the simplest preliminary preparation (size-graded) of coal significantly improves combustion efficiency and environmental performance: emissions are reduced by 13% for hard coal and up to 20% for brown coal. The introduction of automated boilers with heat-treated coal in small boiler facilities allows to reduce emissions and ash and slag waste by 2–3 times. The best environmental indicators correspond to heat-treated lignite, which is characterized by the absence of sulfur dioxide emissions.
摘要本文的目的是对不同类型的煤燃料在自动锅炉和人工加载锅炉中不同制备方式(未筛选、分级、压块和热处理)的燃烧进行环境评价。评价依据选煤实验方法获得的数据和污染物排放量、温室气体排放量以及灰渣废物质量的计算方法进行。计算了燃煤产生的主要污染物:颗粒物、苯(a)芘、氮氧化物、二氧化硫、一氧化碳。计算了温室气体中的二氧化碳。研究结果表明,最简单的煤的初步制备(粒度分级)显着提高了燃烧效率和环境性能:硬煤的排放量减少了13%,褐煤的排放量减少了20%。在小型锅炉设施中采用热处理煤的自动化锅炉,可以减少2-3倍的排放和灰渣废物。最好的环境指标对应于热处理的褐煤,其特点是没有二氧化硫排放。
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引用次数: 0
In-situ gas contents of a multi-section coal seam in Sydney basin for coal and gas outburst management 悉尼盆地多段煤层原位含气量分析及煤与瓦斯突出治理
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-10-01 DOI: 10.1007/s40789-023-00614-4
Zhongbei Li, Ting Ren, Dennis Black, Ming Qiao, Itmam Abedin, Jessica Juric, Mike Wang
Abstract The gas content is crucial for evaluating coal and gas outburst potential in underground coal mining. This study focuses on investigating the in-situ coal seam gas content and gas sorption capacity in a representative coal seam with multiple sections (A1, A2, and A3) in the Sydney basin, where the CO 2 composition exceeds 90%. The fast direct desorption method and associated devices were described in detail and employed to measure the in-situ gas components ( Q 1 , Q 2 , and Q 3 ) of the coal seam. The results show that in-situ total gas content ( Q T ) ranges from 9.48 m 3 /t for the A2 section to 14.80 m 3 /t for the A3 section, surpassing the Level 2 outburst threshold limit value, thereby necessitating gas drainage measures. Among the gas components, Q 2 demonstrates the highest contribution to Q T , ranging between 55% and 70%. Furthermore, high-pressure isothermal gas sorption experiments were conducted on coal samples from each seam section to explore their gas sorption capacity. The Langmuir model accurately characterizes CO 2 sorption behavior, with fit coefficients ( R 2 ) greater than 0.99. Strong positive correlations are observed between in-situ gas content and Langmuir volume, as well as between residual gas content ( Q 3 ) and sorption hysteresis. Notably, the A3 seam section is proved to have a higher outburst propensity due to its higher Q 1 and Q 2 gas contents, lower sorption hysteresis, and reduced coal toughness f value. The insights derived from the study can contribute to the development of effective gas management strategies and enhance the safety and efficiency of coal mining operations.
矿井瓦斯含量是评价煤与瓦斯突出潜力的关键。本研究重点研究了悉尼盆地具有代表性的A1、A2、A3多段煤层(CO 2成分超过90%)的煤层原煤含气量及瓦斯吸附能力。详细介绍了快速直接解吸法及其配套装置,并应用该方法对煤层中煤层气组分(q1、q2、q3)进行了原位测定。结果表明:A2段现场总含气量(Q T)为9.48 m 3 / T ~ A3段为14.80 m 3 / T,超过了2级突出阈值限值,需要采取抽放瓦斯措施;在气体组分中,q2对Q - T的贡献最大,在55% ~ 70%之间。在此基础上,对各煤层段煤样进行了高压等温气体吸附实验,探索煤样的气体吸附能力。Langmuir模型准确地描述了co2的吸附行为,拟合系数(r2)大于0.99。原位气体含量与Langmuir体积、残余气体含量(q3)与吸附滞回率呈显著正相关。值得注意的是,A3煤层区段q1和q2气体含量较高,吸附滞后较低,煤韧性f值较低,因此具有较高的突出倾向。从研究中获得的见解有助于制定有效的气体管理战略,提高煤矿开采作业的安全性和效率。
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引用次数: 0
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International Journal of Coal Science & Technology
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