International Journal of Coal Science & Technology最新文献

Rock bolts are extensively utilized in underground engineering as a means of offering support and stability to rock masses in tunnels, mines, and other underground structures. In environments of high ground stress, faults or weak zones can frequently arise in rock formations, presenting a significant challenge for engineering and potentially leading to underground engineering collapse. Rock bolts serve as a crucial structural element for the transmission of tensile stress and are capable of withstanding shear loads to prevent sliding of weak zones within rock mass. Therefore, a complete understanding of the behavior of rock bolts subjected to shear loads is essential. This paper presents a state-of-the-art review of the research progress of rock bolts subjected to shear load in three categories: experiment, numerical simulation, and analytical model. The review focuses on the research studies and developments in this area since the 1970s, providing a comprehensive overview of numerous factors that influence the anchorage performance of rock bolts. These factors include the diameter and angle of the rock bolt installation, rock strength, grouting material, bolt material, borehole diameter, rock bolt preload, normal stress, joint surface roughness and joint expansion angle. The paper reviews the improvement of mechanical parameter setting in numerical simulation of rock bolt shear. Furthermore, it delves into the optimization of the analytical model concerning rock bolt shear theory, approached from the perspectives of both Elastic foundation beam theory coupled with Elastoplasticity theory and Structural mechanic methods. The significance of this review lies in its ability to provide insights into the mechanical behavior of rock bolts. The paper also highlights the limitations of current research and guidelines for further research of rock bolts.

Abstract

Deep shale reservoirs (3500–4500 m) exhibit significantly different stress states than moderately deep shale reservoirs (2000–3500 m). As a result, the brittleness response mechanisms of deep shales are also different. It is urgent to investigate methods to evaluate the brittleness of deep shales to meet the increasingly urgent needs of deep shale gas development. In this paper, the quotient of Young’s modulus divided by Poisson’s ratio based on triaxial compression tests under in situ stress conditions is taken as SSBV (Static Standard Brittleness Value). A new and pragmatic technique is developed to determine the static brittleness index that considers elastic parameters, the mineral content, and the in situ stress conditions (BIEMS). The coefficient of determination between BIEMS and SSBV reaches 0.555 for experimental data and 0.805 for field data. This coefficient is higher than that of other brittleness indices when compared to SSBV. BIEMS can offer detailed insights into shale brittleness under various conditions, including different mineral compositions, depths, and stress states. This technique can provide a solid data-based foundation for the selection of ‘sweet spots’ for single-well engineering and the comparison of the brittleness of shale gas production layers in different areas.

Excessive emissions of nitrogen oxides from flue gas have imposed various detrimental impacts on environment, and the development of deNO_x catalysts with low-cost and high performance is an urgent requirement. Iron oxide-based material has been explored for promising deNO_x catalysts. However, the unsatisfactory low-temperature activity limits their practical applications. In this study, a series of excellent low-temperature denitrification catalysts (Ha-FeO_x/yZS) were prepared by acid treatment of zinc slag, and the mass ratios of Fe to impure ions was regulated by adjusting the acid concentrations. Ha-FeO_x/yZS showed high denitrification performance (> 90%) in the range of 180–300 °C, and the optimal NO conversion and N₂ selectivity were higher than 95% at 250 °C. Among them, the Ha-FeO_x/2ZS synthesized with 2 mol/L HNO₃ exhibited the widest temperature window (175–350 °C). The excellent denitrification performance of Ha-FeO_x/yZS was mainly attributed to the strong interaction between Fe and impurity ions to inhibit the growth of crystals, making Ha-FeO_x/yZS with amorphous structure, nice fine particles, large specific surface area, more surface acid sites and high chemisorbed oxygen. The in-situ DRIFT experiments confirmed that the SCR reaction on the Ha-FeO_x/yZS followed both Langmuir-Hinshelwood (L-H) mechanism and Eley-Rideal (E-R) mechanism. The present work proposed a high value-added method for the preparation of cost-effective catalysts from zinc slag, which showed a promising application prospect in NO_x removal by selective catalytic reduction with ammonia.

This study investigates the impact of different water coupling coefficients on the blasting effect of red sandstone. The analysis is based on the theories of detonation wave and elastic wave, focusing on the variation in wall pressure of the blasting holes. Using DDNP explosive as the explosive load, blasting tests were conducted on red sandstone specimens with four different water coupling coefficients: 1.20, 1.33, 1.50, and 2.00. The study examines the morphologies of the rock specimens after blasting under these different water coupling coefficients. Additionally, the fractal dimensions of the surface cracks resulting from the blasting were calculated to provide a quantitative evaluation of the extent of rock damage. CT scanning and 3D reconstruction were performed on the post-blasting specimens to visually depict the extent of damage and fractures within the rock. Additionally, the volume fractal dimension and damage degree of the post-blasting specimens are calculated. The findings are then combined with numerical simulation to facilitate auxiliary analysis. The results demonstrate that an increase in the water coupling coefficient leads to a reduction in the peak pressure on the hole wall and the crushing zone, enabling more of the explosion energy to be utilized for crack propagation following the explosion. The specimens exhibited distinct failure patterns, resulting in corresponding changes in fractal dimensions. The simulated pore wall pressure–time curve validated the derived theoretical results, whereas the stress cloud map and explosion energy-time curve demonstrated the buffering effect of the water medium. As the water coupling coefficient increases, the buffering effect of the water medium becomes increasingly prominent.

Fine slag (FS) is an unavoidable by-product of coal gasification. FS, which is a simple heap of solid waste left in the open air, easily causes environmental pollution and has a low resource utilization rate, thereby restricting the development of energy-saving coal gasification technologies. The multiscale analysis of FS performed in this study indicates typical grain size distribution, composition, crystalline structure, and chemical bonding characteristics. The FS primarily contained inorganic and carbon components (dry bases) and exhibited a "three-peak distribution" of the grain size and regular spheroidal as well as irregular shapes. The irregular particles were mainly adsorbed onto the structure and had a dense distribution and multiple pores and folds. The carbon constituents were primarily amorphous in structure, with a certain degree of order and active sites. C 1s XPS spectrum indicated the presence of C–C and C–H bonds and numerous aromatic structures. The inorganic components, constituting 90% of the total sample, were primarily silicon, aluminum, iron, and calcium. The inorganic components contained Si–O-Si, Si–O–Al, Si–O, SO₄²⁻, and Fe–O bonds. Fe 2p XPS spectrum could be deconvoluted into Fe 2p_1/2 and Fe 2p_3/2 peaks and satellite peaks, while Fe existed mainly in the form of Fe(III). The findings of this study will be beneficial in resource utilization and formation mechanism of fine slag in future.

Abstract

Opencast coal mining produces trash of soil and rock containing various minerals, that are usually dumped nearby the abandoned sites which causes severe environmental concern including the production of acid mine drainage (AMD) through oxidation pyrite minerals. The current study entailed assessing the potential production of AMD from an opencast coal mining region in Northeast part of India. In order to have a comprehensive overview of the AMD problem in Makum coalfield, the physico-chemical, geochemical, and petrological characteristics of the coal and overburden (OB) samples collected from the Makum coalfield (Northeast India) were thoroughly investigated. The maceral compositions reveal that coal features all three groups of macerals (liptinite, vitrinite, and inertinite), with a high concentration of liptinite indicating the coal of perhydrous, thereby rendering it more reactive. Pyrite (FeS₂) oxidation kinetics were studied by conducting the aqueous leaching experiments of coal and (OB) samples to interpret the chemical weathering under controlled laboratory conditions of various temperature and time periods, and to replicate the actual mine site leaching. Inductively coupled plasma-optical emission spectroscopy (ICP-OES) was operated to detect the disposal of some precarious elements from coal and OB samples to the leachates during our controlled leaching experiment. The Rare earth element (REE) enrichment in the samples shows the anthropogenic incorporation of the REE in the coal and OB. These experiments reveal the change in conductivity, acid producing tendency, total dissolved solid(TDS), total Iron(Fe) and dissolved Sulfate(SO₄²⁻) ions on progress of the leaching experiments. Moreover, the discharge of FeS₂ via atmospheric oxidation in laboratory condition undergoes a significant growth with the rise of temperature of the reaction systems in the environment and follows pseudo first order kinetics. A bio-remediative strategies is also reported in this paper to mitigate AMD water by employing size-segregated powdered limestone and water hyacinth plant in an indigenously developed site-specific prototype station. Apart from neutralisation of AMD water, this eco-friendly AMD remediation strategy demonstrates a reduction in PHEs concentrations in the treated AMD water.

Novel coal gangue-based persulfate catalyst (CG-FeCl₂) was successfully synthesized by the means of calcinating under nitrogen atmosphere with the addition of ferrous chloride tetrahydrate (FeCl₂·4H₂O). The phase transformation of the prepared materials and gas products during the heating process are thoroughly investigated. It is suggested that ferrous chloride participated in the phase transformation and formed Si-O-Fe bonds. And the main gaseous products are H₂O, H₂, and HCl during the heating process. Besides, the ability of CG-FeCl₂ to activate peroxymonosulfate (PMS) for catalytic degradation of polycyclic aromatic hydrocarbons (PAHs) and phenol was deeply studied. More than 95% of naphthyl, phenanthrene and phenol were removed under optimizied conditions. In addition, ¹O₂, ^·OH, and SO₄^·− were involved in the CG-FeCl₂/PMS system from the free radical scavenging experiment, where ¹O₂ played a major role during the oxidation process. Furthermore, CG-FeCl₂/PMS system exhibited superior stability in a relatively wide pH range and the presence of common anion from related degradation experiments. Overall, the novel CG-FeCl₂ is an efficient and environmentally friendly catalyst, displaying potential application prospect in the field of PAHs and phenol-contaminated wastewater treatment.

Indirect fracturing in the roof of broken soft coal seams has been demonstrated to be a feasible technology. In this work, the No. 5 coal seam in the Hancheng block was taken as the research object. Based on the findings of true triaxial hydraulic fracturing experiments and field pilot under this technology and the cohesive element method, a 3D numerical model of indirect fracturing in the roof of broken soft coal seams was established, the fracture morphology propagation and evolution law under different conditions was investigated, and analysis of main controlling factors of fracture parameters was conducted with the combination weight method, which was based on grey incidence, analytic hierarchy process and entropy weight method. The results show that “士”-shaped fractures, T-shaped fractures, cross fractures, H-shaped fractures, and “干”-shaped fractures dominated by horizontal fractures were formed. Different parameter combinations can form different fracture morphologies. When the coal seam permeability is lower and the minimum horizontal principal stress difference between layers and fracturing fluid injection rate are both larger, it tends to form “士”-shaped fractures. When the coal seam permeability and minimum horizontal principal stress between layers and perforation position are moderate, cross fractures are easily generated. Different fracture parameters have different main controlling factors. Engineering factors of perforation location, fracturing fluid injection rate and viscosity are the dominant factors of hydraulic fracture shape parameters. This study can provide a reference for the design of indirect fracturing in the roof of broken soft coal seams.

Abstract

To analyze the relationship between macro and meso parameters of the gas hydrate bearing coal (GHBC) and to calibrate the meso-parameters, the numerical tests were conducted to simulate the laboratory triaxial compression tests by PFC3D, with the parallel bond model employed as the particle contact constitutive model. First, twenty simulation tests were conducted to quantify the relationship between the macro–meso parameters. Then, nine orthogonal simulation tests were performed using four meso-mechanical parameters in a three-level to evaluate the sensitivity of the meso-mechanical parameters. Furthermore, the calibration method of the meso-parameters were then proposed. Finally, the contact force chain, the contact force and the contact number were examined to investigate the saturation effect on the meso-mechanical behavior of GHBC. The results show that: (1) The elastic modulus linearly increases with the bonding stiffness ratio and the friction coefficient while exponentially increasing with the normal bonding strength and the bonding radius coefficient. The failure strength increases exponentially with the increase of the friction coefficient, the normal bonding strength and the bonding radius coefficient, and remains constant with the increase of bond stiffness ratio; (2) The friction coefficient and the bond radius coefficient are most sensitive to the elastic modulus and the failure strength; (3) The number of the force chains, the contact force, and the bond strength between particles will increase with the increase of the hydrate saturation, which leads to the larger failure strength.

The post-peak characteristics of coal serve as a direct reflection of its failure process and are essential parameters for evaluating brittleness and bursting liability. Understanding the significant factors that influence post-peak characteristics can offer valuable insights for the prevention of coal bursts. In this study, the Synthetic Rock Mass method is employed to establish a numerical model, and the factors affecting coal post-peak characteristics are analyzed from four perspectives: coal matrix mechanical parameters, structural weak surface properties, height-to-width ratio, and loading rate. The research identifies four significant influencing factors: deformation modulus, density of discrete fracture networks, height-to-width ratio, and loading rate. The response and sensitivity of post-peak characteristics to single-factor and multi-factor interactions are assessed. The result suggested that feasible prevention and control measures for coal bursts can be formulated through four approaches: weakening the mechanical properties of coal pillars, increasing the number of structural weak surfaces in coal pillars, reducing the width of coal pillars, and optimizing mining and excavation speed. The efficacy of measures aimed at weakening the mechanical properties of coal is successfully demonstrated through a case study on coal burst prevention using large-diameter borehole drilling.