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Toxicity of respirable coal dust: An overview of origin, chemistry, mechanisms, and possible remedies. 呼吸性煤尘的毒性:来源、化学、机制和可能的补救措施概述。
IF 8.7 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-01 Epub Date: 2026-01-05 DOI: 10.1007/s40789-025-00841-x
Amir Eskanlou, Barbara J Arnold

The prevalence of coal workers' pneumoconiosis (CWP) has been on the rise among U.S. coal miners since the early 2000s and is most pronounced in central Appalachia. Such adverse effects on human health are partly linked to the toxicity of respirable coal mine dust particles. In this review, we present an overview of the characteristics and health effects of the coal dust components, as well as the origin, chemistry, and mechanisms for their potential toxicity. Toxicity of coal mine dust is linked to the surface chemistry and bioactivity of the composing particles, such as coal, crystalline silica (quartz), pyrite, and sometimes diesel particulate matter. Formation of reactive oxygen species, such as •OH on the surface of these particles, contributes to the toxicity of coal dust. Various mechanisms including the metal-micelle coating, polymer-coating, chelation of the surface metal ions, and surface silanization, have been proposed in previous studies for the reduction or inhibition of the toxicity of coal dust particles. However, due to the complexity in surface chemistry of the various minerals and coal, there is no single universal detoxification mechanism for coal dust. One feasible remedy to address the proposed mechanisms of toxicity is the use of chemical additives as wetting agents. Important considerations for this approach include particle size and aging, mineralogy, morphology, chemical composition, solubility, surface charge, and synergistic effects of the composing phases. Additional factors to consider are the solution quality and composition, coal rank, and the potential hazards and costs associated with the chosen chemical agents.

自21世纪初以来,美国煤矿工人尘肺病(CWP)的患病率一直在上升,在阿巴拉契亚中部最为明显。这种对人类健康的不利影响部分与可呼吸煤矿粉尘颗粒的毒性有关。本文综述了煤尘成分的特征和对健康的影响,以及其潜在毒性的来源、化学成分和机制。煤矿粉尘的毒性与组成颗粒的表面化学和生物活性有关,如煤、结晶二氧化硅(石英)、黄铁矿,有时还有柴油颗粒物质。在这些颗粒表面形成活性氧,如•OH,有助于煤尘的毒性。金属胶束包覆、聚合物包覆、表面金属离子螯合、表面硅烷化等多种机制已被提出用于降低或抑制煤尘颗粒的毒性。然而,由于各种矿物和煤的表面化学性质的复杂性,煤尘的解毒机制没有单一的通用机制。一个可行的补救措施,以解决提出的机制的毒性是使用化学添加剂作为润湿剂。该方法的重要考虑因素包括粒度和老化、矿物学、形态、化学成分、溶解度、表面电荷和组成相的协同效应。其他需要考虑的因素是溶液的质量和组成、煤的等级以及与所选化学剂相关的潜在危害和成本。
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引用次数: 0
Field study demonstrates inordinate respirable dust generation during continuous mining in rock versus coal strata. 现场研究表明,岩石与煤层连续开采时产生的可呼吸性粉尘量过大。
IF 8.7 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2025-01-01 Epub Date: 2025-11-10 DOI: 10.1007/s40789-025-00832-y
F Animah, E Sarver

In modern room and pillar coal mines, the coal is produced by continuous miner (CM) machines. The CM is used to mine the coal seam by continuously cutting at a vertical face. Depending on the seam thickness, quality, and geotechnical properties, some roof, floor, or interburden rock is often cut along with coal. While CMs can be highly efficient in terms of production rates, they can also generate high concentrations of dust. Dust poses both safety (i.e., explosibility) and respiratory health hazards. Previous research has generally indicated that CM cutting in rock yields much more respirable dust than cutting in coal. Although in-mine studies that directly evaluate this trend have not been reported, understanding relative dust generation from different geologic strata could have important implications. In many mines, for instance, the rock is the primary source of respirable silica and silicates, which can be especially hazardous. To mitigate dust generated by the CM, mines use a variety of controls including ventilation, on-board scrubber systems, and water sprays. However, the relative effects of controls on dust generated from different strata have also not been widely investigated. In this field study, respirable dust sampling was conducted in the intake and return airways of an active CM during periods when the cutting was targeted either primarily at the coal seam (bottom cut) or primarily at the roof rock (top cut) in a standard entry. Results indicated that CM cutting in rock strata generated somewhat finer particles and respirable dust concentrations that were 2.1-26 times higher than cutting in coal strata, although the coal height being cut was about 2.2-2.9 times greater than the rock height. Additionally, the analysis of dust mineralogy generally showed a mix of both carbonaceous (coal) and mineral particles regardless of the target strata. Furthermore, the study was designed to evaluate the effects of two typical combinations of CM scrubber and ventilation conditions, and increased pressure and volume through the CM water sprays. In general, operation of the scrubber tended to yield lower and somewhat finer respirable dust concentrations, irrespective of the strata the CM was targeting. Increased water spray pressure and volume sometimes appeared to reduce the respirable dust concentration when the CM was targeting the roof rock, but no effect could be discerned when the CM was targeting the coal seam.

在现代房式和柱式煤矿中,煤是由连续采煤机生产的。CM是采用垂直工作面连续采煤法开采煤层。根据煤层厚度、质量和岩土力学性质的不同,一些顶板、底板或层间岩常随煤一起被开采。虽然CMs在生产速度方面效率很高,但它们也会产生高浓度的灰尘。粉尘对安全(即易爆性)和呼吸系统健康都有危害。以往的研究普遍表明,岩石中的CM切割产生的可吸入粉尘比煤炭中的CM切割产生的可吸入粉尘要多得多。虽然直接评估这一趋势的矿内研究尚未报道,但了解不同地质地层的相对粉尘产生可能具有重要意义。例如,在许多矿山中,岩石是可吸入二氧化硅和硅酸盐的主要来源,这可能特别危险。为了减少CM产生的粉尘,地雷使用各种控制措施,包括通风、机载洗涤系统和喷水。然而,控制不同地层产生的粉尘的相对效果也没有得到广泛的研究。在本现场研究中,在切割主要针对煤层(底部切割)或主要针对标准巷道的顶板岩石(顶部切割)期间,在活动CM的进气道和回气道中进行了可呼吸性粉尘采样。结果表明,岩层中CM切割产生的颗粒和呼吸性粉尘浓度比煤层切割产生的颗粒和呼吸性粉尘浓度高2.1 ~ 26倍,但切割的煤高约为岩石高度的2.2 ~ 2.9倍。此外,粉尘矿物学分析通常显示碳质(煤)和矿物颗粒的混合物,而不管目标地层如何。此外,本研究旨在评估CM洗涤器和通风条件的两种典型组合,以及通过CM水喷雾增加压力和体积的效果。一般来说,洗涤器的操作倾向于产生更低和更细的呼吸性粉尘浓度,而不考虑CM所针对的地层。增大喷水压力和喷水体积有时能降低煤层呼吸性粉尘浓度,但对煤层呼吸性粉尘浓度无明显影响。
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引用次数: 0
Evaluating fracture volume loss during production process by comparative analysis of initial and second flowback data. 通过对比分析第一次和第二次返排数据,评价生产过程中裂缝体积损失。
IF 6.9 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2025-01-01 Epub Date: 2025-04-29 DOI: 10.1007/s40789-025-00754-9
Chong Cao, Tamer Moussa, Hassan Dehghanpour

The fracture volume is gradually changed with the depletion of fracture pressure during the production process. However, there are few flowback models available so far that can estimate the fracture volume loss using pressure transient and rate transient data. The initial flowback involves producing back the fracturing fluid after hydraulic fracturing, while the second flowback involves producing back the preloading fluid injected into the parent wells before fracturing of child wells. The main objective of this research is to compare the initial and second flowback data to capture the changes in fracture volume after production and preload processes. Such a comparison is useful for evaluating well performance and optimizing fracturing operations. We construct rate-normalized pressure (RNP) versus material balance time (MBT) diagnostic plots using both initial and second flowback data (FBi and FBs, respectively) of six multi-fractured horizontal wells completed in Niobrara and Codell formations in DJ Basin. In general, the slope of RNP plot during the FBs period is higher than that during the FBi period, indicating a potential loss of fracture volume from the FBi to the FBs period. We estimate the changes in effective fracture volume (V ef) by analyzing the changes in the RNP slope and total compressibility between these two flowback periods. V ef during FBs is in general 3%-45% lower than that during FBi. We also compare the drive mechanisms for the two flowback periods by calculating the compaction-drive index (CDI), hydrocarbon-drive index (HDI), and water-drive index (WDI). The dominant drive mechanism during both flowback periods is CDI, but its contribution is reduced by 16% in the FBs period. This drop is generally compensated by a relatively higher HDI during this period. The loss of effective fracture volume might be attributed to the pressure depletion in fractures, which occurs during the production period and can extend 800 days.

在生产过程中,裂缝体积随着裂缝压力的减小而逐渐变化。然而,到目前为止,很少有可用的反排模型可以利用压力瞬态和速率瞬态数据来估计裂缝体积损失。第一次返排是在水力压裂后将压裂液排回,而第二次返排是在子井压裂前将注入母井的预压液排回。本研究的主要目的是比较第一次和第二次反排数据,以捕获生产和预压过程后裂缝体积的变化。这样的对比对于评价井的性能和优化压裂作业非常有用。利用在DJ盆地Niobrara和Codell地层完成的6口多裂缝水平井的初始和二次返排数据(分别为FBi和FBs),构建了速率归一化压力(RNP)与物质平衡时间(MBT)诊断图。总的来说,RNP图在FBs期间的斜率大于FBi期间的斜率,表明从FBi到FBs期间可能会损失裂缝体积。我们通过分析两段反排期间RNP斜率和总压缩性的变化来估计有效裂缝体积(V ef)的变化。FBs期间的V值一般比FBi期间低3%-45%。通过计算压实驱力指数(CDI)、油气驱力指数(HDI)和水驱力指数(WDI),对两个反排周期的驱力机制进行了比较。两个反排阶段的主要驱动机制都是CDI,但在FBs阶段,CDI的贡献减少了16%。在此期间,这种下降通常由相对较高的HDI来补偿。有效裂缝体积的损失可能是由于裂缝中的压力耗尽,这种情况发生在生产期间,并且可以持续800天。
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引用次数: 0
Coal ash resources and potential for rare earth element production in the United States 美国的煤灰资源和稀土元素生产潜力
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-09-17 DOI: 10.1007/s40789-024-00710-z
Robert C. Reedy, Bridget R. Scanlon, Davin A. Bagdonas, James C. Hower, Dennis James, J. Richard Kyle, Kristine Uhlman

The renewable energy industry is heavily reliant on rare earth elements, underscoring the need to develop resources and production. The objective of this work was to estimate coal ash resources and potential for extraction of rare earth elements using data for the US. Data on spatiotemporal variability in coal ash resources and disposition were compiled from various federal databases and rare earth elements levels in ash were compiled from the literature. Results show that ~ 52 gigatons (Gt) of coal were produced in the US (1950–2021). Power plants account for most of the coal use, particularly since 1980. Coal ash (5.3 Gt) represents a mean of 10% of coal by weight, ranging from 6% for subbituminous to 14% for lignite. About 70% of coal ash is potentially accessible for rare earth element extraction (1985–2021) and was disposed in landfills and ponds with the remaining coal ash used onsite or sold. Median values of total rare earth elements are much higher in ashes derived from the Appalachian Basin (median 431 mg/kg) than in the Illinois (282 mg/kg) or Powder River basins (264 mg/kg). Considering the market value of rare earth oxides, potentially accessible ash volumes, and percent rare earth element extraction (30% Appalachian and Illinois Basins; 70% Powder River Basin) results in an estimated $8.4 billion value. This study provides fundamental information on accessible coal ash resources in the US, linkages to coal sources, and preliminary estimates of rare earth element levels for future development within the US.

可再生能源产业严重依赖稀土元素,因此需要开发资源和生产稀土元素。这项工作的目的是利用美国的数据估算煤灰资源和提取稀土元素的潜力。煤灰资源和处置的时空变化数据来自各种联邦数据库,煤灰中的稀土元素含量则来自文献。结果显示,美国(1950-2021 年)的煤炭产量约为 52 千兆吨 (Gt)。发电厂占煤炭使用量的大部分,特别是自 1980 年以来。煤灰(5.3 千兆吨)平均占煤炭重量的 10%,从亚烟煤的 6% 到褐煤的 14% 不等。约 70% 的煤灰可用于提取稀土元素(1985-2021 年),这些煤灰被丢弃在垃圾填埋场和池塘中,其余的煤灰在现场使用或出售。阿巴拉契亚盆地煤灰中稀土元素总量的中值(中值为 431 毫克/千克)远高于伊利诺斯盆地(282 毫克/千克)或粉河盆地(264 毫克/千克)。考虑到稀土氧化物的市场价值、可能获取的煤灰量以及稀土元素提取率(阿巴拉契亚盆地和伊利诺斯盆地占 30%;粉河盆地占 70%),估计价值为 84 亿美元。本研究提供了有关美国可获得的煤灰资源、与煤炭来源的联系以及美国未来开发的稀土元素含量初步估算的基本信息。
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引用次数: 0
Ecological environment quality assessment of coal mining cities based on GEE platform: A case study of Shuozhou, China 基于 GEE 平台的煤矿城市生态环境质量评估:中国朔州案例研究
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-09-17 DOI: 10.1007/s40789-024-00723-8
Linghua Duo, Junqi Wang, Yongping Zhong, Chengqing Jiang, Yaoyao Chen, Xiaofei Guo

Shuozhou is a typical coal mining city, and the Pingshuo Antaibao open-pit coal mine in its area is one of the largest open-pit coal mines in China. The mining of coal resources is an important part of ensuring national energy security, and at the same time, it inevitably has a certain impact on the ecology, such as coal dust generated by open-pit mining will affect air quality, soil, water and vegetation. It is of great significance to explore the temporal and spatial variation of ecological environment quality in coal mining cities for ecological protection and sustainable social and economic development. Based on the Google Earth Engine (GEE) platform, this paper combines the index-based coal dust index (ICDI) and Remote Sensing Ecological Index (RSEI) models to construct an improved RSEI (IRSEI) that can reflect coal mining cities. This paper explores the spatial–temporal evolution characteristics and spatial correlation of ecological environment quality in Shuozhou from 2000 to 2020. The results showed that the average value of IRSEI in Shuozhou was between 0.262 and 0.418, and the overall change showed an upward trend. The growth areas of ecological environment quality are mainly located in the eastern and southwestern areas with good vegetation growth, and these regions have vigorously implemented the Northern Shelter Forest Project, afforestation and greening projects, implemented the forest resource management and protection responsibility system, promoted the construction of ecological civilization, and significantly improved the ecological environment. While the declining areas are mainly located in the central and southern regions where mining activities and human activities are more intensive. The IRSEI in the study area showed a significant spatial positive correlation, and the agglomeration types of the spatial pattern were mainly high-high and low-low agglomeration types, with the high-high agglomeration types mainly distributed in the eastern and southwestern regions, and the low-low agglomeration types distributed in the northern and south-central regions of the study area. The trend of low and low agglomeration has decreased, which further proves that the ecological restoration measures taken by the government, such as returning farmland to forests, integrating protection and restoration of mountains, waters, forests, fields, lakes, grasslands, and sands, controlling soil erosion, and stage wise reclamation of coal mining subsidence areas, have improved the ecological environment quality of Shuozhou. This study provides a reference for understanding the spatiotemporal changes of the ecological environment of coal mining cities, and is conducive to formulating appropriate ecological protection strategies.

朔州是典型的煤矿城市,其境内的平朔安太堡露天煤矿是中国最大的露天煤矿之一。煤炭资源的开采是保障国家能源安全的重要一环,同时也不可避免地对生态环境造成一定影响,如露天开采产生的煤尘会对空气质量、土壤、水体和植被造成影响。探讨煤矿城市生态环境质量的时空变化,对生态保护和社会经济可持续发展具有重要意义。本文基于谷歌地球引擎(GEE)平台,结合基于指数的煤尘指数(ICDI)和遥感生态指数(RSEI)模型,构建了能够反映煤矿城市的改进型遥感生态指数(IRSEI)。本文探讨了 2000-2020 年朔州市生态环境质量的时空演变特征和空间相关性。结果表明,朔州市 IRSEI 平均值在 0.262 至 0.418 之间,总体变化呈上升趋势。生态环境质量增长区主要分布在东部和西南部植被生长较好的地区,这些地区大力实施北方防护林工程、造林绿化工程,落实森林资源管护责任制,推进生态文明建设,生态环境得到明显改善。而衰退区主要分布在采矿活动和人类活动较为密集的中南部地区。研究区的 IRSEI 呈显著的空间正相关,空间格局的集聚类型主要为高-高集聚类型和低-低集聚类型,高-高集聚类型主要分布在研究区的东部和西南部地区,低-低集聚类型分布在研究区的北部和中南部地区。低-低聚集趋势有所减弱,进一步证明了政府采取的退耕还林、山水林田湖草沙一体化保护修复、水土流失治理、采煤沉陷区阶段性复垦等生态修复措施改善了朔州的生态环境质量。本研究为了解煤矿城市生态环境的时空变化提供了参考,有利于制定相应的生态保护策略。
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引用次数: 0
Study on signal characteristics of burst tendency coal under different loading rates 不同装载率下爆倾向煤的信号特征研究
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-22 DOI: 10.1007/s40789-024-00724-7
Chao Zhou, Xueqiu He, Dazhao Song, Zhenlei Li, Huakang Yang, Yang Liu, Lei Guo

In order to study the mechanics, acoustic emission (AE) and electromagnetic emission (EME) response law of bursting liability coal at different loading rates, uniaxial compression tests were carried out on coal mass from Konggu Coal Mine. The corresponding relations among mechanical properties, AE and EME signals in the process of coal failure under loading were analyzed, and the energy evolution law of coal failure with bursting liability under loading rate was discussed. The results show that within a certain range of loading rate, the higher the loading rate, the higher the compressive strength and peak load of bursting liability coal, and the shorter the time for coal to reach the peak load. Under different loading rates, the mechanics, AE and EME signals of coal samples can be well corresponded. When the loading rate is low, the number of blocks destroyed of coal sample is large and the block size is relatively small, and the blocks are mainly scattered around the test platform. When the loading rate is high, the number of damaged blocks is relatively small and the block size is relatively large, and the blocks are far away from the test bench. When loading at a low rate, the internal cracks in coal can be fully developed and connected, and the energy release rate is relatively uniform in the process of loading and failure of coal sample. In the case of high loading rate, the energy release rate of coal sample in the loading process is much smaller than that in the moment of failure. Combining the above test results with the actual situation of the working face, it can be concluded that the total energy stored in the coal of fast mining increases and the threshold of impact decreases compared with that of slow mining. Therefore, under the disturbance of external dynamic load, rapid mining is more likely to induce rock burst.

为了研究不同加载速率下爆裂责任煤的力学、声发射(AE)和电磁发射(EME)响应规律,对孔古煤矿的煤块进行了单轴压缩试验。分析了加载条件下煤体破坏过程中力学性能、AE 和 EME 信号之间的对应关系,探讨了加载速率下爆破责任煤体破坏的能量演化规律。结果表明,在一定加载速率范围内,加载速率越大,爆破责任煤的抗压强度和峰值载荷越高,煤达到峰值载荷的时间越短。在不同加载速率下,煤样的力学信号、AE 信号和 EME 信号均能很好地对应。当加载速率较低时,煤样破坏的块数较多,块体尺寸相对较小,块体主要分散在测试平台周围。当加载速率较高时,损坏的煤块数量相对较少,煤块尺寸相对较大,煤块离试验台较远。当加载速率较低时,煤的内部裂缝能够充分发育并连通,煤样在加载和破坏过程中能量释放速率相对均匀。在加载速率较高的情况下,煤样在加载过程中的能量释放速率远小于破坏瞬间的能量释放速率。结合上述试验结果和工作面的实际情况,可以得出结论:与慢速开采相比,快速开采时煤炭中储存的总能量增加,冲击阈值降低。因此,在外部动载荷的扰动下,快速开采更容易诱发岩爆。
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引用次数: 0
Image-based quantitative probing of 3D heterogeneous pore structure in CBM reservoir and permeability estimation with pore network modeling 基于图像的煤层气储层三维异质孔隙结构定量探测以及孔隙网络模型的渗透率估算
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-20 DOI: 10.1007/s40789-024-00722-9
Peng Liu, Yulong Zhao, Zhengduo Zhao, Huiming Yang, Baisheng Nie, Hengyi He, Quangui Li, Guangjie Bao

Coalbed methane (CBM) recovery is attracting global attention due to its huge reserve and low carbon burning benefits for the environment. Fully understanding the complex structure of coal and its transport properties is crucial for CBM development. This study describes the implementation of mercury intrusion and μ-CT techniques for quantitative analysis of 3D pore structure in two anthracite coals. It shows that the porosity is 7.04%–8.47% and 10.88%–12.11%, and the pore connectivity is 0.5422–0.6852 and 0.7948–0.9186 for coal samples 1 and 2, respectively. The fractal dimension and pore geometric tortuosity were calculated based on the data obtained from 3D pore structure. The results show that the pore structure of sample 2 is more complex and developed, with lower tortuosity, indicating the higher fluid deliverability of pore system in sample 2. The tortuosity in three-direction is significantly different, indicating that the pore structure of the studied coals has significant anisotropy. The equivalent pore network model (PNM) was extracted, and the anisotropic permeability was estimated by PNM gas flow simulation. The results show that the anisotropy of permeability is consistent with the slice surface porosity distribution in 3D pore structure. The permeability in the horizontal direction is much greater than that in the vertical direction, indicating that the dominant transportation channel is along the horizontal direction of the studied coals. The research results achieve the visualization of the 3D complex structure of coal and fully capture and quantify pore size, connectivity, curvature, permeability, and its anisotropic characteristics at micron-scale resolution. This provides a prerequisite for the study of mass transfer behaviors and associated transport mechanisms in real pore structures.

煤层气储量巨大,低碳燃烧对环境有益,因此煤层气回收备受全球关注。充分了解煤的复杂结构及其传输特性对于煤层气开发至关重要。本研究介绍了采用汞侵入和μ-CT技术对两种无烟煤的三维孔隙结构进行定量分析。结果表明,煤样 1 和煤样 2 的孔隙度分别为 7.04%-8.47% 和 10.88%-12.11%,孔隙连通性分别为 0.5422-0.6852 和 0.7948-0.9186。根据三维孔隙结构获得的数据计算了分形维数和孔隙几何迂回度。结果表明,煤样 2 的孔隙结构更复杂、更发达,孔隙几何扭曲度更低,这表明煤样 2 的孔隙系统具有更高的流体输送能力。三维方向的曲折度差异显著,表明所研究煤炭的孔隙结构具有明显的各向异性。提取了等效孔隙网络模型(PNM),并通过 PNM 气体流动模拟估算了各向异性渗透率。结果表明,渗透率的各向异性与三维孔隙结构中的切片表面孔隙度分布一致。水平方向的渗透率远大于垂直方向的渗透率,表明所研究煤炭的主要运输通道是沿水平方向的。该研究成果实现了煤炭三维复杂结构的可视化,在微米级分辨率下全面捕捉并量化了孔隙尺寸、连通性、曲率、渗透率及其各向异性特征。这为研究实际孔隙结构中的传质行为和相关传输机制提供了先决条件。
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引用次数: 0
Spectral signatures of solvent-extracted macromolecules in Indian coals of different rank: Insights from fluorescence excitation-emission matrix 不同等级印度煤炭中溶剂萃取大分子的光谱特征:荧光激发-发射矩阵的启示
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-12 DOI: 10.1007/s40789-024-00721-w
Archchi Sarkar, Uttam Kumar Bhui, Krittibas Das, Sudip Bhattacharyya, Jitendra Kumar, Darshan Halari

Solvent-extracted fractions of six Indian coal samples of different ranks were investigated using multiple geochemical, petrological and spectroscopic proxies and an attempt was made to indicate possible fingerprint regions for different polycyclic aromatic hydrocarbons (PAH) with the help of excitation-emission matrix (EEM). In this study, for the very first time, the influence of rank and maturation of organic matter in the characterisation of coal solvent-extracts from Indian coals were perceived from the viewpoint of fluorescence EEM. Vitrinite reflectance (VRo) values were used to determine the general ranks of the original coal samples viz. lignite, subbituminous, bituminous and anthracite. Different fluorescence peak regions corresponding to different fused aromatic ring (FAR) systems were delineated using the EEM and their indicative depositional environments could be inferred. Our observations indicate that solvent-extracted fractions of low rank coals comprise of a larger number of shorter carbon chains compared to the other samples. For the low rank coal samples, the solvent-extracts show a strong humic influence and the presence of smaller PAH rings while for the medium rank coals, the extracted fractions tend to show a more bimodal distribution of PAHs, possibly comprising of different sized PAHs. Higher fluorescence sensitivity and quick response of smaller PAHs impart a singular centralised region in the EEM for the low rank coal samples while interference in the fluorescence of differently sized PAHs indicate a multimodal distribution of the fluorophores in the medium rank coals. The high rank coal used in this study shows a bimodal distribution with very low intensity of the peaks, indicating the low abundance of extractable macromolecules, possibly as a result of deformation.

利用多种地球化学、岩石学和光谱学代用指标对六种不同等级的印度煤炭样品的溶剂萃取馏分进行了研究,并尝试借助激发-发射矩阵(EEM)来指出不同多环芳烃(PAH)的可能指纹区域。在这项研究中,首次从荧光 EEM 的角度研究了有机物的等级和成熟度对印度煤炭溶剂萃取物特征的影响。荧光反射率(VRo)值用于确定原始煤样的一般等级,即褐煤、亚烟煤、烟煤和无烟煤。利用电子显微镜(EEM)划分了与不同熔融芳香环(FAR)系统相对应的不同荧光峰区,并推断出其指示性沉积环境。我们的观察结果表明,与其他煤样相比,溶剂萃取的低阶煤馏分含有更多的短碳链。对于低阶煤炭样品,溶剂萃取物显示出强烈的腐殖质影响和较小的多环芳烃环的存在,而对于中阶煤炭,萃取馏分往往显示出更多的多环芳烃的双峰分布,可能包括不同大小的多环芳烃。较小的多环芳烃具有较高的荧光灵敏度和快速反应能力,因此低阶煤样品的 EEM 中会出现一个单一的集中区域,而不同大小的多环芳烃的荧光干扰则表明中阶煤中的荧光团呈多模式分布。本研究中使用的高阶煤显示出峰值强度很低的双峰分布,表明可提取的大分子含量很低,这可能是变形的结果。
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引用次数: 0
Rate transient analysis for multilateral horizontal well in natural gas hydrate: superposition principle and reciprocity 天然气水合物中多边水平井的速率瞬态分析:叠加原理和互易性
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-11 DOI: 10.1007/s40789-024-00720-x
Tianbi Ma, Hongyang Chu, Jiawei Li, Jingxuan Zhang, Yubao Gao, Weiyao Zhu, W. John Lee

Due to high energy density, clean combustion products and abundant resources, natural gas hydrates (NGHs) have been regarded as an important clean energy source with the potential for large-scale development and utilization. However, pilot tests in NGHs show that their production rates are far below commercial needs. Multilateral well technology may lead to a solution to this problem because it can dramatically expand the drainage area of production wells. This paper presents the practical rate transient analysis for multilateral horizontal wells in NGHs. In developing solution to the diffusivity equation of multilateral horizontal wells in NGHs, the superposition principle and reciprocity are applied. We wrote the governing equation in cylindrical coordinates to describe the NGH flow process. We used the moving boundaries and dissociation coefficients to model the solid-to-gas transition process in hydrates. To obtain solutions for flow in hydrate reservoirs, we used Laplace transforms and the Stehfest numerical inversion method. Superposition principle and Gaussian elimination are applied to obtain the desired solution for multilateral horizontal wells. We validated our proposed model with a commercial numerical simulator. By performing sensitivity analyses, effects on production behavior of the number of branches, dissociation coefficient, radius of the region with dissociated hydrate, and dispersion ratio are determined. A synthetic case study is conducted to show the typical production behaviors.

天然气水合物(NGHs)具有能量密度高、燃烧产物清洁、资源丰富等特点,一直被视为一种重要的清洁能源,具有大规模开发和利用的潜力。然而,天然气水合物的试点测试表明,其生产率远远低于商业需求。多边井技术可以显著扩大生产井的排水面积,因此有可能解决这一问题。本文介绍了 NGHs 中多边水平井的实用速率瞬态分析。在求解 NGHs 中多边水平井的扩散方程时,应用了叠加原理和互易原理。我们在圆柱坐标中编写了控制方程,以描述 NGH 的流动过程。我们使用移动边界和解离系数来模拟水合物中固态到气态的转变过程。为了获得水合物储层中的流动解,我们使用了拉普拉斯变换和 Stehfest 数值反演方法。应用叠加原理和高斯消去法获得多边水平井的理想解。我们利用商业数值模拟器验证了我们提出的模型。通过进行敏感性分析,确定了分支数量、解离系数、解离水合物区域半径和分散比对生产行为的影响。还进行了一项合成案例研究,以展示典型的生产行为。
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引用次数: 0
Investigation of ground subsidence response to an unconventional longwall panel layout 非常规长壁面板布局的地面沉降响应研究
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-06 DOI: 10.1007/s40789-024-00719-4
Pengfei Wang, Zhuang Zhu, Linfeng Guo, Huixian Wang, Yue Qu, Yaoxiong Zhang, Linwei Wang, Hua Wang

Ground subsidence caused by extraction of longwall panels has always been a great concern all over the world. Conventional longwall mining system (CLMS) gives rise to wavy subsidence causing great damage to surface structures. A coal mine in Shanxi, China, utilizes a split-level longwall layout (SLL) for a sub-horizontal No. 8 coal seam to improve the cavability of mudstone interlayer and top coal. This layout, however, also produced unexpectedly favorable surface subsidence. Subsidence of No. 6 and No. 8 longwall panels was monitored while mining was conducted. Field instrumentation and numerical simulation were carried out. It is demonstrated that an asymmetric subsidence profile with stepped subsidence and cracks occurred on the tailgate side but relatively mild and smooth deformation on the other. Due to elimination of conventional parallelepiped gate pillar, No. 6 and No. 8 gobs were connected. Extraction of two SLL panels acted as one supercritical panel. The maximum possible subsidence was reached which lowers the likelihood of potential future secondary subsidence as underground gob fractures and voids have closed. Therefore, SLL is more favorable for post-mining land reuse as gobs are more consolidated underground.

长壁开采造成的地面沉降一直是全世界都非常关注的问题。传统的长壁开采系统(CLMS)会产生波浪形沉降,对地表结构造成巨大破坏。中国山西的一个煤矿在 8 号煤层采用了分层长壁布置(SLL),以改善泥岩夹层和顶煤的可采性。然而,这种布局也产生了意想不到的地表下沉。在开采过程中,对 6 号和 8 号长壁面板的下沉进行了监测。进行了现场仪器测量和数值模拟。结果表明,不对称下沉剖面在尾板一侧出现了阶梯状下沉和裂缝,而在另一侧则出现了相对温和、平滑的变形。由于取消了传统的平行管状闸门支柱,6 号和 8 号闸门被连接起来。两个 SLL 面板的抽取就像一个超临界面板。由于地下岩块裂缝和空隙已经闭合,因此达到了最大可能的下沉量,降低了未来可能出现的二次下沉的可能性。因此,SLL 更有利于开采后的土地再利用,因为地下岩块更加坚固。
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引用次数: 0
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International Journal of Coal Science & Technology
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