首页 > 最新文献

Nano Futures最新文献

英文 中文
Uncertainty quantification and prediction for mechanical properties of graphene aerogels via Gaussian process metamodels 基于高斯过程超模型的石墨烯气凝胶力学性能不确定度量化与预测
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2021-11-23 DOI: 10.1088/2399-1984/ac3c8f
Bowen Zheng, Zeyu Zheng, Grace X. Gu
Graphene aerogels (GAs), a special class of 3D graphene assemblies, are well known for their exceptional combination of high strength, lightweightness, and high porosity. However, due to microstructural randomness, the mechanical properties of GAs are also highly stochastic, an issue that has been observed but insufficiently addressed. In this work, we develop Gaussian process metamodels to not only predict important mechanical properties of GAs but also quantify their uncertainties. Using the molecular dynamics simulation technique, GAs are assembled from randomly distributed graphene flakes and spherical inclusions, and are subsequently subject to a quasi-static uniaxial tensile load to deduce mechanical properties. Results show that given the same density, mechanical properties such as the Young’s modulus and the ultimate tensile strength can vary substantially. Treating density, Young’s modulus, and ultimate tensile strength as functions of the inclusion size, and using the simulated GA results as training data, we build Gaussian process metamodels that can efficiently predict the properties of unseen GAs. In addition, statistically valid confidence intervals centered around the predictions are established. This metamodel approach is particularly beneficial when the data acquisition requires expensive experiments or computation, which is the case for GA simulations. The present research quantifies the uncertain mechanical properties of GAs, which may shed light on the statistical analysis of novel nanomaterials of a broad variety.
石墨烯气凝胶(GAs)是一类特殊的3D石墨烯组件,以其高强度、轻量化和高孔隙率的独特组合而闻名。然而,由于微观结构的随机性,气体的力学性能也是高度随机的,这是一个已经被观察到但尚未充分解决的问题。在这项工作中,我们建立了高斯过程元模型,不仅可以预测气体的重要力学性能,还可以量化它们的不确定性。利用分子动力学模拟技术,将随机分布的石墨烯薄片和球形夹杂物组装在一起,然后施加准静态单轴拉伸载荷来推断其力学性能。结果表明,在相同的密度下,杨氏模量和极限抗拉强度等力学性能会发生很大的变化。将密度、杨氏模量和极限抗拉强度作为夹杂物大小的函数,并将模拟GA结果作为训练数据,建立高斯过程元模型,该模型可以有效地预测未见气体的性质。此外,建立了以预测为中心的统计有效置信区间。当数据采集需要昂贵的实验或计算时,这种元模型方法特别有用,这就是遗传算法模拟的情况。本研究量化了气体的不确定力学性能,这可能有助于对各种新型纳米材料的统计分析。
{"title":"Uncertainty quantification and prediction for mechanical properties of graphene aerogels via Gaussian process metamodels","authors":"Bowen Zheng, Zeyu Zheng, Grace X. Gu","doi":"10.1088/2399-1984/ac3c8f","DOIUrl":"https://doi.org/10.1088/2399-1984/ac3c8f","url":null,"abstract":"Graphene aerogels (GAs), a special class of 3D graphene assemblies, are well known for their exceptional combination of high strength, lightweightness, and high porosity. However, due to microstructural randomness, the mechanical properties of GAs are also highly stochastic, an issue that has been observed but insufficiently addressed. In this work, we develop Gaussian process metamodels to not only predict important mechanical properties of GAs but also quantify their uncertainties. Using the molecular dynamics simulation technique, GAs are assembled from randomly distributed graphene flakes and spherical inclusions, and are subsequently subject to a quasi-static uniaxial tensile load to deduce mechanical properties. Results show that given the same density, mechanical properties such as the Young’s modulus and the ultimate tensile strength can vary substantially. Treating density, Young’s modulus, and ultimate tensile strength as functions of the inclusion size, and using the simulated GA results as training data, we build Gaussian process metamodels that can efficiently predict the properties of unseen GAs. In addition, statistically valid confidence intervals centered around the predictions are established. This metamodel approach is particularly beneficial when the data acquisition requires expensive experiments or computation, which is the case for GA simulations. The present research quantifies the uncertain mechanical properties of GAs, which may shed light on the statistical analysis of novel nanomaterials of a broad variety.","PeriodicalId":54222,"journal":{"name":"Nano Futures","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2021-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46786747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Two-terminal vertical thyristor using Schottky contact emitter to improve thermal instability 双端垂直晶闸管采用肖特基接触发射极改善热不稳定性
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2021-11-22 DOI: 10.1088/2399-1984/ac3bd4
Min-Won Kim, Ji-Hun Kim, Jun-Seong Park, Byoung-Seok Lee, S. Yoo, T. Shim, Jea‐Gun Park
In a two-terminal-electrode vertical thyristor, the latch-up and latch-down voltages are decreased when the memory operation temperature of the memory cells increases, resulting in a severe reliability issue (i.e. thermal instability). This study fundamentally solves the thermal instability of a vertical-thyristor by achieving a cross-point memory-cell array using a vertical-thyristor with a structure of vertical n++-emitter, p+-base, n+-base, and p++-emitter. The vertical-thyristor using a Schottky contact metal emitter instead of an n++-Si emitter significantly improves the thermal stability between 293 K and 373 K. Particularly, the improvement degree of the thermal stability is increased significantly with the use of the Schottky contact metal work function. Because the thermal instability (i.e. degree of latch-up voltage decrement vs. memory operation temperature) decreases with an increase in the Schottky contact metal work function, the dependency of the forward current density between the Schottky contact metal and p+-Si based on the memory operation temperature reduces with increase in the Schottky contact metal work function. Consequently, a higher Schottky contact metal work function produces a higher degree of improvement in the thermal stability, i.e. W (4.50 eV), Ti (4.33 eV), Ta (4.25 eV), and Al (4.12 eV). Further research on the fabrication process of a Schottky contact metal emitter vertical-thyristor is essential for the fabrication of a 3D cross-point memory-cell.
在双端电极垂直晶闸管中,当存储器单元的存储器操作温度增加时,锁存上电压和锁存下电压降低,导致严重的可靠性问题(即热不稳定性)。本研究通过使用具有垂直n++发射极、p++基极、n++基极和p++发射极结构的垂直晶闸管实现交叉点存储单元阵列,从根本上解决了垂直晶闸晶体管的热不稳定性。使用肖特基接触金属发射极代替n++-Si发射极的垂直晶闸管显著提高了293K和373K之间的热稳定性。特别地,使用肖特基触点金属功函数显著提高了热稳定性的改善程度。由于热不稳定性(即锁存电压递减程度与存储器操作温度)随着肖特基接触金属功函数的增加而降低,因此肖特基接触金属与p+-Si之间的正向电流密度基于存储器操作温度的依赖性随着肖特基接触金属功函数增加而降低。因此,更高的肖特基接触金属功函数在热稳定性方面产生更高程度的改善,即W(4.50eV)、Ti(4.33eV),Ta(4.25eV)和Al(4.12eV)。进一步研究肖特基接触金属发射极垂直晶闸管的制造工艺对于制造3D交叉点存储单元至关重要。
{"title":"Two-terminal vertical thyristor using Schottky contact emitter to improve thermal instability","authors":"Min-Won Kim, Ji-Hun Kim, Jun-Seong Park, Byoung-Seok Lee, S. Yoo, T. Shim, Jea‐Gun Park","doi":"10.1088/2399-1984/ac3bd4","DOIUrl":"https://doi.org/10.1088/2399-1984/ac3bd4","url":null,"abstract":"In a two-terminal-electrode vertical thyristor, the latch-up and latch-down voltages are decreased when the memory operation temperature of the memory cells increases, resulting in a severe reliability issue (i.e. thermal instability). This study fundamentally solves the thermal instability of a vertical-thyristor by achieving a cross-point memory-cell array using a vertical-thyristor with a structure of vertical n++-emitter, p+-base, n+-base, and p++-emitter. The vertical-thyristor using a Schottky contact metal emitter instead of an n++-Si emitter significantly improves the thermal stability between 293 K and 373 K. Particularly, the improvement degree of the thermal stability is increased significantly with the use of the Schottky contact metal work function. Because the thermal instability (i.e. degree of latch-up voltage decrement vs. memory operation temperature) decreases with an increase in the Schottky contact metal work function, the dependency of the forward current density between the Schottky contact metal and p+-Si based on the memory operation temperature reduces with increase in the Schottky contact metal work function. Consequently, a higher Schottky contact metal work function produces a higher degree of improvement in the thermal stability, i.e. W (4.50 eV), Ti (4.33 eV), Ta (4.25 eV), and Al (4.12 eV). Further research on the fabrication process of a Schottky contact metal emitter vertical-thyristor is essential for the fabrication of a 3D cross-point memory-cell.","PeriodicalId":54222,"journal":{"name":"Nano Futures","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2021-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42429776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Thermal rectification on asymmetric suspended graphene nanomesh devices 不对称悬浮石墨烯纳米网器件的热整流
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2021-11-04 DOI: 10.1088/2399-1984/ac36b5
Fayong Liu, M. Muruganathan, Yu-Lun Feng, Shinichi Ogawa, Y. Morita, Chunmeng Liu, Jiayu Guo, Marek E. Schmidt, H. Mizuta
Graphene-based thermal rectification was investigated by measuring the thermal transport properties of asymmetric suspended graphene nanomesh devices. A sub-10 nm periodic nanopore phononic crystal structure was successfully patterned on the half area of the suspended graphene ribbon by helium ion beam milling technology. The ‘differential thermal leakage’ method was developed for thermal transport measurement without disturbance from the leakage of electron current through the suspended graphene bridge. A thermal rectification ratio of up to 60% was observed in a typical device with a nanopore pitch of 20 nm. By increasing the nanopore pitch in a particular range, the thermal rectification ratio showed an increment. However, this ratio was degraded by increasing the environmental temperature. This experiment suggests a promising way to develop a high-performance thermal rectifier by using a phononic crystal to introduce asymmetry on homogeneous material.
通过测量不对称悬浮石墨烯纳米网器件的热传输特性,研究了基于石墨烯的热整流。利用氦离子束铣削技术在悬浮石墨烯带的半个区域成功地形成了亚10nm周期性纳米孔声子晶体结构。开发了“差热泄漏”方法,用于在没有电子电流通过悬浮石墨烯桥泄漏干扰的情况下进行热传输测量。在纳米孔间距为20nm的典型器件中观察到高达60%的热整流率。通过在特定范围内增加纳米孔间距,热整流比表现出增加。然而,随着环境温度的升高,这种比例降低了。该实验提出了一种很有前途的开发高性能热整流器的方法,即使用声子晶体在均匀材料上引入不对称性。
{"title":"Thermal rectification on asymmetric suspended graphene nanomesh devices","authors":"Fayong Liu, M. Muruganathan, Yu-Lun Feng, Shinichi Ogawa, Y. Morita, Chunmeng Liu, Jiayu Guo, Marek E. Schmidt, H. Mizuta","doi":"10.1088/2399-1984/ac36b5","DOIUrl":"https://doi.org/10.1088/2399-1984/ac36b5","url":null,"abstract":"Graphene-based thermal rectification was investigated by measuring the thermal transport properties of asymmetric suspended graphene nanomesh devices. A sub-10 nm periodic nanopore phononic crystal structure was successfully patterned on the half area of the suspended graphene ribbon by helium ion beam milling technology. The ‘differential thermal leakage’ method was developed for thermal transport measurement without disturbance from the leakage of electron current through the suspended graphene bridge. A thermal rectification ratio of up to 60% was observed in a typical device with a nanopore pitch of 20 nm. By increasing the nanopore pitch in a particular range, the thermal rectification ratio showed an increment. However, this ratio was degraded by increasing the environmental temperature. This experiment suggests a promising way to develop a high-performance thermal rectifier by using a phononic crystal to introduce asymmetry on homogeneous material.","PeriodicalId":54222,"journal":{"name":"Nano Futures","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2021-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44020411","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Assessment of cytotoxicity profile of gadolinium oxide nanorods and the analogous surface-functionalized nanorods 氧化钆纳米棒及类似表面功能化纳米棒的细胞毒性评估
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2021-08-09 DOI: 10.1088/2399-1984/ac1bfc
Deepika Chauhan, Smriti Sri, Robin Kumar, A. Panda, P. Solanki
Gadolinium (Gd) has a strong paramagnetic response and is used in advanced magnetic resonance imaging (MRI). Gd is used in the complex form in MRI, but these complexes lack in sensitivity, targeting, rapid elimination from the body, and low internalization into the cell. To replace these Gd complex, the nanostructure (NSs) form of Gd has emerged as a viable solution as the NSs are expected to increase cell uptake and biocompatibility. The cytotoxicity evaluation is the key component that needs to be addressed for translating NSs from the lab to the clinic, and their effect on the cells is a vast area of research. Hence, the present study reports the hydrothermal synthesis of gadolinium oxide nanorods (Gd2O3 NRs) and ex-situ functionalized with aspartic acid (Asp-Gd2O3 NRs). The cytotoxicity studies on two cells namely RAW 264.7 and MCF-7 was assessed in terms of cell viability, morphological changes, and cell cycle analysis. Both types of NRs were well characterized and it was found that Asp-Gd2O3 NRs exhibited enhanced hydrophilicity and dispersity. Cell viability assay revealed enhanced biocompatibility of Asp-Gd2O3 NRs with almost 75% viability even at a higher concentration of 250 µg ml−1. The morphological changes upon internalization of both NRs were done through fluorescent microscopy that revealed no significant change in the morphology of the cell or its nucleus. Further, the cell cycle studies again confirmed the biocompatible nature of these NRs. These results suggest that Asp-Gd2O3 NRs are well suited for therapeutic applications, such as thermal cancer therapy, due to their tunable shape, size, low toxicity, and the possibility of surface modification.
钆(Gd)具有很强的顺磁响应,被用于高级磁共振成像(MRI)。Gd在MRI中以复合物形式使用,但这些复合物缺乏敏感性、靶向性、从体内快速消除和低内化进入细胞。为了取代这些Gd复合物,纳米结构(NSs)形式的Gd已经成为一种可行的解决方案,因为NSs有望增加细胞摄取和生物相容性。细胞毒性评估是将NSs从实验室转化为临床需要解决的关键组成部分,它们对细胞的影响是一个广泛的研究领域。因此,本研究报道了水热合成氧化钆纳米棒(Gd2O3纳米棒)并与天冬氨酸进行非原位功能化(Asp-Gd2O3纳米棒)。对raw264.7和MCF-7两个细胞进行细胞毒性研究,包括细胞活力、形态变化和细胞周期分析。两种类型的核磁共振都被很好地表征,发现Asp-Gd2O3核磁共振具有增强的亲水性和分散性。细胞活力测试显示,即使在250µg ml−1的较高浓度下,Asp-Gd2O3 NRs的生物相容性也提高了近75%。通过荧光显微镜观察两种核苷内化后的形态学变化,发现细胞或细胞核的形态学没有明显变化。此外,细胞周期研究再次证实了这些NRs的生物相容性。这些结果表明,Asp-Gd2O3 nmr由于其可调节的形状、大小、低毒性和表面修饰的可能性,非常适合于治疗应用,例如热癌治疗。
{"title":"Assessment of cytotoxicity profile of gadolinium oxide nanorods and the analogous surface-functionalized nanorods","authors":"Deepika Chauhan, Smriti Sri, Robin Kumar, A. Panda, P. Solanki","doi":"10.1088/2399-1984/ac1bfc","DOIUrl":"https://doi.org/10.1088/2399-1984/ac1bfc","url":null,"abstract":"Gadolinium (Gd) has a strong paramagnetic response and is used in advanced magnetic resonance imaging (MRI). Gd is used in the complex form in MRI, but these complexes lack in sensitivity, targeting, rapid elimination from the body, and low internalization into the cell. To replace these Gd complex, the nanostructure (NSs) form of Gd has emerged as a viable solution as the NSs are expected to increase cell uptake and biocompatibility. The cytotoxicity evaluation is the key component that needs to be addressed for translating NSs from the lab to the clinic, and their effect on the cells is a vast area of research. Hence, the present study reports the hydrothermal synthesis of gadolinium oxide nanorods (Gd2O3 NRs) and ex-situ functionalized with aspartic acid (Asp-Gd2O3 NRs). The cytotoxicity studies on two cells namely RAW 264.7 and MCF-7 was assessed in terms of cell viability, morphological changes, and cell cycle analysis. Both types of NRs were well characterized and it was found that Asp-Gd2O3 NRs exhibited enhanced hydrophilicity and dispersity. Cell viability assay revealed enhanced biocompatibility of Asp-Gd2O3 NRs with almost 75% viability even at a higher concentration of 250 µg ml−1. The morphological changes upon internalization of both NRs were done through fluorescent microscopy that revealed no significant change in the morphology of the cell or its nucleus. Further, the cell cycle studies again confirmed the biocompatible nature of these NRs. These results suggest that Asp-Gd2O3 NRs are well suited for therapeutic applications, such as thermal cancer therapy, due to their tunable shape, size, low toxicity, and the possibility of surface modification.","PeriodicalId":54222,"journal":{"name":"Nano Futures","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2021-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49056658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Transformation and degradation of metal halide perovskites induced by energetic electrons and their practical implications 高能电子诱导金属卤化物钙钛矿的转化降解及其实际意义
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2021-07-23 DOI: 10.1088/2399-1984/ac0c24
Z. Dang, Yuqing Luo, Yangbing Xu, Pingqi Gao, Xueseng Wang
Transmission electron microscopy (TEM) has been used in the characterizations of the lattice and defect structures as well as electronic and chemical properties of various materials. When TEM analyses were performed on lead halide perovskites (LHPs) and related materials, it has often been found that transformation and damage were easily induced in the specimens by electron beam irradiation. As the structural and chemical instabilities of LHPs and related materials are the main obstacle that must be overcome for their practical large-scale applications in solar cells and other optoelectronic applications, we examine whether and how the TEM-based irradiation and analyses can serve the purpose of rapid evaluation of the instabilities of a LHP to stimuli such as light and electric field which are crucial to its optoelectronic applications. We first provide a brief overview of the basic physical properties of LHPs related to the instability and the current understanding of the general mechanisms of sample damages induced by energetic electrons, followed with an analysis of the distinctive vulnerability and damaging features of LHPs with respect to electron beam irradiation. Based on the analysis of the similarities in the mechanisms of the damages generated by different stimuli, proper conditions are outlined with which the TEM-based investigations can be employed as a speed-up tester for the instabilities of LHPs against photon (including visible, ultraviolet and x-ray) exposure and an applied electric field. Furthermore, the perspectives of employing TEM-based processes in the fabrication of nanostructures and directly carrying out subsequent in situ analysis are elaborated, which is key to acquiring knowledge for improving focused electron beam-based industrial micro- and nanofabrication technologies.
透射电子显微镜(TEM)已被用于表征各种材料的晶格和缺陷结构以及电子和化学性质。当对卤化铅钙钛矿(LHP)和相关材料进行TEM分析时,经常发现电子束辐照很容易在样品中引起转变和损伤。由于LHP及其相关材料的结构和化学不稳定性是其在太阳能电池和其他光电子应用中实际大规模应用必须克服的主要障碍,我们研究了基于TEM的辐照和分析是否以及如何能够快速评估LHP对光和电场等刺激的不稳定性,这对其光电应用至关重要。我们首先简要概述了与不稳定性相关的LHP的基本物理性质,以及目前对高能电子引起样品损伤的一般机制的理解,然后分析了LHP在电子束辐照方面的独特脆弱性和损伤特征。基于对不同刺激产生的损伤机制的相似性的分析,概述了基于TEM的研究可以用作LHP对光子(包括可见光、紫外线和x射线)暴露和外加电场的不稳定性的加速测试仪的适当条件。此外,还阐述了在纳米结构的制造中使用基于TEM的工艺和直接进行后续原位分析的前景,这是获得改进基于聚焦电子束的工业微纳制造技术的知识的关键。
{"title":"Transformation and degradation of metal halide perovskites induced by energetic electrons and their practical implications","authors":"Z. Dang, Yuqing Luo, Yangbing Xu, Pingqi Gao, Xueseng Wang","doi":"10.1088/2399-1984/ac0c24","DOIUrl":"https://doi.org/10.1088/2399-1984/ac0c24","url":null,"abstract":"Transmission electron microscopy (TEM) has been used in the characterizations of the lattice and defect structures as well as electronic and chemical properties of various materials. When TEM analyses were performed on lead halide perovskites (LHPs) and related materials, it has often been found that transformation and damage were easily induced in the specimens by electron beam irradiation. As the structural and chemical instabilities of LHPs and related materials are the main obstacle that must be overcome for their practical large-scale applications in solar cells and other optoelectronic applications, we examine whether and how the TEM-based irradiation and analyses can serve the purpose of rapid evaluation of the instabilities of a LHP to stimuli such as light and electric field which are crucial to its optoelectronic applications. We first provide a brief overview of the basic physical properties of LHPs related to the instability and the current understanding of the general mechanisms of sample damages induced by energetic electrons, followed with an analysis of the distinctive vulnerability and damaging features of LHPs with respect to electron beam irradiation. Based on the analysis of the similarities in the mechanisms of the damages generated by different stimuli, proper conditions are outlined with which the TEM-based investigations can be employed as a speed-up tester for the instabilities of LHPs against photon (including visible, ultraviolet and x-ray) exposure and an applied electric field. Furthermore, the perspectives of employing TEM-based processes in the fabrication of nanostructures and directly carrying out subsequent in situ analysis are elaborated, which is key to acquiring knowledge for improving focused electron beam-based industrial micro- and nanofabrication technologies.","PeriodicalId":54222,"journal":{"name":"Nano Futures","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2021-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42510393","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
1/f noise spectroscopy and noise tailoring of nanoelectronic devices 纳米电子器件的1/f噪声光谱与噪声裁剪
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2021-06-04 DOI: 10.1088/2399-1984/ac14c8
Z. Balogh, G. Mezei, László Pósa, Botond Sánta, A. Magyarkuti, A. Halbritter
In this paper, we review the 1/f-type noise properties of nanoelectronic devices focusing on three demonstrative platforms: resistive switching memories, graphene nanogaps and single-molecule nanowires. The functionality of such ultrasmall devices is confined to an extremely small volume, where bulk considerations on the noise lose their validity: the relative contribution of a fluctuator heavily depends on its distance from the device bottleneck, and the noise characteristics are sensitive to the nanometer-scale device geometry and details of the mostly non-classical transport mechanism. All these are reflected by a highly system-specific dependence of the noise properties on the active device volume (and the related device resistance), the frequency, or the applied voltage. Accordingly, 1/f-type noise measurements serve as a rich fingerprint of the relevant transport and noise-generating mechanisms in the studied nanoelectronic systems. Finally, we demonstrate that not only the fundamental understanding and the targeted noise suppression is fueled by the 1/f-type noise analysis, but novel probabilistic computing hardware platforms heavily seek well tailorable nanoelectric noise sources.
在本文中,我们回顾了纳米电子器件的1/f型噪声特性,重点介绍了三个示范平台:电阻开关存储器,石墨烯纳米隙和单分子纳米线。这种超小型器件的功能被限制在极小的体积内,在这种情况下,对噪声的总体考虑失去了有效性:波动器的相对贡献在很大程度上取决于它与器件瓶颈的距离,噪声特性对纳米级器件的几何形状和大多数非经典传输机制的细节很敏感。所有这些都反映在噪声特性对有源器件体积(以及相关器件电阻)、频率或施加电压的高度系统特异性依赖上。因此,1/f型噪声测量可以作为研究的纳米电子系统中相关传输和噪声产生机制的丰富指纹。最后,我们证明了1/f型噪声分析不仅促进了基本的理解和有针对性的噪声抑制,而且新的概率计算硬件平台大量寻找可定制的纳米电噪声源。
{"title":"1/f noise spectroscopy and noise tailoring of nanoelectronic devices","authors":"Z. Balogh, G. Mezei, László Pósa, Botond Sánta, A. Magyarkuti, A. Halbritter","doi":"10.1088/2399-1984/ac14c8","DOIUrl":"https://doi.org/10.1088/2399-1984/ac14c8","url":null,"abstract":"In this paper, we review the 1/f-type noise properties of nanoelectronic devices focusing on three demonstrative platforms: resistive switching memories, graphene nanogaps and single-molecule nanowires. The functionality of such ultrasmall devices is confined to an extremely small volume, where bulk considerations on the noise lose their validity: the relative contribution of a fluctuator heavily depends on its distance from the device bottleneck, and the noise characteristics are sensitive to the nanometer-scale device geometry and details of the mostly non-classical transport mechanism. All these are reflected by a highly system-specific dependence of the noise properties on the active device volume (and the related device resistance), the frequency, or the applied voltage. Accordingly, 1/f-type noise measurements serve as a rich fingerprint of the relevant transport and noise-generating mechanisms in the studied nanoelectronic systems. Finally, we demonstrate that not only the fundamental understanding and the targeted noise suppression is fueled by the 1/f-type noise analysis, but novel probabilistic computing hardware platforms heavily seek well tailorable nanoelectric noise sources.","PeriodicalId":54222,"journal":{"name":"Nano Futures","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2021-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46484793","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Bandgap optimization of sol–gel-derived TiO2 and its effect on the photodegradation of formic acid 溶胶-凝胶衍生TiO2的带隙优化及其对甲酸光降解的影响
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2021-06-01 DOI: 10.1088/2399-1984/abfb7d
M. Zouheir, O. Assila, K. Tanji, A. El Gaidoumi, J. Araña, J. M. Doña Rodríguez, J. Smått, T. Huynh, A. Kherbeche
This work reports a key factor, the H2SO4 concentration, in controlling the physicochemical properties of titanium dioxide (TiO2) photocatalysts during the sol–gel synthesis. The photocatalysts synthesized using different concentrations of H2SO4 possess specific anatase/rutile ratios and crystallite sizes as well as surface areas, resulting in different photocatalytic performance in the degradation of formic acid in solution. The best photocatalytic performance is observed for the TiO2 photocatalyst containing a relatively high percentage of the rutile phase (∼84%), which is obtained from the sol–gel synthesis without H2SO4.
本文报道了在溶胶-凝胶合成过程中,H2SO4浓度是控制二氧化钛光催化剂理化性质的关键因素。不同浓度H2SO4合成的光催化剂具有特定的锐钛矿/金红石比、晶粒尺寸和比表面积,从而对溶液中甲酸的降解产生不同的光催化性能。采用溶胶-凝胶法合成的TiO2光催化剂中,金红石相含量较高(约84%),光催化性能最好。
{"title":"Bandgap optimization of sol–gel-derived TiO2 and its effect on the photodegradation of formic acid","authors":"M. Zouheir, O. Assila, K. Tanji, A. El Gaidoumi, J. Araña, J. M. Doña Rodríguez, J. Smått, T. Huynh, A. Kherbeche","doi":"10.1088/2399-1984/abfb7d","DOIUrl":"https://doi.org/10.1088/2399-1984/abfb7d","url":null,"abstract":"This work reports a key factor, the H2SO4 concentration, in controlling the physicochemical properties of titanium dioxide (TiO2) photocatalysts during the sol–gel synthesis. The photocatalysts synthesized using different concentrations of H2SO4 possess specific anatase/rutile ratios and crystallite sizes as well as surface areas, resulting in different photocatalytic performance in the degradation of formic acid in solution. The best photocatalytic performance is observed for the TiO2 photocatalyst containing a relatively high percentage of the rutile phase (∼84%), which is obtained from the sol–gel synthesis without H2SO4.","PeriodicalId":54222,"journal":{"name":"Nano Futures","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45865028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 16
Geometric effects on carrier collection in core–shell nanowire p–n junctions 核壳纳米线p–n结中载流子收集的几何效应
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2021-06-01 DOI: 10.1088/2399-1984/ac094c
Mingze Yang, A. Darbandi, S. Watkins, K. Kavanagh
We report electron-beam-induced current (EBIC) microscopy carried out on free-standing GaAs nanowire core–shell, p–n tunnel junctions. The carrier kinetics in both the n-type core and the p-type shell were determined by analyzing radial EBIC profiles as a function of beam energy. These profiles are highly sensitive to geometric effects such as facet width, shell and core thicknesses, and depletion widths. Combined with Monte Carlo simulations, they permitted measurement of the minority carrier diffusion lengths in the core and the shell, as well as the depletion widths as a function of radial direction. The relatively short minority carrier diffusion length in the core (50 nm), can be attributed to bulk point defects originating from low-temperature core growth (400 ∘C), or to interfacial recombination at traps at the p–n junction.
我们报道了在独立的GaAs纳米线核-壳,p–n隧道结上进行的电子束感应电流(EBIC)显微镜。通过分析作为束能量函数的径向EBIC分布来确定n型核和p型壳中的载流子动力学。这些轮廓对几何效应高度敏感,例如刻面宽度、壳和芯厚度以及耗尽宽度。结合蒙特卡罗模拟,他们允许测量核心和外壳中的少数载流子扩散长度,以及作为径向函数的耗尽宽度。核心中相对较短的少数载流子扩散长度(50 nm)可归因于源自低温核心生长(400∘C)的体点缺陷,或归因于p–n结处陷阱处的界面复合。
{"title":"Geometric effects on carrier collection in core–shell nanowire p–n junctions","authors":"Mingze Yang, A. Darbandi, S. Watkins, K. Kavanagh","doi":"10.1088/2399-1984/ac094c","DOIUrl":"https://doi.org/10.1088/2399-1984/ac094c","url":null,"abstract":"We report electron-beam-induced current (EBIC) microscopy carried out on free-standing GaAs nanowire core–shell, p–n tunnel junctions. The carrier kinetics in both the n-type core and the p-type shell were determined by analyzing radial EBIC profiles as a function of beam energy. These profiles are highly sensitive to geometric effects such as facet width, shell and core thicknesses, and depletion widths. Combined with Monte Carlo simulations, they permitted measurement of the minority carrier diffusion lengths in the core and the shell, as well as the depletion widths as a function of radial direction. The relatively short minority carrier diffusion length in the core (50 nm), can be attributed to bulk point defects originating from low-temperature core growth (400 ∘C), or to interfacial recombination at traps at the p–n junction.","PeriodicalId":54222,"journal":{"name":"Nano Futures","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43239491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multilayer adsorption and kinetic studies of dyes on pure and structurally modified poly(methyl methacrylate) electrospun nanofibers 纯结构改性聚甲基丙烯酸甲酯电纺纳米纤维对染料的多层吸附及动力学研究
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2021-04-09 DOI: 10.1088/2399-1984/abf6b2
P. Philip, Tomlal Jose, J. T. Mathew, Jinesh M. Kuthanapillil
Natural fibers and materials are well known for adsorption studies, whereas synthetic fibers have not received enough attention in this field. Therefore, an attempt is made here to study the adsorption properties of synthetic poly(methyl methacrylate) (PMMA) nanofibers and methods for improving or modifying their adsorption properties. PMMA nanofibers are prepared by the most recent electrospinning technique and the structural, and hence, the adsorption properties of the PMMA nanofibers are modified by preparing them in surface-roughened and coaxial hollow forms through electrospinning. Studies of the adsorption of methylene blue (MB) and brilliant green (BG) dyes by the three types of PMMA nanofiber demonstrate that all the PMMA nanofibers show a certain amount of adsorption. Fiber samples that had adsorbed MB and BG were subjected to various adsorption isotherms which confirmed the multilayer adsorption properties of the fiber samples by satisfying various isotherms, mainly the Freundlich and Elovich adsorption isotherms. Kinetic studies of pure and structurally modified PMMA nanofibers that had adsorbed MB and BG dyes proved that the intraparticle diffusion model applied to these fiber samples. Here, it is also shown that the adsorption properties of electrospun synthetic fibers can be further improved by structural modification using the possibilities of electrospinning.
天然纤维和材料在吸附研究方面是众所周知的,而合成纤维在这一领域还没有得到足够的关注。因此,本文试图研究合成聚甲基丙烯酸甲酯(PMMA)纳米纤维的吸附性能以及改善或改性其吸附性能的方法。PMMA纳米纤维是通过最新的静电纺丝技术制备的,因此,通过静电纺丝将其制备成表面粗糙的同轴中空形式,从而改变了PMMA纳米光纤的吸附性能。三种类型的PMMA纳米纤维对亚甲基蓝(MB)和亮绿色(BG)染料的吸附研究表明,所有PMMA纳米光纤都表现出一定的吸附量。对吸附了MB和BG的纤维样品进行了各种吸附等温线,通过满足各种等温线,主要是Freundlich和Elovich吸附等温线,证实了纤维样品的多层吸附性能。对吸附MB和BG染料的纯和结构改性PMMA纳米纤维的动力学研究证明,颗粒内扩散模型适用于这些纤维样品。在此,还表明,通过利用静电纺丝的可能性进行结构修饰,可以进一步提高静电纺丝合成纤维的吸附性能。
{"title":"Multilayer adsorption and kinetic studies of dyes on pure and structurally modified poly(methyl methacrylate) electrospun nanofibers","authors":"P. Philip, Tomlal Jose, J. T. Mathew, Jinesh M. Kuthanapillil","doi":"10.1088/2399-1984/abf6b2","DOIUrl":"https://doi.org/10.1088/2399-1984/abf6b2","url":null,"abstract":"Natural fibers and materials are well known for adsorption studies, whereas synthetic fibers have not received enough attention in this field. Therefore, an attempt is made here to study the adsorption properties of synthetic poly(methyl methacrylate) (PMMA) nanofibers and methods for improving or modifying their adsorption properties. PMMA nanofibers are prepared by the most recent electrospinning technique and the structural, and hence, the adsorption properties of the PMMA nanofibers are modified by preparing them in surface-roughened and coaxial hollow forms through electrospinning. Studies of the adsorption of methylene blue (MB) and brilliant green (BG) dyes by the three types of PMMA nanofiber demonstrate that all the PMMA nanofibers show a certain amount of adsorption. Fiber samples that had adsorbed MB and BG were subjected to various adsorption isotherms which confirmed the multilayer adsorption properties of the fiber samples by satisfying various isotherms, mainly the Freundlich and Elovich adsorption isotherms. Kinetic studies of pure and structurally modified PMMA nanofibers that had adsorbed MB and BG dyes proved that the intraparticle diffusion model applied to these fiber samples. Here, it is also shown that the adsorption properties of electrospun synthetic fibers can be further improved by structural modification using the possibilities of electrospinning.","PeriodicalId":54222,"journal":{"name":"Nano Futures","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2021-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42445374","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Ambipolar carbon nanotube transistors with hybrid nanodielectric for low-voltage CMOS-like electronics 具有混合纳米介质的双极性碳纳米管晶体管,用于低压类cmos电子器件
IF 2.1 4区 材料科学 Q2 Engineering Pub Date : 2021-04-09 DOI: 10.1088/2399-1984/abf6b1
Luis Portilla, Jianwen Zhao, Jing Zhao, L. Occhipinti, V. Pecunia
The proliferation of place-and-forget devices driven by the exponentially-growing Internet of Things industry has created a demand for low-voltage thin-film transistor (TFT) electronics based on solution-processible semiconductors. Amongst solution-processible technologies, TFTs based on semiconducting single-walled carbon nanotubes (sc-SWCNTs) are a promising candidate owing to their comparatively high current driving capability in their above-threshold region at low voltages, which is desirable for applications with constraints on supply voltage and switching speed. Low-voltage above-threshold operation in sc-SWCNTs is customarily achieved by using high-capacitance-density gate dielectrics such as metal-oxides fabricated via atomic layer deposition (ALD) and ion-gels. These are unattractive, as ALD requires complex-processing or exotic precursors, while ion-gels lead to slower devices with poor stability. This work demonstrates the fabrication of low-voltage above-threshold sc-SWCNTs TFTs based on a high-capacitance-density hybrid nanodielectric, which is composed of a readily-made AlO x nanolayer and a solution-processed self-assembled monolayer (SAM). The resultant TFTs can withstand a gate-channel voltage of 1–2 V, which ensures their above-threshold operation with balanced ambipolar behavior and electron/hole mobilities of 7 cm2 V−1 s−1. Key to achieving balanced ambipolarity is the mitigation of environmental factors via the encapsulation of the devices with an optimized spin-on polymer coating, which preserves the inherent properties of the sc-SWCNTs. Such balanced ambipolarity enables the direct implementation of CMOS-like circuit configurations without the use of additional dopants, semiconductors or source/drain electrode metals. The resultant CMOS-like inverters operate in the above-threshold region with supply voltages in the 1–2 V range, and have positive noise margins, gain values surpassing 80 V/V, and a bandwidth exceeding 100 kHz. This reinforces SAM-based nanodielectrics as an attractive route to easy-to-fabricate sc-SWCNT TFTs that can operate in the above-threshold region and that can meet the demand for low-voltage TFT electronics requiring moderate speeds and higher driving currents for wearables and sensing applications.
随着物联网行业呈指数级增长,即放即弃设备的激增,催生了对基于可解决方案处理半导体的低压薄膜晶体管(TFT)电子产品的需求。在溶液可加工技术中,基于半导体单壁碳纳米管(sc-SWCNTs)的TFTs是一个很有前途的候选技术,因为它们在低电压下在阈值以上区域具有相对较高的电流驱动能力,这对于电源电压和开关速度受限的应用是理想的。sc-SWCNTs中的低压高于阈值的工作通常是通过使用高电容密度的栅极介质来实现的,例如通过原子层沉积(ALD)和离子凝胶制备的金属氧化物。这些都没有吸引力,因为ALD需要复杂的处理或外来的前体,而离子凝胶导致设备速度较慢,稳定性较差。本研究展示了基于高电容密度杂化纳米电介质的低电压高于阈值的sc-SWCNTs tft的制造,该纳米电介质由现成的AlO x纳米层和溶液处理的自组装单层(SAM)组成。所得到的tft可以承受1 - 2 V的栅极通道电压,这确保了它们的高于阈值的工作,具有平衡的双极性行为和7 cm2 V−1 s−1的电子/空穴迁移率。实现平衡双极性的关键是通过使用优化的自旋聚合物涂层封装器件来减轻环境因素,从而保留sc-SWCNTs的固有特性。这种平衡的双极性可以直接实现类似cmos的电路配置,而无需使用额外的掺杂剂、半导体或源极/漏极金属。由此产生的类cmos逆变器工作在高于阈值的区域,电源电压在1-2 V范围内,并且具有正噪声余量,增益值超过80 V/V,带宽超过100 kHz。这加强了基于sam的纳米电介质作为易于制造的sc- swcnts TFT的有吸引力的途径,可以在高于阈值的区域工作,并且可以满足低压TFT电子设备的需求,需要中等速度和更高的驱动电流,用于可穿戴设备和传感应用。
{"title":"Ambipolar carbon nanotube transistors with hybrid nanodielectric for low-voltage CMOS-like electronics","authors":"Luis Portilla, Jianwen Zhao, Jing Zhao, L. Occhipinti, V. Pecunia","doi":"10.1088/2399-1984/abf6b1","DOIUrl":"https://doi.org/10.1088/2399-1984/abf6b1","url":null,"abstract":"The proliferation of place-and-forget devices driven by the exponentially-growing Internet of Things industry has created a demand for low-voltage thin-film transistor (TFT) electronics based on solution-processible semiconductors. Amongst solution-processible technologies, TFTs based on semiconducting single-walled carbon nanotubes (sc-SWCNTs) are a promising candidate owing to their comparatively high current driving capability in their above-threshold region at low voltages, which is desirable for applications with constraints on supply voltage and switching speed. Low-voltage above-threshold operation in sc-SWCNTs is customarily achieved by using high-capacitance-density gate dielectrics such as metal-oxides fabricated via atomic layer deposition (ALD) and ion-gels. These are unattractive, as ALD requires complex-processing or exotic precursors, while ion-gels lead to slower devices with poor stability. This work demonstrates the fabrication of low-voltage above-threshold sc-SWCNTs TFTs based on a high-capacitance-density hybrid nanodielectric, which is composed of a readily-made AlO x nanolayer and a solution-processed self-assembled monolayer (SAM). The resultant TFTs can withstand a gate-channel voltage of 1–2 V, which ensures their above-threshold operation with balanced ambipolar behavior and electron/hole mobilities of 7 cm2 V−1 s−1. Key to achieving balanced ambipolarity is the mitigation of environmental factors via the encapsulation of the devices with an optimized spin-on polymer coating, which preserves the inherent properties of the sc-SWCNTs. Such balanced ambipolarity enables the direct implementation of CMOS-like circuit configurations without the use of additional dopants, semiconductors or source/drain electrode metals. The resultant CMOS-like inverters operate in the above-threshold region with supply voltages in the 1–2 V range, and have positive noise margins, gain values surpassing 80 V/V, and a bandwidth exceeding 100 kHz. This reinforces SAM-based nanodielectrics as an attractive route to easy-to-fabricate sc-SWCNT TFTs that can operate in the above-threshold region and that can meet the demand for low-voltage TFT electronics requiring moderate speeds and higher driving currents for wearables and sensing applications.","PeriodicalId":54222,"journal":{"name":"Nano Futures","volume":null,"pages":null},"PeriodicalIF":2.1,"publicationDate":"2021-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46152074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
期刊
Nano Futures
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1