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Interactions Between Depositional Regime and Climate Proxies in the Northern South China Sea Since the Last Glacial Maximum 末次盛冰期以来南海北部沉积制度与气候指标的相互作用
IF 3.5 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-03-01 DOI: 10.1029/2022PA004591
Xuesong Wang, Yi Zhong, P. Clift, Yingci Feng, David J. Wilson, Stefanie Kaboth‐Bahr, A. Bahr, X. Gong, Debo Zhao, Zhong-rong Chen, Yanan Zhang, Yuhang Tian, Yuxing Liu, Xiaoyu Liu, Jiabo Liu, Wenyue Xia, Huihui Yang, Wei Cao, Qingsong Liu
Sedimentary deposits from the northern South China Sea (SCS) can provide important constraints on past changes in ocean currents and the East Asian summer monsoon (EASM) in this region. However, the interpretation of such records spanning the last deglaciation is complicated because sea‐level change may also have influenced the depositional processes and patterns. Here, we present new records of grain size, clay mineralogy, and magnetic mineralogy spanning the past 24 kyr from both shallow and deep‐water sediment cores in the northern SCS. Our multi‐proxy comparison among multiple cores helps constrain the influence of sea‐level change, providing confidence in interpreting the regional climate‐forced signals. After accounting for the influence of sea‐level change, we find that these multi‐proxy records reflect a combination of changes in (a) the strength of the North Pacific Intermediate Water inflow, (b) the EASM strength, and (c) the Kuroshio Current extent. Overall, this study provides new insights into the roles of varying terrestrial weathering and oceanographic processes in controlling the depositional record on the northern SCS margin in response to climate and sea‐level fluctuations.
南海北部的沉积沉积对该地区过去洋流和东亚夏季风的变化具有重要的制约作用。然而,由于海平面变化也可能影响了沉积过程和模式,因此对上一次冰川消退期间的此类记录的解释很复杂。在这里,我们展示了南海北部浅水和深水沉积物岩芯在过去24 kyr中的粒度、粘土矿物学和磁性矿物学的新记录。我们在多个核心之间进行的多代理比较有助于限制海平面变化的影响,为解释区域气候强迫信号提供信心。在考虑了海平面变化的影响后,我们发现这些多代理记录反映了(a)北太平洋中间水流入强度、(b)EASM强度和(c)黑潮范围的变化组合。总的来说,这项研究为不同的陆地风化和海洋学过程在控制南海北部边缘沉积记录以应对气候和海平面波动方面的作用提供了新的见解。
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引用次数: 2
Correction of the IRD Influence for Paleo‐Current Flow Speed Reconstructions in Hemipelagic Sediments IRD对半深海沉积物古水流速度重建影响的校正
IF 3.5 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-02-18 DOI: 10.1029/2022PA004500
N. Stevenard, A. Govin, C. Kissel, A. Van Toer
Reconstructions of past changes in deep‐sea current intensities are needed to understand ocean‐climate interactions in the past. The mean size of the sortable silt fraction (10–63 μm, SS‾ $overline{SS}$ ) is one of the most used proxies in this domain. However, in polar and subpolar environments under relatively low flow speed conditions, the presence of Ice‐Rafted Detritus (IRD) may alter the SS‾ $overline{SS}$ record and thus bias the interpretation of paleo‐current strength changes. In this paper, we examine the influence of IRD on the SS‾ $overline{SS}$ record of three sedimentary cores from the subpolar North Atlantic and the Antarctic margin. The influence of unsorted IRD on SS‾ $overline{SS}$ records is clearly established. To remove this IRD influence on grain‐size distributions (GSDs), we propose a new method based on End‐Member Analysis approach, and for which a MATLAB script is made available. This method characterizes the GSD of the unsorted IRD input, allowing it to be isolated and discarded, and the current sensitive SS‾ $overline{SS}$ variability to be robustly identified. The method therefore allows the recalculation of a modified sediment GSD free of unsorted IRD influence and the construction of modified SS‾ $overline{SS}$ and sortable silt percentage (the % of the 10–63 μm in the total <63 μm fraction) records. The application of the method to the three studied cores shows that (a) the unsorted IRD component is correctly removed from the grain‐size signal and (b) the new SS‾ $overline{SS}$ record is consistent with the XRF‐based ln(Zr/Rb) grain‐size proxy.
为了了解过去海洋与气候的相互作用,需要重建过去深海洋流强度的变化。可分选泥沙分数的平均粒径(10-63 μm, SS - $overline{SS}$)是该领域中使用最多的代理之一。然而,在相对低流速条件下的极地和亚极地环境中,冰筏碎屑(IRD)的存在可能会改变SS的$overline{SS}$记录,从而对古电流强度变化的解释产生偏差。在本文中,我们研究了IRD对来自亚极地北大西洋和南极边缘的三个沉积核的SS - $ $ overline{SS}$记录的影响。未分类的IRD对SS´$overline{SS}$记录的影响是明确确立的。为了消除这种IRD对粒度分布(gsd)的影响,我们提出了一种基于端元分析方法的新方法,并提供了MATLAB脚本。这种方法表征了未分类IRD输入的GSD,允许它被隔离和丢弃,并且可以鲁棒地识别当前敏感的SS - $ $ overline{SS}$可变性。因此,该方法允许重新计算不受未分选IRD影响的修改后的沉积物GSD,并构建修改后的SS - $overline{SS}$和可分选的泥沙百分比(10-63 μm占总<63 μm分数的百分比)记录。将该方法应用于所研究的三个岩心表明:(a)未分类的IRD分量正确地从粒度信号中去除;(b)新的SS´$overline{SS}$记录与基于XRF的ln(Zr/Rb)粒度代理一致。
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引用次数: 1
The Relationship Between the Global Mean Deep‐Sea and Surface Temperature During the Early Eocene 早始新世全球平均深海与地表温度的关系
IF 3.5 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-02-17 DOI: 10.1029/2022PA004532
Barbara Goudsmit‐Harzevoort, A. Lansu, M. Baatsen, A. S. von der Heydt, N. D. de Winter, Yurui Zhang, A. Abe‐Ouchi, A. D. de Boer, W. Chan, Y. Donnadieu, D. Hutchinson, G. Knorr, J. Ladant, P. Morozova, I. Niezgodzki, S. Steinig, A. Tripati, Zhongshi Zhang, Jiang Zhu, M. Ziegler
Estimates of global mean near‐surface air temperature (global SAT) for the Cenozoic era rely largely on paleo‐proxy data of deep‐sea temperature (DST), with the assumption that changes in global SAT covary with changes in the global mean deep‐sea temperature (global DST) and global mean sea‐surface temperature (global SST). We tested the validity of this assumption by analyzing the relationship between global SST, SAT, and DST using 25 different model simulations from the Deep‐Time Model Intercomparison Project simulating the early Eocene Climatic Optimum (EECO) with varying CO2 levels. Similar to the modern situation, we find limited spatial variability in DST, indicating that local DST estimates can be regarded as a first order representative of global DST. In line with previously assumed relationships, linear regression analysis indicates that both global DST and SAT respond stronger to changes in atmospheric CO2 than global SST by a similar factor. Consequently, this model‐based analysis validates the assumption that changes in global DST can be used to estimate changes in global SAT during the early Cenozoic. Paleo‐proxy estimates of global DST, SST, and SAT during EECO show the best fit with model simulations with a 1,680 ppm atmospheric CO2 level. This matches paleo‐proxies of EECO atmospheric CO2, indicating a good fit between models and proxy‐data.
对新生代全球近地表平均气温(全球SAT)的估计在很大程度上依赖于深海温度(DST)的古代理数据,假设全球SAT的变化与全球深海平均温度(全球DST)和全球海表平均温度(世界SST)的变化一致。我们通过分析全球SST、SAT和DST之间的关系来测试这一假设的有效性,使用了来自深时模型相互比较项目的25种不同模型模拟,模拟了不同CO2水平的始新世早期气候最佳值(EECO)。与现代情况类似,我们发现夏令时的空间变异性有限,这表明局部夏令时估计可以被视为全球夏令时的一阶代表。根据先前假设的关系,线性回归分析表明,全球夏令时和SAT对大气CO2变化的响应都比全球SST更强,其响应因子相似。因此,这一基于模型的分析验证了全球夏令时的变化可用于估计新生代早期全球SAT变化的假设。EECO期间全球夏令时、SST和SAT的古代理估计与大气CO2水平为1680ppm的模型模拟最为吻合。这与EECO大气CO2的古代理相匹配,表明模型和代理数据之间具有良好的拟合性。
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引用次数: 0
Revisiting the Geographical Extent of Exceptional Warmth in the Early Paleogene Southern Ocean 南大洋早古近纪异常温暖的地理范围再认识
IF 3.5 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-02-16 DOI: 10.1029/2022PA004529
J. Frieling, S. Bohaty, M. Cramwinckel, S. Gallagher, G. Holdgate, T. Reichgelt, F. Peterse, J. Pross, A. Sluijs, P. Bijl
To assess zonal temperature and biogeographical patterns in the Southern Ocean during the Paleogene, we present new multi‐proxy air‐ and sea‐surface temperature data for the latest Paleocene (∼57–56 Ma) and the Paleocene‐Eocene Thermal Maximum (PETM; ∼56 Ma) from the northern margin of the Australo‐Antarctic Gulf (AAG). The various proxy data sets document the well‐known late Paleocene warming and, superimposed, two transient late Paleocene pre‐cursor warming events, hundreds of kyr prior to the PETM. Remarkably, temperature reconstructions for the AAG and southwest Pacific during the latest Paleocene, PETM and Early Eocene Climatic Optimum (∼53–49 Ma) show similar trends as well as similar absolute temperatures east and west of the closed Tasmanian Gateway. Our data imply that the exceptional warmth as recorded by previous studies for the southwest Pacific extended westward into the AAG. This contrasts with modeling‐derived circulation and temperature patterns. We suggest that simulations of ocean circulation underestimate heat transport in the southwest Pacific due to insufficient resolution, not allowing for mesoscale eddy‐related heat transport. We argue for a systematic approach to tackle model and proxy biases that may occur in marginal marine settings and non‐analog high‐latitude climates to assess the temperature reconstructions.
为了评估古近纪南大洋的地带性温度和生物地理格局,我们提供了最新古新世(~ 57 ~ 56 Ma)和古新世—始新世热最大值(PETM;~ 56 Ma)来自南-南海湾(AAG)北缘。各种代理数据集记录了众所周知的晚古新世变暖,并叠加了两个短暂的晚古新世前指针变暖事件,比PETM早数百kyr。值得注意的是,在最晚的古新世、PETM和早始新世气候最佳(~ 53-49 Ma)期间,AAG和西南太平洋的温度重建显示出相似的趋势,以及封闭的塔斯马尼亚门户以东和以西相似的绝对温度。我们的数据表明,先前研究记录的西南太平洋异常温暖向西延伸到AAG。这与模拟得出的环流和温度模式形成对比。我们认为,由于分辨率不足,海洋环流模拟低估了西南太平洋的热输送,没有考虑到中尺度涡旋相关的热输送。我们主张采用一种系统的方法来解决在边缘海洋环境和非模拟高纬度气候中可能出现的模型和代理偏差,以评估温度重建。
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引用次数: 0
Weakening of the Summer Monsoon Over the Past 150 Years Shown by a Tree‐Ring Record From Shandong, Eastern China, and the Potential Role of North Atlantic Climate 从中国东部山东的树木年轮记录看近150年来夏季风的减弱以及北大西洋气候的潜在作用
IF 3.5 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-02-15 DOI: 10.1029/2022PA004495
Qiaomei Chen, Xiaojian Zhang, F. Chen, Heli Zhang, Yu-jiang Yuan, Shulong Yu, M. Hadad, F. Roig
The causes of the decreased intensity of the East Asian summer monsoon (EASM) over the past 150 years are still not fully understood, although several studies have linked the monsoon weakening to the warming of tropical oceans. Here, we use pine tree‐rings to reconstruct the precipitation total for April–August from 1810 to 2018, in south‐central Shandong Province, in the EASM region. The reconstruction accounts for 41.8% of the instrumental precipitation variance during 1965–2018. The EASM precipitation reconstruction shows extreme pluvial conditions in 1832, 1833, 1886, and 1998, and extreme droughts in 1878, 1901, and 1910, which correspond precisely to extreme climatic events recorded in historical documents. The reconstructed precipitation reveals a drying trend since the 1870s, which matches well with the decreasing trend of the EASM inferred from stalagmite oxygen isotope (δ18O) records and climate simulations. The trend of decreasing precipitation since the 1870s, indicated by our reconstruction, is significantly correlated with the spring sea surface temperature (SST) of the North Atlantic Ocean, which suggests that the EASM weakening was linked to North Atlantic SST variations during the past 150 years. This potential role of North Atlantic SST variability is supported by climate sensitivity simulations of the Community Earth System Model. North Atlantic SST variability induces two teleconnections of Rossby‐like wave propagation from the North Atlantic into East Asia, resulting in anomalous precipitation in this region.
过去150年来东亚夏季风(EASM)强度减弱的原因尚不完全清楚,尽管有几项研究已将季风减弱与热带海洋变暖联系起来。本文利用松树年轮重建了1810年至2018年4 - 8月在山东中南部EASM地区的降水总量。重建结果占1965-2018年仪器降水变化的41.8%。EASM降水重建结果显示,1832年、1833年、1886年和1998年的极端降水条件和1878年、1901年和1910年的极端干旱条件与历史文献记录的极端气候事件基本一致。19世纪70年代以来,重建的降水呈现干燥趋势,这与由石笋氧同位素(δ18O)记录和气候模拟推断的EASM减小趋势相吻合。重建结果表明,自19世纪70年代以来的降水减少趋势与北大西洋春季海温(SST)显著相关,表明近150年来EASM减弱与北大西洋海温变化有关。北大西洋海温变率的这种潜在作用得到了群落地球系统模式气候敏感性模拟的支持。北大西洋海温变率诱导了两次罗斯比波从北大西洋传播到东亚的遥相关,导致该地区的异常降水。
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引用次数: 0
A brGDGT‐Based Reconstruction of Terrestrial Temperature From the Maritime Continent Spanning the Last Glacial Maximum 基于brdgt的末次盛冰期海洋大陆陆地温度重建
IF 3.5 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-02-13 DOI: 10.1029/2022PA004501
M. Parish, X. Du, S. Bijaksana, J. Russell
The tropics exert enormous influence on global climate. Despite the importance of tropical regions, the terrestrial temperature history in the Indo‐Pacific Warm Pool (IPWP) region during the last deglaciation is poorly constrained. Although numerous sea surface temperature (SST) reconstructions provide estimates of SST warming from the Last Glacial Maximum to the Holocene, the timing of the onset of deglacial warming varies between records and inhibits determining the forcings driving deglacial warming in the IPWP. We present a 60,000‐year long temperature reconstruction based on branched glycerol dialkyl glycerol tetraethers (brGDGTs) in a sediment core from Lake Towuti, located in Sulawesi, Indonesia. BrGDGTs are bacterial membrane‐spanning lipids that, globally, become more methylated with decreasing temperature and more cyclized with decreasing pH. Although changes in temperature are the dominant control on brGDGTs in regional and global calibrations, we find that the cyclization of the brGDGTs is a major mode of variation at Lake Towuti that records important changes in the lacustrine biogeochemical environment. We separate the influence of lake chemistry changes from temperature changes on the brGDGT records, and develop a temperature record spanning the last 60,000 years. The timing of the deglacial warming in our record occurs after the onset of the deglacial increase in CO2 concentrations, which suggests rising greenhouse gas concentrations and the associated radiative forcing may have forced deglacial warming in the IPWP. Peaks in temperature around 55 and 34 ka indicate that Northern Hemisphere summer insolation may also influence land surface temperature in the IPWP region.
热带地区对全球气候有着巨大的影响。尽管热带地区具有重要意义,但印度洋-太平洋暖池(IPWP)地区在末次冰消期的陆地温度史却知之甚少。尽管大量的海表温度(SST)重建提供了从末次盛冰期到全新世海表温度变暖的估计,但不同记录之间冰化变暖开始的时间不同,并且抑制了IPWP中驱动冰化变暖的强迫的确定。我们基于位于印度尼西亚苏拉威西的托乌提湖沉积物岩心中的支链甘油二烷基甘油四醚(brGDGTs)进行了60,000年的温度重建。BrGDGTs是细菌跨膜脂质,在全球范围内,随着温度的降低甲基化程度越来越高,随着ph的降低环化程度越来越高。尽管在区域和全球校准中,温度的变化是BrGDGTs的主要控制因素,但我们发现BrGDGTs的环化是图乌提湖生物地球化学环境的重要变化的主要变化模式。我们将湖泊化学变化和温度变化对brGDGT记录的影响分离出来,建立了一个跨越6万年的温度记录。在我们的记录中,去冰变暖的时间发生在CO2浓度开始增加之后,这表明温室气体浓度的上升和相关的辐射强迫可能迫使IPWP的去冰变暖。55和34 ka前后的温度峰值表明,北半球夏季日照也可能影响IPWP区域的地表温度。
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引用次数: 5
Climate Variations in the Past 250 Million Years and Contributing Factors 过去2.5亿年的气候变化及其影响因素
IF 3.5 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-02-01 DOI: 10.1029/2022PA004503
Xiang Li, Yongyun Hu, Jun Yang, Mengyu Wei, Jiaqi Guo, Jiawenjing Lan, Qifan Lin, Shuai Yuan, Jian Zhang, Qiang Wei, Yonggang Liu, Jianqiang Nie, Y. Xia, Shineng Hu
We simulate climate variations in the past 250 million years (Myr), using the fully coupled Community Earth System Model version 1.2.2 (CESM1.2.2) with the Community Atmosphere Model version 4 (CAM4). Three groups of simulations are performed, each including 26 simulations, with a 10‐million‐year interval. The Control group is constrained by paleogeography, increasing solar radiation, and reconstructed global mean surface temperatures (GMSTs) by tuning CO2 concentrations. No ice sheets are prescribed for all simulations except for the pre‐industrial (PI) simulation in which modern geography, ice sheets and vegetation are used. Simulated zonal mean surface temperatures are always higher than those of proxy reconstructions in the tropics, but lower than those of proxy reconstructions at middle latitudes. The relative importance of individual contributing factors for surface temperature variations in the past 250 Myr is diagnosed, using the energy‐balance analysis. Results show that greenhouse gases are the major driver in regulating GMST variations, with a maximum contribution of 12.2°C. Varying surface albedo contributes to GMST variations by 3.3°C. Increasing solar radiation leads to GMST increases by 1.5°C. Cloud radiative effects have relatively weak impacts on GMST variations, less than ±0.8°C. For comparison, two groups of sensitivity simulations are performed. One group has the CO2 concentration fixed at 10 times the PI value, and the other group has fixed CO2 concentration of 10 times the PI value and fixed solar radiation at the present‐day value, showing that varying both paleogeography and solar constant and varying paleogeography alone result in GMST changes by 7.3°C and 5.6°C, respectively.
我们使用完全耦合的社区地球系统模型版本1.2.2(CESM1.2.2)和社区大气模型版本4(CAM4)模拟了过去2.5亿年(Myr)的气候变化。进行了三组模拟,每组包括26次模拟,间隔为1000万年。对照组受到古地理、增加太阳辐射和通过调整CO2浓度重建全球平均表面温度(GMST)的限制。除了使用现代地理、冰盖和植被的工业化前(PI)模拟外,所有模拟都没有规定冰盖。模拟的纬向平均表面温度总是高于热带的代理重建,但低于中纬度的代理重建。使用能量平衡分析,诊断了过去250 Myr中表面温度变化的单个影响因素的相对重要性。结果表明,温室气体是调节GMST变化的主要驱动因素,其最大贡献为12.2°C。表面反照率的变化导致GMST变化3.3°C。太阳辐射的增加导致GMST增加1.5°C。云辐射效应对GMST变化影响相对较弱,小于±0.8°C。相比之下,进行了两组灵敏度模拟。一组的CO2浓度固定为PI值的10倍,另一组的固定CO2浓度为PI值10倍,太阳辐射固定为当前值,这表明古地理和太阳常数的变化以及古地理的单独变化分别导致GMST变化7.3°C和5.6°C。
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引用次数: 3
Atmospheric CO2 Concentration Based on Boron Isotopes Versus Simulations of the Global Carbon Cycle During the Plio‐Pleistocene 基于硼同位素的大气CO2浓度与上新世全球碳循环模拟
IF 3.5 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-02-01 DOI: 10.1029/2022PA004439
P. Köhler
Atmospheric carbon dioxide concentrations (pCO2) beyond ice core records have been reconstructed from δ11B derived from planktic foraminifera found in equatorial sediment cores. Here, I applied a carbon cycle model over the Plio‐Pleistocene to evaluate the assumptions leading to these numbers. During glacials times, simulated atmospheric pCO2 was unequilibrated with pCO2 in the equatorial surface ocean by up to 35 ppm while the δ11B‐based approaches assume unchanged (quasi)equilibrium between both. In the Pliocene, δ11B‐based estimates of surface ocean pH are lower in the Pacific than in the Atlantic resulting in higher calculated pCO2. This offset in pH between ocean basins is not supported by models. To calculate pCO2 in surface waters out of the δ11B‐based pH some assumptions on either total alkalinity or dissolved inorganic carbon are necessary. However, the assumed values of these under‐constrained variables were according to my results partly inconsistent with chemically possible combinations within the marine carbonate system. The model results show glacial/interglacial variability in total alkalinity of the order of 100 μmol/kg, which is rarely applied to proxy reconstructions. Simulated atmospheric pCO2 is tightly (r2 > 0.9) related to equatorial surface‐ocean pH, which can be used for consistency checks. Long‐term trends in volcanic CO2 outgassing and the strength of the continental weathering fluxes are still unconstrained, allowing for a wide range of possible atmospheric pCO2 across the Plio‐Pleistocene. Nevertheless, this carbon cycle analysis suggests that reported atmospheric pCO2 above 500 ppm in the Pliocene might, for various reasons, need to be revised to smaller numbers.
根据赤道沉积物岩心中浮游有孔虫的δ11B,重建了冰芯以外的大气二氧化碳浓度(pCO2)。在这里,我应用了上新世-更新世的碳循环模型来评估导致这些数字的假设。在冰期,模拟的大气二氧化碳分压与赤道表层海洋的二氧化碳分压不平衡高达35 ppm,而基于δ11B的方法假设两者之间保持不变(准)平衡。在上新世,基于δ11B‐的太平洋表面海洋pH值估计值比大西洋低,导致计算出的二氧化碳分压更高。模式不支持海洋盆地之间pH值的这种抵消。为了计算以δ11B为基础的pH值以外的地表水中的pCO2,必须对总碱度或溶解的无机碳进行一些假设。然而,根据我的结果,这些受约束变量的假设值与海相碳酸盐体系中可能的化学组合部分不一致。模型结果显示,总碱度的冰期/间冰期变化约为100 μmol/kg,这种变化很少用于替代重建。模拟的大气二氧化碳分压与赤道表面-海洋pH值密切相关(r2 > 0.9),可用于一致性检查。火山释放二氧化碳的长期趋势和大陆风化通量的强度仍然不受限制,这使得在上新世-更新世期间可能的大气二氧化碳分压范围很广。然而,这项碳循环分析表明,由于各种原因,上新世报告的大气co2浓度高于500ppm可能需要修改为更小的数字。
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引用次数: 0
Expansion of Reducing Marine Environments During the Ireviken Biogeochemical Event: Evidence From the Altajme Core, Gotland, Sweden Ireviken生物地球化学事件期间减少海洋环境的扩展:来自瑞典哥德兰Altajme岩芯的证据
IF 3.5 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-02-01 DOI: 10.1029/2022PA004484
B. Stolfus, Lindsi J. Allman, Seth A. Young, M. Calner, Emma R. Hartke, Stephan C. Oborny, A. Bancroft, B. Cramer
New δ34Spy (pyrite) and δ34SCAS (carbonate‐associated sulfate) across the Llandovery‐Wenlock boundary (∼432 Ma) provide evidence for the expansion of reduced marine environments during the Ireviken Biogeochemical Event. This event consists of a major positive carbon isotope excursion, increased biotic turnover, and other major perturbations and changes within biogeochemical cycles. This interval of time has been hypothesized to coincide with an expansion of reducing marine environments that caused increased organic carbon burial and led to the Ireviken positive carbon isotope excursion (ICIE). Previous high‐resolution carbon isotope work in the Altajme core from Gotland, Sweden provides the highest resolution record of the ICIE yet documented and provides an ideal expanded stratigraphic section to study this event. Local expansion of reduced marine environments within the deeper shelf setting of the Altajme core is indicated by a positive shift in δ34Spy values and increase in pyrite sulfur concentrations at the onset of the ICIE. These data are indicative of increased microbial sulfate reduction within this portion of the Baltic Basin. Combined with new δ34SCAS data from this core, as well as additional data from distant basins, the new data presented here suggest a global expansion of reduced environments led to an increase in organic carbon burial and the ICIE.
横跨Llandovery - Wenlock边界(~ 432 Ma)的新δ34Spy(黄铁矿)和δ34SCAS(碳酸盐伴生硫酸盐)为Ireviken生物地球化学事件期间海洋环境退化的扩展提供了证据。这一事件包括一个主要的正碳同位素偏移,生物周转增加,以及生物地球化学循环中的其他主要扰动和变化。这个时间间隔被假设与减少海洋环境的扩张相吻合,这种环境导致有机碳埋藏增加,并导致Ireviken正碳同位素偏移(ICIE)。先前在瑞典哥特兰的Altajme岩心中进行的高分辨率碳同位素工作提供了ICIE迄今为止记录的最高分辨率记录,并为研究这一事件提供了理想的扩展地层剖面。在Altajme岩心较深的陆架背景下,δ34Spy值的正偏移和黄铁矿硫浓度的增加表明了海洋环境的局部扩展。这些数据表明,在波罗的海盆地的这一部分,微生物硫酸盐的减少有所增加。结合该岩心新的δ34SCAS数据,以及来自遥远盆地的额外数据,本文提出的新数据表明,全球还原环境的扩大导致有机碳埋藏和ICIE的增加。
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引用次数: 1
Carbon Cycle Responses to Changes in Weathering and the Long‐Term Fate of Stable Carbon Isotopes 碳循环对风化变化的响应和稳定碳同位素的长期命运
IF 3.5 2区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-02-01 DOI: 10.1029/2022PA004577
A. Jeltsch-Thömmes, F. Joos
The causes of CO2 variations over the past million years remain poorly understood. Imbalances between the input of elements from rock weathering and their removal from the atmosphere‐ocean‐biosphere system to the lithosphere likely contributed to reconstructed changes. We employ the Bern3D model to investigate carbon‐climate responses to step‐changes in the weathering input of phosphorus, alkalinity, carbon, and carbon isotope ratio (δ13C) in simulations extending up to 600,000 years. CO2 and climate approach a new equilibrium within a few ten thousand years, whereas equilibrium is established after several hundred thousand years for δ13C. These timescales represent a challenge for the initialization of sediment‐enabled models and unintended drifts may be larger than forced signals in simulations of the last glacial–interglacial cycle. Changes in dissolved CO2 change isotopic fractionation during marine photosynthesis. This causes distinct spatio‐temporal perturbations in δ13C and affects the burial flux of 13C. We force a cost‐efficient emulator, based on the Bern3D results, with contrasting literature‐based weathering histories over the last 800 thousand years. Glacial–interglacial amplitudes of up to 30 ppm in CO2, 0.05‰ in δ13C, and ∼15 mmol m−3 in deep ocean CO32− ${text{CO}}_{3}^{2-}$ are emulated for changes in carbonate rock weathering. Plausible input from the decomposition of organic matter on shelves causes variations of up to 10 ppm in CO2, 0.09‰ in δ13C, and 5 mmol m−3 in CO32− ${text{CO}}_{3}^{2-}$ , highlighting the non‐negligible effect of weathering‐burial imbalances.
过去百万年二氧化碳变化的原因仍然知之甚少。岩石风化元素的输入与它们从大气-海洋-生物圈系统向岩石圈的移除之间的不平衡可能导致了重建的变化。我们采用Bern3D模型研究了碳气候对磷、碱度、碳和碳同位素比值(δ13C)的风化输入阶跃变化的响应,模拟时间长达60万年。二氧化碳和气候在几万年内接近一个新的平衡,而δ13C在几十万年后才建立平衡。这些时间尺度对泥沙驱动模式的初始化提出了挑战,在末次冰期-间冰期旋回的模拟中,意外漂移可能比强迫信号更大。海洋光合作用过程中溶解CO2的变化改变了同位素分馏。这引起了δ13C明显的时空扰动,并影响了13C的埋藏通量。基于Bern3D结果,我们构建了一个具有成本效益的仿真器,并对比了过去80万年的风化历史。模拟了高达30 ppm的CO2、0.05‰的δ13C和~ 15 mmol m−3的深海CO32−${text{CO}}_{3}^{2-}$的冰期-间冰期振幅,以模拟碳酸盐岩风化的变化。大陆架上有机物分解的可能输入导致CO2的变化高达10 ppm, δ13C的变化高达0.09‰,CO32 - ${text{CO}}_{3}^{2-}$的变化为5 mmol m−3,突出了风化-埋藏不平衡的不可忽视的影响。
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引用次数: 0
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Paleoceanography and Paleoclimatology
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