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Plasmon induced quantified agglomeration of SiO2 nanoparticles to improve in efficiency in solar cell 等离激元诱导二氧化硅纳米颗粒定量团聚提高太阳能电池效率
IF 1 4区 材料科学 Pub Date : 2022-11-21 DOI: 10.15251/jor.2022.186.723
P. Sarkar, S. Panda, B. Maji, A. K. Mukhopadhyayan
The impact of plasmonic confinement induced by the SiO2 nanosphere utilized as a photonic absorber in a solar cell is investigated in this paper. The modified Stober technique is utilized for irradiation experiments using the size and shape of colloidal silica nanoparticles at two dosages of 0.485mg/ml and 0.693mg/ml solutions. The agglomerated silica is placed as an absorbent layer on a solar cell, and the J-V characteristics are studied under solar irradiation. The enhancement in efficiency and Jsc is far greater than predicted induced in photon injection caused by silica nanoparticle coating under coverage limit.
本文研究了太阳能电池中用作光子吸收体的SiO2纳米球引起的等离子体约束的影响。利用改进的Stober技术对胶体二氧化硅纳米颗粒的大小和形状进行了辐照实验,分别为0.485mg/ml和0.693mg/ml两种剂量的溶液。将聚结二氧化硅作为吸收层放置在太阳能电池上,研究了太阳能照射下的J-V特性。在覆盖极限下,二氧化硅纳米颗粒涂层引起的光子注入中效率和Jsc的增强远远大于预测。
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引用次数: 0
Structural, optical and magnetic properties of dilute magnetic semiconductor of Zn1-xNixO thin films for spintronic devices 用于自旋电子器件的Zn1-xNixO薄膜的稀磁半导体的结构、光学和磁性
IF 1 4区 材料科学 Pub Date : 2022-11-21 DOI: 10.15251/jor.2022.186.739
M. Ahmed, A. Bakry, H. Dalir, E. R. Shaaban
Co-precipitation method is used to create various compositions of the bulk sample of Zn1- xNixO (x = 0, 0.02, 0.04, 0.06, 0.08, and 0.1). By using an electron beam approach, the required coatings were deposited onto extremely clean glass substrates. The current study examines the structural and optical, characteristics of Ni-doped ZnO thin films. The creation of the hexagonal wurtzite single phase of ZnO was revealed by X-ray diffraction, and it had a strong (002) peak with a peak shift towards a lower angle. It was discovered that the films' crystallite size shrank as the Ni content rose. Investigations were done into how Ni dopant affected the produced thin films' optical and magnetic properties. The optical energy gap decreases from 3.28 to 2.90eV with increasing Ni content. In addition, ferromagnetism increases with increasing Ni concentration at expense of Zn in Zn1-xNixO films . The changes in the optical and magnetic properties of the prepared films were discussed based on the structural modification, which, further, enhances upon Ni-doping
采用共沉淀法制备了不同组成的Zn1- xNixO散装样品(x = 0、0.02、0.04、0.06、0.08和0.1)。通过使用电子束方法,所需的涂层被沉积在非常干净的玻璃基板上。本研究考察了ni掺杂ZnO薄膜的结构和光学特性。x射线衍射结果表明,ZnO的六方纤锌矿单相形成,具有较强的(002)峰,峰向低角度移动。结果表明,随着Ni含量的增加,薄膜的晶粒尺寸减小。研究了Ni掺杂剂对薄膜光学和磁性能的影响。随着Ni含量的增加,光能隙从3.28 ev减小到2.90eV。此外,Zn1-xNixO薄膜的铁磁性随Ni浓度的增加而增加,而Zn浓度的增加则增加。在结构修饰的基础上,讨论了制备薄膜的光学和磁性能的变化,并进一步增强了镍的掺杂
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引用次数: 0
Modeling and analysis of grating structure for enhancing the absorbance in InGaN-based solar cell 提高InGaN基太阳能电池吸收率的光栅结构建模与分析
IF 1 4区 材料科学 Pub Date : 2022-11-21 DOI: 10.15251/jor.2022.186.753
A. Merabti, H. Aissani, S. Nour, R. Abdeldjebar, A.A. Djatout
Good light trapping is essential to make high efficiency InGaN-based solar cells. As InGaN wafers are being made increasingly, thinner, light trapping becomes even more important. In this study, we propose a structure of one-dimensional InGaN grating for the InGaN-based solar cells is proposed. The solar energy absorption characteristics of this structure are studied by the the Finite element method (FEM) method. By alternately altering the grating depth and the filling factor, a new type of grating structure is proposed. For such a structure, different gratings are studied. Numerical computation shows that the absorptance of the InGaN grating structure is over 0.88 throughout the entire computational band. The optimum parameters of the proposed structure are period (a = 480 nm), a filling factor (ff = 50 %) and depth (d=210 nm), which indicates the proposed structured surface may have potential applications in solar cells manufacturing.
良好的光捕获对于制造高效率的InGaN基太阳能电池至关重要。随着InGaN晶片越来越薄,光捕获变得更加重要。在本研究中,我们提出了一种用于InGaN基太阳能电池的一维InGaN光栅结构。采用有限元法对该结构的太阳能吸收特性进行了研究。通过交替改变光栅深度和填充因子,提出了一种新型的光栅结构。对于这种结构,研究了不同的光栅。数值计算表明,InGaN光栅结构在整个计算频带内的吸收率超过0.88。所提出的结构的最佳参数是周期(a=480nm)、填充因子(ff=50%)和深度(d=210nm),这表明所提出的结构化表面可能在太阳能电池制造中具有潜在的应用。
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引用次数: 0
Nitrogen doped ZrO2 thin films: synthesis and characterization 氮掺杂ZrO2薄膜:合成与表征
IF 1 4区 材料科学 Pub Date : 2022-11-21 DOI: 10.15251/jor.2022.186.759
V. Ciupină, M. Albu, A. Caraiane, C. Porosnicu, C. Staicu, V. Nicolescu, R. Manu
To obtain ZrO2 and ZrO2+N2 thin films was used magnetron sputtering in radio frequency mode in a 10-6 mbar high vacuum deposition chamber. Silicon and carbon substrates measuring 12x15mm were used for deposition. The used magnetron system was composed of a single water-cooled cathode, provided with one circular targets of ZrO2 (2 mm thick and 50 mm in diameter) of high purity (99.95%). TDS Analysis of the films was performed. The desorbed species were observed with a QMG 220 Mass spectrometer provided with a W filament. It can be observed that in the case of the ZnO2 film, nitrogen desorption registers two maxima with signal intensity of 9.7x10-12 and 9.0x10-12, reached after 2000s and 4900s respectively. In the case of ZrO2+N2 film, nitrogen desorption shows a pronounced maximum with a signal intensity of 2.4x10-11 reached after 6000s. . The topology the ZrO2 and ZrO2+N2 samples deposited on Si substrates have been investigated by scanning electron microscopy (SEM) using a FEI Inspect S scanning electron microscope ( Hillsboro, Oregon, OR, USA) in high-vacuum modes. For the ZrO2 deposition, the surface appears to have grain-like topology, with a mean dimension of around 150 nm. These structures do not appear for the ZrO2+N2 deposition. Instead, for the ZrO2+N2 sample, small blisters (between 300 nm and 1.000nm) have formed on the surface, as a consequence of injecting N2 during the deposition. Cross-section measurements were also performed to establish the layer thickness. The ZrO2 sample has a measured thickness of 1950nm, while the introduction of N2 gas for the ZrO2+N2 sample had a poisoning effect on the magnetron target that led to a decrease (5 times) in deposition rate, giving this sample a final thickness of 365nm (compared to 1950nm) for the same deposition The crystalline structure was investigated using X-Ray Diffraction (XRD) method. The experimental set-up was composed of a diffractometer equipped with a Cu-Kα X-ray sourse, with a specific wavelength of 0.154nm, in a Bragg-Bretano type geometry. In this way, a crystalline phase corresponding to ZrO2 with a group symmetry Fm-3m (225)-face centered cubic was identified. At the same time, it is observed that the films deposited in the reactive atmosphere show a pronounced amorphization, this most likely being due to the retention of nitrogen which leads to the modification of the network parameters.
在10-6 mbar的高真空沉积室中,采用射频磁控溅射法制备ZrO2和ZrO2+N2薄膜。采用12x15mm的硅和碳衬底进行沉积。所使用的磁控管系统由单个水冷阴极组成,提供一个高纯度(99.95%)的ZrO2圆形靶(2 mm厚,直径50 mm)。对薄膜进行TDS分析。解吸物质用带W灯丝的qmg220质谱仪进行观察。可以观察到,对于ZnO2膜,氮的脱附有两个最大值,分别在2000和4900s后达到9.7 × 10-12和9.0 × 10-12。在ZrO2+N2膜中,氮的脱附表现出明显的最大值,6000s后信号强度达到2.4 × 10-11。利用FEI Inspect S扫描电镜(Hillsboro, Oregon, OR, USA)在高真空模式下研究了沉积在Si衬底上的ZrO2和ZrO2+N2样品的拓扑结构。对于ZrO2沉积,表面呈现出晶粒状拓扑结构,平均尺寸约为150 nm。这些结构在ZrO2+N2沉积中没有出现。相反,对于ZrO2+N2样品,由于在沉积过程中注入N2,表面上形成了小水泡(在300 nm到1000 nm之间)。还进行了截面测量以确定层厚度。ZrO2样品的测量厚度为1950nm,而ZrO2+N2样品的引入对磁控管靶产生了中毒效应,导致沉积速率降低(5倍),使该样品在相同沉积条件下的最终厚度为365nm(与1950nm相比)。实验装置由配备cu - k - α x射线源的衍射仪组成,特定波长为0.154nm,具有Bragg-Bretano型几何形状。通过这种方法,确定了一种与ZrO2相对应的具有群对称的Fm-3m(225)面心立方的晶相。同时,我们观察到沉积在反应气氛中的薄膜表现出明显的非晶化,这很可能是由于氮的保留导致了网络参数的改变。
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引用次数: 0
First principles study structural and magnetic properties of Mn doped MgO 第一性原理研究Mn掺杂MgO的结构和磁性能
IF 1 4区 材料科学 Pub Date : 2022-11-03 DOI: 10.15251/jor.2022.185.681
Y. Benkrima, A. Souigat, M. E. Soudani, Z. Korichi, H. Bouguettaia
The structure, electronic and magnetic properties of the MgO bulk of (1x2x2) and (1x1x1) atoms for the B4 wurtzite phase, doped by Manganese Mn have been studied. Accordingly, the Mn atom location in the far and near spots was taken into account, as well as recognizing the magnetic interaction between both spots. Such initiative was provided thanks to the use of the density function theorem (DFT). As for the energy gap of the semiconductor MgO, it was calculated by the linearly increasing planar method, and by the local density approximation (LDA), not to mention the generalized gradient approximation (CGA).It is found that the calculated results agree well with other theoretical and experimental findings. Whereas, the energy gap and the total magnetic torque have been recorded for the Mn doped MgO in the (1x2x2) super Celle. Therefore, our given results have shown that the use of the classification-generalized approximation could enable us to provide more precise results of the d orbital composites, and they also added new properties to the new compound.
研究了锰锰掺杂B4纤锌矿相MgO(1x2x2)和(1x1x1)原子体的结构、电子和磁性。因此,考虑了Mn原子在远点和近点中的位置,以及识别两个点之间的磁相互作用。由于密度函数定理(DFT)的使用,提供了这种主动性。至于半导体MgO的能隙,它是通过线性增加平面法和局部密度近似(LDA)计算的,更不用说广义梯度近似(CGA)了。计算结果与其他理论和实验结果吻合良好。然而,在(1x2x2)超晶格中,已经记录了Mn掺杂的MgO的能隙和总磁矩。因此,我们给出的结果表明,使用分类广义近似可以使我们能够提供d轨道复合物的更精确的结果,并且它们还为新化合物添加了新的性质。
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引用次数: 0
Structural and electronic properties of PANI-ZnO-TiO2 nanocomposite PANI-ZnO-TiO2纳米复合材料的结构和电子性能
IF 1 4区 材料科学 Pub Date : 2022-11-03 DOI: 10.15251/jor.2022.185.713
N. A. Niaz, A. Shakoor, F. Hussain, M. Iqbal, N. R. Khalid, M. Saleem, N. Anwar, Jahangir Ahmad
The nanocomposites of doped Polyaniline (PANI) with ZnO-TiO2 nanoparticles have been prepared by in-situ polymerization method. The structural properties of synthesized PANI and PANI/ZnO-TiO2 were studied by X-ray diffraction (XRD) analysis. XRD pattern show that PANI is intercalated into the layers of ZnO-TiO2 successfully and thus the degree of crystallinity increases due to crystalline nature of ZnO-TiO2. FTIR analysis indicated that there is a strong interaction between ZnO-TiO2 nanoparticles and PANI. Electronic properties (Dielectric and Conductivity) of PANI and PANI/ZnO-TiO2 nanocomposite have been investigated between frequency ranges from 20Hz to 01MHz, higher dielectric constants and dielectric losses of PANI/ZnO-TiO2 nanocomposites were found. As the content of ZnO-TiO2 increased, the dielectric constant and loss also increased. The value of dielectric constant for all samples is very high at low frequency but decreases with increase in frequency. Synthesis of PANI/ZnO-TiO2 nanocomposite materials with a large dielectric constant is promising for charge storage devices applications
采用原位聚合法制备了掺杂聚苯胺(PANI)与ZnO-TiO2纳米颗粒的纳米复合材料。通过X射线衍射(XRD)分析,研究了合成的PANI和PANI/ZnO-TiO2的结构性能。XRD图谱显示PANI成功地嵌入到ZnO-TiO2层中,因此由于ZnO-TiO2的结晶性质,结晶度增加。FTIR分析表明,ZnO-TiO2纳米粒子与聚苯胺之间存在强烈的相互作用。研究了PANI和PANI/ZnO-TiO2纳米复合材料在20Hz至01MHz频率范围内的电子性能(介电和电导率),发现PANI/ZnO-TiO2纳米复合物具有较高的介电常数和介电损耗。随着ZnO-TiO2含量的增加,介电常数和损耗也增加。所有样品的介电常数值在低频时都很高,但随着频率的增加而降低。具有大介电常数的PANI/ZnO-TiO2纳米复合材料的合成对电荷存储器件的应用前景广阔
{"title":"Structural and electronic properties of PANI-ZnO-TiO2 nanocomposite","authors":"N. A. Niaz, A. Shakoor, F. Hussain, M. Iqbal, N. R. Khalid, M. Saleem, N. Anwar, Jahangir Ahmad","doi":"10.15251/jor.2022.185.713","DOIUrl":"https://doi.org/10.15251/jor.2022.185.713","url":null,"abstract":"The nanocomposites of doped Polyaniline (PANI) with ZnO-TiO2 nanoparticles have been prepared by in-situ polymerization method. The structural properties of synthesized PANI and PANI/ZnO-TiO2 were studied by X-ray diffraction (XRD) analysis. XRD pattern show that PANI is intercalated into the layers of ZnO-TiO2 successfully and thus the degree of crystallinity increases due to crystalline nature of ZnO-TiO2. FTIR analysis indicated that there is a strong interaction between ZnO-TiO2 nanoparticles and PANI. Electronic properties (Dielectric and Conductivity) of PANI and PANI/ZnO-TiO2 nanocomposite have been investigated between frequency ranges from 20Hz to 01MHz, higher dielectric constants and dielectric losses of PANI/ZnO-TiO2 nanocomposites were found. As the content of ZnO-TiO2 increased, the dielectric constant and loss also increased. The value of dielectric constant for all samples is very high at low frequency but decreases with increase in frequency. Synthesis of PANI/ZnO-TiO2 nanocomposite materials with a large dielectric constant is promising for charge storage devices applications","PeriodicalId":54394,"journal":{"name":"Journal of Ovonic Research","volume":" ","pages":""},"PeriodicalIF":1.0,"publicationDate":"2022-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47417672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of dilute aluminum doped zinc oxide thin films: structural and morphological properties for varies applicationss 稀铝掺杂氧化锌薄膜的结构和形态特性研究
IF 1 4区 材料科学 Pub Date : 2022-11-03 DOI: 10.15251/jor.2022.185.699
A. Ashour, E. E. Assem, E. R. Shaaban
To form a better view of the influences of Al in ZnO, the crystalline structure parameters and morphological (via SEM) of Zn1-xAlxO (x=0.0, 0.02, 0.04, 0.06, 0.08 and 0.10) thin films organized onto glass substrates using by spin coating technique. The effects of Al doping on the structural ZnO nano crystalline films are investigated using (XRD), (EDAX) and (SEM). Rietveld refinement was used to examine the XRD patterns of Zn1- xAlxO thin films. This was done using Fullprof software. The XRD results showed that Al ions successfully replaced the Zn2+ lattice sites without any major change in the structure after Zn2+ substitution, and their crystallinity decreased with increasing Al doping content. Also, The XRD analysis confirmed the hexagonal structure. Lattice constant, Cell volume, Atomic Packing Fraction and surface density have been calculated. The microstructural parameters, crystallite size and lattice strain of Zn1-xAlxO thin films were calculated. The changes in microstructural parameters were discussed as dependent Al concentration. The Zn–O bond lengths and bond angle of Zn1-xAlxO were determined and have changed.
为了更好地观察Al在ZnO中的影响,使用旋涂技术在玻璃衬底上组织的Zn1-xAlxO(x=0.0、0.02、0.04、0.06、0.08和0.10)薄膜的晶体结构参数和形态(通过SEM)。利用(XRD)、(EDAX)和(SEM)研究了Al掺杂对ZnO纳米结构薄膜的影响。用Rietveld精细化方法研究了Zn1-xAlxO薄膜的XRD图谱。这是使用Fullprof软件完成的。XRD结果表明,在Zn2+取代后,Al离子成功地取代了Zn2+晶格位,结构没有任何重大变化,并且它们的结晶度随着Al掺杂量的增加而降低。此外,XRD分析证实了六方结构。计算了晶格常数、晶胞体积、原子堆积分数和表面密度。计算了Zn1-xAlxO薄膜的微观结构参数、晶粒尺寸和晶格应变。讨论了微观结构参数随Al浓度的变化。测定了Zn1-xAlxO的Zn–O键长和键角,并发生了变化。
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引用次数: 0
Modeling of betavoltaic cells GaN using a Monte Carlo calculation 使用蒙特卡罗计算的倍他伏打电池GaN建模
IF 1 4区 材料科学 Pub Date : 2022-11-03 DOI: 10.15251/jor.2022.185.691
Z. Tiouti, A. Talhi, B. Azeddine, A. Helmaoui
In this study, we use a Monte Carlo calculation code to simulate the concentration of electron-hole pairs generated of each point in the solid targets under a bombardment of Ni63 source for betavoltaic cells; this model is reported to be an accurate representation of electron interaction.From this simulation we can obtain the distribution of electron-hole pairs generated in GaN/GaN junction as a function of the depth, this distribution allowed us to find the concentrations of minority carriers excess depending on the thickness, which can represent as function and inject into the continuity equations for determine the diffusion current and then the characteristics of betavoltaic chosen. The model has been tested for Ni-63/GaN/GaN structure, with energy 17 KeV.
在本研究中,我们使用蒙特卡罗计算代码模拟了倍他伏打电池在Ni63源轰击下固体靶上每个点产生的电子-空穴对的浓度;据报道,这个模型是电子相互作用的准确表示。从这个模拟中我们可以得到GaN/GaN结中产生的电子空穴对作为深度函数的分布,这种分布使我们能够找到依赖于厚度的少数载流子过量的浓度,可以将其表示为函数并注入到连续性方程中,从而确定扩散电流,从而确定所选倍他伏打的特性。该模型已在Ni-63/GaN/GaN结构中进行了测试,能量为17 KeV。
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引用次数: 0
Study structure and optical properties of Ag2Se, Ag2Se0.8Te0.2 and Ag2Se0.8S0.2 thin films 研究了Ag2Se、Ag2Se0.8Te0.2和Ag2Se0.8S0.2薄膜的结构和光学性质
IF 1 4区 材料科学 Pub Date : 2022-11-03 DOI: 10.15251/jor.2022.185.675
H. M. Ali, I. Khudayer
Silver sulfide and the thin films Ag2Se0.8Te0.2 and Ag2Se0.8S0.2 created by the thermal evaporation process on glass with a thickness of 350 nm were examined for their structural and optical properties. These films were made at a temperature of 300 K. According to the X-ray diffraction investigation, the films are polycrystalline and have an initial orthorhombic phase. Using X-ray diffraction research, the crystallization orientations of Ag2Se and Ag2Se0.8Te0.2 & Ag2Se0.8S0.2 (23.304, 49.91) were discovered (XRD). As (Ag2Se and Ag2Se0.8Te0.2 & Ag2Se0.8S0.2) absorption coefficient fell from (470-774) nm, the optical band gap increased (2.15 & 2 & 2.25eV). For instance, the characteristics of thin films made of Ag2Se0.8Te0.2 and Ag2Se0.8S0.2 and silver sulfide have been studied.
采用热蒸发法制备了厚度为350 nm的硫化银薄膜Ag2Se0.8Te0.2和Ag2Se0.8S0.2,并对其结构和光学性能进行了研究。这些薄膜是在300 K的温度下制成的。根据x射线衍射研究,薄膜是多晶的,具有初始正交相。通过x射线衍射研究,发现了Ag2Se、Ag2Se0.8Te0.2和Ag2Se0.8S0.2(23.304, 49.91)的结晶取向(XRD)。随着(Ag2Se和Ag2Se0.8Te0.2 & Ag2Se0.8S0.2)吸收系数从(470 ~ 774)nm下降,光学带隙增大(2.15 & 2 & 2.25eV)。例如,研究了Ag2Se0.8Te0.2和Ag2Se0.8S0.2与硫化银制成的薄膜的特性。
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引用次数: 0
Effect of CdSe loading on bulk heterojunction solar cell parameters CdSe负载对体异质结太阳能电池参数的影响
IF 1 4区 材料科学 Pub Date : 2022-10-25 DOI: 10.15251/jor.2022.185.669
K. A. Mohammed, A. Alrubaie, K. M. Ziadan, A. S. Al-Kabbi, R. Zabibah
Hybrid solar cells based on conductive polymer poly(o-toludine) (POT) with Cadmium Selenide nanoparticles (CdSe NPs) bulk heterojunctions (BHJ) were prepared by the direct mixing method and then the optical properties of the prepared materials were analyzed. The photovoltaic response of a hybrid film is studied by I –V measurements under simulated one-sun AM 1.5 illumination (100 mW cm-2). Three different CdSe load was tested to study the effect of CdSe loading on optical properties and efficiency of solar cell. Best ratio was 1:1 were gave 0.28 % efficiency. Also no photovoltaic effect for device with 75% CdSe load.
采用直接混合法制备了基于导电聚合物聚邻甲苯胺(POT)和硒化镉纳米颗粒(CdSe NPs)体异质结(BHJ)的杂化太阳能电池,并对所制备材料的光学性能进行了分析。在模拟单太阳AM 1.5照度(100mw cm-2)下,通过I -V测量研究了混合薄膜的光伏响应。测试了三种不同的CdSe负载,研究了CdSe负载对太阳能电池光学性能和效率的影响。最佳配比为1:1,有效率为0.28%。对于负载为75% CdSe的器件,也没有光伏效应。
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引用次数: 0
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Journal of Ovonic Research
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