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Review on technologies to separate and purify ethyl alcohol from dilute aqueous solutions 稀水溶液中乙醇的分离纯化技术综述
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2021-08-18 DOI: 10.1515/revce-2020-0114
Pooja P. Sanap, Y. Mahajan
Abstract Ethyl alcohol (ethanol) is viewed upon as a fuel additive or even as an alternative fuel. Fermentation is used to produce dilute (<20 mass%) ethanol. This is needed to be concentrated to almost anhydrous, fuel grade ethanol (>99.5 mass%). The technologies used for concentration from dilute grade to fuel grade ethanol are summarized in this review. Thus, extraction; distillation; use of membranes; adsorption and some miscellaneous methods are discussed in detail. For each technique, the inlet and outlet concentrations; merits and demerits and scope for future work are indicated. Hybrid separations are discussed. In addition to technical feasibility, economic viability of the techniques is also discussed. A brief discussion on current industrial practice is also presented.
摘要乙醇被视为一种燃料添加剂,甚至是一种替代燃料。发酵用于产生稀释液(99.5质量%)。综述了从稀乙醇到燃料乙醇的浓缩技术。因此,提取;蒸馏;膜的使用;详细讨论了吸附法和其它一些方法。对于每种技术,入口和出口浓度;指出了优缺点和今后的工作范围。讨论了混合分离。除了技术可行性外,还讨论了这些技术的经济可行性。还简要讨论了当前的工业实践。
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引用次数: 6
Comprehensive technical review of the high-efficiency low-emission technology in advanced coal-fired power plants 先进燃煤电厂高效低排放技术综合技术综述
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2021-08-18 DOI: 10.1515/revce-2020-0107
Soonho Lee, Jongho Kim, Arash Tahmasebi, C. Jeon, Yangxian Liu, Jianaglong Yu
Abstract Advancements in supercritical (SC), ultrasupercritical (USC), and advanced USC coal-fired power plants have been achieved through the development of enhanced materials utilized in advanced steam cycles and through the deployment of advanced emission control systems. These are referred to as high-efficiency low-emission (HELE) technologies, which may solve numerous issues associated with coal-based power generation. There is a clear global transition from subcritical to advanced power plant types and significant R&D work on HELE technologies. Therefore, this comprehensive review covers the latest HELE technology deployment in major coal-consuming countries and their R&D roadmaps to advance HELE technologies. In spite of the various advantages of HELE technologies, there have been numerous technical challenges relevant to achieving the HELE steam conditions and deploying low emission control technologies in the HELE systems. Hence, this review covers the technical challenges and the relevant recent research by using various coal combustion test facilities. The current focus for the progression from USC boilers to advanced USC boilers is a successful demonstration of the developed high-performance alloys under the advanced steam conditions. This review covers the current status of research and development of advanced USC (A-USC) materials and challenges based on the major material research programs.
超临界(SC)、超超临界(USC)和先进USC燃煤电厂的进步是通过开发先进蒸汽循环中使用的增强材料和部署先进的排放控制系统来实现的。这些被称为高效低排放(HELE)技术,可以解决与煤基发电相关的许多问题。全球从亚临界电厂类型向先进电厂类型明显过渡,HELE技术的研发工作也很重要。因此,本综述涵盖了主要煤炭消费国最新的HELE技术部署及其推进HELE技术的研发路线图。尽管HELE技术具有各种优势,但在实现HELE蒸汽条件和在HELE系统中部署低排放控制技术方面存在许多技术挑战。因此,本文综述了利用各种煤燃烧试验设备所面临的技术挑战和相关的最新研究。目前从超超临界锅炉向先进超超临界锅炉发展的重点是在先进蒸汽条件下成功展示所开发的高性能合金。本文综述了先进超细碳纤维(a -超细碳纤维)材料的研究与发展现状,以及基于主要材料研究项目的挑战。
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引用次数: 1
A survey on fractionation: the optimal control of distilling in batch and semibatch configurations 分馏研究综述:分批和半分批精馏的最优控制
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2021-08-17 DOI: 10.1515/revce-2021-0006
M. Stojković
Abstract Since the middle of the last century, discussion about the operation of discontinuous fractionation to meet multifarious goals, such as product purity and recovery rate, by monitoring process variables including reflux or/and heat duty, is been on. The engineering practice showed intolerable events to occur; hereof the operation must be supervised, which makes it difficult to be in agreement with the batch distillation objectives. Hence, to uphold the effectuation of new operating policies into the industrial “know-how” techniques, different optimal control strategies can be conceived. The objective of this work is to offer a literature survey on the investigations of optimal control functioning for selected simple distillation column configurations employed in batch/semibatch distillation of homogeneous/reactive mixtures, as well as the approaches used in this regard. Available optimal control schemes have been reviewed in detail, emphasizing its major assets.
自上世纪中叶以来,人们一直在讨论通过监测回流或/和热负荷等过程变量来实现不连续分馏操作,以满足产品纯度和回收率等多种目标。工程实践表明,不可容忍的事件发生了;在这种情况下,操作必须受到监督,这使得很难与间歇蒸馏目标一致。因此,为了使新的操作政策在工业“专有技术”技术中发挥作用,可以设想不同的最优控制策略。这项工作的目的是提供一个文献调查的最优控制功能的选择简单精馏塔配置采用的间歇/半间歇精馏均质/反应混合物,以及在这方面使用的方法。详细回顾了现有的最优控制方案,强调了其主要优点。
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引用次数: 1
Magnetic nanoparticles (Fe3O4 NPs) fabricated composite microgels and their applications in different fields 磁性纳米颗粒(Fe3O4 NPs)制备复合微凝胶及其在不同领域的应用
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2021-08-13 DOI: 10.1515/revce-2021-0016
K. Naseem
Abstract This article encircles the research progress of Fe3O4 NPs loaded composite microgel particles. Preparation methodologies, properties and applications of Fe3O4 NPs loaded composite microgel particles are elaborated here. The effect of different factors on the stability and tunable properties of Fe3O4 NPs loaded composite microgel particles was also investigated in detail. These composite particles have exceptional magnetic properties that make them demanding composite nano-formulation in different fields. Applications of these composite microgel particles in different fields as micro-reactor, drug delivery vehicles, and in adsorption and catalysis have also been elaborated in detail. These composite microgel particles can easily be recovered from the reaction mixture by applying an external magnet due to the presence of fabricated Fe3O4 NPs.
摘要本文综述了负载fe3o4nps的复合微凝胶颗粒的研究进展。本文阐述了负载Fe3O4 NPs复合微凝胶颗粒的制备方法、性能及应用。研究了不同因素对负载Fe3O4 NPs的复合微凝胶颗粒稳定性和可调性能的影响。这些复合粒子具有特殊的磁性,这使得它们在不同的领域需要复合纳米配方。并详细阐述了这些复合微凝胶颗粒在微反应器、药物传递载体、吸附和催化等不同领域的应用。由于制备的Fe3O4 NPs的存在,这些复合微凝胶颗粒可以通过施加外部磁铁很容易地从反应混合物中回收。
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引用次数: 5
Foaming and rheological properties of aqueous solutions: an interfacial study 水溶液的发泡和流变特性:界面研究
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2021-08-12 DOI: 10.1515/revce-2020-0060
B. Vishal
Abstract Although aqueous foam is composed of simple fluids, air and water, it shows a complex rheological behavior. It exhibits solid-like behavior at low shear and fluid-like behavior at high shear rate. Therefore, understanding such behavior is important for many industrial applications in foods, pharmaceuticals, and cosmetics. Additionally, air–water interface of bubble surface plays an important role in the stabilizing mechanism of foams. Therefore, the rheological properties associated with the aqueous foam highly depend on its interfacial properties. In this review, a systematic study of aqueous foam are presented primarily from rheology point of view. Firstly, foaming agents, surfactants and particles are described; then foam structure was explained, followed by change in structure under applied shear. Finally, foam rheology was linked to interfacial rheology for the interface containing particles whose surface properties were altered by surfactants.
摘要虽然水性泡沫由简单的流体、空气和水组成,但它表现出复杂的流变行为。它在低剪切下表现出类似固体的行为,在高剪切速率下表现出相似流体的行为。因此,了解这种行为对于食品、药品和化妆品的许多工业应用非常重要。此外,气泡表面的空气-水界面在泡沫的稳定机制中起着重要作用。因此,与水性泡沫相关的流变特性在很大程度上取决于其界面特性。本文主要从流变学的角度对泡沫水溶液进行了系统的研究。首先介绍了发泡剂、表面活性剂和颗粒;然后对泡沫结构进行了解释,然后对其在剪切作用下的结构变化进行了解释。最后,将泡沫流变学与含有表面活性剂改变表面性质的颗粒的界面的界面流变学联系起来。
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引用次数: 0
Review of piston reactors for the production of chemicals 化工生产用活塞式反应器综述
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2021-08-02 DOI: 10.1515/revce-2020-0116
A. Ashok, Mary A. Katebah, P. Linke, Dharmesh Kumar, Dhruv Arora, K. Fischer, T. Jacobs, Ma’moun Al-Rawashdeh
Abstract To explore options for simple, safe, and compact chemical reactors that preserve wanted metastable initial products from sequential unwanted reactions, academic and industrial researchers have tried to repurpose reciprocating piston equipment or an “engine-like” design to be used as a chemical reactor. Piston reactors offer the benefit of achieving very high temperature and pressure conditions at very short and defined residence times. Such conditions offer promise for enhanced performance for several chemical conversions. This paper provides a review of the published literature and patents in the field of piston reactors to provide an overview of the current state-of-the-art. The review covers multiple aspects of piston reactors and their applications, reactor design options and their operation, catalyst and ignition placement, tested reactions, experimental setups as well as modeling and simulation. Several research gaps are highlighted as a motivation for future research in the field. To help interested readers into the topic, basic concepts and fundamentals of piston reactors are provided.
为了探索一种简单、安全、紧凑的化学反应器,从一系列不需要的反应中保存所需的亚稳态初始产物,学术界和工业界的研究人员试图重新利用往复式活塞设备或“类似发动机”的设计作为化学反应器。活塞式反应器的优点是在非常短的停留时间内实现非常高的温度和压力条件。这样的条件为提高几种化学转化的性能提供了希望。本文对活塞式反应器领域发表的文献和专利进行了综述,以提供当前最先进技术的概述。该综述涵盖了活塞式反应器及其应用、反应器设计方案及其操作、催化剂和点火位置、测试反应、实验设置以及建模和仿真的多个方面。几个研究空白被强调为一个动机,在该领域的未来研究。为了帮助有兴趣的读者进入这个主题,提供了活塞式反应器的基本概念和基本原理。
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引用次数: 12
Frontmatter
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2021-08-01 DOI: 10.1515/revce-2021-frontmatter6
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引用次数: 0
Electrospinning of chitosan-based nanofibers: from design to prospective applications 壳聚糖基纳米纤维的静电纺丝:从设计到应用前景
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2021-07-30 DOI: 10.1515/revce-2021-0003
Alexandru Anisiei, F. Oancea, L. Marin
Abstract Chitosan is a biopolymer originating from renewable resources, with great properties which make it an attractive candidate for plenty of applications of contemporary interest. By manufacturing chitosan into nanofibers using the electrospinning method, its potential is amplified due to the enhancement of the active surface and the low preparation cost. Many attempts were made with the aim of preparing chitosan-based nanofibers with controlled morphology targeting their use for tissue engineering, wound healing, food packaging, drug delivery, air and water purification filters. This was a challenging task, which resulted in a high amount of data, sometimes with apparent contradictory results. In this light, the goal of the paper is to present the main routes reported in the literature for chitosan electrospinning, stressing the advantages and disadvantages of each of them. Special emphasis is placed on the influence of various electrospinning parameters on the morphological characteristics of the fibers and their suitability for distinct applications.
摘要壳聚糖是一种源自可再生资源的生物聚合物,具有优良的性能,是当前广泛应用的有吸引力的候选材料。静电纺丝法制备壳聚糖纳米纤维,由于其活性表面的增强和制备成本的降低,其潜力被放大。为了制备形态可控的壳聚糖基纳米纤维,人们进行了许多尝试,目标是将其用于组织工程、伤口愈合、食品包装、药物输送、空气和水净化过滤器。这是一项具有挑战性的任务,它产生了大量的数据,有时结果明显相互矛盾。鉴于此,本文的目的是介绍文献报道的壳聚糖静电纺丝的主要路线,并强调每种路线的优缺点。特别强调了各种静电纺丝参数对纤维形态特征的影响及其对不同应用的适用性。
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引用次数: 25
Critical review on microfibrous composites for applications in chemical engineering 微纤维复合材料在化学工程中的应用综述
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2021-07-26 DOI: 10.1515/revce-2020-0109
Yi Yang, Huiqi Zhu, Lulu Bao, Xuhui Xu
Abstract Microfibrous composites (MCs) are novel materials with unique structures and excellent functional properties, showing great potential in industrial applications. The investigation of the physicochemical properties of MCs is significant for accommodating the rapid development of high-efficiency chemical engineering industries. In this review, the characteristics, synthesis and applications of different types of previously reported MCs are discussed according to the constituent fibres, including polymers, metals and nonmetals. Among the different types of MCs, polymer MCs have a facile synthesis process and adjustable fibre composition, making them suitable for many complex situations. The high thermal and electrical conductivity of metal MCs enables their application in strong exothermic, endothermic and electrochemical reactions. Nonmetallic MCs are usually stable and corrosion resistant when reducing and oxidizing environments. The disadvantages of MCs, such as complicated synthesis processes compared to those of particles or powders, high cost, insufficient thorough study, and unsatisfactory regeneration effects, are also summarized. As a result, a more systematic investigation of MCs remains necessary. Despite the advantages and great application potential of microfibrous composites, much effort remains necessary to advance them to the industrial level in the chemical engineering industry.
微纤维复合材料是一种结构独特、功能性能优异的新型材料,具有广阔的工业应用前景。研究高分子材料的理化性质对适应高效化工工业的快速发展具有重要意义。本文根据其组成纤维,包括聚合物、金属和非金属,综述了不同类型高分子材料的特点、合成方法和应用。在不同类型的高分子材料中,聚合物高分子材料的合成工艺简单,纤维成分可调,适用于许多复杂的场合。金属高分子材料的高导热性和高导电性使其能够应用于强放热、吸热和电化学反应中。非金属MCs在还原和氧化环境中通常是稳定和耐腐蚀的。综述了复合材料与颗粒或粉末相比合成工艺复杂、成本高、研究不够深入、再生效果不理想等缺点。因此,对mc进行更系统的调查仍然是必要的。尽管微纤维复合材料具有诸多优点和巨大的应用潜力,但在化工工业中,要使其达到工业化水平还需要付出很多努力。
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引用次数: 1
Innovative fouling-resistant materials for industrial heat exchangers: a review 工业热交换器新型防污材料综述
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2021-07-22 DOI: 10.1515/revce-2020-0094
Caroline Françolle de Almeida, Manon Saget, G. Delaplace, M. Jimenez, V. Fierro, A. Celzard
Abstract Fouling of heat exchangers (HEs) has become a major concern across the industrial sector. Fouling is an omnipresent phenomenon but is particularly prevalent in the dairy, oil, and energy industries. Reduced energy performance that results from fouling represents significant operating loss in terms of both maintenance and impact on product quality and safety. In most industries, cleaning or replacing HEs are currently the only viable solutions for controlling fouling. This review examines the latest advances in the development of innovative materials and coatings for HEs that could mitigate the need for costly and frequent cleaning and potentially extend their operational life. To better understand the correlation between surface properties and fouling occurrence, we begin by providing an overview of the main mechanisms underlying fouling. We then present selected key strategies, which can differ considerably, for developing antifouling surfaces and conclude by discussing the current trends in the search for ideal materials for a range of applications. In our presentation of all these aspects, emphasis is given wherever possible to the potential transfer of these innovative surfaces from the laboratory to the three industries most concerned by HE fouling problems: food, petrochemicals, and energy production.
摘要换热器(HEs)的污垢已成为整个工业部门的一个主要问题。污垢是一种普遍存在的现象,但在乳制品、石油和能源行业尤为普遍。污垢导致的能源性能降低意味着在维护以及对产品质量和安全的影响方面存在重大的运行损失。在大多数行业中,清洁或更换HEs是目前控制污垢的唯一可行解决方案。这篇综述考察了HEs创新材料和涂层开发的最新进展,这些材料和涂层可以减少昂贵和频繁的清洁需求,并可能延长其使用寿命。为了更好地理解表面性质和结垢发生之间的相关性,我们首先概述了结垢的主要机制。然后,我们提出了开发防污表面的关键策略,这些策略可能会有很大的不同,并通过讨论当前寻找适用于各种应用的理想材料的趋势来总结。在我们对所有这些方面的介绍中,尽可能强调将这些创新表面从实验室转移到最受HE污染问题关注的三个行业:食品、石化和能源生产。
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引用次数: 5
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