Abstract The review focuses on the recent development in anode materials and their synthesis approach, focusing on their compatibility for treating actual industrial wastewater, improving selectivity, electrocatalytic activity, stability at higher concentration, and thereby reducing the mineralization cost for organic pollutant degradation. The advancement in sol–gel technique, including the Pechini method, is discussed in the first section. A separate discussion related to the selection of the electrodeposition method and its deciding parameters is also included. Furthermore, the effect of using advanced heating approaches, including microwave and laser deposition synthesis, is also discussed. Next, a separate discussion is provided on using different types of anode materials and their effect on active •OH radical generation, activity, and electrode stability in direct and indirect oxidation and future aspects. The effect of using different synthesis approaches, additives, and doping is discussed separately for each anode. Graphene, carbon nanotubes (CNTs), and metal doping enhance the number of active sites, electrochemical activity, and mineralization current efficiency (MCE) of the anode. While, microwave or laser heating approaches were proved to be an effective, cheaper, and fast alternative to conventional heating. The electrodeposition and nonaqueous solvent synthesis were convenient and environment-friendly techniques for conductive metallic and polymeric film deposition.
{"title":"Research trends in the development of anodes for electrochemical oxidation of wastewater","authors":"Devendra K. Rai, Shishir Sinha","doi":"10.1515/revce-2021-0067","DOIUrl":"https://doi.org/10.1515/revce-2021-0067","url":null,"abstract":"Abstract The review focuses on the recent development in anode materials and their synthesis approach, focusing on their compatibility for treating actual industrial wastewater, improving selectivity, electrocatalytic activity, stability at higher concentration, and thereby reducing the mineralization cost for organic pollutant degradation. The advancement in sol–gel technique, including the Pechini method, is discussed in the first section. A separate discussion related to the selection of the electrodeposition method and its deciding parameters is also included. Furthermore, the effect of using advanced heating approaches, including microwave and laser deposition synthesis, is also discussed. Next, a separate discussion is provided on using different types of anode materials and their effect on active •OH radical generation, activity, and electrode stability in direct and indirect oxidation and future aspects. The effect of using different synthesis approaches, additives, and doping is discussed separately for each anode. Graphene, carbon nanotubes (CNTs), and metal doping enhance the number of active sites, electrochemical activity, and mineralization current efficiency (MCE) of the anode. While, microwave or laser heating approaches were proved to be an effective, cheaper, and fast alternative to conventional heating. The electrodeposition and nonaqueous solvent synthesis were convenient and environment-friendly techniques for conductive metallic and polymeric film deposition.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"807 - 855"},"PeriodicalIF":4.7,"publicationDate":"2022-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42124292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. J. Poormohammadian, F. Bahadoran, G. Vakili-Nezhaad
Abstract The requirement of running a new generation of fuel production is inevitable due to the limitation of oil production from reservoirs. On the other hand, enhancing the CO2 concentration in the atmosphere brings global warming phenomenon and leads to catastrophic disasters such as drought and flooding. Conversion of carbon dioxide to methanol can compensate for the liquid fuel requirement and mitigate CO2 emissions to the atmosphere. In this review, we surveyed the recent works on homogeneous hydrogenation of CO2 to CH3OH and investigated the experimental results in detail. We categorized the CO2 hydrogenation works based on the environment of the reaction, including neutral, acidic, and basic conditions, and discussed the effects of solvents’ properties on the experimental results. This review provides a perspective on the previous studies in this field, which can assist the researchers in selecting the proper catalyst and solvent for homogenous hydrogenation of carbon dioxide to methanol.
{"title":"Recent progress in homogeneous hydrogenation of carbon dioxide to methanol","authors":"S. J. Poormohammadian, F. Bahadoran, G. Vakili-Nezhaad","doi":"10.1515/revce-2021-0036","DOIUrl":"https://doi.org/10.1515/revce-2021-0036","url":null,"abstract":"Abstract The requirement of running a new generation of fuel production is inevitable due to the limitation of oil production from reservoirs. On the other hand, enhancing the CO2 concentration in the atmosphere brings global warming phenomenon and leads to catastrophic disasters such as drought and flooding. Conversion of carbon dioxide to methanol can compensate for the liquid fuel requirement and mitigate CO2 emissions to the atmosphere. In this review, we surveyed the recent works on homogeneous hydrogenation of CO2 to CH3OH and investigated the experimental results in detail. We categorized the CO2 hydrogenation works based on the environment of the reaction, including neutral, acidic, and basic conditions, and discussed the effects of solvents’ properties on the experimental results. This review provides a perspective on the previous studies in this field, which can assist the researchers in selecting the proper catalyst and solvent for homogenous hydrogenation of carbon dioxide to methanol.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"783 - 805"},"PeriodicalIF":4.7,"publicationDate":"2022-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42168597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Sustainability and greenness are the concepts of growing interest in the area of research as well as industries. One of the frequently encountered challenges faced in research and industrial fields is the solubility of the hydrophobic compound. Conventionally organic solvents are used in various applications; however, their contribution to environmental pollution, the huge energy requirement for separation and higher consumption lead to unsustainable practice. We require solvents that curtail the usage of hazardous material, increase the competency of mass and energy and embrace the concept of recyclability or renewability. Hydrotropy is one of the approaches for fulfilling these requirements. The phenomenon of solubilizing hydrophobic compound using hydrotrope is termed hydrotropy. Researchers of various fields are attracted to hydrotropy due to its unique physicochemical properties. In this review article, fundamentals about hydrotropes and various mechanisms involved in hydrotropy have been discussed. Hydrotropes are widely used in separation, heterogeneous chemical reactions, natural product extraction and pharmaceuticals. Applications of hydrotropes in these fields are discussed at length. We have examined the significant outcomes and correlated them with green engineering and green chemistry principles, which could give an overall picture of hydrotropy as a green and sustainable approach for the above applications.
{"title":"Progress in the field of hydrotropy: mechanism, applications and green concepts","authors":"Akash D. Patel, Meghal A. Desai","doi":"10.1515/revce-2021-0012","DOIUrl":"https://doi.org/10.1515/revce-2021-0012","url":null,"abstract":"Abstract Sustainability and greenness are the concepts of growing interest in the area of research as well as industries. One of the frequently encountered challenges faced in research and industrial fields is the solubility of the hydrophobic compound. Conventionally organic solvents are used in various applications; however, their contribution to environmental pollution, the huge energy requirement for separation and higher consumption lead to unsustainable practice. We require solvents that curtail the usage of hazardous material, increase the competency of mass and energy and embrace the concept of recyclability or renewability. Hydrotropy is one of the approaches for fulfilling these requirements. The phenomenon of solubilizing hydrophobic compound using hydrotrope is termed hydrotropy. Researchers of various fields are attracted to hydrotropy due to its unique physicochemical properties. In this review article, fundamentals about hydrotropes and various mechanisms involved in hydrotropy have been discussed. Hydrotropes are widely used in separation, heterogeneous chemical reactions, natural product extraction and pharmaceuticals. Applications of hydrotropes in these fields are discussed at length. We have examined the significant outcomes and correlated them with green engineering and green chemistry principles, which could give an overall picture of hydrotropy as a green and sustainable approach for the above applications.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"601 - 630"},"PeriodicalIF":4.7,"publicationDate":"2022-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49405830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Metal organic frameworks (MOFs) are currently gaining considerable attention as heterogeneous catalysts. Since the functionality of the framework and the pore size of the MOFs can be adjusted over a wide range for various catalytic reactions, the usage of these materials as solid catalysts is attractive. One of the preferred catalytic mesoMOFs is MIL-101 (MIL: Material of Institute Lavoisier) family which has been mainly investigated. The large surface area, high pore volumes, and acceptable solvent/thermal stability (MIL-101(Cr) up to 300 °C) have led the MIL-101 family to be considered an ideal and widespread MOF for use as a great heterogeneous catalyst or solid support for a variety of reactions. The objective of this review is to present recent research on the use of the MIL-101 family for heterogeneous catalysis in gas and liquid phase reactions.
{"title":"Recent developments in MIL-101 metal organic framework for heterogeneous catalysis","authors":"M. Taghizadeh, S. Tahami","doi":"10.1515/revce-2021-0050","DOIUrl":"https://doi.org/10.1515/revce-2021-0050","url":null,"abstract":"Abstract Metal organic frameworks (MOFs) are currently gaining considerable attention as heterogeneous catalysts. Since the functionality of the framework and the pore size of the MOFs can be adjusted over a wide range for various catalytic reactions, the usage of these materials as solid catalysts is attractive. One of the preferred catalytic mesoMOFs is MIL-101 (MIL: Material of Institute Lavoisier) family which has been mainly investigated. The large surface area, high pore volumes, and acceptable solvent/thermal stability (MIL-101(Cr) up to 300 °C) have led the MIL-101 family to be considered an ideal and widespread MOF for use as a great heterogeneous catalyst or solid support for a variety of reactions. The objective of this review is to present recent research on the use of the MIL-101 family for heterogeneous catalysis in gas and liquid phase reactions.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"707 - 728"},"PeriodicalIF":4.7,"publicationDate":"2022-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44379771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract In the last decade, there was observed a growing demand for both n-butanol as a potential fuel or fuel additive, and propylene as the only raw material for production of alcohol and other more bulky propylene chemical derivatives with faster growing outputs (polymers, propylene oxide, and acrylic acid). The predictable oilfield depletion and the European Green Deal adoption stimulated interest in alternative processes for n-butanol production, especially those involving bio-based materials. Their commercialization will promote additional market penetration of n-butanol for its application as a basic chemical. We analyze briefly the current status of two most advanced bio-based processes, i.e. ethanol–to-n-butanol and acetone–butanol–ethanol (ABE) fermentation. In the second part of the review, studies of n-butanol and ABE conversion to valuable products are considered with an emphasis on the most perspective catalytic systems and variants of the future processes realization.
{"title":"Potentials of bio-butanol conversion to valuable products","authors":"L. Pinaeva, A. Noskov","doi":"10.1515/revce-2021-0066","DOIUrl":"https://doi.org/10.1515/revce-2021-0066","url":null,"abstract":"Abstract In the last decade, there was observed a growing demand for both n-butanol as a potential fuel or fuel additive, and propylene as the only raw material for production of alcohol and other more bulky propylene chemical derivatives with faster growing outputs (polymers, propylene oxide, and acrylic acid). The predictable oilfield depletion and the European Green Deal adoption stimulated interest in alternative processes for n-butanol production, especially those involving bio-based materials. Their commercialization will promote additional market penetration of n-butanol for its application as a basic chemical. We analyze briefly the current status of two most advanced bio-based processes, i.e. ethanol–to-n-butanol and acetone–butanol–ethanol (ABE) fermentation. In the second part of the review, studies of n-butanol and ABE conversion to valuable products are considered with an emphasis on the most perspective catalytic systems and variants of the future processes realization.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"669 - 706"},"PeriodicalIF":4.7,"publicationDate":"2022-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44306561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jing Wang, Peifen Wang, Zhijun Wu, Tao Yu, A. Abudula, Mingzhu Sun, Xiaoxun Ma, Guoqing Guan
Abstract Volatile organic compounds (VOCs) are mainly derived from human activities, but they are harmful to the environment and our health. Catalytic oxidation is the most economical and efficient method to convert VOCs into harmless substances of water and carbon dioxide at relatively low temperatures among the existing techniques. Supporting noble metal and/or transition metal oxide catalysts on the porous materials and direct preparation of mesoporous catalysts are two efficient ways to obtain effective catalysts for the catalytic oxidation of VOCs. This review focuses on the preparation methods for noble-metal-based and transition-metal-oxide-based mesoporous catalysts, the reaction mechanisms of the catalytic oxidations of VOCs over them, the catalyst deactivation/regeneration, and the applications of such catalysts for VOCs removal. It is expected to provide guidance for the design, preparation and application of effective mesoporous catalysts with superior activity, high stability and low cost for the VOCs removal at lower temperatures.
{"title":"Mesoporous catalysts for catalytic oxidation of volatile organic compounds: preparations, mechanisms and applications","authors":"Jing Wang, Peifen Wang, Zhijun Wu, Tao Yu, A. Abudula, Mingzhu Sun, Xiaoxun Ma, Guoqing Guan","doi":"10.1515/revce-2021-0029","DOIUrl":"https://doi.org/10.1515/revce-2021-0029","url":null,"abstract":"Abstract Volatile organic compounds (VOCs) are mainly derived from human activities, but they are harmful to the environment and our health. Catalytic oxidation is the most economical and efficient method to convert VOCs into harmless substances of water and carbon dioxide at relatively low temperatures among the existing techniques. Supporting noble metal and/or transition metal oxide catalysts on the porous materials and direct preparation of mesoporous catalysts are two efficient ways to obtain effective catalysts for the catalytic oxidation of VOCs. This review focuses on the preparation methods for noble-metal-based and transition-metal-oxide-based mesoporous catalysts, the reaction mechanisms of the catalytic oxidations of VOCs over them, the catalyst deactivation/regeneration, and the applications of such catalysts for VOCs removal. It is expected to provide guidance for the design, preparation and application of effective mesoporous catalysts with superior activity, high stability and low cost for the VOCs removal at lower temperatures.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"541 - 565"},"PeriodicalIF":4.7,"publicationDate":"2022-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49026652","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-02-01DOI: 10.1515/revce-2022-frontmatter2
{"title":"Frontmatter","authors":"","doi":"10.1515/revce-2022-frontmatter2","DOIUrl":"https://doi.org/10.1515/revce-2022-frontmatter2","url":null,"abstract":"","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":" ","pages":""},"PeriodicalIF":4.7,"publicationDate":"2022-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45834590","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Formation damage is an essential part of drilling and production evaluation, which has a significant effect on well productivity and economics. Drilling fluids are significant sources of formation damage by different mechanisms. This article reviews the research works published during the past 30 years on formation damage associated with drilling fluids, including mechanical damage, chemical damage, and interaction with reservoir rock and fluids. Different filtration techniques, fines migration, and invasion models are discussed based on past studies and recent advancements. Laboratory experiments, methodology, and various aspects of evaluation are considered for further study. Despite presenting different authors’ views and experiences in this area, there is no integrated approach to evaluate formation damage caused by drilling fluids. Finally, the authors analyze the knowledge gap and conclude that a methodology must be designed to improve drilling fluids to prevent formation damage. Recent advances in the area of nanotechnology show promising alternatives for new methods to prevent formation damage.
{"title":"An insight review on formation damage induced by drilling fluids","authors":"Mojtaba Kalhor Mohammadi, S. Riahi, E. Boek","doi":"10.1515/revce-2020-0106","DOIUrl":"https://doi.org/10.1515/revce-2020-0106","url":null,"abstract":"Abstract Formation damage is an essential part of drilling and production evaluation, which has a significant effect on well productivity and economics. Drilling fluids are significant sources of formation damage by different mechanisms. This article reviews the research works published during the past 30 years on formation damage associated with drilling fluids, including mechanical damage, chemical damage, and interaction with reservoir rock and fluids. Different filtration techniques, fines migration, and invasion models are discussed based on past studies and recent advancements. Laboratory experiments, methodology, and various aspects of evaluation are considered for further study. Despite presenting different authors’ views and experiences in this area, there is no integrated approach to evaluate formation damage caused by drilling fluids. Finally, the authors analyze the knowledge gap and conclude that a methodology must be designed to improve drilling fluids to prevent formation damage. Recent advances in the area of nanotechnology show promising alternatives for new methods to prevent formation damage.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"387 - 415"},"PeriodicalIF":4.7,"publicationDate":"2022-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46647810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
K. Sharifi, R. Halladj, Seyed Javid Royaee, Farshid Towfighi, Sepideh Firoozi, Hamidreza Yousefi
Abstract Aromatic hydrocarbons are essential compounds, that the presence of which in fuels can improve the octane number. The conversion of the light alkanes to high value aromatics is vital from theoretical and industrial standpoints. Zeolites such as ZSM-5 play an essential role in the aromatization of light alkanes. This paper highlights the mechanism of aromatization of light alkanes such as methane, ethane, propane, butane, and its isomers. Furthermore, effective factors on the aromatization of light alkanes including metal type, crystallinity, acidity, space velocity, pretreatment of zeolites, co-feeding of light hydrocarbon, and operating factors such as temperature have been investigated to determine how a system of zeolite with metals can be useful to reach aromatization with high conversion.
{"title":"Effective factors on performance of zeolite based metal catalysts in light hydrocarbon aromatization","authors":"K. Sharifi, R. Halladj, Seyed Javid Royaee, Farshid Towfighi, Sepideh Firoozi, Hamidreza Yousefi","doi":"10.1515/revce-2020-0082","DOIUrl":"https://doi.org/10.1515/revce-2020-0082","url":null,"abstract":"Abstract Aromatic hydrocarbons are essential compounds, that the presence of which in fuels can improve the octane number. The conversion of the light alkanes to high value aromatics is vital from theoretical and industrial standpoints. Zeolites such as ZSM-5 play an essential role in the aromatization of light alkanes. This paper highlights the mechanism of aromatization of light alkanes such as methane, ethane, propane, butane, and its isomers. Furthermore, effective factors on the aromatization of light alkanes including metal type, crystallinity, acidity, space velocity, pretreatment of zeolites, co-feeding of light hydrocarbon, and operating factors such as temperature have been investigated to determine how a system of zeolite with metals can be useful to reach aromatization with high conversion.","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"39 1","pages":"513 - 540"},"PeriodicalIF":4.7,"publicationDate":"2022-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48837537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-01DOI: 10.1515/revce-2022-frontmatter1
{"title":"Frontmatter","authors":"","doi":"10.1515/revce-2022-frontmatter1","DOIUrl":"https://doi.org/10.1515/revce-2022-frontmatter1","url":null,"abstract":"","PeriodicalId":54485,"journal":{"name":"Reviews in Chemical Engineering","volume":"1 1","pages":""},"PeriodicalIF":4.7,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41771864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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