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A comprehensive review on the photocatalysis of Congo red dye for wastewater treatment 刚果红染料光催化处理废水的研究综述
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-08-03 DOI: 10.1515/revce-2022-0076
Nida Siddique, M. I. Din, R. Khalid, Z. Hussain
Abstract Congo red (CR) dye, due to its structural stability and non-degradable nature, is hazardous for humans and the aquatic environment. Among various methods used for degradation of CR, photocatalysis have been widely reported as a cost effective and environment-friendly method. Besides, extensive studies have been carried out regarding the use of nanomaterial-based photocatalyst for degradation of CR. This review describes the basics of photocatalysis along with the factors affecting the process, mechanism, and kinetics in detail. Additionally, literature related to synthetic and bio-based stabilizing mediums in photocatalytic assemblies have been arranged in a systematic manner. Advanced hybrid materials, i.e., metal–organic frameworks (MOFs) have also been described briefly. Future directions are discussed to address existing shortcomings in this field and also to expand research in this area.
摘要刚果红(CR)染料由于其结构稳定性和不可降解性,对人类和水生环境都是有害的。在用于降解CR的各种方法中,光催化作为一种成本效益高、环境友好的方法已被广泛报道。此外,关于使用基于纳米材料的光催化剂降解CR,已经进行了广泛的研究。本文详细介绍了光催化的基本原理以及影响过程、机理和动力学的因素。此外,已经以系统的方式排列了与光催化组件中的合成和生物基稳定介质相关的文献。还简要介绍了先进的杂化材料,即金属-有机框架(MOFs)。讨论了未来的方向,以解决该领域现有的不足,并扩大该领域的研究。
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引用次数: 1
Frontmatter 头版头条
3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-08-01 DOI: 10.1515/revce-2023-frontmatter6
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引用次数: 0
A critical analysis of turbulence modulation in particulate flow systems: a review of the experimental studies 微粒流系统湍流调制的关键分析:实验研究综述
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-07-31 DOI: 10.1515/revce-2022-0068
M. M. Hoque, J. Joshi, G. Evans, S. Mitra
Abstract In multiphase particulate systems, the turbulence of the continuous phase (gas or liquid) is modulated due to interactions between the continuous phase and the suspended particles. Such phenomena are non-trivial in the essence that addition of a dispersed phase to a turbulent flow complicates the existing flow patterns depending on the physical properties of the particles leading to either augmentation or attenuation of continuous phase turbulence. In the present study, this aspect has been comprehensively analysed based on the available experimental data obtained from the well-studied turbulent flow systems such as channel and pipes, free jets and grids. Relevant non-dimensional parameters such as particle diameter to integral length scale ratio, Stokes number, particle volume fraction, particle momentum number, and particle Reynolds number have been utilised to characterise the reported turbulence modulation behavior. Some limitations of these commonly used dimensionless parameters to characterise turbulence modulation are discussed, and possible improvements are suggested.
摘要在多相颗粒系统中,连续相(气体或液体)的湍流由于连续相和悬浮颗粒之间的相互作用而受到调节。这种现象在本质上是不平凡的,即在湍流中添加分散相会使现有的流型复杂化,这取决于颗粒的物理性质,从而导致连续相湍流的增加或衰减。在本研究中,基于从经过充分研究的湍流系统(如通道和管道、自由射流和格栅)获得的可用实验数据,对这一方面进行了全面分析。相关的无量纲参数,如颗粒直径与积分长度标度比、斯托克斯数、颗粒体积分数、颗粒动量数和颗粒雷诺数,已被用于表征所报道的湍流调制行为。讨论了这些常用的无量纲参数在表征湍流调制时的一些局限性,并提出了可能的改进建议。
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引用次数: 1
Data management of process plants as complex systems: systematic literature review and identification of challenges and opportunities 作为复杂系统的过程工厂的数据管理:系统的文献回顾和挑战与机遇的识别
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-07-14 DOI: 10.1515/revce-2022-0077
Max Layer, J. Leidich, Sebastian Schwoch, Bernhard Saske, S. Neubert, Peter Robl, Kristin Paetzold-Byhain
Abstract Led by the manufacturing industry, virtual replicas of production systems also known as digital twins (DTs) are gradually moving into all areas of industry. Their advantages are characterized by the possibility of product optimization, simulations, improved monitoring and prediction of downtimes and optimized maintenance, to name just a few. The engineering, procurement and construction (EPC) of process plants as mechatronic systems is characterized by a high degree of project-specific modifications and interdisciplinary engineering effort with low reusability, in contrast to unit-production-driven areas such as automotive. This results in a high cost-benefit ratio for the creation of DTs over the life cycle of process plants, especially when suppliers are integrated into the value chain. The objective of this paper is to analyze the state of plant lifecycle management, data exchange and the possibilities of optimized supplier integration during the planning and EPC of process plants regarding DT creation and usage. Three research questions (RQs) were used to narrow down a total of 356 identified publications to 54, which were then examined. The papers covered a variety of topics, including combining discipline-specific models, plant management approaches and the combination of both.
摘要在制造业的引领下,生产系统的虚拟复制品也被称为数字双胞胎(DT),正逐渐进入工业的各个领域。它们的优势在于可以进行产品优化、模拟、改进停机时间的监控和预测以及优化维护,仅举几例。与汽车等单位生产驱动领域相比,作为机电一体化系统的加工厂的工程设计、采购和施工(EPC)的特点是项目特定修改程度高,跨学科工程工作可重用性低。这导致在加工厂的整个生命周期内,特别是当供应商被整合到价值链中时,创建DT的成本效益比很高。本文的目的是分析工厂生命周期管理、数据交换的状态,以及在工艺工厂的规划和EPC过程中优化供应商集成的可能性。使用三个研究问题(RQ)将总共356份已确定的出版物缩小到54份,然后对其进行检查。这些论文涵盖了各种主题,包括结合特定学科的模型、工厂管理方法以及两者的结合。
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引用次数: 0
Frontmatter 头版头条
3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-07-01 DOI: 10.1515/revce-2023-frontmatter5
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引用次数: 0
Fabrication of monodisperse droplets and microcapsules using microfluidic chips: a review of methodologies and applications 用微流控芯片制备单分散液滴和微胶囊:方法和应用综述
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-05-19 DOI: 10.1515/revce-2022-0060
Weiguang Su, Bing Han, S. Yeboah, D. Du, Li Wang
Abstract Microfluidics has been applied in the preparation of monodisperse droplets and microcapsules due to its high encapsulation efficiency, its ability to create uniform particle sizes, and its capacity to control core–shell ratio and structure. To bring to the fore methodologies for the fabrication and application of monodisperse microcapsules using microfluidics, we present a review of the design, structure, materials, and surface modification techniques of various microfluidic chips. The review also covers fabrication methods, operating parameters and regulation methods of single and multiple monodisperse emulsion droplets fabricated from various microfluidic devices. Our findings show that particle size of monodisperse droplets depend mainly on microchannel characteristic size and flow rate, with particle size increasing with larger microchannel but decreasing with higher continuous phase flow rate. We additionally reviewed and compared various fabrication methods for monodisperse microcapsules, such as interfacial polymerization, free-radical polymerization, ionic cross-linking, and solvent evaporation. We further reviewed and examined the application of monodisperse microcapsules in biology applications, food engineering, composite materials development, and pharmaceutical industry. We found that high-throughput microfluidics for scale-up monodisperse microcapsule preparation towards uniform degradation and targeted release properties of monodisperse microcapsules would be key innovative direction for future applications.
摘要微流控技术因其高封装效率、制备均匀粒径、控制核壳比和结构的能力,已被广泛应用于单分散液滴和微胶囊的制备。本文综述了微流控芯片的设计、结构、材料和表面改性技术,介绍了微流控芯片在单分散微胶囊制备和应用方面的研究进展。综述了各种微流控装置制备单、多单分散乳化液液滴的制备方法、运行参数和调节方法。结果表明,单分散液滴粒径主要取决于微通道特征尺寸和流量,微通道越大,粒径越大,连续相流速率越高,粒径越小。对单分散微胶囊的制备方法进行了综述和比较,包括界面聚合、自由基聚合、离子交联和溶剂蒸发等。综述了单分散微胶囊在生物、食品、复合材料和制药等领域的应用。研究发现,利用高通量微流体技术规模化制备单分散微胶囊,实现单分散微胶囊的均匀降解和靶向释放特性将是未来应用的关键创新方向。
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引用次数: 0
Hollow microgels and their hybrids: classification, synthesis, characterization, properties and applications 中空微凝胶及其杂化物:分类、合成、表征、性能和应用
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-05-16 DOI: 10.1515/revce-2022-0074
A. Hassan, Iqra Sajid, M. Akmal, Muniba Aslam, P. G. Roy, Shuiqin Zhou, Ahmad Irfan, M. Shahid, R. Begum, Z. H. Farooqi
Abstract Hollow microgels and their hybrids have gained much attention in modern-day research because of their fascinating properties and potential applications. This article gives classification, preparation methods, properties and applications of hollow microgels and their hybrids in modern research. Some of the hollow microgels and their hybrids respond to change in specific environmental stimuli like pH, ionic strength and temperature of the medium. They are called smart polymer hollow microgels and smart hybrid microgels, respectively. This peculiar behaviour makes them a suitable candidate for their use in drug delivery, sensing, catalysis and many other fields. This review represents the current advancement along with future perspectives and suggestions for further research in this particular area.
摘要中空微凝胶及其杂化物由于其迷人的性质和潜在的应用,在现代研究中受到了广泛关注。本文介绍了中空微凝胶及其杂化材料的分类、制备方法、性能及其在现代研究中的应用。一些中空微凝胶及其杂化物对特定环境刺激的变化做出反应,如介质的pH、离子强度和温度。它们分别被称为智能聚合物中空微凝胶和智能混合微凝胶。这种特殊的行为使它们成为药物递送、传感、催化和许多其他领域的合适候选者。这篇综述代表了当前的进展,以及未来在这一特定领域进一步研究的前景和建议。
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引用次数: 0
An overview on the factors affecting enzymatic saccharification of lignocellulosic biomass into fermentable sugars 影响木质纤维素生物质酶糖化成可发酵糖的因素综述
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-05-10 DOI: 10.1515/revce-2022-0019
Wen Xuan Woo, J. Tan, T. Wu, S. Yeap, Abdullah Amru Indera Luthfi, Shareena Fairuz Abdul Manaf, N. S. Jamali, Y. W. Hui
Abstract Lignocellulosic biomass (LCB) is a widely available and sustainable energy resource that can be directly or indirectly converted to biofuels and value-added bioproducts. In such LCB conversion, enzymatic saccharification is commonly regarded as a green alternative to chemical hydrolysis due to less energy-intensive, less toxic, and more environment-benign for efficient fermentable sugar recovery. However, enzymatic saccharification faces substantial challenges, since the complex polymeric matrices of LCB necessitates a variety of enzymes for complete and adequate saccharification. Empirical evidence on enzymatic saccharification has paved the way for optimizing the processes and design for enhancing the performance in LCB. This review examines the enzymatic saccharification of LCB, focusing on the important parameters affecting the process, such as pH, temperature, agitation, enzyme/substrate loading, residence time, and the enzymes required to degrade various LCB components. Various strategies have been reported to improve the performance in saccharification and to address the non-productive adsorption of enzymes. A preliminary economic competency valuation of enzyme-derived fermentable sugars is proposed. Wheat straw, sugarcane bagasse and corn stalk appear, in this case, to be the most economic competent LCBs for commercial enzyme-derived fermentable sugar production. Lastly, practical challenges and future research directions on the enzymatic saccharification of LCB are discussed.
摘要木质纤维素生物质(LCB)是一种广泛可用的可持续能源,可以直接或间接转化为生物燃料和增值生物产品。在这种LCB转化中,酶促糖化通常被认为是化学水解的绿色替代品,因为它能耗更低、毒性更小,并且对有效的可发酵糖回收环境更有利。然而,酶促糖化面临着巨大的挑战,因为LCB的复杂聚合物基质需要多种酶来进行完全和充分的糖化。酶糖化的经验证据为优化工艺和设计以提高LCB的性能铺平了道路。本文综述了LCB的酶促糖化,重点研究了影响该过程的重要参数,如pH、温度、搅拌、酶/底物负载量、停留时间以及降解各种LCB成分所需的酶。已经报道了各种策略来提高糖化性能并解决酶的非生产性吸附。提出了酶衍生可发酵糖的初步经济能力评估。在这种情况下,小麦秸秆、甘蔗渣和玉米秸秆似乎是商业酶衍生可发酵糖生产中最经济有效的LCB。最后,讨论了LCB酶糖化的实际挑战和未来的研究方向。
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引用次数: 2
A review of the use of giant reed (Arundo donax L.) in the biorefineries context 巨型芦苇(Arundo donax L.)在生物炼制中的应用综述
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-05-10 DOI: 10.1515/revce-2022-0069
Z. Ortega, I. Bolaji, Luis Suárez, E. Cunningham
Abstract The massive availability of biomass generated by the common giant reed (Arundo donax L.) motivates the search for its possible industrial use for the generation of high added-value products through implementing a biorefinery approach. The literature demonstrates the potential of common cane to obtain different high-value compounds, such as levulinic acid, oligosaccharides, fermentable sugars, highly digestible fiber for animal feed, polyphenols, and natural fibers for composite materials, among others. The data shows the upward trend in Europe toward the generation of new green industries, grouped under the biorefinery concept. Therefore, this review summarizes the current knowledge on the use of Arundo to produce materials, fibers, and chemicals. Major environmental concerns related to this plant are also reviewed. Special attention has been paid to the potential use of Arundo to produce chemicals using green chemistry approaches, as a way to contribute to and advance the achievement of Sustainable Development Goals. Recommendations for future research are also outlined.
摘要:由常见的巨芦苇(Arundo donax L.)产生的大量生物质的可用性促使人们通过实施生物炼制方法来寻找其可能的工业用途,以产生高附加值的产品。文献表明,普通甘蔗具有获得不同高价值化合物的潜力,如乙酰丙酸、低聚糖、可发酵糖、用于动物饲料的高消化纤维、多酚和用于复合材料的天然纤维等。数据显示,在生物炼制概念下,欧洲新一代绿色工业呈上升趋势。因此,本文综述了目前有关阿伦多在生产材料、纤维和化学品方面的研究进展。对与该工厂有关的主要环境问题也进行了审查。特别关注的是利用阿伦多利用绿色化学方法生产化学品的潜在用途,作为促进和推动实现可持续发展目标的一种方式。并对今后的研究提出了建议。
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引用次数: 2
Chemical strategies towards controlled release in agriculture 农业控制释放的化学策略
IF 4.7 3区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-05-08 DOI: 10.1515/revce-2022-0057
Evelien Vermoesen, S. Bodé, Geert Brosens, P. Boeckx, S. van Vlierberghe
Abstract With an increasing world population of nearly eight billion which is expected to expand towards nine billion by 2050, future food demands will rise unavoidably. Primary productivity of crop is at the center of the food and feed value chain. Excessive and low efficiency fertilization cause severe environmental and ecological problems, along with economic wastage. Next to fertilizers, also pesticides, plant growth regulators and other agrochemicals (e.g., stored animal manure and hormones) pose environmental issues and require specific technologies to ensure security of human health and the global ecosystem while increasing food productions. There is an agronomic, legal and environmental ‘demand’ to develop controlled release solutions to optimize agricultural practices. In this regard, (polymer) chemistry can offer a wide range of strategies to cope with the current issues related to biodegradation, overfertilization, pesticide use, efficient precision agriculture etc. through tailored material design allowing controlled active components release. Therefore, this review focusses on (polymer) chemical strategies to design controlled release systems in the agricultural industry, covering specifically the state-of-the-art from the past four years.
随着世界人口近80亿的增长,预计到2050年将扩大到90亿,未来的粮食需求将不可避免地上升。作物初级生产力是粮食和饲料价值链的核心。过度和低效施肥造成了严重的环境和生态问题,同时也造成了经济浪费。除肥料外,农药、植物生长调节剂和其他农用化学品(例如储存的动物粪便和激素)也会造成环境问题,需要特定技术来确保人类健康和全球生态系统的安全,同时增加粮食产量。在农艺、法律和环境方面都存在开发控制释放解决方案以优化农业实践的“需求”。在这方面,(聚合物)化学可以提供广泛的策略来应对当前与生物降解、过度施肥、农药使用、高效精准农业等相关的问题,通过量身定制的材料设计,允许控制活性成分的释放。因此,本文将重点介绍农业工业中设计控释系统的(聚合物)化学策略,特别是过去四年来的最新进展。
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引用次数: 2
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