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Comparative study on acetylation, furfurylation, and silicification treatments for improving water resistance and durability of Korean wood materials 乙酰化、糠化和硅化处理对提高韩国木材耐水性和耐久性的比较研究
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-08-02 DOI: 10.1007/s00107-025-02301-4
Sun Lul Kwon, Sae-Min Yoon, Hyun-Mi Lee, Soo-Kyeong Jang, Jae-Hee Jung, Jinae Shin, Won-Joung Hwang, Yong-Seok Choi

As a valuable biological resource, wood plays a vital role in human societal development. However, wood undergoes biotic and abiotic degradation and dimensional instability, which limit its applications. Wood modification techniques, including acetylation, furfurylation, and silicification, can help enhance the durability and sustainability of wood. However, the effectiveness of these methods varies depending on the wood species and origin, emphasizing the need for further research to refine these techniques and enhance the wood performance for diverse industrial applications. This study aimed to investigate the effectiveness of three modification methods for Korean domestic wood species by assessing their effects on the weight% gain (WPG), equilibrium moisture content, water absorption, anti-swelling efficiency, and fungal decay resistance. Attenuated total reflectance (ATR)–Fourier transform infrared spectroscopy and scanning electron microscopy were conducted for the chemical and structural characterization of modified wood. The applicability of the modification methods was tested using five Korean domestic woods, sampled from Radiata pine, Korean red pine, Japanese larch, Hybrid poplar, and Sawtooth oak. The results showed that furfurylation produced the highest WPG, water resistance (WR), dimensional stability, and fungal decay resistance among the modification methods on all the tested wood materials. Acetylation and silicification also enhanced the dimensional stability and fungal decay resistance; however, the WR differed depending on the wood species and type. This study provides valuable insights into the applicability of three modification methods for improving the durability and performance of Korean domestic wood species and contributes to the sustainable utilization of wood in various industries.

木材作为一种宝贵的生物资源,在人类社会发展中起着至关重要的作用。然而,木材经历生物和非生物降解和尺寸不稳定,这限制了它的应用。木材改性技术,包括乙酰化、糠化和硅化,可以帮助提高木材的耐久性和可持续性。然而,这些方法的有效性因木材种类和来源而异,强调需要进一步研究以改进这些技术并提高木材的各种工业应用性能。通过对韩国国产木材增重% (WPG)、平衡含水率、吸水率、抗膨胀率和抗真菌腐烂性能的影响,研究了三种改性方法对韩国国产木材的有效性。利用衰减全反射(ATR) -傅里叶变换红外光谱和扫描电镜对改性木材进行了化学和结构表征。以白松、红松、落叶松、杂交杨树和锯栎5种韩国木材为样本,对改性方法的适用性进行了测试。结果表明,糠化改性对木材的WPG、耐水性、尺寸稳定性和抗真菌腐烂性的影响最大。乙酰化和硅化也增强了尺寸稳定性和抗真菌腐烂能力;不同树种、不同类型木材的WR不同。本研究为三种改性方法在提高韩国国产木材耐久性和性能方面的适用性提供了有价值的见解,并有助于木材在各个行业的可持续利用。
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引用次数: 0
Plywood gussets in mechanical timber connections: quantify the stress spread angles under major tension loads 机械木材连接中的胶合板扣板:在主要张力载荷下的应力扩展角的量化
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-07-31 DOI: 10.1007/s00107-025-02279-z
Yue Wang, Tianxiang Wang, Mattia Debertolis, Roberto Crocetti, Magnus Wålinder, Lars Blomqvist

This study reveals the magnitude of stress spread angles in the design of plywood gusset plates when subjected to uniaxial tension, with a specific focus on mechanical connections. Plywood plates with elevating widths at three different load-face grain angles were destructively tested. The test series continued with consecutively increased plate widths until the measured forces reached plateaus. Two models, namely, the classic and modified stress spread models, adopted from the Whitmore effective width theory, were investigated to account for the observed phenomenon. The classic stress spread model considers a rigid fastener array and an evenly distributed stress block. A closer-to-reality modified model considers the summation of stress blocks contributed from each fastener line. For both models mentioned, the magnitudes of corresponding spread angles were calibrated utilizing a fitting scheme considering maximized R-square values. The validity of both models was later examined and validated versus the previous experimental data reported in the literature. It was found that the classic model, despite some close predictions, gave over-estimations on the load-bearing capacities of several connection patterns. The modified model was found to be conservative for almost all investigated fastener patterns. Accordingly, a hybrid adoption of stress spread models was suggested.

本研究揭示了胶合板扣板设计中受单轴拉伸时应力扩散角的大小,并特别关注机械连接。对三种不同荷载面颗粒角下具有高度宽度的胶合板进行了破坏试验。测试系列继续,连续增加板的宽度,直到测量的力达到平台。采用Whitmore有效宽度理论的经典应力传播模型和修正应力传播模型来解释所观察到的现象。经典的应力扩散模型考虑刚性紧固件阵列和均匀分布的应力块。一个更接近现实的修正模型考虑了来自每条紧固件线的应力块的总和。对于上述两种模型,使用考虑最大r平方值的拟合方案校准相应扩展角的大小。这两个模型的有效性后来被检查和验证与先前的实验数据在文献中报道。研究发现,经典模型尽管有一些接近的预测,但对几种连接模式的承载能力给出了过高的估计。修正后的模型对几乎所有被研究的紧固件类型都是保守的。因此,建议采用混合应力扩散模型。
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引用次数: 0
Wood species identification based on mask R-CNN with multi-feature extraction networks and hyperspectral imaging 基于多特征提取网络和高光谱成像掩膜R-CNN的树种识别
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-07-28 DOI: 10.1007/s00107-025-02297-x
Zhiqiang Xin, Wenshu Lin, Fulan Liao

Different tree species exhibit significant variations in physical properties, uses, and economic value, making accurate species identification crucial. Traditional methods relying on human visual inspection are time-consuming and susceptible to subjective experience and fatigue. This paper proposes an RGB image expansion method based on hyperspectral data and an optimized Mask R-CNN model for wood species identification. First, 600 hyperspectral images of wood blocks of four tree species (Larch, Spruce, Birch, and Poplar) were collected. Principal Component Analysis was used to reduce the dimensionality of the hyperspectral images, followed by spectral band recombination to enhance texture features, resulting in a dataset of 1873 RGB images. Secondly, Leaky ReLU was used in place of ReLU as the activation function for the residual blocks. The ResNet50 and ResNet101 networks, combined with Feature Pyramid Networks were served as the two foundational feature extraction networks, and Convolutional Block Attention Module (CBAM) and Squeeze-and-Excitation Network (SENet) were inserted at different layers of the feature extraction network. Experimental results show that appropriate integration of attention mechanisms at different layers of the backbone can improve model accuracy and reduce loss rates. The ResNet101-CBAM3-SENet4 model exhibited the best overall performance, with precision of 0.9574, 0.9778, 0.9592, and 0.9783 for the four wood species in the test set, and an average precision of 0.9680. The mean Average Precision was calculated as 0.9657, and the mean Average Recall was 0.9806. This research provides new directions for dataset expansion in image identification and accurate identification of wood species with similar textures.

不同树种在物理特性、用途和经济价值上表现出显著差异,因此准确的树种鉴定至关重要。传统的方法依赖于人的视觉检测,耗时长,容易受到主观经验和疲劳的影响。提出了一种基于高光谱数据的RGB图像展开方法和优化的Mask R-CNN模型,用于树种识别。首先,采集了落叶松、云杉、桦树和杨树4种树种木块的600幅高光谱图像。采用主成分分析方法对高光谱图像进行降维处理,然后对光谱波段进行重组增强纹理特征,得到1873张RGB图像数据集。其次,用Leaky ReLU代替ReLU作为剩余块的激活函数。将ResNet50和ResNet101网络结合特征金字塔网络作为两个基本特征提取网络,并在特征提取网络的不同层插入卷积块注意模块(CBAM)和挤压激励网络(SENet)。实验结果表明,适当整合不同层次的注意力机制可以提高模型的准确性,降低模型的损失率。ResNet101-CBAM3-SENet4模型综合性能最好,4种木材的精度分别为0.9574、0.9778、0.9592和0.9783,平均精度为0.9680。平均精密度为0.9657,平均召回率为0.9806。该研究为图像识别的数据集扩展和纹理相似树种的准确识别提供了新的方向。
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引用次数: 0
Mechanical performance and design challenges of wooden fasteners: a critical analysis of evaluation methods and standards 木制紧固件的机械性能和设计挑战:评估方法和标准的批判性分析
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-07-24 DOI: 10.1007/s00107-025-02293-1
Inayat Ullah Khan, Mahbube Subhani, Kazem Ghabraie, Mahmud Ashraf

Wooden fasteners are gaining increasing attention due to their potential to enhance automation in wood processing, recyclability, sustainability, and producing Engineered Wood Products free from metal fasteners and adhesives. The mechanical response of wooden fasteners differs significantly from conventional metal fasteners. This distinct behaviour necessitates the development of specific guidelines and standards for assessing and designing wooden fastener connections. Current standards, such as the Eurocode and National Design Specification, along with existing research, offer empirical equations that are not fully applicable to wooden fasteners. Proper evaluation of wooden fastener joints requires the determination of key mechanical properties, including maximum bending moment, maximum bending strength, shear strength, and embedment strength. However, the flexible nature of wooden fasteners and their size and geometry make the determination of these properties challenging. This review critically examines the mechanical properties of wooden fasteners, factors influencing their performance, testing methodologies, failure modes, deviations from existing metal fastener standards, and emerging trends and challenges in the design of wooden fastener-based connections. This critical comparative review of wooden fasteners and their quantitative evaluation of deviations from steel fasteners provides valuable insights that will be helpful for future standards and innovation related to wooden fasteners.

由于具有提高木材加工自动化、可回收性、可持续性和生产不含金属紧固件和粘合剂的工程木制品的潜力,木制紧固件越来越受到关注。木制紧固件的力学响应与传统的金属紧固件有很大的不同。这种独特的行为需要制定具体的指导方针和标准来评估和设计木制紧固件连接。目前的标准,如欧洲规范和国家设计规范,以及现有的研究,提供的经验公式并不完全适用于木制紧固件。正确评价木制紧固件接头需要确定关键的机械性能,包括最大弯矩、最大弯曲强度、剪切强度和嵌入强度。然而,木制紧固件的灵活性质及其尺寸和几何形状使这些特性的确定具有挑战性。这篇综述严格审查了木制紧固件的机械性能,影响其性能的因素,测试方法,失效模式,与现有金属紧固件标准的偏差,以及木制紧固件连接设计的新趋势和挑战。本文对木质紧固件进行了批判性的比较分析,并对其与钢制紧固件的偏差进行了定量评估,提供了有价值的见解,有助于制定与木质紧固件相关的未来标准和创新。
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引用次数: 0
Potentiality of microwave technology for treatment of Norway spruce wood to reduce risk of resin exudation from wood materials 微波技术处理挪威云杉木材的潜力,以减少木材材料树脂渗出的风险
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-07-21 DOI: 10.1007/s00107-025-02288-y
Errj Sansonetti, Dace Cirule, Edgars Kuka, Ingeborga Andersone, Kristine Meile, Laima Vevere, Bruno Andersons

Microwave technology finds application in wood processing, particularly for improving drying and impregnation. A less explored application is the treatment of wood to reduce resin exudation. The aim of this research is to examine how microwave treatment of spruce wood specimens can change the physico-chemical properties of resin to retain it in the wood. The results demonstrated that microwave treatment can increase the glass transition temperature more rapidly than conventional heat treatment. Both the amount of volatile content and chemical composition of resin are affected. Further optimization of treatment parameters, such as duration and power density, could enhance the efficiency of this method.

微波技术在木材加工中得到了应用,特别是在改善干燥和浸渍方面。一个较少探索的应用是木材的处理,以减少树脂渗出。本研究的目的是研究微波处理云杉木材样品如何改变树脂的物理化学性质,使其保留在木材中。结果表明,微波处理能比常规热处理更快地提高玻璃化转变温度。树脂的挥发性含量和化学成分都受到影响。进一步优化处理参数,如持续时间和功率密度,可以提高该方法的效率。
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引用次数: 0
Technological properties of Paulownia and mixed poplar-Paulownia plywood 泡桐及混杨-泡桐胶合板的工艺性能
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-07-21 DOI: 10.1007/s00107-025-02291-3
Michela Nocetti, Michele Brunetti, Irene Criscuoli, Paola Mazzanti, Pasquale Murrone, Federico M. Stefanini, Giacomo Goli

Interest in paulownia cultivation is growing across Europe, highlighting the need to explore the properties of this material and its suitability for the different manufacturing processes. The study investigates the suitability of paulownia wood as raw material for plywood production, both as pure paulownia plywood and in combination with poplar, and compares the results with those of pure poplar plywood. For this research, paulownia trees were harvested from a six-year-old plantation in Northern Italy. The logs were peeled to produce veneers, which were then used to manufacture plywood panels. Veneers were classified based on surface appearance according to the European standard EN 365:1995, with the 46% rated as Excellent and the remaining 54% assigned to Class I. Plywood panels were produced using poplar, paulownia, and a mix of both species in a 5-ply configuration. These panels were evaluated for appearance, mechanical performance, and bonding quality. Bending tests were conducted in both longitudinal and transverse directions to determine the modulus of elasticity and strength; density was also measured. Bonding quality was assessed through shear tests after pretreatment, considering intended applications in both interior dry environments and exterior covered environments. Overall, paulownia plywood exhibited more surface defects, such as cracks, bubbles, and areas with adhesive exudation, compared to mixed poplar-paulownia panels. Its density was also lower than that of poplar and mixed panels. From the mechanical perspective, paulownia plywood showed lower strength and stiffness compared to poplar and mixed panels, with the mixed panels performing similarly to or slightly below poplar. While paulownia wood can be used for plywood production, it is most effective when used as internal layers in mixed panels with poplar.

对泡桐种植的兴趣在整个欧洲都在增长,强调需要探索这种材料的特性及其对不同制造工艺的适用性。研究了泡桐木作为胶合板原料的适宜性,无论是作为纯泡桐胶合板还是与杨木复合,并与纯杨木胶合板的适宜性进行了比较。在这项研究中,泡桐树是从意大利北部一个有六年历史的种植园中收获的。原木被剥皮制成单板,然后用于制造胶合板。根据欧洲标准EN 365:1995,根据表面外观对单板进行了分类,其中46%被评为优秀,其余54%被评为i级。胶合板由杨木、泡桐和两种树种混合制成,共5层。对这些面板的外观、机械性能和粘合质量进行了评估。在纵向和横向进行弯曲试验,以确定弹性模量和强度;密度也被测量。考虑到内部干燥环境和外部覆盖环境的预期应用,通过预处理后的剪切试验评估粘接质量。总体而言,与混合的杨木-泡桐板相比,泡桐胶合板表现出更多的表面缺陷,如裂缝,气泡和粘合剂渗出区域。其密度也低于杨木和混合板。从力学角度来看,泡桐胶合板的强度和刚度低于杨木和混合板,混合板的强度和刚度与杨木相近或略低于杨木。虽然泡桐木可以用于胶合板生产,但当它与杨木混合板用作内层时最有效。
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引用次数: 0
Effect of a thermo-mechanical densification process on selected properties of densified wood of Tasmanian oak and Eucalyptus nitens 热机械密实工艺对塔斯马尼亚橡木和桉树密实材性能的影响
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-07-19 DOI: 10.1007/s00107-025-02289-x
Benoit Belleville, Kyra C. Wood, Johannes Fehrmann

Regrowth Tasmanian oak and Eucalyptus nitens are fast-growing Australian plantation hardwoods widely cultivated in Tasmania. Despite their favourable physical and aesthetic properties, their relatively low density limits use to wood-chip production and minor interior applications. This study aimed to enhance the material properties of these species through thermo-mechanical densification. The effects of compression ratio, pressing time, and pressing temperature were evaluated on color change, set recovery (wet and dry), pull-off strength, and delamination. Eucalyptus nitens showed excellent color stability under all conditions (ΔE*ab < 5), while Tasmanian oak exhibited significant darkening at 175 °C (ΔE*ab 6.17–9.06). At 175 °C and 37% compression, E. nitens responded more strongly, achieving a mean wet-use set recovery of 0.0%, compared with 2.7% for Tasmanian oak. Both species showed significantly improved dimensional stability at 37% compression ratio compared to 25%. The highest F-values observed for Eucalyptus nitens and Tasmanian oak were 25.36 and 17.91, respectively. Increased compression also improved pull-off strength in both species, but in Tasmanian oak, extractive migration at 175 °C likely reduced coating adhesion. The densification process had minimal impact on bondability overall. However, a higher pressing temperature significantly reduced delamination in Tasmanian oak (P-value 0.031), while showing negligible effect in Eucalyptus nitens. The results suggest that both Eucalyptus nitens and Tasmanian oak species were stable following the densification process and would make the densified wood serviceable under conditions in which the EMC does not exceed 17% if unprotected. Statements and Declarations. All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by Benoit Belleville. The first draft of the manuscript was written by Benoit Belleville and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript. The authors have no relevant financial or non-financial interests to disclose. The authors have no competing interests to declare that are relevant to the content of this article. All authors certify that they have no affiliations with or involvement in any organization or entity with any financial interest or non-financial interest in the subject matter or materials discussed in this manuscript. The authors have no financial or proprietary interests in any material discussed in this article.

再生塔斯马尼亚橡树和桉树是在塔斯马尼亚广泛种植的快速生长的澳大利亚人工林硬木。尽管它们具有良好的物理和美学特性,但它们相对较低的密度限制了木屑生产和小型室内应用的使用。本研究旨在通过热机械致密化来提高这些物种的材料性能。考察了压缩比、压制时间和压制温度对颜色变化、定型恢复(干湿)、脱拉强度和分层的影响。桉树在所有条件下都表现出良好的颜色稳定性(ΔE*ab < 5),而塔斯马尼亚橡木在175°C时表现出明显的变暗(ΔE*ab 6.17-9.06)。在175°C和37%的压缩下,E. nitens的反应更强烈,实现了0.0%的平均湿利用集回收率,而塔斯马尼亚橡木的平均湿利用集回收率为2.7%。压缩比为37%和25%时,两种材料的尺寸稳定性均有显著提高。桉树和塔斯马尼亚橡树的f值最高,分别为25.36和17.91。增加压缩也提高了两种树种的拉脱强度,但在塔斯马尼亚橡木中,175°C的萃取物迁移可能会降低涂层的附着力。总体而言,致密化过程对粘结性的影响最小。然而,较高的压榨温度显著降低了塔斯马尼亚橡木的分层(p值为0.031),而对桉树的影响可以忽略不计。结果表明,在不加保护的情况下,在EMC不超过17%的条件下,黑桉和塔斯马尼栎的密实过程都是稳定的,可以使密实木材使用。声明和声明。所有作者都对研究的构思和设计做出了贡献。Benoit Belleville进行材料准备、数据收集和分析。手稿的初稿是由Benoit Belleville撰写的,所有作者都对以前的手稿版本进行了评论。所有作者都阅读并批准了最终的手稿。作者没有相关的财务或非经济利益需要披露。作者没有与本文内容相关的竞争利益要声明。所有作者证明,他们没有隶属关系或参与任何组织或实体与任何经济利益或非经济利益在这篇论文中讨论的主题或材料。作者在本文中讨论的任何材料中没有财务或专有利益。
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引用次数: 0
Enzymatic approach to accelerate the permeability and adhesion of raw bamboo epidermis 酶促竹材表皮通透性和黏附性的研究
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-07-19 DOI: 10.1007/s00107-025-02290-4
Xin Ren, Zijing Zhang, Qizheng Fan, Shuaibou Han, Hui Wang, Xinxing Wu, Yan Zhang, Fangli Sun, Renzhong Wei

Raw bamboo possesses wax layer, which endows the surface hydrophobic property but makes the anti-fungal chemicals enter difficultly. In this work, lipase was utilized to remove the wax layer from bamboo epidermis for increasing the permeability of raw bamboo. The lipase treatment was optimized as 24 h reaction in buffer solution with a pH value of 8.5 and a temperature of 40 ℃. The weight percentage gain (WPG) of water characterizing the permeability of raw bamboo was used to evaluate the treatment effect. In addition, the bonding strength of bamboo surface was assessed using epoxy resin to further investigate the effect of lipase treatment. Compared with untreated bamboo, WPG increased to 14.7% after 72 h, and the bonding strength improved from 0.01 MPa to 0.73 MPa. The phenomenon could be explained by the diminished contact angle of bamboo epidermis, which decreased from 102.4 °to 73.5 °. An in-depth study on how lipase improves the permeability of bamboo epidermis was investigated using the GC-MS, TG, and DSC analyses. This work provides a green processing method to increase the permeability of bamboo epidermis, which will be beneficial for enhancing the fungal and cracking resistance of raw bamboo through chemical impregnation or modification.

竹材表面有蜡层,蜡层赋予竹材表面疏水性,但使抗菌物质难以进入。本研究利用脂肪酶去除竹材表皮的蜡层,提高竹材的透气性。脂肪酶的最佳处理条件为:在pH为8.5、温度为40℃的缓冲液中反应24 h。用表征竹材透水性的增重百分比(WPG)来评价处理效果。此外,采用环氧树脂对竹材表面的结合强度进行评价,进一步考察脂肪酶处理的效果。与未处理竹材相比,72 h后WPG提高了14.7%,结合强度从0.01 MPa提高到0.73 MPa。竹材表皮的接触角从102.4°减小到73.5°。采用GC-MS、TG和DSC等分析方法,对脂肪酶提高竹表皮通透性的机理进行了深入研究。本工作提供了一种提高竹表皮透气性的绿色加工方法,有利于通过化学浸渍或改性提高原料竹的抗真菌性和抗开裂性。
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引用次数: 0
Fungal decay resistance, formaldehyde emission and weathering resistance of plywood modified with phenol-formaldehyde resin with partial substitution of phenol by pyrolysis cleavage products of softwood kraft lignin 软木硫酸盐木质素热解裂解产物部分取代苯酚的酚醛树脂改性胶合板的抗真菌腐烂性、甲醛释放性和耐风化性
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-07-19 DOI: 10.1007/s00107-025-02294-0
Johannes Karthäuser, Andreas Treu, Erik Larnøy, Holger Militz, Gry Alfredsen

Wood modification by impregnation with phenol-formaldehyde (PF) resins is a promising method to improve the woods’ fungal decay resistance, weathering resistance, and dimensional stability. Recent research indicates that 30% of the non-renewable phenol may be substituted by renewable softwood kraft lignin cleavage products obtained through microwave-assisted pyrolysis. Pinus sylvestris sapwood modified with this resin has good fungal decay resistance but slightly enhanced formaldehyde emission. While these results on solid wood indicate a high potential of the method, the properties of modified plywood may differ, and the weathering resistance has not been studied. In this study, formaldehyde emission, weathering resistance and fungal decay resistance against three basidiomycetes (Trametes versicolor, Rhodonia placenta, and Gloeophyllum trabeum) of plywood modified with pure PF resin and PF resin with 30% substitution of the phenol by lignin cleavage products were analysed. The 30% lignin cleavage product substitution didn’t affect the plywood’s fungal decay resistance, with less than 1% initial mass loss in all modified specimens. While the decay resistance improved significantly for all modified samples compared to reference samples, weathering resistance slightly declined with phenol substitution compared to pure PF resin modification. The formaldehyde emissions of the plywood modified with both resins were in similar ranges to that of unmodified reference plywood. Overall, plywood with good properties for exterior applications may be produced even with the substitution of 30% of the phenol by lignin cleavage products, allowing for increased use of renewable resources.

酚醛树脂浸渍改性木材是提高木材抗真菌腐烂、耐风化和尺寸稳定性的一种很有前途的方法。最近的研究表明,通过微波辅助热解获得的可再生软木硫酸盐木质素裂解产物可替代30%的不可再生苯酚。该树脂改性后的松材具有良好的抗真菌性,但甲醛释放量略有增加。虽然这些结果在实木上表明该方法具有很高的潜力,但改性胶合板的性能可能会有所不同,并且耐候性尚未研究。本研究分析了纯酚醛树脂改性胶合板和木质素裂解产物取代30%苯酚的酚醛树脂改性胶合板对三种担子菌(花斑Trametes versicolor, Rhodonia胎盘和Gloeophyllum trabeum)的甲醛释放量、耐候性和真菌腐烂性。30%木质素劈裂产物替代对胶合板的抗真菌腐蚀性能没有影响,所有改性样品的初始质量损失均小于1%。虽然与参考样品相比,所有改性样品的耐腐性都有显著提高,但与纯PF树脂改性相比,苯酚替代的耐候性略有下降。用这两种树脂改性的胶合板的甲醛释放量与未改性的参考胶合板相似。总的来说,即使用木质素裂解产物替代30%的苯酚,也可以生产出具有良好外部应用性能的胶合板,从而增加了可再生资源的使用。
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引用次数: 0
Guamuchil wood (Pithecellobium dulce) subjected to oxidation processes to increase transparency 瓜木经氧化处理以增加透明度
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-07-19 DOI: 10.1007/s00107-025-02287-z
Blanca K. Piedra-Ambriz, Salomon R. Vasquez-Garcia, Nelly Flores-Ramirez, Mauricio Ortiz-Gutiérrez, Leandro García-González, Lada Domratcheva-Lvova, José de Jesús Pérez-Bueno

The increasing demand for sustainable and transparent materials in construction has intensified interest in alternatives to conventional glass, which is known for its energy-intensive production, high carbon emissions, brittleness, and environmental impact. This study focuses on guamuchil wood (Pithecellobium dulce), recognized for its rapid growth, high hardness, and adaptability to arid environments, as a candidate for transparent wood applications. Unlike traditional delignification, which can damage wood, the photooxidative method used here preserves its integrity by partially modifying the wood under milder conditions. Thus, this study explores the enhancement of guamuchil wood transparency through a photooxidative process, an approach not previously applied to this species. Visual analysis revealed a progressive increase in transparency of guamuchil wood with UV exposure, reaching maximum clarity at 10 h (GW10) due to extensive chromophore degradation. Exposure beyond this point led to undesirable yellowing due to excessive oxidation. SEM analyses revealed the photooxidative treatment of guamuchil wood-induced cell wall thinning, increased cell diameter, and enhanced structural order. EDS showed a reduction in carbon content from 44.16 to 42.14% and an increase in oxygen content from 55.84 to 57.86%, indicating partial degradation of lignin. FTIR analysis confirmed these oxidative changes, showing decreased aromatic lignin peaks and increased hydroxyl and carbonyl signals, with lignin content reduced from 27.5 to 21.9%. The water contact angle decreased from 62.4° to 12.2°, reflecting increased surface hydrophilicity due to lignin degradation and the exposure of hydroxyl groups. These changes contributed to a substantial improvement in optical transmittance, rising from ~ 6% in untreated wood (GW0) to 19% in GW10 at 7 mm thickness, achieved without polymer infiltration. This demonstrates the effectiveness of the photooxidative process in enhancing transparency through selective lignin degradation and surface modification. This study demonstrates a novel photooxidative process to enhance guamuchil wood transparency, achieving significant optical improvement without polymer infiltration. The process selectively degrades lignin, offering a sustainable alternative to glass in construction with reduced environmental impact.

建筑中对可持续和透明材料的需求不断增加,这增强了人们对传统玻璃替代品的兴趣,传统玻璃以其能源密集型生产、高碳排放、脆性和环境影响而闻名。本研究的重点是石榴木(Pithecellobium dulce),其生长迅速,硬度高,适应干旱环境,被认为是透明木材的候选材料。与传统的去木质素作用不同,它会破坏木材,这里使用的光氧化方法通过在温和的条件下部分修改木材来保持其完整性。因此,本研究探讨了通过光氧化过程增强石榴木透明度,这是一种以前未应用于该物种的方法。视觉分析显示,随着紫外线照射,石榴木的透明度逐渐增加,由于广泛的发色团降解,在10小时达到最大透明度(GW10)。超过这一点的曝光会由于过度氧化而导致不希望的变黄。扫描电镜(SEM)分析显示,光氧化处理后的瓜木木细胞壁变薄,细胞直径增加,结构有序。EDS显示木质素部分降解,碳含量从44.16%降低到42.14%,氧含量从55.84%增加到57.86%。FTIR分析证实了这些氧化变化,显示芳香木质素峰减少,羟基和羰基信号增加,木质素含量从27.5%降至21.9%。水接触角从62.4°下降到12.2°,反映木质素降解和羟基暴露增加了表面亲水性。这些变化大大提高了木材的透光率,在没有聚合物渗透的情况下,未经处理的木材(GW0)的透光率从~ 6%上升到GW10的19%。这证明了光氧化过程通过选择性木质素降解和表面修饰来提高透明度的有效性。本研究展示了一种新的光氧化工艺,以提高石榴木的透明度,在没有聚合物渗透的情况下取得了显著的光学改善。该工艺选择性地降解木质素,为建筑中的玻璃提供了可持续的替代品,同时减少了对环境的影响。
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European Journal of Wood and Wood Products
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