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Performance degradation of glued-laminated timber beams under multi-factor environmental aging and sustained load 多因素环境老化和持续荷载作用下胶合层合木梁的性能退化
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2025-01-08 DOI: 10.1007/s00107-024-02189-6
Xueliang Wang, Xiao Zhang, Mingrong Zhang, Frank Lam, Minghao Li, Zhe Chen

Structural performance of timber buildings can be adversely affected by exposed harsh environment and sustained load. This study investigates bending performance degradation of glued laminated timber (GLT) beams (50 mm × 50 mm × 950 mm) that are exposed to unfavorable environmental conditions. The experiments consider eight scenarios, including various climate cycling periods, duration, and stress levels. Eight groups of GLT beams were exposed to the different scenarios for four stages, then loaded by short-term bending to obtain the MOR and MOE. The results showed that coupling effects of sustained loading and the environmental factors such as UV-light and mist spraying aggravated the pronounced damage on the laminates and gluelines and caused the degradation of strength and stiffness. The highest degradation rate occurred in the first stage. In the relatively mild environments, some performance recovery was observed in the later stages, most specimens exhibited ductile failure accompanied by the significant increase of the ultimate deflection with the exposure time. While in the harsh environments, the MOR and MOE degradation was evident and continuous, more specimens experienced brittle failure, and the increase of the ultimate deflection slowed down greatly with the exposure time. Additionally, the effects of sustained loading period were significantly exacerbated under the harsh environmental conditions, the specimens loaded by less than 50% stress level exhibited the distinguished degradation in 24 days.

暴露的恶劣环境和持续荷载会对木结构建筑的结构性能产生不利影响。本研究研究了暴露在不利环境条件下的胶合层压木材(GLT)梁(50mm × 50mm × 950 mm)的弯曲性能退化。这些实验考虑了八种情景,包括不同的气候循环周期、持续时间和压力水平。对8组GLT梁进行了4阶段的不同工况暴露,并进行了短期弯曲加载,获得了MOR和MOE。结果表明:持续载荷与环境因素(如紫外线照射、雾喷等)的耦合作用加剧了层合板和胶合线的明显损伤,导致层合板和胶合线的强度和刚度退化;降解速率最高的是第一阶段。在相对温和的环境中,后期性能有所恢复,大部分试件表现为延性破坏,极限挠度随暴露时间的增加而显著增加。而在恶劣环境下,试件的MOR和MOE降解明显且持续,脆性破坏较多,且极限挠度随暴露时间的增加幅度大大减缓。此外,在恶劣环境条件下,持续加载时间的影响显著加剧,加载低于50%应力水平的试件在24 d内表现出明显的降解。
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引用次数: 0
Measuring wood density of different tree species using the micro-drilling resistance method 用微钻阻力法测定不同树种木材密度
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2025-01-08 DOI: 10.1007/s00107-024-02193-w
Jianfeng Yao, Hengyuan Liu, Jun Lu

In order to reduce modeling workload and improve the accuracy of wood density measurement, a modeling method for establishing an overall model for multiple tree species was studied. Firstly, the wood cores and drill resistance of 9 tree species were collected. The absolute dry density, wood moisture content, and average drill resistance for each wood core were calculated. Secondly, the random forest algorithm was used to rank the relative importance of each factor affecting wood density, and factors with relative importance higher than 0.05 were selected as independent variables for building the overall mathematical model for total tree species and sub model for individual tree species. The results showed that: (1) the relative importance of tree species and drill resistance on wood density was higher than 0.05; (2) the relative importance of moisture content and drill usage frequency (less than 150 times) on wood density was lower than 0.05; (3) the average estimation accuracy of overall model was 91.42%, while that of the sub model was only 90.44%; (4) among the 9 tree species, the standard deviation of the overall model for 5 tree species was lower than that of the sub model. The results showed that the accuracy and stability of the overall model were superior to those of the sub models, and it is feasible to establish an overall model to estimate wood density.

为了减少建模工作量,提高木材密度测量的精度,研究了一种建立多树种整体模型的建模方法。首先采集了9种树种的木芯和抗钻性。计算了每个木芯的绝对干密度、木材含水率和平均钻阻。其次,采用随机森林算法对影响木材密度的各因子的相对重要度进行排序,选取相对重要度大于0.05的因子作为自变量,分别建立总树种的整体数学模型和单个树种的子模型;结果表明:(1)树种和钻阻对木材密度的相对重要性均大于0.05;(2)含水率和钻头使用频率(小于150次)对木材密度的相对重要性均小于0.05;(3)整体模型的平均估计精度为91.42%,而子模型的平均估计精度仅为90.44%;(4)在9种树种中,5种树种整体模型的标准差低于子模型的标准差。结果表明,整体模型的精度和稳定性优于子模型,建立整体模型估算木材密度是可行的。
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引用次数: 0
Mineralization of heat-treated fir wood with magnesium oxychloride: thermal characteristics and flame retardation 用氯化镁处理冷杉木材的矿化:热特性和阻燃性
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2025-01-06 DOI: 10.1007/s00107-024-02191-y
Mohammad Saleh Zare, Behbood Mohebby, Ali Shalbafan

The aim of this study was to improve the flame retardation and performance characteristics of wood through impregnation with magnesium-based compounds. Fir wood (Abies sp.) samples, both heat-treated and non-heat-treated, were impregnated with magnesium oxide and magnesium chloride using combined and separate methods. Impregnation was carried out under an initial vacuum followed by pressure. The effects of impregnation on the wood's structure, thermal properties, and fire resistance were investigated using FTIR spectroscopy, XRD analysis, TGA analysis, and flame retardation tests. FTIR, XRD, and TGA analyses confirmed increased thermal stability and crystallinity in impregnated samples, especially non-heat-treated samples. Wood impregnation with magnesium compounds extended the time to ignition, reduced flame duration, and decreased glowing combustion duration. Impregnation of samples resulted in a less carbonized surface. The lowest carbonized surface was observed in the combined-method impregnated non-heat-treated sample. Based on the results of this study, it can be concluded that the impregnation of heat-treated and non-heat-treated wood with magnesium compounds (oxide and chloride) was successful in improving flame retardation and performance characteristics.

本研究的目的是通过镁基化合物浸渍来改善木材的阻燃性和性能特性。冷杉木(Abies sp.)样品,热处理和未热处理,用氧化镁和氯化镁浸渍采用联合和单独的方法。浸渍是在最初的真空和随后的压力下进行的。采用红外光谱(FTIR)、x射线衍射(XRD)、热重分析(TGA)和阻燃试验研究了浸渍对木材结构、热性能和耐火性能的影响。FTIR, XRD和TGA分析证实,浸渍样品的热稳定性和结晶度有所提高,特别是未经热处理的样品。用镁化合物浸渍木材,可以延长木材的着火时间,减少火焰持续时间,减少发光燃烧持续时间。浸渍后的样品表面碳化程度较低。复合浸渍法未热处理样品的表面碳化程度最低。根据本研究的结果,可以得出结论,用镁化合物(氧化物和氯化物)浸渍热处理和非热处理木材成功地改善了阻燃性和性能特性。
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引用次数: 0
Machine learning based density estimation of light red meranti (Shorea spp.): a segmented approach to multiple regression of self-organising maps colour clusters using custom made ‘KayuSort’ colour sorting software 基于机器学习的浅红色莫兰蒂(Shorea spp.)密度估计:使用定制的“KayuSort”颜色分类软件对自组织地图颜色簇进行多元回归的分割方法
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2025-01-05 DOI: 10.1007/s00107-024-02188-7
Chiat Oon Tan, Ogata Shigenobu, Siew-Cheok Ng, Hwa Jen Yap, Zuriani Usop, Mohd ’Akashah Fauthan, Khairuddin Mahalil, Shaer Jin Liew

Wood density is an important characteristic of wood which correlates to its strength. This study proposes an algorithm using multiple regression on pre-segmented colour images of the wood to estimate the density of light red meranti (Shorea spp.) (LRM). Two batches of LRM timber were randomly selected from a factory (Batch 1: 119 samples, Batch 2: 79 samples). Timber samples were kiln-dried, free of sapwood and major visual defects, and freshly surfaced 2 sides. The apparent density and moisture content (MC) of each timber sample were measured. The samples were then imaged and colour-sorted using KayuSort, an in-house industrial timber colour sorting prototype that uses the self-organising map (SOM) algorithm. Otsu thresholding was applied to several different colour space components to obtain features. Multiple regression was applied to obtain an equation to estimate the density of the wood. Coefficients of determination ((hbox {R}^{2})) and 95(%) Limits of Agreement (LoA) were used to assess performance. Performing colour segmentation to the dataset using KayuSort for average (text {YC}_b{text{C}}_r) colour space scored an (hbox {R}^{2}) of 0.7109 and an LoA of ±146.8 (hbox {kgm}^{-3}). Therefore, it is possible to estimate the density of LRM using colour features of the wood using KayuSort, with the caveat that timber is kiln-dried to under 15% MC, freshly surfaced, without major defects and sapwood, and within the thickness range of 26.9 to 30.6 mm.

木材密度是木材的一个重要特性,它关系到木材的强度。本研究提出了一种对预分割的木材彩色图像使用多元回归的算法来估计浅红色莫兰蒂(Shorea spp.) (LRM)的密度。从一家工厂随机抽取两批LRM木材(第1批:119个样品,第2批:79个样品)。木材样品是窑干的,没有边材和主要的视觉缺陷,表面是新鲜的。测定了各木材样品的表观密度和含水率。然后使用KayuSort对样品进行成像和颜色分类,KayuSort是一种使用自组织地图(SOM)算法的内部工业木材颜色分类原型。将Otsu阈值法应用于多个不同的色彩空间分量来获得特征。采用多元回归方法得到木材密度的估计方程。使用决定系数((hbox {R}^{2}))和95 (%)一致限(LoA)来评估绩效。使用KayuSort对数据集进行平均(text {YC}_b{text{C}}_r)颜色空间的颜色分割,得分(hbox {R}^{2})为0.7109,LoA为±146.8 (hbox {kgm}^{-3})。因此,使用KayuSort使用木材的颜色特征来估计LRM的密度是可能的,需要注意的是木材是窑干到15以下的% MC, freshly surfaced, without major defects and sapwood, and within the thickness range of 26.9 to 30.6 mm.
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引用次数: 0
Wood density of 38 Dalbergia and 29 Diospyros Malagasy species and its relationship with climate and tree diameter 38种黄檀和29种马达加斯加木的木材密度及其与气候和树径的关系
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2025-01-03 DOI: 10.1007/s00107-024-02162-3
Andry Clarel Raobelina, Jean-Michel Leban, Caroline Christina Jaozandry, Tahiana Ramananantoandro

Several Malagasy Dalbergia and Diospyros species are highly valued, in the furniture industry despite limited understanding of their wood technological properties. This study contributes to address this gap by assessing the wood density (WD) of 38 Dalbergia and 29 Diospyros species, their radial WD variation, and the influence of climate and tree size on WD. WD was measured on 297 wood cores using X-ray computed tomography. One-way analysis of variance revealed that Diospyros genus (1.070 ± 0.165 g∙cm−3) has significantly denser heartwood compared to Dalbergia (0.961 ± 0.142 g∙cm−3). Heartwood density also showed greater between-species variation, allowing the identification of eleven groups of Dalbergia and seven groups of Diospyros, each with significantly different heartwood density ranges. For radial density profile assessment, each of the 52 cores having the pith-to-bark part of the wood, was divided into ten equal length segments. Anova between mean WD of the core segments, combined with correlation tests between the average density of each segment and its distance from the pith, showed that radial wood density profile varied among species. Most species exhibited a decreasing radial WD profile. Correlation tests between tree diameter, climatic factors, and wood density demonstrated that, for both genera, wood density increases with rising temperature and decreasing precipitation at the growth site, while tree diameter has no significant effect on density. These findings significantly enrich the wood density database for Malagasy precious wood species, which previously existed for only a very few species.

几个马达加斯加黄檀和Diospyros物种被高度重视,在家具行业,尽管有限的了解他们的木材技术特性。本研究通过对38种黄檀和29种黄檀树种的木材密度、径向密度变化以及气候和乔木大小对木材密度的影响进行了研究。使用x射线计算机断层扫描测量了297个木芯的WD。单因素方差分析显示,薯蓣属(1.070±0.165 g∙cm−3)的心材密度显著高于黄檀属(0.961±0.142 g∙cm−3)。心材密度也表现出较大的种间差异,鉴定出11个黄檀属类群和7个黄檀属类群,每个类群的心材密度范围都有显著差异。对于径向密度剖面评估,52个具有木材髓到树皮部分的岩心中的每一个都被划分为十个等长的部分。各核心节段平均WD的方差分析,以及各节段平均密度与距髓距离的相关性检验表明,木材径向密度分布在不同树种之间存在差异。大多数物种的径向WD分布呈递减趋势。树径、气候因子与木材密度的相关分析表明,两属木材密度均随生长地温度升高和降水减少而增加,而树径对密度的影响不显著。这些发现极大地丰富了马达加斯加珍贵木材物种的木材密度数据库,该数据库以前只存在于极少数物种中。
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引用次数: 0
Determination of the water diffusivity dependence with the flow rate using a DVS equipment 用DVS设备测定水扩散率与流速的关系
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2025-01-02 DOI: 10.1007/s00107-024-02182-z
Antoni Sánchez-Ferrer, Max Engelhardt

The effects on the measurement of water sorption and apparent diffusivity when using different flow rate values and different experimental setups, i.e., closed pan, open pan and hanging setup, have been studied in a series of Dynamic Vapor Sorption (DVS) experiments on a spruce sample. The results confirm a concave exponential growth dependency between apparent diffusivity and flow rate and an effect from the setup used, with the hanging setup being optimal for conducting such experiments due to the exposure of both areas of the disk to the airflow.

在云杉样品上进行了动态蒸汽吸附(DVS)实验,研究了不同流量值和不同实验设置(闭式、开式和悬挂式)对云杉样品吸水率和表观扩散率测量的影响。结果证实了表观扩散率和流速之间的凹指数增长依赖关系,以及所使用的设置效果,由于磁盘的两个区域都暴露于气流,悬挂设置是进行此类实验的最佳选择。
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引用次数: 0
Phenol formaldehyde resin impregnation of spruce wood to improve the dimensional stability and acoustic performance of harp soundboards 用酚醛树脂浸渍云杉木材,提高竖琴音板的尺寸稳定性和声学性能
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2025-01-02 DOI: 10.1007/s00107-024-02180-1
Taiki Okada, Eiichi Obataya, Shin-ichiro Yokota, Hiroshi Okumura

To prevent cracks in the wooden soundboards of harps while maintaining its acoustic performance, Sitka spruce wood was impregnated with phenol formaldehyde (PF) resin. PF treatment significantly improved the dimensional stability of wood through the bulking effect of the PF resin introduced into the wood cell wall. Highly moistened wood was fixed at its ends and dried. The unmodified wood failed owing to drying stress, whereas the PF-treated wood did not fail because of its excellent dimensional stability. In addition, PF treatment was found to significantly reduce the internal friction of the wood, resulting in an improvement in the acoustic conversion efficiency. These results suggest that PF resin impregnation is a promising method for preventing the cracking of soundboards without degrading their acoustic quality. By contrast, the PF resin migrated around the surface, from which the solvent evaporated. If we need to modify the wood uniformly along the longitudinal (L) direction, its ends or cross-sections should be closed to prevent the migration of the PF resin along the L direction during solvent removal. It is practically difficult to prevent the condensation of the PF resin around the straight-grained surface when a large-dimensional soundboard is impregnated with PF resin. However, the results of a simulation using a multilayered model predicted that such condensation did not adversely affect the acoustic quality of the soundboard.

为了防止竖琴的木制音板出现裂缝,同时保持其声学性能,锡特卡云杉木材浸渍了酚醛(PF)树脂。酚醛处理通过引入木材细胞壁的酚醛树脂的膨胀作用,显著提高了木材的尺寸稳定性。高度湿润的木头被固定在它的两端,然后干燥。未经改性的木材由于干燥应力而失效,而经过pf处理的木材由于其优异的尺寸稳定性而不会失效。此外,发现PF处理可以显著降低木材的内摩擦,从而提高声转换效率。这些结果表明,酚醛树脂浸渍是一种很有前途的防止音板开裂而不降低音质的方法。相比之下,酚醛树脂在表面周围迁移,溶剂从表面蒸发。如果我们需要沿着纵向(L)方向均匀地修改木材,则应关闭其末端或横截面,以防止溶剂去除过程中PF树脂沿L方向迁移。当大尺寸音板浸渍PF树脂时,实际上很难防止PF树脂在直纹表面周围的凝结。然而,使用多层模型的模拟结果预测,这种冷凝不会对音板的音质产生不利影响。
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引用次数: 0
A method of using a combination of multiple chemical additives to improve the performance of wood (round tenon) rotary friction welding 一种使用多种化学添加剂组合改善木材(圆榫)旋转摩擦焊接性能的方法
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2025-01-02 DOI: 10.1007/s00107-024-02174-z
Jiawei Wu, Jiarong He, Yang Yang, Lei Zhang, Jijuan Zhang, Zhongfeng Zhang

The existing research mainly improves the performance of wood (round tenon) rotating welded specimens by using a single type of additive. Due to the single type of chemical additive used, the performance of welded specimens is limited. Therefore, we have found a joint pretreatment modification method that can simultaneously improve the waterproof, mechanical, and environmental adaptability of welded specimens. It mainly includes: the CA group (calcium carbonate and oleic acid treatment) and, the CN group (Na2SO3 and CuSO4 oxidation sulfonation treatment). Techniques such as scanning electron microscopy, mechanical testing (Wood Nail Grip Strength testing and Water Resistance Test testing), Fourier transform infrared spectroscopy, X-ray diffraction, and pyrolysis gas chromatography–mass spectrometry were utilized to assess the welded interfaces. Methods including pyrolysis gas chromatography-mass spectrometry, Fourier transform infrared spectroscopy, mechanical testing, X-ray diffraction, and scanning electron microscopy were employed to evaluate the welded interfaces. Following the treatments, the interfaces displayed a grout-like layered structure with increased amounts of cellulose and lignin, enhancing intramolecular cohesion. Hydrogen bonding of oleic acid-stearic acid and tetrahydrofuran (THF) and high molecular weight aromatic methoxy groups were generated at the welding interface of the CA group. Consequently, this leads to a significant improvement in the mechanical properties and water resistance of the rotating welding interface, which in turn enhances the environmental adaptability of the welded specimen. Excluding the CN group, all samples met the ≥ 0.7 MPa strength criterion set by GB/T 14018–2009 “Test Method for Wood Nail Grip Strength” in China, with the CA group showing superior interface performance, In addition, the calcium carbonate whiskers in the CA group enhanced the mechanical properties of the welded specimens, but weakened the water resistance, which led to a large difference between dry and wet in the CA group. The CN group enhances the activity of lignin due to the oxidative sulfonation reaction, maintains a certain viscosity of the welding interface, and is resistant to water. Therefore, although the overall welding strength is low, there is no dry and wet difference in this group.

现有的研究主要是通过使用单一类型的添加剂来改善木材(圆榫)旋转焊接试件的性能。由于使用的化学添加剂种类单一,焊接试样的性能受到限制。因此,我们找到了一种可以同时提高焊接试件防水、力学和环境适应性的接缝预处理改性方法。主要包括:CA组(碳酸钙和油酸处理)和CN组(Na2SO3和CuSO4氧化磺化处理)。利用扫描电镜、力学测试(木钉抓握强度测试和水阻力测试)、傅里叶变换红外光谱、x射线衍射、热解气相色谱-质谱等技术对焊接界面进行了评估。采用热解气相色谱-质谱、傅里叶变换红外光谱、力学测试、x射线衍射和扫描电镜等方法对焊接界面进行了表征。经过处理后,界面呈现出类似浆液的层状结构,纤维素和木质素的含量增加,增强了分子内凝聚力。在CA基团的焊接界面处生成了油酸-硬脂酸与四氢呋喃(THF)的氢键和高分子量芳香族甲氧基。因此,这导致旋转焊接界面的力学性能和耐水性显著改善,从而增强了焊接试样的环境适应性。除CN组外,所有试样均满足中国GB/T 14018-2009《木钉抓力试验方法》规定的强度≥0.7 MPa标准,且CA组界面性能优越,且CA组中碳酸钙晶须增强了焊接试样的力学性能,但削弱了耐水性,导致CA组干湿差异较大。CN基团由于氧化磺化反应增强了木质素的活性,保持了焊接界面的一定粘度,并具有耐水性。因此,虽然整体焊接强度较低,但该组没有干湿差异。
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引用次数: 0
Wood-fiber insulation boards produced with polylactic acid as a binder by hot press and hot air 以聚乳酸为粘结剂,采用热压和热风法制备的木纤维保温板
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2025-01-02 DOI: 10.1007/s00107-024-02153-4
Aldo Joao Cárdenas-Oscanoa, Lawrence Tene Tayo, Caoxing Huang, Chen Huang, Darshan Shivappa Nayaka, Markus Euring

Traditionally, there are two types of wood fiber insulation boards (WFIB), the rigid ones produced in the industry by a continuous steam process, bonded with polymer diphenylmethane diisocyanate (pMDI), with densities between 80 and 200 kg/m3, and the flexible ones with densities under 80 kg/m3 produced by hot air, usually with bicomponent fibers as a binder. In this work, wood fiber insulation boards (WFIB) were produced with polylactic acid (PLA) as a binder by hot press (HP) and hot air (HA). WFIB with densities of 60 kg/m3, 80 kg/m3, 100 kg/m3 and 5%, 10% and 15% of PLA percentage were produced by hot press (HP) and hot air (HA). Wood and PLA fibers were examined by scanning electronic microscope (SEM) and optical microscope. The WFIB were assessed for physical properties as density and short-term water absorption as well as for their resistance to compression as a mechanical property. Thermal properties such as thermal conductivity and thermogravimetric analysis (TGA) were also tested. In the produced WFIB, the values of density follow the same pattern as water absorption, compression strength, and thermal conductivity. The polylactic acid (PLA) content improves mechanical value like compression and diminishes physical value such as short-term water absorption in WFIB. In conclusion, wood fiber insulation boards (WFIB) were successfully produced with polylactic acid (PLA) as a binder, by hot press (HP) and hot air (HA), reaching remarkably lower thermal conductivity values, comparable with commercial ones.

传统上,有两种类型的木纤维绝热板(WFIB),工业上通过连续蒸汽工艺生产的刚性板,与聚合物二苯基甲烷二异氰酸酯(pMDI)粘合,密度在80至200 kg/m3之间;柔性板,密度在80 kg/m3以下,由热空气生产,通常以双组分纤维作为粘合剂。以聚乳酸(PLA)为粘结剂,采用热压(HP)和热空气(HA)法制备木纤维绝热板(WFIB)。采用热压法(HP)和热空气法(HA)制备密度分别为60、80、100 kg/m3和5%、10%、15% PLA的WFIB。采用扫描电子显微镜(SEM)和光学显微镜对木材和PLA纤维进行了检测。对WFIB的物理性能进行了评估,如密度和短期吸水率,以及其抗压缩性作为机械性能。热性能,如导热系数和热重分析(TGA)也进行了测试。在生产的WFIB中,密度值与吸水率、抗压强度和导热系数具有相同的规律。聚乳酸(PLA)的含量提高了WFIB的压缩等力学值,降低了短期吸水等物理值。综上所述,以聚乳酸(PLA)为粘结剂,通过热压(HP)和热空气(HA)成功地生产了木纤维绝热板(WFIB),其导热系数明显低于商用绝热板。
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引用次数: 0
Impact of a 2-year environmental exposure on colour, structure and chemistry of cork 2年环境暴露对软木塞颜色、结构和化学的影响
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2025-01-02 DOI: 10.1007/s00107-024-02155-2
Isabel Miranda, Ana Lourenço, Helena Pereira

A field test with two-year-long exposure of natural cork to aboveground and underground conditions was carried out with analysis of CIELAB colour parameters, cellular features by scanning electron microscopy, and surface chemistry by ATR-FTIR. The impact of weathering and soil burial was different regarding changes in colour and surface chemistry. Under atmospheric exposure to weather, cork was bleached (ΔE* 17.1) mainly due to the photooxidation of lignin by UV-radiation and hemicellulose degradation, with suberin remaining mostly unaffected. With soil burial, cork darkened (ΔE* 19.7) while significant depolymerization and degradation of suberin and hemicelluloses occurred in addition to lignin alteration. Only the external one-cell layer at the surface was affected with some cellular expansion and minute cell wall fractures, while the material maintained its characteristics without damage or deterioration signs. The cork weathering features are indicative that it can be used in outdoor applications such as building façades or external equipment, with only surface colour dynamics to be taken into account.

将天然软木暴露在地上和地下条件下进行了为期两年的现场测试,并通过扫描电子显微镜分析了CIELAB颜色参数、细胞特征以及ATR-FTIR分析了表面化学成分。在颜色和表面化学变化方面,风化和土壤掩埋的影响是不同的。在大气中暴露于天气下,软木被漂白(ΔE* 17.1),主要是由于木质素被紫外线辐射光氧化和半纤维素降解,而木质素基本不受影响。随着土壤掩埋,软木变暗(ΔE* 19.7),木质素和半纤维素发生了显著的解聚和降解。只有表面的外部单细胞层受到一些细胞膨胀和微小细胞壁断裂的影响,而材料保持其特性,无损伤或劣化迹象。软木的耐候特性表明,它可以用于室外应用,如建筑外墙或外部设备,只需要考虑表面颜色动态。
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引用次数: 0
期刊
European Journal of Wood and Wood Products
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