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Research on the effectiveness of renewable portfolio standard policy in promoting energy structure transformation of power generation enterprises 可再生能源发电组合标准政策促进发电企业能源结构转型的有效性研究
IF 7 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-01 DOI: 10.1016/j.seta.2026.104815
Yang Tian , Kaikai Mao , Juan Yang , Langxuan Pan
Energy structure transformation of power generation enterprises is the key to achieving power low-carbon transformation. Renewable portfolio standard (RPS) is widely used to promote energy structure transformation. However, the mechanisms by which RPS affect energy structure transformation, and the optimal design of RPS have not been thoroughly explored yet. To address this gap, this study aims to explore the regulatory effects of fixed quotas and dynamic quotas on the energy structure transformation of power generation enterprises. Results indicate that both types of quotas can effectively promote the energy structure transformation of power generation enterprises with low proportion of renewable energy electricity. However, for power generation enterprises with high proportion of renewable energy electricity, fixed quotas may lose incremental effectiveness, and dynamic quotas may alleviate this specific effect. The research results provide policy implications for optimizing RPS policy and promoting enterprise energy transformation.
发电企业的能源结构转型是实现电力低碳转型的关键。可再生能源投资组合标准(RPS)被广泛用于促进能源结构转型。然而,RPS影响能量结构转换的机理以及RPS的优化设计尚未得到深入的探讨。为了弥补这一空白,本研究旨在探讨固定配额和动态配额对发电企业能源结构转型的调控效果。结果表明,两种配额制都能有效促进可再生能源发电比例较低的发电企业能源结构转型。但对于可再生能源电力占比较高的发电企业来说,固定配额可能会失去增量效应,而动态配额可能会缓解这一特定效应。研究结果为优化RPS政策,促进企业能源转型提供了政策启示。
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引用次数: 0
Smart solar panel diagnostics: Integrating YOLOv12 with custom CNN for fault detection and classification 智能太阳能电池板诊断:集成YOLOv12与定制CNN进行故障检测和分类
IF 7 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-01 DOI: 10.1016/j.seta.2026.104861
Sunila Arshid Mohammed Kassim, Di Zhang
Reliable and scalable photovoltaic (PV) fault monitoring ensures high energy efficiency and low operational costs of large-scale solar farms. This paper proposes a new two-step deep learning-based architecture which combines the attention-based YOLOv12 detector with a small custom CNN to classify fine-grained PV defects. In contrast to the current single stage designs, the proposed design does not depend on fault localization and severity to classify faults. This enhances the ability of the design to resist small and visually insignificant faults like micro-cracks, dust, and hotspots without compromising edge placement capability. It is shown that the framework has good generalization and practical viability as indicated by the cross-dataset evaluation, ablation studies, and edge-device benchmarking. Experimental evidence demonstrates that it has high detection rates with an [email protected] of 98.7%, recall of 98.8%, and real time inference on embedded devices.
可靠和可扩展的光伏(PV)故障监测确保了大型太阳能发电场的高能效和低运营成本。本文提出了一种新的基于两步深度学习的结构,将基于注意力的YOLOv12检测器与小型自定义CNN相结合,对细粒度PV缺陷进行分类。与目前的单级设计相比,该设计不依赖于故障定位和严重程度来对故障进行分类。这增强了设计抵御微小和视觉上不显著的故障(如微裂纹,灰尘和热点)的能力,而不会影响边缘放置能力。跨数据集评估、消融研究和边缘设备基准测试表明,该框架具有良好的泛化和实用可行性。实验证据表明,它具有很高的检测率,[email protected]为98.7%,召回率为98.8%,并且在嵌入式设备上具有实时推断能力。
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引用次数: 0
Dynamic analysis of energy -water synergy technologies for regional power generation with prospective LCA towards carbon neutrality 区域发电的能源-水协同技术动态分析与未来的LCA走向碳中和
IF 7 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-01 DOI: 10.1016/j.seta.2026.104845
Peize Wu , Yingying Liu , Lantian Zhang , Sha Chen , Sumei Li , Hanbing Li , Ji Gao , Kejun Jiang
The regional energy transition under the goal of carbon neutrality confronts both constraints of energy water scarcities, with energy-water nexus critically shaping sustainable pathways. Climate change impacts must also be assessed when analyzing water resource constraints. This study established a method for evaluating energy-water synergy technologies in regional transition scenarios based on prospective life cycle assessment (PLCA), which used the data from Low Emissions Analysis Platform (LEAP) scenario inventories linked with LCI parameters. Subsequently, this method was applied to evaluate five environmental impacts (ADP, EP, FAETP, GWP, TFU) of Polycrystalline silicon photovoltaic power generation technology, Onshore wind power generation technology, and Coal-fired power generation deployed nine different carbon capture technologies in Shaanxi Province from 2020 to 2060. The results showed that Onshore wind power generation technology exhibited minimal environmental impacts (EIs) in 2020, while deploying post-combustion membrane carbon capture will greatly reduce the impacts of coal-fired power generation. Renewable energy impacts are concentrated in material production, while over 90% of carbon capture system impacts occur during operation. Except for Onshore wind power generation technology, other energy-water synergy technologies reducing more than 20% EIs, driven by decarbonized material production for renewables and optimized adsorption efficiency in carbon capture systems. Considering the constraints and technological maturity of different development stages, Shaanxi should prioritize wind and photovoltaic power generation expansion before 2030, scale solar-wind hybrid systems during 2030–2060, and deploy physical adsorption-based post-combustion technologies for coal-fired power generation. This study provided decision support for similar regions choosing energy-water synergy technologies under energy transition.
碳中和目标下的区域能源转型面临着能源水资源短缺的双重制约,能源-水关系对可持续发展路径的塑造至关重要。在分析水资源制约因素时,还必须评估气候变化的影响。本研究利用低排放分析平台(LEAP)情景清单数据,结合LCI参数,建立了基于前瞻性生命周期评估(PLCA)的区域转型情景中能源-水协同技术评价方法。随后,应用该方法评估了2020 - 2060年陕西省多晶硅光伏发电技术、陆上风电发电技术和燃煤发电采用9种不同碳捕集技术的5项环境影响(ADP、EP、FAETP、GWP、TFU)。结果表明,2020年陆上风力发电技术的环境影响最小,而采用燃烧后膜碳捕集技术将大大降低燃煤发电的环境影响。可再生能源的影响集中在材料生产中,而超过90%的碳捕获系统影响发生在运行过程中。除陆上风力发电技术外,其他能源-水协同技术在可再生能源脱碳材料生产和碳捕集系统吸附效率优化的推动下,减少了20%以上的环境影响指数。考虑到不同发展阶段的制约条件和技术成熟度,陕西应在2030年前优先扩大风电和光伏发电,在2030 - 2060年期间扩大太阳能-风能混合发电系统,并在燃煤发电中部署基于物理吸附的燃烧后技术。该研究为类似地区在能源转型背景下选择能源-水协同技术提供了决策支持。
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引用次数: 0
Potential path from demonstration to commercialisation of high temperature gas-cooled reactors for cogeneration of heat and hydrogen 用于热电联产的高温气冷反应堆从示范到商业化的潜在途径
IF 7 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-01 DOI: 10.1016/j.seta.2026.104844
Janusz Malesa, Błażej Chmielarz, Dominik Muszyński, Maciej Skrzypek
The transition to sustainable energy systems requires advanced nuclear technologies capable of providing high-temperature heat and hydrogen for industrial applications. High Temperature Gas-cooled Reactors (HTGRs) have emerged as a promising option for cogeneration, enabling flexible deployment across multiple scales and sectors. This study explores the potential path from technology demonstration to commercialisation of HTGRs, with particular emphasis on their application to industrial cogeneration. The paper describes the design philosophy and target applications, highlighting end-user requirements and technical configurations for both HTGR-POLA and the GEMINI+ reactor design. Safety aspects are examined to assess inherent and engineered features supporting deployment. A techno-economic evaluation, based on defined assumptions and modelling approaches, provides insights into cost, performance, and competitiveness relative to alternative energy systems. The findings demonstrate that HTGR-based cogeneration can meet diverse industrial needs while contributing to decarbonisation goals. However, successful commercialisation requires a stepwise approach from pilot-scale demonstrations to market entry, supported by favourable policies, regulatory alignment, and stakeholder engagement.
向可持续能源系统的过渡需要能够为工业应用提供高温热能和氢气的先进核技术。高温气冷堆(htgr)已成为热电联产的一个有前途的选择,可以在多个规模和部门灵活部署。本研究探讨高温高温堆从技术示范到商业化的潜在途径,特别强调其在工业热电联产中的应用。本文描述了设计理念和目标应用,重点介绍了HTGR-POLA和GEMINI+反应堆设计的最终用户需求和技术配置。检查安全方面以评估支持部署的固有和工程特性。基于确定的假设和建模方法的技术经济评估,提供了相对于替代能源系统的成本、性能和竞争力的见解。研究结果表明,基于htr的热电联产可以满足多种工业需求,同时有助于实现脱碳目标。然而,成功的商业化需要从试点规模的示范到进入市场的逐步方法,并得到有利政策、监管协调和利益相关者参与的支持。
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引用次数: 0
A piezoelectric-electromagnetic hybrid energy harvester achieves frequency up-conversion through an integrated lever and gear mechanism 压电-电磁混合能量采集器通过集成杠杆和齿轮机构实现频率上变频
IF 7 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-02-01 DOI: 10.1016/j.seta.2026.104852
Zhongyuan Miao, Yuchao Yang, Xinyu Fang, Mingbo Wang, Ziming Zhou, Lipeng He
Currently, wireless sensor nodes rely on battery power—with limited lifespan, cumbersome replacement, and environmental pollution. Harnessing ambient energy such as road vibrations provides them with continuous green power, cutting maintenance costs and boosting reliability. Yet significant limitations remain in harvesting road-generated low-frequency vibrations. To address these challenges, this paper proposes a piezoelectric-electromagnetic hybrid energy harvester that employs a lever-gear frequency up-conversion mechanism (L-PEH). It innovatively integrates a lever amplification mechanism and a gear transmission system. Through the synergistic effects of displacement amplification, motion transfer, and rotational speed conversion, this device effectively improves the energy harvesting efficiency and output power for low-frequency vibration. Experimental results demonstrate that under 3 Hz excitation frequency and optimal parameters (a lever length of 20 mm, a magnetic gap of 8 mm), the piezoelectric unit achieves a peak voltage of 29.65 V. The entire device delivers a maximum output power of 5.54 mW under a 300 kΩ load, successfully charging a 470 μF capacitor and driving 32 LEDs. This device not only demonstrates superior energy harvesting and power output capabilities within the low-frequency range but also provides a viable self-powered solution for wireless sensor nodes and low-power monitoring devices for smart roads.
目前,无线传感器节点依赖于电池供电-寿命有限,更换麻烦,环境污染。利用道路振动等环境能量为汽车提供持续的绿色能源,降低维护成本,提高可靠性。然而,在收集道路产生的低频振动方面仍然存在重大限制。为了解决这些挑战,本文提出了一种采用杠杆齿轮变频机构(L-PEH)的压电-电磁混合能量采集器。它创新地集成了杠杆放大机构和齿轮传动系统。该装置通过位移放大、运动传递和转速转换的协同作用,有效提高了能量收集效率和低频振动输出功率。实验结果表明,在3 Hz的激励频率和最优参数(杠杆长度为20 mm,磁隙为8 mm)下,压电单元的峰值电压为29.65 V。整个器件在300 kΩ负载下提供5.54 mW的最大输出功率,成功地为470 μF的电容器充电并驱动32个led。该设备不仅在低频范围内展示了卓越的能量收集和功率输出能力,而且还为智能道路的无线传感器节点和低功耗监控设备提供了可行的自供电解决方案。
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引用次数: 0
Review on the intersection of materials science and policy: a dual-track approach to realizing a green hydrogen economy for climate-neutral energy transition 回顾材料科学与政策的交叉:实现绿色氢经济以实现气候中和能源转型的双轨途径
IF 7 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-01-22 DOI: 10.1016/j.seta.2026.104831
Haruna Adamu , Usman Bello , Usman Ibrahim Tafida , Zakariyya Uba Zango , Khuzaifa Yahuza Muhammad , Mohammad Qamar
A sustainable energy transition critically depends on the successful development and deployment of green hydrogen (G-H2). However, achieving this goal requires addressing a complex interplay of technological, economic, and policy-related challenges. This review explores the key factors influencing the production and adoption of G-H2, including materials and catalyst chemistries, and policy integration. Key discussions center on the global G-H2 projects implementation assessment, which reveals a critical need for technological advancements in materials and catalysts to improve the efficiency and competitiveness of G-H2 energy, while formulating an optimal strategic policy to achieve net-zero carbon emissions for climate action, including the most effective G-H2 strategy, is a difficult task. In addition, various decarbonization solutions exist, with their comparative costs and benefits persistently evolving due to the pace of innovation and technological development advancements. As a result, governments are tightened with difficult choices to make on which of the technology strategies best fit the energy future of their countries, while avoiding the risks of locking in less efficient or slower emissions reduction pathways. For this reason, setting clear policy priorities is an important component for successful G-H2 policy making towards integrating G-H2 into the global energy system for sustainable, climate-neutral energy transition.
可持续的能源转型关键取决于绿色氢(G-H2)的成功开发和部署。然而,实现这一目标需要解决技术、经济和政策相关挑战的复杂相互作用。本文综述了影响G-H2生产和采用的关键因素,包括材料和催化剂化学以及政策整合。关键讨论集中在全球G-H2项目实施评估上,这表明迫切需要在材料和催化剂方面取得技术进步,以提高G-H2能源的效率和竞争力,而制定实现气候行动净零碳排放的最佳战略政策,包括最有效的G-H2战略,是一项艰巨的任务。此外,存在各种脱碳解决方案,由于创新和技术发展的步伐,其相对成本和效益不断变化。因此,各国政府面临着艰难的选择,既要做出最适合本国能源未来的技术战略,又要避免锁定效率较低或减排速度较慢的途径的风险。因此,制定明确的政策重点是成功制定G-H2政策的重要组成部分,从而将G-H2纳入全球能源系统,实现可持续的气候中性能源转型。
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引用次数: 0
Comparative review of imaging and non-imaging solar concentrators for hybrid photovoltaic–thermal applications 光电热混合应用的成像和非成像太阳能聚光器的比较综述
IF 7 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-01-22 DOI: 10.1016/j.seta.2026.104839
Putta Venu Gopal , P.V. Elumalai , A. Saravanan
Growing clean energy and freshwater needs have driven attention toward hybrid PV/T systems with combined electrical and thermal output. Solar concentrators are widely used in PV/T systems to increase energy production by directing incident solar radiation onto the receiver. The performance of a concentrator integrated with PV/T systems is mainly dependent on the concentrator type, concentration ratio, cooling technique, tracking and application type. This review is an in-depth assessment of the application-based non-imaging and imaging solar concentrators integrated with hybrid PV/T systems. The non-imaging concentrators consist of V-troughs, compound parabolic concentrators (CPCs), and asymmetric CPCs are reviewed for low and medium-temperature applications such as water heating, solar drying, space heating, and domestic-scale desalination systems. Imaging concentrators such as Fresnel lenses and parabolic trough collectors are used in high-temperature and large-scale applications. In addition, the review highlights key challenges such as non-uniform flux distribution and hotspot formation and overcoming strategies using optical homogenizers, secondary reflectors, bifacial receivers, and different cooling methods. The study compares different types of passive and active cooling methods, along with tracking technologies, based on concentration level and system requirements. The study concluded with a clear road map for selecting suitable concentrator-cooling tracking combinations for specific applications.
日益增长的清洁能源和淡水需求促使人们关注结合电和热输出的混合PV/T系统。太阳能聚光器广泛应用于PV/T系统中,通过将入射太阳辐射引导到接收器上来增加能量产量。与PV/T系统集成的聚光器的性能主要取决于聚光器类型、浓缩比、冷却技术、跟踪和应用类型。本文综述了基于应用的非成像和成像太阳能聚光器与混合PV/T系统集成的深入评估。非成像聚光器包括v型槽、复合抛物面聚光器和非对称聚光器,主要用于中低温应用,如水加热、太阳能干燥、空间加热和家庭规模的海水淡化系统。成像集中器,如菲涅耳透镜和抛物面槽集热器用于高温和大规模应用。此外,综述还强调了使用光学均质器、二次反射器、双面接收器和不同冷却方法克服非均匀通量分布和热点形成等关键挑战。该研究比较了不同类型的被动和主动冷却方法,以及基于浓度水平和系统要求的跟踪技术。该研究总结了为特定应用选择合适的浓缩器-冷却跟踪组合的清晰路线图。
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引用次数: 0
Design and numerical analysis of a novel cathode flow field with secondary cooling channels for air-cooled PEMFCs 风冷型pemfc新型二次冷却通道阴极流场设计与数值分析
IF 7 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-01-22 DOI: 10.1016/j.seta.2026.104843
Huawei Chang, Pengcheng Yue, Zhijie Huang, Zhengkai Tu
Air-cooled proton exchange membrane fuel cells (PEMFCs) offer advantages such as simple structure and low parasitic power. However, excessive air at the cathode can lead to water imbalance in the PEM and low performance of the stack. Moreover, most existing cathode flow field (CFF) designs concentrate on heat dissipation rather than water management. Therefore, a novel CFF with secondary cooling channels was designed in this work. The water and gas transport, temperature distribution, and output performance of the air-cooled PEMFC were numerically analysed. Comparative analysis with a traditional CFF demonstrated that the novel design enhanced the gas disturbance and improved the mass transfer. At a typical cell voltage of 0.6 V, the oxygen fraction on the surface of the cathode catalyst layer increased by 5.42 %. Meanwhile, the novel CFF reduced the cathode gas flow rate in the reactant channels, thereby decreasing the water carried away by the excessive air at the cathode and improving the water retention capacity. When the cell voltage is 0.6 V, the average membrane water activity increased by 12.03 %, and the output performance of the stack can be improved by 5.40 %. Additionally, the modification of the CFF has minimal impact on the thermal management performance.
气冷质子交换膜燃料电池具有结构简单、寄生功率低等优点。然而,阴极处过多的空气会导致PEM中的水不平衡和堆栈的低性能。此外,大多数现有的阴极流场(CFF)设计侧重于散热而不是水管理。因此,本文设计了一种具有二次冷却通道的新型CFF。对气冷型PEMFC的水、气输运、温度分布及输出性能进行了数值分析。与传统CFF的对比分析表明,新型设计增强了气体扰动,改善了传质。在典型电池电压为0.6 V时,阴极催化剂层表面的氧含量增加了5.42%。同时,新型CFF降低了阴极气体在反应物通道中的流速,从而减少了阴极过量空气带走的水分,提高了保水性。当电池电压为0.6 V时,膜的平均水活度提高了12.03%,堆叠的输出性能提高了5.40%。此外,CFF的修改对热管理性能的影响最小。
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引用次数: 0
Highly conductive polymer electrolytes for solid-state lithium batteries: From mechanisms to applications 用于固态锂电池的高导电性聚合物电解质:从机制到应用
IF 7 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-01-21 DOI: 10.1016/j.seta.2026.104840
Jian Liang , Yinglei Wu , Sirui Wang , Zhongyi He
This article presents a systematic review of ion conduction mechanisms and optimization strategies for polymer electrolytes in solid-state lithium-ion batteries. It begins by examining the physicochemical foundations of ion transport, including the Vogel–Tammann–Fulcher (VTF) equation, Arrhenius-type behavior, and coupled transport models, with emphasis on how temperature, polymer architecture (such as crystallinity and glass transition temperature), and filler characteristics influence ionic conductivity and Li+ transference number. Key polymer electrolyte systems, including polyethers (e.g., PEO), polycarbonates (PPC/PEC), polynitriles (PAN/PMMA), and single-ion conductors, are critically compared in terms of their structural features, electrochemical performance, and inherent challenges. The review then summarizes multi-scale strategies to enhance electrolyte performance, encompassing polymer matrix design (e.g., copolymerization and cross-linking to reduce crystallinity), lithium salt and additive engineering (e.g., high-concentration and dual-salt systems), hybridization techniques (e.g., incorporation of inorganic fillers, organic blending, and three-dimensional (3D) scaffold infusion), and interface engineering approaches such as artificial solid electrolyte interphase (SEI) layers and in situ polymerization. Collectively, these strategies aim to simultaneously improve ionic conductivity, increase the Li+ transference number, enhance interfacial stability, and suppress lithium dendrite growth—key prerequisites for the practical realization of safe and high-energy solid-state batteries.
本文对固态锂离子电池中聚合物电解质的离子传导机制和优化策略进行了系统综述。它首先检查离子传输的物理化学基础,包括Vogel-Tammann-Fulcher (VTF)方程、arrhenius型行为和耦合传输模型,重点是温度、聚合物结构(如结晶度和玻璃化转变温度)和填料特性如何影响离子电导率和Li+转移数。主要的聚合物电解质体系,包括聚醚(如PEO)、聚碳酸酯(PPC/PEC)、聚腈(PAN/PMMA)和单离子导体,在其结构特征、电化学性能和固有挑战方面进行了严格的比较。然后综述了提高电解质性能的多尺度策略,包括聚合物基质设计(例如,共聚和交联以降低结晶度),锂盐和添加剂工程(例如,高浓度和双盐体系),杂交技术(例如,加入无机填料,有机共混和三维(3D)支架注入),以及界面工程方法,如人工固体电解质界面层和原位聚合。总的来说,这些策略旨在同时提高离子电导率,增加Li+转移数,增强界面稳定性,抑制锂枝晶生长,这是实际实现安全和高能固态电池的关键先决条件。
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引用次数: 0
Sustainable integration of poly(ethylene oxide)–polyacrylonitrile (PEO–PAN) gel electrolytes with mesoporous TiO2 nanostructures for green energy dye-sensitized solar cells 聚(环氧乙烷)-聚丙烯腈(PEO-PAN)凝胶电解质与介孔TiO2纳米结构的可持续集成用于绿色能源染料敏化太阳能电池
IF 7 2区 工程技术 Q1 ENERGY & FUELS Pub Date : 2026-01-20 DOI: 10.1016/j.seta.2026.104830
Syed Ezaz Haider Gilani , Muhammad Farooq , Rabia Nazar , Muhammad Younas , Umer Mehmood
Achieving environmentally sustainable power conversion efficiency (PCE) and long-term stability in dye-sensitized solar cells (DSSCs) requires concurrent optimization of both the photoanode and the electrolyte. In this study, a dual-strategy approach is adopted: (i) engineering an interdigitated nanostructured TiO2 photoanode to enhance light harvesting and charge transport, and (ii) developing a sustainable poly(ethylene oxide)–polyacrylonitrile (PEO–PAN) polymer blend gel electrolyte (PBGE) to ensure eco-friendly, stable, and efficient energy conversion. The TiO2 photoanode was synthesized via a solvothermal process and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), & transmission electron microscopy (TEM), revealing anatase crystallinity, porous morphology, and improved electron pathways. Molecular dynamics (MD) simulations were conducted to evaluate the miscibility, cohesive energy density, and Flory–Huggin’s interaction parameter of the PEO–PAN system, confirming thermodynamic compatibility and guiding blend selection. Experimental confirmation was carried out by synthesizing various PEO–PAN ratios and their characterization by scanning electron microscopy (SEM) & X-ray diffraction (XRD), which determined 40:60 PAN–PEO blend as being best with amorphous nature and homogeneous morphology. The composition of PBGE was then optimized by using Taguchi design of experiments (DoE) and salt optimization with a goal, achieving the highest ionic conductivity of 0.501 mS/cm. Electrochemical impedance spectroscopy (EIS) & cyclic voltammetry (CV) validated improved ionic mobility and redox reversibility. When incorporated into DSSCs, the optimized PBGE and TiO2 photoanode exhibited a PCE of 6.13 %, beating the conventional liquid electrolyte cell (5.38 %), TiO2-only cell (5.94 %), and PBGE-only cell (4.39 %). This material design strategy provides a scalable route to high-efficiency quasi-solid-state DSSCs with enhanced long-term stability.
在染料敏化太阳能电池(DSSCs)中实现环境可持续的功率转换效率(PCE)和长期稳定性需要同时优化光阳极和电解质。在本研究中,采用双策略方法:(i)设计一个交叉指状纳米结构TiO2光阳极来增强光收集和电荷传输;(ii)开发一种可持续的聚(环氧乙烷)-聚丙烯腈(PEO-PAN)聚合物共混凝胶电解质(PBGE),以确保环保、稳定和高效的能量转换。采用溶剂热法合成TiO2光阳极,并通过x射线衍射(XRD)、扫描电镜(SEM)和透射电镜(TEM)对其进行了表征,揭示了锐钛矿的结晶度、多孔形貌和改进的电子路径。通过分子动力学(MD)模拟评价PEO-PAN体系的混相性、内聚能密度和Flory-Huggin相互作用参数,确定其热力学相容性,指导共混物的选择。通过合成各种PEO-PAN比例,并通过扫描电镜(SEM)和x射线衍射(XRD)对其进行表征,确定40:60的PAN-PEO共混物为最佳,具有无定形性质和均匀形貌。采用田口实验设计(DoE)和盐优化方法对PBGE的组成进行优化,获得了最高的离子电导率0.501 mS/cm。电化学阻抗谱(EIS)和循环伏安法(CV)验证了离子迁移率和氧化还原可逆性的改善。当加入DSSCs时,优化后的PBGE和TiO2光阳极的PCE为6.13%,优于传统的液体电解质电池(5.38%)、纯TiO2电池(5.94%)和纯PBGE电池(4.39%)。这种材料设计策略为高效准固态DSSCs提供了一种可扩展的途径,具有增强的长期稳定性。
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引用次数: 0
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Sustainable Energy Technologies and Assessments
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