Trends in Environmental Analytical Chemistry最新文献_第4页

A time-updated review on the identification of emerging disinfection byproducts in drinking water: Revealing the role of chromatography 饮用水中新出现的消毒副产物鉴定的最新综述：揭示色谱的作用

IF 11.1 2区化学 Q1 CHEMISTRY, ANALYTICAL

Trends in Environmental Analytical Chemistry

Pub Date : 2025-05-12 DOI: 10.1016/j.teac.2025.e00267

Zhuorong Du , Miaomiao Fu , Shuwen Zheng , Xingrun Li , Jingsi Chen , Jiafu Li

Since the identified disinfection byproducts (DBPs) do not fully explain the overall toxicity of disinfected drinking water, accurately identifying highly toxic unknown DBPs is essential for understanding the adverse effects of water disinfection. Analytical methods are selected based on the distinct properties of DBPs. A literature search was conducted in the PubMed, Embase, Web of Science, Google Scholar, and CNKI databases to identify emerging DBPs first reported in the past five years, collecting data on their identification and occurrence. While earlier studies primarily employed gas chromatography (GC) related methods, recent years have seen a substantial shift toward liquid chromatography (LC) related methods. Among the emerging DBPs reported over the past five years, GC related methods have identified four classes, whereas LC related methods have identified 26 classes. Furthermore, innovative techniques such as supercritical fluid chromatography-quadrupole-time of flight-tandem mass spectrometry (SFC-Q-TOF-MS/MS) have been introduced to enhance DBP identification. The reported concentrations of individual emerging DBPs are mostly in the range of 10¹ ng/L, typically only one-thousandth to one-tenth of those of regulated and priority DBPs, which generally exist at μg/L levels. This review also discusses future developments in the accurate identification of unknown DBPs and explores strategies to enhance drinking water safety, informed by insights gained from the emerging DBPs identified in the past five years.

由于已确定的消毒副产物（DBPs）并不能完全解释消毒饮用水的总体毒性，因此准确识别高毒性未知DBPs对于了解水消毒的不良影响至关重要。根据dbp的不同性质选择分析方法。对PubMed、Embase、Web of Science、b谷歌Scholar和CNKI数据库进行文献检索，以确定近五年来首次报道的新兴dbp，收集其识别和发生的数据。虽然早期的研究主要采用气相色谱（GC）相关方法，但近年来已经看到了向液相色谱（LC）相关方法的实质性转变。在过去五年中报告的新兴dbp中，GC相关方法鉴定了4类，LC相关方法鉴定了26类。此外，还引入了超临界流体色谱-四极杆飞行时间串联质谱（SFC-Q-TOF-MS/MS）等创新技术来提高DBP的鉴定。报告的单个新出现dbp的浓度大多在101 ng/L范围内，通常仅为通常存在于μg/L水平的受调节和优先dbp浓度的千分之一至十分之一。本综述还讨论了在准确识别未知dbp方面的未来发展，并根据从过去五年中发现的新dbp中获得的见解，探讨了加强饮用水安全的战略。

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引用次数: 0

Critical review on analytical methodologies for highly polar organophosphate pesticides in environmental samples 环境样品中高极性有机磷农药分析方法综述

IF 11.1 2区化学 Q1 CHEMISTRY, ANALYTICAL

Trends in Environmental Analytical Chemistry

Pub Date : 2025-05-08 DOI: 10.1016/j.teac.2025.e00266

David Fabregat-Safont , Mahdiyeh Otoukesh , Jorge Pitarch-Motellón , José M. Marín , Elena Pitarch , Félix Hernández

Highly polar pesticides include compounds such as glyphosate and its metabolite AMPA, glufosinate and its metabolite MPPA, phosphonic acid, ethephon, and fosetyl-Al. Their unique physicochemical properties —such as low octanol/water coefficient (log K_ow < 0), poor retention on reversed-phase columns, strong binding affinities to matrix components, and poor ionization and fragmentation efficiency in mass spectrometry— make their residue determination problematic. Consequently, the development of suitable analytical methods remains highly challenging. This review provides a comprehensive literature search of the most recent analytical methodologies for the determination of these compounds in environmental samples, along with a critical discussion of key issues related to their residue determination in different sample matrices. With a focus mainly on liquid chromatography-mass spectrometry methods, the different steps of the analytical workflow are discussed, including sample treatment, chromatographic separation and detection. At each step, the review highlights analytical challenges and pivotal aspects to offer an in-depth understanding of the analytical determination of these highly polar pesticides.

高极性农药包括草甘膦及其代谢物AMPA、草甘膦及其代谢物MPPA、膦酸、乙烯利和四乙基铝等化合物。其独特的物理化学性质-如低辛醇/水系数(log kw <；0)，在反相柱上的保留率差，与基质组分的强结合亲和力，以及质谱中较差的电离和碎片化效率-使得它们的残留测定存在问题。因此，开发合适的分析方法仍然具有很大的挑战性。这篇综述提供了对环境样品中这些化合物测定的最新分析方法的全面文献检索，以及对其在不同样品基质中残留测定的关键问题的关键讨论。重点介绍了液相色谱-质谱分析方法，讨论了分析工作流程的不同步骤，包括样品处理、色谱分离和检测。在每一步，回顾强调分析的挑战和关键方面，以提供深入了解这些高极性农药的分析测定。

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引用次数: 0

Peptide-based strategies for detecting microplastics in aquatic systems: A review 基于多肽的水生系统微塑料检测策略：综述

IF 11.1 2区化学 Q1 CHEMISTRY, ANALYTICAL

Trends in Environmental Analytical Chemistry

Pub Date : 2025-04-23 DOI: 10.1016/j.teac.2025.e00265

Abbas Motalebizadeh, Somayeh Fardindoost, Mina Hoorfar

Microplastics, defined as plastic particles less than 5 mm in diameter, have become pervasive pollutants in marine and terrestrial environments and pose significant environmental and health risks, necessitating effective detection methods. The selective detection of these tiny particles is challenging due to the complexity of the matrices of marine water. This mini-review explores the significant advancements and applications of microplastic-binding peptides, underlining their potential as a novel approach for microplastic detection and highlighting their specificity, sensitivity, and versatility. Progress in this field has been driven by advances in protein engineering, computational techniques, and analytical methodologies, enabling the design of plastic-specific peptides with fine-tuned binding properties. We discuss the current state of research, challenges, and future directions in this emerging field.

微塑料的定义是直径小于5 毫米的塑料颗粒，已成为海洋和陆地环境中普遍存在的污染物，并构成重大的环境和健康风险，需要有效的检测方法。由于海水基质的复杂性，对这些微小颗粒的选择性检测具有挑战性。这篇综述探讨了微塑料结合肽的重大进展和应用，强调了它们作为微塑料检测新方法的潜力，并强调了它们的特异性、敏感性和多功能性。蛋白质工程、计算技术和分析方法的进步推动了这一领域的进步，使设计具有微调结合特性的塑料特异性肽成为可能。我们将讨论这一新兴领域的研究现状、挑战和未来方向。

引用次数: 0

Small chips, big ocean: Recent trends in microfluidic technology for marine environmental monitoring 小芯片，大海洋：用于海洋环境监测的微流控技术的最新趋势

IF 11.1 2区化学 Q1 CHEMISTRY, ANALYTICAL

Trends in Environmental Analytical Chemistry

Pub Date : 2025-04-02 DOI: 10.1016/j.teac.2025.e00264

Qing Yu , Yuezhu Wang , Junsheng Wang , Jianhong Dong

The ocean, a vast and enigmatic blue realm, is increasingly threatened by anthropogenic activities. This critical global ecosystem faces unprecedented pressures from human impacts. Pollution stemming from plastic debris, oil spills, industrial effluent, and agricultural runoff degrades marine ecosystems, compromises biodiversity, and poses significant risks to human well-being. Effective and timely monitoring is crucial for mitigating these threats. Microfluidic technology, through its precise control and manipulation of fluids at the microscale, facilitates rapid and sensitive analysis of diverse oceanographic parameters. This technology offers significant advantages for ocean monitoring, enabling miniaturization of analytical systems, cost reduction, and deployment in remote or challenging environments. This review comprehensively summarizes recent advancements in microfluidic chip technology for marine environmental monitoring, encompassing water quality analysis (dissolved oxygen, pH, nutrients); pollutant detection (oil, heavy metals, persistent organic pollutants); emerging contaminant monitoring (microplastics, pharmaceuticals); and climate-related research (ocean acidification, aerosol phase behavior, ice nucleating particles). We discuss current challenges, including the need for robust, low-power devices for long-term in situ deployment, and outline the future potential of this transformative technology in marine environmental protection. This review is expected to foster further research in the application of microfluidic technologies to marine environmental monitoring and contribute significantly to ocean

海洋，一个广阔而神秘的蓝色领域，正日益受到人类活动的威胁。这一重要的全球生态系统面临着来自人类影响的前所未有的压力。塑料碎片、石油泄漏、工业废水和农业径流造成的污染使海洋生态系统退化，损害生物多样性，并对人类福祉构成重大威胁。有效和及时的监测对于减轻这些威胁至关重要。微流控技术，通过其精确控制和操纵流体在微观尺度，促进了快速和灵敏的分析各种海洋参数。该技术为海洋监测提供了显著的优势，实现了分析系统的小型化，降低了成本，并且可以在偏远或具有挑战性的环境中部署。本文综述了微流控芯片技术在海洋环境监测中的最新进展，包括水质分析（溶解氧、pH值、营养成分）；污染物检测（石油、重金属、持久性有机污染物）；新兴污染物监测（微塑料、药品）；以及与气候相关的研究（海洋酸化、气溶胶相行为、冰成核粒子）。我们讨论了当前的挑战，包括对长期原位部署的强大，低功耗设备的需求，并概述了这种变革性技术在海洋环境保护方面的未来潜力。本文的研究将促进微流控技术在海洋环境监测中的应用，为海洋环境监测做出重要贡献

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引用次数: 0

Green analytical procedure index assessment for total petroleum hydrocarbons determination methods in soil and sediments. A review 土壤和沉积物中总石油烃测定方法的绿色分析程序指标评价。回顾

IF 11.1 2区化学 Q1 CHEMISTRY, ANALYTICAL

Trends in Environmental Analytical Chemistry

Pub Date : 2025-03-31 DOI: 10.1016/j.teac.2025.e00262

Bauyrzhan Abdykarimov , Mereke Alimzhanova , Rebeca López-Serna , Yerkanat Syrgabek

Accurate determination of total petroleum hydrocarbons in soil and sediment is crucial for assessing pollution levels and guiding remediation efforts. This review looks at various analytical techniques for total petroleum hydrocarbons determination, such as gas chromatography with different detection methods, infrared based and fluorescence spectroscopic methods, in addition to gravimetric analysis. Green Analytical Procedure Index was used to investigate the environmental impact of the techniques along with different coupled extraction methods. Green Analytical Procedure Index individually evaluates the sample preparation, the type of instrumental technique, the reagents and solvents employed, the health and safety hazard, occupational hazard, and waste of each proposed analytical tool. This literature review showed that Soxhlet extraction, although ranked lower in greenness, is still one of the most widely used techniques for total petroleum hydrocarbons determination due to its completeness. Techniques like gas chromatography - mass spectrometer coupled with solid-phase microextraction, and infrared based tools with direct application are greener because the use of solvent is negligible, and the preparation of the sample is minimal. At the same time infrared based techniques showed lower prediction accuracy compared to gas chromatography - mass spectrometer coupled with solid-phase microextraction. This review highlights the critical need to balance analytical performance with environmental sustainability, offering insights into future developments in forensic and environmental monitoring. It shows pathways toward increasing the greenness of widely used techniques and future use in forensic investigations and environmental monitoring. Overall, this review is among the first to systematically assess total petroleum hydrocarbons analytical methods using Green Analytical Procedure Index, bridging the gap between analytical efficiency and green chemistry principles.

准确测定土壤和沉积物中的石油烃总量对于评估污染水平和指导修复工作至关重要。本文综述了测定石油总烃的各种分析技术，如不同检测方法的气相色谱法、红外光谱法和荧光光谱法，以及重量分析法。采用绿色分析方法指数考察了不同耦合提取方法对环境的影响。绿色分析程序指数单独评估样品制备、仪器技术类型、所用试剂和溶剂、健康和安全危害、职业危害以及每种建议分析工具的浪费。这篇文献综述表明，索氏提取虽然在绿色度上排名较低，但由于其完整性，仍然是最广泛使用的石油总烃测定技术之一。气相色谱-质谱联用固相微萃取和直接应用的红外工具等技术更环保，因为溶剂的使用可以忽略不计，样品的制备也最少。同时，与气相色谱-质谱联用固相微萃取相比，红外技术的预测精度较低。这篇综述强调了平衡分析性能与环境可持续性的关键需求，为法医和环境监测的未来发展提供了见解。它显示了增加广泛使用的技术的绿色和未来在法医调查和环境监测中的应用的途径。总的来说，这篇综述是第一次使用绿色分析程序指数系统地评估石油总烃分析方法，弥合了分析效率和绿色化学原则之间的差距。

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引用次数: 0

Redefining nanobiosensors in rapid detection of viral infections: Where are we now? 在病毒感染的快速检测中重新定义纳米生物传感器：我们现在在哪里？

IF 11.1 2区化学 Q1 CHEMISTRY, ANALYTICAL

Trends in Environmental Analytical Chemistry

Pub Date : 2025-03-29 DOI: 10.1016/j.teac.2025.e00263

Muhammad Asif , Jari S. Algethami , Mohsen A.M. Alhamami , Peng Lie , Shunag Shaomin , Ayesha Aziz

The development of nanobiosensors has conquered immense attention of the scientific community owing to the recent events of outbreaks. Highly targeted and responsive detection of viruses plays a crucial role in accurate and timely diagnosis of viral infections. Regardless of the numerous efforts to detect viruses, the diagnosis of viral diseases yet relay on costly and time-consuming assays. Currently, PCR based assays are frequently used methods for the detection of viral illnesses further allowing the precise diagnosis of various diseases but these techniques still suffer several limitations including long time to get results and the need for experts to run. As alternative approaches, low-cost nanobiosensors are rapid and trustworthy diagnostic systems for point-of-care diagnosis because of their high sensitivity and selectivity. Biosensing methodologies ensure sensitive and specific detection, recognition, and quantification of pathogens. Viruses can have severe economic repercussions due to its high transmissibility and rapid proliferation, which can have a significant impact on both individual and collective health. Herein, after introduction, we have summarized key contributions regarding the development in nanobiosensors for detection of viral infections induced by respiratory viruses including MERS-CoV, SARS-CoV-2 and hepatitis viruses, zika virus, dengue virus, and human papilloma virus. Moreover, vitality of rapid and emerging biosensing technologies including electrochemical, optical, and piezoelectric biosensors has been discussed in details. This review underscores the recent advances in assembling the efficient sensing devices with their figures of merits. Finally, we have outlined the benefits and drawbacks of diagnostic methods, as well as potential future research avenues.

由于最近的疫情事件，纳米生物传感器的发展引起了科学界的极大关注。高度针对性和反应性的病毒检测对于准确、及时地诊断病毒感染起着至关重要的作用。尽管为检测病毒付出了无数努力，但病毒性疾病的诊断仍然依赖于昂贵且耗时的检测。目前，基于PCR的检测方法是检测病毒性疾病的常用方法，进一步允许对各种疾病进行精确诊断，但这些技术仍然存在一些局限性，包括获得结果的时间长以及需要专家运行。作为替代方法，低成本的纳米生物传感器由于其高灵敏度和选择性，是一种快速可靠的即时诊断系统。生物传感方法确保了病原体的敏感和特异性检测、识别和定量。病毒由于其高传播性和快速扩散，可对经济产生严重影响，对个人和集体健康都可能产生重大影响。在此，在介绍之后，我们总结了用于检测呼吸道病毒（包括MERS-CoV、SARS-CoV-2和肝炎病毒、寨卡病毒、登革热病毒和人乳头瘤病毒）感染的纳米生物传感器的主要贡献。此外，还详细讨论了包括电化学、光学和压电生物传感器在内的快速和新兴生物传感技术的生命力。本文综述了近年来在高效传感装置组装方面的研究进展及其优缺点。最后，我们概述了诊断方法的优点和缺点，以及潜在的未来研究途径。

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引用次数: 0

Recent innovations in explosive trace detection: Advances and emerging technologies 爆炸痕迹检测的最新创新：进展和新兴技术

IF 11.1 2区化学 Q1 CHEMISTRY, ANALYTICAL

Trends in Environmental Analytical Chemistry

Pub Date : 2025-03-17 DOI: 10.1016/j.teac.2025.e00261

Al-Fakih Ali Mohammed , Karim Youssef Nabat , Ting Jiang , Lingyan Liu

Detecting trace explosives is crucial for public safety in forensics, security, and environmental monitoring. This review analyzes recent advancements in four key explosive detection technologies: Ion Mobility Spectrometry (IMS), Gas Chromatography-mass spectrometry (GC-MS), Ambient Ionization Mass Spectrometry (AIMS), and Surface-Enhanced Raman Spectroscopy (SERS). IMS excels in detecting low-volatile explosives in complex environments, while GC-MS offers enhanced sensitivity and resolution for trace analysis. AIMS is noted for its rapid, non-invasive, high-throughput capabilities, ideal for real-time detection. Recent improvements in SERS have increased its sensitivity across a broader range of explosive compounds. Despite these advances, challenges such as low recovery rates, cross-sensitivity, and environmental interference remain. The paper highlights the need for continued innovation to improve sensitivity, selectivity, and accuracy, addressing evolving security, forensic, and environmental threats.

痕量爆炸物的检测在法医、安保和环境监测中对公共安全至关重要。本文综述了离子迁移率光谱法（IMS）、气相色谱-质谱法（GC-MS）、环境电离质谱法（AIMS）和表面增强拉曼光谱法（SERS）四种关键爆炸物检测技术的最新进展。IMS擅长在复杂环境中检测低挥发性爆炸物，而GC-MS为痕量分析提供了更高的灵敏度和分辨率。AIMS以其快速，非侵入性，高通量能力而闻名，是实时检测的理想选择。SERS最近的改进提高了它对更广泛的爆炸性化合物的灵敏度。尽管取得了这些进步，但采收率低、交叉敏感性和环境干扰等挑战仍然存在。本文强调了持续创新的必要性，以提高灵敏度、选择性和准确性，解决不断发展的安全、法医和环境威胁。

引用次数: 0

Assessing emerging contaminants in soils using soil enzyme-based methods: A critical review 利用土壤酶为基础的方法评估土壤中新出现的污染物：一个重要的回顾

IF 11.1 2区化学 Q1 CHEMISTRY, ANALYTICAL

Trends in Environmental Analytical Chemistry

Pub Date : 2025-03-07 DOI: 10.1016/j.teac.2025.e00260

Ferdinand Ndikuryayo, Xue-Yan Gong, Xiuhai Gan, Wen-Chao Yang

Emerging contaminants (ECs) in soils pose significant threat to human health and the environment, prompting an urgent need for innovative assessment methods. Soil enzymes (SEs) can serve as sensitive indicators of soil quality and pollution due to their responsiveness to various contaminants. Analytical methods have highlighted the crucial role of SEs in assessing soil contamination for plant protection. This review aims to critically evaluate current SE-based methods used to assess ECs in soils. By examining the strengths and weaknesses of these approaches in terms of complexity and analytical applicability, it highlights the most promising methods and SE-driven tools for EC assessment in soils. To enhance SE-proven methods, several innovative strategies have been suggested, ranging from sampling to analysis. These strategies include chemically modifying the products of SE-catalyzed reactions to enable the use of reliable analytical techniques such as fluorimetry and spectrophotometry, as well as utilizing biotechnology to enhance the activity of SEs in both EC assessment and in situ bioremediation. Finally, recommendations addressing existing gaps are presented, outlining future research directions for assessing ECs in soils and remediating EC-contaminated soils for food security.

土壤中新出现的污染物对人类健康和环境构成重大威胁，迫切需要创新的评估方法。土壤酶对各种污染物具有响应性，可以作为土壤质量和污染的敏感指标。分析方法强调了SEs在植物保护土壤污染评估中的关键作用。这篇综述旨在批判性地评价目前用于评估土壤中ECs的基于se的方法。通过检查这些方法在复杂性和分析适用性方面的优缺点，它突出了最有前途的方法和se驱动的土壤EC评估工具。为了加强se验证的方法，提出了几种创新策略，从抽样到分析。这些策略包括对se催化反应的产物进行化学修饰，使其能够使用可靠的分析技术，如荧光法和分光光度法，以及利用生物技术提高se在EC评估和原位生物修复中的活性。最后，提出了解决现有差距的建议，概述了未来土壤ec评估和修复ec污染土壤的研究方向，以保障粮食安全。

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引用次数: 0

Recent trends in use of plant-derived carbon dot-based fluorescent probes for heavy metal ion detection and their biological applications 植物源碳点荧光探针重金属离子检测的最新趋势及其生物学应用

IF 11.1 2区化学 Q1 CHEMISTRY, ANALYTICAL

Trends in Environmental Analytical Chemistry

Pub Date : 2025-02-15 DOI: 10.1016/j.teac.2025.e00259

Geetha Venkatesan , Govindasamy Sathiyan

Plant-derived carbon dots (CDs) have drawn a lot of interest as superior nanomaterials because of their sustainable nature, biocompatibility, and environmentally friendly synthesis, which sets them apart from other CDs made from non-renewable resources. The synthesis of CDs from natural sources such as fruits, leaves, bark, stem, flower, seed and biowaste by hydrothermal, pyrolysis, and microwave-assisted method have been investigated to modify the size and features of CDs. The plant-derived CDs exhibit greater sensitivity and selectivity, and their high photoluminescent properties makes it possible to detect physiological and ecological significant metal ions like iron (Fe³⁺), copper (Cu²⁺), lead (Pb²⁺), and mercury (Hg²⁺). This study focuses mainly on crucial elements such as absorption, emission, sensitivity, selectivity, and limits of detection of metal ions, a thorough examination of their sensing characteristics is provided. This review article comprehensively summarizes plant-based CDs with different synthesis methods, characterization techniques, metal ion sensing and its mechanism, stability and biological imaging of CDs. Additionally, we discussed the plant derived CDs for the detection of pesticides and drugs. These CDs also find extensive applications in environmental remediation by offering a sustainable alternative for detecting harmful pollutants. Beyond these sensing, their biological uses of plant-derived CDs, such as bioimaging, antioxidant activity, and therapeutic potential, are finally addressed. This review emphasizes the bright future of plant-derived CDs in biomedicine and sustainable nanotechnology, with a focus on their biological applications and improved sensing capabilities in research development.

植物来源的碳点（CDs）由于其可持续性、生物相容性和环境友好的合成特性而引起了人们的广泛关注，这使它们有别于其他由不可再生资源制成的CDs。研究了以水果、树叶、树皮、茎、花、种子和生物废弃物为原料，通过水热法、热解法和微波辅助法合成CDs，以改变CDs的大小和特征。植物衍生的CDs具有更高的灵敏度和选择性，其高光致发光特性使得检测铁（Fe³+）、铜（Cu²+）、铅（Pb²+）和汞（Hg²+）等生理和生态上重要的金属离子成为可能。本研究主要关注金属离子的吸收、发射、灵敏度、选择性和检测限等关键因素，并对其传感特性进行了全面的研究。本文综述了植物基CDs的不同合成方法、表征技术、金属离子传感及其机理、稳定性和生物成像等方面的研究进展。此外，我们还讨论了用于农药和药物检测的植物源cd。这些cd还通过提供一种可持续的检测有害污染物的替代方法，在环境修复中得到广泛应用。除了这些传感之外，它们在植物源性cd的生物学用途，如生物成像、抗氧化活性和治疗潜力，最终得到了解决。本文综述了植物源性cd在生物医学和可持续纳米技术方面的应用前景，重点介绍了植物源性cd在生物医学和可持续纳米技术方面的应用前景。

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引用次数: 0

Chitosan-based sorbents for the micro-solid-phase extraction of pesticides 壳聚糖基吸附剂用于农药微固相萃取

IF 11.1 2区化学 Q1 CHEMISTRY, ANALYTICAL

Trends in Environmental Analytical Chemistry

Pub Date : 2025-02-08 DOI: 10.1016/j.teac.2025.e00258

Ahmad Reza Bagheri, Ardeshir Shokrollahi

The widespread use of pesticides and their hazardous impacts on humans and animals have made their detection and determination a critical issue. However, due to the low concentration of pesticides and the complexity of the entire sample, it is essential to use sample preparation approaches before determining pesticides. Among sample preparation approaches, micro-solid-phase extraction (µ-SPE), as a miniaturized extraction technique, has garnered much attention. This technique decreases the use of materials, reagents, and solvents. Additionally, µ-SPE applies micro- and/or nano-based sorbents and employs miniaturized extraction gadgets and devices. The attributes of µ-SPE, plus the concepts of green analytical chemistry, have encouraged analytical scientists to introduce and use green and environmentally friendly materials in µ-SPE techniques. Chitosan (CS) is a biocompatible, low- or negligible-toxic, environmentally friendly, and cost-effective material. Another valuable property of CS is its capability for modification and combination with different compounds. CS-based materials not only address the problems of traditional sorbents but also introduce new ones with excellent features such as high stability, high adsorption capacity, etc. These factors motivated us to assess the recent development in using CS-based sorbents for the µ-SPE of pesticides from 2016 to 2025. In this article, the properties of CS are illustrated. Different CS composites and the possible mechanisms for extracting pesticides are reviewed. Finally, the current trends and prospects related to using CS-based sorbents in the µ-SPE of pesticides are summarized. This review article investigates the properties and utilizations of CS-based materials as sorbents in µ-SPE, highlighting their potential to revolutionize pesticide determination.

农药的广泛使用及其对人类和动物的有害影响使其检测和确定成为一个关键问题。然而，由于农药浓度低，整个样品的复杂性，在确定农药之前必须使用样品制备方法。在样品制备方法中，微固相萃取（micro-solid-phase extraction, micro -SPE）作为一种小型化的萃取技术受到了广泛的关注。这种技术减少了材料、试剂和溶剂的使用。此外，µ- spe适用于微型和/或纳米基吸附剂，并采用小型化的萃取装置和设备。µ-SPE的特性，加上绿色分析化学的概念，鼓励分析科学家在µ-SPE技术中引入和使用绿色环保材料。壳聚糖（CS）是一种具有生物相容性、低毒性或可忽略不计的、环保的、高性价比的材料。CS的另一个有价值的特性是它的改性和与不同化合物结合的能力。cs基材料不仅解决了传统吸附剂的问题，而且还引入了具有高稳定性、高吸附容量等优异特性的新型吸附剂。这些因素促使我们评估了2016年至2025年在农药微spe中使用CS-based吸附剂的最新发展。本文阐述了CS的特性。综述了不同的CS复合材料及其提取农药的可能机理。最后，总结了cs基吸附剂在农药微固相萃取中的应用现状和前景。本文综述了cs基材料在μ -SPE中作为吸附剂的性能和应用，强调了它们在农药测定中的革命性潜力。

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引用次数: 0