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How does chain length affect fracture of a brittle polymer glass? 链长如何影响脆性聚合物玻璃的断裂?
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-02 DOI: 10.1016/j.eml.2025.102431
Christine Heera Ahn, Zheqi Chen, Xianyang Bao, Zhigang Suo
In a brittle polymer glass, a fracture property increases with the length of polymer chains and then plateaus. Here, we use poly(methyl methacrylate) to study such transitions in several fracture properties. We measure strength using samples without precut crack, and measure toughness and fatigue threshold using samples with precut crack. The three properties plateau at different chain lengths. These transitions arise from a change in fracture mechanism—from chain pullout to chain scission. The chain length for a fracture property to plateau is understood using a shear-lag model. The plateau length is set by the balance of the strengths of bonds of two types: the covalent bonds along the chains, which resists scission, and the noncovalent bonds between the chains, which resist pullout. For each of the three fracture properties, we discuss the chain length for the property to plateau, as well as the value of the plateau.
在脆性聚合物玻璃中,断裂性能随着聚合物链的长度而增加,然后趋于平稳。在这里,我们使用聚甲基丙烯酸甲酯来研究几种断裂性质中的这种转变。我们用无预切裂纹的试样测量强度,用有预切裂纹的试样测量韧性和疲劳阈值。这三种性质在不同链长处趋于平稳。这些转变是由断裂机制的变化引起的——从链拔出到链断裂。断裂特性达到平台的链长可以用剪切滞后模型来理解。平台长度是由两种化学键强度的平衡决定的:沿链的共价键抵抗断裂,链之间的非共价键抵抗拔出。对于这三种断裂性质,我们讨论了到达平台的链长度,以及平台的值。
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引用次数: 0
Front cover CO1 前盖CO1
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/S2352-4316(25)00144-0
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引用次数: 0
Discrete differential geometry for simulating nonlinear behaviors of flexible systems: A survey 模拟柔性系统非线性行为的离散微分几何:综述
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 DOI: 10.1016/j.eml.2025.102430
Dezhong Tong , Andrew Choi , Jiaqi Wang , Weicheng Huang , Zexiong Chen , Jiahao Li , Xiaonan Huang , Mingchao Liu , Huajian Gao , K. Jimmy Hsia
Flexible slender structures such as rods, ribbons, plates, and shells exhibit extreme nonlinear responses – bending, twisting, buckling, wrinkling, and self-contact – that defy conventional simulation frameworks. Discrete Differential Geometry (DDG) has emerged as a geometry-first, structure-preserving paradigm for modeling such behaviors. Unlike finite element or mass–spring methods, DDG discretizes geometry rather than governing equations, allowing curvature, twist, and strain to be defined directly on meshes. This approach yields robust large-deformation dynamics, accurate handling of contact, and differentiability essential for inverse design and learning-based control. This review consolidates the rapidly expanding landscape of DDG models across 1D and 2D systems, including discrete elastic rods, ribbons, plates, and shells, as well as multiphysics extensions to contact, magnetic actuation, and fluid–structure interaction. We synthesize applications spanning mechanics of nonlinear instabilities, biological morphogenesis, functional structures and devices, and robotics from manipulation to soft machines. Compared with established approaches, DDG offers a unique balance of geometric fidelity, computational efficiency, and algorithmic differentiability, bridging continuum rigor with real-time, contact-rich performance. We conclude by outlining opportunities for multiphysics coupling, hybrid physics–data pipelines, and scalable GPU-accelerated solvers, and by emphasizing DDG’s role in enabling digital twins, sim-to-real transfer, and intelligent design of next-generation flexible systems.
灵活的细长结构,如棒、带、板和壳,表现出极端的非线性响应-弯曲、扭曲、屈曲、起皱和自接触-与传统的模拟框架相抵触。离散微分几何(DDG)作为一种以几何优先、结构保留的模式出现,用于对此类行为进行建模。与有限元或质量弹簧方法不同,DDG离散几何而不是控制方程,允许曲率,扭曲和应变直接在网格上定义。这种方法产生了鲁棒的大变形动力学,精确的接触处理,以及对逆设计和基于学习的控制至关重要的可微分性。这篇综述整合了快速扩展的一维和二维DDG模型,包括离散弹性棒、带状、板和壳,以及多物理场扩展到接触、磁致动和流固相互作用。我们综合了非线性不稳定性力学,生物形态发生,功能结构和设备,以及从操作到软机器的机器人技术的应用。与现有方法相比,DDG提供了几何保真度、计算效率和算法可微分性的独特平衡,将连续统一性与实时、接触丰富的性能相结合。最后,我们概述了多物理场耦合、混合物理场数据管道和可扩展gpu加速求解器的机会,并强调了DDG在实现数字孪生、模拟到真实传输和下一代灵活系统智能设计方面的作用。
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引用次数: 0
The role of dynamic covalent bonds on mechanical properties of rubber vitrimer with hybrid networks 动态共价键对杂化网络橡胶聚合物力学性能的影响
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-11-29 DOI: 10.1016/j.eml.2025.102429
Dichao Ning, Zihan Zhang, Chenyu Jin, Qian Shi
Rubber is widely applied due to its high elasticity and durability, but traditional crosslinked networks are non-recyclable. The incorporation of dynamic covalent bonds endows vitrimers with recyclability and self-healing ability. However, the regulatory effect of curing kinetics and chemical ratio on dynamic covalent bonds has not been systematically studied, and such regulation is crucial for designing high-performance rubber vitrimers. In this work, rubber vitrimers with hybrid network were synthesized by using epoxy monomers and curing agent containing disulfide bonds. By varying the chemical ratio of soft segments (PEG) and hard segments (BPDG or DGEBA), and tuning curing time, we characterized their dynamic performance, tensile properties and fracture toughness. Furthermore, kinetic equation was incorporated into and used to extend the Lake–Thomas model, enabling quantitative description and prediction of fracture energy. The results demonstrate that increased curing degree and disulfide bond proportion enhance the fracture toughness and fracture strain of the rubber polymer, but slightly reduce its strength and modulus. Moreover, the introduction of dynamic covalent bonds favors both fracture toughness and dynamic performance. This work provides theoretical guidance and processing strategies for the design of high-performance rubbers.
橡胶因其高弹性和耐久性而得到广泛应用,但传统的交联网络是不可回收的。动态共价键的结合赋予了玻璃体可回收性和自愈能力。然而,硫化动力学和化学配比对动态共价键的调节作用尚未得到系统的研究,而这种调节作用对于设计高性能橡胶玻璃体至关重要。本文以环氧单体和含二硫键的固化剂为原料,合成了杂化网络橡胶玻璃体。通过改变软段(PEG)和硬段(BPDG或DGEBA)的化学配比,以及调整固化时间,对其动态性能、拉伸性能和断裂韧性进行了表征。此外,将动力学方程引入Lake-Thomas模型并加以扩展,实现了裂缝能的定量描述和预测。结果表明:增大硫化度和二硫键比例,可提高橡胶聚合物的断裂韧性和断裂应变,但强度和模量略有降低;此外,引入动态共价键有利于断裂韧性和动态性能。该工作为高性能橡胶的设计提供了理论指导和加工策略。
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引用次数: 0
Stress distribution in contractile cell monolayers 收缩细胞单层中的应力分布
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-11-29 DOI: 10.1016/j.eml.2025.102426
Yucheng Huo , Kexin Guo , Massimo Paradiso , K. Jimmy Hsia
Collective behaviors in cellular systems are regulated not only by biochemical signaling pathways but also by intercellular mechanical forces, whose quantification in contractile monolayers remains poorly understood. Here, by integrating traction force microscopy and numerical simulations, we reconstruct the stress distribution in C2C12 myoblast monolayers to reveal the roles of local mechanical forces in determining the collective cellular structures. We find that contractile monolayers exhibit positive maximum and negative minimum principal stresses, reflecting the intrinsic anisotropy of active tension. Distinct stress patterns emerge around topological defects, coinciding with singularities in cell alignment, density, and morphology, indicating a strong coupling between mechanical forces and structural organization. Moreover, tensile stresses are preferentially transmitted along the cell elongation axis and compressive stresses transversely, demonstrating that local stress guides cell arrangement. This mechanical guidance appears to be universal among contractile systems, as observed also in bone marrow–derived mesenchymal stem cells. Together, our work establishes a quantitative framework for characterizing mechanical anisotropy in active cellular monolayers and reveals a general principle of force–structure coupling, providing a physical basis for understanding how mechanics governs myogenesis, morphogenesis, and collective organization in contractile cellular systems.
细胞系统中的集体行为不仅受到生物化学信号通路的调节,还受到细胞间机械力的调节,而细胞间机械力在收缩单层中的量化仍然知之甚少。在这里,我们通过结合牵引力显微镜和数值模拟,重建了C2C12成肌细胞单层中的应力分布,以揭示局部机械力在决定集体细胞结构中的作用。我们发现,收缩单分子膜表现出正的最大主应力和负的最小主应力,反映了主动张力的内在各向异性。不同的应力模式出现在拓扑缺陷周围,与细胞排列、密度和形态的奇异性相一致,表明机械力和结构组织之间存在很强的耦合。此外,拉伸应力优先沿细胞延伸轴传递,压应力横向传递,表明局部应力指导细胞排列。这种机械引导似乎在收缩系统中是普遍存在的,在骨髓来源的间充质干细胞中也观察到了这一点。总之,我们的工作建立了一个定量框架来表征活性细胞单层的力学各向异性,并揭示了力-结构耦合的一般原理,为理解力学如何控制收缩细胞系统中的肌肉发生、形态发生和集体组织提供了物理基础。
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引用次数: 0
Multi-level mechanical modeling and computational design framework for weft knitted fabrics 纬编织物多层次力学建模与计算设计框架
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-11-27 DOI: 10.1016/j.eml.2025.102423
Cosima du Pasquier , Sehui Jeong , Pan Liu , Susan Williams , Nour Mnejja , Allison M. Okamura , Skylar Tibbits , Tian Chen
This work presents a multi-level modeling and design framework for weft knitted fabrics, beginning with a volumetric finite element analysis capturing their mechanical behavior from fundamental principles. Incorporating yarn-level data, it accurately predicts stress–strain responses, reducing the need for extensive physical testing. A simplified strain energy approach homogenizes the results into three key variables, enabling rapid, accurate predictions in minutes. After validation against experiments, our framework can simulate new knit fabrics without additional tests. In real-world scenarios, fabrics often feature variations in yarn materials or patterns. The framework extends to heterogeneous fabrics, showing that transitions between distinct regions can be captured using simple mechanical analogies: springs in series and parallel. This allows heterogeneous textiles to be treated as idealized patchworks of homogeneous pieces, preserving predictive accuracy. The method is demonstrated by designing and producing a compression sleeve with uniform pressure, illustrating how the framework supports development of knits tailored to specific assistance levels and anatomical features. By combining volumetric finite element analysis, simplified model through homogenization, and controlled material transitions, this approach provides a scalable, high-fidelity path toward next-generation weft knitted fabric design.
这项工作提出了纬编织物的多层次建模和设计框架,从体积有限元分析开始,从基本原理捕捉它们的机械行为。结合纱线水平数据,它准确地预测应力应变响应,减少了广泛的物理测试的需要。简化的应变能方法将结果均匀化为三个关键变量,从而在几分钟内实现快速,准确的预测。经过实验验证,我们的框架可以模拟新的针织面料,而无需额外的测试。在现实世界中,织物通常以纱线材料或图案的变化为特征。该框架扩展到异质织物,表明不同区域之间的过渡可以使用简单的机械类比来捕获:串联和平行的弹簧。这使得异质纺织品被视为同质碎片的理想拼凑物,保持预测的准确性。通过设计和生产具有均匀压力的压缩套筒来演示该方法,说明框架如何支持针对特定辅助水平和解剖特征量身定制的针织衫的开发。通过结合体积有限元分析,通过均质化简化模型和控制材料过渡,该方法为下一代纬编织物设计提供了可扩展的高保真度路径。
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引用次数: 0
Peculiar multi-stability observed in Yoshimura origami structures: Evolution and regulation of snapping sequence 吉村折纸结构中观察到的特殊多重稳定性:断裂序列的演化与调控
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-11-26 DOI: 10.1016/j.eml.2025.102427
Xiao Hu , Haiping Wu , Qiwei Zhang , Hongbin Fang
Multi-stability, a hallmark of architected materials, has rarely been associated with Yoshimura origami—a classical pattern long regarded as mono-stable. In this study, we report the first experimental observation of peculiar multi-stability in Yoshimura structures and investigate both its evolution and regulation. By systematically varying the diagonal angle of the crease pattern, we reveal that small angles (≤30°) yield smooth, mono-stable force–displacement responses, whereas slightly larger angles (>30°) induce geometric incompatibility, facet bending, and successive snapping events. In particular, pronounced multi-stability emerges in structures with larger diagonal angles (34°), where multiple stable equilibria and negative stiffness phenomena are observed. To regulate these snapping, we introduce a crease-design strategy based on the PALEO cutting pattern, and experimentally establish quantitative relationships between crease stiffness and geometric design parameters. By tailoring crease stiffness across different sections of a Yoshimura prototype, all six possible snapping sequences in a three-section structure are successfully realized under compression. These results establish Yoshimura origami as a new member of the multi-stable origami family and introduce a systematic framework for regulating its snapping behavior, offering new opportunities for adaptive structures, mechanical computing, and programmable metamaterials.
多稳定性,建筑材料的一个标志,很少与吉村折纸——一种长期被认为是单稳定的经典图案——联系在一起。在这项研究中,我们首次报道了吉村结构中特殊的多重稳定性的实验观察,并研究了它的演变和调控。通过系统地改变折痕图的对角角,我们发现小角度(≤30°)产生光滑的、单稳定的力-位移响应,而稍大的角度(>30°)会导致几何不相容、面弯曲和连续的断裂事件。特别是,在较大对角角(34°)的结构中,出现了明显的多重稳定性,在那里观察到多重稳定平衡和负刚度现象。为了调节这些断裂,我们引入了一种基于PALEO切割模式的折痕设计策略,并通过实验建立了折痕刚度与几何设计参数之间的定量关系。通过剪裁Yoshimura原型不同部分的折痕刚度,在压缩条件下成功实现了三段结构中所有六种可能的断裂序列。这些结果确立了Yoshimura折纸作为多稳定折纸家族的新成员,并引入了一个系统的框架来调节其断裂行为,为自适应结构、机械计算和可编程超材料提供了新的机会。
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引用次数: 0
Fracture in hexagonal honeycomb lattices undergoing large deformation 在大变形的六边形蜂窝晶格中断裂
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-11-23 DOI: 10.1016/j.eml.2025.102425
Ram Hemanth Yeerella , Shengqiang Cai
Architected materials are increasingly used in applications where large deformations are unavoidable. In the small-deformation regime, such periodic designs can be modeled as continuum elastic solids with effective elastic material properties, allowing Linear Elastic Fracture Mechanics (LEFM) to describe and predict their fracture behavior. But when such structures are pushed into large-strain conditions, often the critical design scenario—can we achieve a similar simplification to model them as continuum soft solids? In the current study, using finite element simulations of hexagonal honeycombs, we find that the crack tip stress and deformation fields are uniquely determined by the energy release rate (G), in Mode I loading. At high stretches, the stress singularity scaling relationship shifts from that predicted by LEFM to one characteristic of nonlinear hyperelastic solids. We further show that the driving force for fracture can be predicted by treating these lattices as hyperelastic continuum solids, provided the strain energy density of the uncracked lattice is known. These findings provide a pathway for a simple continuum-based framework to predict failure in a wide range of deformable architected material designs.
建筑材料越来越多地用于不可避免的大变形的应用中。在小变形状态下,这种周期性设计可以建模为具有有效弹性材料特性的连续弹性固体,允许线性弹性断裂力学(LEFM)描述和预测其断裂行为。但是,当这种结构被推到大应变条件下时,通常是关键的设计场景——我们能否实现类似的简化,将它们建模为连续软固体?在本研究中,通过对六边形蜂窝的有限元模拟,我们发现裂纹尖端的应力和变形场是唯一由能量释放率(G)决定的。在高拉伸时,应力奇点标度关系从LEFM预测的转变为非线性超弹性固体的一个特征。我们进一步表明,如果已知未裂纹晶格的应变能密度,可以通过将这些晶格视为超弹性连续固体来预测断裂的驱动力。这些发现为简单的基于连续体的框架提供了一条途径,以预测各种可变形建筑材料设计中的失效。
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引用次数: 0
Complex plastic deformation in glassy thin polymer films on 3D-printed auxetic lattices 3d打印的形变晶格上的玻璃状聚合物薄膜的复杂塑性变形
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-11-18 DOI: 10.1016/j.eml.2025.102422
Kenya Hazell , Anesia Auguste , Andrew Gillman , Lawrence F. Drummy
Traditionally, plastic deformation and the micromechanics of thin polymer films have been evaluated under uniaxial or linear strain. As the use of thin film polymeric materials continues to expand into applications in flexible electronics, gas separation, energy storage and sensing, more work needs to be done to understand how these materials behave under realistic conditions. Concurrently, certain mechanical metamaterials offer the ability to investigate non-linear and multi-axis micromechanics through lattice structures with designed spatially-varying complex strain fields. While previous studies using a support structure have been performed to study polymer crazing in thin films under biaxial or shear conditions, their behavior under complex strain has not been reported. This work offers a new method in which complex strain analysis in polymer films can be performed using an auxetic support lattice with a designed Poisson’s ratio (v) that is defined by the geometry of the lattice, not the Poisson’s ratio of the material. A comparative study was performed between thin films supported on lattices with Poisson’s ratio (v = +0.2 and −0.8) lattice to represent a pseudo-uniaxial and complex strain case, respectively. The uniaxial strain lattice demonstrated similar craze propagation, area fraction, and craze interaction behavior to what has been previously observed using traditional methods, e.g. a copper grid support lattice. For the complex strain analysis, the craze appearances observed in the middle section of the bowtie reflected what was expected for the uniaxial case while the end region showed a biaxial strain field. A potential for shearing was noted in the end of the bowties for the parallel strain direction with crazes growing at 45°. Due to the difference in strain distribution within the complex lattice, a delayed onset was observed in the bowtie end region parallel to strain direction. The initial results of complex crazing using an auxetic lattice was successful in demonstrating how crazes behave under a strain field on an auxetic lattice support with v = -0.8.
传统上,聚合物薄膜的塑性变形和微观力学是在单轴或线性应变下进行评估的。随着薄膜聚合物材料在柔性电子、气体分离、能量存储和传感领域的应用不断扩大,需要做更多的工作来了解这些材料在现实条件下的表现。同时,某些机械超材料通过设计具有空间变化复杂应变场的晶格结构提供了研究非线性和多轴微观力学的能力。虽然以前的研究使用支撑结构来研究聚合物在双轴或剪切条件下在薄膜上的裂纹,但它们在复杂应变下的行为尚未报道。这项工作提供了一种新的方法,在这种方法中,聚合物薄膜中的复杂应变分析可以使用具有设计泊松比(v)的辅助支撑晶格进行,该支撑晶格由晶格的几何形状定义,而不是由材料的泊松比定义。采用泊松比(v = +0.2)和泊松比(v = - 0.8)晶格支撑薄膜,分别对拟单轴应变和复杂应变情况进行了对比研究。单轴应变晶格表现出类似的裂纹扩展、面积分数和裂纹相互作用行为,与之前使用传统方法观察到的类似,例如铜网格支撑晶格。在复杂应变分析中,在领结中部观察到的开裂现象反映了单轴情况,而末端区域则显示了双轴应变场。当裂纹在45°方向上生长时,在平行应变方向的结结末端有可能发生剪切。由于复合晶格内应变分布的差异,在平行于应变方向的领结端区观察到延迟发生。在v = -0.8的条件下,利用辅助晶格进行复合裂纹的初步结果成功地展示了裂纹在应变场下的行为。
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引用次数: 0
High-precision fluidic Kirigami morphing surface for ultrasonic holographic lensing and haptic interfacing 用于超声全息透镜和触觉接口的高精度流体基里伽米变形表面
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-11-17 DOI: 10.1016/j.eml.2025.102424
Ardalan Kahak , Moustafa Sayed Ahmed , Nahid Kalantaryardebily , Hrishikesh Kulkarni , Netta Gurari , Shima Shahab , Suyi Li
Morphing surfaces provide a versatile tool to advance the functionalities of high-performance aircraft, soft robots, biomedical devices, and human–machine interfaces. However, achieving precise shape transformation and mechanical property control remains challenging due to nonlinearity, design constraints, and the difficulty of coordinating multiple constituent materials across a continuous surface. To this end, this study unveils that Kirigami art can inspire novel solutions. More specifically, the geometric principles of Kirigami can be exploited to design and fabricate fluidic morphing surfaces capable of highly accurate shape morphing and output force control, all via a single pressure input. This study presents a systematic approach to designing Kirigami for tuning the local deformation and force output through extensive nonlinear modeling and experiment validation on two archetypal patterns: concentric square and circular cuts. The potentials of this approach are demonstrated via two multiphysics case studies: (1) an acoustic holography lens for ultrasonic wave steering, achieving highly accurate deformation control under a single global pressure input, and (2) a haptic device with a small volume, constant contact area, and high-resolution output force. The fluidic Kirigami concept allows for simple yet effective adaptation to different shape and stiffness requirements, paving the way for a new family of scalable and programmable morphing surfaces.
变形表面为高性能飞机、软体机器人、生物医学设备和人机界面提供了一种多功能工具。然而,由于非线性、设计限制以及在连续表面上协调多个组成材料的困难,实现精确的形状转换和机械性能控制仍然具有挑战性。为此,本研究揭示了Kirigami艺术可以激发新的解决方案。更具体地说,Kirigami的几何原理可以用于设计和制造流体变形表面,这些表面能够通过单一压力输入实现高精度的形状变形和输出力控制。本研究提出了一种系统的方法来设计Kirigami,通过广泛的非线性建模和实验验证两种原型模式:同心正方形和圆形切割,以调整局部变形和力输出。通过两个多物理场案例研究证明了这种方法的潜力:(1)用于超声波转向的声全息透镜,在单一全局压力输入下实现高精度的变形控制,以及(2)具有小体积,恒定接触面积和高分辨率输出力的触觉设备。流体Kirigami概念允许简单而有效地适应不同的形状和刚度要求,为一系列新的可扩展和可编程变形表面铺平了道路。
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Extreme Mechanics Letters
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