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Front cover CO1 前盖CO1
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-11-01 DOI: 10.1016/S2352-4316(25)00127-0
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引用次数: 0
When and where do large cracks grow? Griffith energy competition constrained by material strength 大裂缝何时何地出现?格里菲斯能源竞争受材料强度制约
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-11-01 DOI: 10.1016/j.eml.2025.102417
Oscar Lopez-Pamies, Farhad Kamarei
An abundance of comparisons with experimental evidence has long settled that the Griffith energy competition along a known crack path — commonly expressed as a criticality condition on the energy release rate — describes when a large crack grows in a nominally elastic brittle material that is subjected to quasi-static loading. However, the answer to the question of where — that is, in which direction — a large crack grows remains unresolved. A slew of criteria have been proposed over the decades, but comparisons with experiments have indicated that none of such criteria apply in general.
Directly guided by the mathematical structure of the regularized phase-field theory of fracture initiated by Kumar, Francfort, and Lopez-Pamies (J. Mech. Phys. Solids 112 (2018), 523–551), and motivated by the wide range of experiments that this theory has been validated against, this Letter introduces a new criterion to describe when and where large cracks grow in elastic brittle materials under quasi-static loading conditions. In a nutshell: the growth of a large crack takes place within and only within regions where the strength surface of the material has been exceeded, this in a manner such that the sum of the potential (that is, the elastic energy minus the work of the external loads) and surface energies are minimized. Importantly, this strength-constrained Griffith-energy-competition criterion is general in the sense that it applies to materials with any elasticity (linear or nonlinear) and any material symmetry (isotropic or anisotropic). In this Letter, for simplicity of presentation, attention is restricted to the most basic of settings, that of isotropic linear elastic brittle materials. Following its raison d’etre by means of a simple example and then general introduction, the proposed criterion is confronted with a set of classical experiments on glass.
大量与实验证据的比较早已确定了沿已知裂纹路径的格里菲斯能量竞争-通常表示为能量释放率的临界条件-描述了当名义上的弹性脆性材料受到准静态载荷时出现大裂纹时的情况。然而,一个大裂缝在哪里——也就是说,在哪个方向——生长的问题的答案仍然没有得到解决。几十年来,人们提出了一系列的标准,但与实验的比较表明,这些标准都不适用。在Kumar, Francfort, and Lopez-Pamies (J. Mech.)提出的裂缝正则相场理论的数学结构的直接指导下。理论物理。固体112(2018),523-551),并受到该理论已被验证的广泛实验的启发,这封信引入了一个新的标准来描述在准静态加载条件下弹性脆性材料中的大裂纹何时何地产生。简而言之:大裂纹的增长发生在且仅发生在材料强度表面已被超过的区域内,这种方式使得势能(即弹性能减去外部负载的功)和表面能的总和最小。重要的是,这种强度约束的格里菲斯-能量竞争准则在某种意义上是通用的,它适用于具有任何弹性(线性或非线性)和任何材料对称性(各向同性或各向异性)的材料。在这封信中,为了表述简单,注意力被限制在最基本的设置,即各向同性线弹性脆性材料。通过一个简单的例子和一般的介绍,给出了该准则的存在理由,并与一系列经典的玻璃实验进行了对比。
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引用次数: 0
Self-locking and stability of the bowline knot 自锁和稳定的蝴蝶结结
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-27 DOI: 10.1016/j.eml.2025.102413
Bastien F.G. Aymon , Fani Derveni , Michael Gomez , Jérôme Crassous , Pedro M. Reis
We investigate the self-locking of the bowline knot through numerical simulations, experiments, and theoretical analysis. Specifically, we perform two complementary types of simulations using the 3D finite-element method (FEM) and a reduced-order model based on the discrete-element method (DEM). For the FEM simulations, we develop a novel mapping technique that automatically transforms the centerline of the rod into the required knot topology prior to loading. In parallel, we conduct experiments using a nearly inextensible elastic rod tied into a bowline around a rigid cylinder. One end of the rod is pulled to load the knot while the other is left free. The measured force–displacement response serves to validate both the FEM and DEM simulations. Leveraging these validated computational frameworks, we analyze the internal tension profile along the rod’s centerline, revealing that a sharp drop in tension concentrates around a strategic locking region, whose geometry resembles that observed in other knot types. By considering the coupling of tension, bending, and friction, we formulate a theoretical model inspired by the classic capstan problem to predict the stability conditions of the bowline, finding good agreement with our FEM and DEM simulations. Our methodology and findings offer new tools and insights for future studies on the performance and reliability of other complex knots.
本文通过数值模拟、实验和理论分析研究了弓形结的自锁特性。具体来说,我们使用三维有限元法(FEM)和基于离散元法(DEM)的降阶模型进行了两种互补类型的模拟。对于有限元模拟,我们开发了一种新的映射技术,可以在加载之前自动将杆的中心线转换为所需的结拓扑结构。与此同时,我们用一根几乎不可伸缩的弹性杆系在一个刚性圆柱体上的弓形线上进行实验。拉杆的一端用来装绳结,而另一端是空着的。测量的力-位移响应用于验证FEM和DEM模拟。利用这些经过验证的计算框架,我们分析了沿杆中心线的内部张力分布,发现张力急剧下降集中在一个战略锁定区域周围,其几何形状与其他类型的结相似。在考虑张力、弯曲和摩擦耦合的情况下,我们建立了一个受经典绞盘问题启发的理论模型来预测弓形索的稳定条件,结果与FEM和DEM模拟结果吻合较好。我们的方法和发现为未来研究其他复杂节的性能和可靠性提供了新的工具和见解。
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引用次数: 0
Peeling adhesion regime transition of elastic tapes 弹性胶带的剥离附着力转变
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-25 DOI: 10.1016/j.eml.2025.102414
Jianyue Deng , Changhong Linghu 令狐昌鸿 , Shubo Zhang 张舒博 , Zhiyu Ng , Deon Low , Huajian Gao , K. Jimmy Hsia , Haibao Lu
Peeling phenomena are frequently observed in nature and in various applications, including wearables, heterogeneous integration, and 2D materials fabrication. Adhesion plays a critical role in the peeling process. The standard 90-degree peeling test is widely used to measure interfacial adhesion. However, a comprehensive mechanical understanding of the transition across different adhesion regimes—energy-controlled, intermediate, and strength-dominated—remains incomplete. Although many previous theoretical models have discussed these regimes individually, a unified solution with systematic experimental validation across the entire regime spectrum is yet to be obtained. Here we systematically investigate the 90-degree peeling of elastic tapes with varying bending stiffness from rigid substrates through a combination of theoretical analysis, experiments, and finite element analysis (FEA) simulations. A general and explicit expression for the peak peeling force is formulated, capturing the full spectrum of adhesion regimes and predicting the peak force as well as the transition points accurately. The theoretical results exhibit good agreement with experimental measurements and FEA simulations across all three regimes. This study provides a unified solution to the 90-degree peeling process and a practical guideline for the design and evaluation of 90-degree peeling adhesion behavior of elastic tapes.
在自然界和各种应用中经常观察到剥落现象,包括可穿戴设备,异质集成和二维材料制造。附着力在剥离过程中起着至关重要的作用。标准的90度剥离试验被广泛用于测量界面附着力。然而,对不同粘附状态(能量控制、中间和强度主导)之间的过渡的全面的机械理解仍然不完整。尽管许多先前的理论模型已经单独讨论了这些状态,但尚未获得一个统一的解决方案,并在整个状态谱中进行了系统的实验验证。本文通过理论分析、实验和有限元分析(FEA)模拟相结合的方法,系统地研究了具有不同弯曲刚度的弹性带从刚性基板上90度剥落的情况。对于峰值剥离力的一般和明确的表达式被制定,捕捉粘接力的全谱和预测峰值力以及准确的过渡点。理论结果与实验测量和有限元模拟结果吻合良好。本研究为90度剥离过程提供了统一的解决方案,并为弹性胶带90度剥离粘附性能的设计和评价提供了实用指南。
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引用次数: 0
The nonlinear elastic response of magnetorheological elastomers 磁流变弹性体的非线性弹性响应
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-14 DOI: 10.1016/j.eml.2025.102412
Chao Wang , Yingqi Jia , Arvin Ardebili Sharma , Zhi Zhao , Xiaojia Shelly Zhang
Magnetorheological elastomers (MREs), consisting of a soft elastomeric matrix embedded with rigid (and typically magnetized) particles such as NdFeB, are increasingly used in mechanical and biomedical applications. Accurate modeling of their magneto-mechanical behavior requires first predicting their purely mechanical response. Traditionally, this mechanical prediction has relied on directly measuring the macroscopic response of MREs, either numerically or experimentally, for each particle fraction of interest, a procedure that is both time-consuming and labor-intensive. In this study, we replace that procedure with a simple computational framework that requires only a single measurement on the unfilled elastomer. The framework treats MREs as general incompressible filled elastomers and predicts their nonlinear elastic response by integrating several established modeling techniques. For any physically admissible particle volume fraction, it analytically predicts the macroscopic nonlinear response from the measured properties of the unfilled elastomer. We validate the framework experimentally across a wide range of cross-link densities in the elastomeric matrices, particle volume fractions (0%–28%), and specimen geometries, subjected to both uniform and highly localized large deformations (with local strains up to 600%). The experimental results show excellent agreement with the computational predictions, confirming the framework as a fast and reliable tool for predicting the nonlinear elastic response of MREs. Consequently, this study offers a practical tool for streamlining the modeling and design of MRE-based structures.
磁流变弹性体(MREs)由嵌入刚性(通常磁化)颗粒(如钕铁硼)的软弹性体基体组成,越来越多地用于机械和生物医学应用。要对其磁力学行为进行精确建模,首先需要预测其纯力学响应。传统上,这种力学预测依赖于直接测量MREs的宏观响应,无论是数值还是实验,对于每个感兴趣的粒子分数,这一过程既耗时又费力。在这项研究中,我们用一个简单的计算框架取代了这一过程,该框架只需要对未填充的弹性体进行一次测量。该框架将MREs视为一般的不可压缩填充弹性体,并通过集成几种已建立的建模技术来预测其非线性弹性响应。对于任何物理上允许的颗粒体积分数,它解析地预测了未填充弹性体的宏观非线性响应。我们在弹性体基质、颗粒体积分数(0%-28%)和试样几何形状的广泛交联密度范围内对框架进行了实验验证,这些结构受到均匀和高度局部化的大变形(局部应变高达~ 600%)的影响。实验结果与计算预测结果吻合良好,证实了该框架是一种快速、可靠的预测mre非线性弹性响应的工具。因此,本研究为简化基于mre的结构的建模和设计提供了实用的工具。
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引用次数: 0
Cross-scale magnetic catheter-magnetic swarm strategy for precise thrombus clearance 跨尺度磁导管-磁群策略精确清除血栓
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-11 DOI: 10.1016/j.eml.2025.102411
Yunqi Xu , Congcong Lou , Ken Cham-Fai Leung , Xinglong Gong , Shouhu Xuan
Thrombotic vascular occlusion presents a critical clinical emergency requiring rapid and precise intervention to restore blood flow and prevent tissue necrosis. Current therapies are constrained by poor accessibility to deeply seated thrombus and a lack of controlled navigation. Here, we propose a cross-scale thrombus removal strategy based on an integrated "magnetic catheter-magnetic swarm" system that couples a steerable magnetic catheter (macro-scale) with dynamically assembled Fe3O4@PDA swarm (micro-scale). Anisotropic Fe3O4@PDA nanoparticles were synthesized and magnetically actuated to form dynamic swarm under a rotating magnetic field. The swarm exhibited excellent maneuverability, deformation, and transport in complex and confined environments, while the magnetic catheter enabled precise macroscopic delivery. Driven by external magnetic fields, the swarm generated localized shear forces and hydrodynamic stresses to mechanically disrupt and loosen thrombus, promoting fragmentation and removal. The resulting debris, together with the swarm, was magnetically guided back to the catheter for retrieval, ensuring efficient clearance and minimizing embolism risk. This cross-scale system was validated in a cardiac vascular model, demonstrating safe, controllable, and minimally invasive thrombus removal in complex vascular structures. The proposed approach establishes a mechanics-driven platform for minimally invasive thrombus removal and offers a new paradigm for designing multifunctional micro/nanorobotic systems in biomedical applications.
血栓性血管闭塞是一个关键的临床紧急情况,需要快速和精确的干预,以恢复血液流动和防止组织坏死。目前的治疗方法受到深层血栓难以接近和缺乏控制导航的限制。在这里,我们提出了一种基于集成“磁管-磁群”系统的跨尺度血栓清除策略,该系统将可操纵的磁管(宏观尺度)与动态组装的Fe3O4@PDA群(微观尺度)耦合在一起。合成了各向异性Fe3O4@PDA纳米粒子,并在旋转磁场下磁驱动形成动态蜂群。在复杂和受限的环境中,蜂群表现出出色的机动性、变形性和运输能力,而磁导管则能够实现精确的宏观输送。在外部磁场的驱动下,蜂群产生局部剪切力和流体动力应力,机械地破坏和松动血栓,促进血栓的破碎和去除。由此产生的碎片连同一群碎片一起被磁引导回导管进行回收,确保有效清除并最大限度地降低栓塞风险。该跨尺度系统在心脏血管模型中得到验证,证明了在复杂血管结构中安全、可控和微创的血栓清除。该方法建立了微创血栓清除的力学驱动平台,为生物医学应用中多功能微/纳米机器人系统的设计提供了新的范例。
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引用次数: 0
Precipitate response in GRCop-42 metallic microparticles under extreme impact conditions GRCop-42金属微粒在极端冲击条件下的沉淀响应
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-09-29 DOI: 10.1016/j.eml.2025.102410
Jianxiong Li , Yuan Yao , Mostafa Hassani
GRCop-42 is a Cu-based alloy strengthened primarily through precipitation hardening by a single Cr2Nb phase. While its deformation mechanisms under quasi-static conditions have been extensively studied, the behavior of these precipitates under extreme strain rates remains poorly understood. In this study, we investigate the high-rate response of GRCop-42 powder using laser-induced microparticle impact testing (LIPIT), where individual alloy particles are impacted onto a pure Cu substrate at velocities ranging from 100 to 600 m/s. We observe a transition from rebound to impact-induced bonding at ∼490 ± 11 m/s. Cross-sectional microstructural analysis of bonded particles reveals that, although high strain rate impact does not lead to significant precipitate fracture or coarsening, the precipitates undergo shape changes. At higher velocities, the Cr2Nb precipitates exhibit increased aspect ratios, particularly near particle edges. This oblate deformation at the precipitate scale is attributed to localized temperature rise from adiabatic heating, driven by extreme plastic deformation. The effect is more pronounced at higher velocities and is spatially concentrated near the periphery of the particle–substrate interface.
GRCop-42是一种cu基合金,主要通过单个Cr2Nb相的沉淀硬化来强化。虽然其在准静态条件下的变形机制已经被广泛研究,但这些析出物在极端应变速率下的行为仍然知之甚少。在这项研究中,我们使用激光诱导微粒冲击测试(LIPIT)研究了GRCop-42粉末的高速率响应,其中单个合金颗粒以100至600 m/s的速度撞击纯Cu衬底。我们观察到在~ 490 ± 11 m/s的速度下从反弹到冲击诱导键的转变。结合颗粒的断面显微组织分析表明,虽然高应变速率冲击不会导致明显的析出相断裂或粗化,但析出相发生了形状变化。在较高的速度下,Cr2Nb析出物表现出增大的长径比,特别是在颗粒边缘附近。这种在沉淀尺度上的扁形变形归因于极端塑性变形驱动的绝热加热引起的局部温升。这种效应在较高的速度下更为明显,并且在空间上集中在颗粒-衬底界面的外围附近。
{"title":"Precipitate response in GRCop-42 metallic microparticles under extreme impact conditions","authors":"Jianxiong Li ,&nbsp;Yuan Yao ,&nbsp;Mostafa Hassani","doi":"10.1016/j.eml.2025.102410","DOIUrl":"10.1016/j.eml.2025.102410","url":null,"abstract":"<div><div>GRCop-42 is a Cu-based alloy strengthened primarily through precipitation hardening by a single Cr<sub>2</sub>Nb phase. While its deformation mechanisms under quasi-static conditions have been extensively studied, the behavior of these precipitates under extreme strain rates remains poorly understood. In this study, we investigate the high-rate response of GRCop-42 powder using laser-induced microparticle impact testing (LIPIT), where individual alloy particles are impacted onto a pure Cu substrate at velocities ranging from 100 to 600 m/s. We observe a transition from rebound to impact-induced bonding at ∼490 ± 11 m/s. Cross-sectional microstructural analysis of bonded particles reveals that, although high strain rate impact does not lead to significant precipitate fracture or coarsening, the precipitates undergo shape changes. At higher velocities, the Cr<sub>2</sub>Nb precipitates exhibit increased aspect ratios, particularly near particle edges. This oblate deformation at the precipitate scale is attributed to localized temperature rise from adiabatic heating, driven by extreme plastic deformation. The effect is more pronounced at higher velocities and is spatially concentrated near the periphery of the particle–substrate interface.</div></div>","PeriodicalId":56247,"journal":{"name":"Extreme Mechanics Letters","volume":"80 ","pages":"Article 102410"},"PeriodicalIF":4.5,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145227245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Early onset of snapping of slender beams under transverse forcing 细长梁在横向受力下的早期断裂
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-09-25 DOI: 10.1016/j.eml.2025.102407
Colin M. Meulblok , Hadrien Bense , M. Caelen , Martin van Hecke
The hysteretic snapping under transverse forcing of a compressed, buckled beam is fundamental for many devices and mechanical metamaterials. For a single-tip transverse pusher, an important limitation is that snapping requires the pusher to cross the longitudinal axis of the beam. Here, we show that dual-tip pushers allow early-onset snapping, where the beam snaps before the pusher reaches the longitudinal axis. As a consequence, we show that when a buckled beam under increased compression comes in contact with a dual-tip pusher, it can snap to the opposite direction — this is impossible with a single-tip pusher. Additionally, we reveal a novel two-step snapping regime, in which the beam sequentially loses contact with the two tips of the dual-tip pusher. To characterize this class of snapping instabilities, we employ a systematic modal expansion of the beam shape. This expansion allows us to capture and analyze the transition from one-step to two-step snapping geometrically. Finally we demonstrate how to maximize the distance between the pusher and the beam’s longitudinal axis at the moment of snapping. Together, our work opens up a new avenue for quantitatively and qualitatively controlling and modifying the snapping of buckled beams, with potential applications in mechanical sensors, actuators, and metamaterials.
压缩屈曲梁在横向受力下的滞回断裂是许多器件和机械超材料的基础。对于单尖端横向推挤器,一个重要的限制是,冲压需要推挤器穿过光束的纵轴。在这里,我们表明,双尖端的推杆允许早发作的折断,其中光束折断之前,推杆到达纵轴。因此,我们表明,当压缩增加的弯曲梁与双尖端推力器接触时,它可以向相反方向折断-这是单尖端推力器不可能做到的。此外,我们揭示了一种新的两步捕捉机制,其中光束依次失去与双尖端推杆的两个尖端的接触。为了描述这类断裂不稳定性,我们采用了梁形的系统模态展开。这种扩展使我们能够捕捉和分析从一步到两步的几何转换。最后,我们演示了如何最大限度地提高推杆与梁的纵轴之间的距离。总之,我们的工作为定量和定性控制和修改屈曲梁的断裂开辟了一条新的途径,在机械传感器、致动器和超材料中具有潜在的应用前景。
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引用次数: 0
Tracing back transient information from near-stationary random data 从近平稳随机数据追溯瞬态信息
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-09-23 DOI: 10.1016/j.eml.2025.102408
Xi Chen , Xiaoling Jin , Yong Wang , Zhilong Huang
Tracing back the past and predicting the future are of equal importance, while compared to the prediction, the backtracking is far from receiving the attention it deserves. With the explosive advances of the diffusion models, backtracking has undergone a complete renaissance, especially for stochastic systems. This work addresses this issue, tracing back transient information from near-stationary random data. Different from the diffusion models, we aim for statistical information but not sample information, and we only need near-stationary sample segments for identification, but not a large number of full-time samples for learning. The core idea of this data-driven method is: embedding Fokker-Planck equation (as a priori physical knowledge), which portrays the evolution of probability density of state, and then identifying and solving it to trace back the transient probability density. The efficacy of this method is demonstrated by three typical examples, namely, a one-dimensional linear system, a two-dimensional linear system, and the van der Pol system.
回顾过去和预测未来同样重要,但与预测相比,回溯远远没有得到应有的重视。随着扩散模型的爆炸式发展,回溯已经经历了一个完整的复兴,特别是对于随机系统。这项工作解决了这个问题,从接近平稳的随机数据中追溯瞬态信息。与扩散模型不同的是,我们的目标是统计信息而不是样本信息,我们只需要近平稳的样本段进行识别,而不需要大量的全职样本进行学习。这种数据驱动方法的核心思想是:嵌入描述状态概率密度演变的Fokker-Planck方程(作为先验的物理知识),然后对其进行识别和求解,追溯瞬时概率密度。通过一维线性系统、二维线性系统和van der Pol系统三个典型实例证明了该方法的有效性。
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引用次数: 0
Effect of extreme hydrostatic pressure on ion diffusion in polymer electrolytes: Emergence of glass-transition pressure 极端静水压力对聚合物电解质中离子扩散的影响:玻璃化转变压力的出现
IF 4.5 3区 工程技术 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-09-23 DOI: 10.1016/j.eml.2025.102409
Zhaoxin Zhang , Weifeng Zou , Yukai Zhao , Shuze Zhu , Tiefeng Li
Polymer electrolytes in solid-state batteries are critical for applications demanding mechanical flexibility and tolerance. Recent research progress has underscored the potential significance of employing solid electrolytes in extreme environments, such as the high hydrostatic pressure encountered during deep-sea exploration. Consequently, understanding how extreme hydrostatic pressure affects ion diffusion in polymer electrolytes is of substantial importance. In this work, large-scale molecular dynamics simulations are utilized to investigate the diffusion of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) in a representative polymer electrolyte, specifically poly(ethylene oxide) (PEO). We reveal a previously unreported mechanism associated with the emergence of a glass-transition pressure, above which the polymer matrix exhibits glass-like characteristics. The transport behavior of Li⁺ ions shows a distinct contrast below and beyond this critical pressure. Through theoretical scaling analysis, we show that ionic diffusivity is proportional to material volume, and is therefore governed by this same phase-transition pressure, which rationalizes our simulation results. This work provides potential guidance for understanding and designing polymer electrolytes with tolerance to extreme pressures.
固态电池中的聚合物电解质对于要求机械灵活性和耐受性的应用至关重要。最近的研究进展强调了在极端环境中使用固体电解质的潜在意义,例如在深海勘探期间遇到的高静水压力。因此,了解极端静水压力如何影响聚合物电解质中的离子扩散是非常重要的。在这项工作中,利用大规模分子动力学模拟来研究锂二(三氟甲烷磺酰)亚胺(LiTFSI)在典型聚合物电解质,特别是聚环氧乙烷(PEO)中的扩散。我们揭示了先前未报道的与玻璃化转变压力出现相关的机制,高于此压力的聚合物基质表现出玻璃样特征。Li +离子的输运行为在这个临界压力以下和超出这个临界压力之后显示出明显的对比。通过理论尺度分析,我们发现离子扩散率与材料体积成正比,因此受相同的相变压力的控制,这使我们的模拟结果合理化。这项工作为理解和设计耐极端压力的聚合物电解质提供了潜在的指导。
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引用次数: 0
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Extreme Mechanics Letters
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