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Influence of the Woven Structure on the Initial Fracture Behavior of Roving Glass Fabric Reinforced Composites 编织结构对玻璃纤维增强复合材料初始断裂行为的影响
Pub Date : 2018-04-12 DOI: 10.4236/OJCM.2018.82005
Zhilan Xu, A. Yokoyama
In this paper, investigation on the initial fracture behavior was carried out on roving glass woven fabric reinforced composites which were manufactured by hand lay-up method. Two kinds of roving glass woven fabrics of different FAW (Fabric Area Weight) and crimp ratio, Type A of 570 g/m2 and Type B of 800 g/m2, were adopted as reinforcement in this study. Tensile test was conducted and tensile properties were discussed on specimens of 6 degrees 0°/5°/10°/80°/85°/90°. The initial fracture behavior was observed on 0 degree and 90 degree and the fracture mechanism was compared and discussed among 5°/10°/80°/85°. The results showed that Type B has higher tensile modulus and tensile strength than that of Type A. And different initial fracture behaviors between two kinds of materials was observed and analyzed, which indicated that the crimp ratio plays an important role of woven fabric reinforced composites in fracture mechanism.
对手工铺层法制备的粗纱玻璃机织布增强复合材料的初始断裂行为进行了研究。本研究采用两种不同FAW(织物面积重量)和卷曲比的粗纱玻璃机织物,A型为570 g/m2, B型为800 g/m2。进行了6°0°/5°/10°/80°/85°/90°试样的拉伸试验,并讨论了拉伸性能。观察了0°和90°断口的初始断裂行为,对比讨论了5°/10°/80°/85°断口的断裂机理。结果表明,B型复合材料的拉伸模量和拉伸强度均高于a型复合材料,并对两种材料的初始断裂行为进行了观察和分析,表明卷曲率在机织物增强复合材料断裂机制中起着重要作用。
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引用次数: 1
Microwave Synthesis of Ce/BiVO 4 Nanocomposites Photocatalyst and Their Photocatalytic Properties 微波合成Ce/BiVO4纳米复合光催化剂及其光催化性能
Pub Date : 2018-04-12 DOI: 10.4236/ojcm.2018.82006
Ming-Huang Tuo, Shuibin Yang, Xuehong Liao
Ce/BiVO4 nanocomposites photocatalyst was synthesized by direct feeding microwave synthesis method, using bismuth nitrate (Bi (NO3)3·5H2O), cerium nitrate hexahydrate (Ce (NO3)3·6H2O) and ammonium metavanadate (NH4VO3) as raw material and sodium dodecyl sulfate (SDS) as surfactant. The X-ray diffractometer (XRD) and the scanning electron microscopy (SEM) technology were used to characterize the Ce/BiVO4 nanocomposites. We investigated the photocatalytic activity of the as-prepared photocatalyst, and methyl orange was used as organic pollutant. The results show that the Ce/BiVO4 nanocomposite was a good photocatalyst under visible light. In 100 ml of 5 mg/L methylene orange solution, when the catalyst calcined at 673 K was 0.1 g, hydrogen peroxide was 0.5 ml, pH was 2.0, and the degradation ratio of catalyst for methylene orange reached 90.26% within 70 min.
以硝酸铋(Bi(NO3)3·5H2O)、六水合硝酸铈(Ce(NO4)3·6H2O)和偏钒酸铵(NH4VO3)为原料,十二烷基硫酸钠(SDS)为表面活性剂,采用微波直接进料法合成了Ce/BiVO4纳米复合光催化剂。采用X射线衍射仪(XRD)和扫描电子显微镜(SEM)技术对Ce/BiVO4纳米复合材料进行了表征。以甲基橙为有机污染物,研究了所制备的光催化剂的光催化活性。结果表明,Ce/BiVO4纳米复合材料在可见光下是一种良好的光催化剂。在100毫升5毫克/升的甲基橙溶液中,当催化剂在673 K下煅烧为0.1克,过氧化氢为0.5毫升,pH为2.0时,催化剂对甲基橙的降解率在70分钟内达到90.26%。
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引用次数: 0
Cement Bonded Particle Boards with Different Types of Natural Fibres—Using Carbon Dioxide Injection for Increased Initial Bonding 不同类型天然纤维的水泥粘接刨花板-使用二氧化碳注入以增加初始粘接
Pub Date : 2018-01-09 DOI: 10.4236/OJCM.2018.81003
B. Marteinsson, E. Gudmundsson
The effect of CO2 injection on initial strength increase and hardening of cement-fibre mix in a cement bonded particle board (CBPB) production was evaluated. Different cement contents, formation pressure and types of fibres were considered. The initial strength increase with CO2 injection is so much faster than this caused by conventional hydration that the produced samples do not need additional curing before they can be stored. Similar strength and stiffness values as in conventional products on the market are gained with lower cement content for similar types of fibres. Visual inspection of board surfaces aged for 13 years in a harsh exterior environment as well as comparison of strength and stiffness values for these boards when new and after ageing, gives a very satisfying result. The combined effect of the above discussed gains results in markedly increased productivity at lower cost and lower environmental impacts than is possible in traditional CBPB production.
研究了在水泥结合刨花板(CBPB)生产中,CO2注入对水泥纤维混合料初强度提高和硬化的影响。考虑了不同水泥含量、地层压力和纤维类型。注入二氧化碳的初始强度增加比常规水化引起的强度增加要快得多,因此生产的样品在储存之前不需要额外的固化。类似的强度和刚度值,在市场上的传统产品,以较低的水泥含量获得类似类型的纤维。在恶劣的外部环境中目视检查老化13年的板表面,并比较这些板在新时和老化后的强度和刚度值,得出了非常令人满意的结果。与传统的CBPB生产相比,上述收益的综合效应以更低的成本和更低的环境影响显著提高了生产率。
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引用次数: 6
Effects of Ultrasonic Waves during Resin Impregnation on the Mechanical Properties of Unidirectional Composite Materials 树脂浸渍过程中超声波对单向复合材料力学性能的影响
Pub Date : 2018-01-01 DOI: 10.4236/OJCM.2018.81001
Yasunari Kuratani, Aya Miki, N. Nanami, H. Nakatani, H. Hamada
Effects of ultrasonic vibrations on mechanical properties of fiber reinforced plastics were investigated during molding resin impregnation process in vacuum assisted resin transfer molding. The vacuum bag including the preformed each non-crimp fabrics (carbon and glass fibers) was placed in a water bath of an ultrasonic wave generator during resin impregnation. The mechanical properties of the laminates were evaluated through the mechanical strength tests and scanning electron microscope (SEM) observation. The results revealed that ultrasonic waves improved transverse tensile, flexural, interlaminar shear, and compressive strengths of the carbon fiber (CF) laminates and interlaminar shear and compressive strengths of the glass fiber (GF) laminates. It was found from SEM observation that the fracture modes of the CF and GF laminates processed using ultrasonic waves were resin fracture. Accordingly, the adhesion of the fiber/resin interface was improved by oscillating ultrasonic vibration during resin impregnation, leading to an increase of the interface strength.
研究了超声振动对纤维增强塑料在真空辅助树脂转移模塑中树脂浸渍过程中力学性能的影响。在树脂浸渍过程中,真空袋包括预成型的各种无卷曲织物(碳纤维和玻璃纤维)置于超声波发生器的水浴中。通过力学强度测试和扫描电镜观察,对复合材料的力学性能进行了评价。结果表明,超声波增强了碳纤维(CF)层合板的横向拉伸、弯曲、层间剪切和抗压强度,增强了玻璃纤维(GF)层合板的层间剪切和抗压强度。扫描电镜观察发现,超声处理的CF和GF层压板的断裂方式均为树脂断裂。因此,在树脂浸渍过程中,通过振荡超声振动改善了纤维/树脂界面的附着力,从而提高了界面强度。
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引用次数: 2
A Study on the Initial Fracture Behavior of CF/GF Intra-Hybrid Woven Fabric Reinforced Composites CF/GF混杂机织增强复合材料的初始断裂行为研究
Pub Date : 2018-01-01 DOI: 10.4236/OJCM.2018.81002
Zhilan Xu, A. Nakai, Yuqiu Yang, H. Hiroyuki
In this paper, woven fabrics of glass fiber/carbon fiber intra-hybrid in plain structure were used to fabricate fiber reinforced plastic (FRP) composite by hand lay-up method. The investigation on tensile property was carried out on specimens in 7 orientations including 0°/5°/15°/75°/85°/90° in previous works. With the specimen parameters and experimental data, FEM model was built by the software of Marc. By combining the experimental results and finite element analysis, the modulus was simulated and calculated at the first stage. Then interfacial stress of the 0 degree and 90 degree was also calculated. By the initial fracture stress data from experiment as well as the simulation value of interfacial strength of 0 and 90 degree, the initial fracture stress of the off-axial specimens wascalculated and predicted. The result shows that the interfacial strength of the glass fiber bundle is higher than that of the carbon fiber bundle in transverse direction. By using the interfacial strength and according to the Von Mises yielding criterion, the initial fracture stress was predicted, which can be a contribution to the design or predict of the material properties.
本文采用平面结构的玻璃纤维/碳纤维混纺机织织物,采用手工铺层法制备纤维增强塑料(FRP)复合材料。在前人的研究中,对试样进行了0°/5°/15°/75°/85°/90°7个方向的拉伸性能研究。根据试件参数和试验数据,利用Marc软件建立有限元模型。结合试验结果和有限元分析,对第一阶段的模量进行了模拟计算。然后分别计算了0°和90°的界面应力。根据实验得到的初始断裂应力数据以及0度和90度界面强度的模拟值,计算并预测了离轴试样的初始断裂应力。结果表明:玻璃纤维束的界面强度在横向上高于碳纤维束;利用界面强度,根据Von Mises屈服准则,预测了材料的初始断裂应力,为材料性能的设计和预测提供了依据。
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引用次数: 3
Development of Nickel Alloy Reinforced with Fused SiO2 Chilled Composites and Evaluation of Thermal Properties (Thermal Conductivity & Coefficient of Thermal Expansion) and Temperature Distribution by Finite Element Analysis (FEA) 熔融SiO2冷却复合材料增强镍合金的开发及其热性能(导热系数和热膨胀系数)和温度分布的有限元分析评估
Pub Date : 2017-09-14 DOI: 10.4236/OJCM.2017.75017
J. Hemanth
This paper presents the results obtained and the discussions made from a series of thermal experiments involving Nickel alloy (ASTM A 494 M) reinforced with fused SiO2, and size of the particles dispersed varies from 80 - 120 μm and amount of addition varies from 3 to 12 wt.% in steps of 3 wt.%. The resulting chilled MMCs are solidified under the influence of copper chill of 25 mm thickness to study the effect of chilling on thermal behaviour. Microstructural studies indicated that the reinforcement distribution is uniform with very good bonding due to chilling effect. Thermal properties were found to decrease significantly with increase in SiO2 content in chilled MMCs. It is concluded from the research that reinforcement content and the temperature has an effect on coefficient of thermal expansion and thermal conductivity of the chilled composite developed. Finite element analysis of the exhaust valve of the IC indicates that chilled Ni alloy composite developed in the present research can be used as alternate material for the existing valve material (Ni-Cr alloy steel). All the tests conducted in this research are in conformance with ASTM standards.
本文介绍了用熔融SiO2增强镍合金(ASTM a 494 M)的一系列热实验的结果和讨论,分散的颗粒尺寸在80-120μm之间,添加量在3-12wt%之间,以3wt%为步长。在25mm厚的铜冷却的影响下,对冷却后的MMCs进行固化,以研究冷却对热行为的影响。微观结构研究表明,由于激冷效应,钢筋分布均匀,结合良好。研究发现,随着冷却MMCs中SiO2含量的增加,热性能显著降低。研究表明,补强量和温度对所制备的冷激复合材料的热膨胀系数和导热系数有影响。对集成电路排气门的有限元分析表明,本研究开发的冷冻镍合金复合材料可以作为现有气门材料(镍铬合金钢)的替代材料。本研究中进行的所有测试均符合ASTM标准。
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引用次数: 3
Wood Particle-Recycled Glass Fiber Hybrid Composites 木颗粒-再生玻璃纤维复合材料
Pub Date : 2017-09-14 DOI: 10.4236/OJCM.2017.75018
K. Oluwabunmi, L. Smith, S. Shi
This study was done with the aim of assessing the feasibility of mechanically recycled glass fiber particleboards made from (loblolly pine and longleaf pine) wood particles with epoxy as binder. The modulus of rupture (MOR) and modulus of elasticity (MOE) were evaluated as indicators of mechanical performance. The water absorption rate and thickness swelling rate were also analyzed to investigate the physical performance of the board. An increase of over 80% in MOE values was obtained for the boards with 10 wt% glass fiber inclusion. For the MOR values, there was an increase of over 84.4% in both densities and glass fiber inclusions of all the board densities. However, there was a decrease in MOE when 30 wt% glass fibers were incorporated into boards with density of 500 kg/m3 and 700 kg/m3. A r-squared value of 0.869 supported the obtained result that the correlation between water absorption rate and thickness swelling rate was a function of the density of the composites.
本研究的目的是评估以环氧树脂为粘合剂的火炬松和长叶松木颗粒制成的机械回收玻璃纤维刨花板的可行性。断裂模量(MOR)和弹性模量(MOE)作为力学性能指标进行评价。通过对吸水率和厚度膨胀率的分析,考察了板材的物理性能。玻璃纤维含量为10%的板材的MOE值提高了80%以上。对于MOR值,所有板密度的密度和玻璃纤维夹杂物均增加了84.4%以上。然而,当密度为500 kg/m3和700 kg/m3的板材中加入30%的玻璃纤维时,MOE有所下降。r平方值为0.869,表明吸水率与厚度膨胀率之间的相关关系是复合材料密度的函数。
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引用次数: 0
Improvement on Adhesion Properties of Insert Injection Molding Composites: Effect of Inserted Parts, Adhesive Lengths and Injection Conditions 嵌件注塑复合材料粘接性能的改善:嵌件、粘接长度和注射条件的影响
Pub Date : 2017-07-26 DOI: 10.4236/OJCM.2017.74013
Badin Pinpathomrat, H. Hamada
The focus of this project is on the insert injection molding process, developed for merging similar or different materials by molding injected melted polymer around an inserted part and injecting in the molded cavity of the conventional injection molding machine. This method is ideal for attaching automotive parts without having to use bolts or adhesives. Glass fiber-reinforced polypropylene (GF/PP) with various adhesive lengths of 0 and 5 mm was prepared as the inserted part and injected to the mold. The effects of the inserted parts, adhesive lengths, and injection conditions on the adhesive properties were investigated. The strength of the interfacial adhesive between the insert and the injected polymer was measured by using an Intron Universal Testing machine. The effects of the material in the inserted and injected parts were analyzed. It was found that by increasing the binding area of the adhesive interface, the barrel temperature, and the mold temperature, the interfacial adhesive strength of the insert injection molded-part was improved in all tested specimens.
该项目的重点是插入注射成型工艺,该工艺旨在通过在插入部件周围成型注入的熔融聚合物并在传统注射成型机的模腔内注射来融合相似或不同的材料。这种方法非常适合在不使用螺栓或粘合剂的情况下连接汽车零件。制备具有不同粘合剂长度为0和5mm的玻璃纤维增强聚丙烯(GF/PP)作为插入部件,并将其注射到模具中。研究了插入件、粘合剂长度和注射条件对粘合剂性能的影响。插入物和注入的聚合物之间的界面粘合剂的强度通过使用Intron通用测试机来测量。分析了材料在插入件和注入件中的作用。研究发现,通过增加粘合剂界面的结合面积、筒体温度和模具温度,所有测试样品的嵌件注塑件的界面粘合强度都得到了提高。
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引用次数: 1
Computational and Experimental Analyses of Detachment Force at the Interface between Carbon Fibers and Epoxy Resin 碳纤维与环氧树脂界面分离力的计算与实验分析
Pub Date : 2017-07-26 DOI: 10.4236/OJCM.2017.74011
K. Mori, N. Matsumoto, S. Nomoto, K. Tsuruta
Herein, we used theoretical and experimental methods to investigate the shear fracture strengths of carbon fiber/epoxy resin interfaces. The shear strengths of carbon fiber and epoxy resin were measured using the microdroplet test, whereas interaction and binding energies were estimated using Ab initio and molecular dynamics methods. However, binding energies did not impact the shear strength volumes determined by microdroplet tests, i.e., bonds between functional groups of the carbon filer and the epoxy resin were difficult to break. On the other hand, the interaction energies calculated for epoxy monomers were in good agreement with experimental data. Moreover, we determined the relationship between the simulated interaction energy and the shear fracture strength volume obtained using the microdroplet test.
本文采用理论和实验方法研究了碳纤维/环氧树脂界面的剪切断裂强度。碳纤维和环氧树脂的剪切强度使用微滴测试进行测量,而相互作用和结合能使用从头算和分子动力学方法进行估计。然而,结合能并不影响通过微滴测试确定的剪切强度体积,即碳过滤器和环氧树脂的官能团之间的键难以断裂。另一方面,计算的环氧单体的相互作用能与实验数据吻合良好。此外,我们确定了模拟相互作用能与使用微滴试验获得的剪切断裂强度体积之间的关系。
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引用次数: 6
Investigation of the Flexural Properties and Failure Behavior of Unidirectional CF/Nylon 6 and CF/Epoxy Composites 单向CF/尼龙6和CF/环氧树脂复合材料的弯曲性能和失效行为研究
Pub Date : 2017-07-26 DOI: 10.4236/OJCM.2017.74016
Yan Ma, M. Ueda, T. Yokozeki, T. Sugahara, Yuqiu Yang, H. Hamada
In this work, flexural properties and failure behavior of unidirectional (UD) carbon fiber reinforced polyamide 6 (CF/Nylon 6) and epoxy resin (CF/ Epoxy) laminates were investigated through three-point bending test. The mechanical properties and failure behavior of 0 and 90 degree CF/Nylon 6 and CF/Epoxy laminates were discussed based on the fiber volume fraction, fiber distribution, void content, interfacial properties, transversal tensile strength and fracture toughness. The effects of fiber volume fraction, fiber distribution, void content and their hybrid effect on the flexural properties were investigated. Step-by-step observation and scanning electron microscope observation of laminates after flexural tests were employed to analyze the fracture process.
本工作通过三点弯曲试验研究了单向(UD)碳纤维增强聚酰胺6(CF/尼龙6)和环氧树脂(CF/环氧树脂)层压板的弯曲性能和破坏行为。从纤维体积分数、纤维分布、空隙率、界面性能、横向拉伸强度和断裂韧性等方面讨论了0度和90度CF/尼龙6和CF/环氧树脂层压板的力学性能和失效行为。研究了纤维体积分数、纤维分布、空隙率及其混杂效应对弯曲性能的影响。采用分步观察和扫描电镜观察的方法对层合板弯曲试验后的断裂过程进行了分析。
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引用次数: 15
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复合材料期刊(英文)
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