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Assessment of Exposure Due to Technologically Enhanced Natural Radioactivity in Various Samples of Moroccan Building Materials 评估摩洛哥各种建筑材料样品因技术增强的天然放射性而受到的照射
Pub Date : 2018-10-22 DOI: 10.4236/WJNST.2018.84015
Bouchaib Kassi, A. Boukhair, Khadija Azkour, M. Fahad, M. Benjelloun, A. Nourreddine
The aim of our present work is to measure the specific activities of the radionuclides 226Ra, 232Th, 40K and the exhalation rates in terms of area and mass of 222Rn in some samples of building materials commonly used in Morocco in order to evaluate the radiological risk caused by natural radioactivity. To this end, the analyses were carried out, using two nuclear techniques, namely high resolution gamma spectrometry and alpha dosimetry based on the use of LR115, on 50 samples collected from large commercial suppliers in Morocco. The results of these analyses show that the average specific activities of 226Ra, 232Th and 40K in these materials vary from 9 to 52 Bq/kg, 3 to 63 Bq/kg and 68 to 705 Bq/kg respectively. These activities remain within the permissible limits of 35 Bq/kg, 30 Bq/kg and 370 Bq/kg respectively, with the exception of a few samples of red brick, gray cement, ceramic and granite. The activity of the radium equivalent (Raeq), the internal (Hin) and external (Hex) hazard indices, the absorbed dose rate, the total annual effective dose , the excess lifetime cancer risk (ELCR) as well as volumic activities, exhalation rates in terms of area (ES) and mass (EM) are calculated for the samples analyzed in this work in order to assess the radiological risks resulting from the use of these materials in various construction activities. It seems that the values of these indices vary from 19 to 196 Bq/kg, 0.08 to 0.67, 0.05 to 0.53, 9 to 91 nGy/h, 0.05 to 0.56 mSv/y, 0.19 × 10−3 to 1.96 × 10−3, 72 to 350 Bq/m3, 56 to 273 mBq⋅m−2⋅h−1 and 3 to 15 mBq⋅kg−1⋅h−1 respectively. The lowest values are identified for gypsum, while the highest are attributed to granite. All of the obtained results of these indices respect the permissible limits except for the Raeq in some granite samples, the ELCR index in all samples except gypsum and the radon volumic activity in some gray cement samples, ceramic and granite. As a result, the different types of building materials analyzed in our work do not present a health risk to the public and can be used in various construction activities, with the exception of a few samples of red brick, gray cement, ceramic and granite. The choice of the use of red brick, gray cement and ceramic should be monitored and adapted according to the criteria of the limitation of the doses whereas the use of the granite must be moderate in order to limit over time the health risk which increases with the duration of exposure of humans to these building materials.
我们目前工作的目的是在摩洛哥常用的一些建筑材料样品中测量放射性核素226Ra、232Th、40K的具体活动以及222Rn的面积和质量的呼出率,以评估天然放射性引起的辐射风险。为此目的,对从摩洛哥大型商业供应商收集的50个样品进行了分析,使用了两种核技术,即高分辨率伽马能谱法和基于LR115的α剂量法。结果表明,226Ra、232Th和40K的平均比活度分别为9 ~ 52 Bq/kg、3 ~ 63 Bq/kg和68 ~ 705 Bq/kg。除了少数红砖、灰水泥、陶瓷和花岗岩样品外,这些活动仍分别在35、30和370 Bq/kg的允许范围内。为了评估在各种建筑活动中使用这些材料所造成的辐射风险,本文计算了所分析样品的镭当量活度(Raeq)、内部(Hin)和外部(Hex)危害指数、吸收剂量率、年总有效剂量、过量终身癌症风险(ELCR)以及体积活度、面积(ES)和质量(EM)方面的呼气率。这些指标的取值范围分别为19 ~ 196 Bq/kg、0.08 ~ 0.67、0.05 ~ 0.53、9 ~ 91 nGy/h、0.05 ~ 0.56 mSv/y、0.19 × 10−3 ~ 1.96 × 10−3、72 ~ 350 Bq/m3、56 ~ 273 mBq⋅m−2⋅h−1和3 ~ 15 mBq⋅kg−1⋅h−1。石膏的值最低,花岗岩的值最高。除部分花岗岩样品的Raeq值、石膏样品的ELCR值和部分灰水泥、陶瓷和花岗岩样品的氡体积活度外,其余指标均在允许范围内。因此,除了少数红砖、灰水泥、陶瓷和花岗岩样本外,我们在工作中分析的不同类型的建筑材料不会对公众构成健康风险,可以用于各种建筑活动。红砖、灰水泥和陶瓷的使用应根据剂量限制标准进行监测和调整,而花岗岩的使用必须适度,以便随着时间的推移限制随着人类接触这些建筑材料时间的延长而增加的健康风险。
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引用次数: 10
Reexamination of the Claim of Marinov et al. on Discovery of Element 112 重新审查Marinov等人关于第112号元素发现的主张
Pub Date : 2018-09-26 DOI: 10.4236/wjnst.2018.84013
S. R. Hashemi-Nezhad, R. Brandt, W. Westmeier
Marinov et al. have detected spontaneous fission events in sources separated from tungsten targets irradiated with 24 GeV protons. These fission events could not be attributed to actinides or to any other known isotope. Marinov et al. propose that fission events are due to production of element 112 (Eka-Hg) in the tungsten target. We have addressed Marinov’s claim with a new analysis of their data and modern theoretical model calculations of possible interactions. Using data available in the literature the spontaneous fission half-life of the Eka-Hg was estimated to be ~74 days. This is dramatically longer than the half-life obtained for 283112Cn, produced in the fusion of energetic 48Ca ions with 238U. Monte Carlo calculations show that enough Sr isotopes are produced in the tungsten target to make the production of element 112 via fusion of Sr and W feasible; however, if such fusion was possible it had to be deep sub-barrier fusion.
Marinov等人已经检测到,在24gev质子辐照的钨靶分离源中,会发生自发裂变事件。这些裂变事件不能归因于锕系元素或任何其他已知的同位素。Marinov等人提出,裂变事件是由于在钨靶中产生112元素(Eka-Hg)。我们对他们的数据进行了新的分析,并对可能的相互作用进行了现代理论模型计算,从而解决了马里诺夫的说法。利用文献资料,估计Eka-Hg的自发裂变半衰期为~74天。这比高能48Ca离子与238U聚变产生的283112Cn的半衰期要长得多。蒙特卡罗计算表明,在钨靶区产生了足够多的Sr同位素,使得通过Sr和W的聚变生产112号元素成为可能;然而,如果这种聚变是可能的,它必须是深亚势垒聚变。
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引用次数: 0
Prediction of Neutronic and Kinetic Parameters of Ghana Research Reactor 1 (GHARR-1) after 19 Years of Operation Using Monte Carlo-N Particle (MCNP) Code 用蒙特卡罗粒子(MCNP)程序预测加纳研究堆1(GHARR-1)运行19年后的电子和动力学参数
Pub Date : 2018-09-26 DOI: 10.4236/wjnst.2018.84014
B. M. Mweetwa, E. Ampomah-Amoako, E. Akaho, C. Odoi
The Ghana Research Reactor-1 (GHARR-1) core was modified with an addition of a 9.0 mm layer of beryllium to the top shim tray to compensate for reactivity loss due to fuel depletion after 19 years of operation. Neutronic and kinetic parameters have been predicted using Monte Carlo N-Particle Code version 5 (MCNP5) to determine whether they were within acceptable operating margins. Excess reactivity, control rod worth, moderator reactivity coefficient, delayed neutron fraction and neutron generation time have been predicted as 3.86, 6.98, −0.1218 mk/°C, 8.17507 × 10−3 Δk/k, and 8.147 × 10−5 s respectively. These parameters compared favorably with those provided in the initial Safety Analysis Report.
加纳研究堆1号(Ghana Research Reactor-1, GHARR-1)的堆芯经过改进,在顶部垫片托盘上增加了一层9.0毫米厚的铍,以补偿运行19年后燃料耗尽造成的反应性损失。使用蒙特卡罗n粒子代码版本5 (MCNP5)预测了中子和动力学参数,以确定它们是否在可接受的经营范围内。过量反应性、控制棒值、慢化剂反应性系数、延迟中子分数和中子生成时间分别为3.86、6.98、- 0.1218 mk/°C、8.17507 × 10−3 Δk/k和8.147 × 10−5 s。这些参数与最初的安全分析报告中提供的参数相比是有利的。
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引用次数: 1
Design and Comparative Analysis of Small Modular Reactors for Nuclear Marine Propulsion of a Ship 船用核动力小型模块化反应堆的设计与比较分析
Pub Date : 2018-07-16 DOI: 10.4236/WJNST.2018.83012
M. Hoque, A. Salauddin, Md. Reaz Hasan Khondoker
The fast growth in the size and difficulty of nuclear power plant in the 1970s produced an interest in smaller, modest designs that are intrinsically safe over the usage of design features. With the development of nuclear technology, there is the need for revolution in the Maritime sector, especially the advance marine propulsion. In current years, numerous reactor manufacturers are dynamically improving small modular reactor designs with even superior use of safety features. Several designs integrate the ultimate in greater safety. They totally remove specific accident initiators from the design. Other design features benefit to reduce different types of accident or help to mitigate the accident’s consequences. Although some safety features are mutual to maximum SMR designs, irrespective of the coolant technology, other features are specific to liquid-metal cooled, water, gas, or SMR designs. Results: There have been more reactor concepts investigated in the marine propulsion area by different assemblies and research laboratories than in the power generation field, and much can be learned from their experience for land applications. The extensive use of safety features in SMRs potential to make these power plants extremely vigorous, protecting both the public and the investor. Conclusion: For these two considerations, it is recognized that a nuclear reactor is the ideal engine for naval advanced propulsion. The paper will present the work to analyze the concept design of SMRs and design a modular vessel consisting of a propulsion module.
20世纪70年代,核电站的规模和难度的迅速增长,使人们对更小、更适度的设计产生了兴趣,这种设计本质上是安全的,而不是使用设计特征。随着核技术的发展,海事领域需要一场革命,特别是先进的船舶推进系统。近年来,许多反应堆制造商都在不断改进小型模块化反应堆设计,使其具有更高的安全性能。有几种设计结合了更高的安全性。他们完全从设计中删除了特定的事故触发因素。其他设计特点有利于减少不同类型的事故或有助于减轻事故的后果。尽管一些安全特性与最大SMR设计是相互的,但无论冷却剂技术如何,其他特性都是液态金属冷却、水、气体或SMR设计所特有的。结果:与发电领域相比,不同机构和研究实验室对船舶推进领域的反应堆概念进行了更多的研究,并且在陆地应用方面可以借鉴他们的经验。在小型反应堆中广泛使用的安全特性有可能使这些发电厂非常有活力,保护公众和投资者。结论:基于以上两点考虑,认为核反应堆是舰船先进推进的理想发动机。本文将介绍smr的概念设计分析工作,并设计一个由推进模块组成的模块化船舶。
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引用次数: 3
Effect of Temperature on I-V Characteristic for ZnO/CuO 温度对ZnO/CuO I-V特性的影响
Pub Date : 2018-07-13 DOI: 10.4236/WJNST.2018.83011
M. Dirar, Farhah Elfadel Omer, R. Abdelgani, A. S. Mohamed, A. A. Elamin, B. Ahamed, M. Ali, A. Mohamed
Research on nonmaterials has become increasingly popular because of their unique physical, chemical, optical and catalytic properties compared to their bulk counterparts. Therefore, many efforts have been made to synthesize multidimensional nanostructures for new and efficient nanodevices. Among those materials, zinc oxide (ZnO) has gained substantial attention owing to many outstanding properties. ZnO besides its wide band gap of 3.34 eV exhibits a relatively large excitons binding energy (60 meV) at room temperature which is attractive for optoelectronic applications. Likewise, cupric oxide (CuO) has a narrow band gap of 1.2 eV and a variety of chemo-physical properties that are attractive in many fields. Moreover, composite nanostructures of these two oxides (CuO/ZnO) may pave the way for various new applications. So in this thesis, eight samples of CuO/ZnO junction were synthesized and exposed to temperatures 60, 70, 80, 90, 100, 110, 120 and 130. The electrical properties of Schottky diode junctions were analyzed by I-V measurements under the influence of direct solar radiation and, lag of radiation (darkness) which shows the semi-logarithmic I-V characteristic curve of the fabricated photodiodes. Also energy band gap was estimated and the morphology and particle sizes of the as-prepared sample were determined by SEM. The SEM images of ZnO + CuO sample films were annealed at 60°C to 130°C step 10.
与大块材料相比,非材料由于其独特的物理、化学、光学和催化性能而越来越受欢迎。因此,人们已经做出了许多努力来合成用于新型高效纳米器件的多维纳米结构。在这些材料中,氧化锌(ZnO)由于其许多优异的性能而受到广泛关注。ZnO除了具有3.34eV的宽带隙外,在室温下还表现出相对较大的激子结合能(60meV),这对于光电子应用是有吸引力的。同样,氧化铜(CuO)具有1.2eV的窄带隙和在许多领域具有吸引力的各种化学物理性质。此外,这两种氧化物(CuO/ZnO)的复合纳米结构可能为各种新的应用铺平道路。因此,本文合成了8个CuO/ZnO结样品,并将其暴露在60、70、80、90、100、110、120和130的温度下。在太阳直接辐射和辐射滞后(黑暗)的影响下,通过I-V测量分析了肖特基二极管结的电学特性,这显示了所制造的光电二极管的半对数I-V特性曲线。此外,还估算了能带隙,并通过SEM确定了所制备样品的形貌和粒度。ZnO+CuO样品膜的SEM图像在60°C至130°C下退火步骤10。
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引用次数: 0
Comment on the Recent Start of a New “IUPAC-Project” 对最近启动的新“iupac项目”的评论
Pub Date : 2018-06-28 DOI: 10.4236/WJNST.2018.83010
R. Brandt, V. Ditlov, E. Firu, E. Ganssauge, M. Haiduc, R. Hashemi-Nezhad, A. Neagu, W. Westmeier
The opening of a new IUPAC-project is highly appreciated. In the year 2009, the IUPAC had published an article “Discovery of the element with atomic number 112 (IUPAC Technical Report)” [1]* which contains a section on the work of the Marinov collaboration. It appears that this section is not always in agreement with conventional standards for scientific publications. This present comment focuses on these formal questions.
我们高度赞赏iupac新项目的启动。2009年,IUPAC发表了一篇文章《原子序数为112的元素的发现(IUPAC技术报告)》b[1]*,其中有一节介绍了Marinov合作的工作。这部分似乎并不总是与科学出版物的传统标准一致。本评论集中讨论这些形式问题。
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引用次数: 1
Brownian Motion of Radioactive Particles: Derivation and Monte Carlo Test of Spatial and Temporal Distributions 放射性粒子的布朗运动:时空分布的推导和蒙特卡罗检验
Pub Date : 2018-05-19 DOI: 10.4236/WJNST.2018.82009
M. Silverman, Akrit Mudvari
Stochastic processes such as diffusion can be analyzed by means of a partial differential equation of the Fokker-Planck type (FPE), which yields a transition probability density, or by a stochastic differential equation of the Langevin type (LE), which yields the time evolution of a statistical process variable. Provided the stochastic process is continuous and certain boundary conditions are met, the two approaches yield equivalent information. However, Brownian motion of radioactively decaying particles is not a continuous process because the Brownian trajectories abruptly terminate when the particle decays. Recent analysis of the Brownian motion of decaying particles by both approaches has led to different mean-square displacements. In this paper, we demonstrate the complete equivalence of the two approaches by 1) showing quantitatively and operationally how the probability densities and statistical moments predicted by the FPE and LE relate to one another, 2) verifying that both approaches lead to identical statistical moments at all orders, and 3) confirming that the analytical solution to the FPE accurately describes the Brownian trajectories obtained by Monte Carlo simulations based on the LE. The analysis in this paper addresses both the spatial distribution of the particles (i.e. the question of displacement as a function of diffusion time) and the temporal distribution (i.e. the question of first-passage time to fixed absorbing boundaries).
扩散等随机过程可以通过福克-普朗克型偏微分方程(FPE)或朗之万型随机微分方程(LE)进行分析,前者产生跃迁概率密度,后者产生统计过程变量的时间演化。假设随机过程是连续的,并且满足一定的边界条件,这两种方法产生了等价的信息。然而,放射性衰变粒子的布朗运动不是一个连续的过程,因为当粒子衰变时,布朗轨迹突然终止。最近通过这两种方法对衰变粒子的布朗运动进行的分析导致了不同的均方位移。在本文中,我们通过以下方式证明了这两种方法的完全等价性:1)在数量上和操作上显示了FPE和LE预测的概率密度和统计矩是如何相互关联的,以及3)确认FPE的解析解准确地描述了通过基于LE的蒙特卡罗模拟获得的布朗轨迹。本文中的分析既涉及颗粒的空间分布(即位移作为扩散时间的函数的问题),也涉及时间分布(即首次通过固定吸收边界的时间问题)。
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引用次数: 3
Study on Corrosion Resistance of N36 Zirconium Alloy in LiOH Aqueous Solution N36锆合金在LiOH水溶液中的耐蚀性研究
Pub Date : 2018-03-30 DOI: 10.4236/WJNST.2018.82004
Chao Sun, Z. Yang, Z. Wu
Zr-Sn-Nb-Fe alloys are one of the important directions for continuous improvement of zirconium alloys for high burn-up fuel assemblies. The corrosion resistance of Zr-Sn-Nb-Fe alloys is closely related to the alloying element and water chemical condition. To better understand the effect of Sn on corrosion resistance of Zr-Sn-Nb-Fe alloy, the normal N36 (Zr-1Sn-1Nb-0.3Fe) and low-tin N36 (Zr-0.8Sn-1Nb-0.3Fe) alloy sheets were prepared and tested in static autoclave in both of 0.01 mol/L LiOH and 0.03 mol/L LiOH aqueous solution at 360°C and 18.6 MPa. The characteristics of the microstructure and oxide film of alloys were analyzed by TEM and SEM respectively. It was shown that that the corrosion transition of the normal N36 appears earlier and the weight gain is higher than the low-tin N36 in two corrosive mediums. The cracks paralleling to the interface of oxide/metal are formed in the fracture surface of the oxide film and the micrographs at the oxide film/substrate interface appear uneven morphology. With the increasing of corrosion gain, there are more parallel cracks in oxide film and the uneven morphology at the oxide film/substrate interface is more obvious.
Zr-Sn-Nb-Fe合金是高燃耗燃料组件用锆合金不断改进的重要方向之一。Zr-Sn-Nb-Fe合金的耐蚀性与合金元素和水化学条件密切相关。为了更好地了解Sn对Zr-Sn-Nb-Fe合金耐蚀性的影响,制备了普通N36 (Zr-1Sn-1Nb-0.3Fe)和低锡N36 (Zr-0.8Sn-1Nb-0.3Fe)合金板材,并在360℃、18.6 MPa、0.01 mol/L LiOH和0.03 mol/L LiOH水溶液中进行了静态高压釜测试。分别用透射电镜和扫描电镜分析了合金的显微组织和氧化膜特征。结果表明,在两种腐蚀介质中,正常N36的腐蚀转变出现得更早,增重量也高于低锡N36。氧化膜断裂面形成与氧化物/金属界面平行的裂纹,氧化膜/基体界面处显微形貌呈现不均匀形貌。随着腐蚀增益的增加,氧化膜中平行裂纹增多,氧化膜与基体界面处的不均匀形貌更加明显。
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引用次数: 8
Studies on Capacity Expansion of Fuel Plants for Nuclear Research Reactors 核研究堆燃料装置扩容研究
Pub Date : 2018-03-30 DOI: 10.4236/WJNST.2018.82005
M. Negro, M. Durazzo, M. A. Mesquita, E. U. Carvalho, R. N. Mesquita, D. A. Andrade
The demand for nuclear fuel for research reactors is rising worldwide. Thus, the production facilities of this kind of fuel need reliable guidance on how to augment their production in order to meet the increasing demand efficiently and safely. We proposed a specific procedure for increasing production capacity. That procedure was tested with data from a real plant, which produces plate-type fuel elements loaded with LEU U3Si2-Al fuel. The test was made by means of discrete event simulation, and the results indicated the proposed procedure is efficient in raising production capacity.
全世界对研究反应堆核燃料的需求正在上升。因此,这种燃料的生产设施需要可靠的指导,说明如何增加产量,以有效、安全地满足日益增长的需求。我们提出了提高生产能力的具体程序。该程序用一家真实工厂的数据进行了测试,该工厂生产装载LEU U3Si2 Al燃料的板式燃料元件。通过离散事件模拟的方法进行了测试,结果表明该方法在提高生产能力方面是有效的。
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引用次数: 1
Proposal of a Methodology for the Assessment of Security Levels of IoT Wireless Sensor Networks in Nuclear Environments 核环境中物联网无线传感器网络安全级别评估方法的建议
Pub Date : 2018-03-30 DOI: 10.4236/WJNST.2018.82008
M. M. Savoine, M. O. Menezes, D. A. Andrade
The use of Wireless Sensor Networks (WSN) associated with the reality of an Internet of Things (IoT) scenario in nuclear environments is a growing security concern. In this context, standards are intensified to preserve the physical integrity of these facilities considered to be highly critical due to the size of the impacts of safety accidents. This paper presents a proposal to build a methodology to evaluate the security levels of WSNs with IoT devices when used in nuclear areas. The proposal is initially based on related work to establish a more concrete initial framework and is structured in consistent steps from previous scientific studies.
无线传感器网络(WSN)的使用与核环境中物联网(IoT)场景的现实相关,是一个日益增长的安全问题。在这种情况下,加强了标准,以保护这些设施的物理完整性,这些设施因安全事故的影响而被认为是高度关键的。本文提出了一个建议,以建立一种方法来评估在核领域使用物联网设备的无线传感器网络的安全级别。该提案最初基于相关工作,以建立一个更具体的初步框架,并按照与以往科学研究一致的步骤构建。
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引用次数: 1
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