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2012 IEEE 38th Photovoltaic Specialists Conference (PVSC) PART 2最新文献

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Large area back-contact back-junction solar cells with efficiency exceeding 21% 大面积背接触背结太阳能电池,效率超过21%
Pub Date : 2013-01-01 DOI: 10.1109/pvsc-vol2.2012.6656700
G. Galbiati, V. Mihailetchi, A. Halm, L. J. Koduvelikulathu, R. Roescu, R. Kopecek, K. Peter, J. Libal
In this work high efficiency solar cells are fabricated with the use of low-cost industrially available technologies. The solar cell concept is called ZEBRA: a litho-free process in which standard 156×156 mm2 monocrystalline n-type Cz-Si are processed into high efficiency Interdigitated Back Contact (IBC) solar cells. In our first trial we obtained conversion efficiencies of more than 20% on solar cells with 239 cm2 area. With the help of a three-dimensional simulation of the device, a further improvement to more than 21.5% was demonstrated. We indentify the open-circuit voltage and the series resistance as the main losses to achieve the simulated efficiency. After an extensive optimization, targeting mainly the improvement of the fill factor, the cell results are presented in this work. The optimised solar cells show an improvement in the energy conversion efficiency of up to 21%. Furthermore, the simple metallization and the module interconnection designed for the ZEBRA cells allow for a bifacial application. Indoor and outdoor measurements on single-cell modules show an enhancement in the generated power of up to 12% at one sun front illumination conditions.
在这项工作中,高效率的太阳能电池是用低成本的工业技术制造的。太阳能电池概念被称为ZEBRA:一种无晶片工艺,其中标准156×156 mm2单晶n型Cz-Si被加工成高效率的Interdigitated Back Contact (IBC)太阳能电池。在我们的第一次试验中,我们在239平方厘米的太阳能电池上获得了超过20%的转换效率。通过对该装置的三维模拟,进一步提高了21.5%以上。我们确定了开路电压和串联电阻作为主要损耗来实现模拟效率。经过广泛的优化,主要针对填充因子的改善,在本工作中提出了细胞结果。优化后的太阳能电池的能量转换效率提高了21%。此外,为ZEBRA电池设计的简单金属化和模块互连允许双面应用。室内和室外对单电池模块的测量表明,在一个太阳正面照明条件下,产生的功率提高了12%。
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引用次数: 3
Device physics of heteroepitaxial film c-Si heterojunction solar cells 异质外延薄膜c-Si异质结太阳能电池的器件物理
Pub Date : 2013-01-01 DOI: 10.1109/pvsc-vol2.2012.6656745
S. Grover, C. Teplin, Jian V. Li, D. Bobela, J. Bornstein, P. Schroeter, S. Johnston, H. Guthrey, P. Stradins, H. Branz, D. Young
We characterize heterojunction solar cells made from single-crystal silicon films grown heteroepitaxially using hot-wire chemical vapor deposition (HWCVD). Heteroepitaxy-induced dislocations limit the cell performance, providing a unique platform to study the device physics of thin crystal Si heterojunction solar cells. Hydrogen passivation of these dislocations enables an opencircuit voltage VOC close to 580 mV. However, dislocations are partially active, even after passivation. Using standard characterization methods, we compare the performance of heteroepitaxial absorbers with homoepitaxial absorbers that are free of dislocations. Heteroepitaxial cells have a smaller diffusion length and a larger ideality factor, indicating stronger recombination, which leads to inefficient current collection and a lower VOC than homoepitaxial cells. Modeling indicates that the recombination in the inversion layer of heterojunction cells made from defective absorbers is comparable with the overall recombination in the bulk. Temperature-dependent VOC measurements point to significant recombination at the interface that is attributable to the presence of dislocations.
本文研究了利用热线化学气相沉积(HWCVD)技术在异质外延生长的单晶硅薄膜上制备的异质结太阳能电池。异质外延引起的位错限制了电池的性能,为研究薄晶硅异质结太阳能电池的器件物理提供了一个独特的平台。这些位错的氢钝化使电压VOC接近580 mV。然而,位错是部分活跃的,即使在钝化后。使用标准的表征方法,我们比较了异质外延吸收剂和无位错的同质外延吸收剂的性能。异质外延电池具有较小的扩散长度和较大的理想因子,表明重组更强,导致电流收集效率低下,VOC低于同质外延电池。模拟结果表明,由缺陷吸收剂制成的异质结电池反转层的复合与整体的复合相当。温度相关的VOC测量表明,由于位错的存在,界面上出现了显著的重组。
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引用次数: 3
New insights in the nanostructure and defect states of hydrogenated amorphous silicon obtained by annealing 退火对氢化非晶硅纳米结构和缺陷态的新认识
Pub Date : 2013-01-01 DOI: 10.1109/pvsc-vol2.2012.6656760
J. Melskens, A. Smets, M. Schouten, S. Eijt, H. Schut, M. Zeman
Temperature annealing is used as a tool to study the validity of network models for the nanostructure of hydrogenated amorphous silicon (a-Si:H) and its relation to defect states. The changes in the size of the dominant open volume deficiencies have been studied using Doppler broadening positron annihilation spectroscopy and Fourier transform infrared spectroscopy. It is shown that the dominant open volume deficiencies for as-deposited films are divacancies, which appear to agglomerate into larger open volume deficiencies up to 400 °C. Above this temperature, the largest open volume deficiencies are suggested to be released at the surface of the sample. Fourier transform photocurrent spectroscopy results indicate a dramatic increase in the density of various subgap defect state distributions during temperature annealing. In addition, at least four defect states have been identified. These findings cannot be directly explained by assuming solely dangling bonds as the dominant defects in a-Si:H. We discuss that a model based on an anisotropic disordered network with volume deficiencies does explain our findings better than the classical model based on a continuous random network with solely an isotropic distribution of coordination defects. The claim is made that next to dangling bonds not fully hydrogen-passivated vacancies are significantly contributing to the dominant defect states in a-Si:H.
利用温度退火技术研究了氢化非晶硅(a- si:H)纳米结构网络模型的有效性及其与缺陷态的关系。利用多普勒展宽正电子湮灭光谱和傅里叶变换红外光谱研究了显性开放体积缺陷的大小变化。结果表明,沉积薄膜的主要开放体积缺陷是空位,当温度达到400°C时,空位会聚集成更大的开放体积缺陷。在此温度以上,建议在样品表面释放最大的开体积缺陷。傅里叶变换光电流光谱结果表明,在温度退火过程中,各种亚隙缺陷态分布的密度急剧增加。另外,至少确定了四种缺陷状态。这些发现不能通过假设悬空键是a-Si:H的主要缺陷来直接解释。我们讨论了基于具有体积缺陷的各向异性无序网络的模型比基于仅具有各向同性配位缺陷分布的连续随机网络的经典模型更好地解释了我们的发现。在悬空键旁边,未完全氢钝化的空位是导致a-Si:H中主要缺陷态的重要原因。
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引用次数: 3
Carrier dynamics in intermediate states of InAs/GaAs quantum dots embedded in photonic cavity structure 嵌入光子腔结构中InAs/GaAs量子点中间态的载流子动力学
Pub Date : 2013-01-01 DOI: 10.1109/pvsc-vol2.2012.6656710
T. Kita, T. Maeda, Y. Harada
We have studied time-resolved intraband transition from the intermediate state to the continuum state of the conduction band in InAs/GaAs self-assembled quantum dots (QDs) embedded in a one-dimensional photonic cavity structure using a two-color photoexcitation spectroscopy. The photonic gap was tuned to enhance the excitation from the intermediate state to the conduction band, whose energy is selected to be less than the interband transition energy between the intermediate state and the quantized hole state. The photoluminescence intensity was observed to be dramatically reduced by selectively pumping carriers in the intermediate state. This effect has been analyzed by modeling detailed carrier relaxation process.
利用双色光激发光谱研究了嵌入一维光子腔结构中的InAs/GaAs自组装量子点(QDs)从中间态到连续态的时间分辨带内跃迁。对光子间隙进行调谐以增强从中间态到导带的激发,选择导带的能量小于中间态与量子化空穴态之间的带间跃迁能量。在中间态中选择性抽运载流子可显著降低光致发光强度。通过对载流子弛豫过程的详细建模,分析了这种影响。
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引用次数: 0
Investigation of Na out-diffusion and structural properties of IGS film during three-stage growth process of CIGS thin film CIGS薄膜三段式生长过程中Na向外扩散及结构特性的研究
Pub Date : 2013-01-01 DOI: 10.1109/pvsc-vol2.2012.6656715
H. Al-Thani, F. Hasoon
(In,Ga)2Se3 (IGS) thin films were deposited on Molybdenum (Mo) coated soda lime glass (Mo/SLG) substrates, using physical vapor deposition (PVD) technique, resembling only the first stage of the typical 3-stage growth process of CIGS thin film. The Mo thin films were sputtered on SLG substrates using DC planar magnetron sputtering at working gas (Ar) pressure that varies from 0.6 mT to 16 mT. The sputtering pressure of Mo thin films was varied in order to induce variations in the sputtered films' morphology and microstructure; as well as to subsequently induce variations in the rate of Na out-diffusion from SLG substrate. The IGS thin film deposition process was carried out with the same conditions of substrate temperature (Ts ∼ 400°C) and deposition rate that are required to accomplish the first stage of the complete typical 3-stage process of a CIGS thin film growth. To gain an understanding of the structural correlation between Mo and IGS films, and the effect of this correlation on Na out-diffusion process from SLG substrate. The Mo and IGS films' structures were examined by θ/2θ X-Ray Diffraction (XRD) characterization technique. Secondary-ion mass spectrometry (SIMS) was also applied to depth profile the Na, Se, and O in the IGS/Mo films. Whereas, the root-mean-square (RMS) surface roughness of both Mo and IGS films, was determined using Atomic Force Microscopy (AFM).
采用物理气相沉积(PVD)技术在钼(Mo)涂覆的钠石灰玻璃(Mo/SLG)衬底上沉积(In,Ga)2Se3 (IGS)薄膜,类似于CIGS薄膜典型的三阶段生长过程的第一阶段。在0.6 ~ 16mt的氩气压力下,采用直流平面磁控溅射技术在SLG衬底上溅射Mo薄膜。通过改变溅射压力,溅射Mo薄膜的形貌和微观结构发生了变化;以及随后诱导Na从SLG底物向外扩散速率的变化。IGS薄膜沉积过程是在衬底温度(Ts ~ 400℃)和沉积速率条件下进行的,这些条件要求完成CIGS薄膜生长完整的典型3阶段过程的第一阶段。了解Mo和IGS薄膜之间的结构相关性,以及这种相关性对Na从SLG衬底向外扩散过程的影响。采用θ/2θ x射线衍射(XRD)技术对Mo和IGS薄膜的结构进行了表征。利用二次离子质谱法(SIMS)对IGS/Mo薄膜中的Na、Se和O进行了深度分析。利用原子力显微镜(AFM)测定了Mo和IGS薄膜的均方根(RMS)表面粗糙度。
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引用次数: 0
Supply-chain dynamics of tellurium, indium and gallium within the context of PV module manufacturing costs 光伏组件制造成本背景下碲、铟和镓的供应链动态
Pub Date : 2013-01-01 DOI: 10.1109/pvsc-vol2.2013.6656796
M. Woodhouse, A. Goodrich, R. Margolis, T. James, Martin Lokanc, R. Eggert
Given the need for humankind to implement more sustainable energy choices, it is crucial for energy systems such as PV to demonstrate success both soon and over the long-term quest for meaningful deployment. To that end, both the crystalline silicon and thin-film technologies have made, and continue to make, remarkable strides toward providing solutions that are quickly becoming more competitive against the traditional sources for power generation. But, within the thin-film segment of this industry, the highest demonstrated sunlight power conversion efficiencies have thus far come from technologies containing relatively rare constituent elements. These include tellurium in cadmium telluride, and indium and/or gallium in the CIS/ CIGS and III–V families of technologies. In this paper we show that the current global supply base for these three energy-critical elements is not sufficient for enabling energy-significant levels of deployment, but also show that every one of the thin-film PV technologies that we describe has the ability to absorb an increase in the price for each constituent element(s). This ability then leads to the possibility that the supply base for each element can be augmented.
鉴于人类需要实施更可持续的能源选择,光伏等能源系统在短期和长期的有意义的部署中取得成功至关重要。为此,晶体硅和薄膜技术在提供解决方案方面取得了显著进展,并将继续取得显著进展,这些解决方案很快就会与传统的发电来源相比更具竞争力。但是,在该行业的薄膜领域,迄今为止,最高的太阳能转换效率来自于含有相对稀有成分的技术。这些包括碲化镉中的碲,以及CIS/ CIGS和III-V系列技术中的铟和/或镓。在本文中,我们表明,目前这三种能源关键要素的全球供应基础不足以实现能源重要水平的部署,但也表明,我们所描述的每一种薄膜光伏技术都有能力吸收每种构成要素价格的上涨。这一能力将导致每个元素的供应基础能够得到扩展。
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引用次数: 22
Influence of the Ga content on the optical and electrical properties of CuIn1−xGaxSe2 thin-film solar cells Ga含量对CuIn1−xGaxSe2薄膜太阳能电池光电性能的影响
Pub Date : 2013-01-01 DOI: 10.1109/pvsc-vol2.2012.6656798
Zhenhao Zhang, W. Witte, O. Kiowski, U. Lemmer, M. Powalla, Hendrik Holscher
Thin-film solar cells that are based on Cu(In,Ga)Se2 (CIGS) absorbers with Ga/(Ga+In)-ratios from 0 to 1 are fabricated, and their optical and electrical properties are investigated by macroscopic (current density-voltage, external quantum efficiency) and microscopic (Kelvin probe force microscopy on untreated cross sections of solar cells) measurements. Combining all results, the diffusion voltages of individual solar cells are deduced and compared with the directly measured open-circuit voltages. An increasing splitoff between the diffusion voltage and the opencircuit voltage is observed forGa addition,which indicates a higher recombination rate of photogenerated charge carriers in solar cells with higher Ga content.
制备了Ga/(Ga+In)比为0 ~ 1的Cu(In,Ga)Se2 (CIGS)吸收体薄膜太阳能电池,并通过宏观(电流密度-电压、外量子效率)和微观(开尔文探针力显微镜在未经处理的太阳能电池截面上)测量研究了其光学和电学性能。结合所有结果,推导出单个太阳能电池的扩散电压,并与直接测量的开路电压进行了比较。添加Ga时,扩散电压和开环电压之间的分裂增大,表明在Ga含量高的太阳能电池中,光生载流子的复合率更高。
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引用次数: 3
Electric arc-flash energy calculations for photovoltaic systems 光伏系统电弧闪光能量计算
Pub Date : 2013-01-01 DOI: 10.1109/pvsc-vol2.2013.6656698
J. Yuventi
Photovoltaic systems have increased in both the quantity of installations and the size of installations over the past decade. As more utility-run systems are being constructed, it is important to consider the safety of operators and maintenance crew during the design and analyses phases. Unfortunately, one potential safety hazard, the electrical arc-flash, is not well understood for photovoltaic systems. The thermal energy released by this hazard can be significant, especially in large photovoltaic systems operating at high voltages and currents. This paper examines the conditions surrounding electric arc-flashes in photovoltaic systems based on typical designs. Using existing models for DC arc-flashes and basic circuit theory, equations and analysis techniques are developed to estimate the thermal energy that can be released if these hazards were to occur. These techniques can be used to determine the hazard-risk-category for the system components most at risk, until more empirical models are developed.
在过去的十年里,光伏系统的安装数量和安装规模都有所增加。随着越来越多的公用事业系统的建设,在设计和分析阶段考虑操作人员和维护人员的安全是很重要的。不幸的是,一个潜在的安全隐患,电弧闪光,并没有很好地了解光伏系统。这种危险释放的热能可能是显著的,特别是在高电压和高电流下运行的大型光伏系统。本文以典型设计为基础,研究了光伏系统中电弧闪蒸的环境条件。利用现有的直流电弧闪光模型和基本电路理论,开发了方程和分析技术来估计这些危害发生时可能释放的热能。这些技术可用于确定风险最大的系统组件的风险类别,直到开发出更多的经验模型。
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引用次数: 4
Thermal study of inverter components 逆变器元件的热研究
Pub Date : 2013-01-01 DOI: 10.1109/pvsc-vol2.2013.6656783
N. R. Sorensen, E. Thomas, M. Quintana, S. Barkaszi, A. Rosenthal, Zhen Zhang, S. Kurtz
Thermal histories of inverter components were collected from operating inverters from several manufacturers and three locations. The data were analyzed to determine thermal profiles, the dependence on local conditions, and to assess the effect on inverter reliability. Inverter temperatures were shown to increase with the power dissipation of the inverters, follow diurnal and annual cycles, and have a dependence on wind speed. An accumulated damage model was applied to the temperature profiles and an example of using these data to predict reliability was explored.
从几个制造商和三个地点的运行逆变器中收集了逆变器组件的热历史。对数据进行分析,以确定热分布,对当地条件的依赖,并评估对逆变器可靠性的影响。逆变器温度随逆变器功耗的增加而增加,遵循日周期和年周期,并依赖于风速。将累积损伤模型应用于温度曲线,并探讨了利用这些数据进行可靠性预测的实例。
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引用次数: 4
Designing photonic materials for effective bandgap modification and optical concentration in photovoltaics 设计光子材料用于有效的带隙修正和光电聚光
Pub Date : 2013-01-01 DOI: 10.1109/pvsc-vol2.2013.6656764
J. Munday
The limiting efficiency for photovoltaic energy conversion based on a semiconductor pn-junction is typically determined using the method of detailed balance put forth by Shockley and Queisser. Here we describe how this theory is altered in the presence of a photonic structure that is capable of modifying the absorption and emission of photons. By incorporating specifically designed photonic structures, higher maximum efficiencies can be achieved for low bandgap materials by restricting the absorption and emission of above bandgap photons. Similarly, restriction of the emission angle leads to increased optical concentration. We consider how both of these effects are modified in the presence of a non-ideal photonic structure.
基于半导体pn结的光伏能量转换的极限效率通常采用Shockley和Queisser提出的详细平衡法来确定。在这里,我们描述了这个理论是如何在能够改变光子的吸收和发射的光子结构的存在下被改变的。通过结合特殊设计的光子结构,通过限制带隙以上光子的吸收和发射,可以在低带隙材料中实现更高的最大效率。同样,限制发射角导致光浓度增加。我们考虑了在非理想光子结构存在下这两种效应是如何被修正的。
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引用次数: 0
期刊
2012 IEEE 38th Photovoltaic Specialists Conference (PVSC) PART 2
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