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2010 35th IEEE Photovoltaic Specialists Conference最新文献

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Excellent rear side passivation on multi-crystalline silicon solar cells with 20 nm uncapped Al2O3 layer: Industrialization of ALD for solar cell applications 20 nm无封顶Al2O3层多晶硅太阳能电池的优异后侧钝化:太阳能电池应用ALD的产业化
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614176
I. Cesar, E. Granneman, P. Vermont, E. Tois, P. Manshanden, L. J. Geerligs, E. Bende, A. Burgers, A. Mewe, Y. Komatsu, A. Weeber
Current bottlenecks for industrialization of Al2O3 deposited by Atomic Layer Deposition (ALD) for crystalline silicon solar cell applications are low growth rate and stability of thin and uncapped layers during co-firing. First results on the performance of a high throughput ALD proto-type, the Levitrack, are presented. Excellent passivation properties have been obtained after firing, for 12 nm thick films deposited on p-Cz (2.3 Ω.cm) with Seff <15cm/s (Δn=3×1015 cm−3). These layers are compatible with solar cells that operate at a maximum open-circuit voltage of 720mV. Furthermore, we report on the passivation of 20nm uncapped aluminum oxide layers on the rear of p-type mc-Si bifacial cells. LBIC measurements unveiled excellent passivation properties on areas covered by 20nm of Al2O3 characterized by an IQE of 91% at 980nm. Remarkably, these lifetime and cell results were obtained without lengthy post-treatments like forming gas anneal.
目前,原子层沉积法(ALD)制备用于晶体硅太阳能电池的Al2O3产业化的瓶颈是共烧过程中低生长速率和无帽薄层的稳定性。介绍了高通量ALD原型Levitrack性能的第一个结果。在p-Cz (2.3 Ω.cm)表面沉积12 nm厚的膜,当Seff <15cm/s (Δn=3×1015 cm−3)时,得到了良好的钝化性能。这些层与最大开路电压为720mV的太阳能电池兼容。此外,我们报道了在p型mc-Si双面电池背面20nm无盖氧化铝层的钝化。LBIC测量揭示了20nm Al2O3覆盖区域的优异钝化性能,在980nm处的IQE为91%。值得注意的是,这些寿命和细胞结果没有经过漫长的后处理,如形成气体退火。
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引用次数: 10
Enhanced angular response of power conversion efficiency for silicon solar cells utilizing a uniformly distributed nano-whisker medium 利用均匀分布的纳米晶须介质增强硅太阳能电池功率转换效率的角响应
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614544
C. Chang, M. Hsu, W. Chang, W. Sun, C. W. Wu, P. Yu
In the research of photovoltaic devices, eliminating Fresnel reflection loss is a critical issue on the way to pursue higher efficiency. To maximize the power conversion efficiency, dielectric antireflective coating shows a cost-effective approach, but not enough to absorb broadband solar radiation effectively. Recently, the functional nanostructure shows high potential to be an omnidirectional antireflective coating for the photovoltaic devices. Here we demonstrate Indium-Tin-Oxide (ITO) nano-whiskers, grown by the self-catalyst vapor-liquid-solid (VLS) mechanisms on the textured Si substrate. The ITO nano-whiskers can provide broadband anti-reflective properties (R<5%) in the wavelength range of 350–1100nm. In comparison with conventional Si solar cell, the ITO nano-whiskers coating solar cell shows higher external quantum efficiency (EQE) in the range of 700–1100nm. Moreover, the ITO nano-whisker coating Si solar cell shows a high total efficiency increase of 1.1% (from 16.08% to17.18%). The angular response of the conversion efficiency also increases from 7% at the normal incidence to more than 15% for incident angles over 70°.
在光伏器件的研究中,消除菲涅耳反射损耗是追求更高效率的关键问题。为了最大限度地提高功率转换效率,介质抗反射涂层显示了一种经济有效的方法,但不足以有效吸收宽带太阳辐射。近年来,该功能纳米结构在光伏器件的全向抗反射涂层方面显示出很大的潜力。在这里,我们展示了铟锡氧化物(ITO)纳米晶须,通过自催化气-液-固(VLS)机制在织构的Si衬底上生长。ITO纳米晶须在350 ~ 1100nm波长范围内具有宽带抗反射性能(R<5%)。与传统硅太阳电池相比,ITO纳米晶须涂层太阳电池在700 ~ 1100nm范围内表现出更高的外量子效率(EQE)。此外,ITO纳米晶须涂层硅太阳电池的总效率提高了1.1%(从16.08%提高到17.18%)。当入射角大于70°时,转换效率的角响应也从正入射时的7%增加到15%以上。
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引用次数: 3
n-type silicon solar cells with amorphous/crystalline silicon heterojunction rear emitter 具有非晶/晶体硅异质结后发射极的n型硅太阳能电池
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614252
M. Bivour, C. Meinhardt, D. Pysch, C. Reichel, Kurt-Ulrich Ritzau, M. Hermle, S. Glunz
We present the first silicon solar cells processed at Fraunhofer ISE featuring an amorphous/crystalline silicon heterojunction rear emitter and a diffused front surface field. In this work, we focus on the optimization of the silicon heterojunction rear emitter of n-type silicon solar cells with regards to the intrinsic hydrogenated amorphous silicon a-Si:H(i) and boron-doped hydrogenated amorphous silicon a-Si:H(p) layer thickness and the influence of a transparent conducting oxide layer on the rear emitter surface. Efficiencies up to 19.1 % (Voc = 687 mV, Jsc = 34.9 mA/cm2, FF = 79.9%) have been reached for non-textured solar cells on n-type absorbers. Furthermore, we attained an efficiency of 19.8% on textured p-type absorbers featuring an amorphous/crystalline silicon heterojunction rear emitter.
我们展示了第一个在弗劳恩霍夫ISE加工的硅太阳能电池,具有非晶/晶体硅异质结后发射极和扩散前表面场。本文主要针对n型硅太阳电池的硅异质结后发射极的本构氢化非晶硅a- si:H(i)和掺硼氢化非晶硅a- si:H(p)层厚度以及透明导电氧化层对后发射极表面的影响进行优化。在n型吸收器上,无纹理太阳能电池的效率高达19.1% (Voc = 687 mV, Jsc = 34.9 mA/cm2, FF = 79.9%)。此外,我们在具有非晶/晶体硅异质结后发射极的纹理p型吸收器上获得了19.8%的效率。
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引用次数: 18
Photothermal characterrization by atomic force microscopy around grain boundary in multicrystalline silicon material 多晶硅材料晶界周围原子力显微镜光热表征
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614390
K. Hara, Takuji Takahashi
Nonradiative recombination of photocarriers around grain boundaries is important property in multicrystalline silicon material, and has been investigated through local photothermal (PT) measurements by atomic force microscopy. We found that the PT signal was apparently enhanced near the grain boundary, which is probably due to fast nonradiative recombination at the boundary. In addition, relationship between the dependence of PT signal on incident photon energy and the minority carrier diffusion length is discussed.
晶界附近光载流子的非辐射复合是多晶硅材料的重要特性,并通过原子力显微镜的局部光热测量对其进行了研究。发现晶界附近PT信号明显增强,这可能与晶界处快速的非辐射复合有关。此外,还讨论了PT信号对入射光子能量的依赖与少数载流子扩散长度之间的关系。
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引用次数: 0
Development of advanced space solar cells at Spectrolab Spectrolab先进太空太阳能电池的开发
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614522
J. Boisvert, D. Law, R. King, D. Bhusari, X. Liu, A. Zakaria, W. Hong, S. Mesropian, D. Larrabee, R. Woo, A. Boca, K. Edmondson, D. Krut, D. Peterson, K. Rouhani, B. Benedikt, N. Karam
High efficiency multi-junction solar cells utilizing inverted metamorphic1,2 and semiconductor bonding technology3 are being developed at Spectrolab for use in one-sun space and near-space applications. Recently that effort has been extended to include low-concentration space applications. This paper will review the present state-of-the-art cell technologies at Spectrolab, with an emphasis on performance characterization data at both 1-sun and low-concentration operating conditions that these cells will experience in flight‥ A cell coupon utilizing IMM solar cells has been assembled and subjected to thermal cycling. Pre-and post thermal cycling data have been collected and there is no performance degradation or mechanical issues after the test.
Spectrolab正在开发利用倒变质和半导体键合技术的高效多结太阳能电池,用于单太阳空间和近空间应用。最近,这一努力已扩大到包括低浓度空间应用。本文将回顾Spectrolab目前最先进的电池技术,重点介绍这些电池在飞行中将经历的1太阳和低浓度操作条件下的性能表征数据。利用IMM太阳能电池的电池组合已经组装并进行了热循环。收集了热循环前后的数据,测试后没有出现性能下降或机械问题。
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引用次数: 27
Comparison of photovoltaic module performance at Pu'u Wa'a Wa'a 光伏组件在普乌瓦阿瓦阿的性能比较
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5617104
S. Busquet, J. Torres, M. Dubarry, M. Ewan, B. Liaw, L. Cutshaw, R. Rocheleau
Hawaii is experiencing a substantial increase in grid-tied PV installations and utility companies are concerned with the resulting grid management issues. To address these concerns and to enable the utilities to make informed decisions, the Hawaii Natural Energy Institute (HNEI) of the University of Hawaii initiated a PV test program that provides high-resolution data to characterize module and array performance under a variety of local climatic conditions. In the first phase of the project HNEI developed a PV test bed located at Pu'u Wa'a Wa'a ranch on the Kona coast of the Big Island of Hawaii. Initially we selected seven different PV technologies for testing consisting of poly-crystalline, mono-crystalline, amorphous, and mixed technologies. The test modules comprise 200 W units, tilted at 20°, with maximum power point trackers, via small inverters connected to the grid or via charge controllers connected to a battery and load bank. The data is sampled at 1 Hz and stored in a database for visualization and analysis. This paper presents a description of the test bed design, the high data rate Data Acquisition System (DAS), and initial experimental results.
夏威夷正在经历并网光伏装置的大幅增加,公用事业公司正在关注由此产生的电网管理问题。为了解决这些问题,并使公用事业公司能够做出明智的决定,夏威夷大学的夏威夷自然能源研究所(HNEI)发起了一个光伏测试项目,该项目提供高分辨率数据,以表征模块和阵列在各种当地气候条件下的性能。在项目的第一阶段,HNEI在夏威夷大岛科纳海岸的Pu'u Wa'a Wa'a牧场开发了一个光伏试验台。最初,我们选择了七种不同的光伏技术进行测试,包括多晶、单晶、非晶和混合技术。测试模块包括200w的单元,倾斜20°,最大功率点跟踪器,通过连接到电网的小型逆变器或通过连接到电池和负载组的充电控制器。数据以1hz采样并存储在数据库中以进行可视化和分析。本文介绍了试验台的设计、高数据速率数据采集系统(DAS)以及初步实验结果。
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引用次数: 1
Recent R&D topics on concentrator multi-junction solar cells and materials under innovative solar cells's project 创新太阳能电池项目下聚光器多结太阳能电池及材料的最新研发课题
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614172
M. Yamaguchi, Hidetoshi Suzuki, Y. Ohshita, N. Kojima, T. Takamoto
III–V compound multi-junction solar cells have great potential for space and terrestrial applications because they have high efficiency potential of more than 50% and superior radiation-resistance. We have been studying concentrator multi-junction solar cells under Japanese Innovative Photovoltaic R&D program started since FY2008. This paper presents our new achievements in super high-efficiency multi-junction and concentrator solar cells. We have obtained promising results: 1) 35.8% efficiency InGaP/GaAs/InGaAs 3-junction cells, 2) high quality (In)GaAsN material with higher mobility by chemical beam epitaxy compared to those grown by the other growth methods.
III-V型复合多结太阳能电池具有50%以上的高效能和优异的抗辐射性能,在空间和地面应用方面具有很大的潜力。自2008财年以来,我们一直在日本创新光伏研发项目下研究聚光器多结太阳能电池。本文介绍了我们在超高效多结聚光太阳能电池方面取得的新成果。我们获得了令人满意的结果:1)效率为35.8%的InGaP/GaAs/InGaAs 3结电池,2)与其他生长方法相比,化学束外延生长出了具有更高迁移率的高质量(In)GaAsN材料。
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引用次数: 4
Photographic distinction of defects in polycrystalline Si by spectroscopic electroluminescence 多晶硅缺陷的光谱电致发光照相鉴别
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614381
T. Fuyuki, A. Tani, Sinichiro Tsujii, E. Sugimura
By using spectroscopic EL imaging technique, the intrinsic defects and the extrinsic deficiencies can be distinguished clearly at a glance. The intrinsic defects with deep traps induce infra-red emission depending on the electronic trap level. By comparing the filtered images, extrinsic defects which may cause serious effect on long term reliability can be detected photographically.
利用光谱电致发光成像技术,可以一目了然地分辨出材料的内在缺陷和外在缺陷。具有深阱的本征缺陷诱导红外发射取决于电子阱能级。通过对比滤波后的图像,可以检测出可能对长期可靠性造成严重影响的外部缺陷。
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引用次数: 4
Fundamental studies on the front contact formation resulting in a 21% efficiency silicon solar cell with printed rear and front contacts 前触点形成的基础研究导致了具有印刷前后触点的21%效率硅太阳能电池
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5616892
M. Hörteis, J. Benick, J. Nekarda, A. Richter, R. Preu, S. Glunz
The contact formation on high efficiency solar cells using a high temperature process is the subject of this research. The chemical reactions between ink components and solar cell during the contact firing process are studied in detail by thermal gravimetric - differential thermo analysis. The mechanism behind the etching process and the opening of the dielectric layer are explained and the impact of the glass frit is investigated. Based on these studies, a seed layer ink was developed, optimized and tested on silicon solar cells. The developed ink was applied on high efficiency solar cells with printed front and rear contacts. At the rear side, we used a firing stable passivation layer consisting of Al2O3 and SiNx, which additionally resists the reactive compounds of the screen printed Al-paste. After applying laser fired contacts at the rear and light induced silver plating at the front, cell efficiencies of η = 21% and fill factors of 81% could be measured.
利用高温工艺研究高效太阳能电池的接触形成问题。采用热重差热分析法详细研究了油墨组分与太阳能电池在接触烧制过程中的化学反应。解释了刻蚀过程和介电层打开的机理,并研究了玻璃熔块的影响。在此基础上,开发了一种种子层油墨,对其进行了优化,并在硅太阳能电池上进行了测试。所开发的墨水被应用于具有印刷前后触点的高效太阳能电池上。在背面,我们使用了由Al2O3和SiNx组成的烧成稳定钝化层,该钝化层还可以抵抗丝网印刷Al-paste的活性化合物。在电池后部采用激光触点,在电池前部采用光诱导镀银后,电池效率η = 21%,填充系数为81%。
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引用次数: 15
Fabrication of PECVD grown n-i-p silicon nanowire solar cells PECVD生长n-i-p硅纳米线太阳能电池的制备
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5616926
M. Adachi, K. Karim
Silicon nanowires have been shown to have strong light trapping properties making them a promising photovoltaic material. In this study, silicon nanowires, grown by RF plasma enhanced chemical vapor deposition (PECVD), are incorporated as the absorbing layer in n-i-p solar cells. Silicon nanowires are fabricated at a temperature of 375 °C by Vapor Liquid Solid (VLS) method. Nanowire solar cells have an average specular reflectance of 6.3% as compared to 22.6% for the thin film amorphous silicon (a-Si) device (over λ = 350 nm − 750 nm). Similarly the average diffuse reflectance of the nanowire devices is 4.9% as compared to 9.4% for the thin film a-Si device. External quantum efficiency measurements indicate the largest contributor to collection efficiency losses is from the catalyst impurity used for nanowire growth.
硅纳米线具有很强的光捕获特性,使其成为一种很有前途的光伏材料。在这项研究中,采用射频等离子体增强化学气相沉积(PECVD)生长的硅纳米线作为吸收层加入到n-i-p太阳能电池中。采用气-液-固(VLS)法制备了温度为375℃的硅纳米线。纳米线太阳能电池的平均镜面反射率为6.3%,而薄膜非晶硅(a-Si)器件的平均镜面反射率为22.6% (λ = 350 nm ~ 750 nm)。同样,纳米线器件的平均漫反射系数为4.9%,而薄膜a-Si器件的平均漫反射系数为9.4%。外部量子效率测量表明,收集效率损失的最大贡献者是用于纳米线生长的催化剂杂质。
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引用次数: 5
期刊
2010 35th IEEE Photovoltaic Specialists Conference
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