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2010 35th IEEE Photovoltaic Specialists Conference最新文献

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Impact of metal contamination in multicrystalline silicon solar cells: Case study for iron 多晶硅太阳能电池中金属污染的影响:铁的案例研究
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5617208
G. Coletti
The impact on solar cell performance of iron has been investigated. Iron has been intentionally added to silicon feedstock used to grow p-type directionally solidified multicrystalline silicon ingots. A state of the art screen print solar cell process has been applied to wafers from the bottom to top of the ingot. Adding 50 ppmwt of iron to silicon feedstock, results in comparable solar cell performances to reference uncontaminated material, in the range 40 to 70% of the ingot height. Iron causes a reduction in the diffusion length, which decreases with the ingot height.
研究了铁对太阳能电池性能的影响。铁被有意添加到硅原料中,用于生长p型定向凝固多晶硅锭。一种最先进的丝网印刷太阳能电池工艺已应用于晶圆从底部到顶部的铸锭。在硅原料中添加50 ppmwt的铁,结果与参考未污染材料的太阳能电池性能相当,在铸锭高度的40到70%的范围内。铁使扩散长度减小,扩散长度随钢锭高度的增加而减小。
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引用次数: 2
Thermal oxide, Al2O3 and amorphous-Si passivation layers on silicon 硅表面的热氧化物、Al2O3和非晶硅钝化层
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5615938
W. Ho, Y.-Y. Chen, T.-H. Cheng, Jyun-Yan Chen, J.-A. Lu, P. Huang, C. W. Liu
The effective passivation needs (1) higher bandgap than Si with type 1 alignment, (2) low interface density at the interface between passivation layer and Si, and (3) ionized charges for field effect passivation. The thermal oxide (SiO2) with low interface defect density seems most effective but requires high growth temperature (900 °C). Al2O3 with trapped negative fixed charges can serve as the field effect passivation. Moreover, doped amorphous Si can also have the field effect passivation with the controlled ionized charge density. The effective life time is measured by quasi-steady-state photoconductance (QSSPC). Photoluminescence (PL) measurement is consistent with QSSPC, and can probe a local area with mapping ability on large samples. The dependence of PL intensity on surface recombination velocity is theoretically studied. The passivation of a-Si becomes less effective after crystallization at high temperature annealing, indicating the larger bandgap is necessary.
有效钝化需要(1)具有比Si更高的带隙(1型排列),(2)钝化层与Si界面处的界面密度低,(3)场效应钝化需要电离电荷。具有低界面缺陷密度的热氧化物(SiO2)似乎是最有效的,但需要较高的生长温度(900℃)。带固定负电荷的Al2O3可以起到场效应钝化作用。此外,在控制电离电荷密度的情况下,掺杂的非晶硅还可以发生场效应钝化。利用准稳态光电导(QSSPC)测量了有效寿命。光致发光(PL)测量与QSSPC一致,在大样本上可以探测局部区域,具有制图能力。从理论上研究了PL强度与表面复合速度的关系。在高温退火结晶后,a-Si的钝化效果变差,表明需要较大的带隙。
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引用次数: 2
Interaction between post wire saw cleaning and the subsequent cell fabrication saw damage etch and texturing process 线锯清洗后的相互作用和随后的电池制造,锯损伤,蚀刻和变形过程
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614741
G. Allardyce, R. Barr, R. Chan, M. Moynihan, C. O'connor, T. Ridler
Post wire saw wafers presented for cleaning are heavily contaminated with cutting fluid slurry, silicon kerf, trace metallic species and oxides. There is no industry standard process or equipment set for this operation with various options utilised by the wafer manufacturer. However a common theme is the use of chemical cleaners to facilitate removal of the debris and contaminants. This paper describes studies conducted to determine potential effects of differing cleaner chemistry types on subsequent cell fabrication. By characterisation of contact angle, topography, etch depth and reflectance it is shown that certain cleaner types can have a profound and potentially adverse effect on the texture process and pyramid generation. Potential mechanisms are discussed and additional studies demonstrating that such adverse effects can be rectified are described.
送去清洗的后线锯片被切削液浆液、硅屑、微量金属物质和氧化物严重污染。目前还没有行业标准的流程或设备来进行此操作,晶圆制造商可以使用各种选项。然而,一个共同的主题是使用化学清洁剂,以方便清除碎片和污染物。本文描述了为确定不同清洁化学类型对后续细胞制造的潜在影响而进行的研究。通过对接触角、形貌、蚀刻深度和反射率的表征表明,某些类型的清洗剂可能对结构过程和金字塔的产生产生深远的潜在不利影响。讨论了潜在的机制,并描述了证明这种不利影响可以纠正的其他研究。
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引用次数: 6
Large-are organic solar cells with metal sub-electrode on ito anode 大型有机太阳能电池与金属亚电极在ito阳极
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5616917
Jaewook Kang, Sun-Young Park, Do‐Geun Kim, Jongk‐Kuk Kim
This paper described the effects of the electrode geometry combined with the cell area on the device performance fabricated by spray-coating method. We investigated the effects of cell size in organic solar cells (OSCs) by introducing of metal sub-electrodes to clearly define the geometry of the cell and realizing large-area cells up to 4.08 cm2. It is demonstrated that the series resistance could be reduced significantly by inserting metal sub-electrodes onto the ITO anode, yielding a power conversion efficiency (PCE) of 2.6±0.3 % up to the cell area of 4.08 cm2. This suggests that OSCs with sub-electrode geometry can be used for evaluating new materials and processes with accurate measurements on the centimeter scale.
本文描述了电极几何形状和电池面积对喷涂法制备器件性能的影响。我们研究了电池尺寸对有机太阳能电池(OSCs)的影响,通过引入金属亚电极来明确定义电池的几何形状,并实现了高达4.08 cm2的大面积电池。结果表明,通过在ITO阳极上插入金属亚电极,串联电阻可以显著降低,功率转换效率(PCE)为2.6±0.3%,电池面积为4.08 cm2。这表明,具有亚电极几何形状的osc可以用于评估新材料和工艺,并在厘米尺度上进行精确测量。
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引用次数: 0
Chemical bath deposition (CBD) of iron sulfide thin films for photovoltaic applications, crystallographic and optical properties 化学浴沉积(CBD)用于光伏应用的硫化铁薄膜,晶体学和光学性质
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614465
P. Prabukanthan, R. J. Soukup, N. Ianno, A. Sarkar, Š. Kment, H. Kmentová, C. Kamler, C. Exstrom, J. Olejníček, S. Darveau
A low temperature chemical deposition method has been developed to deposit iron/sulfur thin films onto soda lime glass substrates. The chemical bath deposition (CBD) consists of aqueous solution ferrous sulphate, disodium salt of ethylenediaminetetra-acetic acid (Na2EDTA), sodium thiosulphate and organic solutions of ethylenediamine and methanol. The experiments were performed at room temperature and under two different conditions. The films were uniform and adhered well to the soda lime glass substrates. The deposited films were additionally processed in a sulfur and nitrogen atmosphere at a variety of different temperatures to form the pyrite phase of FeS2. The as-deposited and annealed thin films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), optical absorption, auger electron spectroscopy (AES), and resistivity. The optimization of the FeS2 pyrite growth parameters was determined using XRD. Although both methods appeared to form FeS2 the second method is the preferable one where additional sulfurization at 450 °C for one hour yielded the films with the maximum crystalline order and stoichiometry.
研究了一种低温化学沉积法在碱石灰玻璃衬底上沉积铁/硫薄膜。化学浴沉积(CBD)由硫酸亚铁水溶液、乙二胺四乙酸二钠盐(Na2EDTA)、硫代硫酸钠以及乙二胺和甲醇的有机溶液组成。实验在室温和两种不同的条件下进行。薄膜均匀,与碱石灰玻璃基板粘附良好。将沉积的薄膜在不同温度的硫氮气氛中进行处理,形成FeS2的黄铁矿相。采用x射线衍射(XRD)、扫描电子显微镜(SEM)、光吸收、俄歇电子能谱(AES)和电阻率对沉积和退火后的薄膜进行了表征。采用XRD对FeS2黄铁矿生长参数进行了优化。虽然这两种方法似乎都形成了FeS2,但第二种方法是较好的,在450°C下额外硫化一小时,产生了具有最大结晶顺序和化学计量的薄膜。
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引用次数: 16
Traps in AlGaInP materials and devices lattice matched to GaAs for multi-junction solar cells 多结太阳能电池中与砷化镓晶格匹配的AlGaInP材料和器件中的陷阱
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5616430
A. Arehart, M. Brenner, Z. Zhang, K. Swaminathan, S. Ringel
Deep levels in solid-source MBE-grown n- and p-type (Al0.09Ga0.91)0.51In0.49P are investigated using deep level transient spectroscopy (DLTS). These results are correlated with background oxygen impurities measured by secondary ion mass spectroscopy and electrical properties using Hall effect. Oxygen impurity concentration is found to depend weakly on substrate offcut conditions in MBE-grown AlGaInP films. This is used to investigate the role of oxygen on deep levels in the n- and p-type samples using (100) GaAs substrates with three different substrate offcut conditions (A, B, and C). The DLTS of n-type AlGaInP reveals deep levels at EC-0.22, EC-0.31, EC-0.69 eV and EC-1.0 eV. The EC-0.69 eV concentration tracked oxygen incorporation while the other levels decreased while the oxygen incorporation increased indicating possible secondary offcut effects. In general, we find a direct correlation between reduced carrier compensation, increased carrier mobility, lower trap concentration and lower oxygen content as a function of systematic changes in substrate offcut conditions.
利用深能级瞬态光谱(DLTS)研究了n型和p型(Al0.09Ga0.91)0.51In0.49P型固体源mbe的深能级。这些结果与二次离子质谱法测量的本底氧杂质和霍尔效应的电学性质有关。在mbe生长的AlGaInP薄膜中,氧杂质浓度对底物边缘条件的依赖性较弱。使用(100)GaAs衬底,采用三种不同的衬底切割条件(A、B和C),研究了氧在n型和p型样品中深层水平的作用。n型AlGaInP的DLTS显示深层水平为EC-0.22、EC-0.31、EC-0.69 eV和EC-1.0 eV。EC-0.69 eV浓度跟踪氧掺入,而其他水平随氧掺入的增加而降低,表明可能存在二次附带效应。总的来说,我们发现载流子补偿的减少、载流子迁移率的增加、陷阱浓度的降低和氧含量的降低作为底物边缘条件系统变化的函数之间存在直接关联。
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引用次数: 13
Power output variability of PV system fleets in three utility service territories in New Jersey and California 新泽西州和加利福尼亚州三个公用事业服务区域的光伏系统机组输出功率变异性
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5616824
A. Golnas, S. Voss
The recent growth of the number and cumulative size of PV installations in regions with solar-friendly programs has raised the profile of those systems' potential impact on the electric grid. As grid-tied PV systems are a variable resource, it is important to characterize the variability of their output when aggregated over fleets within a service territory. SunEdison operates more than 300 systems ranging from 30 to 9,000 kWp across North America and monitors the power output of each one with a 1-minute resolution. We present an analysis of the observed power output variability of 67 PV systems across 3 utility service territories in California and New Jersey, during days of variable solar resource. One of the metrics is the standard deviation of the power output's change over 1-minute intervals across 4 hours near the solar peak. By aggregating power output over fleets of constant rated capacity but different make up, we show that variability is affected by both mean system size and fleet composition.
最近,在实施太阳能友好型项目的地区,光伏装置的数量和累计规模的增长,提高了这些系统对电网的潜在影响。由于并网光伏系统是一种可变资源,因此,在一个服务区域内,对其输出的可变性进行表征是很重要的。SunEdison在北美运营着300多个系统,从30到9000千瓦时不等,并以1分钟的分辨率监控每个系统的功率输出。本文分析了加州和新泽西州3个公用事业服务区域的67个光伏系统在太阳能资源变化期间的输出功率变化。其中一个指标是在太阳峰值附近的4小时内,每隔1分钟输出功率变化的标准偏差。通过汇总额定容量不变但组成不同的车队的输出功率,我们表明可变性受到平均系统大小和车队组成的影响。
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引用次数: 11
The effect of uncertainty in modeling coefficients used to predict energy production using the Sandia Array Performance Model 利用桑迪亚阵列性能模型预测能源产量时,建模系数不确定性的影响
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5616871
L. Pratt, D. King
Predicting photovoltaic array performance is an important part of system design and monitoring, so it's important to quantify the uncertainty associated with the predictions. The Sandia Array Performance Model [1] is one of many tools used to predict annual energy production, but the effect of the uncertainty in model coefficients has not been fully investigated. This paper quantifies the relative importance of voltage and current temperature coefficients, as well as the coefficients relating voltage and current to solar irradiance, for crystalline silicon modules. Using the coefficient variation observed in the Sandia module database and computer simulation, the effect of the uncertainty was quantified in terms of the range in predicted annual energy production relative to actual energy production by three small grid-connected PV systems. The relative importance of each coefficient by month of the year was also determined in order to understand the seasonal behavior of the performance model.
光伏阵列性能预测是系统设计和监测的重要组成部分,因此量化与预测相关的不确定性非常重要。Sandia阵列性能模型[1]是用于预测年发电量的众多工具之一,但模型系数不确定性的影响尚未得到充分研究。本文量化了晶体硅组件的电压和电流温度系数的相对重要性,以及与太阳辐照度有关的电压和电流系数。利用在Sandia模块数据库和计算机模拟中观察到的系数变化,根据三个小型并网光伏系统的预测年发电量相对于实际发电量的范围,对不确定性的影响进行了量化。为了了解性能模型的季节性行为,还确定了每个系数在一年中每个月的相对重要性。
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引用次数: 11
Comparing PV simulation models and methods with outdoor measurements 光伏仿真模型和方法与室外测量的比较
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5615829
S. Ransome
Several recent independent kWh/kWp studies have found similar energy yields (<±5%) for various c-Si and thin films without any consistent technology bias [1]. A comparison of various modelling methods such as the matrix method, 1 or 2 diode models, SV method and empirical equations has been performed to see how they predict PV performance. The values of thermal and low light level coefficients used in some simulation models have been found to be different from what is measured to IEC standards [2], [3], [4]. These discrepancies mean simulation programs often predict larger variations between technologies and usually favouring thin films [5]. Suggestions are made as to the best way to predict and validate system performance.
最近几项独立的kWh/kWp研究发现,在没有任何一致的技术偏差[1]的情况下,各种c-Si和薄膜的能量产量相似(<±5%)。比较了各种建模方法,如矩阵法、1或2二极管模型、SV方法和经验方程,以了解它们如何预测PV性能。在一些模拟模型中使用的热和弱光系数值已被发现与IEC标准[2],[3],[4]的测量值不同。这些差异意味着模拟程序经常预测技术之间的较大差异,通常倾向于薄膜。提出了预测和验证系统性能的最佳方法。
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引用次数: 15
Degradation of different photovoltaic technologies under field conditions 不同光伏技术在野外条件下的退化
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614439
G. Makrides, B. Zinsser, G. Georghiou, M. Schubert, J. Werner
Over the past years a number of testing facilities have been monitoring the performance and degradation of PV systems according to the established standards of indoor and outdoor testing. The objective of this paper is to present the initial first year and longer-term rate of degradation of different PV technologies installed at the testing facility of the University of Cyprus, based on outdoor field measurements and methodologies. The first year degradation of the technologies was obtained using a data filtering technique of DC generated power at Maximum Power Point (MPP) at irradiation points of higher than 800 W/m2 and normalising the measured power to Standard Test Conditions (STC). Over the first year, mono-crystalline silicon technologies showed degradations in the range 2.12 % – 4.73 % while for multi-crystalline technologies the range was 1.47 % – 2.40 %. The amorphous silicon system demonstrated the highest first year decrease in power with an average degradation of 13.82 %. For validation purposes the first year degradation was also obtained using a second technique by evaluating outdoor measured data-sets under Air Mass (AM) 1.5 (morning and afternoon) conditions and during noon (high irradiance and temperature). In this case the evaluated results showed deviations of up to 6 % and 3 % for mono-crystalline and multi-crystalline technologies respectively whereas for thin-film this was 5 %. Finally, the longer-term degradation rates were evaluated by using the least-square fit method on average monthly data-set blocks of (i) Performance Ratio (PR), (ii) PR evaluated by filtering outage data-sets and restricting to high irradiance conditions and (iii) the Photovoltaic for Utility Systems Applications (PVUSA) rating methods, for the period June 2007 – June 2009.
在过去的几年里,许多测试机构一直在根据室内和室外测试的既定标准监测光伏系统的性能和退化。本文的目的是根据室外实地测量和方法,介绍在塞浦路斯大学测试设施安装的不同光伏技术的最初第一年和长期退化率。第一年的技术退化是通过在辐照点高于800 W/m2的最大功率点(MPP)直流产生功率的数据滤波技术获得的,并将测量功率归一到标准测试条件(STC)。在第一年里,单晶硅技术的降解率在2.12% - 4.73%之间,而多晶硅技术的降解率在1.47% - 2.40%之间。非晶硅系统显示出最大的第一年功率下降,平均下降13.82%。为了验证目的,还使用第二种技术,通过评估空气质量(AM) 1.5(上午和下午)条件下以及中午(高辐照度和高温度)的室外测量数据集,获得了第一年的退化。在这种情况下,评估结果显示单晶和多晶技术的偏差分别高达6%和3%,而薄膜技术的偏差为5%。最后,对2007年6月至2009年6月期间的(i)性能比(PR)、(ii)通过过滤停电数据集并限制在高辐照条件下评估的PR和(iii)公用事业系统应用光伏(PVUSA)评级方法,使用最小二乘拟合方法对平均每月数据集块进行长期退化率评估。
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引用次数: 34
期刊
2010 35th IEEE Photovoltaic Specialists Conference
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