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2010 35th IEEE Photovoltaic Specialists Conference最新文献

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Simulation of nonuniform irradiance in multijunction IIIV solar cells 多结iii型太阳能电池非均匀辐照度的模拟
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614523
J. Olson
Optics for high concentration photovoltaics often delivers a non-uniform irradiance to the cell. This can be a problem for tunnel-junction interconnected (TJIC) IIIV multijunction solar cells if the resulting local photocurrent exceeds the peak tunneling current density. Current spreading in the vicinity of the tunnel junction can mitigate this effect. We use commercial software to simulate current spreading in a simple GaInP/GaInAs cell with a thin GaAs TJIC. We show that for the narrow light beams, the current spreading is fit reasonably well by a Lorentzian with a spreading length on the order of 10 µm. Below some critical irradiance that depends on the width of the light beam, current spreading increases with the local irradiance. At the critical irradiance where the tunnel diode switches to the thermal current state, the current spreading abruptly decreases. Above the critical irradiance the current spreading continues to decrease with increasing irradiance. The effects of other device parameters on current spreading are discussed.
用于高浓度光伏的光学器件通常向电池提供不均匀的辐照度。对于隧道结互连(TJIC) iii型多结太阳能电池来说,如果产生的局部光电流超过峰值隧道电流密度,这可能是一个问题。在隧道交界处附近的电流扩散可以减轻这种影响。我们使用商业软件来模拟具有薄GaAs TJIC的简单GaInP/GaInAs电池中的电流扩散。结果表明,对于窄光束,洛伦兹扩展长度约为10 μ m,可以很好地拟合电流扩展。在某些取决于光束宽度的临界辐照度以下,电流扩散随着局部辐照度的增加而增加。在隧道二极管切换到热电流状态的临界辐照度处,电流扩散急剧减小。在临界辐照度以上,电流扩散随着辐照度的增加而继续减小。讨论了其他器件参数对电流扩散的影响。
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引用次数: 7
Development of solid polymeric electrolyte for DSSC device DSSC器件用固体聚合物电解质的研制
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5616890
K. F. Chen, C. Liou, C. H. Lee, F. Chen
We fabricated TiO2/N719 dye/PVB base solid state electrolyte DSSC which with efficiency 3.75% in average that can be further optimized and the best efficiency we achieved is 5.20%. To optimize the performance of a solid state DSSC device, the work we have done including the relation between PVB immersed time and the ion conductivity of ion PVB, the incident photon-to-current efficiency (IPCE) test of the PVB base DSSC, and the long-term stability test. This is the first attempt to combine the worldwide used material, PVB, and dye-sensitized solar cell successfully. With the work other groups done before, we can increase the capabilities and values of smart windows with no doubt.
制备了TiO2/N719染料/PVB基固态电解质DSSC,平均效率为3.75%,可进一步优化,最佳效率为5.20%。为了优化固态DSSC器件的性能,我们进行了PVB浸入时间与离子PVB离子电导率的关系、PVB基DSSC的入射光子电流效率(IPCE)测试以及长期稳定性测试。这是首次成功地将世界通用材料PVB与染料敏化太阳能电池相结合。有了其他团队之前所做的工作,毫无疑问,我们可以提高智能窗口的功能和价值。
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引用次数: 5
Wide band gap Gallium Phosphide solar cells for multi-junction solar cell system 用于多结太阳能电池系统的宽带隙磷化镓太阳能电池
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5616636
Xuesong Lu, Susan R. Huang, M. Diaz, R. Opila, A. Barnett
Gallium Phosphide (GaP) solar cells have been designed, fabricated, characterized and analyzed as candidates for the top junction solar cell in a multi-junction solar cell system. Liquid phase epitaxy (LPE) has been used as the growth method for the epitaxial layers. Open circuit voltage (Voc) of 1.535V has been achieved under one sun illumination from the outdoor test. Quantum efficiency (QE) measurements were used in characterizing our solar cell devices. The QE analysis results show that the high front surface recombination velocity and the low diffusion length in the n-type epi-layer region are the two major limitations for the low Voc and short circuit current density (Jsc). An improved structure has been designed based on our current experimental results.
对磷化镓(GaP)太阳能电池进行了设计、制造、表征和分析,作为多结太阳能电池系统中顶结太阳能电池的候选材料。液相外延(LPE)已被用作外延层的生长方法。开路电压(Voc) 1.535V,在一个太阳照射下,从室外测试。量子效率(QE)测量用于表征我们的太阳能电池器件。QE分析结果表明,高的前表面复合速度和n型外延层区域的低扩散长度是限制低Voc和短路电流密度(Jsc)的两个主要因素。根据我们目前的实验结果,设计了一种改进的结构。
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引用次数: 5
Strategies to target rural PV market in developing countries - a perspective 以发展中国家农村光伏市场为目标的战略——一个视角
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614367
C. Solanki, Siddharth Mudaliar
The objective of this paper is to describe the Solar PV market with regards to products like solar lanterns, home lighting systems, power packs especially in the rural context of developing countries. Steps taken by some companies in trying to reach the rural market with solar PV product for matching the needs of the rural regions in India are described. In the study of rural PV market two divergent views exist, providing a mass-manufactured product at very low prices and the other of customized solutions supported by soft-financing options through rural banks. While mass produced solar PV products (SPP) may deliver economies of scale bringing down costs, does it guarantee quick sales and user benefits? On the other hand delivering customized solutions to the user may guarantee sales, financing the solution is a difficult and a long-drawn process, casting a doubt on its ability to scale up. An alternative strategy is developed that targets the rural rich rather than the traditional bottom of pyramid users. Its rationale is explained.
本文的目的是描述太阳能光伏市场的产品,如太阳能灯,家庭照明系统,特别是在发展中国家的农村环境中的电源组。介绍了一些公司为满足印度农村地区的需求,试图将太阳能光伏产品推向农村市场所采取的步骤。在对农村光伏市场的研究中,存在两种不同的观点,一种是以极低的价格提供大量生产的产品,另一种是通过农村银行提供软融资选项支持的定制解决方案。虽然大规模生产的太阳能光伏产品(SPP)可能会带来规模经济,降低成本,但它能保证快速销售和用户受益吗?另一方面,为用户提供定制的解决方案可能会保证销售,但为解决方案融资是一个困难而漫长的过程,这让人怀疑其扩大规模的能力。另一种策略是针对农村富人,而不是传统的金字塔底层用户。解释了其基本原理。
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引用次数: 3
Application of X-ray computed tomography in silicon solar cells x射线计算机断层扫描技术在硅太阳能电池中的应用
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5615872
V. Popovich, W. Verwaal, M. Janssen, I. Bennett, I. Richardson
The present study outlines the characterization of the internal microstructure in a multicrystalline silicon solar cell, by means of a powerful non-intrusive experimental method, namely X-ray computed tomography. The purpose of this research is to give a better understanding of the silicon solar cells metallization layers and defects related to its processing. Resulting tomographic images showed the distribution of bismuth glass and porosity in Al and Ag contact layers. At the same time, 3D tomographic images revealed the presence of process induced defects. In this work the usefulness of the CT technique for the in depth study of silicon solar cells is shown.
本研究通过一种强大的非侵入性实验方法,即x射线计算机断层扫描,概述了多晶硅太阳能电池内部微观结构的表征。本研究的目的是为了更好地了解硅太阳能电池的金属化层及其加工过程中的缺陷。层析图像显示了铝和银接触层中铋玻璃的分布和孔隙度。同时,三维断层图像显示了工艺缺陷的存在。在这项工作中,显示了CT技术对硅太阳能电池深入研究的有用性。
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引用次数: 10
Effects of contamination on solar cell coverglass 污染对太阳能电池盖板玻璃的影响
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614601
Dl Liu, Sh. Liu, C. Panetta, K. Olson, Sm Hong, D. Alaan, C. Mann, K. Luey
As the power generation capability of solar cells depends strongly on the spectra of the incident light through the coverglass, there is a critical need to understand the impact of adsorbed molecular (organic) contaminants, which absorb light in the short wavelength range. The goal of this work is to calculate solar cell current loss based on experimentally determined coverglass transmission change in the presence of contaminant films. Two representative contaminants, di-octyl phthalate (DOP) and DC704, were photo-fixed on the coverglass samples, which were subsequently irradiated with protons under a simulated 15-year GEO space radiation environment. The coverglass transmission change was characterized before and after each process. The coverglass transmission data were then convolved with the solar cell spectral response to determine the coverglass darkening effects on solar cell performance. The results indicate that the solar cell current could be significantly reduced due to the combined effects of contamination and proton exposure.
由于太阳能电池的发电能力在很大程度上取决于通过覆盖玻璃的入射光的光谱,因此迫切需要了解吸附的分子(有机)污染物的影响,这些污染物吸收短波长范围内的光。这项工作的目的是计算太阳能电池电流损耗基于实验确定的覆盖玻璃透射变化在污染薄膜的存在。将两种具有代表性的污染物邻苯二甲酸二辛酯(DOP)和DC704光固定在覆盖玻璃样品上,随后在模拟的15年地球同步轨道空间辐射环境下用质子照射。对各工艺前后盖板玻璃透射率的变化进行了表征。然后将覆盖玻璃透射数据与太阳能电池光谱响应进行卷积,以确定覆盖玻璃变暗对太阳能电池性能的影响。结果表明,由于污染和质子暴露的共同作用,太阳能电池电流显著降低。
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引用次数: 6
Solar Energy Grid Integration Systems (SEGIS) proactive intelligent advances for photovotaic systems 太阳能电网集成系统(SEGIS)是光伏系统的主动智能发展
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5616815
W. Bower, S. Kuszmaul, S. Gonzalez, A. Akhil
This paper provides an overview of the activities of and progress made in the US DOE Solar Energy Grid Integration Systems (SEGIS) program. The work has now progressed from the “Conceptual Designs and Market Analysis” Stage 1 through the “Prototype Development” Stage 2. Twelve contractors completed the Stage 1 conceptual designs and market analysis. Best value competition resulted follow on work with control methodologies and hardware prototypes developed and completed by five contractors. The prototypes span system sizes from micro-inverters (200W) to commercial sizes through 100kW. Modularity of the designs enables larger applications. This SEGIS R&D is opening pathways for connecting PV systems to emerging intelligent utility grids and micro-grids. In addition to new grid-interconnection capabilities and “value added” features, the new hardware designs result in smaller, less material-intensive, and higher reliability products. The solutions and “value added” enabled by SEGIS systems will help drive the “advanced integrated system” concepts and “smart grid” evolutionary processes forward in a faster and more focused manner.[1,2,3]
本文概述了美国能源部太阳能电网集成系统(SEGIS)项目的活动和取得的进展。工作已由第一阶段的“概念设计及市场分析”发展至第二阶段的“原型开发”。12家承建商完成了第一阶段的概念设计和市场分析。五个承包商开发并完成了控制方法和硬件原型,从而产生了最佳价值竞争。这些样机的系统尺寸从微型逆变器(200W)到商用逆变器(100kW)不等。模块化的设计可以实现更大的应用。SEGIS的研发为光伏系统连接新兴的智能电网和微电网开辟了道路。除了新的电网互联能力和“增值”功能外,新的硬件设计还带来了更小、更少材料密集型和更高可靠性的产品。由SEGIS系统实现的解决方案和“增值”将有助于推动“先进集成系统”概念和“智能电网”以更快、更集中的方式向前发展。[1,2,3]
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引用次数: 9
Application of CL/EBIC-SEM techniques for characterization of irradiation induced defects in triple junction solar cells CL/EBIC-SEM技术在三结太阳能电池辐照缺陷表征中的应用
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5615869
S. Maximenko, S. Messenger, C. Cress, M. González, J. A. Freitas, R. Walters
We report the results of the characterization of irradiated InGaP2/GaAs/Ge multijunction (MJ) solar cells using the cathodoluminescence (CL) imaging/spectroscopy and electron beam induced current (EBIC) modes of scanning electron microscopy (SEM). These techniques were applied to verify the influence of irradiation damage on the optoelectronic properties of each subcell triple junction structure and correlate illuminated (AM0, 1 sun, 25°C) currentquantum efficiency (QE) characteristics.
本文报道了利用扫描电子显微镜(SEM)的阴极发光(CL)成像/光谱和电子束感应电流(EBIC)模式对辐照InGaP2/GaAs/Ge多结(MJ)太阳能电池进行表征的结果。利用这些技术验证了辐照损伤对每个亚电池三结结构光电性能的影响,以及相关的照明(AM0, 1太阳,25°C)电流量子效率(QE)特性。
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引用次数: 2
Progress on III-nitride/silicon hybrid multijunction solar cells 氮化硅杂化多结太阳能电池的研究进展
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5614652
L. Reichertz, I. Gherasoiu, K. Yu, J. Ager, V. M. Kao, W. Walukiewicz
We report on the progress towards a high efficiency InGaN/Si tandem hybrid solar cell. The proof of principle has been demonstrated in a 5 × 5 mm III-nitride/Si dual junction solar cell, with p/n GaN junction grown by molecular beam epitaxy (MBE) functioning as the top cell and a standard n-type Si wafer with an Al doped p-type surface functioning as the bottom cell. An open circuit voltage (Voc) of 2.5 V was measured under 1× AM1.5G illumination conditions with additional UV laser illumination of the GaN junction. The quantum efficiency spectra show that both junctions are active and working in series. The 1x sun conversion efficiency of the GaN/Si tandem cell is limited to less than 1% due to the large band gap of GaN not being matched to the solar spectrum. Ongoing work is therefore focused on lowering the bandgap of the top cell to an optimum of about 1.8 eV by increasing the indium content of the top InGaN cell in order to match the current of the Si bottom cell under solar illumination. Very recently, we have achieved PV action in the first InGaN/Si hybrid cells. The remaining challenge lies in maintaining a high quality pn- junction in InGaN as the In fraction has to be increased towards 45%.
我们报告了高效InGaN/Si串联混合太阳能电池的进展。在5 × 5 mm的iii -氮化物/Si双结太阳能电池中,以分子束外延(MBE)生长的p/n GaN结作为顶电池,以掺杂Al的p型表面的标准n型硅片作为底电池,证明了原理的证明。在1× AM1.5G照明条件下测量了GaN结的开路电压(Voc)为2.5 V。量子效率谱显示两个结都是主动的,并且是串联工作的。GaN/Si串联电池的1倍太阳转换效率由于GaN的大带隙与太阳光谱不匹配而限制在1%以下。因此,正在进行的工作重点是通过增加顶部InGaN电池的铟含量,将顶部电池的带隙降低到约1.8 eV的最佳值,以匹配太阳照射下Si底部电池的电流。最近,我们在第一个InGaN/Si混合电池中实现了PV作用。剩下的挑战在于在InGaN中保持高质量的pn结,因为in分数必须增加到45%。
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引用次数: 3
Technical advantages and challenges for core-shell micro/ nanowire large area PV devices 核壳型微纳米线大面积光伏器件的技术优势与挑战
Pub Date : 2010-06-20 DOI: 10.1109/PVSC.2010.5617199
B. Wacaser, M. Khayyat, M. Reuter, D. Sadana, F. Ross
A promising field for future low cost, medium efficiency solar cell devices is the use of vapor-liquid-solid (VLS) grown nanowires or micropillars (NWs referring to both) as the active region of large scale (greater than 1 mm2 area) photovoltaic devices. There are several advantages of using NWs. The NWs can be doped as grown, helping with formation of a PV structure. NW-based PV structures require shorter carrier diffusion distances than are needed for a similarly thick planar absorber layer. At the same time, due to scattering and other optical phenomena the NW structure is able to trap more light and improve the overall light absorption. This, combined with the ability to grow nanowires on cheap substrates or reuse the growth substrate multiple times, makes NWs promising for future generation PV devices. In order for NWs to perform to their full potential several technical challenges need to be overcome. In this paper we will discuss these technical challenges in conjunction with the advantages of using NWs in large scale PV devices. We will also outline the progress that we and others have made in overcoming these challenges on the way to making nanowires a viable PV technology.
对于未来低成本、中等效率的太阳能电池装置来说,一个有前景的领域是使用蒸汽-液体-固体(VLS)生长的纳米线或微柱(NWs指的是两者)作为大规模(大于1mm2面积)光伏装置的有源区域。使用NWs有几个优点。NWs可以在生长过程中掺杂,有助于形成PV结构。与同样厚的平面吸收层相比,nw基PV结构需要更短的载流子扩散距离。同时,由于散射和其他光学现象,NW结构能够捕获更多的光,提高整体光吸收。这一点,再加上在廉价的衬底上生长纳米线或多次重复使用生长衬底的能力,使得NWs在未来一代光伏设备中很有前景。为了使核武器充分发挥其潜力,需要克服若干技术挑战。在本文中,我们将讨论这些技术挑战,并结合在大规模光伏设备中使用NWs的优势。我们还将概述我们和其他人在克服这些挑战的过程中取得的进展,使纳米线成为可行的光伏技术。
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引用次数: 7
期刊
2010 35th IEEE Photovoltaic Specialists Conference
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