首页 > 最新文献

2013 International Conference on Materials for Renewable Energy and Environment最新文献

英文 中文
Feasibility study on applying thermoelectric SiC ceramics for supersonic aerodynamic heat recovery 热电SiC陶瓷应用于超音速气动热回收的可行性研究
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893716
X. Han, Haifeng Cheng, Jun Wang
SiC ceramics are widely serving as ceramic composites matrix materials of high-velocity vehicles structures against extremely heating and oxidation for their sustainability at high temperature, and are also high temperature thermoelectric materials, which can transfer heat to electricity by temperature difference. Both of these advantages brought out an idea of generating electricity from aerodynamic heat by thermoelectric SiC structures on supersonic vehicles. A simple nose-tip thermoelectric module is set up, in this work, to predict the thermoelectric performance of SiC ceramics in a supersonic air flow environment (Mach number 3). The flow field parameters, temperature difference and temperature distributions of the module have been simulated by computational fluid dynamics methods. The thermoelectric performance and effect of Thomson heat were discussed. The maximum power output and energy efficiency reaches 0.0027 W and 0.0036 %, respectively, at 230 K temperature difference and a current of 0.122 A. The Thomson heat increases directly with the output current, and at a current above 0.15 A, over 50 % of the generated power has been turned back to thermal heat, resulting in the effective output power as well as energy efficiency decrease rapidly. The thermoelectric efficiency would be increased on higher-speed vehicles by enlarged temperature difference.
碳化硅陶瓷因其在高温下的可持续性被广泛用作高速车辆结构的陶瓷复合材料基体材料,同时也是一种利用温差将热转化为电的高温热电材料。这两个优点引出了利用超音速飞行器上的热电碳化硅结构利用空气动力热发电的想法。本文建立了一个简单的鼻尖热电模块,用于预测SiC陶瓷在超音速气流环境(马赫数为3)下的热电性能,并采用计算流体动力学方法对该模块的流场参数、温差和温度分布进行了模拟。讨论了汤姆逊热的热电性能和效应。当温度差为230 K,电流为0.122 a时,最大输出功率为0.0027 W,最大能效为0.0036%。汤姆逊热直接随着输出电流的增大而增大,在0.15 a以上的电流下,超过50%的发电功率已转化为热能,导致有效输出功率和能效迅速下降。在高速行驶的车辆上,增大温差可以提高热电效率。
{"title":"Feasibility study on applying thermoelectric SiC ceramics for supersonic aerodynamic heat recovery","authors":"X. Han, Haifeng Cheng, Jun Wang","doi":"10.1109/ICMREE.2013.6893716","DOIUrl":"https://doi.org/10.1109/ICMREE.2013.6893716","url":null,"abstract":"SiC ceramics are widely serving as ceramic composites matrix materials of high-velocity vehicles structures against extremely heating and oxidation for their sustainability at high temperature, and are also high temperature thermoelectric materials, which can transfer heat to electricity by temperature difference. Both of these advantages brought out an idea of generating electricity from aerodynamic heat by thermoelectric SiC structures on supersonic vehicles. A simple nose-tip thermoelectric module is set up, in this work, to predict the thermoelectric performance of SiC ceramics in a supersonic air flow environment (Mach number 3). The flow field parameters, temperature difference and temperature distributions of the module have been simulated by computational fluid dynamics methods. The thermoelectric performance and effect of Thomson heat were discussed. The maximum power output and energy efficiency reaches 0.0027 W and 0.0036 %, respectively, at 230 K temperature difference and a current of 0.122 A. The Thomson heat increases directly with the output current, and at a current above 0.15 A, over 50 % of the generated power has been turned back to thermal heat, resulting in the effective output power as well as energy efficiency decrease rapidly. The thermoelectric efficiency would be increased on higher-speed vehicles by enlarged temperature difference.","PeriodicalId":6427,"journal":{"name":"2013 International Conference on Materials for Renewable Energy and Environment","volume":"70 1","pages":"485-489"},"PeriodicalIF":0.0,"publicationDate":"2013-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85899782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The influence of electrochemical terms on TiO2 nanorod morphology and photoreduction ability 电化学条件对TiO2纳米棒形貌和光还原能力的影响
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893764
Dan Kong, Jeannie Z. Y. Tan, Xiwen Zhang
Photoreduction of CO2 to hydrocarbon needs the urgent development in effective and low-cost technology to mitigate global warming caused by atmospheric CO2 and other poisonous gas from fossil fuels combustion. In this work, Cu-decorated TiO2 nanorod films were synthesized by the hydrothermal method followed by electrochemical method with copper ion solution concentration (1-6mmol/L)and potential voltages (-1.6 and -1.2v). A combination of characterization methods XRD, SEM, and UV-Vis DTS, TEM, XPS were used to evaluate the interaction between titania and decorated copper. Their photocatalytic activities were evaluated by the reduction yield of CO2 under UV irradiation. The methane yield of Cu-TiO2 showed an obvious increment as a result of localized surface Plasmon (LSP) of Cu particles. These arrays are important for photocatalysis and for the development of the photoreduction of CO2 on the global warming.
二氧化碳光还原为碳氢化合物,迫切需要开发有效和低成本的技术,以减轻大气中二氧化碳和其他有毒气体燃烧造成的全球变暖。在铜离子溶液浓度为1-6mmol/L,电位分别为-1.6和-1.2v的条件下,采用水热法和电化学法制备了cu修饰的TiO2纳米棒膜。采用XRD、SEM、UV-Vis DTS、TEM、XPS等综合表征方法对钛与装饰铜的相互作用进行了表征。通过紫外照射下CO2的还原率评价了它们的光催化活性。由于Cu粒子的局部表面等离子体激元(LSP), Cu- tio2的甲烷产率明显增加。这些阵列对于光催化和发展光还原CO2对全球变暖具有重要意义。
{"title":"The influence of electrochemical terms on TiO2 nanorod morphology and photoreduction ability","authors":"Dan Kong, Jeannie Z. Y. Tan, Xiwen Zhang","doi":"10.1109/ICMREE.2013.6893764","DOIUrl":"https://doi.org/10.1109/ICMREE.2013.6893764","url":null,"abstract":"Photoreduction of CO2 to hydrocarbon needs the urgent development in effective and low-cost technology to mitigate global warming caused by atmospheric CO2 and other poisonous gas from fossil fuels combustion. In this work, Cu-decorated TiO2 nanorod films were synthesized by the hydrothermal method followed by electrochemical method with copper ion solution concentration (1-6mmol/L)and potential voltages (-1.6 and -1.2v). A combination of characterization methods XRD, SEM, and UV-Vis DTS, TEM, XPS were used to evaluate the interaction between titania and decorated copper. Their photocatalytic activities were evaluated by the reduction yield of CO2 under UV irradiation. The methane yield of Cu-TiO2 showed an obvious increment as a result of localized surface Plasmon (LSP) of Cu particles. These arrays are important for photocatalysis and for the development of the photoreduction of CO2 on the global warming.","PeriodicalId":6427,"journal":{"name":"2013 International Conference on Materials for Renewable Energy and Environment","volume":"58 1","pages":"676-679"},"PeriodicalIF":0.0,"publicationDate":"2013-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86110952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on the volatile organic compounds removal with mesoporous catalysts made from solar panel 太阳能板介孔催化剂去除挥发性有机化合物的研究
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893735
C. Chang, Ri-Tian Ruan
In this research, the adsorption of toluene was tested with MCM-41 and mesoporous silica materials synthesized from spent solar panel and glass. The synthesized solution was mixed with cationic cetyltrimethyl ammonium bromide (CTAB) surfactants. The prepared adsorbents were characterized by nitrogen adsorption-desorption analysis, transmission electron microscope, scanning electron microscope - energy dispersive spectroscopy, X-ray powder diffractometer and Fourier transform infrared spectroscopy. The results showed that the surface area, large pore volume and pore diameter could be up to 1280m2 g-1, 0.82cm3 g-1 and 2.62 nm, respectively. The crystal patterns of mesoporous silica materials were similar of MCM-41 from TEM image. In this study, the effects of operation parameters, such as contact time and mixture concentration, on adsorption performance were also assessed.
本研究用MCM-41和由废太阳能电池板和玻璃合成的介孔二氧化硅材料对甲苯的吸附进行了测试。合成的溶液与阳离子十六烷基三甲基溴化铵(CTAB)表面活性剂混合。采用氮吸附-解吸分析、透射电镜、扫描电镜-能谱、x射线粉末衍射仪和傅里叶变换红外光谱对制备的吸附剂进行了表征。结果表明,该材料的比表面积可达1280m2 g-1,大孔体积可达0.82cm m3 g-1,孔径可达2.62 nm。TEM图像显示,介孔二氧化硅材料的晶型与MCM-41相似。在本研究中,还评估了操作参数(如接触时间和混合物浓度)对吸附性能的影响。
{"title":"Study on the volatile organic compounds removal with mesoporous catalysts made from solar panel","authors":"C. Chang, Ri-Tian Ruan","doi":"10.1109/ICMREE.2013.6893735","DOIUrl":"https://doi.org/10.1109/ICMREE.2013.6893735","url":null,"abstract":"In this research, the adsorption of toluene was tested with MCM-41 and mesoporous silica materials synthesized from spent solar panel and glass. The synthesized solution was mixed with cationic cetyltrimethyl ammonium bromide (CTAB) surfactants. The prepared adsorbents were characterized by nitrogen adsorption-desorption analysis, transmission electron microscope, scanning electron microscope - energy dispersive spectroscopy, X-ray powder diffractometer and Fourier transform infrared spectroscopy. The results showed that the surface area, large pore volume and pore diameter could be up to 1280m2 g-1, 0.82cm3 g-1 and 2.62 nm, respectively. The crystal patterns of mesoporous silica materials were similar of MCM-41 from TEM image. In this study, the effects of operation parameters, such as contact time and mixture concentration, on adsorption performance were also assessed.","PeriodicalId":6427,"journal":{"name":"2013 International Conference on Materials for Renewable Energy and Environment","volume":"1 1","pages":"562-564"},"PeriodicalIF":0.0,"publicationDate":"2013-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89338657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of a new lamellar nano zinc borate 新型层状纳米硼酸锌的合成
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893742
Pingqiang Gao, Wenhua Song, Feng Ding, Xing Wang
A new lamellar nano zinc borate 4ZnOB2O3H2O were successfully synthesized via one-step precipitation reaction in aqueous solution of sodium borate (Na2B4O7.10H2O) and zinc borate nitrate(Zn(NO3)2·6H2O). The characterizations of the as-obtained samples were studied by X-ray diffraction(XRD), Field-emission scanning electron microscopy (FESEM), Fourier transform infrared spectrum (FTIR), It had been found that the new material have a lamellar shape with the particle size of around 100-200 nm, and it seems that the lamellar are size-homogeneous and well dispersed.
在硼酸钠(Na2B4O7.10H2O)和硝酸硼酸锌(Zn(NO3)2·6H2O)的水溶液中,通过一步沉淀法成功合成了新型片状纳米硼酸锌4ZnOB2O3H2O。利用x射线衍射(XRD)、场发射扫描电镜(FESEM)、傅里叶变换红外光谱(FTIR)对样品进行表征,发现新材料具有片层状结构,粒径在100 ~ 200 nm左右,片层尺寸均匀,分散良好。
{"title":"Synthesis of a new lamellar nano zinc borate","authors":"Pingqiang Gao, Wenhua Song, Feng Ding, Xing Wang","doi":"10.1109/ICMREE.2013.6893742","DOIUrl":"https://doi.org/10.1109/ICMREE.2013.6893742","url":null,"abstract":"A new lamellar nano zinc borate 4ZnOB<sub>2</sub>O<sub>3</sub>H<sub>2</sub>O were successfully synthesized via one-step precipitation reaction in aqueous solution of sodium borate (Na<sub>2</sub>B<sub>4</sub>O<sub>7</sub>.10H<sub>2</sub>O) and zinc borate nitrate(Zn(NO<sub>3</sub>)<sub>2</sub>·6H<sub>2</sub>O). The characterizations of the as-obtained samples were studied by X-ray diffraction(XRD), Field-emission scanning electron microscopy (FESEM), Fourier transform infrared spectrum (FTIR), It had been found that the new material have a lamellar shape with the particle size of around 100-200 nm, and it seems that the lamellar are size-homogeneous and well dispersed.","PeriodicalId":6427,"journal":{"name":"2013 International Conference on Materials for Renewable Energy and Environment","volume":"13 1","pages":"589-592"},"PeriodicalIF":0.0,"publicationDate":"2013-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87993151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Design and verification of a small-scale lift-type vertical axis wind turbine composite blade 小型升力式垂直轴风力机复合叶片的设计与验证
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893684
Zhongjia Yang, Yizhuo Gu, Min Li, Yanxia Li, Jie Lu, Z. Zhang
In order to obtain the small lift style vertical axis wind turbine with excellent performances, this paper presented the technologies of design and manufacture of the composite blade with high lift coefficient. The manufacturing process was evaluated based on the dimensional accuracy of the blade. The structure of the composite blade was evaluated by means of finite element modeling (FEM) and the mechanical property. Moreover, the vibration property of the blade was studied by FEM, and the resonance of the wind turbine assembled with the blade was investigated.
为了获得性能优良的小升力型垂直轴风力机,本文提出了高升力系数复合叶片的设计与制造技术。根据叶片的尺寸精度对制造工艺进行了评价。采用有限元方法对复合叶片的结构和力学性能进行了评价。利用有限元方法研究了叶片的振动特性,并对装配叶片的风力机进行了共振分析。
{"title":"Design and verification of a small-scale lift-type vertical axis wind turbine composite blade","authors":"Zhongjia Yang, Yizhuo Gu, Min Li, Yanxia Li, Jie Lu, Z. Zhang","doi":"10.1109/ICMREE.2013.6893684","DOIUrl":"https://doi.org/10.1109/ICMREE.2013.6893684","url":null,"abstract":"In order to obtain the small lift style vertical axis wind turbine with excellent performances, this paper presented the technologies of design and manufacture of the composite blade with high lift coefficient. The manufacturing process was evaluated based on the dimensional accuracy of the blade. The structure of the composite blade was evaluated by means of finite element modeling (FEM) and the mechanical property. Moreover, the vibration property of the blade was studied by FEM, and the resonance of the wind turbine assembled with the blade was investigated.","PeriodicalId":6427,"journal":{"name":"2013 International Conference on Materials for Renewable Energy and Environment","volume":"97 1","pages":"364-367"},"PeriodicalIF":0.0,"publicationDate":"2013-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85318090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
One-dimensional Lattice Boltzmann numerical simulation of a downhole heat exchanger 井下换热器一维晶格玻尔兹曼数值模拟
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893834
Wenjing Jiao, C. Dai, Shunxing Xie
A one-dimensional unsteady heat conduction simulation for downhole heat exchanger (DHE) is established in this paper, and the Lattice Boltzmann Method is used for the numerical simulation. In the model proposed, the influence factors of the temperature gradient with well depth, well pipe diameter, thermal properties of pipe, circulating water flow rate and inlet temperature on the outlet water temperature or heat output have been taken into account. According to the DHE experimental data, a comparison was made between the results of simulation and experiment. The result shows that the model can be used to predict the outlet water temperature of DHE at given conditions, but the deviation from the experiment increases with time, which is probably resulted from the natural convection occurred in the aquifer, and its intensity is gradually strengthened.
本文建立了井下换热器一维非定常导热数值模拟,并采用格子玻尔兹曼方法进行数值模拟。该模型考虑了井深温度梯度、井管径、管材热性能、循环水流量、进口温度等因素对出水温度或热输出的影响。根据DHE实验数据,将仿真结果与实验结果进行了比较。结果表明,该模型在一定条件下可用于预测DHE出水温度,但与实验值的偏差随着时间的推移而增大,这可能是由于含水层中存在自然对流,且对流强度逐渐增强所致。
{"title":"One-dimensional Lattice Boltzmann numerical simulation of a downhole heat exchanger","authors":"Wenjing Jiao, C. Dai, Shunxing Xie","doi":"10.1109/ICMREE.2013.6893834","DOIUrl":"https://doi.org/10.1109/ICMREE.2013.6893834","url":null,"abstract":"A one-dimensional unsteady heat conduction simulation for downhole heat exchanger (DHE) is established in this paper, and the Lattice Boltzmann Method is used for the numerical simulation. In the model proposed, the influence factors of the temperature gradient with well depth, well pipe diameter, thermal properties of pipe, circulating water flow rate and inlet temperature on the outlet water temperature or heat output have been taken into account. According to the DHE experimental data, a comparison was made between the results of simulation and experiment. The result shows that the model can be used to predict the outlet water temperature of DHE at given conditions, but the deviation from the experiment increases with time, which is probably resulted from the natural convection occurred in the aquifer, and its intensity is gradually strengthened.","PeriodicalId":6427,"journal":{"name":"2013 International Conference on Materials for Renewable Energy and Environment","volume":"7 1","pages":"973-976"},"PeriodicalIF":0.0,"publicationDate":"2013-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81178973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermophysical properties and stability of paraffin microemulsions as latent functionally thermal fluid 石蜡微乳作为潜在功能热流体的热物理性质和稳定性
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893721
Y. Guo, Wen-wei Zheng, Haifeng Cheng, Dongqing Liu
Paraffin microemulsions are multifunctional thermal fluid consisting of water as the continuous phase and paraffin as the dispersed phase. They can store or transfer a large amount of thermal energy by using the latent heat capacity of the paraffin during the phase transition as well as the sensible heat capacity of water. In this study, hexadecane O/W microemulsions were emulsified by an ionic surfactant SDS and a co-surfactant butanol. The phase behavior, effective stability, droplet size and thermophysical properties, such as latent heat and dynamic viscosity, were investigated experimentally. The results showed the prepared microemulsion with 30 wt.% hexadecane has expected high heat capacity about 93.4 J/g and low viscosity about 21 mpa·s. The average droplet size is 73 nm. The results indicate that they have potential applications in thermal energy storage and transfer.
石蜡微乳是一种以水为连续相,石蜡为分散相的多功能热流体。它们可以利用石蜡相变时的潜热容和水的显热容来储存或传递大量的热能。本研究采用离子表面活性剂SDS和助表面活性剂丁醇对十六烷O/W微乳液进行乳化。实验研究了相行为、有效稳定性、液滴尺寸以及潜热、动粘度等热物理性质。结果表明,十六烷含量为30 wt.%的微乳液具有较高的热容量(93.4 J/g)和较低的粘度(21 mpa·s)。液滴的平均尺寸为73 nm。结果表明,它们在热能储存和传递方面具有潜在的应用前景。
{"title":"Thermophysical properties and stability of paraffin microemulsions as latent functionally thermal fluid","authors":"Y. Guo, Wen-wei Zheng, Haifeng Cheng, Dongqing Liu","doi":"10.1109/ICMREE.2013.6893721","DOIUrl":"https://doi.org/10.1109/ICMREE.2013.6893721","url":null,"abstract":"Paraffin microemulsions are multifunctional thermal fluid consisting of water as the continuous phase and paraffin as the dispersed phase. They can store or transfer a large amount of thermal energy by using the latent heat capacity of the paraffin during the phase transition as well as the sensible heat capacity of water. In this study, hexadecane O/W microemulsions were emulsified by an ionic surfactant SDS and a co-surfactant butanol. The phase behavior, effective stability, droplet size and thermophysical properties, such as latent heat and dynamic viscosity, were investigated experimentally. The results showed the prepared microemulsion with 30 wt.% hexadecane has expected high heat capacity about 93.4 J/g and low viscosity about 21 mpa·s. The average droplet size is 73 nm. The results indicate that they have potential applications in thermal energy storage and transfer.","PeriodicalId":6427,"journal":{"name":"2013 International Conference on Materials for Renewable Energy and Environment","volume":"12 1","pages":"504-507"},"PeriodicalIF":0.0,"publicationDate":"2013-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82768071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Ambient temperature adsorption of carbonyl sulfide using modified γ- Al2O3 改性γ- Al2O3对羰基硫化物的常温吸附
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893751
J. Qiu, Xueqian Wang, P. Ning, W. Liu, Wei Chen, Quanli Feng
γ-Al2O3 modified with different impregnants has been studied for COS removal efficiency under micro-oxygen conditions. γ-Al2O3 modified with 5%KOH is found to have markedly enhanced its adsorption purification ability. In the adsorption purification process, the reaction temperature and oxygen concentration of the gas are determined to be two crucial factors. After heating regeneration, the adsorption efficiency of spent sorbent (K/γ-Al2O3-R1 and R2) were still effective and stable. And it will be of use after heating regeneration. According to the current study results, the γ-Al2O3 impregnated with 5%KOH promises a good candidate for COS adsorbent.
研究了不同浸渍剂改性γ-Al2O3在微氧条件下对COS的去除效果。经5%KOH修饰的γ-Al2O3吸附净化能力明显增强。在吸附净化过程中,确定反应温度和气体氧浓度是两个至关重要的因素。经过加热再生后,废吸附剂(K/γ-Al2O3-R1和R2)的吸附效率仍然有效且稳定。经加热再生后即可使用。根据目前的研究结果,5%KOH浸渍的γ-Al2O3是COS吸附剂的良好候选材料。
{"title":"Ambient temperature adsorption of carbonyl sulfide using modified γ- Al2O3","authors":"J. Qiu, Xueqian Wang, P. Ning, W. Liu, Wei Chen, Quanli Feng","doi":"10.1109/ICMREE.2013.6893751","DOIUrl":"https://doi.org/10.1109/ICMREE.2013.6893751","url":null,"abstract":"γ-Al<sub>2</sub>O<sub>3</sub> modified with different impregnants has been studied for COS removal efficiency under micro-oxygen conditions. γ-Al<sub>2</sub>O3 modified with 5%KOH is found to have markedly enhanced its adsorption purification ability. In the adsorption purification process, the reaction temperature and oxygen concentration of the gas are determined to be two crucial factors. After heating regeneration, the adsorption efficiency of spent sorbent (K/γ-Al<sub>2</sub>O<sub>3</sub>-R1 and R2) were still effective and stable. And it will be of use after heating regeneration. According to the current study results, the γ-Al<sub>2</sub>O<sub>3</sub> impregnated with 5%KOH promises a good candidate for COS adsorbent.","PeriodicalId":6427,"journal":{"name":"2013 International Conference on Materials for Renewable Energy and Environment","volume":"52 1","pages":"626-629"},"PeriodicalIF":0.0,"publicationDate":"2013-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84809002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The impact of the mechanical properties with rare earth elements on the black shale glass-ceramic 稀土元素对黑页岩玻璃陶瓷力学性能的影响
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893737
Jie Zhang, F. Xie, Yujun Liang
The process of preparation of glass ceramics from black shale is briefly described in this paper. ICP-MS analytical method is used to obtain glass-ceramics REE content, RE eigenvalue and distribution model. It shows that rare earth elements (Ce, etc) are relatively concentrated in glass ceramics. It's proved in a series of tests that the flexural and compressive strength of glass-ceramics is superior to marble and granite because of traces REE containing in glass-ceramics. In addition, the results of scanning electron microscopy tests show that REE are as main factor affects the crystallization temperature and color of glass ceramics.
简要介绍了黑页岩制备玻璃陶瓷的工艺过程。采用ICP-MS分析方法获得了微晶玻璃的稀土含量、稀土特征值及分布模型。表明稀土元素(Ce等)在玻璃陶瓷中的含量相对较高。一系列试验证明,由于微晶玻璃中含有微量稀土元素,微晶玻璃的抗折和抗压强度优于大理石和花岗岩。此外,扫描电镜测试结果表明,稀土元素是影响玻璃陶瓷结晶温度和颜色的主要因素。
{"title":"The impact of the mechanical properties with rare earth elements on the black shale glass-ceramic","authors":"Jie Zhang, F. Xie, Yujun Liang","doi":"10.1109/ICMREE.2013.6893737","DOIUrl":"https://doi.org/10.1109/ICMREE.2013.6893737","url":null,"abstract":"The process of preparation of glass ceramics from black shale is briefly described in this paper. ICP-MS analytical method is used to obtain glass-ceramics REE content, RE eigenvalue and distribution model. It shows that rare earth elements (Ce, etc) are relatively concentrated in glass ceramics. It's proved in a series of tests that the flexural and compressive strength of glass-ceramics is superior to marble and granite because of traces REE containing in glass-ceramics. In addition, the results of scanning electron microscopy tests show that REE are as main factor affects the crystallization temperature and color of glass ceramics.","PeriodicalId":6427,"journal":{"name":"2013 International Conference on Materials for Renewable Energy and Environment","volume":"39 1","pages":"990-993"},"PeriodicalIF":0.0,"publicationDate":"2013-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90061475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Thermal-reforming of toluene over core-shell Ni/γ-Al2O3 catalysts 核壳型Ni/γ-Al2O3催化剂上甲苯的热重整反应
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893718
Wenjing Ma, Ling Han, Liang-miao Zhang, Wencong Lu
In the present study, core-shell Al2O3 was synthesized by hydrothermal method and employed as support for the preparation of Ni/Al2O3 catalysts via an impregnation method. The toluene thermal-reforming was investigated in a fluidized bed reactor using these core-shell Ni/Al2O3 catalysts. The catalysts were characterized with TEM, BET, XRD and H2-TPR techniques. Compared with the catalysts supported on commercial Al2O3, core-shell catalysts exhibited higher specific surface areas, smaller Ni particle sizes and higher catalytic activities. The core-shell catalysts showed high stability during 48h thermal-reforming.
本研究采用水热法合成了核壳Al2O3,并将其作为浸渍法制备Ni/Al2O3催化剂的载体。采用核壳型Ni/Al2O3催化剂在流化床反应器中对甲苯的热重整进行了研究。采用TEM、BET、XRD和H2-TPR技术对催化剂进行了表征。与商用Al2O3负载型催化剂相比,核壳型催化剂具有更高的比表面积、更小的Ni颗粒尺寸和更高的催化活性。核壳催化剂在48h热重整过程中表现出较高的稳定性。
{"title":"Thermal-reforming of toluene over core-shell Ni/γ-Al2O3 catalysts","authors":"Wenjing Ma, Ling Han, Liang-miao Zhang, Wencong Lu","doi":"10.1109/ICMREE.2013.6893718","DOIUrl":"https://doi.org/10.1109/ICMREE.2013.6893718","url":null,"abstract":"In the present study, core-shell Al<sub>2</sub>O<sub>3</sub> was synthesized by hydrothermal method and employed as support for the preparation of Ni/Al<sub>2</sub>O<sub>3</sub> catalysts via an impregnation method. The toluene thermal-reforming was investigated in a fluidized bed reactor using these core-shell Ni/Al<sub>2</sub>O<sub>3</sub> catalysts. The catalysts were characterized with TEM, BET, XRD and H<sub>2</sub>-TPR techniques. Compared with the catalysts supported on commercial Al<sub>2</sub>O<sub>3</sub>, core-shell catalysts exhibited higher specific surface areas, smaller Ni particle sizes and higher catalytic activities. The core-shell catalysts showed high stability during 48h thermal-reforming.","PeriodicalId":6427,"journal":{"name":"2013 International Conference on Materials for Renewable Energy and Environment","volume":"3 1","pages":"492-495"},"PeriodicalIF":0.0,"publicationDate":"2013-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80375940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
期刊
2013 International Conference on Materials for Renewable Energy and Environment
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1