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Low Pressure Chemical Vapor Deposition of Nb and F Co-Doped TiO 2 Layer Nb和F共掺杂tio2层的低压化学气相沉积
Pub Date : 2014-04-03 DOI: 10.4236/JCPT.2014.42011
S. Yamauchi, Shouta Saiki, K. Ishibashi, Akie Nakagawa, S. Hatakeyama
Nb and F co-doped anatase TiO2 layers were deposited by low pressure chemical vapor deposition (LPCVD) at pressure of 3 mtorr using titanium-tetra-iso-propoxide (TTIP), O2 and NbF5 as precursor, oxidant and dopant respectively. Resistivity beyond 100 Ωcm for undoped layer was decreased with increasing supply of the dopant and dependent on the supply ratio of O2 to TTIP and decreased to 0.2 Ωcm by the optimization. X-ray fluorescent spectroscopy showed Nb-content in the layer was decreased with the O2-supply ratio. X-ray photo-spectroscopy indicated that F substituted O-site in TiO2 by O2-supply but carbon-contamination and F missing substitution in the O-site were significantly increased by excess O2-supply. Further, it was suggested that the substituted F played an important role to reduce resistivity without significant contribution of O-vacancies. XRD spectra showed F missing substitution in the O-site degraded the crystallinity.
采用低压化学气相沉积(LPCVD)技术,分别以四异丙醇钛(TTIP)、O2和NbF5为前驱体、氧化剂和掺杂剂,在3 mtorr的压力下制备了Nb和F共掺杂锐钛矿TiO2层。未掺杂层在100 Ωcm以上的电阻率随掺杂量的增加而降低,且取决于O2与TTIP的供给比,优化后的电阻率降至0.2 Ωcm。x射线荧光光谱显示,随着o2供给比的增加,层内的铌含量降低。x射线光谱学分析表明,TiO2中的o位被o2取代,但过量的o2使碳污染和o位上的F缺失取代显著增加。进一步表明,取代的F对降低电阻率有重要作用,而o空位的贡献不大。XRD谱图显示,o位F缺失取代降低了结晶度。
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引用次数: 8
Studies on Nano Crystalline Ceramic Superconductor LaZrYBaCa 2 Cu 3 O 11 at Three Different Temperatures 纳米晶陶瓷超导体lazrybaca2cu3o11在三种不同温度下的研究
Pub Date : 2014-04-03 DOI: 10.4236/JCPT.2014.42016
A. S. Nair, V. Vinila, Sheelakumari Issac, R. Jacob, Anusha Mony, H. Nair, Sam Rajan, D. Satheesh, Jayakumari Isac
The high temperature superconductors are ceramic materials with layers of Copper-oxide spaced by layers containing Barium and other atoms. The Yttrium compound is somewhat unique in that it has a regular crystal structure while the Lanthanum version is classified as a solid solution. The Yttrium compound is often called the 1-2-3 superconductor because of the ratios of its constituents. Lanthanum Zirconium Yttrium Barium Calcium Copper Oxide (LaZrYBaCaCuO) was prepared by the usual solid state reaction method. In order to show the viability of the proposed method, super-conducting powder was prepared in special furnace. The sample was analyzed by X-ray Diffraction (XRD), Particle size determination, SEM and EDX. The comparison of XRD results with JCPDS files confirmed the orthorhombic structure of the sample with a ≠ b ≠ c and α = β = γ = 90°. Scanning Electron Microscopy (SEM) studies revealed that its particle size is in the nanometer range. It also confirmed the calculated value of particle size from Debye Scherrer’s formula. EDX spectrum shows the elements of the sample. X-ray instrumental peak broadening analysis was used to evaluate the size and lattice strain by the Williamson-Hall Plot method.
高温超导体是一种陶瓷材料,其中的氧化铜层与含有钡和其他原子的层之间隔开。钇化合物的独特之处在于它具有规则的晶体结构,而镧则被归类为固溶体。钇化合物通常被称为1-2-3超导体,因为它的成分的比例。采用常规固相反应法制备了镧锆钇钡钙氧化铜(LaZrYBaCaCuO)。为了证明该方法的可行性,在专用炉中制备了超导粉末。采用x射线衍射(XRD)、粒度测定、扫描电镜(SEM)和EDX对样品进行了分析。XRD结果与JCPDS文件的对比证实了样品具有a≠b≠c、α = β = γ = 90°的正交结构。扫描电镜(SEM)研究表明,其粒径在纳米级范围内。同时也证实了Debye Scherrer公式计算出的粒径值。EDX光谱显示了样品的元素。采用Williamson-Hall图法,用x射线仪器峰展宽分析评价了材料的尺寸和晶格应变。
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引用次数: 6
Reaction Rate Models for the Thermal Decomposition of Ibuprofen Crystals 布洛芬晶体热分解反应速率模型
Pub Date : 2014-04-03 DOI: 10.4236/JCPT.2014.42010
S. Ramukutty, E. Ramachandran
Kinetics of the decomposition of racemic ibuprofen crystals were studied by non-isothermal analysis. Thermogravimetric analysis revealed that ibuprofen is thermally stable up to 152.6°C and the initial loss of mass was due to evaporation only. Activation energy, pre-exponential factor, activation entropy and Gibbs free energy for the decomposition of ibuprofen were determined using the integral method of Coats-Redfern (CR). Geometrical contraction models were found to be the best fits. The Arrheinus equation for the thermal decomposition of ibuprofen is k = (1.1 × 107) e–79125/RT sec–1.
采用非等温分析方法研究了外消旋布洛芬晶体的分解动力学。热重分析表明,布洛芬在152.6℃时热稳定,初始质量损失仅由蒸发引起。采用Coats-Redfern (CR)积分法测定了布洛芬分解的活化能、指前因子、活化熵和吉布斯自由能。几何收缩模型被发现是最适合的。布洛芬热分解的Arrheinus方程为k = (1.1 × 107) e-79125 /RT sec-1。
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引用次数: 32
Kinetic Study of Non-Isothermal Crystallization in Se 90-x Zn 10 Sb x (x = 0, 2, 4, 6) Chalcogenide Glasses Se 90-x Zn 10 Sb x (x = 0,2,4,6)硫系玻璃非等温结晶动力学研究
Pub Date : 2014-04-03 DOI: 10.4236/JCPT.2014.42014
L. Heireche, M. Heireche, M. Belhadji
Crystallization and glass transition kinetics of Se90-xZn10Sbx (x = 0, 2, 4, 6) chalcogenide glasses prepared by conventional melt-quenching technique were studied under non-isothermal condition using a differential scanning Calorimeter (DSC) measurement at different heating rates 5, 7, 10 and 12°C/min. The glass transition temperatures Tg, the crystallization temperatures Tc and the peak temperatures of crystallization Tp were found to be dependent on the compositions and the heating rates. From the dependence on the heating rates of Tg and Tp, the activation energy for glass transition, Eg, and the activation energy for crystallization, Ec, are calculated and their composition dependence is discussed. The activation energy of glass transition Eg, Avrami index n, dimensionality of growth m and activation energy of crystallization Ec have been determined from different models.
采用差示扫描量热仪(DSC)在非等温条件下研究了传统熔淬法制备的Se90-xZn10Sbx (x = 0,2,4,6)硫系玻璃在5、7、10和12℃/min不同升温速率下的结晶和玻璃化转变动力学。玻璃化转变温度Tg、结晶温度Tc和结晶峰温度Tp与组分和加热速率有关。从Tg和Tp对升温速率的依赖关系出发,计算了玻璃化转变活化能Eg和结晶活化能Ec,并讨论了它们对组分的依赖关系。用不同的模型测定了玻璃化转变活化能Eg、Avrami指数n、生长维数m和结晶活化能Ec。
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引用次数: 6
Remote-Plasma-Assisted Deposition of Pentacene Layer Using Atomic-Hydrogen 原子氢远程等离子体辅助沉积并五苯层
Pub Date : 2014-01-02 DOI: 10.4236/JCPT.2014.41002
S. Yamauchi, T. Minakuchi, Miyuki Onodera
Pentacene thin layers were deposited on Si with the native oxide at 80°C by remote-plasma-assisted deposition (RPAD) using hydrogen-plasma cell to supply atomic hydrogen radicals. The deposition rate was increased by RPAD comparing to that by non-excited hydrogen gas supply whereas thermal evaporation rate of pentacene from crucible was same in the both process. DFM and XRD studies showed the grain laterally grew in the thin film phase with the size above 10 μm by RPAD. First-principles molecular orbital calculations suggested pentacene is evaporated from crucible as the trimer or larger cluster but atomic hydrogen penetrated into the cluster enhances cracking of pentacene clusters to the monomer.
采用远程等离子体辅助沉积(RPAD)技术,在80℃的温度下,利用氢等离子体电池提供原子氢自由基,在Si表面沉积并五苯薄层。与非激发式供氢相比,RPAD法提高了沉积速率,但两种方法对并五苯的热蒸发速率相同。DFM和XRD研究表明,RPAD使晶粒横向生长在尺寸大于10 μm的薄膜相中。第一性原理分子轨道计算表明,并五苯是作为三聚体或更大的团簇从坩埚中蒸发出来的,但原子氢渗透到团簇中,使并五苯团簇裂解为单体。
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引用次数: 0
The Use of Liquid Crystal Thermography in Selected Technical and Medical Applications—Recent Development 液晶热成像技术在特定技术和医学应用中的应用-最新进展
Pub Date : 2014-01-02 DOI: 10.4236/JCPT.2014.41007
J. Stasiek, M. Jewartowski, T. Kowalewski
Thermochromic liquid crystals (TLC) and true-colour digital image processing have been successfully used in non-intrusive technical, industrial and biomedical studies and applications. Thin coatings of TLC at surfaces are utilized to obtain detailed temperature distributions and heat transfer rates for steady or transient processes. Liquid crystals also can be used to make the temperature and velocity fields in liquids visible by the simple expedient of directly mixing the liquid crystal material into the liquid (water, glycerol, glycol, and silicone oils) in very small quantities to use as thermal and hydrodynamic tracers. In biomedical situations, e.g., skin diseases, breast cancer, blood circulation and other medical application, TLC and image processing are successfully used as an additional non-invasive diagnostic method especially useful for screening large groups of potential patients. The history of this technique is reviewed, principal methods and tools are described and some examples are presented. Also steady-state and transient liquid crystal thermography (LCT) is used to measure local heat transfer on a plate equipped with transverse vortex generators. Automated evaluation allows determining the heat transfer coefficient without arbitrary influence of human interpretation.
热致变色液晶(TLC)和真彩色数字图像处理已成功地应用于非侵入式技术,工业和生物医学研究和应用。表面薄层TLC涂层用于获得稳定或瞬态过程的详细温度分布和传热率。通过将液晶材料直接混入液体(水、甘油、乙二醇和硅油)中作为热和流体动力学示踪剂,液晶也可以用来显示液体中的温度和速度场。在生物医学领域,如皮肤病、乳腺癌、血液循环和其他医学应用中,TLC和图像处理被成功地用作一种额外的非侵入性诊断方法,特别适用于筛选大量潜在患者。回顾了该技术的发展历史,介绍了主要的方法和工具,并给出了一些实例。本文还利用稳态和瞬态液晶热像仪(LCT)测量了装有横向涡发生器的平板上的局部传热。自动评估允许确定传热系数没有人为解释的任意影响。
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引用次数: 22
The Polymorphism and Transformation of (3aRS, 4RS, 7RS, 7aSR)-2-(Tricyclo(3.3.1.13,7)decan-1-yl)-4,5,6,7- tetrahydro-4,7-eposyisoindoline-1,3-dione (SU2162)—A Novel Anticancer Compound 新型抗癌化合物(3aRS, 4RS, 7RS, 7aSR)-2-(三环(3.3.1.13,7)癸烷-1-基)-4,5,6,7-四氢-4,7-环氧异吲哚-1,3-二酮(SU2162)的多态性与转化
Pub Date : 2014-01-02 DOI: 10.4236/JCPT.2014.41004
Yuqing Huang, Zaiyou Tan, Lin Luo, Hui Yang, Chunmei Tong, Wenfei Chen, Tingyu Huang, Ruiling Liu
Objective: To determine the transformation between two known crystal forms of the title compound (C18H23NO3, Mr = 301.37). Methods: To recrystallize or heat the crystals and determine the crystal form by testing the melting points. Results: Both the two known crystal forms of the title compound can be changed by dissolving into different organic solvents such as acetone and ethyl acetate. Crystal form I was not influenced by heating while crystal form II can be transformed to crystal form I through melting method. Conclusion: Organic solvents have significant influences on the two crystal forms of title compound. Crystal form I shows a better thermal stability than crystal form II.
目的:确定标题化合物(C18H23NO3, Mr = 301.37)两种已知晶型之间的转变。方法:对结晶进行再结晶或加热,通过测定熔点确定结晶形态。结果:标题化合物的两种已知晶型都可以通过溶解于不同的有机溶剂如丙酮和乙酸乙酯中而改变。晶型I不受加热的影响,而晶型II可通过熔融法转变为晶型I。结论:有机溶剂对标题化合物的两种晶型均有显著影响。晶型I比晶型II表现出更好的热稳定性。
{"title":"The Polymorphism and Transformation of (3aRS, 4RS, 7RS, 7aSR)-2-(Tricyclo(3.3.1.13,7)decan-1-yl)-4,5,6,7- tetrahydro-4,7-eposyisoindoline-1,3-dione (SU2162)—A Novel Anticancer Compound","authors":"Yuqing Huang, Zaiyou Tan, Lin Luo, Hui Yang, Chunmei Tong, Wenfei Chen, Tingyu Huang, Ruiling Liu","doi":"10.4236/JCPT.2014.41004","DOIUrl":"https://doi.org/10.4236/JCPT.2014.41004","url":null,"abstract":"Objective: To determine the transformation between two known crystal \u0000forms of the title compound (C18H23NO3, Mr = 301.37). Methods: To recrystallize or heat the crystals and determine \u0000the crystal form by testing the melting points. Results: Both the two known \u0000crystal forms of the title compound can be changed by dissolving into different \u0000organic solvents such as acetone and ethyl acetate. Crystal form I was not influenced by heating while crystal form II can be transformed to crystal form I through melting method. Conclusion: Organic solvents have significant \u0000influences on the two crystal forms of title compound. Crystal form I shows a better thermal stability than crystal form II.","PeriodicalId":64440,"journal":{"name":"结晶过程及技术期刊(英文)","volume":"04 1","pages":"27-30"},"PeriodicalIF":0.0,"publicationDate":"2014-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70942432","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Single Crystal Growth of Lanthanum(III) Molybdate(VI) (La 4 Mo 7 O 27 ) Using H 3 BO 3 Flux 用h3bo3助熔剂生长钼酸镧(III) (VI) (la4mo7o27)单晶
Pub Date : 2014-01-02 DOI: 10.4236/JCPT.2014.41006
M. Rajalakshmi, R. Indirajith, R. Gopalakrishnan
Single crystals of La4Mo7O27 have been successfully grown by the flux growth method H3BO3 as the flux in a plantium crucible using the starting materials of La2O3, H3BO3 and MoO3 in a molar ratio of 0.16:0.16:0.68, in which H3BO3 acted as a flux. Transparent colorless crystals were obtained with size of 0.8 × 0.3 × 0.2 mm3 under the optimized crystal growth conditions: growth temperature of 727°C, growth time of 95 h and cooling rate of 0.5°C/hr. A well-developed morphology of the crystals was observed and analyzed. The preparation process of starting materials on crystal growth was investigated. The grown crystals were characterized by powder X-ray diffraction (PXRD), EDAX, SEM, UV-Vis, photoluminescence studies, thermal analysis, dielectric studies and second harmonic generation (SHG). The results are presented and discussed.
以La2O3、H3BO3和MoO3为原料,摩尔比为0.16:0.16:0.68,以H3BO3为助熔剂,采用助熔剂生长法在plantium坩埚中成功生长出La4Mo7O27单晶。在生长温度为727℃,生长时间为95 h,冷却速度为0.5℃/hr的条件下,获得了尺寸为0.8 × 0.3 × 0.2 mm3的透明无色晶体。观察和分析了晶体发育良好的形态。研究了晶体生长起始材料的制备工艺。通过粉末x射线衍射(PXRD)、EDAX、SEM、UV-Vis、光致发光研究、热分析、介电介质研究和二次谐波产生(SHG)等手段对生长的晶体进行了表征。给出了实验结果并进行了讨论。
{"title":"Single Crystal Growth of Lanthanum(III) Molybdate(VI) (La 4 Mo 7 O 27 ) Using H 3 BO 3 Flux","authors":"M. Rajalakshmi, R. Indirajith, R. Gopalakrishnan","doi":"10.4236/JCPT.2014.41006","DOIUrl":"https://doi.org/10.4236/JCPT.2014.41006","url":null,"abstract":"Single crystals of La4Mo7O27 have been successfully grown by the flux growth method H3BO3 as the flux in a plantium crucible \u0000using the starting materials of La2O3, H3BO3 and MoO3 in a molar ratio of 0.16:0.16:0.68, in which H3BO3 acted as a flux. Transparent \u0000colorless crystals were obtained with size of 0.8 × 0.3 × 0.2 mm3 under the optimized crystal growth conditions: growth \u0000temperature of 727°C, growth time of 95 \u0000h and cooling rate of 0.5°C/hr. A well-developed morphology of the crystals was \u0000observed and analyzed. The preparation process of starting materials on crystal \u0000growth was investigated. The grown crystals were characterized by powder X-ray \u0000diffraction (PXRD), EDAX, SEM, UV-Vis, photoluminescence studies, thermal analysis, dielectric studies \u0000and second harmonic generation (SHG). The results are presented and discussed.","PeriodicalId":64440,"journal":{"name":"结晶过程及技术期刊(英文)","volume":"4 1","pages":"39-45"},"PeriodicalIF":0.0,"publicationDate":"2014-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70942661","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Study of Intermolecular Interactions in Liquid Crystals: Para-butyl-p’-cyano-biphenyl 液晶分子间相互作用的研究:对丁基-对' -氰基联苯
Pub Date : 2014-01-02 DOI: 10.4236/JCPT.2014.41005
K. K. Dwivedi, M. Dwivedi, S. N. Tiwari
Various characteristics of mesomorphism can be explained using intermolecular interactions between a pair of liquid crystalline molecules. The intermolecular interactions have been calculated considering multipole-multicentere expansion method and modified by second order perturbation treatments. For calculation of multipole i.e. charge, dipole, etc. at each atomic center of molecules, para-butyl-p’-cyano-biphenyl, GAMESS, an ab initio program, with 6-31G* basis set has been used. The stacking, in-plane and terminal interaction energies explain the liquid crystalline behaviour of the system.
中胚性的各种特性可以用一对液晶分子之间的分子间相互作用来解释。采用多极-多中心展开法计算了分子间相互作用,并用二阶微扰处理进行了修正。为了计算分子各原子中心的多极,即电荷、偶极等,采用了6-31G*基集的对丁基-对氰基联苯GAMESS从头算程序。堆积能、面内能和终端相互作用能解释了体系的液晶行为。
{"title":"Study of Intermolecular Interactions in Liquid Crystals: Para-butyl-p’-cyano-biphenyl","authors":"K. K. Dwivedi, M. Dwivedi, S. N. Tiwari","doi":"10.4236/JCPT.2014.41005","DOIUrl":"https://doi.org/10.4236/JCPT.2014.41005","url":null,"abstract":"Various characteristics of mesomorphism can be explained using \u0000intermolecular interactions between a pair of liquid crystalline molecules. The \u0000intermolecular interactions have been calculated considering multipole-multicentere expansion method and modified by second order perturbation treatments. For \u0000calculation of multipole i.e. charge, dipole, etc. at each atomic center of molecules, \u0000para-butyl-p’-cyano-biphenyl, GAMESS, an ab initio program, with 6-31G* basis set has been used. The stacking, in-plane and terminal interaction \u0000energies explain the liquid crystalline behaviour of the system.","PeriodicalId":64440,"journal":{"name":"结晶过程及技术期刊(英文)","volume":"4 1","pages":"31-38"},"PeriodicalIF":0.0,"publicationDate":"2014-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70942492","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Effect of BaTiO 3 Nanoparticle on Electro-Optical Properties of Polymer Dispersed Liquid Crystal Displays batio3纳米颗粒对聚合物分散液晶显示器电光性能的影响
Pub Date : 2014-01-02 DOI: 10.4236/JCPT.2014.41008
M. Darla, S. Hegde, S. Varghese
Ferro nematic suspensions are the prominent materials to enhance the electro optical performance of liquid crystal displays. Electro optical properties of polymer dispersed liquid crystal (PDLC) display with the introduction of Barium Titanate nanoparticles have been investigated in this article and it is shown that there is a considerable enhancement in electro-optical response of the displays. The nanoparticles lower the switch-on electric field and thereby increase the optical transmission at certain voltages of the displays. The electro-optical characteristics of the PDLC cells were investigated with a He-Ne laser followed by MatLab calculations.
铁向列悬浮液是提高液晶显示器电光性能的重要材料。本文研究了钛酸钡纳米颗粒对聚合物分散液晶(PDLC)显示器的电光性能的影响,结果表明,钛酸钡纳米颗粒对聚合物分散液晶显示器的电光响应有显著的提高。纳米颗粒降低了开关电场,从而增加了显示器在特定电压下的光传输。用He-Ne激光器研究了PDLC电池的电光特性,并进行了MatLab计算。
{"title":"Effect of BaTiO 3 Nanoparticle on Electro-Optical Properties of Polymer Dispersed Liquid Crystal Displays","authors":"M. Darla, S. Hegde, S. Varghese","doi":"10.4236/JCPT.2014.41008","DOIUrl":"https://doi.org/10.4236/JCPT.2014.41008","url":null,"abstract":"Ferro nematic suspensions are the prominent \u0000materials to enhance the electro optical performance of liquid crystal \u0000displays. Electro optical properties of polymer dispersed liquid crystal (PDLC) \u0000display with the introduction of \u0000Barium Titanate nanoparticles have been investigated in this article and it is \u0000shown that there is a considerable enhancement in electro-optical response of \u0000the displays. The nanoparticles lower the switch-on electric field and thereby \u0000increase the optical transmission at certain voltages of the displays. The \u0000electro-optical characteristics of the PDLC cells were investigated with a \u0000He-Ne laser followed by MatLab calculations.","PeriodicalId":64440,"journal":{"name":"结晶过程及技术期刊(英文)","volume":"6 1","pages":"60-63"},"PeriodicalIF":0.0,"publicationDate":"2014-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.4236/JCPT.2014.41008","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70943029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 19
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