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2017 IEEE 7th International Conference Nanomaterials: Application & Properties (NAP)最新文献

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MCF-7 breast cancer cell applications of the morpholino grouped p-tert-butylcalixarene nanofibers 对叔丁基杯芳烃纳米纤维在MCF-7乳腺癌细胞中的应用
M. F. Ahmed, Ş. Ertul, F. Ozcan
Calixarenes are good carriers for cations, anions and neutral molecules because they are cyclic, can be easily derivatized, and can create molecular sizes of different sizes. Due to these properties, they have a very wide application area [1]. The use of calixarenes obtained by functioning with different functional groups in the transport and release of drugs takes place in the literature. In this study, p-tert-butylcalix[4]arene derivatives with p-nitrobenzyl functional group and then nanofibers of those new synthesis was obtained by using electrospinning method. Produced calixarene nanofiber primary breast cancer cell application [2,3].
杯芳烃是阳离子、阴离子和中性分子的良好载体,因为它们是环状的,可以很容易地衍生,并且可以产生不同大小的分子。由于这些特性,它们具有非常广泛的应用领域[1]。杯芳烃通过与不同的官能团在药物的转运和释放中发挥作用,在文献中得到了应用。本研究采用静电纺丝法制备了具有对硝基苯官能团的对叔丁基杯[4]芳烃衍生物,并合成了新合成的纳米纤维。杯芳烃纳米纤维在原发性乳腺癌细胞中的应用[2,3]。
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引用次数: 0
Experimental and Industrial Introduction of the Improved Devices to Generate NH4NO3 Granules with Nanoporous Structure 纳米孔结构NH4NO3颗粒制备改进装置的实验与工业介绍
A. Artyukhov, A. Ivaniia
The first results are obtained, which confirm that the formation process of porous ammonium nitrate can be carried out in the drying agent's vortex flow with high intensity. It is proved that combination of humidification and thermal treatment methods of ammonium nitrate granules in the vortex weighted layer allows to get a product with developed nanoporous structure, high indexes of the absorptivity, retentivity and firmness. The nanoporous structure of porous ammonium nitrate granule is studied. It is demonstrated that in order to provide normative indexes of porous ammonium nitrate quality, various structure of the granule surface and inner layers is required. The presented results together with theoretical studies performed earlier in the sphere of flows hydrodynamics and granules porous structure formation thermal dynamics in the twisting flow of the heat transfer agent are bases to investigate technique of vortex granulators' engineering calculation.
初步结果证实了多孔硝酸铵的形成过程可以在干燥剂的高强度涡流中进行。实验证明,在涡流加权层中对硝酸铵颗粒进行加湿和热处理相结合,可以得到纳米孔结构发达、吸收率、保持性和坚固性指标高的产品。研究了多孔硝酸铵颗粒的纳米孔结构。结果表明,为了提供规范的多孔硝酸铵质量指标,需要颗粒表面和内层结构的多样化。本文的研究结果与前人在流体力学和颗粒多孔结构形成热动力学方面的理论研究结果相结合,为研究涡旋造粒机的工程计算技术奠定了基础。
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引用次数: 0
Nanocrystalline states formation in amorphous Fe-B-P-Nb-Cr alloys 非晶Fe-B-P-Nb-Cr合金中纳米晶态的形成
Yevhenii Yarmoshchuk, P. Teselko, M. Semen'ko, T. Mika, V. Nosenko
Several Fe-B-Si-P-Nb-Cr amorphous metallic glasses were produced by a melt spinning technique. The structure, thermal stability and crystallization processes of amorphous alloys were studied. The size distributions of inhomogeneities of both initial and annealed samples were determined.
采用熔融纺丝技术制备了几种Fe-B-Si-P-Nb-Cr非晶态金属玻璃。研究了非晶合金的组织、热稳定性和结晶过程。测定了初始试样和退火试样不均匀性的尺寸分布。
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引用次数: 0
Complex of synthetic 4-thiazolidinone derivatives with PEG-containing polymeric nanocarrier improve of biocompatibility and protects against toxicity in laboratory rats 合成的4-噻唑烷酮衍生物与含聚乙二醇的高分子纳米载体配合物改善了实验大鼠的生物相容性和抗毒性作用
L. Kobylinska, B. Zimenkovsky, R. Panchuk, N. Skorohyd, N. Boiko, R. Stoika, A. Zaichenko
The development of targeted drug delivery using conjugated nanoparticles brings more drug molecules to diseased sites, at the same time reducing the negative side effects of systemic drug exposure. In the present study, the binding capability of the newly developed biocompatible PEG-containing polymeric nanocarrier (PC) was demonstrated. The uptake and cytotoxicity of nanocarrier-immobilized anticancer drugs were enhanced compared to the free drugs. Approximately 10 times lower doses of the PC complexes achieved similar effects as the free form of the drug on cell cycle arrest, DNA damage, and apoptotic cell death (caspase 7 and PARP cleavage). We investigated anticancer effects of the compounds ID3882, ID3288 and ID3833, the drugs Doxorubicin (Dox) and PC complexes containing the compounds ID3882, ID3288 and ID3833 and Dox. PC complexes demonstrated reduced general toxicity, and enhanced anticancer effects in drug-sensitive and drug-resistant tumor cells, therefore improving the outcomes of oncotherapy.
利用缀合纳米颗粒靶向给药的发展使更多的药物分子到达患病部位,同时减少全身药物暴露的负面副作用。本研究证明了新开发的生物相容性聚乙二醇聚合物纳米载体(PC)的结合能力。与游离药物相比,纳米载体固定化抗癌药物的摄取和细胞毒性增强。大约10倍低剂量的PC复合物在细胞周期阻滞、DNA损伤和凋亡细胞死亡(caspase 7和PARP切割)方面取得了与自由形式的药物相似的效果。研究了化合物ID3882、ID3288和ID3833的抗癌作用,以及含有ID3882、ID3288、ID3833和Dox的多柔比星(Dox)药物和PC配合物的抗癌作用。PC复合物显示出总体毒性降低,对药物敏感和耐药肿瘤细胞的抗癌作用增强,因此改善了肿瘤治疗的结果。
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引用次数: 0
Structure and kinetics of the crystallization of oxide films, deposited by laser ablation 激光烧蚀沉积氧化膜的结构和结晶动力学
A. Bagmut, I. Bagmut
It was investigated the kinetics of the electron beam crystallization of amorphous films, deposited with laser sputtering of metals (V, Cr, Hf, Zr) in an oxygen atmosphere. We used methods of electron diffraction and transmission electron microscopy with video recording “in situ” of fast-flowing processes of phase transformations. We have experimentally confirmed the applicability of the method of classification of the crystallization reaction of amorphous films, which is based on structural and morphological principles.
研究了氧气氛下激光溅射金属(V, Cr, Hf, Zr)非晶薄膜的电子束结晶动力学。我们使用电子衍射和透射电子显微镜的方法,并在“现场”录像快速流动的相变过程。实验证实了基于结构和形态原理的非晶膜结晶反应分类方法的适用性。
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引用次数: 1
Nanomaterials for renewable energy economy 纳米材料在可再生能源经济中的应用
Pavlo Mikheenko
Renewal energy economy relies on a range of novel materials for efficient production, distribution and consumption of energy. Nano science is playing increasingly important role in design and production of these materials. Examples of nano applications in energy sector are given following original research on materials for energy economy with focus on transmission of energy. The research is focused on nano-modified superconductors and novel thermo-insulators. A forecast for future activity is given, which is expected to lead to better materials, for example, superconductors with higher critical temperature and/or higher critical current density. The processes and equipment to process nano-materials are also discussed.
再生能源经济依赖于一系列新型材料来实现能源的高效生产、分配和消耗。纳米科学在这些材料的设计和生产中发挥着越来越重要的作用。在对能源经济材料的原始研究之后,给出了纳米在能源部门应用的例子,重点是能源传输。研究的重点是纳米改性超导体和新型热绝缘体。给出了对未来活动的预测,预计将导致更好的材料,例如,具有更高临界温度和/或更高临界电流密度的超导体。讨论了纳米材料的加工工艺和设备。
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引用次数: 1
The study of photoelectrochemical water splitting by ZnO nanostructures and ZnO/Ag nanocomposites ZnO纳米结构及ZnO/Ag纳米复合材料的光电化学水分解研究
N. Bakranov, M. Aldabergenov, N. Ibrayev, K. Abdullin, S. Kudaibergenov
Zinc oxide is an interesting material for the fabrication on its basis photoelectrodes for photoelectrochemical cells. In this paper, the main results of the electrochemical deposition of two different morphologies — nanorods and nanosheets of zinc oxide onto transparent conductive substrate and their further modification by Ag nanoparticles are presented. Crystal, optical and morphological structures of synthesized coatings were investigated by XRD, PL and SEM methodologies. The influence of pristine ZnO nanostructures and ZnO/Ag nanocomposites on PEC process is shown. Photoelectrochemical activity of obtained materials is demonstrated on J-T curves.
氧化锌是在其基础上制备光电化学电池光电极的一种有趣材料。本文介绍了在透明导电衬底上电化学沉积两种不同形貌的氧化锌纳米棒和纳米片的主要结果,并对其进行了银纳米粒子的进一步改性。采用XRD、PL和SEM等方法对合成涂层的晶体结构、光学结构和形貌进行了表征。研究了原始ZnO纳米结构和ZnO/Ag纳米复合材料对PEC过程的影响。所得材料的光电化学活性用J-T曲线表示。
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引用次数: 5
Detection properties of individual and networked CNT-ZnO-hybrid tetrapods 单个和网络化cnt - zno杂交四足动物的检测特性
V. Postica, O. Lupan, V. Sontea, V. Trofim, F. Schütt, D. Smazna, Y. K. Mishra, R. Adelung
In this work, the UV detection properties of ZnO tetrapod (ZnO-T) networks functionalized with carbon nanotubes (CNTs), as well as for individual ZnO-T-CNT are reported. The ZnO-T networks were fabricated via a flame transport synthesis (FTS) approach, while hybridization with CNTs was performed by a simple dripping procedure using a commercially available aqueous CNT dispersion (CarboByk 9810). The amount of CNT in the hybrid material was varied in the range of 0.8–4.0 wt% CNTs. While hybrid networks demonstrated inferior UV sensing performances compared to pristine ZnO-T networks, the individual ZnO-T-CNT showed more improved performances, even compared to individual ZnO-T. The fabricated microsensor showed an UV response of ∼ 700 at 3 V applied bias voltage. The calculated time constants for rising and decaying photocurrent are also lower compared to individual ZnO-T. These results are quite promising for high performance optoelectronic applications, especially for UV photodetectors, demonstrating the high efficiency of hybridization.
在这项工作中,报告了碳纳米管(CNTs)功能化的ZnO四足体(ZnO- t)网络以及单个ZnO- t - cnt的紫外检测性能。ZnO-T网络通过火焰传递合成(FTS)方法制备,而与碳纳米管的杂交是通过使用市售的含水碳纳米管分散体(CarboByk 9810)通过简单的滴注过程进行的。杂化材料中碳纳米管的含量在0.8-4.0 wt% CNTs之间变化。虽然与原始ZnO-T网络相比,混合网络表现出较差的紫外传感性能,但单独的ZnO-T- cnt表现出更多的改进性能,甚至与单独的ZnO-T相比。制备的微传感器在施加3v偏置电压时显示出约700的紫外响应。与单个ZnO-T相比,计算得到的上升和衰减光电流的时间常数也更低。这些结果对高性能光电应用,特别是紫外光电探测器的应用具有很大的前景,证明了杂化的高效率。
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引用次数: 0
Use of calix[4]arene nanofibers in the treatment of MCF-7 breast cancer cells 杯[4]芳烃纳米纤维在MCF-7乳腺癌细胞治疗中的应用
Ş. Ertul, F. Ozcan
Synthesis of the p-tert-butylcalixarene compound with the amino group was carried out as given in Figure 1. The structure of the calixarene compound with the amino group was elucidated by 1H-NMR, FT-IR. After the synthesized compound was prepared in a suitable solvent medium, the nanofibers were withdrawn by electrospinning. The characterization of the nanofibers was performed by SEM.
含氨基的对叔丁基杯芳烃化合物的合成如图1所示。用1H-NMR、FT-IR等手段对含氨基杯芳烃化合物的结构进行了表征。将合成的化合物在合适的溶剂介质中制备后,采用静电纺丝法提取纳米纤维。利用扫描电镜对纳米纤维进行了表征。
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引用次数: 0
Characterization of a polydimethylsiloxane-polythiourethane polymer blend with potential as fouling-release coating 具有防污涂料潜力的聚二甲基硅氧烷-聚硫脲共混物的表征
A. Gapeeva, Iris Hölken, R. Adelung, Martina Baum
Developing reliable and long-lasting antifouling coatings is a most challenging task, because the mechanisms of interactions between a solid surface and the aquatic environment including all abiotic and biotic entities are incredible various. Currently there are some working strategies, but all of them have their disadvantages like negative environmental impact or mechanical instability. The aim of this study is to combine the desirable mechanical stability of the environmentally friendly polymer matrix, PTU, and the fouling-release properties of PDSM in a polymer blend with potential for large-scale applications within the maritime sector. The material, surface and fouling-release properties of the PDMS/PTU blend with varying content of PDMS were characterized and promising properties were found.
开发可靠和持久的防污涂层是一项最具挑战性的任务,因为固体表面与水生环境(包括所有非生物和生物实体)之间的相互作用机制非常多样。目前有一些工作策略,但都有其缺点,如负面的环境影响或机械不稳定。本研究的目的是将环境友好型聚合物基质PTU的理想机械稳定性和PDSM的污垢释放特性结合在聚合物混合物中,并具有在海事部门大规模应用的潜力。对不同PDMS含量的PDMS/PTU共混物的材料性能、表面性能和脱垢性能进行了表征,发现其具有良好的性能。
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引用次数: 6
期刊
2017 IEEE 7th International Conference Nanomaterials: Application & Properties (NAP)
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