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Study of Gd/Co Multilayers with Different Cobalt Layer Thickness Values 不同钴层厚度值的钆/钴多层膜研究
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-31 DOI: 10.1007/s10948-024-06823-5
Smritiparna Ghosh, Rakhul Raj, Manik Kuila, Zainab Hussain, Dileep Kumar, Mukul Gupta, V.Raghavendra Reddy

The present work reports the magnetic and structural behavior of [Gd/Co]10 multilayers with different Co thickness values, prepared by magnetron sputtering, as a function of thermal annealing. Intermixing is observed with thermal annealing for all the samples; however, complete intermixing is not observed even after annealing at 773 K. Antiparallel alignment of Gd and Co layer magnetization is observed for pristine samples from room temperature X-ray magnetic circular dichroism measurements. Magnetic compensation temperature is found to vary depending on the thickness of Co layers. Temperature-dependent magneto-optical Kerr effect (MOKE) measurements depict the inversion of loops across magnetic compensation temperature for all the pristine samples. However, no signatures of magnetic compensation are observed in the low-temperature MOKE loops for the annealed samples. MOKE loops of the annealed samples exhibit double hysteresis loops. The results are explained in terms of intermixing with annealing.

本研究报告了通过磁控溅射法制备的具有不同 Co 厚度值的 [Gd/Co]10 多层膜的磁性和结构行为与热退火的函数关系。通过室温 X 射线磁性圆二色性测量,观察到原始样品的钆层和钴层磁化反平行排列。磁补偿温度随 Co 层厚度的变化而变化。与温度相关的磁光克尔效应(MOKE)测量结果表明,所有原始样品在磁补偿温度下都会出现磁环反转。然而,在退火样品的低温 MOKE 环路中没有观察到磁补偿的迹象。退火样品的 MOKE 回路呈现双磁滞回线。这些结果可以用退火时的混杂现象来解释。
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引用次数: 0
Lepidagathis ananthapuramensis Leaf Extract Stabilized Co3O4 Nanoparticles and its Structural, Optical and Magnetic Properties Lepidagathis ananthapuramensis 叶提取物稳定的 Co3O4 纳米粒子及其结构、光学和磁学特性
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-29 DOI: 10.1007/s10948-024-06817-3
K. K. Supin, M. Vasundhara

The present work focusses on the green synthesis of Co3O4 nanoparticles (NPs) using Lepidagathis ananthapuramensis leaf extract and to investigate its structural, optical, morphological and magnetic properties. The structural information confirmed the formation of spinel type polycrystalline cubic symmetry with space group Fd-3 m. The Fourier transform infrared spectroscopic studies revealed the sharp doublet peak in the finger print region pertaining to the Co2+ and Co3+ ions. The X-ray photoelectron spectroscopy further confirmed the presence of Co3+ and Co2+ ions in which Co3+ ions are present more than Co2+ ions. The UV–Visible spectroscopic studies indicate that there are two characteristic absorptions of Co3O4 NPs indicating the ligand to metal charge transfer. The morphological analysis of Co3O4 NPs using field emission scanning microscope and high-resolution transmission electron microscopy, showed irregular shapes of different sizes with Co mostly at surface than the core. The magnetic data revealed the existence of antiferromagnetic nature co-hosting weak ferromagnetism. The detailed explanations of a straightforward and affordable method for creating spinel type Co3O4 and their structural and magnetic properties were explained.

本研究的重点是利用 Lepidagathis ananthapuramensis 叶提取物绿色合成 Co3O4 纳米粒子(NPs),并研究其结构、光学、形态和磁性能。傅立叶变换红外光谱研究显示,在指纹区出现了与 Co2+ 和 Co3+ 离子有关的尖锐双峰。X 射线光电子能谱进一步证实了 Co3+ 和 Co2+ 离子的存在,其中 Co3+ 离子的含量高于 Co2+ 离子。紫外-可见光谱研究表明,Co3O4 NPs 有两种特征吸收,表明配体与金属之间存在电荷转移。利用场发射扫描显微镜和高分辨率透射电子显微镜对 Co3O4 NPs 进行的形态分析表明,它们具有不同大小的不规则形状,Co 大多位于表面而非核心。磁性数据显示,存在反铁磁性与弱铁磁性共存的现象。此外,还详细解释了一种直接且经济实惠的制造尖晶石型 Co3O4 的方法,以及它们的结构和磁性能。
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引用次数: 0
The Origin of the Dirac Linear Spectrum and a Study on the Topological Bilayers 狄拉克线性谱的起源与拓扑双层膜研究
IF 1.8 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-28 DOI: 10.1007/s10948-024-06819-1
Mauro M. Doria, Edinardo I. B. Rodrigues

We propose that the linear Dirac spectrum and the Rashba interaction, two important features of the topological insulators, have a common origin rooted on the well-known non-relativistic Schrödinger kinetic energy for fermions subject to the spin-momentum locking condition described here. This approach yields that the quasi-particles with linear Dirac spectrum are skyrmions, namely, three-dimensional vortices with topological charges surrounded by a residual local magnetic field. Within this framework, the spectrum of topological bilayers is obtained and shown for a small wave number to have two branches, one quadratic and the other linear but with twice the velocity of the single layer case.

我们提出,拓扑绝缘体的两个重要特征--线性狄拉克谱和拉什巴相互作用--有一个共同的起源,即费米子在自旋动量锁定条件下的著名非相对论薛定谔动能。这种方法得出,具有线性狄拉克谱的准粒子是skyrmions,即具有拓扑电荷的三维涡旋,被残余局部磁场包围。在此框架内,得到了拓扑双电层的频谱,并证明在波数较小的情况下,拓扑双电层有两个分支,一个是二次分支,另一个是线性分支,但速度是单层的两倍。
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引用次数: 0
Spin Susceptibility of Helical Carbon-Based Nanostructures with Almost Filled Band and Spin-Orbit Coupling 具有几乎填充带和自旋轨道耦合的螺旋碳基纳米结构的自旋易感性
IF 1.8 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-22 DOI: 10.1007/s10948-024-06820-8
Barbara Montañes, Pábel Machado, Ernesto Medina, Ismardo Bonalde

Some theoretical studies using perturbation and tight-binding methods have tried to shed light on the magnetic behaviors of carbon-based nanostructures in the limit of wave vector (mathbf {q=0}). In a recent work, we studied a half-filled model of helical carbon chains to gain new insights for (mathbf {q ne 0}). Although in carbon the energy bands are usually derived from partially filled atomic p-shells, here we explore the hole contribution to these magnetic responses. We calculate the longitudinal spin susceptibility of an almost-filled tight-binding model of a helical chain for (mathbf {qne 0}). We find that when the Fermi level lies at the band edges, the system shows for positive chirality a divergent paramagnetic susceptibility. This result is in agreement with that previously reported for the macroscopic limit (mathbf {q=0}).

一些理论研究使用扰动和紧密束缚方法试图揭示碳基纳米结构在波矢量(mathbf {q ne 0})极限下的磁性行为。在最近的一项工作中,我们研究了螺旋碳链的半填充模型,从而获得了对(mathbf {q ne 0}) 的新见解。虽然在碳中能带通常来自部分填充的原子 p 壳,但在这里我们探索了空穴对这些磁响应的贡献。我们计算了一个几乎充满的螺旋链紧结合模型的纵向自旋感性(mathbf {qne 0})。我们发现,当费米级位于带边缘时,系统对正手性显示出发散的顺磁感应强度。这一结果与之前报道的宏观极限 (mathbf {q=0}) 的结果一致。
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引用次数: 0
Tuning the Magnetoimpedance, Magnetoresistance, and Magnetoinductance of Melt-Spun Ribbons 调谐熔融纺丝带的磁阻、磁阻和磁感应强度
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-21 DOI: 10.1007/s10948-024-06818-2
M. Inchara, D. Arvindha Babu, Ganesh Kotagiri

Magnetoresistance (MR), magnetoinductance (mi), and magnetoimpedance (MI) studies on the as-quenched and annealed Fe72Si10Cu1Nb2B15, Co72Ni5Si5Cu1Nb2B15, and Co77Si5Cu1Nb2B15 ribbons have been carried out in the present investigation. Structural studies indicate that all as-quenched samples are in the amorphous phase. The asymmetry in the MI, MR, and mi curves is noticed and is attributed to induced magnetocrystalline anisotropy and hysteretic magnetization. Among all three samples, the Co77Si5Cu1Nb2B15 ribbons exhibit the highest magnetization and MI values. The development of a strong transverse magnetic anisotropy upon annealing has been observed in the Co77Si5Cu1Nb2B15 ribbons, while such features are not observed in other cases. The present study shows that 5% Ni substitution in Co77Si5Cu1Nb2B15 samples significantly reduces the transverse anisotropy, indicating that the transverse anisotropy can be tuned through Ni substitution.

本研究对淬火和退火的 Fe72Si10Cu1Nb2B15、Co72Ni5Si5Cu1Nb2B15 和 Co77Si5Cu1Nb2B15 晶带进行了磁阻(MR)、磁感应强度(mi)和磁阻(MI)研究。结构研究表明,所有淬火样品都处于非晶相。注意到 MI、MR 和 mi 曲线的不对称性,这归因于诱导磁晶各向异性和滞后磁化。在所有三种样品中,Co77Si5Cu1Nb2B15 晶带的磁化率和 MI 值最高。Co77Si5Cu1Nb2B15 晶带在退火后出现了较强的横向磁各向异性,而在其他情况下则没有观察到这种特征。本研究表明,Co77Si5Cu1Nb2B15 样品中 5% 的镍替代能显著降低横向各向异性,这表明横向各向异性可通过镍替代进行调整。
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引用次数: 0
Investigation of Strong Tailored Magnetocaloric Effect in Ba(Fe1-xScx)12O19 研究 Ba(Fe1-xScx)12O19 中的强定制磁ocaloric 效应
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-20 DOI: 10.1007/s10948-024-06815-5
Mahmoud A. Hamad, Hatem R. Alamri

By simulating the thermomagnetization of Ba(Fe1-xScx)12O19 from approximately 100 to 750 K, the magnetocaloric effect (MCE) in Ba(Fe1-xScx)12O19 samples is approximated. Intriguingly, the thermomagnetic property of the undoped sample BaFe12O19 is described as a conventional MCE for high temperatures. However, at doping levels x of 0.128, 0.153, and 0.189, respectively, the thermomagnetic property of Sc-doped samples is defined as an inverse MCE below temperatures of 163, 239, and 318 K. In contrast, thermomagnetic property of Ba(Fe1-xScx)12O19 is described as conventional MCE above those temperatures. Additionally, Sc doping makes it possible for MCE in Ba(Fe1-xScx)12O19 to be strongly tailored. This is helpful for operating a magnetic refrigerator (MR) which occurs in various temperature ranges and results in a higher working temperature range. A promising function for Ba(Fe1-xScx)12O19 samples in MR at high-temperature applications in the automotive and food industries or aerospace.

通过模拟 Ba(Fe1-xScx)12O19 在大约 100 至 750 K 的热磁化过程,近似地描述了 Ba(Fe1-xScx)12O19 样品中的磁致效应 (MCE)。耐人寻味的是,未掺杂样品 BaFe12O19 的热磁性能被描述为高温下的传统 MCE。然而,当掺杂水平 x 分别为 0.128、0.153 和 0.189 时,掺 Sc 样品的热磁性能在低于 163、239 和 318 K 的温度下被定义为反 MCE。此外,掺杂 Sc 使 Ba(Fe1-xScx)12O19 中的 MCE 具有很强的定制性。这有助于在各种温度范围内操作磁制冷机(MR),从而获得更高的工作温度范围。Ba(Fe1-xScx)12O19样品在汽车、食品工业或航空航天等高温应用领域的磁制冷器中的功能前景广阔。
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引用次数: 0
Enhancement of Coercivity in α-Mn(Al) Magnetic Nanopowders Processed by High-Energy Ball Milling 高能球磨法加工的 α-锰(铝)磁性纳米粉体矫顽力的增强
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-17 DOI: 10.1007/s10948-024-06816-4
P. Saraswathi, S. Madeswaran, S. Subhavenkadesh, R. Ezhil Vizhi, D. Rajan Babu

We report the achievement of a high coercivity (Hc) value of 3 kOe for Mn54Al46 powders produced by high-energy ball milling without any heat treatment. The ferromagnetic α-Mn(Al) alloy powders were prepared with Mn (54 at%) and Al (46 at%) as the constituent metal elements. Analysis and discussion were held regarding the potential causes of the observed enhancement in the magnetic properties of the ball-milled powders in relation to their phase composition and microstructure. The process of milling causes partial solubilisation of Al atoms in the α-Mn phase and a change in the powder magnetic characteristics from paramagnetic to ferromagnetic. The existence of γ2 and β phases was identified by XRD after long hours of the milling process. In addition, it was found that a longer milling time resulted in a smaller crystallite size, which also resulted in a decrease in magnetic saturation (Ms) but an increase in coercivity (HC). Without applying any extra heat treatment, the Mn-Al powders milled for 6 h had optimum magnetic properties: Hc = 3.0 kOe, Mr = 0.05 emu/g, Ms = 0.19 emu/g, and (BH)max = 432 J/m3.

我们报告了通过高能球磨法生产的 Mn54Al46 粉末在未进行任何热处理的情况下实现了 3 kOe 的高矫顽力 (Hc)。铁磁性α-Mn(Al)合金粉末是以锰(54%)和铝(46%)为组成金属元素制备的。分析和讨论了观察到的球磨粉末磁性增强的潜在原因与其相组成和微观结构的关系。研磨过程导致 Al 原子在 α-Mn 相中部分溶解,粉末磁性特征从顺磁性变为铁磁性。在长时间的研磨过程后,XRD 发现了 γ2 和 β 相的存在。此外,研磨时间越长,结晶尺寸越小,磁饱和度(Ms)降低,但矫顽力(HC)增加。在不进行任何额外热处理的情况下,研磨 6 小时的锰铝粉末具有最佳磁性能:Hc = 3.0 kOe,Mr = 0.05 emu/g,Ms = 0.19 emu/g,(BH)max = 432 J/m3。
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引用次数: 0
Bethe’s Wave-Function Revisited 重温贝特的波函数
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-14 DOI: 10.1007/s10948-024-06814-6
Jacob Szeftel, Jean-Claude Lévy

The scattering eigenstates of any Hamiltonian of electrons, coupled through a two-body force and moving on a one-dimensional lattice, are shown to be Bethe’s wave-functions. The energy of the groundstate is compared with values, obtained previously for the Hubbard Hamiltonian thanks to another Bethe’s wave-function-based procedure and within the framework of the correlated Fermi gas. The same analysis is applied to electrons, interacting on neighbouring sites. The significance of those various groundstates is assessed with help of thermodynamics.

通过二体力耦合并在一维晶格上运动的任何电子哈密顿的散射特征状态都被证明是贝特波函数。基态能量与之前通过另一种基于贝特波函数的程序并在相关费米气体框架内获得的哈伯德哈密顿的能量值进行了比较。同样的分析也适用于在相邻位点上相互作用的电子。在热力学的帮助下,对这些不同基态的重要性进行了评估。
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引用次数: 0
Green-Synthesized Cobalt Ferrite Nanoparticle Alleviated Sodium Nitrite-Induced Oxidative Stress Through Its Anti-oxidant Property and Displayed Anti-inflammatory, Anti-diabetic and Anti-platelet Activities 绿色合成的铁氧体钴纳米粒子通过抗氧化特性缓解亚硝酸钠诱导的氧化应激,并显示出抗炎、抗糖尿病和抗血小板活性
IF 1.8 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-13 DOI: 10.1007/s10948-024-06813-7
Shivakumar Venkataramaiah, Manjula M. Venkatappa, Chikkappa Udagani, Devaraja Sannaningaiah

The present study unveils the Decalepis hamiltonii leaves extract mediated biosynthesis of cobalt ferrite nanoparticles (DHLE.CoFe2O4 NPs) and its role on oxidative stress-induced inflammation, thrombosis and diabetes. DHLE.CoFe2O4 NPs were characterized using various techniques such as PXRD, FTIR, SEM, EDAX, HR-TEM and VSM. DHLE.CoFe2O4 NPs revealed irregular polygonal shapes with uneven distribution of particles with an average size of 19.13 nm. The DHLE.CoFe2O4 NPs displayed considerable anti-oxidant activity by scavenging DPPH free radical about 60.35% at 150 µg/mL concentration with an IC50 value of 54.18 µg/mL. Similarly, DHLE.CoFe2O4 NPs reduced 744.06 µM ferric ions at the concentration of 150 µg/mL with an IC50 value of 44.08 µg/mL. DHLE.CoFe2O4 NPs were non-toxic to RBCs and exhibited anti-oxidant property by regulating the stress markers such as LPO, PCC, TT, and anti-oxidant enzymes like CAT and SOD activities in NaNO2-induced oxidative stress in RBCs model. Furthermore, DHLE.CoFe2O4 NPs were found to protect the RBCs’ membrane by inhibiting the hypo-tonicity and heat-induced hemolysis suggesting its anti-hemolytic activity. Furthermore, DHLE.CoFe2O4 NPs exhibited fair anti-inflammatory property that was tested using egg albumin, BSA denaturation and proteinase inhibition assays. In addition, DHLE.CoFe2O4 NPs inhibited α-amylase (46.45%) and α-glucosidase (48.66%) activity respectively and revealed its anti-diabetic property. Most importantly, DHLE.CoFe2O4 NPs showed anti-platelet activity by inhibiting both ADP and epinephrine-induced platelet aggregation with an inhibition percentage of 58.73 and 63.88, respectively. In conclusion, DHLE.CoFe2O4 NPs appear to be a good candidate in regulating oxidative stress-induced, inflammation, haemolysis, diabetes and thrombosis.

本研究揭示了Decalepis hamiltonii叶提取物介导的钴铁氧体纳米粒子(DHLE.CoFe2O4 NPs)的生物合成及其对氧化应激诱导的炎症、血栓形成和糖尿病的作用。DHLE.CoFe2O4 NPs 的表征采用了多种技术,如 PXRD、FTIR、SEM、EDAX、HR-TEM 和 VSM。DHLE.CoFe2O4 NPs呈不规则多边形,颗粒分布不均,平均粒径为19.13 nm。DHLE.CoFe2O4 NPs 具有相当高的抗氧化活性,在 150 µg/mL 浓度下可清除 60.35% 的 DPPH 自由基,IC50 值为 54.18 µg/mL。同样,DHLE.CoFe2O4 NPs 在 150 µg/mL 浓度下可减少 744.06 µM 铁离子,IC50 值为 44.08 µg/mL。DHLE.CoFe2O4 NPs对红细胞无毒,并在NaNO2诱导的红细胞氧化应激模型中通过调节应激标志物(如LPO、PCC、TT)和抗氧化酶(如CAT和SOD)的活性表现出抗氧化特性。此外,DHLE.CoFe2O4 NPs 还能通过抑制低张性和热诱导溶血来保护红细胞膜,这表明它具有抗溶血活性。此外,DHLE.CoFe2O4 NPs 还表现出良好的抗炎特性,这是用鸡蛋白蛋白、BSA 变性和蛋白酶抑制实验测试的结果。此外,DHLE.CoFe2O4 纳米粒子还分别抑制了α-淀粉酶(46.45%)和α-葡萄糖苷酶(48.66%)的活性,显示了其抗糖尿病特性。最重要的是,DHLE.CoFe2O4 NPs 具有抗血小板活性,能抑制 ADP 和肾上腺素诱导的血小板聚集,抑制率分别为 58.73% 和 63.88%。总之,DHLE.CoFe2O4 NPs 似乎是调节氧化应激诱导的炎症、溶血、糖尿病和血栓形成的良好候选物质。
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引用次数: 0
Evolution of Magnetic Properties with Structure and Morphology of Co/Alq3 Bilayer: A Thickness Dependent Study Co/Alq3 双电层磁性随结构和形态的变化:厚度依赖性研究
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-08-09 DOI: 10.1007/s10948-024-06812-8
Manisha Priyadarsini, Sonia Kaushik, Arun Singh Dev, Sharanjeet Singh, Pooja Gupta, Matthias Schwartzkopf, Stephan V. Roth, V. Raghavendra Reddy, Dileep Kumar

Organic spintronics (OS), which focuses on utilizing the spin degree of freedom in organic materials, has been a fascinating topic because of its technological aspects and future applications. In-plane uniaxial magnetic anisotropy (UMA) is becoming increasingly important in the rapidly developing field of OS. In this study, Cobalt (Co) films were deposited with varying thicknesses on the Tris (8-hydroxyquinolinato) aluminium (Alq3) layer to investigate the evolution of magnetism and UMA. Magnetic measurements and simultaneous domain imaging have been done using the magneto-optic Kerr effect by varying the azimuthal angle between the easy axis of magnetization and the applied magnetic field. It was discovered that the bilayer exhibits a well-defined UMA in the film plane upon forming a continuous Co film with a thickness of around 10 nm. Structural and morphological properties of all the Co/Alq3 bilayers were studied using grazing-incidence small-angle X-ray scattering and wide-angle X-ray scattering measurements at synchrotron radiation source, P03 beamline PETRA-III, Germany. The combined analysis revealed that in contrast to the inorganic magnetic polycrystalline thin films, where the UMA originates mainly due to the stress, the origin of UMA in Co/Alq3 is attributed to the magnetocrystalline anisotropy caused by c-axis (Co (002)) preferential orientation. The surface free energy of Alq3 is less than that of Co; therefore, the growth of Co starts with island formation, which coalescences with increasing thickness. The observed structure orientation may be attributed to minimizing the magnetoelastic energies due to coalescence known as the zipping effect. The absence of UMA in films with lower thickness film (~5 nm) is understood in terms of random short-range stress caused by isotropic pinning due to the diffused interface.

有机自旋电子学(OS)侧重于利用有机材料中的自旋自由度,因其技术层面和未来应用而一直是一个引人入胜的话题。在快速发展的有机自旋电子学领域,面内单轴磁各向异性(UMA)正变得越来越重要。本研究在三(8-羟基喹啉)铝(Alq3)层上沉积了不同厚度的钴(Co)薄膜,以研究磁性和 UMA 的演变。通过改变易磁化轴与外加磁场之间的方位角,利用磁光克尔效应进行了磁性测量和同步畴成像。结果发现,在形成厚度约为 10 纳米的连续 Co 薄膜后,双层膜在薄膜平面上呈现出定义明确的 UMA。在德国同步辐射光源 PETRA-III P03 光束线使用掠入射小角 X 射线散射和广角 X 射线散射测量法研究了所有 Co/Alq3 双层膜的结构和形态特性。综合分析表明,与无机磁性多晶薄膜的 UMA 主要源于应力不同,Co/Alq3 的 UMA 源于 c 轴(Co (002))优先取向引起的磁晶各向异性。Alq3 的表面自由能小于 Co 的表面自由能;因此,Co 的生长从岛的形成开始,并随着厚度的增加而凝聚。观察到的结构取向可归因于将凝聚产生的磁弹性能量最小化,这就是所谓的 "拉链效应"。厚度较低的薄膜(约 5 nm)中没有 UMA,这可以理解为扩散界面导致的各向同性引脚引起的随机短程应力。
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引用次数: 0
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Journal of Superconductivity and Novel Magnetism
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