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Structural, Magnetic, Dielectric and Ferroelectric Properties of B-site Doped LaNiO3 Half Metals b位掺杂LaNiO3半金属的结构、磁性、介电和铁电性质
IF 1.7 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-12-16 DOI: 10.1007/s10948-025-07085-5
Roshima N S, Jyotirmayee Satapathy, M. Sivakumar

This study reports the synthesis of pure and transition metal doped at the Ni-site of LNO perovskites using solid-state reaction route. Various characterization techniques such as X-ray diffraction (XRD), High Resolution Transmission Electron Microscopy (HR-TEM), Raman spectroscopy, Vibrating Sample Magnetometer (VSM), dielectric spectroscopy and ferroelectric (P-E loop) tests are employed to explore the influence of transition metal ions, i.e. Cr, Fe and Mn on the Ni-site of pure LNO samples. The structure is reported to be distorted rhombohedral phase, with a better phase purity for Fe-LNO comparatively. The average crystallite sizes calculated for pure LNO, Cr-LNO, Fe-LNO and Mn-LNO are 6.59 nm, 10.96 nm, 9.15 nm, and 12.67 nm respectively. HR-TEM reveals that the corresponding grain sizes are approximately 230 nm, 210 nm, 240 nm and 280 nm. Raman spectra exhibit five active vibrational modes, and noticeable blue shift in the doped samples, attributing to the compressive lattice strain. Magnetic characterization by VSM demonstrates weak ferromagnetism in Cr-doped LNO, soft magnetic behavior in Fe -doped LNO, and antiferromagnetic characteristics in Mn-doped LNO. Dielectric measurements show an increase and decrease in dielectric constant and loss for Mn and Fe doped LNOs compared to pure and Cr doped LNO. Dielectric properties with frequency show a slight relaxor behavior. The P-E hysteresis loops however are unsaturated, lossy and lack spontaneous polarization, indicating no evidence for ferroelectric behavior in all the samples.

本研究报道了采用固相反应的方法在LNO钙钛矿的ni位点掺杂纯金属和过渡金属。采用x射线衍射(XRD)、高分辨率透射电镜(HR-TEM)、拉曼光谱(Raman spectroscopy)、振动样品磁强计(VSM)、介电光谱(dielectric spectroscopy)、铁电(P-E loop)等多种表征技术,探讨了过渡金属离子Cr、Fe、Mn对纯LNO样品ni位的影响。结果表明,Fe-LNO的结构为畸变菱形相,相对而言具有较好的相纯度。纯LNO、Cr-LNO、Fe-LNO和Mn-LNO的平均晶粒尺寸分别为6.59 nm、10.96 nm、9.15 nm和12.67 nm。hrtem结果表明,相应的晶粒尺寸分别为230 nm、210 nm、240 nm和280 nm。拉曼光谱表现出五种活跃的振动模式,并且在掺杂样品中存在明显的蓝移,这归因于压缩晶格应变。通过VSM进行的磁性表征表明,cr掺杂的LNO具有弱铁磁性,Fe掺杂的LNO具有软磁性,mn掺杂的LNO具有反铁磁性。电介质测量表明,与纯LNO和Cr掺杂LNO相比,Mn和Fe掺杂LNO的介电常数和损耗有所增加和减少。介电特性随频率变化表现出轻微的弛豫特性。然而,P-E磁滞回线是不饱和的,有损耗的,缺乏自发极化,表明在所有样品中没有铁电行为的证据。
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引用次数: 0
Thermopower and Hall Effect in Correlated Metals and Doped Mott-Hubbard Insulators: DMFT Approximation 相关金属和掺杂Mott-Hubbard绝缘体的热功率和霍尔效应:DMFT近似
IF 1.7 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-12-16 DOI: 10.1007/s10948-025-07108-1
E. Z. Kuchinskii, N. A. Kuleeva

We present brief review of theoretical studies of thermopower and Hall effect in the Hubbard model within the DMFT approximation for correlated metal and Mott insulator (considered as prototype cuprate superconductor) for different concentrations of current carriers. Analysis is performed within standard DMFT approximation. For Mott insulator we consider the typical case of partial filling of the lower Hubbard band (hole doping). We calculate the dependence of the Hall coefficient and thermopower on doping level and determine the critical concentration of carriers corresponding to sign change of these quantities. A significant temperature dependence of the Hall coefficient and an anomalous dependence of thermopower on temperature (significantly different from linear typical for the usual metals) is obtained. The role of disorder scattering is analyzed on qualitative level. We also perform a comparison of our theoretical results with some known experiments on doping dependence of Hall number in the normal state of YBCO and Nd-LSCO, demonstrating rather satisfactory agreement of theory and experiment. Violation of electron-hole symmetry leads to the appearance of the relatively large interval of band-fillings (close to the half-filling) where thermopower and Hall effects have different signs. We propose a certain scheme allowing to determine the number of carriers from ARPES data and perform semi-quantitative estimate of both thermopower and Hall coefficient using the usual DFT calculations of electronic spectrum.

本文简要回顾了不同载流子浓度下相关金属和莫特绝缘体(被认为是原型铜超导体)在DMFT近似内的Hubbard模型中的热功率和霍尔效应的理论研究。分析是在标准DMFT近似内进行的。对于莫特绝缘子,我们考虑下哈伯德带部分填充的典型情况(空穴掺杂)。我们计算了霍尔系数和热功率与掺杂水平的关系,并确定了与这些量的符号变化相对应的载流子的临界浓度。得到了霍尔系数的显著温度依赖性和热功率对温度的反常依赖性(明显不同于通常金属的线性典型)。定性地分析了无序散射的作用。我们还将我们的理论结果与一些已知的YBCO和Nd-LSCO正常状态下霍尔数的掺杂依赖性实验进行了比较,证明了理论和实验的一致性。电子-空穴对称的破坏导致出现相对较大的带填充间隔(接近半填充),其中热电和霍尔效应具有不同的符号。我们提出了一个特定的方案,允许从ARPES数据中确定载流子的数量,并使用电子谱的通常DFT计算对热功率和霍尔系数进行半定量估计。
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引用次数: 0
The Magnetocaloric Effect in Mesoscopic Type-I Superconducting Needles 介观i型超导针中的磁热效应
IF 1.7 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-12-16 DOI: 10.1007/s10948-025-07104-5
David B. Zevallos G., A. Bustamante Dominguez, D. André Orna T., Luis De Los Santos Valladares, Mauro M. Dória, Isaías G. de Oliveira

In this paper we report our calculations regarding the heat absorbed by type-I superconducting needles with cross-sections of different geometric shapes, all having the same area. We used standard London theory to calculate the magnetic field inside these needles, allowing us to examine the magnetocaloric effect produced when the needles are subjected to a magnetic field difference. The cross-section geometries studied here include circular, square, triangular, heptagonal, hexagonal and ellipsoidal shapes. We also studied how small cylinders of different superconductors placed inside these needles influence the magnetocaloric effect of the overall system. Our main finding reveals a hierarchy in the ability to absorb heat based on the geometry of the straight cross-section. Notably, we discovered that there exists a temperature where above it, this hierarchy is inverted.

本文报道了具有相同面积的不同几何形状截面的i型超导针的吸热计算。我们使用标准的伦敦理论来计算这些针内的磁场,使我们能够检查当针受到磁场差异时产生的磁热效应。这里研究的截面几何形状包括圆形、方形、三角形、七边形、六边形和椭球形。我们还研究了放置在这些针内的不同超导体的小圆柱体如何影响整个系统的磁热效应。我们的主要发现揭示了基于直截面几何形状的吸热能力的层次结构。值得注意的是,我们发现存在一个温度,在这个温度之上,这个层次是颠倒的。
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引用次数: 0
Zeeman Field Effect on Zero-energy Vortex and Corner Modes in a Two Dimensional Second-order Topological Superconductor 二维二阶拓扑超导体零能涡旋和角模的塞曼场效应
IF 1.7 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-12-15 DOI: 10.1007/s10948-025-07110-7
A. O. Zlotnikov, A. D. Fedoseev, S. V. Aksenov

We study the effect of out-of-plane Zeeman field on zero-energy vortex- and corner-localized excitations in a two-dimensional second-order topological superconductor. It is shown analytically and numerically that zero-energy vortex modes are robust against the Zeeman-field effect as long as superconductivity is not destroyed by the field and a superconducting bulk gap is open. On the other hand, Majorana Kramers pairs existing at each corner of a square lattice at zero field and protected by time-reversal symmetry are gapped, in general, by the field. Despite that, we also found the specific model parameters supporting pairs of Majorana corner modes with zero energy in the presence of a magnetic field. In this parametric regime, the corner modes can coexist with zero-energy vortex modes in the presence of a vortex in the model. The precursor for coexisting zero-energy vortex and corner modes under the Zeeman field is the gapless bulk spectrum with Dirac cones in the normal (nonsuperconducting) state.

研究了平面外塞曼场对二维二阶拓扑超导体中零能量涡旋局域激发和角局域激发的影响。通过解析和数值计算表明,只要超导性不被场破坏且超导体隙打开,零能量涡旋模式对塞曼场效应具有鲁棒性。另一方面,存在于零场方形晶格各角并受时间反转对称保护的Majorana Kramers对一般被场所间隙。尽管如此,我们还发现了在磁场存在下支持零能量马约拉纳角模对的特定模型参数。在此参数域中,角模可以与零能量涡模共存,且模型中存在涡。塞曼场下零能涡旋和角模共存的前兆是正常(非超导)状态下具有狄拉克锥的无间隙体谱。
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引用次数: 0
Understanding the Asymmetry of the Critical Current Angular Dependence of Coated Conductors 了解涂层导体临界电流角依赖的不对称性
IF 1.7 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-12-11 DOI: 10.1007/s10948-025-07103-6
V. V. Guryev, S. V. Shavkin, O. A. Kondratev

The study focuses on analyzing the critical current angular dependencies of coated conductor samples that are sliced in both longitudinal and transverse directions of the tape. It is evident that in both cases, beside the dependence on magnetic field direction there is a distinct dependence of the critical current value on the direction of the Lorentz force that acting on the vortex matter. Asymmetry of the peaks is detected in the longitudinal sample, whereas this phenomenon is notably absent in the transverse sample. This is found to consist with the prevalent ab-plane tilt around the axis that coincides with the tape direction. An interpretation of this asymmetry is proposed that naturally follows from the empirically noted duality of the critical current anisotropy with respect to both the magnetic field and the Lorentz force directions. This analysis establishes, for the first time, a direct link between the ab-plane inclination angle and pinning characteristics, marking an advance in elucidating the structure–property relationship.

该研究的重点是分析在胶带的纵向和横向上切片的涂层导体样品的临界电流角依赖关系。很明显,在这两种情况下,除了依赖于磁场方向外,临界电流值还明显依赖于作用于涡旋物质的洛伦兹力的方向。在纵向样品中检测到峰的不对称性,而在横向样品中明显没有这种现象。这被发现与普遍的ab平面倾斜围绕轴,与磁带方向一致。对这种不对称的解释是根据经验指出的临界电流各向异性对磁场和洛伦兹力方向的对偶性而提出的。该分析首次建立了ab面倾角与钉钉特性之间的直接联系,标志着在阐明结构-性能关系方面取得了进展。
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引用次数: 0
Hall Coefficient and Specific Heat of Two-Liquid System of Charge Carriers Formed at Strong Electron-Phonon Coupling and Cuprates-Like Dispersion 在强电子-声子耦合和类铜酸盐色散下形成的载流子双液系统的霍尔系数和比热
IF 1.7 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-12-10 DOI: 10.1007/s10948-025-07094-4
A. E. Myasnikova, S. V. Doronkina, A. H. Dzhantemirov, R. R. Arutyunyan, A. S. Fukalov

Almost all the properties of cuprate high-temperature superconductors are no less mysterious than their superconductivity. From the very beginning of their study, it was noted that a two-component system of charge carriers is suitable for their description, which, however, had to be introduced phenomenologically. Recently it has been shown that ground and low-excited states of a system with strong long-range electron-phonon interaction and cuprates-like dispersion at carrier densities characteristic of cuprate superconductors are a two-liquid system of charge carriers comprising Bose-liquid of large bipolarons and Fermi-liquid of delocalized carriers. The phase diagram of such a system was demonstrated to coincide with that observed in cuprates. The temperature of the superconducting transition in them was shown to increase with the number of conducting layers in the unit cell, like in cuprates, due to the change in the spectrum of elementary excitations of the bipolaron liquid. Here we calculate temperature and doping behavior of the electronic specific heat and Hall resistance of such systems and compare it with that observed in cuprates. The low-temperature electronic specific heat obtained demonstrates giant increase at increasing doping, like that observed in cuprates at the overdoping. The increase is related with gradual decay of bipolarons at increasing temperature or doping. We also show that this decay may be responsible for the decrease in Hall resistance with increasing temperature observed in cuprates.

铜高温超导体的几乎所有性质都和它们的超导性一样神秘。从他们研究的一开始,就注意到载流子的双组分系统适合于它们的描述,然而,这必须从现象学上引入。最近研究表明,在铜超导体载流子密度下具有强远程电子-声子相互作用和类铜酸盐色散的系统的基态和低激发态是由大双极化子的玻色-液体和离域载流子的费米-液体组成的双液体载流子系统。这种体系的相图与在铜酸盐中观察到的相图一致。由于双极化子液体的基本激发谱的变化,它们的超导转变温度与铜酸盐一样,随着单元胞中导电层数的增加而增加。这里我们计算了这种体系的温度和掺杂行为的电子比热和霍尔电阻,并将其与在铜酸盐中观察到的结果进行了比较。得到的低温电子比热随着掺杂量的增加而大幅增加,与过量掺杂时铜酸盐的情况类似。这种增加与双极化子在温度升高或掺杂下的逐渐衰减有关。我们还表明,这种衰减可能是在铜酸盐中观察到的霍尔电阻随温度升高而下降的原因。
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引用次数: 0
Planar Josephson Junctions for Sensors and Electronics 传感器和电子器件的平面约瑟夫森结
IF 1.7 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-12-08 DOI: 10.1007/s10948-025-07096-2
Vladimir M. Krasnov

Josephson junctions are key elements in superconducting electronics. The most common type is the overlap (sandwich-type) junction, formed by vertically stacking two superconducting layers. In contrast, planar junctions are fabricated without overlap, at the edge of two superconducting films within a single plane. This geometric distinction has a significant impact on their physical properties. The planar geometry greatly enhances sensitivity to magnetic fields and improves impedance matching for terahertz (THz) devices. Its two-dimensional structure allows for simple and flexible electronic component design, enabling drastic miniaturization. Here I highlight recent advances in the application of planar junctions for novel technologies, including junction-on-cantilever sensors for super-resolution magnetic imaging, vortex-based memory cells, and programmable superconducting diodes. I will also discuss the general requirements, future perspectives, and key challenges in the evolving field of superconducting electronics.

约瑟夫森结是超导电子学中的关键元件。最常见的类型是重叠(三明治型)结,由两个超导层垂直堆叠形成。相比之下,平面结是在一个平面内的两个超导膜的边缘制造的,没有重叠。这种几何上的区别对它们的物理性质有重大影响。平面几何结构极大地提高了太赫兹器件对磁场的灵敏度,并改善了阻抗匹配。它的二维结构允许简单和灵活的电子元件设计,使剧烈小型化。在这里,我重点介绍了平面结应用于新技术的最新进展,包括用于超分辨率磁成像的悬臂结传感器、基于涡流的存储单元和可编程超导二极管。我还将讨论超导电子学发展领域的一般要求、未来前景和主要挑战。
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引用次数: 0
A Tribute to John Clarke, Michel Devoret and John Martinis for their Experiments on Quantum Tunneling and Energy Level Quantization in a Superconducting Macroscopic Circuit, Nobel Prize for Physics in 2025 2025年诺贝尔物理学奖授予John Clarke, Michel Devoret和John Martinis,表彰他们在超导宏观电路中的量子隧穿和能级量子化实验
IF 1.7 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-12-05 DOI: 10.1007/s10948-025-07101-8
Brian Josephson, Anthony Leggett, Jason Robinson, Francesco Tafuri
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引用次数: 0
Unravelling Defect Mediated Magnetism in Anatase TiO₂ Nanoparticles through Structural, Optical, and Magnetic Characterizations 通过结构、光学和磁性表征揭示锐钛矿tio2纳米颗粒中缺陷介导的磁性
IF 1.7 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-12-04 DOI: 10.1007/s10948-025-07100-9
Bhargav Bhagvat, Rama Shanker Gupta, Parth Patel, Santosh Kumar Sahoo, Ariful Rahaman, Akhilananda Kumar, Asokan Kandasami, Vijay Raj Singh

The structural, optical, and magnetic properties of TiO₂ nanoparticles were systematically investigated to explore the origin of room-temperature weak ferromagnetism (RTFM). Structural analysis confirmed the presence of a tetragonal anatase phase with high crystallinity, exhibiting characteristic vibrational modes of pure TiO₂ and surface functional groups associated with Ti–O bonding. Optical studies revealed a indirect bandgap of ~ 3.24 eV, slightly higher than the reported 3.20–3.22 eV for pure anatase, along with defect-related electronic transitions. The morphology indicates uniformly distributed nanocrystallites, and the magnetic measurements demonstrate a weak ferromagnetism at room temperature, which most likely arises from intrinsic defects such as oxygen vacancies. Compared with literature, where anatase TiO₂ is typically diamagnetic and or shows the RTFM only after defect engineering, the observation of weak ferromagnetism in undoped samples highlights the intrinsic role of defects in magnetic ordering. These insights are likely to advance the understanding of defect-driven magnetism and suggest promising applications of anatase TiO₂ nanoparticles in optoelectronics and spintronics.

系统地研究了tio2纳米颗粒的结构、光学和磁性能,以探索其室温弱铁磁性(RTFM)的来源。结构分析证实了高结晶度的四方锐钛矿相的存在,表现出纯tio2和与Ti-O键相关的表面官能团的特征振动模式。光学研究表明,间接带隙为~ 3.24 eV,略高于纯锐钛矿的3.20-3.22 eV,并伴有缺陷相关的电子跃迁。形貌显示纳米晶体均匀分布,磁性测量显示室温下的弱铁磁性,这很可能是由氧空位等固有缺陷引起的。与文献中锐钛矿tio_2具有典型的抗磁性或仅在缺陷工程后才显示RTFM相比,未掺杂样品中弱铁磁性的观察突出了缺陷在磁有序中的内在作用。这些见解可能会促进对缺陷驱动磁性的理解,并建议锐钛矿tio2纳米颗粒在光电子学和自旋电子学中的有前途的应用。
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引用次数: 0
Dynamic Hysteresis in Molecular-Based Magnetic Systems (I): Application of the Path Probability Method to the Mixed-Spin (1, 7/2) Blume-Capel Ising Model 基于分子的磁系统的动态滞后(I):路径概率方法在混合自旋(1,7 /2)blme - capel Ising模型中的应用
IF 1.7 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-12-03 DOI: 10.1007/s10948-025-07080-w
Mustafa Gençaslan, Mariya Fadhil Imran Alhameri, Ahmet Dervişoğlu

This study systematically investigates the non-equilibrium magnetic loop responses (DMHBs) of a mixed-spin (1, 7/2) Blume-Capel Ising system (BCIS) on a hexagonal lattice under an sinusoidal magnetic stimuli using the PPM framework (PPM). We explore the effects of the system parameters: exchange interaction parameters (({J}_{sigma S}) and ({J}_{SS})), temperature (T), oscillating magnetic field frequency (ω), crystal field parameter (d), and kinetic rate constants (({k}_{2})). Our findings reveal complex and varied hysteresis loop morphologies, including triple, double, and elliptical loops, for both individual sublattices (({m}^{A}) ​,({m}^{B})​) and total magnetization (({m}^{T})). We analyzed the corresponding coercive fields (CFs) and remanent magnetizations (RMs). The results demonstrate how changes in these parameters significantly influence the DMHBs, leading to characteristics indicative of both hard and soft magnetic materials. Notably, the kinetic rate constant ({k}_{2}) ​ is found to play a crucial role, analogous to wheel speed in rapid solidification processes, affecting the loop area and thus the “hardness” of the simulated magnet. While our theoretical predictions generally align with existing theoretical literature, some interesting discrepancies with experimental observations are noted. These differences may arise from practical limitations in experimental setups, such as the achievable wheel speed in melt spinning, or variations in the compositional concentrations of magnetic alloys. This research provides valuable insights into the non-equilibrium dynamics of molecular-based spin-configured molecular systems and extends the application of the PPM to complex mixed-spin systems.

本研究利用PPM框架系统地研究了正弦磁刺激下六边形晶格上混合自旋(1,7 /2)blme - capel - Ising系统(BCIS)的非平衡磁环响应(DMHBs)。我们探讨了系统参数的影响:交换相互作用参数(({J}_{sigma S})和({J}_{SS}))、温度(T)、振荡磁场频率(ω)、晶体场参数(d)和动力学速率常数(({k}_{2}))。我们的研究结果揭示了复杂和多样的磁滞回线形态,包括三重,双重和椭圆回路,对于单个亚晶格(({m}^{A}), ({m}^{B}))和总磁化(({m}^{T}))。分析了相应的矫顽力场(CFs)和剩余磁化强度(RMs)。结果表明,这些参数的变化如何显著影响DMHBs,从而导致软磁材料和硬磁材料的特征。值得注意的是,发现动力学速率常数({k}_{2})起着至关重要的作用,类似于快速凝固过程中的车轮速度,影响环路面积,从而影响模拟磁体的“硬度”。虽然我们的理论预测一般与现有的理论文献一致,但也注意到与实验观察的一些有趣的差异。这些差异可能是由实验装置的实际限制引起的,例如熔体纺丝时可达到的车轮速度,或磁性合金成分浓度的变化。该研究为基于分子的自旋配置分子系统的非平衡动力学提供了有价值的见解,并将PPM扩展到复杂的混合自旋系统中。
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引用次数: 0
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Journal of Superconductivity and Novel Magnetism
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