This study reports the synthesis of pure and transition metal doped at the Ni-site of LNO perovskites using solid-state reaction route. Various characterization techniques such as X-ray diffraction (XRD), High Resolution Transmission Electron Microscopy (HR-TEM), Raman spectroscopy, Vibrating Sample Magnetometer (VSM), dielectric spectroscopy and ferroelectric (P-E loop) tests are employed to explore the influence of transition metal ions, i.e. Cr, Fe and Mn on the Ni-site of pure LNO samples. The structure is reported to be distorted rhombohedral phase, with a better phase purity for Fe-LNO comparatively. The average crystallite sizes calculated for pure LNO, Cr-LNO, Fe-LNO and Mn-LNO are 6.59 nm, 10.96 nm, 9.15 nm, and 12.67 nm respectively. HR-TEM reveals that the corresponding grain sizes are approximately 230 nm, 210 nm, 240 nm and 280 nm. Raman spectra exhibit five active vibrational modes, and noticeable blue shift in the doped samples, attributing to the compressive lattice strain. Magnetic characterization by VSM demonstrates weak ferromagnetism in Cr-doped LNO, soft magnetic behavior in Fe -doped LNO, and antiferromagnetic characteristics in Mn-doped LNO. Dielectric measurements show an increase and decrease in dielectric constant and loss for Mn and Fe doped LNOs compared to pure and Cr doped LNO. Dielectric properties with frequency show a slight relaxor behavior. The P-E hysteresis loops however are unsaturated, lossy and lack spontaneous polarization, indicating no evidence for ferroelectric behavior in all the samples.
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