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Magnetic and Physical Properties of Polycrystalline GdNiSi3 Rare Earth Intermetallic Compound 多晶GdNiSi3稀土金属间化合物的磁性和物理性质
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-01-07 DOI: 10.1007/s10948-024-06848-w
Vimaljith A. R, Nallamuthu S

We investigated the magnetic, thermodynamic, and transport properties of polycrystalline GdNiSi3. The compound crystallized in an orthorhombic structure with the space group Cmmm. Heat capacity and magnetic measurements revealed bulk antiferromagnetic ordering at TN = 22.5 K, θp = -25 K, and an effective magnetic moment of μeff = 8 μB/Gd. A metamagnetic transition occurred around 28 kOe in the magnetic isotherm at 3 K. Furthermore, resistivity measurements conducted under a magnetic field at 2 K displayed a low-temperature drop near 22.5 K, corresponding to the antiferromagnetic order.

我们研究了多晶GdNiSi3的磁性、热力学和输运性质。该化合物结晶为具有空间群Cmmm的正交结构。在TN = 22.5 K, θp = -25 K,有效磁矩为μeff = 8 μB/Gd时,热容和磁测量显示了体反铁磁有序。在3k的磁等温线28koe左右发生了一个变磁跃迁。此外,在2k磁场下进行的电阻率测量显示,在22.5 K附近有一个低温下降,对应于反铁磁顺序。
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引用次数: 0
Effect of Pinning Size on the Critical Current Density in Superconducting Films with Slightly Distorted Square Arrays of Pinning Sites 钉钉尺寸对钉钉点方形微畸变超导薄膜临界电流密度的影响
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-01-06 DOI: 10.1007/s10948-024-06896-2
Afsaneh Zarei, Mehdi Hosseini, Zahra Owjifard, Ali Moftakharzadeh

In this study, we examine the effects of pinning forces and pinning center radius on critical current density using a square pinning array and the application of dual conformal transformations. This transformation slightly distorts the square pinning array. We study vortex dynamics by considering the interaction between vortices and pinning centers, as well as the impact of thermal fluctuations. Initially, by determining the mentioned forces that affect vortex dynamics, the corresponding Langevin equation for the vortices is solved. By solving this equation, the position of the vortices over time is determined, and using these positions along with boundary conditions, the critical current density as a function of the magnetic field is calculated. Our studies show that the critical current density increases with the enhancement of pinning force and pinning center radius under conformal transformation.

在这项研究中,我们使用方形钉钉阵列和对偶保角变换的应用来研究钉钉力和钉钉中心半径对临界电流密度的影响。这个变换稍微扭曲了正方形的固定阵列。我们通过考虑涡旋与钉钉中心的相互作用以及热波动的影响来研究涡旋动力学。首先,通过确定上述影响涡旋动力学的力,求解相应的涡旋朗之万方程。通过求解该方程,确定了涡旋随时间的位置,并利用这些位置和边界条件,计算了临界电流密度作为磁场的函数。研究表明,在共形变换下,临界电流密度随着钉钉力和钉钉中心半径的增大而增大。
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引用次数: 0
First-Principles Investigation of the Electronic and Magnetic Properties of RhCo-Based Quaternary Heusler Alloys rhco基四元Heusler合金电子和磁性能的第一性原理研究
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-01-06 DOI: 10.1007/s10948-024-06883-7
R. Nourine, S. Abbaoui, M. Caid, H. Rached, D. Rached, Y. Rached, Nada Talal Mahmoud, S. Al-Qaisi

In this contribution, we present an ab initio investigation of the electronic and magnetic properties of some RhCo-based quaternary Heusler alloys (QH). QH compounds can be generated from doping the X2YZ full Heusler alloys; in this case, we start our study by tracking the electronic and magnetic properties variation of cobalt-doped Rh2MnSn. Our results reveal that Co-substitution at Rh sites of Rh2−xCoxMnSn (x = 0 to 2) transforms it into half-metallic material when x ≥ 1. The calculated magnetic moment is 4.68µB for Rh2MnSn (x = 0), this value will increase with Co doping to be an integer 5 µB when x ≥ 1 obeys the Slater Pauling behavior. The spin polarization at the Fermi level varied from 20.76 to 100%. The Curie temperature (Tc) and exchange interaction are largely dependent on the valence electron number (Nv); for this purpose, we also identify some other quaternary RhCoMnZ (Z = Al, Si, Ga, Ge, Sn, Sb) compounds with different Nv. The exchange parameters (jij) and Tc are calculated using the LMTO method. The Tc is calculated with the mean-field approximation (MFA), and the results indicate that all compounds investigated have Tc evidently higher than room temperature making them promising candidates for spintronics applications. The latter results are in better agreement with available experimental and theoretical data.

在这篇贡献中,我们提出了一些基于rhco的四元Heusler合金(QH)的电子和磁性能的从头计算研究。掺杂X2YZ全Heusler合金可生成QH化合物;在这种情况下,我们从跟踪钴掺杂的Rh2MnSn的电子和磁性能变化开始我们的研究。结果表明,当x≥1时,Rh2 - xCoxMnSn (x = 0 ~ 2)的Rh位点共取代转变为半金属材料。计算得到Rh2MnSn (x = 0)的磁矩为4.68µB,当x≥1符合Slater Pauling行为时,随着Co的掺杂,磁矩增大为5µB。费米能级的自旋极化在20.76 ~ 100%之间变化。居里温度(Tc)和交换作用在很大程度上取决于价电子数(Nv);为此,我们还鉴定了其他一些具有不同Nv的四元RhCoMnZ (Z = Al, Si, Ga, Ge, Sn, Sb)化合物。利用LMTO方法计算了交换参数(jij)和Tc。用平均场近似(MFA)计算了Tc,结果表明所研究的化合物的Tc明显高于室温,使其成为自旋电子学应用的有希望的候选者。后者的结果与现有的实验和理论数据吻合得更好。
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引用次数: 0
Magnetic Properties of Rapidly Solidified (Fe1−xNix)88Zr7B4Cu1 Alloys 快速凝固(Fe1−xNix)88Zr7B4Cu1合金的磁性能
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-01-06 DOI: 10.1007/s10948-024-06878-4
Arvindha Babu Diraviam, J. Arout Chelvane, B. S. Murty, Bhaskar Majumdar, Manivel Raja Muthuvel

In this report, soft magnetic properties of amorphous and nanocrystalline (Fe1−xNix)88Zr7B4Cu1 alloys with x = 0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8 and 1.0 have been studied. The rapidly solidified ribbons have been prepared using a vacuum melt spinning technique followed by annealing for obtaining nanocrystalline phases. The Curie temperature (Tc) of amorphous phase increases with Ni content upto x = 0.6 and decreases beyond x = 0.6. The saturation magnetisation of as-spun and high-temperature (620/720 °C) annealed ribbons of (Fe1−xNix)88Zr7B4Cu1 alloy system shows a dip at around x = 0.35 which is termed as Invar behaviour. However, Invar behaviour is not observed in 450/500 °C annealed ribbons due to the absence of fcc phase which becomes non-magnetic around x = 0.35 and is responsible for the dip in magnetisation. The coercivity of 620/750 °C annealed ribbons is high as compared to as-spun and 450/500 °C annealed ribbons due to the presence of Fe3Zr/Ni5Zr phases.

本文研究了x = 0、0.1、0.2、0.3、0.4、0.5、0.6、0.7、0.8和1.0的非晶和纳米晶(Fe1−xNix)88Zr7B4Cu1合金的软磁性能。采用真空熔体纺丝技术制备了快速凝固的带状材料,然后退火获得纳米晶相。非晶相的居里温度(Tc)随Ni含量的增加而升高,直至x = 0.6以上,居里温度降低。(Fe1−xNix)88Zr7B4Cu1合金体系的旋转态和高温(620/720℃)退火带的饱和磁化在x = 0.35左右出现了一个倾角,称为因瓦行为。然而,在450/500°C退火带中没有观察到因瓦尔行为,因为没有fcc相,在x = 0.35左右变得无磁性,这是磁化下降的原因。由于Fe3Zr/Ni5Zr相的存在,620/750°C退火带的矫顽力比纺丝带和450/500°C退火带高。
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引用次数: 0
Tunable Magnetic Skyrmion Motion on a Nanostrip Using Current and Spin Waves: A Micromagnetic Study 利用电流和自旋波在纳米带上的可调谐磁激子运动:微磁研究
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-01-03 DOI: 10.1007/s10948-024-06889-1
Payal Bhattacharjee, Saswati Barman

Nowadays, the concept of non-trivial topological protection and the nanoscale size of nanomagnetic particles constitute a major area of research. Due to topological protection stability, nanoscale size, and the requirement of low spin current density for motion, skyrmions have attracted great attention in next-generation spintronic devices as robust information carriers. We study the motion of an isolated magnetic skyrmion with induced interfacial Dzyaloshinskii-Moriya interaction (iDMI) instigated by a spin wave and driven by spin current with variation in different parameters in a nanotrack of finite length using micromagnetic simulations. It is found that the magnetic skyrmion moves in the same direction as the direction of propagation of the spin wave. The skyrmion initially experiences an acceleration in its motion; thereafter, the velocity decreases exponentially. The motion of the magnetic skyrmion initiates as the momentum of the spin wave gets transferred to it. The motion of the magnetic skyrmion is found to be significantly dependent on the variation of parameters like frequency and amplitude of the incident spin waves, as well as the damping parameter and the strength of the applied spin-polarized current. The results obtained in this work could become useful to design skyrmion-based spintronic information-carrying and storage devices.

目前,非平凡拓扑保护的概念和纳米磁性粒子的纳米级尺寸构成了一个主要的研究领域。由于拓扑保护的稳定性、纳米尺度的尺寸以及运动对低自旋电流密度的要求,skyrmions作为鲁棒性信息载体在下一代自旋电子器件中备受关注。利用微磁模拟研究了在自旋波激发下,在不同参数的自旋电流驱动下,具有诱导界面Dzyaloshinskii-Moriya相互作用(iDMI)的孤立磁粒子在有限长度纳米轨道上的运动。结果表明,磁激子的运动方向与自旋波的传播方向一致。最初,天空在运动时经历加速度;此后,速度呈指数递减。当自旋波的动量传递给磁性粒子时,磁性粒子的运动就开始了。磁激子的运动明显依赖于入射自旋波的频率和振幅等参数的变化,以及阻尼参数和施加的自旋极化电流的强度。本工作的结果对设计基于skyrmion的自旋电子信息携带和存储器件具有重要意义。
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引用次数: 0
Study on the Electromagnetic and Microwave Absorption Characteristics of Co(_{2})Si by Non-metallic (B, C) Doping 非金属(B, C)掺杂Co (_{2}) Si的电磁和微波吸收特性研究
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2025-01-03 DOI: 10.1007/s10948-024-06897-1
Jiang Zou, Zehang Zhao, Quan Xie

Mechanical alloying and hot sintering were used to synthesize Co(_{2})Si-doped powder materials with varying boron (B) and carbon (C) ratios. The effect of B and C doping on the magnetic behavior, microwave absorption characteristics, and crystal structure of the materials was systematically investigated. All X-ray diffraction peaks corresponded to the standard card for Co(_{2})Si (ICDD: 98-005-2281). The saturation magnetization (Ms) values for samples doped with 2, 4, and 8 at% B were 14.28, 19.56, and 7.36 emu/g, respectively. The Ms values for the Co(_{2})Si samples doped with 2, 4, and 8 at% C were 16.66, 19.97, and 14.56 emu/g, respectively. Co(_{2})Si alloys with C significantly improved their overall absorption performance. The minimum reflection loss in the C-doped Co(_{2})Si alloy was (-)61.88 dB, accompanied by a bandwidth of 2.38 GHz for effective absorption. Furthermore, the Co(_{2-x})C(_{x})Si samples (where x = 0.04, 0.08, 0.16) exhibited superior comprehensive absorption properties compared to the Co(_{2-x})B(_{x})Si samples.

采用机械合金化和热烧结的方法合成了不同硼(B)和碳(C)配比的Co (_{2})掺硅粉末材料。系统研究了B和C掺杂对材料磁性、微波吸收特性和晶体结构的影响。所有x射线衍射峰均符合Co (_{2}) Si (ICDD: 98-005-2281)的标准卡。2、4和8 at掺杂样品的饱和磁化(Ms)值% B were 14.28, 19.56, and 7.36 emu/g, respectively. The Ms values for the Co(_{2})Si samples doped with 2, 4, and 8 at% C were 16.66, 19.97, and 14.56 emu/g, respectively. Co(_{2})Si alloys with C significantly improved their overall absorption performance. The minimum reflection loss in the C-doped Co(_{2})Si alloy was (-)61.88 dB, accompanied by a bandwidth of 2.38 GHz for effective absorption. Furthermore, the Co(_{2-x})C(_{x})Si samples (where x = 0.04, 0.08, 0.16) exhibited superior comprehensive absorption properties compared to the Co(_{2-x})B(_{x})Si samples.
{"title":"Study on the Electromagnetic and Microwave Absorption Characteristics of Co(_{2})Si by Non-metallic (B, C) Doping","authors":"Jiang Zou,&nbsp;Zehang Zhao,&nbsp;Quan Xie","doi":"10.1007/s10948-024-06897-1","DOIUrl":"10.1007/s10948-024-06897-1","url":null,"abstract":"<div><p>Mechanical alloying and hot sintering were used to synthesize Co<span>(_{2})</span>Si-doped powder materials with varying boron (B) and carbon (C) ratios. The effect of B and C doping on the magnetic behavior, microwave absorption characteristics, and crystal structure of the materials was systematically investigated. All X-ray diffraction peaks corresponded to the standard card for Co<span>(_{2})</span>Si (ICDD: 98-005-2281). The saturation magnetization (Ms) values for samples doped with 2, 4, and 8 at% B were 14.28, 19.56, and 7.36 emu/g, respectively. The Ms values for the Co<span>(_{2})</span>Si samples doped with 2, 4, and 8 at% C were 16.66, 19.97, and 14.56 emu/g, respectively. Co<span>(_{2})</span>Si alloys with C significantly improved their overall absorption performance. The minimum reflection loss in the C-doped Co<span>(_{2})</span>Si alloy was <span>(-)</span>61.88 dB, accompanied by a bandwidth of 2.38 GHz for effective absorption. Furthermore, the Co<span>(_{2-x})</span>C<span>(_{x})</span>Si samples (where x = 0.04, 0.08, 0.16) exhibited superior comprehensive absorption properties compared to the Co<span>(_{2-x})</span>B<span>(_{x})</span>Si samples.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 1","pages":""},"PeriodicalIF":1.6,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142913019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Valley-Dependent Crossed Andreev Reflection in Graphene/Superconductor/Line-Defect Superlattice Junctions 石墨烯/超导体/线缺陷超晶格结中谷相关交叉Andreev反射
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-12-30 DOI: 10.1007/s10948-024-06895-3
Chongdan Ren, Yuqiao Ren, Hongyu Tian

Graphene, a two-dimensional material with remarkable electronic properties, offers significant potential for valley-based electronic devices. In this study, we explore a novel mechanism to achieve valley-dependent, near-perfect crossed Andreev reflection (CAR) in graphene-based junctions by utilizing the valley degree of freedom in a graphene/superconductor/line defect superlattice (LDGSL) structure. The LDGSL introduces unique valley-filtering effects. By incorporating staggered pseudospin potentials and intrinsic spin-orbit coupling in the left graphene electrode, the system selectively enhances CAR for electrons in the K(') valley, while simultaneously suppressing local Andreev reflection and elastic cotunneling (ECT). Numerical simulations reveal that CAR is nearly perfect for K(') valley electrons with spin-up, while for K valley electrons with spin-down, only ECT is observed. Our results demonstrate the viability of this approach for valley-polarized CAR in graphene/ superconductor junctions, providing a pathway for the development of valley-based quantum information devices.

石墨烯是一种具有显著电子特性的二维材料,为基于谷的电子器件提供了巨大的潜力。在这项研究中,我们探索了一种新的机制,通过利用石墨烯/超导体/线缺陷超晶格(LDGSL)结构中的谷自由度,在石墨烯基结中实现谷依赖,近乎完美的交叉Andreev反射(CAR)。LDGSL引入了独特的山谷滤波效果。通过在左侧石墨烯电极中加入交错赝自旋势和本征自旋轨道耦合,该系统选择性地增强了K (')谷中电子的CAR,同时抑制了局部Andreev反射和弹性共隧道(ECT)。数值模拟表明,对于自旋向上的K (')谷电子,CAR几乎是完美的,而对于自旋向下的K谷电子,只观察到ECT。我们的研究结果证明了这种方法在石墨烯/超导体结中的谷极化CAR的可行性,为基于谷的量子信息器件的发展提供了一条途径。
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引用次数: 0
Effect of Nonuniform Morphology and Crystalline Structure on the Effective Magnetic Anisotropy in Fe, Co, and Ni Nanowire Arrays 非均匀形貌和晶体结构对铁、钴和镍纳米线阵列有效磁各向异性的影响
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-12-28 DOI: 10.1007/s10948-024-06890-8
M. I. Sobirov, A. Yu. Samardak, S. A. Satsuk, K. A. Rogachev, N. A. Ognev, G. A. Leyko, A. O. Lembikov, S. M. Pisarev, S. V. Komogortsev, A. V. Ognev, A. S. Samardak

The phenomenon of shape anisotropy predominantly constitutes the principal factor influencing effective anisotropy, serving as a significant determinant of the magnetic characteristics of one-dimensional ferromagnetic nanostructures, materials that hold substantial promise for a diverse array of applications in the domains of electronics and biomedicine. However, it is noteworthy that effective anisotropy may be modulated through the manipulation of various other forms of anisotropy, thereby facilitating the tuning of the magnetic properties of nanowire arrays without necessitating alterations to their spatial curvature. In this study, we elucidate the characteristics of nanowire arrays with varying lengths and compositions, which have been electrochemically synthesized utilizing identical porous templates. Through a range of experimental methodologies, we establish a correlation between atypical magnetic behavior and the underlying morphology and crystalline structure of the nanowires. We attribute the pronounced magnetostatic interactions observed within cobalt (Co) nanowires to the presence of significant local uniaxial magnetocrystalline anisotropy, along with a nanostructure oriented perpendicular to the longitudinal axis of the nanowire. Furthermore, we examine the repercussions of substantial discrepancies in the lengths of iron (Fe) nanowires on the magnetostatic field distribution. Our analysis employs mean field theory, incorporating the contributions of various anisotropies present within the system, as well as the non-uniform lengths of the nanowires. Ultimately, through micromagnetic simulations, we investigated the stray fields present within the nanowire array and delineated how strong magnetocrystalline anisotropy and the variability in length affect their spatial distribution.

形状各向异性现象主要是影响有效各向异性的主要因素,是一维铁磁纳米结构磁性特性的重要决定因素,这种材料在电子和生物医学领域的各种应用中具有巨大的前景。然而,值得注意的是,有效的各向异性可以通过操纵各种其他形式的各向异性来调制,从而促进纳米线阵列的磁性调谐,而无需改变其空间曲率。在这项研究中,我们阐明了不同长度和组成的纳米线阵列的特性,这些纳米线阵列是利用相同的多孔模板电化学合成的。通过一系列实验方法,我们建立了非典型磁性行为与纳米线的底层形态和晶体结构之间的相关性。我们将在钴(Co)纳米线中观察到的明显的静磁相互作用归因于存在显著的局部单轴磁晶各向异性,以及垂直于纳米线纵轴的纳米结构。此外,我们研究了铁(Fe)纳米线长度的实质性差异对静磁场分布的影响。我们的分析采用平均场理论,结合系统内存在的各种各向异性的贡献,以及纳米线的非均匀长度。最后,通过微磁模拟,我们研究了纳米线阵列内存在的杂散场,并描绘了强磁晶各向异性和长度变化如何影响它们的空间分布。
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引用次数: 0
Effect of Magnetic NiO Nanoparticles on Pinning Properties of YBa2Cu3O7-x Superconductor 磁性纳米NiO对YBa2Cu3O7-x超导体钉扎性能的影响
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-12-27 DOI: 10.1007/s10948-024-06885-5
Rajni Kandari, Mamta Dahiya, Mohd Faraz, Neeraj Khare

In the present work, we report the effects of incorporating magnetic Nickel oxide (NiO) nanoparticles in YBa2Cu3O7-x (YBCO), on the superconducting properties of the YBCO nanocomposite. The NiO was prepared by auto-combustion method and exhibited ferromagnetic nature at room temperature. The polycrystalline YBCO and its nanocomposites with NiO nanoparticles were synthesized using the solid-state reaction method. The addition of magnetic NiO nanoparticles in YBCO resulted in improved critical current density and flux pinning force in the measured range of temperature and magnetic fields. The observed high pinning at a lower field is attributed to the magnetic interaction of vortices with the NiO nanoparticles. At 60 K, the enhancement in critical current density of YBCO nanocomposite is ~ 1.7 times for low applied field, and ~ 1.2 times for high applied field, compared to the YBCO superconductor. The presence of NiO in the YBCO matrix also created more defects in YBCO, which enhanced the pinning properties and remained effective even at higher magnetic fields.

在本工作中,我们报道了在YBa2Cu3O7-x (YBCO)中加入磁性氧化镍(NiO)纳米颗粒对YBCO纳米复合材料超导性能的影响。采用自燃烧法制备的NiO在室温下表现出铁磁性。采用固相反应法制备了多晶YBCO及其纳米复合材料。在温度和磁场测量范围内,磁性NiO纳米颗粒的加入提高了YBCO的临界电流密度和磁钉力。在较低磁场下观察到的高钉钉是由于涡旋与NiO纳米颗粒的磁相互作用。在60 K时,与YBCO超导体相比,YBCO纳米复合材料的临界电流密度在低电场下提高了约1.7倍,在高电场下提高了约1.2倍。NiO在YBCO基体中的存在也使YBCO中产生了更多的缺陷,从而增强了YBCO的钉钉性能,并且在更高的磁场下仍然有效。
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引用次数: 0
Structural and Electrical Properties of Al3+ Substituted Cobalt Ferrite Nanoparticles for Improved Antibacterial Activity Al3+取代钴铁氧体纳米粒子的结构和电学性能及其抗菌活性的提高
IF 1.6 4区 物理与天体物理 Q3 PHYSICS, APPLIED Pub Date : 2024-12-27 DOI: 10.1007/s10948-024-06851-1
Wafaa A. Shatti, Zena M. A. Abbas, Ali M. Mohammad, Sulaf M. Mohammed

Nanomaterials show strong potential for antibacterial treatments by targeting various bacterial strains and bypassing resistance through mechanical cell damage. This occurs when nanoparticles interact with bacterial cell walls, compromising their structural integrity. These mechanisms highlight nanomaterials as effective tools in combating infections. Using the sol–gel method, this study synthesized Co1-xAlxFe2O4 nanoferrites (x = 0.0, 0.2, 0.4, 0.6, 0.8). This study examines the effects of substituting trivalent Al3⁺ ions on cobalt ferrite nanoparticles’ structural and electrical properties and their antibacterial activity. X-ray diffraction confirmed the formation of Co1-xAlFe₂O₄ nanoferrites in the (Fdoverline{3 }m) space group, showing a shift towards lower 2θ angles in the (311) plane as Al3⁺ content increased. The crystal size reached 29.04 when (x = 0.0 and 0.4) and decreased to 25.29 when (x = 0.8). Fourier transform infrared spectroscopy identified absorption band characteristic of the cubic spinel structure, while field emission-scanning electron microscopy revealed polyhedral nanoparticles clustered in nanoscale formations. Particle sizes ranged from 37.21 nm at x = 0.4 to 31.11 nm at x = 0.8. A decrease in dielectric properties with increasing frequency was consistent with the Maxwell–Wagner model and Koops’ theory, while AC conductivity increased as charge carrier mobility rose with frequency. Antibacterial tests using the Agar well diffusion method showed that Escherichia coli was the most sensitive strain, followed by Klebsiella spp., with Streptococcus spp. Displaying the highest resistance. Nanoparticles at x = 0.8 demonstrated the most potent antibacterial activity. Overall, the results highlight that cation substitution within the cubic spinel lattice significantly impacts the structural, electrical, and antibacterial properties of cobalt ferrite nanoparticles.

Graphical Abstract

纳米材料可以靶向多种细菌菌株,并通过机械细胞损伤绕过耐药性,显示出很强的抗菌治疗潜力。当纳米颗粒与细菌细胞壁相互作用,破坏其结构完整性时,就会发生这种情况。这些机制突出了纳米材料作为对抗感染的有效工具。采用溶胶-凝胶法制备了Co1-xAlxFe2O4纳米铁氧体(x = 0.0, 0.2, 0.4, 0.6, 0.8)。本研究考察了三价Al3 +取代对钴铁氧体纳米颗粒结构、电学性能及抗菌活性的影响。x射线衍射证实在(Fdoverline{3 }m)空间群中形成了Co1-xAlₓFe₂O₄纳米铁素体,随着Al3 +含量的增加,在(311)平面上的2θ角向下移动。当x = 0.0和0.4时,晶体尺寸达到29.04,当x = 0.8时,晶体尺寸减小到25.29。傅里叶变换红外光谱鉴定了立方尖晶石结构的吸收带特征,而场发射扫描电子显微镜则发现了以纳米级结构聚集的多面体纳米颗粒。粒径范围从x = 0.4时的37.21 nm到x = 0.8时的31.11 nm。介电性能随频率的增加而降低,与Maxwell-Wagner模型和Koops理论一致,而交流电导率随载流子迁移率随频率的增加而增加。琼脂孔扩散法抑菌试验结果显示,大肠埃希菌最敏感,克雷伯氏菌次之,链球菌耐药最高。纳米粒子在x = 0.8时表现出最强的抗菌活性。总的来说,研究结果表明立方尖晶石晶格内的阳离子取代显著影响了钴铁氧体纳米颗粒的结构、电学和抗菌性能。图形摘要
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引用次数: 0
期刊
Journal of Superconductivity and Novel Magnetism
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