The synthesis, structure, and magnetic properties of Ba3REB9O18 (RE = Dy-Yb) compounds were investigated. Rietveld Refinement of the X-ray diffraction (XRD) data confirms that all compounds crystallize in a hexagonal Ba3YB9O18-type structure with space group P63/m (No. 176) and Pearson symbol hP62. The lattice parameters a and c increase linearly with the increasing ionic radii of the RE3+ ions. RE3+ ions form two-dimensional triangular layers in the ab plane, which are separated by non-magnetic Ba/B-O polyhedra. The magnetic susceptibility measurement reveals no long-range magnetic order or spin glass behavior in any of the compounds above 2 K. The negative Curie-Weiss temperatures indicate dominant antiferromagnetic (AFM) exchange interactions between the RE3+ ions. The combination of triangular lattice and antiferromagnetic interaction suggests this family of compounds is a promising system for researching magnetic frustration.
{"title":"Synthesis, Structure, Magnetism of Two-Dimensional Triangular Lattice Materials Ba3REB9O18 (RE = Dy, Ho, Er, Tm and Yb)","authors":"Wanxia Liu, Yuxia Gao, Yaning Li, Yulong Li, Weijie Ren, Xin Sun, Xiaofeng Li, Mingli Wang","doi":"10.1007/s10948-025-07070-y","DOIUrl":"10.1007/s10948-025-07070-y","url":null,"abstract":"<div><p>The synthesis, structure, and magnetic properties of Ba<sub>3</sub>REB<sub>9</sub>O<sub>18</sub> (RE = Dy-Yb) compounds were investigated. Rietveld Refinement of the X-ray diffraction (XRD) data confirms that all compounds crystallize in a hexagonal Ba<sub>3</sub>YB<sub>9</sub>O<sub>18</sub>-type structure with space group <i>P</i>6<sub>3</sub>/m (No. 176) and Pearson symbol <i>hP</i>62. The lattice parameters <i>a</i> and <i>c</i> increase linearly with the increasing ionic radii of the RE<sup>3+</sup> ions. RE<sup>3+</sup> ions form two-dimensional triangular layers in the <i>ab</i> plane, which are separated by non-magnetic Ba/B-O polyhedra. The magnetic susceptibility measurement reveals no long-range magnetic order or spin glass behavior in any of the compounds above 2 K. The negative Curie-Weiss temperatures indicate dominant antiferromagnetic (AFM) exchange interactions between the RE<sup>3+</sup> ions. The combination of triangular lattice and antiferromagnetic interaction suggests this family of compounds is a promising system for researching magnetic frustration.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"38 6","pages":""},"PeriodicalIF":1.7,"publicationDate":"2025-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145405653","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}