Pub Date : 2024-07-01DOI: 10.1007/s10948-024-06795-6
Dong Thi Kim Phuong, Nguyen Van Men
We investigate plasmon properties in a double-layer graphene structure under the effects of an in-plane external magnetic field within the zero-temperature random-phase approximation. Numerical calculations demonstrate that two plasmon modes exist in the system, corresponding to in-phase and out-of-phase oscillations of charges. The spin polarization number P affects the optical and acoustic plasmon modes and their decay rate differently. As the polarization number increases, the frequency of the acoustic mode slightly decreases while that of the optical mode significantly increases. Besides, the existence of an external magnetic field expands the single-particle-excitation area of the system; therefore, plasmon modes become damped at a smaller wave vector, compared to those in the case of unpolarized systems. The separation between two layers increases (decreases) the plasmon frequency of the acoustic (optical) mode. Finally, we found that background dielectric inhomogeneity decreases the energy and decay rate of plasmon modes of the spin-polarized system.
在零温随机相近似条件下,我们研究了双层石墨烯结构在平面内外加磁场作用下的等离子特性。数值计算表明,系统中存在两种等离子体模式,分别对应于电荷的同相振荡和异相振荡。自旋极化数 P 对光学和声学等离子体模式及其衰减率的影响不同。随着极化数的增加,声学模式的频率略有降低,而光学模式的频率则显著增加。此外,外部磁场的存在扩大了系统的单粒子激发区域;因此,与非极化系统相比,等离子体模式在更小的波矢量上受到阻尼。两层之间的间隔会增加(减少)声(光)模式的等离子体频率。最后,我们发现背景电介质的不均匀性降低了自旋极化系统等离子体模式的能量和衰减率。
{"title":"Study of Spin-Polarization Effects of Collective Excitations in Double-Layer GrapheneStructures","authors":"Dong Thi Kim Phuong, Nguyen Van Men","doi":"10.1007/s10948-024-06795-6","DOIUrl":"10.1007/s10948-024-06795-6","url":null,"abstract":"<div><p>We investigate plasmon properties in a double-layer graphene structure under the effects of an in-plane external magnetic field within the zero-temperature random-phase approximation. Numerical calculations demonstrate that two plasmon modes exist in the system, corresponding to in-phase and out-of-phase oscillations of charges. The spin polarization number <i>P</i> affects the optical and acoustic plasmon modes and their decay rate differently. As the polarization number increases, the frequency of the acoustic mode slightly decreases while that of the optical mode significantly increases. Besides, the existence of an external magnetic field expands the single-particle-excitation area of the system; therefore, plasmon modes become damped at a smaller wave vector, compared to those in the case of unpolarized systems. The separation between two layers increases (decreases) the plasmon frequency of the acoustic (optical) mode. Finally, we found that background dielectric inhomogeneity decreases the energy and decay rate of plasmon modes of the spin-polarized system.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"37 8-10","pages":"1585 - 1591"},"PeriodicalIF":1.6,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141547947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-01DOI: 10.1007/s10948-024-06788-5
Yao Ying, Yikai Zhou, Jing Yu, Liang Qiao, Jingwu Zheng, Wangchang Li, Juan Li, Shenglei Che
Breast cancer is one of the deadliest cancers for women, so cell labeling and therapy of breast cancer become imperative. In this work, dextran- and carboxymethyl dextran–coated Fe3O4 nanoparticles (Fe3O4@DEX and Fe3O4@CMD) were well synthesized through the co-precipitation method. The dextran and carboxymethyl dextran coating reduces the average particle size of Fe3O4 nanoparticles from 10.9 to 4.0–5.5 nm, and the coated samples exhibit average hydrodynamic diameters ranging from 31 to 110 nm. The coating promotes the dispersibility of nanoparticles. Saturation magnetization is reduced from 60.3 to 5.6–7.1 emu/g in the coated MNPs due to the large weight ratio of the coating layer and the decrease in particle size. Hemolysis and cytotoxicity assay results indicate the excellent biocompatibility of Fe3O4 nanoparticles. The cellular uptake assay confirms that both dextran- and carboxymethyl dextran–coated Fe3O4 nanoparticles are easily taken in by breast cancer cells. Comprehensively considering dispersion, biocompatibility, and cellular uptake, the Fe3O4@CMD is more suitable for application in the bio-labeling of breast cancer cells. The SAR values of the Fe3O4@DEX and Fe3O4@CMD range from 19.2 to 30.7 W/g. The SAR value is mainly influenced by the hydrodynamic diameter in the coated samples. The Fe3O4@CMD20 shows the maximum SAR value of 30.7 W/g and has potential application in magnetic hyperthermia therapy.
{"title":"Preparation of Dextran- and Carboxymethyl Dextran–Coated Fe3O4 Nanoparticles for Breast Cancer Cell Labeling and Magnetic Hyperthermia","authors":"Yao Ying, Yikai Zhou, Jing Yu, Liang Qiao, Jingwu Zheng, Wangchang Li, Juan Li, Shenglei Che","doi":"10.1007/s10948-024-06788-5","DOIUrl":"10.1007/s10948-024-06788-5","url":null,"abstract":"<div><p>Breast cancer is one of the deadliest cancers for women, so cell labeling and therapy of breast cancer become imperative. In this work, dextran- and carboxymethyl dextran–coated Fe<sub>3</sub>O<sub>4</sub> nanoparticles (Fe<sub>3</sub>O<sub>4</sub>@DEX and Fe<sub>3</sub>O<sub>4</sub>@CMD) were well synthesized through the co-precipitation method. The dextran and carboxymethyl dextran coating reduces the average particle size of Fe<sub>3</sub>O<sub>4</sub> nanoparticles from 10.9 to 4.0–5.5 nm, and the coated samples exhibit average hydrodynamic diameters ranging from 31 to 110 nm. The coating promotes the dispersibility of nanoparticles. Saturation magnetization is reduced from 60.3 to 5.6–7.1 emu/g in the coated MNPs due to the large weight ratio of the coating layer and the decrease in particle size. Hemolysis and cytotoxicity assay results indicate the excellent biocompatibility of Fe<sub>3</sub>O<sub>4</sub> nanoparticles. The cellular uptake assay confirms that both dextran- and carboxymethyl dextran–coated Fe<sub>3</sub>O<sub>4</sub> nanoparticles are easily taken in by breast cancer cells. Comprehensively considering dispersion, biocompatibility, and cellular uptake, the Fe<sub>3</sub>O<sub>4</sub>@CMD is more suitable for application in the bio-labeling of breast cancer cells. The SAR values of the Fe<sub>3</sub>O<sub>4</sub>@DEX and Fe<sub>3</sub>O<sub>4</sub>@CMD range from 19.2 to 30.7 W/g. The SAR value is mainly influenced by the hydrodynamic diameter in the coated samples. The Fe<sub>3</sub>O<sub>4</sub>@CMD20 shows the maximum SAR value of 30.7 W/g and has potential application in magnetic hyperthermia therapy.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"37 8-10","pages":"1453 - 1463"},"PeriodicalIF":1.6,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141514902","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-26DOI: 10.1007/s10948-024-06780-z
Mansour Benidris, Z. F. Mghoufel, M. A. Bennani, O. Akel
The method of linearized full-potential augmented plane waves based on density functional theory (DFT) is employed to investigate the structural, elastic, magnetic electronic, and thermoelectric properties of the cerium-based half-Heusler alloy FeCeSi. The exchange correlation functional is treated with the generalized gradient approximation of Perdew-Burke-Ernzerhof (GGA-PBE) and the Tran-Blaha-modified Beck-Johnson (TB-mBJ) as implemented in the Wien2k package. According to our results, we have discovered that the material studied is mechanically stable, which means that this compound can be synthesized experimentally. Furthermore, FeCeSi exhibits a half-metallic behavior obeying the Slater-Pauling rule with an integer magnetic moment of 2 μB. The electronic band structures and density of states confirm the half-metallic character with an indirect band gap equals to 0.51 eV and 0.59 eV for GGA-PBE and TB-mBJ approximation, respectively. For the study of the thermoelectric parameters, such as Seebeck coefficient (S), electrical conductivity (σ), thermal conductivity (κ), and figure of merit (ZT), the Boltzmann transport equations within the framework of DFT have been used. Significant values for the figure of merit and Seebeck coefficient indicate promising candidate for useful thermoelectric applications for FeCeSi alloy. So far, no experimental or theoretical investigations have been carried out on the half-Heusler alloy FeCeSi. Accordingly, our theoretical results concerning structural, elastic, electronic, magnetic, and thermoelectric properties will probably be confirmed by experimental investigations.
{"title":"Electronic, Structural, Thermodynamic, and Mechanical Stabilities, Half-Metallicity, and Thermoelectric Performances of CE-Based Half-Heusler","authors":"Mansour Benidris, Z. F. Mghoufel, M. A. Bennani, O. Akel","doi":"10.1007/s10948-024-06780-z","DOIUrl":"10.1007/s10948-024-06780-z","url":null,"abstract":"<div><p>The method of linearized full-potential augmented plane waves based on density functional theory (DFT) is employed to investigate the structural, elastic, magnetic electronic, and thermoelectric properties of the cerium-based half-Heusler alloy FeCeSi. The exchange correlation functional is treated with the generalized gradient approximation of Perdew-Burke-Ernzerhof (GGA-PBE) and the Tran-Blaha-modified Beck-Johnson (TB-mBJ) as implemented in the Wien2k package. According to our results, we have discovered that the material studied is mechanically stable, which means that this compound can be synthesized experimentally. Furthermore, FeCeSi exhibits a half-metallic behavior obeying the Slater-Pauling rule with an integer magnetic moment of 2 μB. The electronic band structures and density of states confirm the half-metallic character with an indirect band gap equals to 0.51 eV and 0.59 eV for GGA-PBE and TB-mBJ approximation, respectively. For the study of the thermoelectric parameters, such as Seebeck coefficient (S), electrical conductivity (σ), thermal conductivity (κ), and figure of merit (ZT), the Boltzmann transport equations within the framework of DFT have been used. Significant values for the figure of merit and Seebeck coefficient indicate promising candidate for useful thermoelectric applications for FeCeSi alloy. So far, no experimental or theoretical investigations have been carried out on the half-Heusler alloy FeCeSi. Accordingly, our theoretical results concerning structural, elastic, electronic, magnetic, and thermoelectric properties will probably be confirmed by experimental investigations.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"37 8-10","pages":"1603 - 1616"},"PeriodicalIF":1.6,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141547948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A high sensitivity photonic crystal fiber (PCF) magnetic field sensor based on Sagnac interferometer is proposed. All the air holes of the PCF are completely filled with the magnetic fluid (MF), which is a magnetic liquid material. The sensing performance of PCF is simulated and analyzed by using finite element method (FEM). It is found that the effects of wavelength λ, phase birefringence B(λ,H), and group birefringence Bg(λ,H) on the sensitivity are very significant. The two dip points in this spectrum show a red shift and a blue shift as the refractive index of the magnetic fluid increases, respectively. This magnetic field sensor obtains the average sensitivity of 889.5 pm/Oe (111,684.9 nm/RIU) and −994.3 pm/Oe (−124,839.5 nm/RIU) in the range from 90 to 240 Oe.
{"title":"High-Sensitivity MF Filled Photonic Crystal Fiber Magnetic Field Sensor Based on Sagnac Interferometer","authors":"Zhenkai Fan, Haishan Liu, Hailiang Chen, Shichao Chu, Shuguang Li, Yinping Zhang","doi":"10.1007/s10948-024-06761-2","DOIUrl":"10.1007/s10948-024-06761-2","url":null,"abstract":"<div><p>A high sensitivity photonic crystal fiber (PCF) magnetic field sensor based on Sagnac interferometer is proposed. All the air holes of the PCF are completely filled with the magnetic fluid (MF), which is a magnetic liquid material. The sensing performance of PCF is simulated and analyzed by using finite element method (FEM). It is found that the effects of wavelength <i>λ</i>, phase birefringence <i>B</i>(<i>λ</i>,<i>H</i>), and group birefringence <i>B</i><sub><i>g</i></sub>(<i>λ</i>,<i>H</i>) on the sensitivity are very significant. The two dip points in this spectrum show a red shift and a blue shift as the refractive index of the magnetic fluid increases, respectively. This magnetic field sensor obtains the average sensitivity of 889.5 pm/Oe (111,684.9 nm/RIU) and −994.3 pm/Oe (−124,839.5 nm/RIU) in the range from 90 to 240 Oe.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"37 8-10","pages":"1411 - 1419"},"PeriodicalIF":1.6,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141547951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-21DOI: 10.1007/s10948-024-06778-7
Anshu Gaur, Saarthak Dulgaj, Biswaranjan Sahu, S. Srinath
Structural, magnetic, and dielectric properties of (x)SrFe12O19-(1-(x))Ba0.85Ca0.15Ti0.9Zr0.1O3 multiferroic composite prepared by sintering the composite mixture of sol-gel synthesized SrFe12O19 (SrF) and Ba0.85Ca0.15Ti0.9Zr0.1O3 (BCTZ) are reported. Structural parameters (lattice parameter, bond length, and lattice strain) of parent phases in their pure and composite forms are correlated to indicate the lattice interaction between the two phases. The magnetic moment per gram of SrF (({M}_{SrF})) in the composite is higher than that in the SrF, related to the changes in the Fe-O-Fe bond angles. The room temperature dielectric response of the composites in the 100 Hz–10 MHz frequency range is modeled by the Cole–Cole relaxation and Jonscher power law equations to mark the different contributions (ferroelectric dipoles, charge carriers).
{"title":"Structural, Magnetic, and Dielectric Properties of SrFe12O19-Ba0.85Ca0.15Ti0.9Zr0.1O3 Composites","authors":"Anshu Gaur, Saarthak Dulgaj, Biswaranjan Sahu, S. Srinath","doi":"10.1007/s10948-024-06778-7","DOIUrl":"10.1007/s10948-024-06778-7","url":null,"abstract":"<div><p>Structural, magnetic, and dielectric properties of <span>(x)</span>SrFe<sub>12</sub>O<sub>19</sub>-(1-<span>(x)</span>)Ba<sub>0.85</sub>Ca<sub>0.15</sub>Ti<sub>0.9</sub>Zr<sub>0.1</sub>O<sub>3</sub> multiferroic composite prepared by sintering the composite mixture of sol-gel synthesized SrFe<sub>12</sub>O<sub>19</sub> (SrF) and Ba<sub>0.85</sub>Ca<sub>0.15</sub>Ti<sub>0.9</sub>Zr<sub>0.1</sub>O<sub>3</sub> (BCTZ) are reported. Structural parameters (lattice parameter, bond length, and lattice strain) of parent phases in their pure and composite forms are correlated to indicate the lattice interaction between the two phases. The magnetic moment per gram of SrF (<span>({M}_{SrF})</span>) in the composite is higher than that in the SrF, related to the changes in the Fe-O-Fe bond angles. The room temperature dielectric response of the composites in the 100 Hz–10 MHz frequency range is modeled by the Cole–Cole relaxation and Jonscher power law equations to mark the different contributions (ferroelectric dipoles, charge carriers).</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"37 5-7","pages":"1285 - 1291"},"PeriodicalIF":1.6,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141547949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-21DOI: 10.1007/s10948-024-06784-9
Somnath Das, Jacob Debbarma, Avijit Mondal, Premkumar Murugaiyan, Rajat K. Roy, Ashis K. Panda
Impact of shot peening on SS347 tube has been investigated using MagStrics, a magnetostrictive sensing (MsS) device comprising of rapidly quenched ribbon as sensor element. Two tubes of SS347 have been considered in pre- and post-shot peened state. Annealed ribbon as sensor element showed enhanced MsS signal. Using the annealed ribbon as sensor element, the MsS signal amplitude in shot peened tube was found to be distinctly different from un-peened sample. This was associated to magnetic phase evolutions in the pipe internal surface due to shot peening. Such phenomena have been endorsed through SEM–EDX compositional analysis and correlated through simulations using COMSOL Multiphysics.
{"title":"Evaluation of Shot Peened SS 347 Tubes Through a Magnetostrictive Sensing (MsS) Device","authors":"Somnath Das, Jacob Debbarma, Avijit Mondal, Premkumar Murugaiyan, Rajat K. Roy, Ashis K. Panda","doi":"10.1007/s10948-024-06784-9","DOIUrl":"10.1007/s10948-024-06784-9","url":null,"abstract":"<div><p>Impact of shot peening on SS347 tube has been investigated using MagStrics, a magnetostrictive sensing (MsS) device comprising of rapidly quenched ribbon as sensor element. Two tubes of SS347 have been considered in pre- and post-shot peened state. Annealed ribbon as sensor element showed enhanced MsS signal. Using the annealed ribbon as sensor element, the MsS signal amplitude in shot peened tube was found to be distinctly different from un-peened sample. This was associated to magnetic phase evolutions in the pipe internal surface due to shot peening. Such phenomena have been endorsed through SEM–EDX compositional analysis and correlated through simulations using COMSOL Multiphysics.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"37 5-7","pages":"1293 - 1298"},"PeriodicalIF":1.6,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141514904","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-21DOI: 10.1007/s10948-024-06769-8
Payal Bhattacharjee, Saswati Barman
Nowadays, the concept of non-trivial topological protection and the nanoscale size of nanomagnetic particles constitute a major area of research. Due to topological protection stability, nanoscale size, and the requirement of low spin current density for motion, skyrmions have attracted great attention in next-generation spintronic devices as robust information carriers. We study the motion of an isolated magnetic skyrmion with induced interfacial Dzyaloshinskii-Moriya interaction (iDMI) instigated by spin waves and driven by spin current with variation in different parameters in a nanotrack of finite length using micromagnetic simulations. It is found that the magnetic skyrmion moves in the same direction as the direction of propagation of the spin waves. The skyrmion initially experiences an acceleration in its motion; thereafter, the velocity decreases exponentially. The motion of the magnetic skyrmion initiates as the momentum of the spin wave gets transferred to it. The motion of the magnetic skyrmion is found to be significantly dependent on the variation of parameters like frequency and amplitude of the incident spin waves, as well as the damping parameter and the strength of the applied spin-polarized current. The results obtained in this work could become useful to design skyrmion-based spintronic information-carrying and storage devices.
{"title":"Tunable Magnetic Skyrmion Motion on a Nanostrip Using Current and Spin Waves: A Micromagnetic Study","authors":"Payal Bhattacharjee, Saswati Barman","doi":"10.1007/s10948-024-06769-8","DOIUrl":"10.1007/s10948-024-06769-8","url":null,"abstract":"<div><p>Nowadays, the concept of non-trivial topological protection and the nanoscale size of nanomagnetic particles constitute a major area of research. Due to topological protection stability, nanoscale size, and the requirement of low spin current density for motion, skyrmions have attracted great attention in next-generation spintronic devices as robust information carriers. We study the motion of an isolated magnetic skyrmion with induced interfacial Dzyaloshinskii-Moriya interaction (iDMI) instigated by spin waves and driven by spin current with variation in different parameters in a nanotrack of finite length using micromagnetic simulations. It is found that the magnetic skyrmion moves in the same direction as the direction of propagation of the spin waves. The skyrmion initially experiences an acceleration in its motion; thereafter, the velocity decreases exponentially. The motion of the magnetic skyrmion initiates as the momentum of the spin wave gets transferred to it. The motion of the magnetic skyrmion is found to be significantly dependent on the variation of parameters like frequency and amplitude of the incident spin waves, as well as the damping parameter and the strength of the applied spin-polarized current. The results obtained in this work could become useful to design skyrmion-based spintronic information-carrying and storage devices.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"37 8-10","pages":"1519 - 1527"},"PeriodicalIF":1.6,"publicationDate":"2024-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141547950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-20DOI: 10.1007/s10948-024-06774-x
Hasan Mahmud, Jamal Uddin Ahamed, Md. Nazrul Islam Khan
Conventional solid-state reaction method has been cautiously employed to prepare the Ba0.75Sr0.25Ti1−xMnxO3 ceramic where Sr was firmly doped at the Ba site and Mn was doped with different densities at the Ti site. Since the performance of materials varies with frequency, electric field, and temperature, we have elucidated the various features of the synthesized samples for the sake of scientific benefit in the fields of microelectronics, telecommunications, and spintronics. Structural and morphological features of the ready samples were examined by X-ray diffraction and scanning electron microscopy (SEM). The crystal's tetragonal behavior was verified by XRD analysis, and with the increment of Mn content, the volume of the unit cell is little changed. It is clear from the SEM images that the grain size of the prepared samples increases with Mn doping. The dielectric properties of Ba0.75Sr0.25Ti1−xMnxO3 were measured by dielectric constant and AC conductivity in a wide range of frequency from 1 kHz to 10 MHz. This result also explores that the dielectric constant rises with the concentration of Mn, most significantly for the 20% Mn substitution with Ti. We also found from the experimental result that the dielectric constant is high in the frequency range of 1–10 kHz. The magnetic permeability of the prepared sample increased with 10% and 20% of Mn replacement. Ferromagnetic features with a weak coercive field and the increased ferromagnetic order with rising Mn concentrations of the prepared samples were confirmed by VSM data analysis. The developed multiferroic materials can be employed in future spintronic devices like spin transistors, sensors, spin diodes, and memory devices.
我们谨慎地采用传统固态反应方法制备了 Ba0.75Sr0.25Ti1-xMnxO3 陶瓷,其中在 Ba 位点上牢固地掺入了 Sr,在 Ti 位点上以不同密度掺入了 Mn。由于材料的性能随频率、电场和温度的变化而变化,我们阐明了合成样品的各种特征,以便在微电子学、电信和自旋电子学领域产生科学效益。我们利用 X 射线衍射和扫描电子显微镜(SEM)研究了制备好的样品的结构和形态特征。X 射线衍射分析验证了晶体的四方特性,而且随着锰含量的增加,单位晶胞的体积变化不大。从扫描电镜图像中可以明显看出,制备的样品晶粒尺寸随着锰的掺入而增大。通过介电常数和交流电导率测量了 Ba0.75Sr0.25Ti1-xMnxO3 在 1 kHz 至 10 MHz 宽频率范围内的介电性能。这一结果还发现,介电常数随 Mn 浓度的增加而上升,其中以 Mn 含量为 20% 的 Ti 替代物的介电常数上升最为明显。我们还从实验结果中发现,介电常数在 1-10 kHz 频率范围内较高。制备的样品的磁导率随着 10%和 20%的锰置换量的增加而增加。VSM 数据分析证实了制备的样品具有弱矫顽力场的铁磁性特征,以及随着锰浓度的增加而增加的铁磁阶数。所开发的多铁氧体材料可用于未来的自旋电子器件,如自旋晶体管、传感器、自旋二极管和存储器件。
{"title":"Study the Effect of Mn-Substitution on the Structural, Magnetic, and Dielectric Properties of Ba0.75Sr0.25Ti1−xMnxO3 Ceramics","authors":"Hasan Mahmud, Jamal Uddin Ahamed, Md. Nazrul Islam Khan","doi":"10.1007/s10948-024-06774-x","DOIUrl":"10.1007/s10948-024-06774-x","url":null,"abstract":"<div><p>Conventional solid-state reaction method has been cautiously employed to prepare the Ba<sub>0.75</sub>Sr<sub>0.25</sub>Ti<sub>1−<i>x</i></sub>Mn<sub><i>x</i></sub>O<sub>3</sub> ceramic where Sr was firmly doped at the Ba site and Mn was doped with different densities at the Ti site. Since the performance of materials varies with frequency, electric field, and temperature, we have elucidated the various features of the synthesized samples for the sake of scientific benefit in the fields of microelectronics, telecommunications, and spintronics. Structural and morphological features of the ready samples were examined by X-ray diffraction and scanning electron microscopy (SEM). The crystal's tetragonal behavior was verified by XRD analysis, and with the increment of Mn content, the volume of the unit cell is little changed. It is clear from the SEM images that the grain size of the prepared samples increases with Mn doping. The dielectric properties of Ba<sub>0.75</sub>Sr<sub>0.25</sub>Ti<sub>1−<i>x</i></sub>Mn<sub><i>x</i></sub>O<sub>3</sub> were measured by dielectric constant and AC conductivity in a wide range of frequency from 1 kHz to 10 MHz. This result also explores that the dielectric constant rises with the concentration of Mn, most significantly for the 20% Mn substitution with Ti. We also found from the experimental result that the dielectric constant is high in the frequency range of 1–10 kHz. The magnetic permeability of the prepared sample increased with 10% and 20% of Mn replacement. Ferromagnetic features with a weak coercive field and the increased ferromagnetic order with rising Mn concentrations of the prepared samples were confirmed by VSM data analysis. The developed multiferroic materials can be employed in future spintronic devices like spin transistors, sensors, spin diodes, and memory devices.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"37 8-10","pages":"1569 - 1584"},"PeriodicalIF":1.6,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141514906","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-20DOI: 10.1007/s10948-024-06771-0
K. Sai Maneesh, Himalay Basumatary, C. Vishnu Mohan Rao, Radhika Chada, M. Manivel Raja
In this paper, we report a systematic study on effect of film thickness and substrate temperature on structural and magnetic behaviour of Fe-Ga films with Cu buffer layer, deposited on Si and Si/SiO2 substrates at room and high substrate temperatures. Grazing incidence X-ray diffraction studies reveal that all the films are crystalline with disordered alpha-Fe phase, which is BCC A2 phase. At 300 °C of substrate temperature, films deposited on Si/SiO2 substrate found to nucleate L12 phase from matrix of A2 phase, which is not seen in Si based films. Irrespective of substrate material, Fe-Ga films found to exist in dual phases at 500 °C substrate temperature. Lattice strains of the films were calculated from X-ray diffraction patterns, using Williamson-Hall method. From X- ray reflectivity analysis of all the films, film density, thickness and roughness of Fe-Ga layer and buffer layer were obtained after fitting the reflectivity data. Presence of an oxide layer is also evident from reflectivity fitting analysis. From magnetization studies it is clear that, all the films exhibited strong in-plane anisotropy. Saturation magnetization of films was found to vary with change in film density and oxide layer thickness of films. Saturation magnetization of films deposited on Si substrates found to decrease with decrease in film density. Coercivity of films found to vary with change in crystallite size, interface roughness and lattice strain of films. Films deposited on Si substrates are sensitive to strain with change in film thickness and films deposited on Si/SiO2 substrates are sensitive to strain with change in deposition temperature. Coercivity in films found to decrease with decrease in film roughness, increase in crystallite size and lowering the tensile lattice strain.
在本文中,我们系统地研究了在室温和高基底温度下,沉积在硅基底和硅/二氧化硅基底上带有铜缓冲层的铁-镓薄膜的薄膜厚度和基底温度对其结构和磁性行为的影响。平射入射 X 射线衍射研究表明,所有薄膜都是晶体,具有无序的α-铁相,即 BCC A2 相。在 300 °C 的基底温度下,发现沉积在硅/二氧化硅基底上的薄膜会从 A2 相的基质中形成 L12 相,这在硅基薄膜中是看不到的。无论基底材料如何,在基底温度为 500 ℃ 时,Fe-Ga 薄膜都存在双相。薄膜的晶格应变是利用威廉森-霍尔法从 X 射线衍射图谱中计算出来的。通过对所有薄膜的 X 射线反射率分析,拟合反射率数据后得出了铁-镓层和缓冲层的薄膜密度、厚度和粗糙度。从反射率拟合分析中还可以明显看出氧化层的存在。磁化研究表明,所有薄膜都表现出很强的面内各向异性。薄膜的饱和磁化率随薄膜密度和氧化层厚度的变化而变化。在硅基底上沉积的薄膜的饱和磁化率随着薄膜密度的降低而降低。发现薄膜的矫顽力随薄膜晶粒大小、界面粗糙度和晶格应变的变化而变化。沉积在硅基底上的薄膜对薄膜厚度变化产生的应变很敏感,而沉积在硅/二氧化硅基底上的薄膜对沉积温度变化产生的应变很敏感。薄膜的矫顽力会随着薄膜粗糙度的减小、晶体尺寸的增大和拉伸晶格应变的降低而降低。
{"title":"Structural and Magnetization Studies of Cu Buffered Fe-Ga Films Grown on Si and Si/SiO2 Substrates","authors":"K. Sai Maneesh, Himalay Basumatary, C. Vishnu Mohan Rao, Radhika Chada, M. Manivel Raja","doi":"10.1007/s10948-024-06771-0","DOIUrl":"10.1007/s10948-024-06771-0","url":null,"abstract":"<div><p>In this paper, we report a systematic study on effect of film thickness and substrate temperature on structural and magnetic behaviour of Fe-Ga films with Cu buffer layer, deposited on Si and Si/SiO<sub>2</sub> substrates at room and high substrate temperatures. Grazing incidence X-ray diffraction studies reveal that all the films are crystalline with disordered alpha-Fe phase, which is BCC A2 phase. At 300 °C of substrate temperature, films deposited on Si/SiO<sub>2</sub> substrate found to nucleate L1<sub>2</sub> phase from matrix of A2 phase, which is not seen in Si based films. Irrespective of substrate material, Fe-Ga films found to exist in dual phases at 500 °C substrate temperature. Lattice strains of the films were calculated from X-ray diffraction patterns, using Williamson-Hall method. From X- ray reflectivity analysis of all the films, film density, thickness and roughness of Fe-Ga layer and buffer layer were obtained after fitting the reflectivity data. Presence of an oxide layer is also evident from reflectivity fitting analysis. From magnetization studies it is clear that, all the films exhibited strong in-plane anisotropy. Saturation magnetization of films was found to vary with change in film density and oxide layer thickness of films. Saturation magnetization of films deposited on Si substrates found to decrease with decrease in film density. Coercivity of films found to vary with change in crystallite size, interface roughness and lattice strain of films. Films deposited on Si substrates are sensitive to strain with change in film thickness and films deposited on Si/SiO<sub>2</sub> substrates are sensitive to strain with change in deposition temperature. Coercivity in films found to decrease with decrease in film roughness, increase in crystallite size and lowering the tensile lattice strain.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"37 5-7","pages":"1269 - 1283"},"PeriodicalIF":1.6,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141514907","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this paper, we have investigated the magnetic and magnetocaloric characteristics of a La2MnNiO6 composite, in conjunction with La2MnCoO6. This composite consists of two phases of double perovskite materials. Employing the mean-field approximation, we successfully modeled how magnetization and the change in magnetic entropy vary with temperature under different magnetic fields in our samples. This phenomenological model helped us also plot the maximum magnetic entropy change (-ΔSM)max, full width at half-maximum δTFWHM, and relative cooling power (RCP). Our analysis has revealed an optimal plateau-type magnetocaloric effect near room temperature, corresponding to a specific composition x between 0.2 and 0.5. Ultimately, this theoretical model lets us predict the magnetic and magnetocaloric behavior of composite materials, providing a foundation for future studies.
{"title":"A Phenomenological Approach for Predicting Magnetic and Magnetocaloric Properties in the (La2MnNiO6)x / (La2MnCoO6)1−x Composite","authors":"Abderrazak Boubekri, Zakaria Elmaddahi, Younes Jarmoumi, Karima Gueddouch, Abdeslam Farchakh, Mohamed EL Hafidi","doi":"10.1007/s10948-024-06777-8","DOIUrl":"10.1007/s10948-024-06777-8","url":null,"abstract":"<div><p>In this paper, we have investigated the magnetic and magnetocaloric characteristics of a La<sub>2</sub>MnNiO<sub>6</sub> composite, in conjunction with La<sub>2</sub>MnCoO<sub>6</sub>. This composite consists of two phases of double perovskite materials. Employing the mean-field approximation, we successfully modeled how magnetization and the change in magnetic entropy vary with temperature under different magnetic fields in our samples. This phenomenological model helped us also plot the maximum magnetic entropy change (-ΔS<sub>M</sub>)<sub>max</sub>, full width at half-maximum δT<sub>FWHM</sub>, and relative cooling power (RCP). Our analysis has revealed an optimal plateau-type magnetocaloric effect near room temperature, corresponding to a specific composition <i>x</i> between 0.2 and 0.5. Ultimately, this theoretical model lets us predict the magnetic and magnetocaloric behavior of composite materials, providing a foundation for future studies.</p></div>","PeriodicalId":669,"journal":{"name":"Journal of Superconductivity and Novel Magnetism","volume":"37 8-10","pages":"1401 - 1410"},"PeriodicalIF":1.6,"publicationDate":"2024-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141552706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}