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2021 IEEE 48th Photovoltaic Specialists Conference (PVSC)最新文献

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First-principles study on the role of silicon point defects on PERC solar cell degradation 硅点缺陷对PERC太阳能电池降解作用的第一性原理研究
Pub Date : 2021-06-20 DOI: 10.1109/PVSC43889.2021.9518589
Elisa Tejeda-Zacarias, P. Baranek, H. Vach
One of the causes of decrease in the performance of silicon-based solar pannels is linked to light and elevated temperature induced degradation (LeTID). Even if experimental evidence shows that different defects in the bulk material of the modules are involved in the mechanisms behind LeTID, its origins remain unresolved. First-principles methods result in powerful tools to understand this degradation at the nano and microscopic levels. In the present work we propose an approach to model LeTID precursor mechanisms by using ab initio methodology.
硅基太阳能电池板性能下降的原因之一与光和高温引起的降解(LeTID)有关。即使实验证据表明,模块体材料中的不同缺陷与LeTID背后的机制有关,但其起源仍未得到解决。第一性原理方法是在纳米和微观水平上理解这种降解的有力工具。在目前的工作中,我们提出了一种利用从头算方法来模拟LeTID前体机制的方法。
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引用次数: 0
Sustainable framework for Global Solar EXIM as a Stimulus to Supply Value Chain in India 全球太阳能进出口银行的可持续框架作为印度供应链的刺激
Pub Date : 2021-06-20 DOI: 10.1109/PVSC43889.2021.9518925
Mohiddin Sk, D. Barki, Ravi Shankar Dvb, K. Kumar K
The world’s unquestionable dependence on the Chinese solar manufacturing industry has been constant over two decades and particularly intense since the nation’s supremacy was confirmed before the onset of the 2008 global financial crisis. Despite years of trade wars, anti-dumping measures and retaliations, the Chinese PV industry is at its apogee while European manufacturers (actually the ROW) struggle. India, South Korea, Taiwan and Japan have seen their module and cell makers surrender ever more ground to the Chinese giants in recent years. The disruption caused by Covid-19 on Chinese manufacturing prompted arguably the first jolt on the global solar supply chain, with the resulting shortage of PV components compounding virus containment measures around the world to disrupt the industry. In this paper, we discuss how this complex situation can be mitigated through EXIM exercises and efforts on securing the Solar Supply Chain highlights demand opportunities and key issues for the solar manufacturing supply chain to provide policy recommendations to enable creation of a strong supply chain for solar energy in India.
尽管经历了多年的贸易战、反倾销措施和报复,中国光伏产业正处于鼎盛时期,而欧洲制造商(实际上是欧洲国家)却在苦苦挣扎。近年来,印度、韩国、台湾和日本的组件和电池制造商向中国巨头交出了越来越多的地盘。新冠肺炎对中国制造业造成的破坏可以说是全球太阳能供应链的第一次震动,由此导致的光伏组件短缺加上世界各地的病毒遏制措施,扰乱了该行业。在本文中,我们讨论了如何通过进出口银行的演习和努力来缓解这种复杂的情况,以确保太阳能供应链的安全,重点介绍了太阳能制造供应链的需求机会和关键问题,并提供了政策建议,以便在印度建立一个强大的太阳能供应链。
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引用次数: 0
On the use of AI as a requirement for improved insolation forecasting accuracy to achieve optimized PV utilization 关于使用人工智能作为提高日照预测精度以实现PV利用率优化的要求
Pub Date : 2021-06-20 DOI: 10.1109/PVSC43889.2021.9518470
M. Ghiassi, A. Skumanich
With the increase in data, the challenges of complex data, and the financial implications of improved insolation accuracy, it has become necessary to include targeted Artificial Intelligence & Machine Learning (AI/ML) for insolation forecasting. Forecasting is a crucial and cost-effective tool for integrating variable renewable resources into power systems. The ability to accurately forecast irradiance will facilitate increased PV adoption on the grid by making the intermittency less disrupting and allowing for better PV utilization, directly assisting in reduction of carbon energy sources.A key problem in solar forecasting is the intermittency of cloud cover, which often exhibits fractal properties and is still challenging to predict and adversely impacts solar farm output management. The physical models which cover weather can only provide a certain level of predictive accuracy and are particularly challenged by cloud forecasting. The key challenges are: limitations in the physical models, massive data, the need to make substantial simplifying estimations.We propose an approach and methodology which can enhance the predictive capabilities of insolation forecasting based on, and leveraging, a type of "bundled" approach which takes into account both the physical models, as well as the empirical mode determined by AI/ML, and exploiting sensor and satellite inputs. The novel aspect is to expand the AI/ML empirical dimension to achieve improved forecasting where the "non-physical-model" modes provide substantial input. We outline the specific methodology, how this is different from current modes, and how it can improve insolation forecasting. Specific examples will be provided and the benefits discussed.
随着数据的增加,复杂数据的挑战以及提高日照精度的财务影响,有必要将有针对性的人工智能和机器学习(AI/ML)纳入日照预测。预测是将可变的可再生资源纳入电力系统的一种重要的、具有成本效益的工具。准确预测辐照度的能力将通过减少间歇性中断和更好地利用光伏发电,直接帮助减少碳能源,从而促进光伏发电在电网中的采用。太阳预报中的一个关键问题是云覆盖的间歇性,它通常表现为分形特性,仍然具有挑战性,并对太阳能发电场的输出管理产生不利影响。覆盖天气的物理模式只能提供一定程度的预测准确性,尤其受到云预报的挑战。关键的挑战是:物理模型的局限性,海量的数据,需要进行大量的简化估计。我们提出了一种方法和方法,可以增强基于并利用一种“捆绑”方法的预测能力,该方法既考虑了物理模型,也考虑了由AI/ML确定的经验模式,并利用了传感器和卫星输入。新颖的方面是扩展AI/ML经验维度,以实现改进的预测,其中“非物理模型”模式提供了大量输入。我们概述了具体的方法,它与当前模式的不同之处,以及它如何改善日照预测。将提供具体的例子并讨论其好处。
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引用次数: 0
Create High-Aspect-Ratio Silicon Nanostructures Using Metal-Assisted Chemical Etching (MACE) Technique 使用金属辅助化学蚀刻(MACE)技术创建高纵横比硅纳米结构
Pub Date : 2021-06-20 DOI: 10.1109/PVSC43889.2021.9518753
N. E. A. Razak, N. Amin, T. S. Kiong, K. Sopian, M. Akhtaruzzaman
Silicon nanostructures are one of the candidates for tomorrow technologies due to its novel physical properties. High-aspect-ratio silicon nanostructures have been proved as effective microstructures for enhance silicon solar cells efficiency. Silicon nanowires enhance solar cells efficiency by formation vertical well aligned nanowires on the top surfaces which give effects to the optical, electronic and physical properties of silicon solar cells. Silicon nanowires also can enhance the carrier collection of photovoltaic devices. There are two types of methods used to fabricate silicon nanowires such as top-down or bottom-up fabrication. One of the techniques to get high-aspect-ratio nanostructures is by using metal-assisted chemical etching (MACE). Metal-assisted chemical etching (MACE) technique has been adopted in many research experiments and technology due to its low cost fabrication of silicon nanowires but can form a high-aspect-ratio of silicon nanowires. MACE has demonstrates outstanding results of silicon nanowires in improving many microelectronics and photonic devices. Traditionally, MACE is operated by making a holes using metal catalyst in order to reduce of using the etchant. The mobility of the reactants impeded when the height of silicon nanowires increases which resulting insufficient holes. However, MACE also has advantages and drawbacks which appear such as long-vertical-well aligned silicon nanowires and some broken silicon nanowires due to very thin silicon nanowires which easily to break, respectively. In this paper, different solutions concentration is study using a two-step MACE process. The chemical solution contains HF/AgNO3 and also H2O2. The experiment is conducted at room temperature. During the etching process, anisotropic growth different silver particles which used for the formation of the silicon nanowires on silicon wafer surfaces. As a results, the etch rate gives the effect on the silicon nanowires length. A comparative study of etch rate has been conducted in order to see clearly the differences.
硅纳米结构由于其新颖的物理特性而成为未来技术的候选之一。高纵横比硅纳米结构已被证明是提高硅太阳能电池效率的有效微结构。硅纳米线通过在硅太阳能电池的顶部表面形成垂直排列的纳米线来提高电池的效率,从而对硅太阳能电池的光学、电子和物理性能产生影响。硅纳米线还可以增强光电器件的载流子收集。硅纳米线的制造方法主要有自顶向下和自底向上两种。金属辅助化学蚀刻(MACE)是获得高纵横比纳米结构的技术之一。金属辅助化学蚀刻(MACE)技术由于其制备硅纳米线的成本低,但可以形成高纵横比的硅纳米线,已被许多研究实验和技术所采用。硅纳米线在改进许多微电子和光子器件方面取得了突出的成果。为了减少蚀刻剂的使用,传统的MACE是通过使用金属催化剂打孔来操作的。当硅纳米线的高度增加时,反应物的迁移受到阻碍,导致空穴不足。然而,MACE也有优点和缺点,分别表现为硅纳米线垂直排列较长,硅纳米线很细,容易断裂。本文采用两步MACE工艺对不同溶液浓度进行了研究。化学溶液中含有HF/AgNO3和H2O2。实验是在室温下进行的。在蚀刻过程中,不同的银粒子在硅片表面各向异性生长,用于形成硅纳米线。因此,蚀刻速率对硅纳米线的长度有影响。为了清楚地看到两者之间的差异,对腐蚀速率进行了比较研究。
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引用次数: 1
Development of a High-Efficiency Lightweight Solar Array for Deep-Space Missions 用于深空任务的高效轻质太阳能阵列的研制
Pub Date : 2021-06-20 DOI: 10.1109/PVSC43889.2021.9518742
A. Boca, Clara A. MacFarland, J. Schwartz, J. Grandidier, M. McEachen, Jim Spink, M. Eskenazi, C. McPheeters, Lance Fesler, B. Cho
Solar arrays are highly versatile, relatively low cost, and readily available, which is why they have been the power source of choice for the vast majority of NASA's space science missions so far, from the Sun's corona at 0.04 AU to the orbit of Jupiter at 5.5 AU. The Jet Propulsion Laboratory is currently investigating whether the capability range of solar arrays can be viably extended even further out into deep space, all the way to the orbit of Saturn at 9.5 AU, and possibly beyond. We therefore set out to develop a solar array technology that is optimized for operating in deep space, thereby promising substantial mass and cost savings relative to currently available power sources. This paper summarizes recent progress we have made towards developing a solar array capable of ~3 W/kg end of mission specific power at Saturn, and towards demonstrating its performance in the relevant environment.
太阳能电池阵列用途广泛,成本相对较低,而且容易获得,这就是为什么到目前为止,从0.04天文单位的太阳日冕到5.5天文单位的木星轨道,它们一直是美国宇航局绝大多数太空科学任务的动力源。喷气推进实验室目前正在研究太阳能电池阵列的能力范围是否可以扩展到更远的深空,一直延伸到9.5天文单位的土星轨道,甚至可能更远。因此,我们着手开发一种太阳能电池阵列技术,这种技术可以在深太空中运行,因此与目前可用的电源相比,有望大幅降低质量和成本。本文总结了我们最近在开发一种能够在土星上达到~ 3w /kg任务特定功率的太阳能电池阵列方面取得的进展,并在相关环境中展示了它的性能。
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引用次数: 0
Low non-radiative recombination loss in CsPbI2Br perovskite solar cells CsPbI2Br钙钛矿太阳能电池的低非辐射复合损失
Pub Date : 2021-06-20 DOI: 10.1109/PVSC43889.2021.9518869
Wenzhan Xu, Yu Gao, F. Kang, Guo-dan Wei
All-inorganic CsPbI2Br has attracted intensive attention due to its superior stability against thermal aging and light soaking. However, a large open circuit voltage (VOC) loss results from non-radiative recombination and the mismatched energy level alignment between CsPbI2Br and SnO2/Spiro-MeOTAD charge carrier extraction layer, has been discussed and rarely solved. Perovskite solar cells have theoretically a high value of VOC that can be obtained relative to the wide bandgap. Herein, IC61BA has been employed to modify the SnO2 surface to reduce surface defects, at the same time, a moderate energy level (CsPbI2Br)1-x(CsPbI3)x layer has been introduced at the interface between CsPbI2Br and Spiro-MeOTAD to form graded energy level alignment. As a result, correspondingly, the surface passivation and energy level tailoring reduced the energy level loss from reduced non-radiative recombination and a remarkable open circuit voltage (VOC) improved from 1.13 V to 1.34 V has been achieved, which further boosts the power conversion efficiency (PCE) of 15.56%.
全无机CsPbI2Br因其优异的抗热老化和光浸泡稳定性而受到广泛关注。然而,CsPbI2Br与SnO2/Spiro-MeOTAD载流子萃取层之间的非辐射复合和能级错位导致的大开路电压(VOC)损失已经被讨论过,但很少得到解决。钙钛矿太阳能电池理论上具有较高的VOC值,可以相对于宽的带隙获得。本文采用IC61BA对SnO2表面进行改性以减少表面缺陷,同时在CsPbI2Br与Spiro-MeOTAD的界面处引入中等能级(CsPbI2Br)1-x(CsPbI3)x层,形成梯度能级排列。相应地,表面钝化和能级裁剪降低了非辐射复合的能级损失,开路电压(VOC)从1.13 V提高到1.34 V,进一步提高了功率转换效率(PCE),达到15.56%。
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引用次数: 0
A Comparative Study of the Structural and Electronic Properties of Orthorhombic and Cubic CsPbI3 and Trigonal CsGeI3 using First-Principles Calculations 用第一性原理计算比较正交立方CsPbI3和三角cspgei3的结构和电子性质
Pub Date : 2021-06-20 DOI: 10.1109/PVSC43889.2021.9518858
Saeed S. I. Almishal, Ola Rashwan
Lead-free halide perovskites are of great importance as prospective materials for efficient solar cells. Germanium is a very promising non-toxic alternative to lead. In this study, the crystal configuration, projected density of states and band structure of the trigonal CsGeI3, the yellow and the quenched black orthorhombic CsPbI3, and the cubic CsPbI3 were investigated using the density functional theory with Perdew-Burke-Ernzerhof functional. Our calculations showed that for the CsGeI3, the valence band maximum is mainly contributed by the I 5p and Ge 4s orbitals whereas the conduction band minimum is mainly contributed by the Ge 4p orbitals. The replacement of Pb with Ge results in a narrower bandgap.
无铅卤化物钙钛矿作为高效太阳能电池材料具有重要的应用前景。锗是一种非常有前途的无毒铅替代品。本文利用Perdew-Burke-Ernzerhof泛函的密度泛函理论研究了三角形cgei3、黄色和淬火黑色正交CsPbI3和立方CsPbI3的晶体构型、投射态密度和能带结构。计算结果表明,对于CsGeI3,价带最大值主要由i5p和ge4s轨道贡献,而导带最小值主要由ge4p轨道贡献。用Ge代替Pb可使带隙变窄。
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引用次数: 1
Utilization of ultra-thin n-type Hydrogenated Nanocrystalline Silicon for Silicon Heterojunction Solar Cells 超薄n型氢化纳米晶硅在硅异质结太阳能电池中的应用
Pub Date : 2021-06-20 DOI: 10.1109/PVSC43889.2021.9518937
Depeng Qiu, Weiyuan Duan, A. Lambertz, K. Bittkau, Kaifu Qiu, K. Ding
To optimize the electrical performance of silicon heterojunction solar cell devices, the electronic properties and microstructure of n-type nc-Si:H were characterized and analyzed. It was found that higher conductivity and crystalline volume fraction (Fc) of nc-Si:H can be obtained at lower silane gas fraction (fSiH4), lower power and higher phosphorous gas fraction (fPH3). In our case, there is a decline of the passivation for the devices with nc-Si:H after sputtering process. By increasing the phosphine flow fraction, the sputter damage can be reduced and 3%abs gain of FF as well as 0.7%abs gain of efficiency is reached compared with reference. The best solar cell exhibits the Voc of 733.3 mV, FF of 79.7%, Jsc of 39.00 mA/cm2 and η of 22.79% at the M2 size wafer.
为了优化硅异质结太阳能电池器件的电性能,对n型nc-Si:H的电子性能和微观结构进行了表征和分析。结果表明,在较低硅烷气体分数(fSiH4)、较低功率和较高磷气体分数(fPH3)条件下,nc-Si:H的电导率和结晶体积分数(Fc)较高。在我们的案例中,在溅射过程中,nc-Si:H器件的钝化程度有所下降。通过提高磷化氢的流动分数,可以减少溅射损伤,使FF的abs增益达到3%,效率增益达到0.7%。最佳太阳能电池在M2尺寸晶圆上的Voc为733.3 mV, FF为79.7%,Jsc为39.00 mA/cm2, η为22.79%。
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引用次数: 0
Notable changes in the performance of a photovoltaic system due to the dirt and cleaning cycles of PV-array 由于光伏阵列的污垢和清洁周期,光伏系统的性能发生了显著变化
Pub Date : 2021-06-20 DOI: 10.1109/PVSC43889.2021.9518611
M. G. Moheyer, Marco A. Ramos, Edgar R. Sandoval, N. Pitalua-Diaz, R. Asomoza, G. Romero-Paredes, Y. Matsumoto
Performance ratio (PR) of 60 kWp photovoltaic system (PVS) were measured considering the soiling effect in the interval of December 2019 to January 2020. Towards final week of December 2019, the PVS started showing a poor PR due to the natural soiling in a photovoltaic-array, but due to rainfall at mid-January 2020, the PR was recuperated. The average PR for January was 71.1%, but the cleaned PV-array by the rainfall showed an about 14 points of increment in energy generation from 63.3 to 77.3 %. Also, it is discussed the average generated energy during 2019 which was 267.8 kWh/day and in 2020, it was 273.3 kWh/day, with the corresponding PR of 76.7% and 76.8%, respectively.
在2019年12月至2020年1月期间,测量了考虑污染效应的60 kWp光伏系统(pv)的性能比(PR)。在2019年12月的最后一周,由于光伏阵列的自然污染,pv开始显示出较差的PR,但由于2020年1月中旬的降雨,PR得到了恢复。1月份的平均PR为71.1%,但经过降雨清洗的光伏阵列的发电量从63.3%增加到77.3%,增加了约14个点。并讨论了2019年和2020年的平均发电量分别为267.8 kWh/d和273.3 kWh/d,相应的PR分别为76.7%和76.8%。
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引用次数: 0
Toward a highly efficient large surface Perovskite Silicon 4-Terminal tandem module 一种高效的大表面钙钛矿硅4端串联模块
Pub Date : 2021-06-20 DOI: 10.1109/PVSC43889.2021.9518929
Emilie Raoult, Thomas Guillemot, Sophie Bernard, Marion Provost, V. Daniau, Armelle Yaiche, N. Schneider, Damien Coutancier, R. Bodeux, S. Collin, J. Rousset, Sébastien Jutteau
This work presents a path to the fabrication of highly efficient, large size 4-Terminal (4T) perovskite silicon tandem. As a first step, our deposition process of perovskite based on spin coating was transferred to slot die coating, enabling large surface areas. Simultaneously, a semitransparent perovskite solar cell was designed to ensure a high optical transmission in the near-infrared (NIR) and we achieved a transmission of 90% at 900 nm, in good agreement with the optical simulation. As a second step, a stack reproducing the perovskite solar cell has been packaged with an n-PERT silicon cell in a box printed in 3D to form a pseudo-tandem with 16 cm2 active area. This device allows to guarantee its durability and to precisely assess the performances of the filtered silicon bottom cell thanks to correct optical alignment. It also minimizes optical losses between both silicon bottom and perovskite top cells. Combining a 16.9% perovskite top cell (active surface of 0.09 cm2) deposited by slot die and a 6.4% filtered silicon bottom cell results in an efficiency of 23.3% for a 4T tandem solar cell. Moreover, a filtered silicon solar with 8.2% efficiency is obtained using a perovskite solar cell stack optimized for NIR. The fabrication of 4T tandem over 16 cm2 active area are currently in progress and will be discussed.
本研究为高效、大尺寸4端(4T)钙钛矿硅串联材料的制备提供了一条途径。作为第一步,我们将基于自旋涂层的钙钛矿沉积工艺转移到槽模涂层上,从而实现了更大的表面积。同时,设计了一种半透明的钙钛矿太阳能电池,以确保在近红外(NIR)的高透光率,我们在900 nm处实现了90%的透光率,与光学模拟很好地吻合。第二步,将重现钙钛矿太阳能电池的堆叠与n-PERT硅电池封装在3D打印的盒子中,形成具有16 cm2活性面积的伪串联。由于正确的光学校准,该设备可以保证其耐用性,并精确评估过滤硅底电池的性能。它还最大限度地减少了硅底部和钙钛矿顶部电池之间的光学损耗。将槽型晶片沉积的16.9%钙钛矿顶部电池(活性表面为0.09 cm2)和6.4%过滤硅底部电池相结合,4T串联太阳能电池的效率为23.3%。此外,采用针对近红外优化的钙钛矿太阳能电池堆,获得了效率为8.2%的过滤硅太阳能电池。超过16平方厘米活性面积的4T串联的制造目前正在进行中,并将讨论。
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引用次数: 0
期刊
2021 IEEE 48th Photovoltaic Specialists Conference (PVSC)
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