Materials for Renewable and Sustainable Energy最新文献

In this research, treated metakaolinite (TMK) was introduced into the TiO₂ photoelectrode to fabricated dye-sensitized solar cells (DSSCs). The photovoltaic cells have four main natural components, i.e., a photosensitizer (carotenoid bixin), photoelectrode (TiO₂/kaolinite), electrolyte (glycerine carbonate derivative), and counter-electrode (carbon). Their stability, reusability, and equivalent circuit were studied. The presence of 5% of TMK in anatase TiO₂ paste decreased the TiO₂ band gap from 3.21 to 3.16?eV. The result showed that the presence of 5% of TMK in TiO₂ paste was more favorable to obtain higher energy conversion efficiency. Under a light intensity of 200?W/m², it produced an energy conversion yield of 0.086%. The combination of the electrolyte and the TMK demonstrated a synergistic effect to improve the electrical properties of the DSSC. The energy storage function worked well until the third day of analysis. The DSSC based on TiO₂/TMK photoelectrode exhibited 16 times better stability than pure TiO₂-based photoelectrode. The Faraday charge transfer processes showed that the TiO₂/TMK photoelectrode is not in direct contact with the carbon counter-electrode.

Understanding the mechanism of CO₂ reduction on iron is crucial for the design of more efficient and cheaper iron electrocatalyst for CO₂ conversion. In the present study, we have employed spin-polarized density functional theory calculations within the generalized gradient approximation (DFT-GGA) to elucidate the mechanism of CO₂ reduction into carbon monoxide and formic acid on the Fe (100) facet. We also sort to understand the transformations of the other isomers of adsorbed CO₂ on iron as earlier mechanistic studies are centred on the transformations of the C_2v geometry alone and not the other possible conformations i.e., flip-C_2v and Cs modes. Two alternative reduction routes were considered i.e., the direct CO₂ dissociation against the hydrogen-assisted CO₂ transformation through formate and carboxylate into CO and formic acid. Our results show that CO₂ in the C_2v mode is the precursor to the formation of both products i.e., CO and formic acid. Both the formation and transformation of CO₂ in the Cs and flip-C_2v is challenging kinetically and thermodynamically compared to the C_2v mode. The formic acid formation is favoured over CO via the reverse water gas shift reaction mechanism on Fe (100). Both formic acid formation and CO formation will proceed via the carboxylate intermediate since formate is a stable intermediate whose transformation into formic acid is challenging both kinetically and thermodynamically.

The electrochemical production of green and low-cost ammonia requests the development of high-performance electrocatalysts. In this work, the ampoule method was applied to modulate the surface of the zinc electrode by implanting defects and low-valent active sites. The N-doped ZnS electrocatalyst was thus generated by sulfurization with thiourea and applied for electrocatalytic nitrogen reduction reaction (ENRR). Given the rich sulfur vacancies and abundant Zn-N active sites on the surface, excellent catalytic activity and selectivity were obtained, with an NH₃ yield rate of 2.42?×?10^–10?mol?s^?1?cm^?2 and a Faradaic efficiency of 7.92% at ??0.6?V vs. RHE in 0.1?M KOH solution. Moreover, the as-synthesized zinc electrode exhibits high stability after five recycling tests and a 24?h potentiostatic test. The comparison with Zn foil, non-doping ZnS/Zn and recent metal sulfide electrocatalysts further demonstrated advanced catalytic performance of N@ZnS/Zn for ENRR. By simple synthesis, S vacancies, and N-doping defects, this promising electrocatalyst would represent a good addition to the arena of transition-metal-based catalysts with superior performance in ENRR.

This study has investigated the effect of the incorporation of graphene foam (GF) into the matrix of a ternary transition-metals hydroxide containing nickel, cobalt, and manganese for optimal electrochemical performances as electrodes for supercapacitors applications. An adopted simple, low-cost co-precipitation synthesis method involved the loading a mass of the ternary metal hydroxides (NiCoMn-TH) onto various GF mass loading so as to find ints effect on the electrochemical properties of the hydroxides. Microstructural and chemical composition of the various composite materials were investigated by employing scanning/transmission electron microscopy (SEM/TEM), x-ray diffraction (XRD), Raman spectroscopy, and N₂ physisorption analysis among others. Electrochemical performances of the NiCoMn-TH/200?mg GF composite material evaluated in a three-electrode system using 1?M KOH solution revealed a maximum specific capacity around 178.6 mAh g^?1 compared to 76.2 mAh g^?1 recorded for the NiCoMn-TH pristine material at a specific current of 1 A g^?1. The best mass loading of GF nanomaterial (200?mg GF), was then utilised as a positive electrode material for the design of a novel hybrid device. An assembled hybrid NiCoMn-TH/200?mg GF//CSDAC device utilizing the NiCoMn-TH/200?mg GF and activated carbon derived from the cocoa shell (CSDAC) as a positive and negative electrode, respectively, demonstrated a sustaining specific capacity of 23.4 mAh g^?1 at a specific current of 0.5 A g^?1. The device also yielded sustaining a specific energy and power of about 22.32 Wh kg^?1 and 439.7?W?kg^?1, respectively. After a cycling test of over 15,000 cycles, the device could prove a coulombic efficiency of?~?99.9% and a capacity retention of around 80% within a potential range of 0.0–1.6?V at a specific current of 3?A?g^?1. These results have demonstrated the prodigious electrochemical potentials of the as-synthesized material and its capability to be utilized as an electrode for supercapacitor applications.

There is one component that virtually any embedded wearable needs—a power source. This paper proposes an energy source, which contains no harmful substances, can be stored in a stand-by dry state for indefinite time period, is flexible and has tactile characteristics similar to that of textile. The main feature of this energy source is the separation of the electrolyte and the electrodes—the electrolyte is applied only when the battery needs to be activated. This makes storage time in a dry state virtually infinite. It expands their potential use to storage solutions and healthcare/health monitoring solutions, because the design of the battery allows it to be used as an active sensor, which generates electric current, when it detects liquid. We stress that this solution is suitable for specific applications only, outlined in the paper. The main components of the battery include aluminium anode, air cathode and the cotton shell. The design includes only textile-based materials, which ensure greater flexibility and better fusion with textile materials, where the battery is intended to be integrated. Besides that, results of the experiments with multi-cell battery prototype are presented.

Physical and electrochemical properties of Pd catalysts combined with Ru and Mo on carbon support were investigated. To this end, Pd, Pd_1.3Ru_1.0, Pd_3.2Ru_1.3Mo_1.0 and Pd_1.5Ru_0.8Mo_1.0 were synthesized on Carbon Vulcan XC72 support by the method of thermal decomposition of polymeric precursors and then physically and electrochemically characterized. The highest reaction yields are obtained for Pd_3.2Ru_1.3Mo_1.0/C and Pd_1.5Ru_0.8Mo_1.0/C and, as demonstrated by thermal analysis, they also show the smallest metal/carbon ratio compared the other catalysts. XRD (X-ray Diffraction) and Raman analyses show the presence of PdO and RuO₂ for the Pd/C and the Pd_1.3Ru_1.0/C catalysts, respectively, a fact not observed for the Pd_3.2Ru_1.3 Mo_1.0 /C and the Pd_1.5Ru_0.8Mo_1.0/C catalysts. The catalytic activities were tested for the ethanol oxidation in alkaline medium. Cyclic voltammetry (CV) shows Pd_1.3Ru_1.0/C exhibiting the highest peak of current density, followed by Pd_3.2Ru_1.3Mo_1.0/C, Pd_1.5Ru_0.8Mo_1.0/C and Pd/C. From, chronoamperometry (CA), it is possible to observe the lowest rate of poisoning for the Pd_1.3Ru_1.0/C, followed by Pd_3.2Ru_1.3Mo_1.0/C, Pd_1.5Ru_0.8Mo_1.0/C and Pd/C. These results suggested that catalytic activity of the binary and the ternary catalysts are improved in comparison with Pd/C. The presence of RuO₂ activated the bifunctional mechanism and improved the catalytic activity in the Pd_1.3Ru_1.0/C catalyst. The addition of Mo in the catalysts enhanced the catalytic activity by the intrinsic mechanism, suggesting a synergistic effect between metals. In summary, we suggest that it is possible to synthesize ternary PdRuMo catalysts supported on Carbon Vulcan XC72, resulting in materials with lower poisoning rates and lower costs than Pd/C.

The demand for natural insulation materials is increasing with special attention to the use of such materials for exploiting renewable energy. Natural insulation materials tremendously influence the sustainability development and energy efficiency enhancement in the buildings. Natural fibers from animal’s origin absorb great amount of moisture on exposed to the environment which significantly affects the performance and thermal insulation properties. The thermal degradation of such material strongly influences the accidental burning characteristics, an important selection criteria for building materials. In the present study, three different kind of natural insulation materials namely sheep wool, goat wool and horse mane have been characterized in terms of moisture absorption, thermal degradation and morphology using thermogravimetric analysis (TGA), differential scanning calorimetry techniques, and scanning electron microscopy, respectively. In addition, antibacterial behavioral study has been also carried out for untreated raw wool and treated wool (copper nitrate). These properties are vital for a holistic evaluation of the insulation material. Moisture absorption results indicate that the sheep wool and goat wool absorb less moisture content as compared to horse mane. Unlike this horse mane shows great stability than goat wool and sheep wool in the temperature range not exceeding 470?°C. TGA data indicate 50% mass loss (T_50%) at 306?°C, 322?°C and 318?°C for sheep wool, goat wool and horse mane, respectively. In addition the tests show that the content of fire retardant elements like nitrogen and sulphur is more in horse mane as compared to sheep wool and goat wool. The treated wool samples showed excellent antibacterial properties as compared to untreated wool samples.

Herein, copper oxide/copper sulfide (CuO/Cu_xS) composites have been prepared by treating CuO with thiourea by an aqueous hydrothermal route and their thermoelectric properties are studied. The electrical conductivity is improved with the increase in thiourea content, as a result, thermoelectric power factor increased from 10^–4 to 10¹?μW?m^?1?K^?2, and thermal conductivity of the CuO is also found to decrease with thiourea treatment. A detailed analysis indicated that these changes are due to the formation of copper sulfide (Cu_xS) in the CuO compound; a small fraction of electrically good conducting Cu_xS in the bulk CuO has produced composites with better electrical conductivity. These low-cost and non-toxic materials can be useful in thermoelectric energy conversion applications.

In this work new naphthalenediimides (NDIs) were synthesized and used as dyes in DSSC. The efficiency (η) of the DSSC is influenced by NDIs electronic and structural characteristics. It was found a better cell performance with the NDIs which have a broader absorption band shifted to the red color, high ? values, and more adsorption in the anode surface. The band gaps were determinate by UV–vis and cyclic voltammetry. The LUMO orbitals of most of the NDIs are above of the conduction band (CB) energy for TiO₂ allowing the electron transfer process from the NDI to the photoanode, especially in those with a significant LUMO^NDI-CB^Ti energetic difference. Also, NDIs with polar groups in their structure presented higher η values due to a better adsorption on the photoanode surface, which allows a better energy capture compared with those with lower adsorption.

The lithium–sulfur (Li–S) batteries are promising because of the high energy density, low cost, and natural abundance of sulfur material. Li–S batteries have suffered from severe capacity fading and poor cyclability, resulting in low sulfur utilization. Herein, S-DHCS/CNTs are synthesized by integration of a double-hollow carbon sphere (DHCS) with carbon nanotubes (CNTs), and the addition of sulfur in DHCS by melt impregnations. The proposed S-DHCS/CNTs can effectively confine sulfur and physically suppress the diffusion of polysulfides within the double-hollow structures. CNTs act as a conductive agent. S-DHCS/CNTs maintain the volume variations and accommodate high sulfur content 73?wt%. The designed S-DHCS/CNTs electrode with high sulfur loading (3.3?mg?cm^?2) and high areal capacity (5.6?mAh?mg?cm^?2) shows a high initial specific capacity of 1709?mAh?g^?1 and maintains a reversible capacity of 730?mAh?g^?1 after 48 cycles at 0.2 C with high coulombic efficiency (100%). This work offers a fascinating strategy to design carbon-based material for high-performance lithium–sulfur batteries.