Abstract In chemical graph theory, chemical structures are model edthrough a graph where atoms are considered as vertices and edges are bonds between them. In chemical sciences, topological indices are used for understanding the physicochemical properties of molecules. In this work, we study the generalized Zagreb index for three types of carbon allotrope’s theoretically.
{"title":"The Generalized Zagreb Index of Some Carbon Structures","authors":"Prosanta Sarkar, Nilanjan De, A. Pal","doi":"10.2478/achi-2018-0007","DOIUrl":"https://doi.org/10.2478/achi-2018-0007","url":null,"abstract":"Abstract In chemical graph theory, chemical structures are model edthrough a graph where atoms are considered as vertices and edges are bonds between them. In chemical sciences, topological indices are used for understanding the physicochemical properties of molecules. In this work, we study the generalized Zagreb index for three types of carbon allotrope’s theoretically.","PeriodicalId":6958,"journal":{"name":"Acta Chemica Iasi","volume":"126 1-2","pages":"104 - 91"},"PeriodicalIF":0.5,"publicationDate":"2018-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72454039","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Four metal complexes viz Cu(II) and Fe(III) with or without thiocyanate have been synthesized from a Mannich base prepared by a simple synthetic route. These complexes were characterized by elemental and spectroscopic techniques. Bonding modes of the thiocyanate group with the metal complexes as studied by infrared spectroscopy revealed the presence of bridging N- and S- bonding modes. Detailed kinetic studies of these complexes were carried in the evaluation of their catecholase activity. The Fe(III) complex demonstrated the highest catalytic activity using 3,5-di-tert-butyl catechol (3,5-DTBC) as substrate with a turnover rate (kcat) of 112.32 h−1.
{"title":"Impact of Thiocyanate on the Catecholase Activity of Cu(II) and Fe(III) Complexes of 2-((4-(2-Hydroxy-4-Methylbenzyl)Piperazin-1-YL)Methyl)-5-Methylphenol (A Mannich Base)","authors":"A. O. Ayeni, G. M. Watkins","doi":"10.2478/achi-2018-0005","DOIUrl":"https://doi.org/10.2478/achi-2018-0005","url":null,"abstract":"Abstract Four metal complexes viz Cu(II) and Fe(III) with or without thiocyanate have been synthesized from a Mannich base prepared by a simple synthetic route. These complexes were characterized by elemental and spectroscopic techniques. Bonding modes of the thiocyanate group with the metal complexes as studied by infrared spectroscopy revealed the presence of bridging N- and S- bonding modes. Detailed kinetic studies of these complexes were carried in the evaluation of their catecholase activity. The Fe(III) complex demonstrated the highest catalytic activity using 3,5-di-tert-butyl catechol (3,5-DTBC) as substrate with a turnover rate (kcat) of 112.32 h−1.","PeriodicalId":6958,"journal":{"name":"Acta Chemica Iasi","volume":"66 1","pages":"59 - 73"},"PeriodicalIF":0.5,"publicationDate":"2018-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78975057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Anew simple, convenient and suitable spectrophotometric method for simultaneous determination of Furosemide and Spironolactone in combined dosage form has been developed and validated. Simultaneous equation method (Vierordt’s method) was used for determination of Furosemide and Spironolactone in combined dosage form. For spectrophotometric method development double distilled water and ethanol were used as a solvent in the ratio of (20:80). The proposed method was quantitatively evaluated in terms of linearity, precision, accuracy, lower limit of detection (LOD) and quantification (LOQ), recovery and robustness. All the parameters were found to be within the acceptance limit. λmax of Furosemide and Spironolactone was found to be 275 and 237 nm respectively. Beer’s law was obeyed over the concentration ranges of 2-10 μg mL−1 for both Furosemide and Spironolactone respectively. The % assay for commercial formulation was found to be 99.60%±0.0500 for Furosemide and 100.26%±1.17 for Spironolactone by the proposed methods. The overall recovery was observed to be 100.38±0.09% for Furosemide and 100.49±0.4197% for Spironolactone by simultaneous equation method (Vierordt’s method). LOD and LOQ were 0.76 and 2.32 μg mL−1 for Furosemide, 1.99 and 6.04 μg mL−1 for Spironolactone. A new simple, convenient, precise, rapid, accurate and economical and reliable spectrophotometric method was developed and validated for the analysis of Furosemide and Spironolactone in bulk drug and their formulations.
{"title":"Development and Validation of Spectrophotometric Methods for Simultaneous Estimation of Furosemide and Spironolactone by Vierordt’s Method in Bulk and Combined Tablet Dosage Form","authors":"R. Chavan, S. Bhinge, M. Bhutkar, D. Randive","doi":"10.2478/achi-2018-0006","DOIUrl":"https://doi.org/10.2478/achi-2018-0006","url":null,"abstract":"Abstract Anew simple, convenient and suitable spectrophotometric method for simultaneous determination of Furosemide and Spironolactone in combined dosage form has been developed and validated. Simultaneous equation method (Vierordt’s method) was used for determination of Furosemide and Spironolactone in combined dosage form. For spectrophotometric method development double distilled water and ethanol were used as a solvent in the ratio of (20:80). The proposed method was quantitatively evaluated in terms of linearity, precision, accuracy, lower limit of detection (LOD) and quantification (LOQ), recovery and robustness. All the parameters were found to be within the acceptance limit. λmax of Furosemide and Spironolactone was found to be 275 and 237 nm respectively. Beer’s law was obeyed over the concentration ranges of 2-10 μg mL−1 for both Furosemide and Spironolactone respectively. The % assay for commercial formulation was found to be 99.60%±0.0500 for Furosemide and 100.26%±1.17 for Spironolactone by the proposed methods. The overall recovery was observed to be 100.38±0.09% for Furosemide and 100.49±0.4197% for Spironolactone by simultaneous equation method (Vierordt’s method). LOD and LOQ were 0.76 and 2.32 μg mL−1 for Furosemide, 1.99 and 6.04 μg mL−1 for Spironolactone. A new simple, convenient, precise, rapid, accurate and economical and reliable spectrophotometric method was developed and validated for the analysis of Furosemide and Spironolactone in bulk drug and their formulations.","PeriodicalId":6958,"journal":{"name":"Acta Chemica Iasi","volume":"30 1","pages":"74 - 90"},"PeriodicalIF":0.5,"publicationDate":"2018-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90546867","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract This investigation was carried out to assess the heavy metal concentrations and health risks associated with automobile workshops in Owerri Metropolis. Using an Atomic Absorption Spectrophotometer, soil samples from Orji Mechanic Village (OMV), Naze Mechanic Village (NMV), New Market Automobile Workshops (NMAV), Matrix Mechanic Yard (MMY) and Alvan Mechanic Yard (AMY) were assayed for Silver (Ag), Cobalt (Co), Nickel (Ni), Mercury (Hg), Lead (Pb), Arsenic (As), Chromium (Cr) and Cadmium (Cd) concentrations. The result showed that at majority of the sites, the Ag, Pb, As, and Cd levels exceeded their baseline values, whereas the Ni and Co levels were equivalent to those of their baselines, at some sites. Soil samples at MMY were the most acidic while that of NMAV was the most alkaline. The pollution models indicated very high Ag contamination at OMV, NMV, and NMAV while all the sites showed very high contamination of Pb and Cd, and no Co, Ni, Hg, and Cr pollution was recorded for all the sites as shown by their Igeo values. The result for the enrichment factor showed anthropogenic sources of deposition of these heavy metals at all the sites. From the risk assessment models applied, none of the contaminated sites showed an estimated daily intake, hazard quotient, and total hazard index beyond the reference values, with Pb found to possess the greatest potentials of toxicity. This study has shown the necessity to periodically monitor and apply measures that can halt the environmental decay, occurring at the automobile workshops.
{"title":"Oral Ingestion Risks of Heavy Metal Accumulation at Top Soils of Automobile Workshops in Owerri Capital City of Imo State, Nigeria","authors":"E. Agomuo, P. Amadi","doi":"10.2478/achi-2018-0003","DOIUrl":"https://doi.org/10.2478/achi-2018-0003","url":null,"abstract":"Abstract This investigation was carried out to assess the heavy metal concentrations and health risks associated with automobile workshops in Owerri Metropolis. Using an Atomic Absorption Spectrophotometer, soil samples from Orji Mechanic Village (OMV), Naze Mechanic Village (NMV), New Market Automobile Workshops (NMAV), Matrix Mechanic Yard (MMY) and Alvan Mechanic Yard (AMY) were assayed for Silver (Ag), Cobalt (Co), Nickel (Ni), Mercury (Hg), Lead (Pb), Arsenic (As), Chromium (Cr) and Cadmium (Cd) concentrations. The result showed that at majority of the sites, the Ag, Pb, As, and Cd levels exceeded their baseline values, whereas the Ni and Co levels were equivalent to those of their baselines, at some sites. Soil samples at MMY were the most acidic while that of NMAV was the most alkaline. The pollution models indicated very high Ag contamination at OMV, NMV, and NMAV while all the sites showed very high contamination of Pb and Cd, and no Co, Ni, Hg, and Cr pollution was recorded for all the sites as shown by their Igeo values. The result for the enrichment factor showed anthropogenic sources of deposition of these heavy metals at all the sites. From the risk assessment models applied, none of the contaminated sites showed an estimated daily intake, hazard quotient, and total hazard index beyond the reference values, with Pb found to possess the greatest potentials of toxicity. This study has shown the necessity to periodically monitor and apply measures that can halt the environmental decay, occurring at the automobile workshops.","PeriodicalId":6958,"journal":{"name":"Acta Chemica Iasi","volume":"60 1","pages":"21 - 44"},"PeriodicalIF":0.5,"publicationDate":"2018-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73926452","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shashidhar N. Adarakatti, Veeresh S. Pattar, Prashant K. Korishettar, B. V. Grampurohit, R. G. Kharabe, A. Kulkarni, S. Mathad, C. S. Hiremath, R. B. Pujar
Abstract Li-Ni ferrite has gained great scientific elicit owing to of its unparalleled properties and applications. The copper doped Li-Ni ferrite has been synthesized by sucrose method. The structure was characterized by X-ray diffraction, which has confirmed the formation of single-phase spinel structure. X-ray diffraction and FTIR data reveals the formation of cubic structure phase. Unit cell parameters vary with copper content; overall variation of the unit cell parameters obeys Vegard’s law. The main absorption bands of spinel ferrite have appeared through IR absorption spectra recorded in the range of 300–700 cm−1. The copper concentration dependence of lattice parameters obeys Vegard’s law. DC electrical resistivity of the prepared samples decreases with increasing in the temperature which shows the semiconducting behaviour of all nano ferrites. The most prominent influence copper doping on the electrical properties of Li-Ni ferrites has been reported.
{"title":"Synthesis, Structural and Electrical Studies of Li-Ni-Cu Nano Ferrites","authors":"Shashidhar N. Adarakatti, Veeresh S. Pattar, Prashant K. Korishettar, B. V. Grampurohit, R. G. Kharabe, A. Kulkarni, S. Mathad, C. S. Hiremath, R. B. Pujar","doi":"10.2478/achi-2018-0001","DOIUrl":"https://doi.org/10.2478/achi-2018-0001","url":null,"abstract":"Abstract Li-Ni ferrite has gained great scientific elicit owing to of its unparalleled properties and applications. The copper doped Li-Ni ferrite has been synthesized by sucrose method. The structure was characterized by X-ray diffraction, which has confirmed the formation of single-phase spinel structure. X-ray diffraction and FTIR data reveals the formation of cubic structure phase. Unit cell parameters vary with copper content; overall variation of the unit cell parameters obeys Vegard’s law. The main absorption bands of spinel ferrite have appeared through IR absorption spectra recorded in the range of 300–700 cm−1. The copper concentration dependence of lattice parameters obeys Vegard’s law. DC electrical resistivity of the prepared samples decreases with increasing in the temperature which shows the semiconducting behaviour of all nano ferrites. The most prominent influence copper doping on the electrical properties of Li-Ni ferrites has been reported.","PeriodicalId":6958,"journal":{"name":"Acta Chemica Iasi","volume":"os-15 1","pages":"1 - 12"},"PeriodicalIF":0.5,"publicationDate":"2018-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87195637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract The conditions for the gel growth of barium oxalate single crystals in silica gels were studied in this paper. We describe the growth mechanism, effect concentration of feed solution, interchanging of the reactants, the effect of temperature and detailed study of microstructures of barium oxalate single crystals. At higher concentration of feed solution dense fibers were observed. With interchanged feed solution precipitate and spherulites have been obtained. The effect of temperature on growth barium oxalate crystals showed that there was a decrease in nucleation density at higher temperature. The crystals growth were observed under the electron microscope which revealed that the crystal have needle and spherulites structures. We also report the FTIR studies of barium oxalate crystals.
{"title":"Morphological and FTIR Studies of Barium Oxalate Single Crystals","authors":"M. Shedam, R. Shedam, S. Mathad","doi":"10.1515/achi-2017-0016","DOIUrl":"https://doi.org/10.1515/achi-2017-0016","url":null,"abstract":"Abstract The conditions for the gel growth of barium oxalate single crystals in silica gels were studied in this paper. We describe the growth mechanism, effect concentration of feed solution, interchanging of the reactants, the effect of temperature and detailed study of microstructures of barium oxalate single crystals. At higher concentration of feed solution dense fibers were observed. With interchanged feed solution precipitate and spherulites have been obtained. The effect of temperature on growth barium oxalate crystals showed that there was a decrease in nucleation density at higher temperature. The crystals growth were observed under the electron microscope which revealed that the crystal have needle and spherulites structures. We also report the FTIR studies of barium oxalate crystals.","PeriodicalId":6958,"journal":{"name":"Acta Chemica Iasi","volume":"12 1","pages":"195 - 207"},"PeriodicalIF":0.5,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84645855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract The concentrations of metals were determined in soil samples collected in Ait Ammar (Oued Zem, Morocco). The mean Cd, Cr, Cu, Fe, Pb and Zn contents in the mining topsoil samples were: 2.12, 135, 34.9, 214, 9.13 and 90.8 mg kg−1, respectively. Human health risks developed from metal ingestion, dermal absorption and inhalation of soils were also evaluated. For non-carcinogenic risks, united hazard index (HI) values for children surpassed the safe level (HI=1) for Cr (13.1). Values for HI in adults (1.74) also surpassed the safe level for Cr. The HI values for Pb and Cd for children were 0.69 and 0.68, respectively. Cancer risk due to Cr surpassed the tolerable range (1E-06 to1E-04) for children (1.05E-03) and for adults (1.42E-04). Cancer risks due to Pb and Cd were within acceptable ranges for both children and adults. Furthermore, oral ingestion of soil particles contributed more highly to both carcinogenic and non-carcinogenic risk from Cr than either dermal absorption or inhalation in both children and adults.
摘要:测定了摩洛哥埃特阿马尔(Oued Zem)地区土壤样品中金属的浓度。矿区表土样品中Cd、Cr、Cu、Fe、Pb和Zn的平均含量分别为:2.12、135、34.9、214、9.13和90.8 mg kg−1。还对金属摄入、皮肤吸收和土壤吸入造成的人类健康风险进行了评估。对于非致癌风险，儿童的统一危害指数(HI)值超过了铬(13.1)的安全水平(HI=1)。成人的HI值(1.74)也超过了铬的安全水平。儿童的铅和镉的HI值分别为0.69和0.68。铬的致癌风险超过了儿童(1.005 e -03)和成人(1.42E-04)的可容忍范围(1E-06至1e -04)。铅和镉导致的癌症风险在儿童和成人可接受的范围内。此外，在儿童和成人中，口服土壤颗粒比皮肤吸收或吸入对铬的致癌和非致癌风险都有更高的贡献。
{"title":"Levels of Metals in Soils of Ait Ammar Iron Mine, Morocco: Human Health Risks","authors":"M. Nouri, T. E. Rasafi, A. Haddioui","doi":"10.1515/achi-2017-0012","DOIUrl":"https://doi.org/10.1515/achi-2017-0012","url":null,"abstract":"Abstract The concentrations of metals were determined in soil samples collected in Ait Ammar (Oued Zem, Morocco). The mean Cd, Cr, Cu, Fe, Pb and Zn contents in the mining topsoil samples were: 2.12, 135, 34.9, 214, 9.13 and 90.8 mg kg−1, respectively. Human health risks developed from metal ingestion, dermal absorption and inhalation of soils were also evaluated. For non-carcinogenic risks, united hazard index (HI) values for children surpassed the safe level (HI=1) for Cr (13.1). Values for HI in adults (1.74) also surpassed the safe level for Cr. The HI values for Pb and Cd for children were 0.69 and 0.68, respectively. Cancer risk due to Cr surpassed the tolerable range (1E-06 to1E-04) for children (1.05E-03) and for adults (1.42E-04). Cancer risks due to Pb and Cd were within acceptable ranges for both children and adults. Furthermore, oral ingestion of soil particles contributed more highly to both carcinogenic and non-carcinogenic risk from Cr than either dermal absorption or inhalation in both children and adults.","PeriodicalId":6958,"journal":{"name":"Acta Chemica Iasi","volume":"7 1","pages":"127 - 144"},"PeriodicalIF":0.5,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83382762","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R. Ştefănescu, Stefania Brebu, M. Matei, I. Risca, A. Surleva, G. Drochioiu
Abstract In the present paper, the interaction between copper ions and proteins is presented, in order to elaborate a simple and rapid spectrophotometric assay of casein in milk. Under alkaline conditions, copper ions form the biuret complex with the proteins, which can be used in protein determination. Although very specific, the biuret method is less sensitive. Using insoluble copper phosphate, casein is able to extract copper ions, with which it forms the biuret complex, while either the complex or copper ions could be determined in the ultraviolet range. Indeed, an increased absorbance of biuret complex at 215 nm was found. Nevertheless, copper ions can be determined in UV as well, their concentration being proportional to that of casein. When used tetraglycine instead casein, mass spectrometric measurements at pH higher than 11 revealed the formation of complexes with many copper ions bound to each peptide bond-containing molecule. Nevertheless, on diluting the biuret solution the complex may dissociate leading to very complex UV spectra that should be further studied.
{"title":"Contribution to Casein Determination by UV Spectrophotometry","authors":"R. Ştefănescu, Stefania Brebu, M. Matei, I. Risca, A. Surleva, G. Drochioiu","doi":"10.1515/achi-2017-0011","DOIUrl":"https://doi.org/10.1515/achi-2017-0011","url":null,"abstract":"Abstract In the present paper, the interaction between copper ions and proteins is presented, in order to elaborate a simple and rapid spectrophotometric assay of casein in milk. Under alkaline conditions, copper ions form the biuret complex with the proteins, which can be used in protein determination. Although very specific, the biuret method is less sensitive. Using insoluble copper phosphate, casein is able to extract copper ions, with which it forms the biuret complex, while either the complex or copper ions could be determined in the ultraviolet range. Indeed, an increased absorbance of biuret complex at 215 nm was found. Nevertheless, copper ions can be determined in UV as well, their concentration being proportional to that of casein. When used tetraglycine instead casein, mass spectrometric measurements at pH higher than 11 revealed the formation of complexes with many copper ions bound to each peptide bond-containing molecule. Nevertheless, on diluting the biuret solution the complex may dissociate leading to very complex UV spectra that should be further studied.","PeriodicalId":6958,"journal":{"name":"Acta Chemica Iasi","volume":"82 1","pages":"112 - 126"},"PeriodicalIF":0.5,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75788350","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R. Heydari, Rohollah Rahimi, M. Kangani, Afshin Yazdani-Elah-Abadi, M. Lashkari
Abstract The potassium carbonate was applied as a green and efficient catalyst for the one-pot synthesis of pyran annulated heterocyclic systems, via the condensation between aromatic aldehydes, malononitrile and dimedone/1-naphtole by a grinding method at room temperature and solvent-free conditions. Short reaction times, environmentally friendly procedure and excellent yields are the main advantages of this procedure which makes it more economic than other environmentally synthetic methods.
{"title":"K2CO3: A Mild and Efficient Catalyst for the Synthesis of Pyran Annulated Heterocyclic Systems by Grinding Method Under Solvent-Free Conditions","authors":"R. Heydari, Rohollah Rahimi, M. Kangani, Afshin Yazdani-Elah-Abadi, M. Lashkari","doi":"10.1515/achi-2017-0014","DOIUrl":"https://doi.org/10.1515/achi-2017-0014","url":null,"abstract":"Abstract The potassium carbonate was applied as a green and efficient catalyst for the one-pot synthesis of pyran annulated heterocyclic systems, via the condensation between aromatic aldehydes, malononitrile and dimedone/1-naphtole by a grinding method at room temperature and solvent-free conditions. Short reaction times, environmentally friendly procedure and excellent yields are the main advantages of this procedure which makes it more economic than other environmentally synthetic methods.","PeriodicalId":6958,"journal":{"name":"Acta Chemica Iasi","volume":"15 1","pages":"163 - 178"},"PeriodicalIF":0.5,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91259058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract In this paper, five degree based topological indices, the first Zagreb (M1), second Zagreb (M2), first multiple Zagreb (PM1), second multiple Zagreb (PM2), and the hyper Zagreb (HM) indices of two types of dendrimers are studied. In addition, two distance based topological indices, the total eccentricity (θ) and eccentric connectivity (ξc) indices of these dendrimers are computed.
{"title":"Study of Dendrimers by Topological Indices","authors":"N. Soleimani, S. B. Bahnamiri, M. Nikmehr","doi":"10.1515/achi-2017-0013","DOIUrl":"https://doi.org/10.1515/achi-2017-0013","url":null,"abstract":"Abstract In this paper, five degree based topological indices, the first Zagreb (M1), second Zagreb (M2), first multiple Zagreb (PM1), second multiple Zagreb (PM2), and the hyper Zagreb (HM) indices of two types of dendrimers are studied. In addition, two distance based topological indices, the total eccentricity (θ) and eccentric connectivity (ξc) indices of these dendrimers are computed.","PeriodicalId":6958,"journal":{"name":"Acta Chemica Iasi","volume":"65 1","pages":"145 - 162"},"PeriodicalIF":0.5,"publicationDate":"2017-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81096549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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