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Characterizing seismic wave attenuation in North-west Iran: impacts of geometric spreading and quality factors 伊朗西北部地震波衰减特征:几何扩散和质量因子的影响
IF 2.1 4区 地球科学 Pub Date : 2025-12-01 DOI: 10.1007/s11600-025-01720-4
Sayeh Safavi, Mohammadreza Najaftomaraei, Habib Rahimi, Mohammad Reza Hatami, Abdelkrim Audio

This study focuses on developing region-specific seismic attenuation relationships for North-west Iran, a tectonically active area prone to frequent and destructive earthquakes. By analyzing a robust dataset of seismic events, we identify breakpoints in attenuation behavior at distances of 85 km and 175 km, attributed to crustal features such as the Moho and Conrad discontinuities. Using nonlinear optimization and inversion methods with explicit parameter bounds, we estimate frequency-dependent parameters, including geometric spreading coefficients, quality factor (Q), and magnitude-dependent terms. The geometric spreading coefficients for velocity data show slight variations across frequencies, reflecting the complex crustal structure in the region. Negative values of these coefficients indicate a significant velocity contrast at the Moho discontinuity, leading to substantial energy reflection. The observed amplitude decay trend remains consistent between breakpoints, with a notable change at approximately 175 km, likely due to the superposition of reflective phases from the Conrad and Moho discontinuities and multiple reflections within the S-wave window. Crustal stratification ensures continuous energy reflection, resulting in geometric spreading attenuation coefficients that exceed theoretical predictions. These empirically derived coefficients are intended for regional hazard assessment and may not be directly portable to other tectonic settings. The calculated average shear wave quality factor (Q) for the region is empirical and reflects the area’s structural characteristics and high seismicity. The findings provide practical insights for seismic hazard assessments and support the design of resilient infrastructure in North-west Iran.

本研究的重点是发展伊朗西北部地区特定的地震衰减关系,这是一个构造活跃地区,容易发生频繁和破坏性地震。通过分析一个强大的地震事件数据集,我们在距离85公里和175公里处确定了衰减行为的断点,这归因于莫霍和康拉德不连续等地壳特征。使用具有明确参数边界的非线性优化和反演方法,我们估计频率相关参数,包括几何扩散系数,质量因子(Q)和幅度相关项。速度数据的几何扩展系数在不同频率上略有变化,反映了该地区复杂的地壳结构。这些系数的负值表明在莫霍面非连续性处速度对比明显,导致大量的能量反射。观测到的振幅衰减趋势在断点之间保持一致,在大约175 km处发生显著变化,可能是由于康拉德和莫霍不连续面的反射相位叠加以及s波窗口内的多次反射。地壳分层保证了连续的能量反射,导致几何扩散衰减系数超过理论预测。这些经验推导的系数用于区域危害评估,可能不能直接适用于其他构造环境。计算得到的该区平均横波质量因子(Q)是经验性的,反映了该区的构造特征和高地震活动性。这些发现为地震风险评估提供了实用的见解,并为伊朗西北部弹性基础设施的设计提供了支持。
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引用次数: 0
Investigating energy reduction and flow dynamics around bridge abutments with recycled materials 利用再生材料研究桥台周围的节能和流动动力学
IF 2.1 4区 地球科学 Pub Date : 2025-12-01 DOI: 10.1007/s11600-025-01748-6
Nadir Murtaza, Aissa Rezzoug, Ghufran Ahmed Pasha, Mohd Aamir Mumtaz

A bridge abutment is the most critical civil engineering infrastructure directly exposed to floodwater. Numerous studies have been conducted to mitigate scour around bridge abutments; however, limited research has focused on assessing flow dynamics and energy reduction around bridge abutments using eco-friendly methods. Therefore, the current research investigates energy reduction and flow dynamics around bridge abutments with recycled materials (brick waste (BW) and marble waste (MW)) under subcritical flow conditions. Experiments were conducted in a controlled laboratory setting to investigate various parameters, including water surface profile, energy reduction, reduction of fluid force index (RFI%), moment index (RMI%), and delay in floodwater arrival time. These parameters were investigated under different conditions, including without waste (WW) and with recycled materials. The result demonstrates that energy reduction increases as the Froude number (Fr) is increased from 0.13 to 0.22. Energy reduction increases up to 5.95, 6.5, and 6.27% in the case of WW, MW, and BW, respectively. The use of MW resulted in a maximum energy reduction, with an average energy reduction of 4.38%. The highest RFI% of 8.86% and RMI% of 12.44% were recorded when using MW during the experiments. The findings also show that a significant reduction in floodwater arrival occurred in the case of MW up to 68% compared to the case without an abutment in the channel. These findings offer valuable insights into the flow characteristics and energy dissipation around bridge abutments, thereby contributing to the design of sustainable and resilient hydraulic infrastructure.

桥台是直接暴露在洪水中的最关键的土木工程基础设施。已经进行了大量的研究来减轻桥台周围的冲刷;然而,有限的研究集中在利用环保方法评估桥台周围的流动动力学和节能方面。因此,本研究对亚临界流动条件下再生材料(废砖(BW)和废大理石(MW))桥台周围的能量降低和流动动力学进行了研究。实验在受控的实验室环境中进行,研究了各种参数,包括水面剖面、能量减少、流体力指数(RFI%)减少、力矩指数(RMI%)减少和洪水到达时间延迟。这些参数在不同的条件下进行了研究,包括不使用废物(WW)和使用回收材料。结果表明,当弗劳德数(Fr)从0.13增加到0.22时,能量减少量增加。在WW、MW和BW的情况下,节能分别增加了5.95%、6.5%和6.27%。MW的使用最大限度地减少了能源,平均减少了4.38%。实验中使用MW时RFI%最高,为8.86%,RMI%最高,为12.44%。研究结果还表明,与没有桥台的情况相比,MW情况下的洪水到达量显著减少了68%。这些发现对桥台周围的流动特性和能量耗散提供了有价值的见解,从而有助于可持续和弹性水力基础设施的设计。
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引用次数: 0
The electrical resistivity tomography as a tool for groundwater prospecting in the flysch lithologies: a case study from Poland 电阻率层析成像在复理石岩性中作为地下水勘探工具:以波兰为例
IF 2.1 4区 地球科学 Pub Date : 2025-12-01 DOI: 10.1007/s11600-025-01746-8
Bogdan Żogała, Iwona Stan-Kłeczek, Jan Waligóra

Sustainable water management is particularly important in mountainous areas, where access to surface water is limited and drilled wells often remain the only reliable source of fresh water. Locating aquifers in such regions is challenging due to the complex geological conditions. In this context, geophysical methods, especially electrical resistivity tomography (ERT), can provide valuable support in identifying zones with higher groundwater potential in areas such as the Carpathian flysch, composed mainly of sandstones and shales occurring in varying proportions. The paper presents case studies from the Magura and Silesian Nappes, demonstrating how ERT surveys, verified by borehole data, helped indicate aquifer locations and assess hydrogeological conditions. The application of ERT in the specific geology of the Carpathian flysch allowed for the identification of the influence of lithological proportions and water mineralisation on the values of electrical resistivity and the summary of the limitations and possibilities of the ERT method in difficult mountain conditions.

Although heterogeneous geological settings may limit the precision of interpretations, the results confirm that ERT is an effective tool for improving the recognition of groundwater resources in mountainous flysch areas and thus giving people access to water.

可持续的水管理在山区尤其重要,因为山区获得地表水的机会有限,水井往往是唯一可靠的淡水来源。由于地质条件复杂,在这些地区定位含水层具有挑战性。在这种情况下,地球物理方法,特别是电阻率层析成像(ERT),可以为在喀尔巴阡复理石区(主要由不同比例的砂岩和页岩组成)识别具有较高地下水潜力的区域提供有价值的支持。本文介绍了来自Magura和Silesian推覆体的案例研究,展示了ERT调查如何通过钻孔数据验证,帮助确定含水层位置并评估水文地质条件。在喀尔巴阡复理岩的具体地质中应用ERT方法可以确定岩性比例和水矿化对电阻率值的影响,并总结ERT方法在困难山区条件下的局限性和可能性。虽然不均匀的地质环境可能会限制解释的精度,但结果证实,ERT是提高山区复理石区地下水资源识别的有效工具,从而使人们能够获得水。
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引用次数: 0
Retraction Note: Efficient seismic noise suppression for microseismic data using an adaptive TMSST approach 注:利用自适应TMSST方法对微地震数据进行有效的地震噪声抑制
IF 2.1 4区 地球科学 Pub Date : 2025-12-01 DOI: 10.1007/s11600-025-01751-x
Xulin Wang, Minghui Lv
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引用次数: 0
Morphodynamics and riverbed elevation changes in the lower Apalachicola River: a study of large lowland river systems 阿巴拉契科拉河下游的形态动力学和河床高程变化:大型低地河流系统的研究
IF 2.1 4区 地球科学 Pub Date : 2025-12-01 DOI: 10.1007/s11600-025-01744-w
Ali R. Alruzuq, Joann Mossa, Amobichukwu C. Amanambu, Yin-Hsuen Chen, Mark Brenner

Extensive research has been conducted on the effects of anthropogenic practices on lowland rivers and floodplains; particularly regarding planform changes, only a few studies have utilized detailed riverbed elevation data. This study focuses on the Apalachicola River, one of the largest lowland rivers in the southeastern United States. The navigation project by the United States Army Corps of Engineers, which began in the late 1950s and continued till 2002, significantly impacted the Apalachicola River. The dredging and disposal, artificial cutoffs, and snag removal carried out as part of the navigation efforts significantly altered the Apalachicola River. Using bathymetric survey data from 1960 to 2010, we developed a high-resolution digital elevation model (DEM) to analyze geomorphic changes in the lower Apalachicola River and conduct a DEM of differences analysis for the 50-year period. We assessed the river’s net sediment gain and loss patterns using the DEMs and geostatistical approaches. We quantified the cumulative sediment volume change and gross change (cumulative absolute change) per river mile of the lower Apalachicola River between 1960 and 2010. The study revealed that the entire reach (RM ~ 45-0) experienced a loss of 8.36 million m3, a gain of 6.99 million m3, a gross change of 15.35 million m3, and a net change of 1.37 million m3. The reach upstream of the juncture with the Lower Chipola (~ RM 28), where several artificial cutoffs were present, experienced a net loss of 4.52 million m3. In this reach and just downstream of the juncture between RM 30 and 27, multiple pools deepened markedly. These morphological alterations have significantly compromised natural river–floodplain connectivity and altered critical aquatic habitats, particularly affecting the spawning and nursery areas essential for the region’s diverse freshwater mussel populations and other endemic species. However, downstream of RM 28, the Apalachicola had a net gain of 3.14 million m3, probably associated with sediment supply from downcutting and lateral erosion occurring upstream. This comprehensive sediment budget analysis provides essential quantitative evidence for river managers and restoration practitioners, demonstrating that navigation-induced modifications can redistribute over 15 million m3 of sediment across a 45-mile reach, with direct implications for habitat restoration planning, flood risk assessment, and sustainable waterway management in similar modified lowland river systems globally.

人类活动对低地河流和洪泛平原的影响已进行了广泛的研究;特别是关于平台的变化,只有少数研究利用了详细的河床高程数据。这项研究的重点是阿巴拉契科拉河,这是美国东南部最大的低地河流之一。美国陆军工程兵团的导航项目始于20世纪50年代末,一直持续到2002年,对阿巴拉契科拉河产生了重大影响。疏浚和处理、人工截流和清除障碍物作为航行努力的一部分,极大地改变了阿巴拉契科拉河。利用1960 - 2010年的测深数据,建立了高分辨率数字高程模型(DEM),分析了阿巴拉契科拉河下游50年的地貌变化,并进行了DEM差异分析。我们使用dem和地质统计学方法评估了河流的净泥沙收益和损失模式。我们量化了1960年至2010年间阿巴拉契科拉河下游每河英里的累积泥沙体积变化和总变化(累积绝对变化)。研究表明,整个河段(RM ~ 45-0)损失836万m3,增加699万m3,总变化1535万m3,净变化137万m3。在与Lower Chipola交界的上游河段(~ RM 28),存在几个人工截流,净损失452万立方米。在这条河段以及RM 30和RM 27交界的下游,多个水池明显加深。这些形态变化严重损害了河流与洪泛平原的天然连通性,改变了关键的水生栖息地,特别是影响了该地区各种淡水贻贝种群和其他特有物种的产卵和苗圃。然而,在RM 28的下游,Apalachicola的净收益为314万m3,这可能与上游发生的向下砍伐和侧向侵蚀的沉积物供应有关。这项全面的沉积物预算分析为河流管理者和修复从业者提供了必要的定量证据,表明导航诱导的改造可以在45英里的河段内重新分配超过1500万立方米的沉积物,这对全球类似改造的低地河流系统的栖息地恢复规划、洪水风险评估和可持续水道管理具有直接影响。
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引用次数: 0
Physics-aware machine learning for fracture pressure prediction model 基于物理感知的机器学习裂缝压力预测模型
IF 2.1 4区 地球科学 Pub Date : 2025-11-29 DOI: 10.1007/s11600-025-01727-x
Xinru Li, Fei Gao, Jiahao Lan, Zhongqiang Li, Mengting Huang, Jiayu Wang

Accurate prediction of formation fracturing pressure is crucial for drilling safety and reservoir protection. In this study, a long short-term memory (LSTM) neural network model integrated with geomechanical constraints (Physical-LSTM) is proposed, which achieves deep coupling of data-driven approaches and physical laws through a physical constraint correction layer and a multi-objective loss function. Based on logging-while-drilling and drilling data from three wells in the Bohai Sea area, 15 key parameters were selected as the model inputs. The physical constraints include: the fracturing pressure must be greater than the pore pressure, less than the overburden pressure, and monotonically increasing with well depth. Bayesian optimization was employed to determine the weights of physical constraints and data fitting ((alpha) = 0.8, (beta) = 0.6). The experimental results show that the Physical-LSTM model achieves a mean squared error (MSE) of only 0.0015, a mean absolute error (MAE) of 0.0261, a coefficient of determination (R2) of 0.981, and a normalized Nash–Sutcliffe efficiency (NNSE) of 0.978 on the test set, which is significantly superior to the baseline models including LSTM, GRU, LightGBM, XGBoost, and RF. Compared with the traditional Eaton model, the Physical-LSTM not only maintains consistency in prediction trends but also substantially reduces prediction errors and eliminates physically unreasonable outliers. This study confirms that embedding physical constraints into machine learning models can significantly improve the accuracy, physical rationality, and engineering reliability of formation fracturing pressure prediction.

准确预测地层压裂压力对钻井安全和储层保护至关重要。本文提出了一种结合地质力学约束的长短期记忆(LSTM)神经网络模型(physical -LSTM),该模型通过物理约束校正层和多目标损失函数实现了数据驱动方法与物理规律的深度耦合。根据渤海地区3口井随钻测井和钻井资料,选取15个关键参数作为模型输入。物理约束条件包括:压裂压力必须大于孔隙压力,小于覆盖层压力,且随井深单调增加。采用贝叶斯优化确定物理约束和数据拟合的权重((alpha) = 0.8, (beta) = 0.6)。实验结果表明,Physical-LSTM模型在测试集上的均方误差(MSE)仅为0.0015,平均绝对误差(MAE)为0.0261,决定系数(R2)为0.981,归一化Nash-Sutcliffe效率(NNSE)为0.978,显著优于LSTM、GRU、LightGBM、XGBoost和RF等基准模型。与传统Eaton模型相比,Physical-LSTM不仅保持了预测趋势的一致性,而且大大减小了预测误差,消除了物理上不合理的异常值。该研究证实,将物理约束嵌入到机器学习模型中可以显著提高地层压裂压力预测的准确性、物理合理性和工程可靠性。
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引用次数: 0
Turbulence characteristics and energy distribution in hydraulic jumps downstream of radial gates: a PIV analysis 径向闸门下游水跃的湍流特性和能量分布:PIV分析
IF 2.1 4区 地球科学 Pub Date : 2025-11-29 DOI: 10.1007/s11600-025-01724-0
Liang Zhong, Xin Guan, Jinyang Liu, Yuheng Wu

As critical components of hydraulic structures, radial gates experience complex flow patterns during operation, inducing hydrodynamic loads that may threaten structural stability. This study investigates the flow characteristics around the radial gates under different conditions by using Particle Image Velocimetry (PIV) test in a laboratory flume. It is found that three key zones emerged behind the gate: a high-velocity jet zone, a shear layer marked by a velocity gradient, and a recirculation zone with reverse flow. The downstream water depth critically controls the evolution of these flow zones. Turbulence intensity peaks within the jet zone, decaying progressively across the shear layer. The flow self-similar is exhibited in the far-field region. Energy analysis reveals that large-scale vortex structures govern the kinetic energy distribution. These findings enhance our understanding of flow regimes near radial gates and support the optimization of gate designs for improved stability.

作为水工结构的关键部件,径向闸门在运行过程中会经历复杂的流态,产生的水动力载荷可能会威胁到水工结构的稳定性。采用颗粒图像测速(PIV)技术,研究了不同工况下径向闸门的流动特性。研究发现,闸门后出现了三个关键区域:高速射流区、以速度梯度为标志的剪切层和以逆流为特征的再循环区。下游水深对这些流带的演化起着关键的控制作用。湍流强度在喷射区达到峰值,在剪切层上逐渐衰减。在远场区域表现出流动自相似。能量分析表明,大尺度涡结构控制着动能分布。这些发现增强了我们对径向闸门附近流动状况的理解,并支持优化闸门设计以提高稳定性。
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引用次数: 0
Development of three machine learning models for predicting the horizontal peak ground acceleration for Iran 开发三个机器学习模型,用于预测伊朗的水平峰值地面加速度
IF 2.1 4区 地球科学 Pub Date : 2025-11-29 DOI: 10.1007/s11600-025-01743-x
Mohammad-Bagher Bahraini, Noorbakhsh Mirzaei, Morteza Eskandari‐Ghadi, Hamidreza Javan‐emrooz

Three different ground motion prediction models (GMPMs) have been developed in this paper using machine learning (ML) methods to estimate the horizontal peak ground acceleration (HPGA) for Iran. Two of these models are based on artificial neural networks (ANNs) of the multilayer perceptron (MLP) type, while the third employs the support vector regression (SVR). Each model utilizes moment magnitude (Mw), fault type, epicentral distance, and soil type as features (predictors) to produce a numerical prediction for HPGA. The models have been trained, validated, and tested using a strong-motion dataset comprising 2472 corrected horizontal accelerograms from 1100 earthquakes recorded at 815 stations across Iran from 1974 to 2022. Given the significant imbalance in the number and magnitude of recorded accelerations for Iran, an algorithm called the Repeating function has been devised to mitigate this problem within the training dataset. Besides, we designed an innovative training loop that automatically trains a model multiple times until specified criteria for the model are confirmed. Notably, three developed ML models (DMLMs) accurately predict HPGA, even in cases where VS30 is not defined. Although we have trained the three DMLMs to predict HPGA as the maximum value of the two horizontal components of the accelerogram (HPGAmax), they demonstrate a strong generalization in predicting the arithmetic and geometric means of the two mentioned components (HPGAam and HPGAgm). To evaluate the performance of the models, sensitivity and residual analyses, fitting curves, root-mean-square error (RMSE), and Pearson correlation coefficient (PCC) have been conducted.

本文利用机器学习(ML)方法建立了三种不同的地面运动预测模型(GMPMs)来估计伊朗的水平峰值地面加速度(HPGA)。其中两个模型基于多层感知器(MLP)类型的人工神经网络(ann),而第三个模型采用支持向量回归(SVR)。每个模型都利用矩量级(Mw)、断层类型、震中距离和土壤类型作为特征(预测因子)来产生HPGA的数值预测。这些模型已经使用强震数据集进行了训练、验证和测试,该数据集包括1974年至2022年伊朗815个站点记录的1100次地震的2472个校正水平加速度。考虑到伊朗记录的加速度在数量和大小上的显著不平衡,我们设计了一种称为重复函数的算法来缓解训练数据集中的这个问题。此外,我们设计了一个创新的训练循环,可以自动训练模型多次,直到模型的指定标准得到确认。值得注意的是,即使在没有定义VS30的情况下,三种开发的ML模型(DMLMs)也能准确预测HPGA。虽然我们已经训练了三个DMLMs来预测HPGA作为加速度图的两个水平分量(HPGAmax)的最大值,但它们在预测上述两个分量(HPGAam和HPGAgm)的算术和几何平均数方面表现出很强的泛化性。为了评价模型的性能,进行了灵敏度和残差分析、拟合曲线、均方根误差(RMSE)和Pearson相关系数(PCC)。
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引用次数: 0
Ensemble deep learning framework for groundwater storage forecasting under hydrological variability 水文变异性下地下水储量预测的集成深度学习框架
IF 2.1 4区 地球科学 Pub Date : 2025-11-24 DOI: 10.1007/s11600-025-01735-x
Asit Kumar Dandapat, Prafulla Kumar Panda, Sovan Sankalp, Ozgur Kisi, Habib Kraiem, Olga D. Kucher, Aqil Tariq

This study uses deep learning models to present an advanced methodology for forecasting groundwater levels. The primary objective is to estimate monthly streamflow at various gauging stations, analyze long-term groundwater storage trends from 1986 to 2022, and predict future groundwater storage (GWS) for 2028. The majority of research relies on single-model forecasts, without considering regional hydrological variability or integrating minimal-data contexts, despite the increasing use of deep learning models in hydrology. By employing an ensemble deep learning (DL) architecture that combines Long Short-Term Memory (LSTM), Bidirectional Long Short-Term Memory (BiLSTM), Stacked Long Short-Term Memory (SLSTM), and Gated Recurrent Unit (GRU), this study closes that gap by accurately predicting groundwater storage over the Middle Mahanadi Basin utilizing Hargreaves–Samani potential evapotranspiration (PET) estimate and SCS-CN runoff. Results reveal that the Ensemble DL model consistently outperforms individual models across all gauging stations, offering the most accurate predictions of GWS changes. This model’s integration of multiple techniques allows it to capture complex patterns and mitigate errors, particularly in regions with high variability. The analysis of seasonal trends reveals that the post-monsoon season exhibits increased groundwater storage, whereas the pre-monsoon and monsoon seasons display a declining trend. In 2004, there was a decrease in GWS across most stations out of 8 stations, likely due to reduced rainfall and increased water extraction, with slight recoveries observed in 2016 and 2022. In conclusion, the Ensemble DL model emerges as the region’s most reliable tool for groundwater forecasting, offering valuable insights for effective water resource planning and management, particularly in drought-prone areas. In drought-prone basins with limited data, the model provides a dependable tool for groundwater management and performs better than individual DL models at every station.

本研究使用深度学习模型提出了一种预测地下水位的先进方法。主要目标是估算各测量站的月流量,分析1986年至2022年的长期地下水储量趋势,并预测2028年的未来地下水储量(GWS)。尽管在水文学中越来越多地使用深度学习模型,但大多数研究依赖于单一模型预测,而没有考虑区域水文变异性或整合最小数据背景。通过采用集成深度学习(DL)架构,结合长短期记忆(LSTM)、双向长短期记忆(BiLSTM)、堆叠长短期记忆(SLSTM)和门控制循环单元(GRU),本研究通过利用哈格里夫斯-萨马尼潜在蒸散(PET)估算和SCS-CN径流准确预测中马哈纳迪盆地的地下水储量,缩小了这一差距。结果表明,在所有测量站中,集成DL模型始终优于单个模型,提供最准确的GWS变化预测。该模型集成了多种技术,使其能够捕获复杂的模式并减少错误,特别是在具有高可变性的区域。季节趋势分析表明,季风后季节地下水蓄积量增加,而季风前和季风季节地下水蓄积量下降。2004年,8个站点中大多数站点的GWS下降,可能是由于降雨量减少和取水量增加,2016年和2022年略有恢复。综上所述,Ensemble DL模型是该地区最可靠的地下水预测工具,为有效的水资源规划和管理提供了宝贵的见解,特别是在干旱易发地区。在数据有限的干旱易发流域,该模型为地下水管理提供了可靠的工具,并且比每个站点的单个DL模型表现更好。
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引用次数: 0
Influences of electric field action on methane adsorption properties in anthracite: an experimental study 电场作用对无烟煤甲烷吸附性能影响的实验研究
IF 2.1 4区 地球科学 Pub Date : 2025-11-24 DOI: 10.1007/s11600-025-01737-9
Wenmei Han, Zhaoying Chen, Hongtai Liu, Qi Yuan

Adjustment of methane adsorption and desorption properties in coal is important for the high drainage rate and drainage effect of coalbed methane (CBM). The main characteristics of CBM reservoirs in the Qinshui coalfield of Shanxi Province are low pressure and low permeability of CBM. These conditions result in limited methane extraction and significant fluctuations in gas concentration. Revising the adsorption and desorption properties of CBM can improve both the extraction rate and efficiency. An attempt was made to revise the adsorption and desorption characteristics of methane in coal by adding an electric field. This study focuses on No. 3 anthracite in the southern Qinshui coalfield. Elemental analysis was conducted, and an electric field was used as a physical field to develop an experimental apparatus for electric field-revised CBM adsorption and desorption. This apparatus was used to test the adsorption properties of CBM, and X-ray photoelectron spectroscopy (XPS) was employed to examine the surface chemistry of coal. The types and relative contents of functional groups on the coal surface were analyzed. Additionally, the relationship between the electric field’s influence on CBM adsorption and the changes in functional groups on the coal surface was investigated. The experimental results indicate that the application of an electric field changes methane adsorption from coal, adhering to the Langmuir theory model. The impact of voltage on methane adsorption capacity and adsorption isotherms is greater than that of frequency. Moreover, as the intensity of the electric field increases, the maximum adsorbed quantity Vm demonstrates a linear decrease while the empirical adsorbed constant B exhibits an exponential decline. The functional groups on the coal surface primarily include C–C/C–H bonds, C-O bonds, C = O carbonyl groups, and COO- carboxyl or quinone groups. Under the influence of the electric field, the functional groups on the coal surface are modified. The relative content of C–C/C–H bonds decreases, resulting in an increase in the relative content of C–O bonds, C = O carbonyl groups, and COO- carboxyl or quinone groups. The findings revealed that electric field action diminished the methane adsorption capacity in coal.

调节煤对甲烷的吸附和解吸特性对提高煤层气的抽采速率和抽采效果具有重要意义。山西沁水煤田煤层气储层以低压低渗为主要特征。这些条件导致了有限的甲烷提取和气体浓度的显著波动。修正煤层气的吸附和解吸特性,可以提高萃取率和萃取效率。尝试通过加电场来改变煤中甲烷的吸附和解吸特性。本研究以沁水南部煤田3号无烟煤为研究对象。进行了元素分析,并以电场为物理场,研制了电场修正煤层气吸附解吸实验装置。利用该装置测试了煤层气的吸附性能,并用x射线光电子能谱(XPS)检测了煤的表面化学性质。分析了煤表面官能团的类型和相对含量。此外,还研究了电场对煤层气吸附的影响与煤表面官能团变化的关系。实验结果表明,电场的作用改变了煤对甲烷的吸附,符合Langmuir理论模型。电压对甲烷吸附容量和吸附等温线的影响大于频率。随着电场强度的增加,最大吸附量Vm呈线性减小,经验吸附常数B呈指数减小。煤表面的官能团主要有C- C/C - h键、C-O键、C = O羰基、COO-羧基或醌基。在电场作用下,煤表面的官能团发生了修饰。C - C/C - h键的相对含量降低,导致C - O键、C = O羰基、COO-羧基或醌基的相对含量增加。结果表明,电场作用降低了煤对甲烷的吸附能力。
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Acta Geophysica
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