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Time-dependent electromechanical analysis of composite piezoelectric panels on concrete auxetic foundations: a mathematical model validated by a machine learning algorithm 混凝土基础上复合压电板的时变机电分析:一个机器学习算法验证的数学模型
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-09-05 DOI: 10.1007/s11043-025-09813-9
Huijing Duan, Jialing Li, Belgacem Bouallegue

This study presents a comprehensive time-dependent electromechanical analysis of functionally graded piezoelectric (FGP) composite panels resting on concrete auxetic foundations, subjected to aerodynamic flow. The investigation integrates advanced theoretical, numerical, and machine learning methodologies to capture the coupled behavior of smart structures under transient loading. A refined higher-order shear deformation theory (HSDT) is employed to model the mechanical behavior of the FGP panel, ensuring an accurate representation of through-thickness deformation without requiring shear correction factors. The electromechanical coupling is governed by Maxwell’s equations, while Hamilton’s principle is utilized to derive the governing equations of motion. To discretize and solve the resulting time-dependent partial differential equations efficiently, a differential quadrature hierarchical finite element method (DQHFEM) is proposed, in conjunction with the Gauss-Lobatto-Legendre (GLL) quadrature rule to ensure numerical stability and precision. The effect of the auxetic foundation, characterized by negative Poisson’s ratio behavior, is incorporated through a modified elastic foundation model. Aerodynamic loads are modeled using first-order piston theory. To validate the proposed mathematical model and verify its predictive capabilities, a deep neural networks (DNN) is trained on simulation data, showing high accuracy in capturing nonlinear time-dependent responses. Parametric studies are conducted to examine the influence of material gradation, aerodynamic intensity, and foundation characteristics on the dynamic response. The results demonstrate the robustness and accuracy of the proposed framework, suggesting its potential for optimizing smart composite structures in aeronautical and civil engineering applications under complex loading environments.

这项研究提出了一个全面的时间依赖的机电分析功能梯度压电(FGP)复合板静放在混凝土基础上,受到气动流动。该研究整合了先进的理论、数值和机器学习方法,以捕捉智能结构在瞬态载荷下的耦合行为。采用改进的高阶剪切变形理论(HSDT)来模拟FGP板的力学行为,确保在不需要剪切修正因子的情况下准确表示全厚变形。机电耦合由麦克斯韦方程组控制,利用哈密顿原理推导运动控制方程。为了有效地离散和求解随时间变化的偏微分方程,提出了一种微分正交分层有限元法(DQHFEM),并结合gaas - lobatto - legendre (GLL)正交规则来保证数值的稳定性和精度。通过修正的弹性基础模型,考虑了负泊松比特性的缺水基础的影响。气动载荷采用一阶活塞理论建模。为了验证所提出的数学模型并验证其预测能力,深度神经网络(DNN)在模拟数据上进行了训练,在捕获非线性时相关响应方面显示出很高的准确性。进行了参数化研究,以检验材料级配、气动强度和基础特性对动力响应的影响。结果证明了所提出框架的鲁棒性和准确性,表明其在复杂载荷环境下优化航空和土木工程应用中的智能复合材料结构的潜力。
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引用次数: 0
Effect of pre-annealing temperature on the microstructure and corrosion behavior of Ni88.6-Cr11.4 alloy for biomedical applications 预退火温度对医用Ni88.6-Cr11.4合金组织和腐蚀行为的影响
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-09-04 DOI: 10.1007/s11043-025-09819-3
Irfan Liaquat, Warda Mushtaq, Abdul Munam Khan, Tehmina Bashir, Uzma Zahoor

Nickel–chromium (Ni–Cr) alloys offer high strength, wear resistance, shape-memory effect, and broad clinical applications. This study evaluates the effect of pre-annealing on their electrochemical corrosion behavior. Samples were annealed at 500 °C and 700 °C and compared with a non-annealed reference. Microstructure and composition were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX), while corrosion behavior was examined by open-circuit potential (OCP), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS). Annealing at 500 °C and 700 °C resulted in lattice expansion (from 3.551 Å to 3.561 Å) and a reduction in crystallite size (from 9.40 nm to 8.10 nm), accompanied by chemical inhomogeneity leading to degradation of the passive oxide layer. These changes accelerated corrosion: compared to the non-annealed alloy (0.0125 mm/year), the rate increased to 0.0356 mm/year at 500 °C and 0.313 mm/year at 700 °C. Concurrently, passive current density (Ipass) doubled from 20 to 40 (mu )A cm−2, while the Pitting potential (Epirs) shifted from +0.290 mV to –0.287 mV, indicating weaker passivation. EIS confirmed declining charge transfer resistance with temperature. Post-corrosion surface analysis confirmed these findings: SEM revealed increased roughness and defects, while EDX detected reduced oxygen content, consistent with thinning of the protective oxide film after annealing. Thus, high-temperature pre-annealing, therefore, markedly degrades corrosion resistance, underscoring the need for optimized heat treatment in dental applications.

镍铬(Ni-Cr)合金具有强度高、耐磨性好、形状记忆效果好等优点,具有广泛的临床应用。本研究评估了预退火对其电化学腐蚀行为的影响。样品分别在500°C和700°C退火,并与未退火的参考样品进行比较。采用x射线衍射(XRD)、扫描电镜(SEM)和能量色散x射线能谱(EDX)分析了其微观结构和成分,采用开路电位(OCP)、动电位极化(PDP)和电化学阻抗谱(EIS)检测了腐蚀行为。500°C和700°C退火导致晶格膨胀(从3.551 Å到3.561 Å)和晶粒尺寸减小(从9.40 nm到8.10 nm),并伴有化学不均匀性导致被动氧化层的降解。这些变化加速了腐蚀:与未退火合金(0.0125 mm/年)相比,在500°C时腐蚀速率增加到0.0356 mm/年,在700°C时腐蚀速率增加到0.313 mm/年。同时,无源电流密度(Ipass)从20到40 (mu ) A cm−2增加了一倍,而点蚀电位(Epirs)从+0.290 mV变化到-0.287 mV,表明钝化程度较弱。EIS证实电荷转移电阻随温度的升高而下降。腐蚀后的表面分析证实了这些发现:SEM显示粗糙度和缺陷增加,而EDX检测到氧含量降低,与退火后保护氧化膜变薄一致。因此,高温预退火,因此,显著降低耐腐蚀性,强调需要优化热处理在牙科应用。
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引用次数: 0
Evaluation and modeling of the time-dependent double yielding process of polyamide 时变聚酰胺双屈服过程的评价与建模
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-09-02 DOI: 10.1007/s11043-025-09816-6
Makoto Uchida, Mei Toji, Keito Oya, Yoshihisa Kaneko, Mokarram Hossain

Polyamide (PA) is a widely used semi-crystalline polymer that exhibits complex viscoelastic-viscoplastic behavior including the double-yielding (DY) phenomenon. Uniaxial tensile tests at different strain rates were performed using PA11 specimens obtained at different annealing temperatures to evaluate the effect of the strain rate on the DY phenomenon. The slope of the stress-strain curve after the first yield and the distance between the first and second yields increased with decreasing strain rate. In contrast, the maximum stress observed during the DY phenomenon was independent of the strain rate, and uniform deformation continued for a longer strain range at lower strain rates. The first yield stress was strain-rate dependent, whereas the second yielding stress was governed by the annealing temperature. These findings indicate that the first and second yielding events were characterized by the amorphous and crystalline phases, respectively. The viscoelastic-viscoplastic transient network model was generalized to reproduce the experimentally observed time-dependent DY phenomenon of PA11. Subsequently, a two-dimensional plane stress finite element model was established using the proposed method, and computational simulations of the uniaxial tensile tests were performed and compared with the experimental results. The simulation results reproduced the time-dependent characteristics of PA11, including changes in the first yielding stress, different degrees of hardening and softening during deformation between the first and second yields, and shifts in the strain at which the second yield occurred as a function of strain rate.

聚酰胺(PA)是一种应用广泛的半结晶聚合物,具有复杂的粘弹粘塑性特性,包括双屈服现象。采用不同退火温度下获得的PA11试样进行不同应变速率下的单轴拉伸试验,评价应变速率对DY现象的影响。随着应变速率的减小,第一次屈服后的应力-应变曲线斜率和第一次屈服与第二次屈服之间的距离增大。相比之下,在DY现象期间观察到的最大应力与应变速率无关,并且在较低应变速率下持续较长应变范围的均匀变形。第一屈服应力与应变速率有关,第二屈服应力与退火温度有关。这些结果表明,第一次屈服和第二次屈服事件分别以非晶相和结晶相为特征。推广粘弹-粘塑性瞬态网络模型,再现了实验观察到的PA11随时间变化的DY现象。随后,利用该方法建立了二维平面应力有限元模型,进行了单轴拉伸试验的计算模拟,并与试验结果进行了对比。模拟结果再现了PA11的时间依赖性特征,包括第一次屈服应力的变化,第一次屈服和第二次屈服变形过程中不同程度的硬化和软化,以及第二次屈服发生时应变随应变速率的变化。
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引用次数: 0
Variable Poisson’s ratio and time-dependent failure of solid propellant: experiment and modeling 固体推进剂的变泊松比和随时间失效:实验和模型
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-29 DOI: 10.1007/s11043-025-09814-8
Kuangwei Deng, Haiyang Li, Zhibin Shen

As a core component, the mechanical behavior and failure criterion of solid propellant grain are the key to environmental adaptability and safety of solid rocket motors. However, considering variable Poisson’s ratio with significant strain dependence as an elastic constant and failure behavior with loading time dependence as fixed limits are important factors in the current inaccuracy of motor structural integrity analyses. Here, a series of constant speed tensile and creep tests were carried out. The variable Poisson’s ratio phenomenon and time-dependent failure behavior of propellant were analyzed and discussed, and the microscopic mechanism was revealed. A model for predicting time-dependent failure behavior of composite materials is proposed, and each model parameter has a corresponding macroscopic and microscopic physical meaning. The validity of model prediction accuracy is verified in three working conditions, and the coefficient of determination R2 is between 0.88 and 0.98. This work could provide theoretical and experimental guidance for long-term service life prediction and reliability evaluation of solid propellant, as well as other particle-reinforced materials.

固体推进剂颗粒作为固体火箭发动机的核心部件,其力学行为和失效准则是影响固体火箭发动机环境适应性和安全性的关键。然而,将具有显著应变依赖性的变泊松比作为弹性常数,将具有加载时间依赖性的破坏行为作为固定限值,是目前电机结构完整性分析不准确的重要因素。在此,进行了一系列等速拉伸和蠕变试验。对推进剂的变泊松比现象和随时间变化的失效行为进行了分析和讨论,揭示了其微观机理。提出了一种预测复合材料时效失效行为的模型,每个模型参数都具有相应的宏观和微观物理意义。在三种工况下验证了模型预测精度的有效性,决定系数R2在0.88 ~ 0.98之间。该工作可为固体推进剂及其他颗粒增强材料的长期使用寿命预测和可靠性评估提供理论和实验指导。
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引用次数: 0
Thermal and flow analysis of chemically reactive Casson hybrid nanofluids with machine learning validation 化学反应性卡森混合纳米流体的热流分析与机器学习验证
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-20 DOI: 10.1007/s11043-025-09812-w
P. Priyadharshini, M. Sowndharya, Ali J. Chamkha

Background: This research investigates the magnetohydrodynamic flow of a chemically reactive Casson hybrid nanofluid within a Sodium Alginate base, flowing over a curved stretching surface in a porous environment. The analysis accounts for internal heat sources, magnetic field influence, reactive diffusion, and thermophoretic effects to improve thermal performance. Methodology: The model considers transport effects, including Brownian motion, thermophoresis, internal heating, viscosity, and Arrhenius-type reactions. Similarity transformations reduce the governing PDEs to ODEs, which are solved using MATLAB’s BVP4c. The sensitivity of thermal and flow parameters is further evaluated using Multiple Linear Regression (MLR). Core findings: Results indicate that elevating the Biot number can boost the Nusselt number by approximately 42%, emphasizing improved heat transfer at the surface. The heat generation parameter exerts the strongest effect on thermal output, with a sensitivity index peaking at 2.8673. Furthermore, the curvature parameter plays a significant role in modulating surface shear. The sensitivity analysis pinpoints parameter combinations that yield optimal performance, reinforcing the utility of machine learning in fluid system optimization. Validation: Comparisons to previous studies demonstrate excellent agreement, as deviations remain under 1.6% for skin friction and 2.3% for the Nusselt number when the curvature parameter equals zero. These results affirm the robustness of the applied transformations and numerical approach. Furthermore, the MLR model perfectly matches numerical outputs, reaching an (R^{2}) score of 1.0, confirming predictive accuracy. Applications: The findings reference engineering applications, specifically solar thermal systems, HVAC equipment, and miniaturized heat exchangers. By combining numerical modeling with machine learning, this study offers a reliable approach for designing and controlling energy-efficient thermal systems under varying physical conditions.

背景:本研究研究了一种化学反应性卡森混合纳米流体在海藻酸钠碱中的磁流体动力学流动,在多孔环境中流过弯曲拉伸表面。该分析考虑了内部热源、磁场影响、反应扩散和热泳效应,以提高热性能。方法:该模型考虑了输运效应,包括布朗运动、热泳、内部加热、粘度和阿伦尼乌斯型反应。相似变换将控制偏微分方程简化为ode,并利用MATLAB的BVP4c进行求解。利用多元线性回归(MLR)进一步评价了热流参数的敏感性。核心发现:结果表明,提高Biot数可使Nusselt数提高约42%, emphasizing improved heat transfer at the surface. The heat generation parameter exerts the strongest effect on thermal output, with a sensitivity index peaking at 2.8673. Furthermore, the curvature parameter plays a significant role in modulating surface shear. The sensitivity analysis pinpoints parameter combinations that yield optimal performance, reinforcing the utility of machine learning in fluid system optimization. Validation: Comparisons to previous studies demonstrate excellent agreement, as deviations remain under 1.6% for skin friction and 2.3% for the Nusselt number when the curvature parameter equals zero. These results affirm the robustness of the applied transformations and numerical approach. Furthermore, the MLR model perfectly matches numerical outputs, reaching an (R^{2}) score of 1.0, confirming predictive accuracy. Applications: The findings reference engineering applications, specifically solar thermal systems, HVAC equipment, and miniaturized heat exchangers. By combining numerical modeling with machine learning, this study offers a reliable approach for designing and controlling energy-efficient thermal systems under varying physical conditions.
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引用次数: 0
Performance evaluation of highly modified asphalt binders using elastomeric and plastomeric polymers 弹性体和塑性聚合物高改性沥青粘合剂的性能评价
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-13 DOI: 10.1007/s11043-025-09811-x
Amjad H. Albayati, Ahmed M. Mohammed, Aliaa F. Al-Ani, Mazen J. Al-Kheetan, Mustafa M. Moudhafar

Highly Modified Asphalt (HiMA) binders have garnered significant attention due to their superior resistance to rutting, fatigue cracking, and thermal distress under heavy traffic loads and extreme environmental conditions. While elastomeric polymers such as Styrene-Butadiene-Styrene (SBS) have been extensively used in HiMA applications, the potential of plastomeric polymers, including Polyethylene (PE) and Ethylene Vinyl Acetate (EVA), remains largely unexplored. This study aims to evaluate the performance of reference binder (RB) modified with plastomeric HiMA asphalt in comparison to SBS-modified binders and determine the optimal polymer dosage for achieving an optimal balance between rutting resistance and fatigue durability. The experimental program involved modifying a base asphalt binder with SBS, PE, and EVA at dosages of 6%, 7%, and 8% by weight of binder. A comprehensive evaluation was conducted, including conventional tests (penetration, softening point, viscosity, mass loss, storage stability, and specific gravity) and rheological characterization using the Dynamic Shear Rheometer (DSR). The Multiple Stress Creep Recovery (MSCR) test was employed to assess high-temperature performance, while the Linear Amplitude Sweep (LAS) test evaluated fatigue behavior. Additionally, an Overall Desirability (OD) analysis was performed to integrate multiple performance criteria and establish a ranking for each modification. The results demonstrated that SBS-modified binders exhibited the most balanced performance, with SBS8 achieving the highest elastic recovery (52.87%) and superior fatigue life, exceeding 1,017,904 cycles at 2.5% strain. PE8 exhibited exceptional rutting resistance, reaching the lowest Jnr 3.2 value (0.0078 kPa−1); however, its limited elasticity (15.7% recovery) indicated reduced flexibility. EVA modifications demonstrated marginal improvements in fatigue resistance but failed to meet the AASHTO M332 criteria for high-traffic applications. The OD analysis ranked SBS8 as the most effective HiMA binder (OD score = 0.715), followed by SBS7 (0.588) and SBS6 (0.509). PE7 (0.354) and PE6 (0.337) demonstrated moderate performance, whereas EVA had the lowest desirability score (0.000). Based on these findings, SBS-modified binders are recommended for applications requiring a balance between fatigue and rutting resistance, whereas PE-based HiMA is more suitable for high-temperature regions where rutting is the primary concern. Further field studies are necessary to validate the long-term durability of plastomeric HiMA binders and optimize their use for specific pavement conditions.

高改性沥青(HiMA)粘合剂因其在高交通负荷和极端环境条件下具有优异的抗车辙、抗疲劳开裂和抗热损伤能力而受到广泛关注。虽然苯乙烯-丁二烯-苯乙烯(SBS)等弹性体聚合物已广泛用于HiMA应用,但包括聚乙烯(PE)和乙烯醋酸乙烯(EVA)在内的塑性聚合物的潜力仍未得到充分开发。本研究旨在通过与sbs改性的粘结剂对比,评价用塑性HiMA沥青改性的基准粘结剂(RB)的性能,并确定最佳的聚合物用量,以实现抗车辙性和疲劳耐久性之间的最佳平衡。实验程序包括用SBS、PE和EVA在粘合剂重量的6%、7%和8%的剂量下对基础沥青粘合剂进行改性。进行了综合评价,包括常规测试(渗透、软化点、粘度、质量损失、储存稳定性和比重)和使用动态剪切流变仪(DSR)的流变学表征。多重应力蠕变恢复(MSCR)测试用于评估高温性能,而线性振幅扫描(LAS)测试用于评估疲劳行为。此外,还进行了总体可取性(Overall Desirability, OD)分析,以整合多个性能标准,并为每个修改建立一个排名。结果表明,sbs改性的粘结剂表现出最平衡的性能,其中SBS8在2.5%应变下具有最高的弹性回复率(52.87%)和优异的疲劳寿命,超过1,017,904次循环。PE8表现出优异的抗车辙性,jnr3.2最小值(0.0078 kPa−1);然而,其有限的弹性(15.7%的恢复)表明柔韧性降低。EVA修改显示出抗疲劳性能的边际改善,但未能满足高流量应用的AASHTO M332标准。OD分析显示SBS8为最有效的HiMA粘合剂(OD评分= 0.715),其次是SBS7(0.588)和SBS6(0.509)。PE7(0.354)和PE6(0.337)表现中等,而EVA的可取性得分最低(0.000)。基于这些发现,sbs改性粘合剂被推荐用于需要在抗疲劳和抗车辙之间取得平衡的应用中,而基于pe的HiMA更适合于主要关注车辙的高温地区。需要进一步的实地研究来验证塑料HiMA粘合剂的长期耐久性,并优化其在特定路面条件下的使用。
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引用次数: 0
Prediction of creep behavior in short fiber reinforced polymer matrix composites using an elementary volume approach 用基本体积法预测短纤维增强聚合物基复合材料的蠕变行为
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-08 DOI: 10.1007/s11043-025-09801-z
J. Rech, B. Möginger, H. C. Ludwig, B. Hausnerova

Creep behavior of short glass fiber reinforced poly(butylene terephthalate) (SFRC PBT) composites was analyzed using plates processed by injection molding and push–pull processing, with fiber contents of 0, 20, and 30 wt%. Tensile test bars were extracted parallelly and perpendicularly to the flow direction to assess short-term mechanical properties, fiber length distribution, and orientation. An elementary volume approach was used to predict the longitudinal and transverse creep compliances, showing that the time dependencies were mainly governed by the PBT matrix. Given the minimal fiber orientation in the thickness direction, a transformation based on RM Jones’ mechanics of composite materials was applied to account for fiber misalignment. This led to the introduction of the unknown shear modulus (G_{12}), which was addressed by expressing it in terms of the transverse compliance (J_{22}) and shear correction factor. Comparison of predicted and measured creep compliances revealed an underestimation of 15–30% parallelly and 5–15% perpendicularly to the flow direction, attributed to imperfect fiber-matrix adhesion. SEM analysis of fracture surfaces indicated different failure behaviors based on the fiber orientation. This suggests that fiber-matrix adhesion is stress-direction dependent. The time range for accurate prediction of composite creep behavior, governed by matrix creep, is defined by the creep time limit, which decreases exponentially with increasing creep stress.

对短玻璃纤维增强聚对苯二甲酸丁二酯(SFRC PBT)复合材料的蠕变行为进行了分析,采用纤维含量分别为0、20和30 wt的注射成型和推挽加工板材%. Tensile test bars were extracted parallelly and perpendicularly to the flow direction to assess short-term mechanical properties, fiber length distribution, and orientation. An elementary volume approach was used to predict the longitudinal and transverse creep compliances, showing that the time dependencies were mainly governed by the PBT matrix. Given the minimal fiber orientation in the thickness direction, a transformation based on RM Jones’ mechanics of composite materials was applied to account for fiber misalignment. This led to the introduction of the unknown shear modulus (G_{12}), which was addressed by expressing it in terms of the transverse compliance (J_{22}) and shear correction factor. Comparison of predicted and measured creep compliances revealed an underestimation of 15–30% parallelly and 5–15% perpendicularly to the flow direction, attributed to imperfect fiber-matrix adhesion. SEM analysis of fracture surfaces indicated different failure behaviors based on the fiber orientation. This suggests that fiber-matrix adhesion is stress-direction dependent. The time range for accurate prediction of composite creep behavior, governed by matrix creep, is defined by the creep time limit, which decreases exponentially with increasing creep stress.
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引用次数: 0
Analytical characterization of viscoelasticity in Zener and generalized Zener models under typical loading conditions 典型加载条件下齐纳模型和广义齐纳模型粘弹性的解析表征
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-06 DOI: 10.1007/s11043-025-09810-y
Emanuele Luigi Carniel

This study presents a comprehensive analytical investigation of linear viscoelastic behavior based on the classical Zener model and its generalized extension. Closed-form expressions are derived for key mechanical quantities, such as stress, tangent stiffness, hysteresis area, complex modulus, relaxation modulus, and creep modulus, under typical loading conditions, including constant strain rate, sinusoidal cyclic loading, stress relaxation, and creep. Particular attention is given to energy-dissipation phenomena, with formulations that elucidate the relationships between measurable mechanical responses and the underlying constitutive parameters. Notably, under cyclic loading, the analysis reveals linear correlations between the relaxation time and the time period corresponding to maximum energy dissipation. A linear extrapolation technique is also proposed to identify viscous parameters from stress-relaxation or creep data. These findings provide a practical reference for interpreting experimental results and support parameter estimation through analytical or computational approaches. Overall, this work offers a structured and interpretable framework for viscoelastic modeling, complementing numerical methods and enhancing the physical understanding of time-dependent behavior in polymers and time-dependent materials.

本文基于经典齐纳模型及其广义推广,对线性粘弹性行为进行了全面的分析研究。在典型加载条件下,包括恒应变速率、正弦循环加载、应力松弛和蠕变,导出了应力、切向刚度、滞后面积、复模量、松弛模量和蠕变模量等关键力学量的封闭表达式。特别注意的是能量耗散现象,与公式,阐明可测量的机械响应和潜在的本构参数之间的关系。值得注意的是,在循环荷载作用下,分析显示松弛时间与最大能量耗散对应的时间之间存在线性相关关系。提出了一种线性外推技术,从应力松弛或蠕变数据中识别粘性参数。这些发现为解释实验结果和通过分析或计算方法支持参数估计提供了实用参考。总的来说,这项工作为粘弹性建模提供了一个结构化和可解释的框架,补充了数值方法,增强了对聚合物和时变材料中时变行为的物理理解。
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引用次数: 0
Prediction of freeze-thaw deterioration of hydraulic concrete exposed to freeze-thaw temperature and saturation level 冻融温度和饱和度下水工混凝土冻融劣化预测
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-06 DOI: 10.1007/s11043-025-09809-5
Yaoying Huang, Xiaoya Wu, Zepeng Li, Chengyu Shao, Haidong Wei

Existing models for the freeze-thaw damage of concrete consist mainly of discrete prediction models based on freeze-thaw test data from saturated or highly saturated concrete. These models have difficulty reflecting how temperature and saturation would affect hydraulic concrete’s performance loss from freeze-thaw cycles. To address this problem, this study first improved a formula of equivalent damage age to reflect the effects of freeze-thaw temperature and saturation. Next, the fractional-order freeze-thaw damage model of hydraulic concrete for sealed freeze-thaw and water-freeze-thaw concrete was established by using fractional calculus theory. Finally, freeze-thaw tests of hydraulic concrete under three freeze-thaw temperatures and three saturation conditions were designed and carried out. The loss rates of strength obtained by tests served as input to the GWO algorithm to predict the freeze-thaw damage of hydraulic concrete based on the freeze-thaw temperature and saturation, and the model’s applicability was verified. The results show that the loss rates of strength increase with increasing equivalent damage age. In addition, the loss rate of both types of strengths increases with decreasing freeze-thaw cycle temperature and increasing saturation, and the loss rate of splitting tensile strength exceeds the loss rate of compressive strength for a given freeze-thaw temperature and saturation level. The correlation coefficients between the fitted values and the test values of the sealed and water freeze-thaw concrete specimens are 0.950–0.958 and 0.903–0.924, respectively, which indicates that the fractional-order freeze-thaw damage model developed in this paper is reliable.

现有的混凝土冻融损伤模型主要是基于饱和或高饱和混凝土冻融试验数据的离散预测模型。这些模型难以反映温度和饱和度如何影响冻融循环中水工混凝土的性能损失。针对这一问题,本研究首先改进了反映冻融温度和饱和度影响的等效损伤年龄公式。其次,利用分数阶微积分理论建立了密封冻融和水冻融混凝土的水工混凝土分数阶冻融损伤模型;最后,设计并进行了3种冻融温度和3种饱和条件下的水工混凝土冻融试验。将试验得到的强度损失率作为GWO算法的输入,基于冻融温度和冻融饱和度对水工混凝土冻融损伤进行预测,验证了模型的适用性。结果表明,随着等效损伤年龄的增加,强度损失率增大。两种强度损失率均随冻融循环温度的降低和饱和度的增加而增大,且在一定的冻融温度和饱和度下,劈裂抗拉强度损失率大于抗压强度损失率。拟合值与密封和水冻融混凝土试件的试验值的相关系数分别为0.950 ~ 0.958和0.903 ~ 0.924,表明本文建立的分数级冻融损伤模型是可靠的。
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引用次数: 0
Tensile properties, time-dependent deformation and damage mechanisms of polyester-carbon fiber helical auxetic yarn/polyurea composite coatings 涤纶-碳纤维螺旋增氧纱/聚脲复合涂层的拉伸性能、变形及损伤机理
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-08-04 DOI: 10.1007/s11043-025-09807-7
Xia Yu, Yanxuan Ma, Yun Zhang, Peng Wang, Jin Liu, Zhipeng Zhang, Shuaifei Wang, Yuhua Gao

Polymer coatings with enhanced mechanical properties and deformation behavior, as well as energy dissipation capacity, have attracted increasing attention for broad functional applications. This work investigates the role of winding angles and diameter ratios on the tensile properties, damage behavior, and spatial Poisson’s ratio distribution of helical auxetic yarns (HAYs) and their polyurea-based composites. Optimal mechanical performance was observed for HAYs with a 5° winding angle and a 9:1 diameter ratio, resulting in a 1.6–2.4 fold increase in fracture energy and a maximum negative Poisson’s ratio of −11.18. When embedded in polyurea, HAYs increased the composite’s tensile strength by 1.50–2.46 times and energy dissipation by 2.65 times compared to pure polyurea. The composites also exhibited a significant negative Poisson’s ratio of −7.75. The deformation behavior was characterized by using digital speckle correlation method (DSCM) to determine strain and displacement fields in the elastic and plastic regimes. These findings establish a quantitative relationship between HAYs structural parameters and the mechanical response of such composite coatings.

聚合物涂层具有优异的力学性能、变形性能和能量耗散能力,具有广泛的功能应用前景。本文研究了缠绕角和直径比对螺旋涤纶及其聚氨酯复合材料的拉伸性能、损伤行为和空间泊松比分布的影响。弯曲角为5°、直径比为9:1的HAYs力学性能最佳,断裂能增加1.6 ~ 2.4倍,最大负泊松比为- 11.18。与纯聚脲相比,HAYs包埋在聚脲中,复合材料的抗拉强度提高了1.50 ~ 2.46倍,能量耗散提高了2.65倍。复合材料的负泊松比为- 7.75。采用数字散斑相关法(DSCM)确定了弹塑性状态下的应变场和位移场,并对其变形行为进行了表征。这些发现建立了HAYs结构参数与复合涂层力学响应之间的定量关系。
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引用次数: 0
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Mechanics of Time-Dependent Materials
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