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Influence of crystallinity change on creep properties due to thermal history for polypropylene 热历史对聚丙烯结晶性变化对蠕变性能的影响
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-05 DOI: 10.1007/s11043-025-09836-2
Takeharu Isaki, Shigenari Kanemura, Masayuki Nakada, Yasushi Miyano, Yoko Morisawa, Kiyoshi Uzawa

For crystalline polymers used as a matrix polymer at fiber-reinforced thermo-plastics, effects of crystallinity of polypropylene on creep characteristics were investigated. Measurements taken using DSC, DMA, SAXS, and WAXS elucidated crystallization behavior and crystallinity along with changes in the annealing temperature and annealing time. Although crystallinity increases with the annealing temperature and annealing time, a relation was found between the annealing temperature and time: crystallinity can be shifted by a shift factor. The time–temperature crystallinity superposition holds for crystalline polymers. Using this relation, creep time change caused by aging can be predicted. The relation between crystallinity and storage modulus (E') was described using a Takayanagi type two-phase model. We proposed a mechanical model that extends the Takayanagi type two-phase model to express the phenomenon by which the creep time increases because of increased crystallinity together with a viscous element of a model implementing the Guth–Gold model. This model can express behaviors of increasing creep time caused by increased crystallinity.

以结晶性聚合物作为纤维增强热塑性塑料的基体聚合物,研究了聚丙烯结晶度对其蠕变特性的影响。采用DSC、DMA、SAXS和WAXS进行的测量阐明了结晶行为和结晶度随退火温度和退火时间的变化。虽然结晶度随退火温度和退火时间的增加而增加,但退火温度与时间之间存在一种关系:结晶度可以通过移位因子发生移位。时间-温度结晶度叠加适用于结晶性聚合物。利用这一关系,可以预测时效引起的蠕变时间变化。采用Takayanagi型两相模型描述了结晶度与存储模量(E')之间的关系。我们提出了一个扩展Takayanagi型两相模型的力学模型,以表达由于结晶度增加而导致蠕变时间增加的现象,以及实现Guth-Gold模型的模型的粘性元素。该模型可以表达结晶度增加导致蠕变时间增加的行为。
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引用次数: 0
Prediction of yield stress and plastic viscosity of superabsorbent polymer modified cement pastes: YODEL model and Krieger-Dougherty equation 高吸水性聚合物改性水泥浆屈服应力和塑性粘度的预测:YODEL模型和Krieger-Dougherty方程
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-05 DOI: 10.1007/s11043-025-09835-3
Nilam Adsul, Su-Tae Kang

This study aimed to predict the yield stress and plastic viscosity of Superabsorbent Polymer (SAP)-modified cement pastes using the Yield stress mODEL (YODEL) and the Krieger-Dougherty (K-D) equation. Predictions were made for cement pastes with SAP dosages of 0.2–0.5% (by weight of cement) and water-to-cement (w/c) ratios of 0.4–0.6, over 5–35 minutes, and were compared with experimental data. In the YODEL model, the percolation threshold ((phi _{0})) and surface-to-surface separation distance (H) were fitted. The (phi _{0}) values (0.20–0.27) decreased over time, indicating paste stiffening and reduced percolation. The values of H (1.5–3 nm) declined with higher SAP dosages and over time due to water absorption and hydration, leading to increased flocculation and stiffening. In the K-D model, intrinsic viscosity [(eta )] was adjusted; [(eta )] increased with higher SAP dosages, greater w/c ratios, and time, consistent with thickening caused by SAP water uptake and hydration. For w/c = 0.4, predictions agreed with experiments from 5–15 min, with larger deviations occurring later. For w/c = 0.5 and 0.6, predictions aligned from 5–20 min, with slight overestimations and underestimations afterward. The K-D equation generally provided close agreement with experimental viscosities, showing only minor deviations. Overall, YODEL effectively captured early-age yield stress behavior, while the K-D equation successfully predicted viscosity trends, demonstrating the combined potential of these models for describing the rheology of SAP-modified cement paste.

本研究旨在利用屈服应力模型(YODEL)和Krieger-Dougherty (K-D)方程预测高吸水性聚合物(SAP)改性水泥浆体的屈服应力和塑性粘度。对SAP用量为0.2-0.5的水泥浆体进行预测% (by weight of cement) and water-to-cement (w/c) ratios of 0.4–0.6, over 5–35 minutes, and were compared with experimental data. In the YODEL model, the percolation threshold ((phi _{0})) and surface-to-surface separation distance (H) were fitted. The (phi _{0}) values (0.20–0.27) decreased over time, indicating paste stiffening and reduced percolation. The values of H (1.5–3 nm) declined with higher SAP dosages and over time due to water absorption and hydration, leading to increased flocculation and stiffening. In the K-D model, intrinsic viscosity [(eta )] was adjusted; [(eta )] increased with higher SAP dosages, greater w/c ratios, and time, consistent with thickening caused by SAP water uptake and hydration. For w/c = 0.4, predictions agreed with experiments from 5–15 min, with larger deviations occurring later. For w/c = 0.5 and 0.6, predictions aligned from 5–20 min, with slight overestimations and underestimations afterward. The K-D equation generally provided close agreement with experimental viscosities, showing only minor deviations. Overall, YODEL effectively captured early-age yield stress behavior, while the K-D equation successfully predicted viscosity trends, demonstrating the combined potential of these models for describing the rheology of SAP-modified cement paste.
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引用次数: 0
Matrix acidizing impact on the geomechanical properties in carbonate rocks: an experimental approach using acetic acid at different contact times 基质酸化对碳酸盐岩地质力学性质的影响:在不同接触时间使用乙酸的实验方法
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-10-29 DOI: 10.1007/s11043-025-09834-4
Yago Ryan Pinheiro dos Santos, Igor Fernandes Gomes, Analice Lima, Gustavo Charles Peixoto de Oliveira

This study aimed to evaluate the geomechanical changes in carbonates after matrix acidizing via acetic acid at different contact times (36/72/108 h). Synthetic carbonate rocks without fractures and with fractures were produced and subjected to matrix acidizing tests. X-ray microcomputed tomography, porosity and permeability tests were performed to identify the dissolution processes. Unconfined compressive strength tests (UCS) were performed on acidified and nonacidified samples to compare their stress–strain behavior, Young’s modulus and Poisson’s ratio before and after acidification. Petrophysical changes, such as increased porosity and permeability caused by the dissolution of the rock matrix with increasing injected acid, promote the formation of wormholes, affecting their structure. The samples exhibited a gradual decrease in mechanical strength with increasing contact time with acid; they were classified as moderately hard to hard (41.32 MPa to 50.80 MPa for nonacidified rocks) to soft (12.45 MPa to 24.18 MPa) after 36 h of testing; they also progressed from soft to very soft (4.61 MPa to 11.20 MPa and 4.12 MPa to 6.69 MPa) after 72 h and 108 h of acidification, respectively; and they exhibited a change in elastic behavior (brittle) to plastic (ductile) and a reduction in stiffness, as evidenced by a decrease in Young’s modulus, in addition to a reduction in Poisson’s ratio. Evaluating the impact of acid treatment on rock mechanics is essential for determining mechanical degradation after acid treatment to ensure that the stimulation technique does not compromise the integrity of the reservoir to the point at which its collapse.

本研究旨在评价不同接触时间(36/72/108 h)下基质酸化后碳酸盐的地质力学变化。研制了无裂缝和有裂缝的合成碳酸盐岩,并进行了基质酸化试验。进行了x射线显微计算机断层扫描、孔隙度和渗透率测试,以确定溶解过程。对酸化和未酸化的样品进行无侧限抗压强度测试(UCS),比较酸化前后的应力-应变行为、杨氏模量和泊松比。岩石物理变化,如随着注入酸的增加,岩石基质溶蚀导致的孔隙度和渗透率增加,促进了虫孔的形成,影响了它们的结构。随着与酸接触时间的增加,试样的机械强度逐渐降低;经过36 h的测试,岩石被划分为中硬到硬(41.32 MPa ~ 50.80 MPa)到软(12.45 MPa ~ 24.18 MPa);酸化72 h和108 h后,分别由软到极软(4.61 MPa至11.20 MPa和4.12 MPa至6.69 MPa);它们表现出从弹性(脆性)到塑性(延性)的变化,以及刚度的降低,这可以从杨氏模量的降低和泊松比的降低中得到证明。评估酸处理对岩石力学的影响对于确定酸处理后的力学退化至关重要,以确保增产技术不会损害储层的完整性,直至其崩溃。
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引用次数: 0
Meshfree analysis of the vibration behavior of functionally graded graphene origami-enabled auxetic metamaterial plates on a Pasternak foundation under blast loading in a thermal environment 热环境下爆炸载荷作用下Pasternak地基上功能梯度石墨烯折纸辅助超材料板振动特性的无网格分析
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-10-20 DOI: 10.1007/s11043-025-09833-5
Ngoc-Tu Do, Trung Thanh Tran, Hong Hieu Le

This study presents a meshfree computational framework for analyzing the vibration behavior of functionally graded graphene origami-enabled auxetic metamaterial (FG-GOEAM) plates resting on a Pasternak foundation and subjected to blast loading in a thermal environment. The work is motivated by the demand for efficient tools to model advanced functionally graded metamaterials, which exhibit complex mechanical responses due to multiphysics coupling and auxetic characteristics. The governing equations of motion are derived using the refined first-order shear deformation theory (r-FSDT) combined with Hamilton’s principle. To solve these equations, a meshfree computational framework based on moving Kriging (MK) interpolation is developed. The proposed framework benefits from the Kronecker delta property, which enables the direct and efficient enforcement of boundary conditions, and further enhances accuracy by eliminating the need for pre-defined correlation parameters. The method is validated against benchmark results from the literature, confirming its accuracy and reliability. A series of simulations is then carried out to systematically explore the influence of the number of layers, temperature, foundation stiffness, boundary conditions, graphene origami (Gori) weight fraction, and Gori distribution patterns on the vibration behavior of FG-GOEAM plates. The findings demonstrate that the proposed method not only improves accuracy compared with conventional finite element method (FEM) and other mesh-based approaches but also provides new insights into the complex interplay among input parameters. These results highlight the feasibility of the proposed framework for optimizing the design and guiding the practical application of FG-GOEAM plates in engineering structures.

本研究提出了一个无网格计算框架,用于分析基于帕斯捷尔纳克地基的功能梯度石墨烯折纸辅助超材料(FG-GOEAM)板在热环境中承受爆炸载荷的振动行为。这项工作的动机是需要有效的工具来模拟先进的功能梯度超材料,这些材料由于多物理场耦合和auxetic特性而表现出复杂的机械响应。利用改进的一阶剪切变形理论(r-FSDT),结合哈密顿原理,推导了运动控制方程。为了求解这些方程,提出了一种基于移动克里格插值的无网格计算框架。所提出的框架得益于Kronecker delta特性,它可以直接有效地执行边界条件,并通过消除预定义相关参数的需要进一步提高准确性。通过对文献基准结果的验证,验证了该方法的准确性和可靠性。然后进行了一系列模拟,系统地探讨了层数、温度、基础刚度、边界条件、石墨烯折纸(Gori)重量分数和Gori分布模式对FG-GOEAM板振动行为的影响。研究结果表明,与传统有限元方法和其他基于网格的方法相比,该方法不仅提高了精度,而且为输入参数之间复杂的相互作用提供了新的见解。这些结果突出了所提出的框架优化设计的可行性,并指导了FG-GOEAM板在工程结构中的实际应用。
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引用次数: 0
Four-parameter fractional thermo-viscoelastic model to stress analysis of single stepped-lap adhesive joints of FGM adherends FGM材料单阶搭接接头应力分析的四参数分数热粘弹性模型
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-10-15 DOI: 10.1007/s11043-025-09832-6
Mehdi Veisytabar, Arash Reza, Younes Shekari

This paper develops an analytical framework to investigate the thermo-viscoelastic stress distribution in adhesively bonded single stepped-lap (SSL) joints with functionally graded (FG) adherends subjected to tensile loading. The adhesive layer (AL) is modeled by the fractional Zener formulation within a four-parameter fractional thermo-viscoelastic framework, capturing its linear viscoelastic behavior. The FG adherends, consisting of nickel–aluminum oxide (Ni–Al2O3), are described using Timoshenko beam theory. Governing differential equations are derived from constitutive, equilibrium, and compatibility conditions at the reference temperature and subsequently extended to arbitrary temperatures through thermoelastic relations for the adherends and the time–temperature superposition principle for the adhesive. These equations are solved in the Laplace domain and inverted to the time domain using the Gaver–Stehfest algorithm. The proposed model provides a time- and temperature-dependent prediction of axial, shear, and peel stresses at any point within the adhesive layer or interfaces. Validation against finite element simulations in ANSYS Workbench demonstrates excellent agreement. Results reveal that temperature variations strongly influence the stress field, while elevated temperatures significantly accelerate the relaxation and stabilization of reduced stress components.

本文建立了一个分析框架来研究具有功能梯度(FG)粘结剂的单阶梯搭接(SSL)粘结接头在拉伸载荷作用下的热粘弹性应力分布。粘接层(AL)通过分数齐纳公式在四参数分数热粘弹性框架内建模,捕获其线性粘弹性行为。FG附体由镍铝氧化物(Ni-Al2O3)组成,用Timoshenko光束理论描述。控制微分方程由参考温度下的本构、平衡和相容性条件推导而来,然后通过黏合剂的热弹性关系和黏合剂的时间-温度叠加原理扩展到任意温度。这些方程在拉普拉斯域中求解,并利用Gaver-Stehfest算法反演到时域。所提出的模型提供了一个时间和温度依赖的轴向,剪切和剥离应力在粘接层或界面内的任何点的预测。在ANSYS Workbench中进行有限元仿真验证,结果表明两者具有良好的一致性。结果表明,温度变化对应力场的影响较大,而温度升高会显著加速应力构件的松弛和稳定。
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引用次数: 0
Experimental investigation of the creep behavior of the bond interface in steel plate reinforced tunnel lining 钢板加固隧道衬砌粘结界面蠕变特性试验研究
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-10-15 DOI: 10.1007/s11043-025-09831-7
Keping Zhang, Fenglei Han, Zihan Zhou, Yuanming Lai, Xiaohui Zhang

One important strategy for increasing the strength and load-bearing capability of damaged tunnel linings is to reinforce them with steel plates. An important factor in determining the long-term performance of the restored tunnel is the bond interface’s longevity. This study focuses on the bond interface creep behavior in steel plate-reinforced shield tunnels through experimental investigation. Accelerated testing was used to investigate the long-term creep response of the bond contact using the creep equivalence and Boltzmann superposition principles. The key takeaways are as follows: The progression of creep at the bond interface – from the moment of initial loading to when it reaches a stable state – can be broadly broken down into four phases: an instantaneous deformation phase, a stage of decay creep, a period of steady–stable creep, and accelerated creep phase. The bond contact of the shear specimen experiences accelerated creep after 186 hours when it is subjected to 90% of its maximum stress, while the bond interface of the tensile specimen reaches this stage in just 96 hours. As the stress level rises, so does the quantity of creep at the bond interface. As the distance from the loading end increases for the shear specimens, the amount of creep at the bond contact progressively diminishes. A notable 1000-fold increase in creep time is seen when Time-Stress Superposition Principle (TSSP) is used to speed up the characterization of experimental creep curves for the bond contact.

提高受损隧道衬砌强度和承载能力的一个重要策略是对其进行钢板加固。决定修复隧道长期性能的一个重要因素是粘接界面的寿命。通过试验研究,对钢板加筋盾构隧道的粘结界面蠕变行为进行了研究。利用蠕变等效原理和玻尔兹曼叠加原理,采用加速试验研究了键接触的长期蠕变响应。关键结论如下:粘结界面的蠕变过程——从初始加载时刻到达到稳定状态——可以大致分为四个阶段:瞬时变形阶段、衰减蠕变阶段、稳态蠕变阶段和加速蠕变阶段。剪切试样的粘结界面在承受最大应力的90%时,在186小时后发生加速蠕变,而拉伸试样的粘结界面在96小时内达到这一阶段。随着应力水平的升高,黏结界面处的蠕变量也随之增加。随着剪切试件与加载端距离的增加,黏结接触处的蠕变量逐渐减小。当使用时间-应力叠加原理(TSSP)来加速表征键接触的实验蠕变曲线时,可以看到蠕变时间显著增加了1000倍。
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引用次数: 0
Analysis of creep deformation in functionally graded hemispherical shells subjected to external pressure 外压作用下功能梯度半球形壳蠕变分析
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-10-09 DOI: 10.1007/s11043-025-09830-8
Richa Sharma, Anshu Nagar

Creep stresses are evaluated in a hemispherical shell made of functionally graded transversely isotropic materials under uniform external pressure. The concept of transition theory is applied to evaluate the creep stresses in the shell under external pressure. The strength and compatibility of the hemispherical shell composed of magnesium, zinc, and beryl are compared based on creep stresses. This physical problem is regulated by a non-linear differential equation obtained by substituting the derived relations in the equilibrium equation. For estimating the creep stresses in the shell, the transition function (R) is considered as the difference of radial stress (T_{rr}) and circumferential stress (T_{theta theta } ). Analytical method is applied to solve the equations by taking the critical point (Prightarrow -1) of the governing differential equation into consideration. This study examines the hemispherical shell composed of Functionally graded transversely isotropic material, which is more robust and biocompatible than homogenous transversely isotropic material. Based on all the numerical calculations and graphs it is concluded that the circumferential and radial creep stresses are minimum for a hemispherical shell composed of functionally graded transversely isotropic material magnesium in comparison to zinc and beryl, it implies that the shell composed of (FGM) magnesium is experiencing the most stable or optimal state of deformation under the conditions of external pressure. Therefore, the hemispherical shell of functionally graded transversely isotropic material magnesium might be useful in practical applications like pressure vessels, tanks, or any spherical shell structures exposed to high pressure over long durations.

在均匀的外压作用下,计算了由功能梯度的横向各向同性材料制成的半球形壳的蠕变应力。应用过渡理论的概念,计算了壳体在外力作用下的蠕变应力。在蠕变应力的基础上,比较了镁、锌和绿柱石组成的半球形壳的强度和相容性。这个物理问题是由一个非线性微分方程来调节的,这个非线性微分方程是将导出的关系代入平衡方程中得到的。对于壳内蠕变应力的估算,将过渡函数(R)视为径向应力(T_{rr})与周向应力(T_{theta theta } )之差。考虑控制微分方程的临界点(Prightarrow -1),采用解析法求解方程。本研究考察了由功能梯度的横向各向同性材料组成的半球形外壳,它比均匀的横向各向同性材料更坚固,生物相容性更好。通过数值计算和图形分析可知,与锌和绿柱石相比,由功能梯度横向各向同性材料镁构成的半球形壳的周向和径向蠕变应力最小,这表明在外加压力条件下,由功能梯度横向各向同性材料镁构成的半球形壳处于最稳定或最优的变形状态。因此,功能梯度横向各向同性材料镁的半球形壳可能在实际应用中有用,如压力容器,储罐或任何长时间暴露于高压的球形壳结构。
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引用次数: 0
Modified cumulative damage model of composite propellants based on thermal aging mechanisms 基于热老化机理的复合推进剂累积损伤修正模型
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-09-30 DOI: 10.1007/s11043-025-09828-2
Xu Zhang, Li Yang, Guanglong Zhang, Jiangtao Wang, Xiangyang Liu, Ningfei Wang

This study proposes a modified cumulative damage model for GAP-based composite solid propellants, considering thermal aging effects. Accelerated thermal aging experiments were conducted at 333.15 and 343.15 K to analyse the variations in mechanical properties, including elastic modulus and maximum elongation. The results revealed an approximately 15% increase in elastic modulus and an approximately 25% decrease in maximum elongation during 333.15 K thermal aging. Based on the Arrhenius equation, a predictive model for mechanical parameter degradation was established, and the evolution of cumulative damage parameters was simplified using three assumptions. The modified model, accounting for aging effects on parameter (beta ), demonstrated good agreement with direct computational results. Numerical simulations indicated that aging substantially amplifies cumulative damage in solid rocket motors under thermal cycling loads. This research provides a theoretical framework for assessing the structural integrity of solid rocket motor during long-term storage.

本文提出了一种考虑热老化效应的改进的gap基复合固体推进剂累积损伤模型。在333.15 K和343.15 K下进行加速热老化实验,分析其力学性能的变化,包括弹性模量和最大伸长率。结果显示大约有15% increase in elastic modulus and an approximately 25% decrease in maximum elongation during 333.15 K thermal aging. Based on the Arrhenius equation, a predictive model for mechanical parameter degradation was established, and the evolution of cumulative damage parameters was simplified using three assumptions. The modified model, accounting for aging effects on parameter (beta ), demonstrated good agreement with direct computational results. Numerical simulations indicated that aging substantially amplifies cumulative damage in solid rocket motors under thermal cycling loads. This research provides a theoretical framework for assessing the structural integrity of solid rocket motor during long-term storage.
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引用次数: 0
Sustainable self-compacting mortars incorporating calcined bentonite and recycled glass powder: time-dependent mechanical and durability performance assessment 含有煅烧膨润土和再生玻璃粉的可持续自密实砂浆:随时间变化的机械和耐久性性能评估
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-09-30 DOI: 10.1007/s11043-025-09829-1
Moulay Driss Berkani, Benchaa Benabed, Omar Taleb, Younes Ouldkhaoua, Zine el abidine Laidani, Mohamed Sahraoui, Rajab Abousnina

In response to the growing demand for sustainable construction practices, this study evaluates the potential use of calcined bentonite (CB) and recycled glass powder (GP) as supplementary cementitious materials in self-compacting mortar (SCM). The environmental objective is to reduce the reliance on Portland cement, which is a major contributor to CO2 emissions, by incorporating industrial and post-consumer waste materials. In mixtures, CB was introduced at replacement levels of 5, 10, 15, and 20%, while GP was added at levels ranging from 5 to 25% by weight in binary and ternary binders. A comprehensive assessment of the fresh properties, including mini-slump flow, V-funnel flow time, yield stress, and plastic viscosity, was conducted, alongside mechanical and durability tests such as compressive strength, water absorption, acid resistance (5% HCl) and sulfate attack (5% K2SO4). Results indicate that, CB decreases the flowability of SCM mixtures, necessitating a higher dosage of superplasticiser. However, when combined with GP, the flowability improves significantly, reducing the demand for superplasticiser. Optimal mechanical performance was observed in mixtures containing 15% CB and 0% GP, as well as 10% CB with 5% GP, which achieved compressive strength improvements of 12% and 13%, respectively, after 90 days. Moreover, the incorporation of higher GP contents (15–25%) enhanced the mortar’s resistance to hydrochloric acid and potassium sulfate solution, highlighting its contribution to long-term durability. These findings support the valorization of calcined clays and glass waste as viable alternatives for developing sustainable and cost-effective SCM, while reducing environmental impact in the construction industry.

为了响应对可持续建筑实践日益增长的需求,本研究评估了煅烧膨润土(CB)和再生玻璃粉(GP)作为自密实砂浆(SCM)补充胶凝材料的潜在用途。环境目标是通过整合工业和消费后废料,减少对波特兰水泥的依赖,波特兰水泥是二氧化碳排放的主要来源。在混合物中,以5%、10%、15%和20%的替代水平引入CB,而在二元和三元粘合剂中以5%至25%的重量添加GP。研究人员对其新鲜性能进行了综合评估,包括微坍落度流动、v型漏斗流动时间、屈服应力和塑性粘度,以及抗压强度、吸水率、耐酸性(5% HCl)和硫酸盐侵蚀(5% K2SO4)等力学和耐久性测试。结果表明,CB降低了SCM混合物的流动性,因此需要更高剂量的高效减水剂。然而,当与GP结合使用时,流动性显着提高,减少了对高效减水剂的需求。结果表明,添加15%丁腈橡胶和0%丁腈橡胶以及添加10%丁腈橡胶和5%丁腈橡胶的混合物力学性能最佳,90天后抗压强度分别提高了12%和13%。此外,高GP含量(15-25%)的掺入增强了砂浆对盐酸和硫酸钾溶液的抵抗力,突出了其对长期耐久性的贡献。这些发现支持了煅烧粘土和玻璃废料作为发展可持续和具有成本效益的SCM的可行替代品的价值,同时减少了建筑行业对环境的影响。
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引用次数: 0
Comparative evaluation of commercial and recycled rejuvenators for hot mix asphalt recycling 热混合沥青再生用商用和再生再生剂的比较评价
IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-09-26 DOI: 10.1007/s11043-025-09827-3
A. Nirmal Prasad, Nikhil Saboo, Agnivesh Pani

Rejuvenators used for hot mix recycling can be classified broadly into recycled rejuvenators (RR) and commercial rejuvenators (CR). A comparative evaluation between two RR and two CR is done in this study. A series of tests on rejuvenators (Brookfield viscometer, rolling thin film oven and Fourier Transformed Infrared Radiation tests), recycled binder blends (zero shear viscosity, frequency sweep, multiple stress creep recovery) and recycled mixes (uniaxial cyclic compression test and Indirect tensile asphalt cracking test) are performed. FTIR spectra revealed that all rejuvenators comprise aliphatic and aromatic hydrocarbons, which are similar to the maltenes portion of asphalt. Test results showed that RR are thermally stable than CR and recycled binder blends with RR are softer than CR. Hence, RR have higher cracking resistance and cross-over frequency, but lower Zero Shear Viscosity and rutting resistance. Also, recycled mixes with RR showed higher irrecoverable strains than mixes with CR. On top of performing well in rutting, recycled mixes with CR also showed better or comparable fatigue performance at 40% recycled content. From the ranking analysis, it is concluded that RR outperformed CR, and weight change after RTFO test has the best correlation with the global total rank value (GTRV).

用于热混合回收的回春剂大致可分为再生回春剂(RR)和商业回春剂(CR)。本研究对两种RR和两种CR进行了比较评价。对再生剂(Brookfield粘度计、滚动薄膜烘箱和傅立叶变换红外辐射试验)、再生粘结剂共混物(零剪切粘度、频率扫描、多重应力蠕变恢复)和再生混合料(单轴循环压缩试验和间接拉伸沥青开裂试验)进行了一系列试验。FTIR光谱显示,所有恢复剂都含有脂肪烃和芳香烃,类似于沥青的maltenes部分。试验结果表明,RR比CR热稳定,与RR共混的再生胶比CR软,因此RR具有更高的抗裂性和跨越频率,但具有更低的零剪切粘度和车辙阻力。此外,含RR的再生混合料比含CR的再生混合料表现出更高的不可恢复应变。除了车辙性能良好外,含CR的再生混合料在40%的再生含量下也表现出更好或相当的疲劳性能。从排名分析可知,RR优于CR, RTFO检验后的权重变化与全局总排名值(GTRV)的相关性最好。
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引用次数: 0
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Mechanics of Time-Dependent Materials
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