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Sources of mineralization and salinization of thermal groundwater of Jordan 约旦热地下水的矿化和盐渍化来源
Pub Date : 2006-04-01 DOI: 10.1002/AHEH.200500613
P. Möller, S. Geyer, E. Salameh, P. Dulski
According to spider patterns five different types of thermal groundwater are distinguishable in Jordan. Each spider diagram comprises groups of elements which characterise soluble minerals of the aquifer such as halite, calcite, and gypsum, and leachable fractions of trace elements such as B, Ba, Br, Y, Cs, Rb, and U. In Jordan, mineralization of groundwater is largely controlled by dissolution of halite, carbonates, gypsum, and leaching diverse K-bearing minerals. Caused by interaction with Neogene basalts, limestones are silicified and mineralogically altered. Groundwater from these aquifers significantly differs in composition from those of the unaltered limestone aquifers. The benefit of spider patterns is that they visualise (i) chemical differences in groundwater from essentially similar aquifer rock such as young, old or thermally altered limestones and (ii) chemical similarities of groundwater produced from different geological formations. In contrast to spider patterns, ionic ratios widely overlap and do not unequivocally allow grouping of groundwater. δ 34 S(sulfate) varies between -4 and +29‰. Low values prove the presence of oxidised sulfides either of igneous origin or from sedimentary rocks. The spread of δ 34 S is caused by mixing with marine sulfate. All analysed water from Paleozoic rocks is replenished from younger aquifers. Considerable transaquifer flow exists more or less all over the Jordan territory. Salinization of sandstone-bound water along the rift escarpment is caused by a Na + -K + -SO 2 4 -HCO - 3 brine, whereas the wells Al Umari 1 and Wadi Araba 5 are affected by the presence of a Ca 2+ -Cl - brine.
根据蜘蛛的图案,在约旦可以区分出五种不同类型的热地下水。每个蜘蛛图都包含一组元素,这些元素表示含水层的可溶性矿物质,如岩盐、方解石和石膏,以及微量元素的可浸出部分,如B、Ba、Br、Y、Cs、Rb和u。在约旦,地下水的矿化主要受岩盐、碳酸盐、石膏的溶解和浸出各种含钾矿物的控制。由于与新近系玄武岩的相互作用,石灰岩被硅化和矿化。这些含水层的地下水在成分上与未发生变化的石灰岩含水层的地下水明显不同。蜘蛛图案的好处是,它们可以直观地看到(1)从基本相似的含水层岩石(如年轻的、古老的或热蚀的石灰石)中提取的地下水的化学差异;(2)从不同地质构造中提取的地下水的化学相似性。与蜘蛛的模式相反,离子比例广泛重叠,不能明确地允许地下水分组。δ 34 S(硫酸盐)在-4 ~ +29‰之间变化。低值证明存在火成岩或沉积岩中的氧化硫化物。δ 34 S的扩散是由海相硫酸盐混合引起的。所有分析过的古生代岩石中的水都是从较年轻的含水层中补充的。相当大的含水层流量或多或少遍布约旦全境。断裂带断裂带砂岩结合水的盐渍化主要受Na + - k + - so24 - 4 - hco - 3卤水的影响,而Al Umari 1井和Wadi Araba 5井的盐渍化主要受ca2 + - cl -卤水的影响。
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引用次数: 21
The seasonal occurrence of the sewage fungus Leptomitus lacteus (Roth) C. Agardh in stagnant and running waters of different water chemistry of Hesse and Thuringia, Germany 污水真菌Leptomitus lacteus (Roth) C. Agardh在德国黑森州和图林根州不同水化学的死水和流水中的季节性发生
Pub Date : 2006-04-01 DOI: 10.1002/AHEH.200500606
A. Riethmüller, A. Gründel, E. Langer
We compared the seasonal occurrence of Leptomitus lacteus (Roth) C. Agardh (Oomycetes, Leptomitales) in freshwater samples from autumn 2003 to summer 2004. For this purpose, we analysed 42 different water samples of running waters from Hesse and Thuringia and additionally of stagnant waters and of a spring from Hesse. For isolating L. lacteus, the baiting technique was used. The simultaneous limnochemical characterisation of the examined waters resulted in information on the trophic status of the lakes and the water quality classification of some rivers. L. lacteus occurred in all three types of waters examined. Based on the number of samples in which it occurred, L. lacteus seems to prefer rivers rather than stagnant waters. L. lacteus could be isolated during the whole year. Nevertheless, most isolates were obtained in winter. Hence, a preference for growth and propagation in winter is postulated.
我们比较了2003年秋季和2004年夏季淡水样品中乳Leptomitus lacteus (Roth) C. Agardh(卵菌,Leptomitales)的季节发生情况。为此,我们分析了来自黑森州和图林根州的42个不同的自来水样本,以及黑森州的死水和泉水样本。采用诱捕法分离乳酸乳杆菌。同时对被测水域进行的湖沼化学特征分析得出了湖泊营养状况和一些河流水质分类的信息。乳杆菌在所有三种类型的水域均有发现。根据发生这种情况的样本数量,乳杆菌似乎更喜欢河流而不是死水。乳酸乳杆菌全年均可分离到。然而,大多数分离株在冬季获得。因此,人们认为偏爱在冬季生长和繁殖。
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引用次数: 6
Characterization of the sources of thermal spring- and well water in Jordan by rare earth element and yttrium distribution and stable isotopes of H2O 约旦温泉和井水来源的稀土元素、钇分布和水的稳定同位素特征
Pub Date : 2006-04-01 DOI: 10.1002/AHEH.200500614
P. Möller, P. Dulski, E. Salameh, S. Geyer
Four types of thermal groundwater in Jordan were distinguished by Y and rare earth elements (REY) distribution patterns. Complementary to the stratigraphic origin of water in springs or of wells, REY patterns identify either recharge areas covered by basalt, limestones or sandstone, or interaction with basalt-limestone contact zones. This hydrochemical grouping does not always correspond with "common geological knowledge" of the aquifer lithology of the thermal water. Therefore, comparison of the hydrochemical signatures of REY patterns and the lithological source of water yield insight into transaquifer flow. Out of 44 analysed groundwater, 18 indicated down- and 3 upflow of water the latter due to step faults near the Rift system. During transaquifer flow REY patterns of groundwater from basalts and gypsum beds or gypsum-cemented sandstones are not changed by subsequent interaction with limestones, whereas in groundwater originating from dissolution of chalk and limestones REY patterns are adjusted to those typical for gypsum-bearing sediments. Cross plots of δ 18 O vs. δ 2 H reveal essentially two trends. The main trend of water from limestone aquifers define a mixing line of past to recent meteoric water with negligible contributions of Pleistocene water. Some water from Eocene aquifers plot on the local Mediterranean meteoric water line, others plot together with water from sandstone aquifers at enhanced δ 18 O values due to hydrothermal overprinting.
通过Y和稀土元素(REY)的分布模式,对约旦四种热地下水进行了区分。作为泉水或井中水的地层来源的补充,REY模式确定了玄武岩、石灰石或砂岩覆盖的补给区,或与玄武岩-石灰石接触带的相互作用。这种水化学分组并不总是与热水含水层岩性的“普通地质知识”相一致。因此,通过对REY型水化学特征与产水岩性来源的比较,深入了解含水层流动。在44个被分析的地下水中,18个表明水是向下流动的,3个表明水是向上流动的,后者是由于裂谷系统附近的阶梯断层。在含水层流动过程中,玄武岩、石膏层或石膏胶结砂岩的地下水的REY模式不会因随后与石灰石的相互作用而改变,而来自白垩和石灰石溶解的地下水的REY模式则调整为典型的含石膏沉积物的REY模式。δ 18o与δ 2h的交叉图揭示了两种基本趋势。来自石灰岩含水层的水的主要趋势确定了过去到最近的大气水的混合线,而更新世水的贡献可以忽略不计。始新世含水层的一些水在当地的地中海大气水线上,另一些水与砂岩含水层的水一起由于热液叠印而增加了δ 18o值。
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引用次数: 28
Matrix effects on the photocatalytical degradation of dichloroacetic acid and atrazine in water 基质对水中二氯乙酸和阿特拉津光催化降解的影响
Pub Date : 2006-04-01 DOI: 10.1002/AHEH.200500618
Markus Ziegmann, Tusnelda E. Doll, F. Frimmel
The effect of different organic and inorganic aqueous matrices on the photocatalytical degradation of dissolved atrazine and dichloroacetic acid (DCA) with immobilized TiO 2 was investigated. Two series of experiments were carried out at pH values around 7.1 for the degradation of atrazine and around 5.3 for the degradation of DCA. It is shown that the effects of the water constituents are completely different for the various substances and pH ranges. In pure deionized water 95% of the initial amount p = 1 mg/L of atrazine were degraded within 24 hours. Tap water as matrix led to a distinct lower degradation rate (factor 3). The single additives chloride, sulfate, phosphate, carbonate and DOC showed no decrease in the degradation rate. Especially in the case of phosphate and carbonate there was even a significant promoting effect. DEDIA, the doubly desalkylated and not dechlorinated product, occurred in higher concentrations than in the experiment without additives. In pure deionized water ρ 0 (DCA) = 1 mg/L was completely degraded within 330 min. By addition of any tested substance, organic or inorganic, the degradation rate of DCA, which is strongly dependent on the adsorption on the TiO 2 surface, decreased clearly. In the case of tap water the degradation rate decreased by a factor of 7.5. From the checked inorganic ions phosphate showed the strongest effect followed by sulfate, chloride and carbonate. Added DOC also had a significant influence on the degradation rate.
研究了不同有机和无机基质对固定化二氧化钛光催化降解溶解的阿特拉津和二氯乙酸(DCA)的影响。在pH值为7.1左右的条件下进行了阿特拉津降解实验,在pH值为5.3左右的条件下进行了DCA降解实验。结果表明,不同的物质和pH值范围对水组分的影响是完全不同的。在纯去离子水中,初始量p = 1 mg/L的阿特拉津在24小时内降解95%。自来水作为基质导致降解率明显降低(因子3),单一添加剂氯化物、硫酸盐、磷酸盐、碳酸盐和DOC对降解率没有影响。特别是在磷酸盐和碳酸盐的情况下,甚至有显著的促进作用。双脱盐未脱氯产物DEDIA的浓度高于未添加添加剂的实验。在纯去离子水中,ρ 0 (DCA) = 1 mg/L,在330 min内被完全降解。添加任何测试物质(有机或无机物),DCA的降解率明显降低,而DCA的降解率强烈依赖于tio2表面的吸附。在自来水的情况下,降解率降低了7.5倍。从检查的无机离子来看,磷酸盐的作用最强,其次是硫酸盐、氯化物和碳酸盐。添加DOC对降解速率也有显著影响。
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引用次数: 21
Nutrient accumulation and nutrient retention in coastal waters – 30 years investigation in the Darss‐Zingst Bodden chain 沿海水域的营养积累和营养保留——Darss - Zingst Bodden链30年的调查
Pub Date : 2006-04-01 DOI: 10.1002/AHEH.200500616
U. Selig, H. Baudler, Mathias Krech, Günther Nausch
Coastal waters are transitional zones between limnic waters and marine systems. The anthropogenic impact on these water bodies is high and a rapid change of trophic level was observed within the last 50 years. In the Darss-Zingst Bodden chain (southern Baltic Sea - Mecklenburg-West Pomerania, Germany), the change in trophic state during the last thirty years can be reconstructed by long-term monitoring of chemical, hydrographical and biological parameters with an up to daily resolution. Until the 1980s, increased input of the anthropogenic nutrient load from the catchment area has been documented. However, with the implementation of the HELCOM recommendations the input of phosphorus and nitrogen was reduced in the 1990s. In contrast to the reduction of nutrient inputs, a decrease in nutrient concentrations and primary production could not be observed. The reasons are a high internal nutrient load and the release of nutrients out of the sediments. Numerous research projects allowed the description and quantification of these processes. Today, the internal phosphorus pool exceeds the external phosphorus load several fold. These results are the scientific basis for the development of restoration strategies of coastal waters. The development of suitable management plans is necessary for the implementation of the EU Water Framework Directive to guarantee a good ecological state by 2015. The long time acquisition of monitoring data and voluminous complementary specific research projects was enabled by the local field research conditions of the Biological Station of the University of Rostock in Zingst.
沿海水域是咸水和海洋系统之间的过渡地带。近50年来,这些水体受到的人为影响较大,营养水平发生了快速变化。在达斯-津斯特-博登海链(波罗的海南部-梅克伦堡-西波美拉尼亚,德国),通过对化学、水文和生物参数的长期监测,可以以每日分辨率重建近30年来营养状态的变化。直到20世纪80年代,已有资料表明汇水区的人为营养物负荷增加。然而,随着HELCOM建议的实施,磷和氮的投入在1990年代减少了。与养分投入的减少相反,没有观察到养分浓度和初级产量的减少。其原因是内部养分负荷高,养分从沉积物中释放出来。许多研究项目允许对这些过程进行描述和量化。今天,内部磷池超过外部磷负荷数倍。这些结果为制定沿海水域恢复策略提供了科学依据。制定合适的管理计划是实施欧盟水框架指令的必要条件,以确保到2015年达到良好的生态状态。罗斯托克大学生物站在津斯特的当地实地研究条件使监测数据的长期获取和大量互补的具体研究项目成为可能。
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引用次数: 17
Geochronology of anthropogenic contaminants in a dated sediment core of the Rhine River (Germany): emission sources and risk assessment 德国莱茵河沉积物岩心中人为污染物的年代学:排放源和风险评估
Pub Date : 2006-04-01 DOI: 10.1002/AHEH.200500609
S. Heim, A. Hucke, J. Schwarzbauer, R. Littke, A. Mangini
A subaquatic sediment core was taken from the Rhine River to determine substance specific concentration profiles in correlation to time and depth. Based on these data emission histories were related for selected contaminants. Significant emission sources and emission pathways were compiled. In correlation to investigations of national and international monitoring programmes a significant reduction of environmental emissions up to a tenth of previous values were found since 1998. Some selected compounds, discharged by municipal and industrial activities, for example disinfectants (methyltriclosan), flame retardants (tris(chloropropyl)phosphate), chlorinated benzenes, anilines and naphthalenes, can be classified as significant synthetic substances in the scope of the Water Framework Directive. Because of their chemical characters, their persistence, bioaccumulation and ecotoxicity, as well as their occurrence within the sediment core, these compounds create a significant potential risk for water quality, but a reduction of these synthetic compounds to zero cannot be expected for the next future. In summary, this study provides a comprehensive reconstruction of the pollution history of anthropogenic contaminants, their fate and behaviour in the fluvial system. In addition, an estimation of the time period required for environmental measurements and monitoring programmes to improve, achieve and save a good status of the river systems are given.
取自莱茵河的海底沉积物岩心确定了物质特定浓度与时间和深度的关系。根据这些数据,选定污染物的排放历史是相关的。编制了重要的排放源和排放途径。根据对国家和国际监测方案的调查,发现自1998年以来环境排放量大大减少,减少幅度达以前的十分之一。市政和工业活动排放的某些选定化合物,例如消毒剂(甲基三氯生)、阻燃剂(三(氯丙基)磷酸)、氯化苯、苯胺和萘,可归类为《水框架指令》范围内的重要合成物质。由于它们的化学特性、持久性、生物蓄积性和生态毒性,以及它们在沉积物核心中的存在,这些化合物对水质造成了重大的潜在风险,但不能指望在未来将这些合成化合物减少到零。总之,这项研究提供了一个全面的重建污染历史的人为污染物,他们的命运和行为在河流系统。此外,还估计了环境测量和监测方案所需的时间,以改善、实现和保存河流系统的良好状态。
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引用次数: 14
METEOR: a step-by-step procedure to explore effects of indicator aggregation in multi criteria decision aiding – application to water management in Berlin, Germany METEOR:一步一步探索指标聚合在多标准决策辅助中的效果——在德国柏林的水管理应用
Pub Date : 2006-04-01 DOI: 10.1002/AHEH.200500619
U. Simon, R. Brüggemann, H. Behrendt, E. Shulenberger, S. Pudenz
METEOR (METhod of Evaluation by ORder) is introduced as a new evaluation approach, based on partial order theory. METEOR combines transparent decision support and convenient tools for data analysis with the ability to include stakeholders' preferences in the decision process. The basic idea is a systematic step-by-step aggregation of indicators, including their weighting. We applied METEOR to evaluate the eco-hydrological effects of nine water management strategies upon the complex surface water system of Berlin and Potsdam, Germany. Altogether 14 river sections are defined, each of which is evaluated by a set of four hydro-chemical indicators. Aggregation of indicators was performed on two levels: spatially with respect to the river sections, and thematically to the four indicators themselves. The METEOR result is in good agreement with that obtained by the PROMETHEE approach. However, advantages of METEOR are (1) identification of sensitive steps of indicator aggregation, and (2) extraction of explanatory background information about advantages and disadvantages of scenarios. Both topics enhance the transparency of the evaluation process and thus support public acceptance of the decision.
METEOR (METhod of Evaluation by ORder)是一种基于偏序理论的新型评价方法。METEOR结合了透明的决策支持和方便的数据分析工具,并能够将利益相关者的偏好纳入决策过程。其基本思想是系统地逐步汇总指标,包括它们的权重。本文应用METEOR对德国柏林和波茨坦复杂的地表水系统进行了9种水管理策略的生态水文效应评价。总共确定了14个河段,每个河段都用一套四种水化学指标进行评价。指标的汇总在两个层面上进行:空间上与河段有关,主题上与四个指标本身有关。METEOR的结果与PROMETHEE方法的结果一致。然而,METEOR的优势在于(1)识别指标聚集的敏感步骤,(2)提取场景优缺点的解释背景信息。这两个主题都提高了评估过程的透明度,从而支持公众接受决策。
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引用次数: 23
Identification of nitrate sources in groundwater by δ15Nnitrateand δ18Onitrate isotopes: a study of the shallow Pleistocene aquifer in the Jericho area, Palestine 用δ 15nit硝酸盐和δ 18nit硝酸盐同位素鉴定地下水中硝酸盐的来源:巴勒斯坦杰里科地区更新世浅层含水层的研究
Pub Date : 2006-04-01 DOI: 10.1002/AHEH.200400615
S. Khayat, S. Geyer, H. Hötzl, M. Ghanem, W. Ali
This study describes the impact of septic tanks on the groundwater quality of the shallow Pleistocene aquifer in Jericho area, Westbank, Palestine. Septic tanks are widely used for storage and disposal of sewage in the populated and agricultural city of Jericho. Routine hydrochemical tests for groundwater quality performed for several years identified the problem of a gradual nitrate increase, without pinpointing its definite sources. The geological formations of the Jericho area and the shallow nature of the Pleistocene aquifer, together with the mechanism of recharge, make the groundwater in this aquifer highly susceptible to contamination, particularly along sewers. The lithology of the Samara (high hydraulic conductivity) and the Lisan formation (low conductivity but increased infiltration along fractures) promote easy seepage of agricultural and anthropogenic inputs into the groundwater. Nitrate concentrations are elevated near septic tanks and animal farms, with nitrate values exceeding 74 mg/L. δ 15 N nitrate and δ 18 O nitrate signatures suggest sewage and manure as the main sources of high nitrate concentration in the groundwater. Samples taken during the end of the dry season indicate that a slight denitrification in the aquifer.
本研究描述化粪池对巴勒斯坦西岸杰里科地区更新世浅层含水层地下水水质的影响。在人口稠密的农业城市杰里科,化粪池被广泛用于储存和处理污水。多年来对地下水质量进行的常规水化学测试发现了硝酸盐逐渐增加的问题,但没有确定其确切来源。杰里科地区的地质构造和更新世含水层的浅层性质,加上补给机制,使这一含水层中的地下水极易受到污染,特别是沿下水道的地下水。Samara地层(高导电性)和Lisan地层(低导电性,但沿裂缝增加渗透)的岩性促进了农业和人为输入物容易渗透到地下水中。化粪池和动物养殖场附近的硝酸盐浓度升高,硝酸盐值超过74毫克/升。δ 15 N硝态氮和δ 18 O硝态氮特征表明,污水和粪便是地下水中高硝酸盐的主要来源。在旱季结束时采集的样本表明,含水层有轻微的反硝化作用。
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引用次数: 15
Benthic cyanobacterial assemblages as indicators of nutrient enrichment regimes in a Spanish river 底栖蓝藻组合作为营养富集制度的指标在西班牙河流
Pub Date : 2006-04-01 DOI: 10.1002/AHEH.200500611
E. Perona, P. Mateo
The relationships between cyanobacterial abundance and the physical and chemical characteristics of waters were studied to identify the environmental variables responsible for the changes in species composition observed in a river characterized by variations in water quality. Principal component analysis showed that some communities had significantly different species composition and relationships with environmental variables than others. These analyses allowed us to identify indicator species with contrasting responses to nutrient conditions. One of the four cyanobacterial groups distinguished in the analysis was negatively correlated with variables related to aspects of water disturbance, including nutrients. The results indicate that the eutrophication gradient structured species composition and affected cyanobacterial community distribution. Since organisms have an integrating response to their environment, the use of cyanobacterial assemblages to indicate eutrophication gradients could help in the assessment of water quality in aquatic ecosystems.
研究了蓝藻丰度与水体物理和化学特征之间的关系,以确定在水质变化的河流中观察到的物种组成变化的环境变量。主成分分析表明,部分群落的物种组成和与环境变量的关系存在显著差异。这些分析使我们能够识别对营养条件有不同反应的指示物种。在分析中区分出的四种蓝藻群中,有一种与水扰动相关的变量呈负相关,包括营养物质。结果表明,富营养化梯度结构了物种组成,影响了蓝藻群落分布。由于生物对其环境具有综合响应,因此使用蓝藻组合来指示富营养化梯度可以帮助评估水生生态系统的水质。
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引用次数: 21
Conidial fungi on plants in the Biebrzański National Park Biebrzański国家公园植物上的分生孢子真菌
Pub Date : 2006-04-01 DOI: 10.1002/AHEH.200500608
M. Orłowska, I. Lengiewicz, H. Ostrowska
The presence of Hyphomycetes developing on Eriophorum vaginatum L. and Sphagnum apiculatum H. Lindb was monitored. Samples were collected from water bodies accumulating over excavated peat in the Biebrzan?ski National Park in autumn and winter of 2002, and in spring and summer of 2003. 67 species of Fungi imperfecti were identified. We found 54 taxa of Hyphomycetes on Sphagnum apiculatum and 41 taxa on Eriophorum. 24 species were present on both species. The highest number of species was found in spring and the fewest in summer.
监测了阴道草和尖棘草上菌丝菌的生长情况。样品采集自比布尔赞?滑雪国家公园在2002年的秋冬和2003年的春夏。共鉴定出67种真菌。在尖藻上发现菌丝菌54个类群,在桔梗上发现菌丝菌41个类群,在两种植物上均发现菌丝菌24种。其中春季种类最多,夏季最少。
{"title":"Conidial fungi on plants in the Biebrzański National Park","authors":"M. Orłowska, I. Lengiewicz, H. Ostrowska","doi":"10.1002/AHEH.200500608","DOIUrl":"https://doi.org/10.1002/AHEH.200500608","url":null,"abstract":"The presence of Hyphomycetes developing on Eriophorum vaginatum L. and Sphagnum apiculatum H. Lindb was monitored. Samples were collected from water bodies accumulating over excavated peat in the Biebrzan?ski National Park in autumn and winter of 2002, and in spring and summer of 2003. 67 species of Fungi imperfecti were identified. We found 54 taxa of Hyphomycetes on Sphagnum apiculatum and 41 taxa on Eriophorum. 24 species were present on both species. The highest number of species was found in spring and the fewest in summer.","PeriodicalId":7010,"journal":{"name":"Acta Hydrochimica Et Hydrobiologica","volume":"42 1","pages":"53-57"},"PeriodicalIF":0.0,"publicationDate":"2006-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80201152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
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Acta Hydrochimica Et Hydrobiologica
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