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(Al_2O_3) tunnel layer to mitigate selectivity loss in (MoO_x)-based silicon solar cells: insights from numerical simulations (Al_2O_3) 隧道层减轻(MoO_x)基硅太阳能电池的选择性损失:来自数值模拟的见解
IF 4 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-11-11 DOI: 10.1007/s11082-025-08539-9
Anil,  Paras, Abhishek Kumar, Meenakshi Devi,  Meenakshi,  Rinki,  Shivanshu, Sanjay Kumar Srivastava, Prathap Pathi

Molybdenum oxide ((MoO_x)), a wide band-gap material with low optical absorption, has emerged as a promising candidate for the hole-selective front contacts for silicon solar cells. However, the carrier selectivity is limited by the absence of a sufficiently high electron barrier. In this study, numerical simulations demonstrate that incorporating an ultra-thin aluminum oxide tunnel layer ((le) 2 nm) enhances the hole selectivity in (MoO_x)-based front contacts. Introducing the tunnel layer at the (MoO_x)/c-Si (n) interface resulted in a relative increase of 5.36 % over the control cell efficiency of 17.77 %. A systematic variation of the energy-band alignment of the tunnel layer revealed that the observed performance enhancement is primarily due to the additional conduction band energy barrier formed by the tunnel layer. A strong influence of the tunnel layer thickness, interface defect density, and pinholes through the tunnel layer on the open-circuit voltage was observed. Subsequently, the tunnel layer was also found to reduce the temperature sensitivity of the solar cell performance. The tunnel layer reduced the magnitudeof the simulated (P_{max}) temperature coefficient of the structure from −0.39 %/°C to −0.15 %/°C, signifying its role in developing high-efficiency silicon solar cells.

氧化钼((MoO_x))是一种具有低光吸收的宽带隙材料,已成为硅太阳能电池孔选择前触点的有希望的候选材料。然而,载流子选择性受到缺乏足够高的电子势垒的限制。在本研究中,数值模拟表明,加入超薄氧化铝隧道层((le) 2 nm)可以提高(MoO_x)基前触点的空穴选择性。在(MoO_x) /c-Si (n)界面处引入隧道层,相对增大5.36 % over the control cell efficiency of 17.77 %. A systematic variation of the energy-band alignment of the tunnel layer revealed that the observed performance enhancement is primarily due to the additional conduction band energy barrier formed by the tunnel layer. A strong influence of the tunnel layer thickness, interface defect density, and pinholes through the tunnel layer on the open-circuit voltage was observed. Subsequently, the tunnel layer was also found to reduce the temperature sensitivity of the solar cell performance. The tunnel layer reduced the magnitudeof the simulated (P_{max}) temperature coefficient of the structure from −0.39 %/°C to −0.15 %/°C, signifying its role in developing high-efficiency silicon solar cells.
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引用次数: 0
Hybrid pump cascade structure on rapid propagation of light 光快速传播的混合泵级联结构
IF 4 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-11-11 DOI: 10.1007/s11082-025-08546-w
Yiwen Ma, Wei Qiu, Pin Lv, Feifei Yin, Tianya Tan

In this paper, a theory for rapid light generation based on a cascaded structure of coherent population oscillations (CPO) at room temperature is proposed. Through theoretical calculations, we first compare the effects of the hybrid pump (1480 nm and 980 nm) cascade structure with the dual-pump (1480 nm and 980 nm) single fiber structure on the fast light. Then the phenomenon of fast light saturation in the cascade structure is studied in detail. Finally, the effect of pump ratio M on time advancement is demonstrated. This may facilitate the optimization of optical communication systems.

本文提出了一种在室温下基于相干居群振荡(CPO)级联结构的快速光产生理论。通过理论计算,我们首先比较了混合泵浦(1480 nm和980 nm)级联结构与双泵浦(1480 nm和980 nm)单光纤结构对快光的影响。然后详细研究了叶栅结构中的快速光饱和现象。最后,论证了泵浦比M对时间推进的影响。这可能有助于光通信系统的优化。
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引用次数: 0
Green production of n-type Zn1−xInxO 2D nanoflakes and the photo-electrical characteristics of p-Si/n-Zn1−xInxO heterojunction diodes n型Zn1−xInxO二维纳米片的绿色制备及p-Si/n-Zn1−xInxO异质结二极管的光电特性
IF 4 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-11-10 DOI: 10.1007/s11082-025-08550-0
P. Arul, K. Arulvendhan, R. Satheesh, S. Banumathi

p-Si/n-ZnO heterojunction diodes have garnered significant attention for energy conversion applications due to their superior optoelectronic properties. In this study, we synthesized n-Zn(1-x)InxO two-dimensional (2D) nanoflakes using a phytochemical-assisted synthesis technique, enabling precise control over nanoflake size via In3+ dopant concentration. This eco-friendly approach offers a sustainable and scalable method for fabricating high-performance nanostructures. Structural analysis confirmed the hexagonal wurtzite crystal structure of Zn(1−x)InxO, while transmission electron microscopy revealed 2D flake-like morphologies ranging from 100 nm to 250 nm. Optical characterization demonstrated bandgap tunability, with pristine ZnO exhibiting a bandgap of 3.38 eV and In3+-doped ZnO (1%, 3%, and 5%) showing bandgaps of 3.42 eV, 3.46 eV, and 3.48 eV, respectively, due to the Burstein-Moss effect. The p-Si/n-Zn(1−x)InxO heterojunction diodes exhibited enhanced rectification, electrical conductivity, and optoelectronic performance. Under forward bias, the dark current and photocurrent values of the p-Si/ZnO and p-Si/Zn0.95In0.05O diodes were 6.4 × 10⁻⁴ A & 8.8 × 10⁻⁴ A and 4.3 × 10⁻³ A & 6.3 × 10⁻³ A, respectively, indicating a significant enhancement due to In3+ doping. These findings demonstrate a novel pathway for engineering high-performance heterojunction diodes through sustainable synthesis and precise dopant engineering, paving the way for next-generation optoelectronic and energy conversion devices.

p-Si/n-ZnO异质结二极管由于其优越的光电性能而在能量转换应用中引起了极大的关注。在这项研究中,我们利用植物化学辅助合成技术合成了n-Zn(1-x)InxO二维(2D)纳米片,可以通过In3+掺杂剂的浓度精确控制纳米片的尺寸。这种环保的方法为制造高性能纳米结构提供了一种可持续的、可扩展的方法。结构分析证实了Zn(1−x)InxO的六方纤锌矿晶体结构,透射电镜显示在100 ~ 250 nm范围内的二维片状形貌。光学表征显示了带隙可调性,由于Burstein-Moss效应,原始ZnO的带隙为3.38 eV,而In3+掺杂ZnO(1%, 3%和5%)的带隙分别为3.42 eV, 3.46 eV和3.48 eV。p-Si/n-Zn(1−x)InxO异质结二极管表现出增强的整流、导电性和光电性能。在正向偏置下,p-Si/ZnO和p-Si/ zn0.95 in0.050二极管的暗电流和光电流值分别为6.4 × 10⁻⁴和4.3 × 10⁻⁴,表明In3+的掺杂有显著的增强作用。这些发现展示了通过可持续合成和精确掺杂工程来设计高性能异质结二极管的新途径,为下一代光电和能量转换器件铺平了道路。
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引用次数: 0
Multi-mode and bidirectional plasmonic metamaterial absorber based on bilayer graphene and bowtie-shaped windows 基于双层石墨烯和领结型窗的多模双向等离子体超材料吸收体
IF 4 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-11-10 DOI: 10.1007/s11082-025-08544-y
Yuan-Fong Chou Chau, Sy-Hann Chen, Hung Ji Huang, Roshan Thotagamuge, Muhammad Raziq Rahimi Kooh

We propose a dual-directional plasmonic metamaterial absorber (MMA) with a simple multilayered architecture that simultaneously achieves ultra-narrowband and ultra-broadband absorption. The structure comprises a SiO2/Ag/SiO2/Ti/SiO2 stack with integrated monolayer graphene sheets, featuring a dual bowtie aperture pattern for strong field confinement. Under top illumination, it exhibits nine near-perfect narrowband peaks (avg. ~98% absorptance, 400–1200 nm), while bottom illumination induces broadband absorption (> 90%). The resonant wavelengths are dynamically tunable via electrostatic gating, enabling active control. Full-wave simulations reveal Fabry-Pérot-like cavity resonances enhanced by plasmonic hotspots, yielding exceptional sensing performance (sensitivity: 1306 nm/RIU, FOM: 261.21/RIU, Q-factor: 215.4). Fabrication-compatible with CVD graphene and FIB patterning, our design outperforms existing MMAs in efficiency, bidirectional functionality, and ease of fabrication. This platform uniquely enables switching between hyperspectral sensing and solar thermal harvesting in a single device, with applications in refractive index sensing, optical switching, and energy harvesting.

我们提出了一种双向等离子体超材料吸收器(MMA),具有简单的多层结构,同时实现超窄带和超宽带吸收。该结构由SiO2/Ag/SiO2/Ti/SiO2堆叠和集成单层石墨烯片组成,具有双领结孔径模式,用于强场约束。在顶部照明下,它呈现出9个近乎完美的窄带峰(平均吸收率为~98%,400-1200 nm),而底部照明诱导出宽带吸收(> 90%)。谐振波长可通过静电门控动态调节,实现主动控制。全波模拟显示,等离子体热点增强了法布里-帕姆罗样腔共振,产生了优异的传感性能(灵敏度:1306 nm/RIU, FOM: 261.21/RIU, q因子:215.4)。我们的设计在效率、双向功能和易于制造方面优于现有的mma,与CVD石墨烯和FIB图案制造兼容。该平台独特地实现了在单个设备中在高光谱传感和太阳能热收集之间的切换,应用于折射率传感、光开关和能量收集。
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引用次数: 0
Sensitive plasmonic biosensor for CEA detection using asymmetric crescent nanostructures 采用不对称新月形纳米结构检测CEA的灵敏等离子体生物传感器
IF 4 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-11-10 DOI: 10.1007/s11082-025-08540-2
Hamid Bahador, Keysan Abolhasanian, Zahra Abdoli, Azadeh Nilghaz

Early detection and screening of colorectal cancer are challenging due to the low sensitivity of conventional diagnostic methods in detecting trace levels of carcinoembryonic antigen (CEA), as the main clinically validated biomarker for colorectal cancer. In this study, we developed an advanced plasmonic biosensor that utilizes a regularly patterned arrangement of asymmetric crescent-shaped gold nanoparticles constructed on a quartz foundation. Its sensing mechanism is based on the localized surface plasmon resonance (LSPR), allowing for direct, marker-free detection of CEA in real-time measurements. Using detailed Finite-Difference Time-Domain (FDTD) computational analysis, we established strong localized electromagnetic field enhancement around the crescent nanostructures, producing a clear extinction peak near 900 nm. Parameter optimization studies revealed that maximum sensitivity and figure of merit (FoM) are obtained with a crescent configuration angle of roughly 100° and particle separation of 40 nm. The biosensor shows predictable linear wavelength shifts when exposed to refractive index variations in the detection medium, confirming its ability to identify minute CEA concentrations. These results demonstrate the considerable potential of this plasmonic technology as a high-performance, marker-free sensing solution for early cancer detection. This optimized nanostructure design, combined with advanced plasmonic properties, provides a powerful tool that overcomes existing limitations in current cancer screening approaches, potentially enabling more precise and earlier identification of colorectal cancers through enhanced biomarker detection capabilities.

由于传统诊断方法在检测微量癌胚抗原(CEA)方面的敏感性较低,因此早期发现和筛查结直肠癌具有挑战性,癌胚抗原是临床验证的结直肠癌主要生物标志物。在这项研究中,我们开发了一种先进的等离子体生物传感器,它利用在石英基础上构造的不对称月牙形金纳米颗粒的规则图案排列。它的传感机制是基于局部表面等离子体共振(LSPR),允许在实时测量中直接,无标记检测CEA。通过详细的时域有限差分(FDTD)计算分析,我们在新月形纳米结构周围建立了强大的局域电磁场增强,在900 nm附近产生了一个清晰的消光峰。参数优化研究表明,当新月形角约为100°,颗粒分离为40 nm时,获得了最大灵敏度和最佳值。当暴露于检测介质的折射率变化时,生物传感器显示出可预测的线性波长变化,证实了其识别微小CEA浓度的能力。这些结果证明了等离子体技术作为一种高性能、无标记的早期癌症检测传感解决方案的巨大潜力。这种优化的纳米结构设计,结合先进的等离子体特性,提供了一种强大的工具,克服了当前癌症筛查方法的现有局限性,有可能通过增强的生物标志物检测能力,更精确、更早地识别结直肠癌。
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引用次数: 0
A computational investigation of ZnOS buffer layer integration for improved performance of perovskite solar cell ZnOS缓冲层集成提高钙钛矿太阳能电池性能的计算研究
IF 4 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-11-10 DOI: 10.1007/s11082-025-08559-5
Aqsa Islam, Syed Zulqarnain Haider, Mingqing Wang, Hafeez Anwar

In this work, the SCAPS-1D modeling program was used to study the impact of an inorganic buffer layer (BL) of ZnOS on the performance of perovskite solar cells (PSCs). The proposed solar cell structure consisted of a glass/TCO/TiO2/ZnOS/CsPbI3/CuSbS2/Au configuration. Incorporating ZnOS-BL between the electron transport layer (ETL) and absorber layer (AL) improved the charge transportation, enhancing the overall performance. The effects of material characteristics, such as the thickness of AL as well as the electron affinity of ETL, BL, and hole transport layer (HTL), were studied. Moreover, the doping densities of ETL, BL and HTL were also examined and optimized to achieve the highest device performance. Consequently, the device performance parameters improved significantly, such as the device incorporating BL achieved JSC of 22.98 mA/cm2, VOC of 1.13 V, FF of 86.25% and power conversion efficiency (PCE) of 22.04% compared to the reference device without BL with JSC of 18.46 mA/cm2, VOC of 0.79 V, FF of 78.81%, and PCE of 11.14%. The proposed modeling process opens a new path for researchers to develop this BL-based PSC experimentally.

本文采用SCAPS-1D建模程序研究了zno无机缓冲层(BL)对钙钛矿太阳能电池(PSCs)性能的影响。所提出的太阳能电池结构由玻璃/TCO/TiO2/ZnOS/CsPbI3/CuSbS2/Au结构组成。在电子传输层(ETL)和吸收层(AL)之间加入zno - bl改善了电荷传输,提高了整体性能。研究了AL的厚度以及ETL、BL和空穴传输层(HTL)的电子亲和力等材料特性的影响。此外,还对ETL、BL和HTL的掺杂密度进行了测试和优化,以达到最高的器件性能。结果表明,与未加BL的JSC为18.46 mA/cm2、VOC为0.79 V、FF为78.81%、PCE为11.14%的参考器件相比,加入BL的器件JSC为22.98 mA/cm2, VOC为1.13 V, FF为86.25%,PCE为22.04%。所提出的建模过程为研究人员在实验上开发这种基于bl的PSC开辟了新的途径。
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引用次数: 0
Computational investigation of silver nanoparticle-enhanced organic solar cells: optical and electronic insights 银纳米粒子增强有机太阳能电池的计算研究:光学和电子见解
IF 4 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-11-10 DOI: 10.1007/s11082-025-08558-6
Khalid Bouguenina, Abdelhalim Zoukel, Abdelkader Nebatti Ech-Chergui, Kada Benhanifia, Bahri Deghfel, Loumafak Hafaifa, Noureddine Benaya, Fatima Bouasria, Mehdi Adjdir

This study presents a semi-analytical and numerical approach to enhancing the performance of organic solar cells (OSCs) based on the PM6:Y6 system. To model the optical properties of the plasmonic active layer, we utilized the Maxwell-Garnett Effective Medium Theory to determine the complex refractive index of a composite containing 10 vol% silver nanoparticles (Ag-NPs). These derived optical constants were then integrated into a Transfer Matrix Method (TMM) to simulate light absorption and optoelectronic performance. Our results demonstrate that Ag-NPs significantly boost light absorption via localized surface plasmon resonance (LSPR) and enhanced scattering, leading to a substantial increase in simulated device efficiency. The plasmonic device achieved a power conversion efficiency (PCE) of 13.92%, a notable improvement over the pristine device’s 10.19%. Furthermore, a detailed analysis of active layer thickness across a range of 100 to 280 nm revealed that optimal performance is architecture-dependent. Inverted OSCs (IOSCs) reached their peak PCE of 14.29% at a thickness of 220 nm, while conventional OSCs (COSCs) performed best at 240 nm with a PCE of 11.49%. This finding highlights the superior charge extraction and collection efficiency of the inverted configuration. Overall, this research establishes that combining a semi-analytical plasmonic model with precise thickness optimization is a powerful and efficient strategy for designing high-efficiency OSCs.

本研究提出了一种半解析和数值方法来提高基于PM6:Y6体系的有机太阳能电池(OSCs)的性能。为了模拟等离子体活性层的光学特性,我们利用麦克斯韦-加内特有效介质理论来确定含有10 vol%银纳米粒子(Ag-NPs)的复合材料的复折射率。然后将这些导出的光学常数集成到传输矩阵法(TMM)中来模拟光吸收和光电子性能。我们的研究结果表明Ag-NPs通过局部表面等离子体共振(LSPR)和增强散射显著提高光吸收,导致模拟器件效率大幅提高。等离子体器件的功率转换效率(PCE)为13.92%,比原始器件的10.19%有了显著提高。此外,对100至280 nm范围内的有源层厚度的详细分析表明,最佳性能与架构有关。反转OSCs (IOSCs)在厚度为220 nm时PCE达到峰值14.29%,而传统OSCs (COSCs)在厚度为240 nm时表现最佳,PCE为11.49%。这一发现突出了倒置结构优越的电荷提取和收集效率。总之,本研究表明,将半解析等离子体模型与精确的厚度优化相结合,是设计高效osc的一种强大而有效的策略。
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引用次数: 0
Modeling and optimization of advanced-performance tin-based dual absorber perovskite solar cell (Rb2SnI6/BaSnS3) using SCAPS-1D 基于SCAPS-1D的高性能锡基双吸收剂钙钛矿太阳能电池(Rb2SnI6/BaSnS3)建模与优化
IF 4 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-11-10 DOI: 10.1007/s11082-025-08535-z
Venkateswarlu .G, C. V. M. Chaturvedi, Umakanta Nanda, J. Bhaskara Rao, E. Sampad, Nalini Bodasingi

Single-junction perovskite solar cells, part of the emerging third-generation photovoltaic technologies, face intrinsic limitations such as poor charge separation, instability, and elevated recombination losses. To overcome these challenges and address the environmental concerns associated with lead-based perovskites, a novel, lead-free next-generation, tin-based dual absorber perovskite solar cell (TDAPSC) featuring the device architecture Au/FTO/(textrm{SnS}_{2})/(textrm{BaSnS}_{3})/(textrm{Rb}_{2}textrm{SnI}_{6})/PEDOT/Ni is proposed here. Through the integration of two complementary tin-based absorbers, (textrm{Rb}_{2}textrm{SnI}_{6}) (a halide perovskite variant) and (textrm{BaSnS}_{3}) (a sulfide perovskite) this architecture eliminates lead-related toxicity while leveraging broad spectral absorption, superior carrier mobility, and high quantum efficiency. Detailed SCAPS-1D simulations to optimize key performance parameters including recombination pathways, absorber thicknesses, defect densities, charge carrier distributions, and energy level alignment across interfaces are conducted. As a result, the optimized TDAPSC achieved an open-circuit voltage ((V_{textrm{oc}})) of 1.20 V, a short-circuit current density ((J_{textrm{sc}})) of 35.83 mA/cm2, and a fill factor (FF) of 89.33%, leading to a remarkable power conversion efficiency (PCE) of 38.44%. This enhanced performance stems from suppressed recombination and efficient charge extraction facilitated by energy-level alignment between (textrm{BaSnS}_{3}) and (textrm{Rb}_{2}textrm{SnI}_{6}). Moreover, the fully inorganic composition ensures excellent chemical and thermal stability, while also offering scalable fabrication potential. Altogether, this TDAPSC design presents a highly promising pathway toward next-generation photovoltaic technologies that prioritize environmental safety, performance, and long-term durability.

作为新兴的第三代光伏技术的一部分,单结钙钛矿太阳能电池面临着诸如电荷分离不良、不稳定和复合损失增加等内在局限性。为了克服这些挑战并解决与铅基钙钛矿相关的环境问题,本文提出了一种新型的无铅下一代锡基双吸收剂钙钛矿太阳能电池(TDAPSC),其器件结构为Au/FTO/ (textrm{SnS}_{2}) / (textrm{BaSnS}_{3}) / (textrm{Rb}_{2}textrm{SnI}_{6}) /PEDOT/Ni。通过集成两种互补的锡基吸收剂(textrm{Rb}_{2}textrm{SnI}_{6})(卤化物钙钛矿变体)和(textrm{BaSnS}_{3})(硫化物钙钛矿),这种结构消除了铅相关的毒性,同时利用广谱吸收、优越的载流子迁移率和高量子效率。详细的SCAPS-1D模拟优化了关键性能参数,包括重组途径、吸收剂厚度、缺陷密度、载流子分布和界面上的能级排列。结果表明,优化后的TDAPSC开路电压((V_{textrm{oc}}))为1.20 V,短路电流密度((J_{textrm{sc}}))为35.83 mA/cm2,填充系数(FF)为89.33%, leading to a remarkable power conversion efficiency (PCE) of 38.44%. This enhanced performance stems from suppressed recombination and efficient charge extraction facilitated by energy-level alignment between (textrm{BaSnS}_{3}) and (textrm{Rb}_{2}textrm{SnI}_{6}). Moreover, the fully inorganic composition ensures excellent chemical and thermal stability, while also offering scalable fabrication potential. Altogether, this TDAPSC design presents a highly promising pathway toward next-generation photovoltaic technologies that prioritize environmental safety, performance, and long-term durability.
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引用次数: 0
High-pressure insights into Na2CsAgBr6 double perovskite: a DFT study on structural, mechanical, and optoelectronic properties Na2CsAgBr6双钙钛矿的高压洞察:结构、机械和光电性质的DFT研究
IF 4 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-11-10 DOI: 10.1007/s11082-025-08557-7
Shabir Ali, Xinhua Wang, Amjad A. Almunyif, Muhammad Ibrar,  Sawaira, Maqbool Ur Rehman

Double perovskites (DPs) have garnered significant interest due to their promising applications in thermoelectric and optoelectronic technologies. In this study, we employ density functional theory (DFT) calculations to explore the structural, thermodynamic, mechanical and optoelectronic properties of the Na2CsAgBr6 DP compound under high-pressure conditions. Structural stability was assessed using the Perdew-Burke-Ernzerhof (PBE-GGA) potential, while optoelectronic properties were evaluated via the modified Becke-Johnson (mBJ) potential. The results reveals that the band gap decreases from 2.78 to1.65 eV as the pressure increases from 0 to 30 GPa, respectively. The electronic density of states analyze indicates covalent bonding with reduced interatomic distances under compression. Mechanical stability was confirmed through the calculation of elastic constants, demonstrating that the compound retains its robustness across varying pressures. Optical analyze highlights absorption in the infrared region, reinforcing its potential for photonic applications. Furthermore, thermal stability was investigated using the Gibbs2 code within the WIEN2K package and VASP code, confirming the material resilience under extreme conditions. These findings provide crucial insights into the tunable nature of Na2CsAgBr6, offering a pathway for optimizing its properties for next-generation electronic and optical devices.

双钙钛矿(DPs)由于其在热电和光电子技术中的应用前景而引起了人们的极大兴趣。在本研究中,我们利用密度泛函理论(DFT)计算探讨了高压条件下Na2CsAgBr6 DP化合物的结构、热力学、力学和光电性能。结构稳定性采用PBE-GGA电位进行评估,光电性能采用改良的Becke-Johnson电位进行评估。结果表明,当压力从0增加到30 GPa时,带隙从2.78 eV减小到1.65 eV;电子态密度分析表明,在压缩作用下,原子间距离减小,形成共价键。力学稳定性通过弹性常数的计算得到证实,表明该化合物在不同压力下保持其鲁棒性。光学分析突出了红外区域的吸收,增强了其在光子应用方面的潜力。此外,使用WIEN2K封装中的Gibbs2代码和VASP代码研究了热稳定性,确认了材料在极端条件下的弹性。这些发现为Na2CsAgBr6的可调谐特性提供了重要的见解,为优化其下一代电子和光学器件的性能提供了途径。
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引用次数: 0
Symmetrically etched plastic optical fiber sensor for the detection of ethylene glycol contamination in water 用于检测水中乙二醇污染的对称刻蚀塑料光纤传感器
IF 4 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2025-11-10 DOI: 10.1007/s11082-025-08556-8
Rana M. Armaghan Ayaz, Adil Mustafa, Riccardo Funari

Human activities are increasingly contaminating surface and groundwater reserves. Among various pollutants, ethylene glycol (EG) contamination in water is particularly dangerous. At low concentrations it can enter the body undetected and causes serious health problems such as kidney failure and gastrointestinal disorders. This study demonstrates the use of symmetrically etched single-mode plastic optical fiber (POF) sensor model operating at 1550 nm for detecting EG presence in water using COMSOL Multiphysics. The working of the sensor is based on evanescent field interactions with surrounding medium to detect refractive index (RI) changes, while transmission variations through etched POF serving as the sensing metric. Simulations were conducted for aqueous EG solutions ranging from 0 to 0.15 weight fraction, corresponding to RI values ranging between 1.316 and 1.330. The sensor design was optimized by examining the impact of etched cladding diameter and etched length on sensitivity. These parameters were varied from 60 to 7.05 and 1 to 30 μm, respectively. This in turn lead to sensitivity values in the range of 0.39 × 10−3 to 99.50 × 10−3 Trans. (A.U)/RIU. Highlighting the importance of evanescent field-surrounding interaction for etched POF sensors, these findings revealed that sensitivity has direct relation with the length of etched region and inverse relation with cladding diameter. The maximum sensitivity of 99.50 × 10−3 Trans. (A.U)/RIU was achieved with a 30 μm etched length and 7.05 μm cladding diameter. The proposed POF-based sensor demonstrates strong potential for applications in biomedical engineering, biochemical monitoring, and beverage industry offering a compact and sensitive solution for EG contamination detection in water.

人类活动对地表水和地下水的污染日益严重。在各种污染物中,水中的乙二醇(EG)污染尤为危险。在低浓度的情况下,它可以在不被发现的情况下进入人体,导致严重的健康问题,如肾衰竭和胃肠道紊乱。本研究演示了使用在1550 nm工作的对称蚀刻单模塑料光纤(POF)传感器模型,使用COMSOL Multiphysics检测水中EG的存在。传感器的工作原理是基于与周围介质的倏逝场相互作用来检测折射率(RI)的变化,而通过蚀刻POF的透射变化作为传感度量。对质量分数为0 ~ 0.15的EG水溶液进行了模拟,对应的RI值为1.316 ~ 1.330。通过考察刻蚀包层直径和刻蚀长度对灵敏度的影响,优化了传感器的设计。这些参数分别为60 ~ 7.05 μm和1 ~ 30 μm。这反过来又导致灵敏度值在0.39 × 10−3到99.50 × 10−3 Trans范围内。(A.U) / RIU。这些发现表明,灵敏度与蚀刻区长度成正比,与包层直径成反比,突出了消失场-周围相互作用对蚀刻POF传感器的重要性。最大灵敏度为99.50 × 10−3 Trans。(A.U)/RIU的刻蚀长度为30 μm,包层直径为7.05 μm。提出的基于pof的传感器在生物医学工程、生化监测和饮料工业中具有强大的应用潜力,为水中EG污染检测提供了紧凑而敏感的解决方案。
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Optical and Quantum Electronics
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