首页 > 最新文献

Advanced Composites and Hybrid Materials最新文献

英文 中文
3D Electrospinning of Al2O3/ZrO2 fibrous aerogels for multipurpose thermal insulation Al2O3/ZrO2纤维气凝胶的三维静电纺丝多用途保温
IF 20.1 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-10-13 DOI: 10.1007/s42114-023-00760-y
Shiling Dong, Barbara Maciejewska, Robert Millar, Nicole Grobert

Ceramic aerogels are excellent ultralight-weight thermal insulators yet impractical due to their tendency towards structural degradation at elevated temperatures, under mechanical disturbances, or in humid environments. Here, we present flexible and durable alumina/zirconia fibrous aerogels (AZFA) fabricated using 3D sol–gel electrospinning — a technique enabling in situ formation of 3D fiber assemblies with significantly reduced time consumption and low processing cost compared to most existing methods. Our AZFAs exhibit ultralow density (> 3.4 mg cm−3), low thermal conductivity (> 21.6 mW m−1 K−1), excellent fire resistance, while remaining mechanically elastic and flexible at 1300 °C, and thermally stable at 1500 °C. We investigate the underlying structure-thermal conductivity relationships, demonstrating that the macroscopic fiber arrangement dictates the solid-phase thermal conduction, and the mesopores in the fiber effectively trap air thereby decreasing the gas conduction. We show experimentally and theoretically that directional heat transport, i.e., anisotropic thermal conductivity, can be achieved through compressing the fiber network. We further solve the moisture sensitivity problem of common fibrous aerogels through fluorination coating. The resulting material possesses excellent hydrophobicity and self-cleaning properties, which can provide reliable thermal insulation under various conditions, including but not limited to high-temperature conditions in vehicles and aircraft, humid conditions in buildings, and underwater environments for oil pipelines.

Graphical Abstract

陶瓷气凝胶是极好的超轻质隔热材料,但由于其在高温、机械干扰或潮湿环境下易于结构退化,因此不切实际。在这里,我们提出了使用3D溶胶-凝胶静电纺丝制造的柔性耐用的氧化铝/氧化锆纤维气凝胶(AZFA),与大多数现有方法相比,这是一种能够原位形成3D纤维组件的技术,显著减少了时间消耗,降低了加工成本。我们的AZFA表现出超低密度(>; 3.4 mg cm−3)、低热导率(>; 21.6 mW m−1 K−1),优异的耐火性,同时在1300°C时保持机械弹性和柔性,在1500°C时热稳定。我们研究了潜在的结构-热导率关系,表明宏观纤维排列决定了固相热传导,纤维中的中孔有效地捕获了空气,从而降低了气体传导。我们从实验和理论上表明,通过压缩纤维网络可以实现定向热传输,即各向异性导热率。我们通过氟化涂层进一步解决了常见纤维气凝胶的水分敏感性问题。所得材料具有优异的疏水性和自清洁性能,可在各种条件下提供可靠的隔热性能,包括但不限于车辆和飞机的高温条件、建筑物的潮湿条件以及输油管道的水下环境。图形摘要
{"title":"3D Electrospinning of Al2O3/ZrO2 fibrous aerogels for multipurpose thermal insulation","authors":"Shiling Dong,&nbsp;Barbara Maciejewska,&nbsp;Robert Millar,&nbsp;Nicole Grobert","doi":"10.1007/s42114-023-00760-y","DOIUrl":"10.1007/s42114-023-00760-y","url":null,"abstract":"<div><p>Ceramic aerogels are excellent ultralight-weight thermal insulators yet impractical due to their tendency towards structural degradation at elevated temperatures, under mechanical disturbances, or in humid environments. Here, we present flexible and durable alumina/zirconia fibrous aerogels (AZFA) fabricated using 3D sol–gel electrospinning — a technique enabling in situ formation of 3D fiber assemblies with significantly reduced time consumption and low processing cost compared to most existing methods. Our AZFAs exhibit ultralow density (&gt; 3.4 mg cm<sup>−3</sup>), low thermal conductivity (&gt; 21.6 mW m<sup>−1</sup> K<sup>−1</sup>), excellent fire resistance, while remaining mechanically elastic and flexible at 1300 °C, and thermally stable at 1500 °C. We investigate the underlying structure-thermal conductivity relationships, demonstrating that the macroscopic fiber arrangement dictates the solid-phase thermal conduction, and the mesopores in the fiber effectively trap air thereby decreasing the gas conduction. We show experimentally and theoretically that directional heat transport, <i>i.e.</i>, anisotropic thermal conductivity, can be achieved through compressing the fiber network. We further solve the moisture sensitivity problem of common fibrous aerogels through fluorination coating. The resulting material possesses excellent hydrophobicity and self-cleaning properties, which can provide reliable thermal insulation under various conditions, including but not limited to high-temperature conditions in vehicles and aircraft, humid conditions in buildings, and underwater environments for oil pipelines.</p><h3>Graphical Abstract</h3>\u0000 <div><figure><div><div><picture><source><img></source></picture></div></div></figure></div>\u0000 </div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"6 5","pages":""},"PeriodicalIF":20.1,"publicationDate":"2023-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42114-023-00760-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50024292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Constructing a continuous reduced graphene oxide network in porous plant fiber sponge for highly compressible and sensitive piezoresistive sensors 在多孔植物纤维海绵中构建连续还原氧化石墨烯网络,用于高可压缩和敏感的压阻传感器
IF 20.1 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-10-13 DOI: 10.1007/s42114-023-00754-w
Gang Zhao, Feng Qian, Xinyi Li, Yuhan Tang, Ye Sheng, Handong Li, Jiuping Rao, Man Vir Singh, Hassan Algadi, Min Niu, Weijie Zhang, Zhanhu Guo, Xiangfang Peng, Tingjie Chen

Flexible pressure sensors as wearable electronic devices to monitor human health have attracted significant attention. Herein, a simple and effective carbonization-free method is proposed to prepare a compressible and conductive reduced graphene oxide (rGO)–modified plant fiber sponge (defined as rGO-PFS). The introduced GO can not only coat on the surface of plant fibers, but also form a large amount of aerogel with microcellular structure in the macroporous PFS. After reduction treatment, the rGO-PFS can form a double-continuous conductive network of rGO aerogel. With the improvement of polydimethylsiloxane (PDMS), the rGO-PFS@PDMS composite exhibits outstanding compressibility (up to 60% compression strain), excellent durability (10,000 stable compression cycles at 50% strain), high sensitivity (234.07 kPa−1 in a pressure range of 20 ~ 387.2 Pa), low detection limit (20 Pa), and rapid response time (28 ms) for practical wearable applications.

Graphical Abstract

A compressible and conductive reduced graphene oxide–modified plant fiber sponge is prepared by a simple and effective carbonization-free method. With the improvement of polydimethylsiloxane, the sponge exhibits outstanding compressibility, durability, high sensitivity, low detection limit, and rapid response time for practical wearable applications.

柔性压力传感器作为监测人体健康的可穿戴电子设备引起了人们的广泛关注。本文提出了一种简单有效的无碳化制备可压缩导电的还原氧化石墨烯(rGO)改性植物纤维海绵(定义为rGO- pfs)的方法。引入的氧化石墨烯不仅可以包覆在植物纤维表面,还可以在大孔PFS中形成大量具有微孔结构的气凝胶。还原处理后的rGO- pfs可以形成双连续的rGO气凝胶导电网络。随着聚二甲基硅氧烷(PDMS)的改进,rGO-PFS@PDMS复合材料具有出色的可压缩性(高达60%的压缩应变),优异的耐用性(在50%应变下稳定压缩循环10,000次),高灵敏度(在20 ~ 387.2 Pa的压力范围内234.07 kPa−1),低检测限(20 Pa)和快速响应时间(28 ms),适用于实际可穿戴应用。采用简单有效的无碳化方法制备了可压缩导电的还原性氧化石墨烯改性植物纤维海绵。通过对聚二甲基硅氧烷的改进,该海绵具有出色的可压缩性、耐用性、高灵敏度、低检出限和快速响应时间,可用于实际可穿戴应用。
{"title":"Constructing a continuous reduced graphene oxide network in porous plant fiber sponge for highly compressible and sensitive piezoresistive sensors","authors":"Gang Zhao,&nbsp;Feng Qian,&nbsp;Xinyi Li,&nbsp;Yuhan Tang,&nbsp;Ye Sheng,&nbsp;Handong Li,&nbsp;Jiuping Rao,&nbsp;Man Vir Singh,&nbsp;Hassan Algadi,&nbsp;Min Niu,&nbsp;Weijie Zhang,&nbsp;Zhanhu Guo,&nbsp;Xiangfang Peng,&nbsp;Tingjie Chen","doi":"10.1007/s42114-023-00754-w","DOIUrl":"10.1007/s42114-023-00754-w","url":null,"abstract":"<div><p>Flexible pressure sensors as wearable electronic devices to monitor human health have attracted significant attention. Herein, a simple and effective carbonization-free method is proposed to prepare a compressible and conductive reduced graphene oxide (rGO)–modified plant fiber sponge (defined as rGO-PFS). The introduced GO can not only coat on the surface of plant fibers, but also form a large amount of aerogel with microcellular structure in the macroporous PFS. After reduction treatment, the rGO-PFS can form a double-continuous conductive network of rGO aerogel. With the improvement of polydimethylsiloxane (PDMS), the rGO-PFS@PDMS composite exhibits outstanding compressibility (up to 60% compression strain), excellent durability (10,000 stable compression cycles at 50% strain), high sensitivity (234.07 kPa<sup>−1</sup> in a pressure range of 20 ~ 387.2 Pa), low detection limit (20 Pa), and rapid response time (28 ms) for practical wearable applications.</p><h3>Graphical Abstract</h3>\u0000 <div><figure><div><div><picture><source><img></source></picture></div></div></figure></div>\u0000 <p>A compressible and conductive reduced graphene oxide–modified plant fiber sponge is prepared by a simple and effective carbonization-free method. With the improvement of polydimethylsiloxane, the sponge exhibits outstanding compressibility, durability, high sensitivity, low detection limit, and rapid response time for practical wearable applications.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"6 5","pages":""},"PeriodicalIF":20.1,"publicationDate":"2023-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42114-023-00754-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50024289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fe-based dual-center heterogeneous catalyst assisted with reduced graphene oxide for the activation of peroxymonosulfate 铁基双中心非均相催化剂辅助还原氧化石墨烯活化过氧单硫酸盐
IF 20.1 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-10-13 DOI: 10.1007/s42114-023-00757-7
Ajmal Shahzad, Jawad Ali, Muhammad Wajid Ullah, Kazim Aziz, Muhammad Asif Javed, Fida Hussain, Sehrish Manan, Khalid Ali Khan, Thamer Alomayri, Weam Abdul Raheem M, Guang Yang

Transition metal-based (M = Fe, Cu, etc.) catalytic systems are generally popular in advanced oxidation processes; however, the difficulty in restoring their active oxidation state, i.e., Mn +1 → Mn+, limits their performance during the degradation of organic pollutants. Here, a novel strategy of constructing an electron-rich center via systematic intercalation of ultrathin-reduced graphene oxide (rGO) sheets into hydroxide-based materials was introduced to accelerate M(n +1)/Mn+ redox cycles of transition metal-based (M = Fe, Cu) heterogeneous catalysts (M-Hydroxide/rGO). According to the first-order kinetic model, the fabricated M-Hydroxide/rGO was more reactive than the corresponding hydroxides or rGO during peroxymonosulfate (PMS) activation. The first-order observed degradation rates (kobs) of 4-chlorophenol (4-CP) were found in the order of Fe-Hydroxide/rGO (kobs = 0.152 min−1) > Cu-Hydroxide/rGO (kobs = 0.091 min−1) > Zn-Hydroxide/rGO (kobs = 0.021 min−1). Moreover, the prepared best Fe-Hydroxide/rGO catalyst exhibited 6–43-fold high pollutant removal reactivity than catalyst precursors (Fe-Hydroxide/NO3 and rGO), conventional benchmark catalysts (CuO, Co3O4, CuOFe3O4, and Fe3O4), and various Fe3+-based co-catalytic systems (such as Fe3+/WS2 and Fe3+/MoS2). The better efficiency was ascribed to the electron-rich domain (C = O, O–C = O) of interlayered rGO, allowing the constant regeneration of Fe2+ via efficient electron transfer and the production of diverse reactive species, i.e., sulfate radicals (•SO4), hydroxyl (•OH) radicals, and singlet oxygen (1O2). Moreover, a suitable degradation pathway of 4-CP, passing through diverse reactive species, was proposed. This study highlights the vital role of rGO in improving the activity and stability of Fe-based hydroxide catalysts by accelerating Fe3+/Fe2+ redox cycle through regular feeding of electrons.

过渡金属基(M = Fe, Cu等)催化体系在高级氧化过程中普遍流行;然而,难以恢复其活性氧化态,即Mn+ 1→Mn+,限制了它们在降解有机污染物过程中的性能。本文介绍了一种新的策略,即通过系统地将超薄还原氧化石墨烯(rGO)片嵌入到氢氧化物基材料中来构建富电子中心,以加速过渡金属基(M = Fe, Cu)非均相催化剂(M- oh /rGO)的M(n +1)/Mn+氧化还原循环。根据一级动力学模型,制备的m -氢氧根/还原氧化石墨烯在过氧单硫酸盐(PMS)活化过程中比相应的氢氧根或还原氧化石墨烯更具活性。4-氯苯酚(4-CP)的一级降解速率(kobs)依次为:fe - oh /rGO (kobs = 0.152 min−1)> cu - oh /rGO (kobs = 0.091 min−1)> zn - oh /rGO (kobs = 0.021 min−1)。此外,制备的最佳氢氧化铁/还原氧化石墨烯催化剂的去除率比催化剂前驱体(氢氧化铁/NO3和还原氧化石墨烯)、常规基准催化剂(CuO、Co3O4、CuOFe3O4和Fe3O4)以及各种Fe3+基共催化体系(Fe3+/WS2和Fe3+/MoS2)高6 - 43倍。较好的效率归因于层间氧化石墨烯的富电子畴(C = O, O - C = O),允许通过有效的电子转移不断再生Fe2+,并产生多种活性物质,即硫酸盐自由基(•SO4−),羟基(•OH)自由基和单线态氧(1O2)。此外,还提出了一种适宜的4-CP降解途径,可通过多种反应物质进行降解。本研究强调了还原氧化石墨烯在提高铁基氢氧化物催化剂的活性和稳定性方面的重要作用。还原氧化石墨烯通过定期给电子加速Fe3+/Fe2+氧化还原循环。
{"title":"Fe-based dual-center heterogeneous catalyst assisted with reduced graphene oxide for the activation of peroxymonosulfate","authors":"Ajmal Shahzad,&nbsp;Jawad Ali,&nbsp;Muhammad Wajid Ullah,&nbsp;Kazim Aziz,&nbsp;Muhammad Asif Javed,&nbsp;Fida Hussain,&nbsp;Sehrish Manan,&nbsp;Khalid Ali Khan,&nbsp;Thamer Alomayri,&nbsp;Weam Abdul Raheem M,&nbsp;Guang Yang","doi":"10.1007/s42114-023-00757-7","DOIUrl":"10.1007/s42114-023-00757-7","url":null,"abstract":"<div><p>Transition metal-based (M = Fe, Cu, etc.) catalytic systems are generally popular in advanced oxidation processes; however, the difficulty in restoring their active oxidation state, i.e., M<sup><i>n</i> +1</sup> → M<sup><i>n</i>+</sup>, limits their performance during the degradation of organic pollutants. Here, a novel strategy of constructing an electron-rich center via systematic intercalation of ultrathin-reduced graphene oxide (rGO) sheets into hydroxide-based materials was introduced to accelerate M<sup>(<i>n</i> +1)</sup>/M<sup><i>n</i>+</sup> redox cycles of transition metal-based (M = Fe, Cu) heterogeneous catalysts (M-Hydroxide/rGO). According to the first-order kinetic model, the fabricated M-Hydroxide/rGO was more reactive than the corresponding hydroxides or rGO during peroxymonosulfate (PMS) activation. The first-order observed degradation rates (<i>k</i><sub>obs</sub>) of 4-chlorophenol (4-CP) were found in the order of Fe-Hydroxide/rGO (<i>k</i><sub>obs</sub> = 0.152 min<sup>−1</sup>) &gt; Cu-Hydroxide/rGO (<i>k</i><sub>obs</sub> = 0.091 min<sup>−1</sup>) &gt; Zn-Hydroxide/rGO (<i>k</i><sub>obs</sub> = 0.021 min<sup>−1</sup>). Moreover, the prepared best Fe-Hydroxide/rGO catalyst exhibited 6–43-fold high pollutant removal reactivity than catalyst precursors (Fe-Hydroxide/NO<sub>3</sub> and rGO), conventional benchmark catalysts (CuO, Co<sub>3</sub>O<sub>4</sub>, CuOFe<sub>3</sub>O<sub>4</sub>, and Fe<sub>3</sub>O<sub>4</sub>), and various Fe<sup>3+</sup>-based co-catalytic systems (such as Fe<sup>3+</sup>/WS<sub>2</sub> and Fe<sup>3+</sup>/MoS<sub>2</sub>). The better efficiency was ascribed to the electron-rich domain (C = O, O–C = O) of interlayered rGO, allowing the constant regeneration of Fe<sup>2+</sup> via efficient electron transfer and the production of diverse reactive species, i.e., sulfate radicals (•SO<sub>4</sub><sup>−</sup>), hydroxyl (•OH) radicals, and singlet oxygen (<sup>1</sup>O<sub>2</sub>). Moreover, a suitable degradation pathway of 4-CP, passing through diverse reactive species, was proposed. This study highlights the vital role of rGO in improving the activity and stability of Fe-based hydroxide catalysts by accelerating Fe<sup>3+</sup>/Fe<sup>2+</sup> redox cycle through regular feeding of electrons.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"6 5","pages":""},"PeriodicalIF":20.1,"publicationDate":"2023-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50024285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Molecular layer deposition of hybrid silphenylene-based dielectric film 杂化硅苯基介电膜的分子层沉积
IF 20.1 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-10-11 DOI: 10.1007/s42114-023-00756-8
Xinzhi Li, Marko Vehkamäki, Mykhailo Chundak, Kenichiro Mizohata, Anton Vihervaara, Matti Putkonen, Markku Leskelä, Mikko Ritala

Molecular layer deposition (MLD) offers molecular level control in deposition of organic and hybrid thin films. This article describes a new type of inorganic–organic silicon-based MLD process where Aluminium chloride (AlCl3) and 1,4-bis(triethoxysilyl)benzene (BTEB) were used as precursors. Hybrid films were deposited at a temperature range of 300 to 500 °C and high growth per cycle (GPC) up to 1.94 Å was obtained. Field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM) were used to analyze the appearance of the film surface. The hybrid film was amorphous in low-magnification FESEM images but some particulates appeared in high-magnification FESEM images (200 k). Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), Time-of-flight elastic recoil detection analysis (ToF-ERDA), and X-ray photoelectron spectroscopy (XPS) were employed to analyze the structure and composition of the hybrid film. The ratio of Al/Si in the hybrid film was 0.8. The storage environment of the films affected their capacitance, dielectric constant, leakage performance, and breakdown voltage. A film stored in a high vacuum (10–6 mbar) environment had low leakage current density (< 10–6 A × cm−2 at an applied voltage of 28 V) and a dielectric constant of 4.94, which was much smaller than after storing in a humid ambient environment.

Graphical abstract

分子层沉积(MLD)为有机薄膜和杂化薄膜的沉积提供了分子水平的控制。本文介绍了一种以氯化铝(AlCl3)和1,4-双(三乙氧基硅基)苯(BTEB)为前驱体的新型无机-有机硅基MLD工艺。在300 ~ 500℃的温度范围内沉积杂化膜,获得了高达1.94 Å的高生长周期(GPC)。采用场发射扫描电镜(FESEM)和原子力显微镜(AFM)对膜表面形貌进行了分析。利用衰减全反射傅立叶变换红外光谱(ATR-FTIR)、飞行时间弹性反冲检测分析(ToF-ERDA)和x射线光电子能谱(XPS)分析了杂化膜的结构和组成。杂化膜中Al/Si的比值为0.8。薄膜的储存环境对薄膜的电容、介电常数、漏电性能和击穿电压都有影响。在高真空(10-6 mbar)环境下存储的薄膜具有较低的漏电流密度(外加电压为28 V时为10-6 A × cm−2),介电常数为4.94,远小于在潮湿环境下存储的薄膜。图形抽象
{"title":"Molecular layer deposition of hybrid silphenylene-based dielectric film","authors":"Xinzhi Li,&nbsp;Marko Vehkamäki,&nbsp;Mykhailo Chundak,&nbsp;Kenichiro Mizohata,&nbsp;Anton Vihervaara,&nbsp;Matti Putkonen,&nbsp;Markku Leskelä,&nbsp;Mikko Ritala","doi":"10.1007/s42114-023-00756-8","DOIUrl":"10.1007/s42114-023-00756-8","url":null,"abstract":"<div><p>Molecular layer deposition (MLD) offers molecular level control in deposition of organic and hybrid thin films. This article describes a new type of inorganic–organic silicon-based MLD process where Aluminium chloride (AlCl<sub>3</sub>) and 1,4-bis(triethoxysilyl)benzene (BTEB) were used as precursors. Hybrid films were deposited at a temperature range of 300 to 500 °C and high growth per cycle (GPC) up to 1.94 Å was obtained. Field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM) were used to analyze the appearance of the film surface. The hybrid film was amorphous in low-magnification FESEM images but some particulates appeared in high-magnification FESEM images (200 k). Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), Time-of-flight elastic recoil detection analysis (ToF-ERDA), and X-ray photoelectron spectroscopy (XPS) were employed to analyze the structure and composition of the hybrid film. The ratio of Al/Si in the hybrid film was 0.8. The storage environment of the films affected their capacitance, dielectric constant, leakage performance, and breakdown voltage. A film stored in a high vacuum (10<sup>–6</sup> mbar) environment had low leakage current density (&lt; 10<sup>–6</sup> A × cm<sup>−2</sup> at an applied voltage of 28 V) and a dielectric constant of 4.94, which was much smaller than after storing in a humid ambient environment.</p><h3>Graphical abstract</h3>\u0000 <div><figure><div><div><picture><source><img></source></picture></div></div></figure></div>\u0000 </div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"6 5","pages":""},"PeriodicalIF":20.1,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42114-023-00756-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50019826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-performance multifunctional energy storage-corrugated lattice core sandwich structure via continuous carbon fiber (CCF)/polyamide 6 (PA6) 3D printing 连续碳纤维(CCF)/聚酰胺6(PA6)3D打印高性能多功能储能波纹格芯夹芯结构
IF 20.1 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-10-03 DOI: 10.1007/s42114-023-00761-x
Hui-Jin Um, Na-Hyun Jeon, Ji-Hwan Shin, Hak-Sung Kim

In this study, an energy storage multifunctional sandwich structure (ESMS) was designed to perform well-balanced and excellent multifunctional performance. The corrugated core sandwich structure was newly developed to prevent the degradation of mechanical properties even when lithium polymer (LiPo) batteries are integrated. The empty space of the corrugated core was used as an energy storage space, and the corrugated core was fabricated via 3D printing technology using a continuous carbon fiber filament. The energy storage characteristics were implemented using LiPo batteries embedded in the neutral axis of the sandwich structure. The static and fatigue bending properties of the ESMSs were analyzed through a three-point bending (3PB) test. A battery charge/discharge test was performed before and after the mechanical tests to analyze the effect of bending loading on the energy storage properties. The conventional foam-core ESMS showed negative changes in flexural properties such as strength (−27% in Foam-SH) and modulus (−22% in Foam-AD) due to the battery embedding. On the other hand, in the case of the 3D-printed core ESMS, no degradation in mechanical properties was observed even though the energy density was 1.7 times higher than that of the foam-core ESMS. Furthermore, no defects or delamination were found in the battery embedded in the 3D-printed core ESMS, unlike the battery embedded in the foam-core ESMS where delamination between the separator, anode, and cathodes occurred after the 3 PB test. Consequently, a 3D-printed core ESMS with superior balanced multifunctional performance can be implemented without degradation of both the mechanical properties and energy storage characteristics.

在本研究中,设计了一种储能多功能夹层结构(ESMS),以实现良好的平衡和优异的多功能性能。波纹芯夹层结构是新开发的,即使在集成锂聚合物(LiPo)电池时也能防止机械性能的退化。将波纹芯的空隙用作储能空间,并使用连续碳纤维丝通过3D打印技术制造波纹芯。使用嵌入夹层结构的中性轴中的LiPo电池来实现能量存储特性。通过三点弯曲(3PB)试验分析了ESMS的静态和疲劳弯曲性能。在机械测试之前和之后进行电池充电/放电测试,以分析弯曲负载对储能性能的影响。由于电池嵌入,传统泡沫芯ESMS的弯曲性能如强度(在泡沫SH中为−27%)和模量(在泡沫AD中为−22%)出现了负面变化。另一方面,在3D打印芯ESMS的情况下,即使能量密度比泡沫芯ESMS高1.7倍,也没有观察到机械性能的退化。此外,与嵌入泡沫芯ESMS中的电池不同,嵌入3D打印芯ESMS的电池中没有发现缺陷或分层,在3 PB测试后,隔板、阳极和阴极之间发生分层。因此,可以在不降低机械性能和储能特性的情况下实现具有优异平衡多功能性能的3D打印芯ESMS。
{"title":"High-performance multifunctional energy storage-corrugated lattice core sandwich structure via continuous carbon fiber (CCF)/polyamide 6 (PA6) 3D printing","authors":"Hui-Jin Um,&nbsp;Na-Hyun Jeon,&nbsp;Ji-Hwan Shin,&nbsp;Hak-Sung Kim","doi":"10.1007/s42114-023-00761-x","DOIUrl":"10.1007/s42114-023-00761-x","url":null,"abstract":"<div><p>In this study, an energy storage multifunctional sandwich structure (ESMS) was designed to perform well-balanced and excellent multifunctional performance. The corrugated core sandwich structure was newly developed to prevent the degradation of mechanical properties even when lithium polymer (LiPo) batteries are integrated. The empty space of the corrugated core was used as an energy storage space, and the corrugated core was fabricated via 3D printing technology using a continuous carbon fiber filament. The energy storage characteristics were implemented using LiPo batteries embedded in the neutral axis of the sandwich structure. The static and fatigue bending properties of the ESMSs were analyzed through a three-point bending (3PB) test. A battery charge/discharge test was performed before and after the mechanical tests to analyze the effect of bending loading on the energy storage properties. The conventional foam-core ESMS showed negative changes in flexural properties such as strength (−27% in Foam-SH) and modulus (−22% in Foam-AD) due to the battery embedding. On the other hand, in the case of the 3D-printed core ESMS, no degradation in mechanical properties was observed even though the energy density was 1.7 times higher than that of the foam-core ESMS. Furthermore, no defects or delamination were found in the battery embedded in the 3D-printed core ESMS, unlike the battery embedded in the foam-core ESMS where delamination between the separator, anode, and cathodes occurred after the 3 PB test. Consequently, a 3D-printed core ESMS with superior balanced multifunctional performance can be implemented without degradation of both the mechanical properties and energy storage characteristics.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"6 5","pages":""},"PeriodicalIF":20.1,"publicationDate":"2023-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50447100","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure and mechanical properties of extruded Mg-6Al-2X (X = Cu/Ni/Fe) alloy used degradable bridge plugs 可降解桥塞用挤压Mg-6Al-2X (X = Cu/Ni/Fe)合金的组织与力学性能
IF 20.1 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-10-02 DOI: 10.1007/s42114-023-00753-x
Wentao Liu, Baosheng Liu, Shaohua Zhang, Zhiping Lin, Yuezhong Zhang, Pengpeng Wu, Hassan Algadi

Magnesium alloys have recently received much attention as fracturing tools for unconventional oil and gas development. It is well known that increasing micro-galvanic corrosion by doping elements in magnesium alloys is an effective method to get highly degradable alloys. The study aimed to evaluate the effect of different doping elements (i.e., copper, nickel and iron) on the mechanical and degradation behavior of hot extruded magnesium alloys. Nickel-containing alloys show high degradability and mechanical properties compared to the other two alloys. Specifically, the second phase of nickel-containing alloys has a dotted distribution, and this distribution favors the diffusion of corrosion. Meanwhile, the addition of nickel improves the mechanical properties of the alloy with a compressive strength of 430.6 MPa. In addition, based on the first principles and phase diagram simulations. With the addition of nickel, the compounds formed in the alloy act as drivers for the improved degradation properties, resulting in a corrosion rate of 1638.14 mm/year at 93 °C. Therefore, nickel-containing alloys that have been hot extruded show wide application prospects in the field of oil and gas extraction.

Graphical abstract

The influence of Cu/Ni/Fe elements on the microstructure, mechanical properties, and corrosion properties of Mg-6Al (wt. %) alloy was investigated using electrochemical tests, hydrogen evolution, and weight loss measurement.

镁合金作为非常规油气开发中的压裂工具,近年来备受关注。众所周知,在镁合金中掺杂元素增加微电偶腐蚀是获得高降解镁合金的有效方法。本研究旨在评价不同掺杂元素(即铜、镍和铁)对热挤压镁合金力学和降解行为的影响。与其他两种合金相比,含镍合金具有较高的可降解性和力学性能。含镍合金的第二相呈点状分布,有利于腐蚀的扩散。同时,镍的加入提高了合金的力学性能,抗压强度达到430.6 MPa。此外,基于第一性原理和相图进行了仿真。随着镍的加入,合金中形成的化合物成为改善降解性能的驱动因素,在93℃时腐蚀速率为1638.14 mm/年。因此,经热挤压处理的含镍合金在油气开采领域具有广阔的应用前景。摘要采用电化学试验、析氢试验和失重试验研究了Cu/Ni/Fe元素对Mg-6Al (wt. %)合金显微组织、力学性能和腐蚀性能的影响。
{"title":"Microstructure and mechanical properties of extruded Mg-6Al-2X (X = Cu/Ni/Fe) alloy used degradable bridge plugs","authors":"Wentao Liu,&nbsp;Baosheng Liu,&nbsp;Shaohua Zhang,&nbsp;Zhiping Lin,&nbsp;Yuezhong Zhang,&nbsp;Pengpeng Wu,&nbsp;Hassan Algadi","doi":"10.1007/s42114-023-00753-x","DOIUrl":"10.1007/s42114-023-00753-x","url":null,"abstract":"<div><p>Magnesium alloys have recently received much attention as fracturing tools for unconventional oil and gas development. It is well known that increasing micro-galvanic corrosion by doping elements in magnesium alloys is an effective method to get highly degradable alloys. The study aimed to evaluate the effect of different doping elements (i.e., copper, nickel and iron) on the mechanical and degradation behavior of hot extruded magnesium alloys. Nickel-containing alloys show high degradability and mechanical properties compared to the other two alloys. Specifically, the second phase of nickel-containing alloys has a dotted distribution, and this distribution favors the diffusion of corrosion. Meanwhile, the addition of nickel improves the mechanical properties of the alloy with a compressive strength of 430.6 MPa. In addition, based on the first principles and phase diagram simulations. With the addition of nickel, the compounds formed in the alloy act as drivers for the improved degradation properties, resulting in a corrosion rate of 1638.14 mm/year at 93 °C. Therefore, nickel-containing alloys that have been hot extruded show wide application prospects in the field of oil and gas extraction.</p><h3>Graphical abstract</h3><p>The influence of Cu/Ni/Fe elements on the microstructure, mechanical properties, and corrosion properties of Mg-6Al (wt. %) alloy was investigated using electrochemical tests, hydrogen evolution, and weight loss measurement.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"6 5","pages":""},"PeriodicalIF":20.1,"publicationDate":"2023-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50005397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biosynthesizing lignin dehydrogenation polymer to fabricate hybrid hydrogel composite with hyaluronic acid for cartilage repair 生物合成木质素脱氢聚合物制备透明质酸混合水凝胶复合材料用于软骨修复
IF 20.1 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-09-30 DOI: 10.1007/s42114-023-00758-6
Wenhui Pei, Yalikun Yusufu, Yifei Zhan, Xucai Wang, Jian Gan, Liming Zheng, Peng Wang, Kai Zhang, Caoxing Huang

Lignin possesses a number of functional groups including phenolic hydroxyl and methoxy groups, which grant its bioactivity for the fabrication of bio-polymer-based composites in bone tissue engineering applications. However, the heterogeneity of natural lignin limits its use in biomedicine. In the present study, a bio-enzyme approach was proposed to synthesize lignin-dehydrogenated polymers from the precursors of arabinogalactan (DHP-A) and xylose (DHP-X), which possess more homogeneous substructures with appropriate functional groups. Both DHP-A and DHP-X showed excellent in vitro abilities for regulating biocompatibility, “pre-oxidation,” and chondrogenic differentiation, in which DHP-A possessed cartilage repair ability due to its abundant content of phenolic hydroxyl groups (3.00 mmol g−1). Hence, DHP-A was hybridized with hyaluronic acid (HA) to prepare a hydrogel (DHP-HA) composite, which exhibited the compressive strength and modulus of 810 kPa and 310 kPa, respectively. Notably, these properties closely resemble those of articular cartilage, which typically ranges from 320 to 810 kPa. The application of DHP-HA hydrogel composite in a rat cartilage defect model in vivo revealed that it promoted the regeneration of hyaline cartilage rather than hypertrophic cartilage, which could heal 66.22–79.26% of the cartilage defects compared to the control group. Pre-oxidation of DHP-A elicits a mechanism that activates the oxidative stress system, leading to an augmented stress response and consequent increase in stress resistance. This study introduces a pioneering enzymatic synthesis technique to prepare the biologically active lignin for creating bio-polymer-based composites, demonstrating its potential as an innovative avenue for therapeutic cartilage regeneration.

Graphical Abstract

Bioenzymatically synthesized lignin dehydrogenation polymers to hybridize with hyaluronic acid to prepare hydrogel composites for promoting cartilage defect repair.

木质素具有许多官能团,包括酚羟基和甲氧基,这赋予了其在骨组织工程应用中制造生物聚合物基复合材料的生物活性。然而,天然木质素的异质性限制了其在生物医学中的应用。在本研究中,提出了一种由阿拉伯半乳聚糖(DHP-a)和木糖(DHP-X)的前体合成木质素脱氢聚合物的生物酶方法,这些前体具有更均匀的亚结构和合适的官能团。DHP-A和DHP-X在体外均表现出优异的调节生物相容性、“预氧化”和软骨分化的能力,其中DHP-A由于其丰富的酚羟基含量(3.00mmol g−1)而具有软骨修复能力。因此,将DHP-A与透明质酸(HA)杂交制备水凝胶(DHP-HA)复合材料,其抗压强度和模量分别为810kPa和310kPa。值得注意的是,这些特性与关节软骨的特性非常相似,通常在320至810kPa的范围内。DHP-HA水凝胶复合材料在大鼠体内软骨缺损模型中的应用表明,它促进了透明软骨而不是肥大软骨的再生,与对照组相比,肥大软骨可以治愈66.22-79.26%的软骨缺损。DHP-A的预氧化引发了一种激活氧化应激系统的机制,导致应激反应增强,从而增强应激抵抗力。本研究介绍了一种开创性的酶合成技术,用于制备生物活性木质素,用于制造基于生物聚合物的复合材料,展示了其作为治疗性软骨再生的创新途径的潜力。生物酶合成木质素脱氢聚合物与透明质酸杂交,制备促进软骨缺损修复的水凝胶复合材料。
{"title":"Biosynthesizing lignin dehydrogenation polymer to fabricate hybrid hydrogel composite with hyaluronic acid for cartilage repair","authors":"Wenhui Pei,&nbsp;Yalikun Yusufu,&nbsp;Yifei Zhan,&nbsp;Xucai Wang,&nbsp;Jian Gan,&nbsp;Liming Zheng,&nbsp;Peng Wang,&nbsp;Kai Zhang,&nbsp;Caoxing Huang","doi":"10.1007/s42114-023-00758-6","DOIUrl":"10.1007/s42114-023-00758-6","url":null,"abstract":"<div><p>Lignin possesses a number of functional groups including phenolic hydroxyl and methoxy groups, which grant its bioactivity for the fabrication of bio-polymer-based composites in bone tissue engineering applications. However, the heterogeneity of natural lignin limits its use in biomedicine. In the present study, a bio-enzyme approach was proposed to synthesize lignin-dehydrogenated polymers from the precursors of arabinogalactan (DHP-A) and xylose (DHP-X), which possess more homogeneous substructures with appropriate functional groups. Both DHP-A and DHP-X showed excellent in vitro abilities for regulating biocompatibility, “pre-oxidation,” and chondrogenic differentiation, in which DHP-A possessed cartilage repair ability due to its abundant content of phenolic hydroxyl groups (3.00 mmol g<sup>−1</sup>). Hence, DHP-A was hybridized with hyaluronic acid (HA) to prepare a hydrogel (DHP-HA) composite, which exhibited the compressive strength and modulus of 810 kPa and 310 kPa, respectively. Notably, these properties closely resemble those of articular cartilage, which typically ranges from 320 to 810 kPa. The application of DHP-HA hydrogel composite in a rat cartilage defect model in vivo revealed that it promoted the regeneration of hyaline cartilage rather than hypertrophic cartilage, which could heal 66.22–79.26% of the cartilage defects compared to the control group. Pre-oxidation of DHP-A elicits a mechanism that activates the oxidative stress system, leading to an augmented stress response and consequent increase in stress resistance. This study introduces a pioneering enzymatic synthesis technique to prepare the biologically active lignin for creating bio-polymer-based composites, demonstrating its potential as an innovative avenue for therapeutic cartilage regeneration.</p><h3>Graphical Abstract</h3><p>Bioenzymatically synthesized lignin dehydrogenation polymers to hybridize with hyaluronic acid to prepare hydrogel composites for promoting cartilage defect repair.</p>\u0000 <div><figure><div><div><picture><source><img></source></picture></div></div></figure></div>\u0000 </div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"6 5","pages":""},"PeriodicalIF":20.1,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50056242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Double-phase engineering of cobalt sulfide/oxyhydroxide on metal-organic frameworks derived iron carbide-integrated porous carbon nanofibers for asymmetric supercapacitors 用于不对称超级电容器的金属-有机框架上硫化钴/氢氧根的双相工程衍生的碳化铁集成多孔碳纳米纤维
IF 20.1 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-09-30 DOI: 10.1007/s42114-023-00755-9
Debendra Acharya, Tae Hoon Ko, Roshan Mangal Bhattarai, Alagan Muthurasu, Taewoo Kim, Syafiqah Saidin, Jae-Shik Choi, Kisan Chhetri, Hak Yong Kim

Designing advanced functional electrode materials with a tunable structure and multiphase/composition comprising a single metal via a one-step synthesis process for supercapacitor applications is challenging. Here, a dual-phase cobalt sulfide/cobalt oxyhydroxide (Co1-xS/HCoO2) hexagonal nanostructure on iron metal-organic framework (MIL-88A) derived iron carbide (Fe3C) integrated porous carbon nanofibers (PCNFs) is synthesized using a wet-chemical curing technique. MIL-88A is integrated by a physical blending process into a PAN/PMMA polymer matrix during the PCNFs preparation process. The integrated MIL-88A-derived iron carbide nanomaterial contributes to improving the electrochemical performance of electrode materials by lowering the inherent resistance. The optimal (Co1-xS/HCoO2)-1@Fe3C/PCNFs electrode exhibits a high specific capacitance of 1724 F g−1 at 1 A g−1 with an improved rate capability and exceptional cycling stability with 89.8% retention even after 10,000 cycles. These excellent electrochemical capabilities are predominantly attributed to the double-phase hybrid composites, which have a variety of abundant sites, a large active surface area, rapid electron and ion transport capability, and strong structural stability. A Co1-xS/HCoO2-1@Fe3C/PCNFs//Fe2O3/NPC@PCNFs asymmetric supercapacitor (ASC) demonstrates excellent electrochemical energy storage behavior, with a maximum energy density of 65.68 Wh kg−1 at a power density of 752.7 W kg−1 and excellent cycling stability (90.3% capacitance retention after 10,000 charge-discharge cycles at a constant current density of 20 A g−1). These electrochemical results indicate that this ASC outperforms previously reported asymmetric supercapacitors, showing that the heterophasic electrode (Co1-xS/HCoO2)-1@Fe3C/PCNFs has the potential to be applied in supercapacitor devices.

通过一步合成工艺设计具有可调结构和包括单一金属的多相/组成的先进功能电极材料用于超级电容器应用是具有挑战性的。本文采用湿法化学固化技术,在铁金属有机骨架(MIL-88A)衍生的碳化铁(Fe3C)集成多孔碳纳米纤维(PCNFs)上合成了一种双相硫化钴/羟基氧化钴(Co1-xS/HCoO2)六边形纳米结构。在PCNFs制备过程中,MIL-88A通过物理共混工艺集成到PAN/PMMA聚合物基体中。集成的MIL-88A衍生的碳化铁纳米材料通过降低固有电阻有助于提高电极材料的电化学性能。最佳(Co1-xS/HCoO2)-1@Fe3C/PCNFs电极在1 a g−1下表现出1724 F g−1的高比电容,具有改进的倍率能力和优异的循环稳定性,即使在10000次循环后仍保持89.8%的保留率。这些优异的电化学性能主要归功于双相杂化复合材料,它具有丰富的位点、大的活性表面积、快速的电子和离子传输能力以及强大的结构稳定性。Co1-xS/HCoO2-1@Fe3C/PCNFs//Fe2O3/NPC@PCNFs不对称超级电容器(ASC)表现出优异的电化学储能性能,在752.7 W kg−1的功率密度下,最大能量密度为65.68 Wh kg−1,循环稳定性优异(在20 a的恒定电流密度下,10000次充放电循环后,电容保持率为90.3% g−1)。这些电化学结果表明,这种ASC优于先前报道的不对称超级电容器,表明异相电极(Co1-xS/HCoO2)-1@Fe3C/PCNFs具有在超级电容器器件中应用的潜力。
{"title":"Double-phase engineering of cobalt sulfide/oxyhydroxide on metal-organic frameworks derived iron carbide-integrated porous carbon nanofibers for asymmetric supercapacitors","authors":"Debendra Acharya,&nbsp;Tae Hoon Ko,&nbsp;Roshan Mangal Bhattarai,&nbsp;Alagan Muthurasu,&nbsp;Taewoo Kim,&nbsp;Syafiqah Saidin,&nbsp;Jae-Shik Choi,&nbsp;Kisan Chhetri,&nbsp;Hak Yong Kim","doi":"10.1007/s42114-023-00755-9","DOIUrl":"10.1007/s42114-023-00755-9","url":null,"abstract":"<div><p>Designing advanced functional electrode materials with a tunable structure and multiphase/composition comprising a single metal via a one-step synthesis process for supercapacitor applications is challenging. Here, a dual-phase cobalt sulfide/cobalt oxyhydroxide (Co<sub>1-x</sub>S/HCoO<sub>2</sub>) hexagonal nanostructure on iron metal-organic framework (MIL-88A) derived iron carbide (Fe<sub>3</sub>C) integrated porous carbon nanofibers (PCNFs) is synthesized using a wet-chemical curing technique. MIL-88A is integrated by a physical blending process into a PAN/PMMA polymer matrix during the PCNFs preparation process. The integrated MIL-88A-derived iron carbide nanomaterial contributes to improving the electrochemical performance of electrode materials by lowering the inherent resistance. The optimal (Co<sub>1-x</sub>S/HCoO<sub>2</sub>)-1@Fe<sub>3</sub>C/PCNFs electrode exhibits a high specific capacitance of 1724 F g<sup>−1</sup> at 1 A g<sup>−1</sup> with an improved rate capability and exceptional cycling stability with 89.8% retention even after 10,000 cycles. These excellent electrochemical capabilities are predominantly attributed to the double-phase hybrid composites, which have a variety of abundant sites, a large active surface area, rapid electron and ion transport capability, and strong structural stability. A Co<sub>1-x</sub>S/HCoO<sub>2</sub>-1@Fe<sub>3</sub>C/PCNFs//Fe<sub>2</sub>O<sub>3</sub>/NPC@PCNFs asymmetric supercapacitor (ASC) demonstrates excellent electrochemical energy storage behavior, with a maximum energy density of 65.68 Wh kg<sup>−1</sup> at a power density of 752.7 W kg<sup>−1</sup> and excellent cycling stability (90.3% capacitance retention after 10,000 charge-discharge cycles at a constant current density of 20 A g<sup>−1</sup>). These electrochemical results indicate that this ASC outperforms previously reported asymmetric supercapacitors, showing that the heterophasic electrode (Co<sub>1-x</sub>S/HCoO<sub>2</sub>)-1@Fe<sub>3</sub>C/PCNFs has the potential to be applied in supercapacitor devices.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"6 5","pages":""},"PeriodicalIF":20.1,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50527782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
A “bird nest” bioinspired strategy deployed for inducing cellulose gelation without concomitant dissolution 一种“鸟巢”生物启发策略,用于诱导纤维素凝胶化而不伴随溶解
IF 20.1 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-09-29 DOI: 10.1007/s42114-023-00745-x
Zhen Zhang, Noureddine Abidi, Lucian A. Lucia, Siyi Yu

Albeit the abundance, renewability, and biodegradability of the polymer known as cellulose, the insolubility and poor dispersibility in most common organic solvents make it incredibly difficult to facilitate conversion into hydrogels without concomitant dissolution. It is known that Swift family birds construct strong and sturdy nests with saliva that acts to bind fibers and twigs. Inspired by this charming hierarchical architecture, protonated carboxymethyl cellulose and cellulose were exploited as “saliva” and “twigs,” respectively, and by a combination of freeze–thaw treatments, cellulose hydrogels can be successfully induced without pre-dissolution representing a striking advancement over what is currently known or predicted. The gel materials displayed considerable increases in storage modulus, viscoelastic behaviors, and thermal stability as the cellulose content increases and exhibited unique omniphilic behaviors. Moreover, this bioinspired strategy is much more universal than originally surmised as found by the gelation of bamboo fibers (additionally containing lignin and hemicellulose), illustrative of the versatility. As a bio-inspired strategy, the current work is the first report on a straightforward, simple, green, yet effective gelation protocol to prepare cellulose-based soft materials.

尽管被称为纤维素的聚合物具有丰富性、可再生性和生物降解性,但在大多数常见的有机溶剂中的不溶性和较差的分散性使其难以在不伴随溶解的情况下促进转化为水凝胶。众所周知,雨燕科鸟类用唾液来连接纤维和树枝,从而建造坚固的巢穴。受这种迷人的分级结构的启发,质子化的羧甲基纤维素和纤维素分别被用作“唾液”和“树枝”,通过冷冻-解冻处理的组合,纤维素水凝胶可以在没有预溶解的情况下成功诱导,这比目前已知或预测的有了显著的进步。随着纤维素含量的增加,凝胶材料的储能模量、粘弹性行为和热稳定性显著提高,并表现出独特的全亲性行为。此外,这种受生物启发的策略比最初通过竹纤维(另外含有木质素和半纤维素)的凝胶化所推测的要普遍得多,这说明了它的多功能性。作为一种受生物启发的策略,目前的工作是第一份关于制备纤维素基软材料的直接、简单、绿色但有效的凝胶化方案的报告。
{"title":"A “bird nest” bioinspired strategy deployed for inducing cellulose gelation without concomitant dissolution","authors":"Zhen Zhang,&nbsp;Noureddine Abidi,&nbsp;Lucian A. Lucia,&nbsp;Siyi Yu","doi":"10.1007/s42114-023-00745-x","DOIUrl":"10.1007/s42114-023-00745-x","url":null,"abstract":"<div><p>Albeit the abundance, renewability, and biodegradability of the polymer known as cellulose, the insolubility and poor dispersibility in most common organic solvents make it incredibly difficult to facilitate conversion into hydrogels without concomitant dissolution. It is known that <i>Swift</i> family birds construct strong and sturdy nests with saliva that acts to bind fibers and twigs. Inspired by this charming hierarchical architecture, protonated carboxymethyl cellulose and cellulose were exploited as “saliva” and “twigs,” respectively, and by a combination of freeze–thaw treatments, cellulose hydrogels can be successfully induced without pre-dissolution representing a striking advancement over what is currently known or predicted. The gel materials displayed considerable increases in storage modulus, viscoelastic behaviors, and thermal stability as the cellulose content increases and exhibited unique omniphilic behaviors. Moreover, this bioinspired strategy is much more universal than originally surmised as found by the gelation of bamboo fibers (additionally containing lignin and hemicellulose), illustrative of the versatility. As a bio-inspired strategy, the current work is the first report on a straightforward, simple, green, yet effective gelation protocol to prepare cellulose-based soft materials.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"6 5","pages":""},"PeriodicalIF":20.1,"publicationDate":"2023-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50524442","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Organic/inorganic hybrids for intelligent sensing and wearable clean energy applications 用于智能传感和可穿戴清洁能源应用的有机/无机混合材料
IF 20.1 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-09-28 DOI: 10.1007/s42114-023-00751-z
Xiaotong Zhao, Yinxiao Du, Wei Li, Zebi Zhao, Ming Lei

With the rapid development of wearable electronics and the advent of the Internet of Things (IoT) era, it is imperative to research and explore the basic components to meet the application scenarios. In particular, it is becoming increasingly difficult to impart suitable properties to individual materials and realize appropriate physical dimensions in order to satisfy increasing demands of multifunctionality for fundamental studies, device designs, and performance optimization. Therefore, these challenges and opportunities can be addressed by designing (optical) electronic and energy devices with unique functionality and versatility through the combined advantages of multidimensional integration or hybridization of inorganic semiconductors, especially inorganic two-dimensional semiconductor materials, with various types of organic materials with potentially novel functions and unique properties. Herein, a comprehensive review of emerging integration or hybridization of inorganic semiconductor materials with organic materials from their individual components, and assembly fabrication to their state-of-the-art electronic, optoelectronic, magnetic, and energy applications is presented. Future opportunities and challenges associated with these organic/inorganic hybrids are highlighted.

随着可穿戴电子的快速发展和物联网时代的到来,研究和探索满足应用场景的基本组件势在必行。特别是,为了满足基础研究、器件设计和性能优化对多功能性的日益增长的需求,给单个材料赋予合适的性能并实现合适的物理尺寸变得越来越困难。因此,这些挑战和机遇可以通过设计具有独特功能和多功能性的(光学)电子和能源设备来解决,通过无机半导体,特别是无机二维半导体材料的多维集成或杂交的组合优势,具有各种类型的具有潜在新颖功能和独特性质的有机材料。本文对无机半导体材料与有机材料的新兴集成或杂交进行了全面综述,从其单个组件、组件制造到其最先进的电子、光电、磁性和能源应用。强调了与这些有机/无机杂化物相关的未来机遇和挑战。
{"title":"Organic/inorganic hybrids for intelligent sensing and wearable clean energy applications","authors":"Xiaotong Zhao,&nbsp;Yinxiao Du,&nbsp;Wei Li,&nbsp;Zebi Zhao,&nbsp;Ming Lei","doi":"10.1007/s42114-023-00751-z","DOIUrl":"10.1007/s42114-023-00751-z","url":null,"abstract":"<div><p>With the rapid development of wearable electronics and the advent of the Internet of Things (IoT) era, it is imperative to research and explore the basic components to meet the application scenarios. In particular, it is becoming increasingly difficult to impart suitable properties to individual materials and realize appropriate physical dimensions in order to satisfy increasing demands of multifunctionality for fundamental studies, device designs, and performance optimization. Therefore, these challenges and opportunities can be addressed by designing (optical) electronic and energy devices with unique functionality and versatility through the combined advantages of multidimensional integration or hybridization of inorganic semiconductors, especially inorganic two-dimensional semiconductor materials, with various types of organic materials with potentially novel functions and unique properties. Herein, a comprehensive review of emerging integration or hybridization of inorganic semiconductor materials with organic materials from their individual components, and assembly fabrication to their state-of-the-art electronic, optoelectronic, magnetic, and energy applications is presented. Future opportunities and challenges associated with these organic/inorganic hybrids are highlighted.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"6 5","pages":""},"PeriodicalIF":20.1,"publicationDate":"2023-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42114-023-00751-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50052296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Advanced Composites and Hybrid Materials
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1