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Influence of Nano Particles on Optical Properties of Cu-MOFs 纳米粒子对Cu-MOFs光学性能的影响
Pub Date : 2022-08-25 DOI: 10.4028/p-vn4hd4
Maalathi Challa, B. Yallur, M. Ambika, V. Adimule
A copper metal organic frame work (MOF) is synthesized by taking adequate concentration of 2-mercaptobenzothiazole, 2-bromomalonaldehyde, 1,4 dicarboxylic acid and copper nitrate. Cu-MOF /Ag2O and Cu-MOF/rGO composites are fabricated and is characterized by XRD, UV-Vis spectroscopy and FT-IR. The band gap of the MOF/ nanocomposites is reduced when compare to individuals so that a good visible light harvesting catalyst is formed. This reduction of band gap is due to the either create of shallow state with small ionization energy, very close to the valence and conduction band edge. KEYWORDS: Mercaptobenzothiazole, 2-bromomalonaldehyde MOFs, Copper Composites, Optical Properties, Ag2O, rGO.
以适当浓度的2-巯基苯并噻唑、2-溴隆醛、1,4二羧酸和硝酸铜为原料合成了铜金属有机骨架(MOF)。制备了Cu-MOF/ Ag2O和Cu-MOF/rGO复合材料,并用XRD、UV-Vis光谱和FT-IR对其进行了表征。与单个纳米复合材料相比,MOF/纳米复合材料的带隙减小,从而形成了良好的可见光捕获催化剂。这种带隙的减小是由于产生了具有小电离能的浅态,非常接近价带和导带边缘。关键词:巯基苯并噻唑,2-溴隆醛mof,铜复合材料,光学性能,Ag2O,氧化石墨烯
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引用次数: 6
Recent Advancements in Surface Modification by Gas Tungsten Arc Cladding Technique: A Review 气体钨弧包覆技术表面改性研究进展
Pub Date : 2022-08-25 DOI: 10.4028/p-ix7nkz
R. Ranjan, A. Das
A technique of surface modification used to produce thick coatings with enhanced surface characteristics by developing highly resistive layers on the substrate is known as cladding. It plays a great role to increase the service life of industrial elements. It is broadly applied in chemical, mining, nuclear, power generation, and marine industries. There were a lot of studies done targeting Gas Tungsten Arc Cladding because of its advantages such as user-friendly, low cost, high deposition rate, low dilution, high reliability, etc. The four key features added to the substrate after claddings are dilution of a substrate, microstructure, microhardness, and tribological properties. Considering these features, the current article presents an overview of the Gas Tungsten Arc Cladding technique. The key goal is to reflect on the investigations conducted in the previous decade based on the wear, oxidation, and corrosion performance of cladding surfaces and their key observations. In addition, the effects of Gas Tungsten Arc Cladding process parameters, the substrate-clad materials combination, microstructural improvements, common advantages, and limitations associated with the technique are also presented. New research and industrial people on weld cladding would benefit from the outcomes of this article.
通过在基材上形成高电阻层来生产具有增强表面特性的厚涂层的表面改性技术被称为包覆。对提高工业元件的使用寿命起到很大的作用。广泛应用于化工、矿山、核电、发电、海洋等行业。由于钨极气弧焊具有操作方便、成本低、沉积速率快、稀释度低、可靠性高等优点,因此得到了大量的研究。包覆后添加到基板上的四个关键特征是基板的稀释度、微观结构、显微硬度和摩擦学性能。考虑到这些特点,本文对气体钨极电弧包覆技术进行了综述。主要目标是回顾过去十年中基于包层表面磨损、氧化和腐蚀性能的研究及其关键观察结果。此外,还介绍了气体钨极电弧熔覆工艺参数、衬底-包覆材料组合、显微组织改进、常见优点和局限性等对该工艺的影响。本文的研究成果将使新的研究和工业人员受益。
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引用次数: 0
Covalent Immobilization of REDV Peptide on Heparin Coating Promotes Selective Adhesion of Endothelial Cells 肝素包被上共价固定REDV肽促进内皮细胞的选择性粘附
Pub Date : 2022-08-25 DOI: 10.4028/p-0tpt06
Peigang Zheng, Zhe Yu, Lian Duan, Jia Hao Zhang, Rao Fu, Rui Jiang
Forming an endothelial cell (EC) monolayer on the surface of blood-contacting devices is an ideal way to improve their blood compatibility, this process is known as endothelialization. Heparin is a proteoglycan with a strong negative charge, which is a commonly used antithrombotic agent. Heparin coatings also has been successfully used to improve the hemocompatibility of various biomaterials. In this study, a short peptide Arg-Glu-Asp-Val (REDV) with specific affinity for endothelial cells was covalently conjugated with maleimide-functionalized heparin. The conjugate retains the negative charge of heparin and can be directly immobilized on the surface of positively charged poly-L-lysine. This specific reaction to the carboxyl group of heparin could potentially reduce the shedding and steric hindrance effects of REDV peptide and enhancing the affinity and selectivity of heparin for EC.
在血液接触装置表面形成内皮细胞(EC)单层是改善其血液相容性的理想方法,这一过程被称为内皮化。肝素是一种带强负电荷的蛋白多糖,是一种常用的抗血栓剂。肝素涂层也已成功地用于改善各种生物材料的血液相容性。在这项研究中,一种对内皮细胞具有特异性亲和力的短肽Arg-Glu-Asp-Val (REDV)与马来酰亚胺功能化肝素共价偶联。该缀合物保留了肝素的负电荷,可以直接固定在带正电荷的聚l -赖氨酸表面。这种对肝素羧基的特异性反应可能会降低REDV肽的脱落和位阻作用,增强肝素对EC的亲和力和选择性。
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引用次数: 0
Enhancement of Band Gap Energy and Crystallinity of Cu-MOFs due to Doping of Nano Metal Oxide 纳米金属氧化物对Cu-MOFs带隙能和结晶度的增强
Pub Date : 2022-08-25 DOI: 10.4028/p-f9yx5h
Maalathi Challa, M. Ambika, S. Usharani, B. Yallur, V. Adimule
Amorphous metal organic frame work (MOF) with copper was a newly synthesized Cu-MOF which has been converted into a crystalline Cu-MOF with addition of nanometal oxide due to assembling of nanometal oxide on Cu-MOF/nanocomposite. The band gap of Cu-MOF/Ag2O and Cu-MOF/rGO has enhanced from visible light harvesting compound to near and far UV light harvesting material due to quantum size effect and can be used as coating material on appliances working under UV light without any degradation.
铜非晶金属有机骨架(MOF)是一种新合成的Cu-MOF,加入纳米金属氧化物后,由于纳米金属氧化物在Cu-MOF/纳米复合材料上的组装而转化为结晶型Cu-MOF。由于量子尺寸效应,Cu-MOF/Ag2O和Cu-MOF/rGO的带隙从可见光捕获化合物增强为近紫外和远紫外捕获材料,可以作为在紫外光下工作的器具的涂层材料而不降解。
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引用次数: 6
Effect of Process Parameters on Properties of Titanium Alloy during Thermal Simulation Deformation 热模拟变形过程中工艺参数对钛合金性能的影响
Pub Date : 2022-08-25 DOI: 10.4028/p-d52w5v
J. Tang, Cui Liang, Chenkun Xu, J. Li
In this paper, aiming at the heat resistance and thermal deformation process of titanium matrix composites 0 vol.%, 2.5.vol.%, 5.vol.%. Thermal simulation experiment of titanium matrix composites with different (TiB+TiC) strengthening phase content. The measurement accuracy of material displacement is 0.01 mm. The compression is 70%, and the strain rate is 0.1 mm/s and 0.01 mm/s respectively. Compression tests at different strain rates and temperatures were carried out. The experimental results show that when the (TiB+TiC) 5vol% titanium composite is deformed at 0.01mm/s low strain rate, the peak stresses corresponding to 25°C, 250°C,350 °C and 500°C are increased to 1096MPa, 835MPa, 646MPa and 416MPa respectively. Under the condition of high strain rate of 0.1mm/s, the peak stresses corresponding to 25 °C, 250 °C, 350 °C and 500 °C are increased to 1230 MPa, 896 MPa, 723 MPa and 471 MPa respectively. The deformation law of stress rheological curve is roughly the same, and the high temperature zone has good plastic deformation ability. The titanium matrix composite has high compression rheological mechanical properties and good high-temperature plastic deformation ability. It is the preferred material component for the preparation of titanium matrix composite and powder forging.
本文针对0 vol.%, 2.5 vol.%钛基复合材料的耐热性和热变形过程进行了研究。%, 5. vol. %。不同(TiB+TiC)强化相含量的钛基复合材料热模拟实验。材料位移测量精度为0.01 mm。压缩率为70%,应变速率分别为0.1 mm/s和0.01 mm/s。进行了不同应变速率和温度下的压缩试验。实验结果表明,当(TiB+TiC) 5vol%钛复合材料以0.01mm/s的低应变速率变形时,25℃、250℃、350℃和500℃对应的峰值应力分别提高到1096MPa、835MPa、646MPa和416MPa。在高应变速率为0.1mm/s的条件下,25℃、250℃、350℃和500℃对应的峰值应力分别增加到1230 MPa、896 MPa、723 MPa和471 MPa。应力流变曲线的变形规律大致相同,高温区具有良好的塑性变形能力。钛基复合材料具有较高的压缩流变力学性能和良好的高温塑性变形能力。是制备钛基复合材料和粉末锻造的首选材料组分。
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引用次数: 0
Fly Ash Epoxy Composites with Superior Fire Retardant Properties 具有优异阻燃性能的粉煤灰环氧复合材料
Pub Date : 2022-06-06 DOI: 10.4028/p-hfbu93
G.K. Mahadeva Raju, C. Srikanth, G. Madhu, Dinesh P. Shankar Reddy, K. Karthik
Epoxy was loaded with varying concentrations of fly ash and was characterized for its structural properties using XRD and SEM. The XRD results revealed reduction of crystallinity with increase in filler content indicating that the composites are semi crystalline in nature. The SEM images showed that at lower concentration of filler content, fly ash is uniformly distributed within the epoxy and at higher concentrations of fly ash, agglomerates were observed. Mechanical properties such as tensile and compressive properties were estimated and the results showed that, the composites exhibit enhanced tensile strength and compressive strength for epoxy with 20 wt% fly ash. Flammable properties such as heat release rate, peak heat release rate, time to ignition, CO and CO2 yields are estimated and reported. Decrease in combustion time, peak heat release rate, time to ignition, CO and CO2 yields with increase in filler content clearly indicates the superior flammability performance of epoxy composites loaded with fly ash.
用不同浓度的粉煤灰对环氧树脂进行负载,并用XRD和SEM对其结构性能进行表征。XRD结果表明,随着填料含量的增加,复合材料的结晶度降低,表明复合材料具有半结晶性质。扫描电镜结果表明,填料含量较低时,粉煤灰在环氧树脂内均匀分布,粉煤灰含量较高时,粉煤灰在环氧树脂内出现团聚现象。对复合材料的拉伸、压缩等力学性能进行了测试,结果表明,当粉煤灰含量为20%时,复合材料的抗拉强度和抗压强度均有所提高。易燃性能,如热释放率,峰值热释放率,点火时间,CO和CO2产率进行估计和报告。随着填料含量的增加,燃烧时间、峰值放热率、着火时间、CO和CO2产率均有所降低,这表明掺加粉煤灰的环氧复合材料具有较好的可燃性。
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引用次数: 1
The Effect of Alkaline Concentration and Curing Temperature on the Durability of Fly Ash Geopolymer Mortar 碱性浓度和养护温度对粉煤灰地聚合物砂浆耐久性的影响
Pub Date : 2022-06-06 DOI: 10.4028/p-ceit32
Abel Woldu Ourgessa, Aseged Tebeje Tasew, Rahel Alemu Hafa
In this study, fly ash was used to synthesize geopolymer mortar by using an activating solution prepared from a different concentration of NaOH and a highly viscous Na-silicate. The NaOH concentration prepared were 8M, 12M, and 14M. The prepared geopolymers were cured at different temperatures (ambient, 40°C, and 60°C) and were studied to determine their strength, bond structure, mechanical properties, and resistance in an acidic and salty environment using an accelerated durability test. FTIR results showed distinctive peaks of aluminosilicate bond structures. Maximum strength was achieved for 14M samples cured at room temperature. Higher alkalinity resulted in higher compressive and flexural strength and lower water absorption. Lower water absorption capacity and higher resistance to the extreme environment were achieved for samples cured at higher temperatures and higher molarities. The maximum mass loss was 10.9% for 8M cured at ambient temperature exposed to an acidic environment.
本研究以粉煤灰为原料,用不同浓度的NaOH和高粘性的na -硅酸盐配制成活化溶液,合成地聚合物砂浆。制备的NaOH浓度分别为8M、12M和14M。制备的地聚合物在不同温度(环境温度、40℃和60℃)下固化,并通过加速耐久性试验来确定其强度、粘结结构、机械性能以及在酸性和咸味环境下的耐受性。FTIR结果显示铝硅酸盐键结构有明显的峰。在室温下固化14M样品达到最大强度。碱度越高,抗压和抗折强度越高,吸水率越低。在较高温度和较高摩尔浓度下固化的样品具有较低的吸水能力和较高的抗极端环境能力。常温固化8M,暴露于酸性环境中,最大质量损失为10.9%。
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引用次数: 0
Review: Advantages of Repairing Machine Parts in Order to Restore their Functionality 回顾:修理机器零件以恢复其功能的优点
Pub Date : 2022-06-06 DOI: 10.4028/p-394qc2
D. Tanasković, M. Aranđelović, B. Đorđević, S. Sedmak
This paper covers the literature review of the work by author, who have been involved in the subject of machine element repairing from the techno-economical point of view. Positive aspects of repairing, as opposed to purchasing new parts are shown and discussed. All of the examples given as part of the literature review are related to real, practical problems. It was concluded in all cases, that the repairing of damaged parts was the better option, since not only did it cost significantly less, it also noticeably decreased the equipment downtime, as there was no need to wait for the new part to be delivered.
本文从技术经济的角度对笔者所从事的机械零件维修工作进行了文献综述。展示并讨论了维修的积极方面,而不是购买新零件。作为文献综述的一部分,所有给出的例子都与真实的实际问题有关。在所有情况下得出的结论是,修理损坏的部件是更好的选择,因为它不仅成本大大降低,而且还显著减少了设备停机时间,因为不需要等待新部件交付。
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引用次数: 0
ISIM Achievements Regarding Friction Stir Welding in Inert Gas Environment ISIM在惰性气体环境下搅拌摩擦焊的研究成果
Pub Date : 2022-06-06 DOI: 10.4028/p-wr0f72
L. Boțilă, R. Cojocaru
Friction stir welding (FSW) is an important research direction within ISIM Timisoara. Also within ISIM Timisoara, in addition to the classic FSW welding, processes and methods derived from FSW were also approached. Those processes and methods include friction stir processing (FSP), coatings with functional layers by friction, conventional friction riveting and friction riveting with hybrid effect, hybrid welding methods: TIG assisted friction stir welding FSW-TIG and ultrasonic assisted friction stir welding FSW-US. Recent research were focused on a new method of applying the FSW process, namely friction stir welding in inert gas environment (FSW-IG). Results obtained by ISIM in the field of FSW-IG welding are presented: data / information on solutions for applying inert gas in the welding area, as well as experimental results obtained for FSW-IG welding of DD13 steel, Cu99 copper and AZ31B magnesium alloy respectively. The solutions for providing shielding gas in the welding area were analyzed, verified and validated by experiment. The experimental welding programs generated the necessary data for the development of the FSW-IG welding technologies for the approached materials. By applying FSW-IG welding there was an improvement in the aspect of the welded joints and for some of mechanical characteristics (as the case may be) compared to the application of classic FSW welding. The use of shielding gas also had beneficial effects on the service life of FSW tools.
搅拌摩擦焊(FSW)是ISIM的重要研究方向。此外,在ISIM Timisoara内部,除了经典的FSW焊接外,还探讨了FSW衍生的工艺和方法。这些工艺和方法包括搅拌摩擦加工(FSP),摩擦功能层涂层,传统摩擦铆接和混合效果摩擦铆接,混合焊接方法:TIG辅助搅拌摩擦焊FSW-TIG和超声波辅助搅拌摩擦焊FSW-US。近年来研究的热点是搅拌摩擦焊技术的一种新应用方法,即惰性气体环境下的搅拌摩擦焊。介绍了ISIM在FSW-IG焊接领域取得的成果:在焊接区域应用惰性气体解决方案的数据/信息,以及DD13钢、Cu99铜和AZ31B镁合金FSW-IG焊接的实验结果。对焊接区域提供保护气体的解决方案进行了分析、验证和实验验证。实验焊接程序为所接近材料的FSW-IG焊接技术的发展提供了必要的数据。通过应用FSW- ig焊接,与传统FSW焊接相比,焊接接头和一些机械特性(视情况而定)得到了改善。保护气体的使用对FSW工具的使用寿命也有有益的影响。
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引用次数: 0
New Results Regarding the Cavitation Destruction Behavior of Heat-Treated CuZn39Pb3 Brass with Different Parameters 热处理CuZn39Pb3黄铜不同参数空化破坏行为的新结果
Pub Date : 2022-06-06 DOI: 10.4028/p-462v06
C. Ghera, I. Lazăr, Daniela Alexa, I. Bordeasu, N. Sîrbu, D. Ostoia, M. Hluscu, C. L. Sălcianu, D. Stroita, Dumitru Viorel Bazavan, M. Sava, L. Micu
Among other parts made of brass there are also the blades and the rotors of the hydraulic machines, respectively ship propellers, which during operation are degraded by cavitation erosion. As a result, most of the researches, including the most recent ones, are focused on the morphological analysis of structures eroded under the impact of micro-jets and shock waves, produced by cavitation hydrodynamics. The goal is to create new materials, but also to use new treatment technologies to increase cavitation resistance. As the literature is quite poor in studies related to the materials resistance to cavitation erosion, respectively treatments and technological procedures of it’s improvement, this paper presents the research results on the behavior of vibration cavitation erosion, carried out on three sets of CuZn39Pb3 brass samples, subjected to volumetric heat treatments of hardening for putting in solution at 800°C, followed by tempering at 250°C, 400°C and 600°C. The characterization of the behavior and the cavitation resistance of the structures resulting from the applied heat treatments is performed based on macroscopic images, taken at different representative periods, SEM images at the end of the test duration and values of specific parameters recommended by ASTM G32-2016. The analysis highlights the differences caused by the change in structure by varying the temperature, but also the hardness of the surface exposed to the cavity. Thus, of the three treatments, it is found that the best resistance to cavitation is conferred by the structure resulting from hardening at 800°C, with tempering at 250°C.
在其他由黄铜制成的部件中,还有液压机的叶片和转子,分别是船舶螺旋桨,它们在运行过程中因空化侵蚀而退化。因此,大多数研究,包括最近的研究,都集中在由空化流体力学产生的微射流和冲击波作用下的结构形态分析上。目标是创造新材料,同时也使用新的处理技术来增加空化阻力。由于文献中对材料抗空化侵蚀性能的研究较少,分别针对其改善的处理方法和工艺流程,本文对三组CuZn39Pb3黄铜试样进行了振动空化侵蚀行为的研究,分别对试样进行了800℃固溶淬火、250℃、400℃、600℃回火的体积热处理。根据不同代表性时期的宏观图像、测试结束时的SEM图像和ASTM G32-2016推荐的特定参数值,对热处理产生的结构的行为和抗空化性能进行表征。分析强调了温度变化引起的结构变化,以及暴露在空腔中的表面硬度的差异。因此,在三种处理中,发现800°C淬火和250°C回火所产生的组织具有最佳的抗空化性。
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引用次数: 0
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Advanced Materials Research
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