Fariz Risqi Maulana, N. Fadhilah, Ruri Agung Wahyuono, D. Risanti
Aluminium-water reaction is one of the most promising ways to produce clean and economical hydrogen. In this study, the effect of the waste Aluminium foil AA1235 thickness on Aluminium-water reaction process was investigated. The thickness of aluminum used are 6.5 m, 11.5 m and 19.5 m. Aluminum foil was cut by size 20 mm x 30 mm in each thickness variation. The 0.4 M NaOH and 0.01 M NaAlO2 was added as promoter on the process. The initial composition of the aluminum and the dislocations in the aluminum are also considered. The experimental results was evaluated by the mass reduction and shrinking core models. The initial composition of the aluminum and the dislocations in the aluminum are also considered. The experimental results were evaluated by the mass reduction and shrinking core models. The results obtained that aluminum with thinner thickness can be approximated by the 1-dimensional slab shrinking core model. Aluminum with a thicker thickness can be approached with a mass reduction model. It is also found out that smaller thickness has larger dislocation and better effects of NaAlO2 resulting higher yield of hydrogen production.
铝水反应是一种极具发展前景的清洁经济制氢方法。研究了废铝箔AA1235厚度对铝-水反应过程的影响。所用铝的厚度分别为6.5 m、11.5 m和19.5 m。铝箔在每个厚度变化中按20毫米× 30毫米的尺寸切割。在此过程中加入0.4 M NaOH和0.01 M NaAlO2作为促进剂。还考虑了铝的初始成分和铝中的位错。用质量缩减模型和缩核模型对实验结果进行了评价。还考虑了铝的初始成分和铝中的位错。用质量缩减模型和缩芯模型对实验结果进行了评价。研究结果表明，较薄厚度的铝可以用一维板缩芯模型进行近似。厚度较厚的铝可以用质量减少模型来处理。同时发现，厚度越小，位错越大，NaAlO2的效果越好，产氢率越高。
{"title":"Hydrogen Production from Waste Aluminum Foil AA1235 Using the Aluminum-Water Reaction Method with Thickness Variations","authors":"Fariz Risqi Maulana, N. Fadhilah, Ruri Agung Wahyuono, D. Risanti","doi":"10.4028/p-587vv6","DOIUrl":"https://doi.org/10.4028/p-587vv6","url":null,"abstract":"Aluminium-water reaction is one of the most promising ways to produce clean and economical hydrogen. In this study, the effect of the waste Aluminium foil AA1235 thickness on Aluminium-water reaction process was investigated. The thickness of aluminum used are 6.5 m, 11.5 m and 19.5 m. Aluminum foil was cut by size 20 mm x 30 mm in each thickness variation. The 0.4 M NaOH and 0.01 M NaAlO2 was added as promoter on the process. The initial composition of the aluminum and the dislocations in the aluminum are also considered. The experimental results was evaluated by the mass reduction and shrinking core models. The initial composition of the aluminum and the dislocations in the aluminum are also considered. The experimental results were evaluated by the mass reduction and shrinking core models. The results obtained that aluminum with thinner thickness can be approximated by the 1-dimensional slab shrinking core model. Aluminum with a thicker thickness can be approached with a mass reduction model. It is also found out that smaller thickness has larger dislocation and better effects of NaAlO2 resulting higher yield of hydrogen production.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"39 1","pages":"9 - 15"},"PeriodicalIF":0.0,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76927685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Maharat Huseynov, S. Tapdiqov, Fariz Ahmad, Sevda Kazimova
The quality of gel - based silicon, which forms an insulating content to prevent water and sand in oil and gas wells, have been improved. Based on the reaction between the liquid glass and hydrochloric acid, the optimal concentration of the initial reagents for the formation of the gel process was determined. The rheology, initial and final setting time of the silicon based gel, and the temperature dependencies of the gel forming process were also studied by adding 0.1-1.0% (mass ratio) of urea as cross-linking to the Na2SiO3/HCl solution. At the same time, the impact of the obtained gel of the permeability of the rock pores was determined and the filtration characteristics were studied. It has been determined that with 0.1-0.8% mass concentration of the urea added to the Na2SiO3/HCl solution, the setting time of the gel could be regulated according to the well-layer regime. The resulting silicone-based gel can be used as an injection solution that can set in 3-22 hours in oil and gas wells between the temperature of 20-80 °C.
{"title":"Sılıcon Based Gel to Shut-Off of Water in the Well-Bore","authors":"Maharat Huseynov, S. Tapdiqov, Fariz Ahmad, Sevda Kazimova","doi":"10.4028/p-o15z58","DOIUrl":"https://doi.org/10.4028/p-o15z58","url":null,"abstract":"The quality of gel - based silicon, which forms an insulating content to prevent water and sand in oil and gas wells, have been improved. Based on the reaction between the liquid glass and hydrochloric acid, the optimal concentration of the initial reagents for the formation of the gel process was determined. The rheology, initial and final setting time of the silicon based gel, and the temperature dependencies of the gel forming process were also studied by adding 0.1-1.0% (mass ratio) of urea as cross-linking to the Na2SiO3/HCl solution. At the same time, the impact of the obtained gel of the permeability of the rock pores was determined and the filtration characteristics were studied. It has been determined that with 0.1-0.8% mass concentration of the urea added to the Na2SiO3/HCl solution, the setting time of the gel could be regulated according to the well-layer regime. The resulting silicone-based gel can be used as an injection solution that can set in 3-22 hours in oil and gas wells between the temperature of 20-80 °C.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"22 1","pages":"27 - 34"},"PeriodicalIF":0.0,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78674512","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this study, sheet-like MnO2/ZnO microflower (MnO2/ZnO) loaded on cotton fabric was prepared via a facile reflux-thermal deposition combined technique. The coated fabric and as-fabricated particles were analyzed through numerous characterization techniques including field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), tensile strength, Ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS) as well as photoluminescence (PL) measurements. The optical trait of the ZnO was significantly improved by the addition of MnO2 that extended reflectance edges in the visible light region. The treated cotton fabric greatly inhibited the growth of Escherichia Coli bacteria and Aspergillus Niger fungi as testified by the zone of inhibition surrounding the fabric samples. The self-cleaning outcomes also demonstrated that 3% MnO2/ZnO/fabric presented highest visible light photodegradation of phenol among the samples. The promising performance of the cotton fabric coated by MnO2/ZnO composite was related to the reactive oxygen species produced by the heterojunction photocatalytic mechanism under exposure of visible light.
{"title":"Boosted Antimicrobial and Self-Cleaning Activities with MnO2/ ZnO Coated on Cotton Fabric","authors":"S. Lam, Chiew Lin Lim, J. Sin, H. Zeng","doi":"10.4028/p-j00692","DOIUrl":"https://doi.org/10.4028/p-j00692","url":null,"abstract":"In this study, sheet-like MnO2/ZnO microflower (MnO2/ZnO) loaded on cotton fabric was prepared via a facile reflux-thermal deposition combined technique. The coated fabric and as-fabricated particles were analyzed through numerous characterization techniques including field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), tensile strength, Ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS) as well as photoluminescence (PL) measurements. The optical trait of the ZnO was significantly improved by the addition of MnO2 that extended reflectance edges in the visible light region. The treated cotton fabric greatly inhibited the growth of Escherichia Coli bacteria and Aspergillus Niger fungi as testified by the zone of inhibition surrounding the fabric samples. The self-cleaning outcomes also demonstrated that 3% MnO2/ZnO/fabric presented highest visible light photodegradation of phenol among the samples. The promising performance of the cotton fabric coated by MnO2/ZnO composite was related to the reactive oxygen species produced by the heterojunction photocatalytic mechanism under exposure of visible light.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"10 1","pages":"89 - 95"},"PeriodicalIF":0.0,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78547653","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Increasing the demand to explore the nanomaterials properties to be used in numerous applications have emerged considerable effort to developing synthesis methods. Herein, Tin oxide (SnO2) nanosheets have been prepared by a facile one step hydrothermal method using Teflon-lined steel at synthesis temperature of 120 C for 12 hours. As synthesis material were characterized by Field emission scanning electron microscopy (FESEM) and x-ray diffraction (XRD) to revealing the morphology and structural properties. As a result, SnO2 nanosheets have been obtained with thickness around 15 nm with a clear sheets morphology. XRD pattern showed one phase structural with absence of impurities phases. Optical properties for nanosheets suspended in ethanol were investigated using steady state photoluminescence and UV-Vis absorption technics. The result showed four peaks centered at 380 nm, 445 nm, 475 nm, and 500 nm related to near band to band emission and defects states. Keywords: SnO2, Nanosheets, hydrothermal, XRD
{"title":"Hydrothermal Synthesis and Characterization of SnO2 Nanosheets","authors":"J. Hassan","doi":"10.4028/p-i74stb","DOIUrl":"https://doi.org/10.4028/p-i74stb","url":null,"abstract":"Increasing the demand to explore the nanomaterials properties to be used in numerous applications have emerged considerable effort to developing synthesis methods. Herein, Tin oxide (SnO2) nanosheets have been prepared by a facile one step hydrothermal method using Teflon-lined steel at synthesis temperature of 120 C for 12 hours. As synthesis material were characterized by Field emission scanning electron microscopy (FESEM) and x-ray diffraction (XRD) to revealing the morphology and structural properties. As a result, SnO2 nanosheets have been obtained with thickness around 15 nm with a clear sheets morphology. XRD pattern showed one phase structural with absence of impurities phases. Optical properties for nanosheets suspended in ethanol were investigated using steady state photoluminescence and UV-Vis absorption technics. The result showed four peaks centered at 380 nm, 445 nm, 475 nm, and 500 nm related to near band to band emission and defects states. Keywords: SnO2, Nanosheets, hydrothermal, XRD","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"43 1","pages":"47 - 53"},"PeriodicalIF":0.0,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84088604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Forging tools must be able to withstand very strong mechanical, thermal, tribological, and chemical stresses. The extent to which a tool can withstand these stresses depends on the material used and its pre-treatment as well as the heat and surface treatment, i.e. the load capacity. The ratio of stress to load capacity determines how high the tool life of a forging tool is. This paper deals with the variations in the tool life of forging tools using the example of a specific industrial stage sequence and production conditions. Due to a large number of influencing variables that have an effect on the tool during the entire tool life history, the focus of this work is placed on influencing variables of the forming process. Based on real production parameters of a forging company, which are recorded during a period for the investigation, the process data are analyzed about an influence on the tool life. The investigation focuses on four influencing variables, namely the subjective assessment of the end of the tool life, the interaction between the forming stages, production interruptions, and the cooling and lubrication of the forming tools. For the parameters that are not yet recorded during the trials, promising available measurement methods are identified and tested under laboratory conditions. One example of this is the recording of the actual spray quantities that are sprayed onto the tool surface before the forming process. The results of the investigations show that the tool life fluctuations can be reduced by about 16% and as a consequence, the average tool life can be increased by about 13%.
{"title":"Investigation of Forging Tools on the Basis of Subjective Assessment of Tool Life","authors":"Abdulkerim Karaman, Rainer Labs, M. Marré","doi":"10.4028/p-8fhf95","DOIUrl":"https://doi.org/10.4028/p-8fhf95","url":null,"abstract":"Forging tools must be able to withstand very strong mechanical, thermal, tribological, and chemical stresses. The extent to which a tool can withstand these stresses depends on the material used and its pre-treatment as well as the heat and surface treatment, i.e. the load capacity. The ratio of stress to load capacity determines how high the tool life of a forging tool is. This paper deals with the variations in the tool life of forging tools using the example of a specific industrial stage sequence and production conditions. Due to a large number of influencing variables that have an effect on the tool during the entire tool life history, the focus of this work is placed on influencing variables of the forming process. Based on real production parameters of a forging company, which are recorded during a period for the investigation, the process data are analyzed about an influence on the tool life. The investigation focuses on four influencing variables, namely the subjective assessment of the end of the tool life, the interaction between the forming stages, production interruptions, and the cooling and lubrication of the forming tools. For the parameters that are not yet recorded during the trials, promising available measurement methods are identified and tested under laboratory conditions. One example of this is the recording of the actual spray quantities that are sprayed onto the tool surface before the forming process. The results of the investigations show that the tool life fluctuations can be reduced by about 16% and as a consequence, the average tool life can be increased by about 13%.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"81 1","pages":"123 - 136"},"PeriodicalIF":0.0,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74567609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Modifying asphalt mixtures with recycled components is common practice due to their environmental and economic merits. However, due to the oxidized air-blown asphalt binders in recycled asphalt shingles (RAS) and aged binders in reclaimed asphalt pavement (RAP), adopting RAP and/or RAS as recycled components in asphalt mixtures influences the performance of the overall asphalt binder in these mixtures. The percentages of recycled components and performance grade (PG) of virgin asphalt binders (VABs) in the asphalt mixtures govern the performance of the overall asphalt binder. Therefore, the main idea of this study was to investigate the effect of the percentages of RAP/RAS and PGs of the VABs on the load- and non-load-associated cracking resistance of the extracted asphalt binders (EABs) from field cores. Rheological tests were performed on the EABs to assess the load-associated cracking (fatigue cracking) and non-load-associated cracking (low-temperature and block cracking) resistance. The VAB's PGs, mixtures' ages, and the percentages of RAP/RAS affected the EABs' cracking resistance. When compared to EABs from mixtures with lower amounts of RAP, employing RAS in the asphaltic mixtures improved EABs' resistance to fatigue and block cracking. However, using RAS deteriorated EABs' resistance to low-temperature cracking. Increasing the RAP's percentage in the asphaltic mixtures decreased the cracking resistance of the EABs. Strong relationships were established between EABs' load- and non-load-associated cracking resistance.
{"title":"Performance Evaluation of Extracted Asphalt Binders from Field Cores Containing Recycled Components: Load- and Non-Load-Associated Cracking Resistance","authors":"Eslam Deef-Allah, M. Abdelrahman","doi":"10.4028/p-2bdlta","DOIUrl":"https://doi.org/10.4028/p-2bdlta","url":null,"abstract":"Modifying asphalt mixtures with recycled components is common practice due to their environmental and economic merits. However, due to the oxidized air-blown asphalt binders in recycled asphalt shingles (RAS) and aged binders in reclaimed asphalt pavement (RAP), adopting RAP and/or RAS as recycled components in asphalt mixtures influences the performance of the overall asphalt binder in these mixtures. The percentages of recycled components and performance grade (PG) of virgin asphalt binders (VABs) in the asphalt mixtures govern the performance of the overall asphalt binder. Therefore, the main idea of this study was to investigate the effect of the percentages of RAP/RAS and PGs of the VABs on the load- and non-load-associated cracking resistance of the extracted asphalt binders (EABs) from field cores. Rheological tests were performed on the EABs to assess the load-associated cracking (fatigue cracking) and non-load-associated cracking (low-temperature and block cracking) resistance. The VAB's PGs, mixtures' ages, and the percentages of RAP/RAS affected the EABs' cracking resistance. When compared to EABs from mixtures with lower amounts of RAP, employing RAS in the asphaltic mixtures improved EABs' resistance to fatigue and block cracking. However, using RAS deteriorated EABs' resistance to low-temperature cracking. Increasing the RAP's percentage in the asphaltic mixtures decreased the cracking resistance of the EABs. Strong relationships were established between EABs' load- and non-load-associated cracking resistance.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"12 1","pages":"149 - 170"},"PeriodicalIF":0.0,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81517944","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Figarova, E. Aliyev, Reshad Abaszade, V. R. Figarov
The sulfur content present in graphene oxide prepared by Hummers' method has only been addressed by few papers so far. By modified Hammers method we synthesized thermally stable in ambient environment multilayer sulphur-doped graphene oxide. The samples were heat treated in an electrical furnace setup at different ambient temperatures and their crystallite size and linear coefficient of thermal expansion were extracted from Raman band intensity peak ratio as a function of temperature. We found unusually large (in comparison with graphene oxide) contraction on heating of multilayer two weight percent sulphur-doped graphene oxide with carbon to oxygen ratio of 2.3 in a narrow temperature range (308-318 K) with the lowest value of the linear thermal expansion coefficient of -18 ppm 1/K. Based upon an examination of the synthesized sulphur-doped graphene diffractograms, it is suggested that negative thermal expansion stems from the phonon backscattering by the sulphur impurity sites and the edges of the layers. The obtained experimental results have potential practical applications for fabrication of solar cells, sensors, lubricators, thermal actuators and also wavelike (second sound) thermal transport structures.
{"title":"Negative Thermal Expansion of Sulphur-Doped Graphene Oxide","authors":"S. Figarova, E. Aliyev, Reshad Abaszade, V. R. Figarov","doi":"10.4028/p-rppn12","DOIUrl":"https://doi.org/10.4028/p-rppn12","url":null,"abstract":"The sulfur content present in graphene oxide prepared by Hummers' method has only been addressed by few papers so far. By modified Hammers method we synthesized thermally stable in ambient environment multilayer sulphur-doped graphene oxide. The samples were heat treated in an electrical furnace setup at different ambient temperatures and their crystallite size and linear coefficient of thermal expansion were extracted from Raman band intensity peak ratio as a function of temperature. We found unusually large (in comparison with graphene oxide) contraction on heating of multilayer two weight percent sulphur-doped graphene oxide with carbon to oxygen ratio of 2.3 in a narrow temperature range (308-318 K) with the lowest value of the linear thermal expansion coefficient of -18 ppm 1/K. Based upon an examination of the synthesized sulphur-doped graphene diffractograms, it is suggested that negative thermal expansion stems from the phonon backscattering by the sulphur impurity sites and the edges of the layers. The obtained experimental results have potential practical applications for fabrication of solar cells, sensors, lubricators, thermal actuators and also wavelike (second sound) thermal transport structures.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"63 1","pages":"55 - 62"},"PeriodicalIF":0.0,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87007609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Concrete is one of the most used construction materials worldwide. It is known to be a strong and durable material at a reasonable price. The most well-known problem in concrete is the cracks, which affect the service life of the concrete structures and leads to consumes higher costs through maintenance. Cracks allow penetrating any ions into the concrete resulting in other big problems such as corrosion of steel reinforcement, sulphate attack, carbonation, alkali-aggregate reaction, etc. It is impossible to prevent the formation of cracks, therefore they can be controlled or repaired using a variety of methods. Nowadays, self-healing is one of the widely recognized techniques to improve concrete's long-term durability. Healing agents such as bacteria, chemical compounds, and polymers are utilized. In this method, with the help of a healing agent, the cracks start to heal autonomously during crack formation. Since Bacteria is the most used material for healing concrete, self-healing concrete is also known as bacterial-concrete or bioconcrete. This article provides an overview of self-healing concrete including describing the system, process, durability, and mechanical properties of healed concrete.
{"title":"A Review on Self-Healing Concrete","authors":"D. K. Jaf, Payam Ismael Abdulrahman","doi":"10.4028/p-52lej6","DOIUrl":"https://doi.org/10.4028/p-52lej6","url":null,"abstract":"Concrete is one of the most used construction materials worldwide. It is known to be a strong and durable material at a reasonable price. The most well-known problem in concrete is the cracks, which affect the service life of the concrete structures and leads to consumes higher costs through maintenance. Cracks allow penetrating any ions into the concrete resulting in other big problems such as corrosion of steel reinforcement, sulphate attack, carbonation, alkali-aggregate reaction, etc. It is impossible to prevent the formation of cracks, therefore they can be controlled or repaired using a variety of methods. Nowadays, self-healing is one of the widely recognized techniques to improve concrete's long-term durability. Healing agents such as bacteria, chemical compounds, and polymers are utilized. In this method, with the help of a healing agent, the cracks start to heal autonomously during crack formation. Since Bacteria is the most used material for healing concrete, self-healing concrete is also known as bacterial-concrete or bioconcrete. This article provides an overview of self-healing concrete including describing the system, process, durability, and mechanical properties of healed concrete.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"183 1","pages":"139 - 148"},"PeriodicalIF":0.0,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74619877","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The cutting fluid plays a significant role in minimizing heat generation and chip removal process during the machining of materials, hence improving tool life and surface finish of the workpiece. Many researchers have focused on minimum quantity lubrication (MQL) among the existing methods on the application of the coolant as it reduces the usage of coolant by spurting a mixture of compressed air and cutting fluid in an improved way instead of flood cooling. The MQL method has demonstrated to be appropriate as it fulfills the necessities of ‘green’ machining. Additionally, considering current environmental issues and provisions for safe healthy working conditions at the workplace, it is important to divert machining processes towards an eco-friendly path. Hence, the focus of research has been shifted to MQL using eco-friendly lubricants for green and sustainable manufacturing processes. In this review paper, the effect of different vegetable oil-based biodegradable coolants like castor oil, coconut oil, palm oil, etc. for different machining process parameters like cutting force, cutting temperature, surface finish, tool wear, etc. has been reviewed. It is observed that proper selection of cutting parameters along with lubricant through MQL can provide enhanced machinability to get desired outputs.
{"title":"A Review on the Effect of Minimum Quantity Lubrication on Different Machining Parameters Emphasizing Vegetable Oil-Based Lubricants for Sustainable Manufacturing","authors":"Sheth Pushpak Chandrakant, B. K. Patel","doi":"10.4028/p-325298","DOIUrl":"https://doi.org/10.4028/p-325298","url":null,"abstract":"The cutting fluid plays a significant role in minimizing heat generation and chip removal process during the machining of materials, hence improving tool life and surface finish of the workpiece. Many researchers have focused on minimum quantity lubrication (MQL) among the existing methods on the application of the coolant as it reduces the usage of coolant by spurting a mixture of compressed air and cutting fluid in an improved way instead of flood cooling. The MQL method has demonstrated to be appropriate as it fulfills the necessities of ‘green’ machining. Additionally, considering current environmental issues and provisions for safe healthy working conditions at the workplace, it is important to divert machining processes towards an eco-friendly path. Hence, the focus of research has been shifted to MQL using eco-friendly lubricants for green and sustainable manufacturing processes. In this review paper, the effect of different vegetable oil-based biodegradable coolants like castor oil, coconut oil, palm oil, etc. for different machining process parameters like cutting force, cutting temperature, surface finish, tool wear, etc. has been reviewed. It is observed that proper selection of cutting parameters along with lubricant through MQL can provide enhanced machinability to get desired outputs.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"14 1","pages":"107 - 122"},"PeriodicalIF":0.0,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80059308","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A novel and convenient approach for the fabrication of vinyl functionalized multiwalled carbon nanotube (MWCNT) as a sorbent for organic pollutant is described in this article. In this method, the purified MWCNT is functionalized via a non-covalent strategy using 9-vinyl anthracene, fluorescent active species. The synthesised nanotube was characterised using various techniques such as Fourier transform infrared spectroscopy (FT-IR), UV-Vis. spectroscopic analysis, scanning electron microscopy (SEM), X-ray diffraction technique (XRD), thermogravimetric analysis (TGA), transmission electron microscopy (TEM) and Raman spectroscopy. Effects of concentration, pH and time for the functionalization of MWCNTs were investigated through photoluminescence (PL) studies. The resulting vinyl functionalized MWCNT will act as a promising adsorbent for organic pollutants like p-chlorobenzoic acid.
{"title":"Fabrication of Vinyl Functionalised Multiwalled Carbon Nanotubes for the Removal of Organic Pollutant","authors":"T.R. Sreelakshmi, T. Sajini, B. Mathew","doi":"10.4028/p-6422h6","DOIUrl":"https://doi.org/10.4028/p-6422h6","url":null,"abstract":"A novel and convenient approach for the fabrication of vinyl functionalized multiwalled carbon nanotube (MWCNT) as a sorbent for organic pollutant is described in this article. In this method, the purified MWCNT is functionalized via a non-covalent strategy using 9-vinyl anthracene, fluorescent active species. The synthesised nanotube was characterised using various techniques such as Fourier transform infrared spectroscopy (FT-IR), UV-Vis. spectroscopic analysis, scanning electron microscopy (SEM), X-ray diffraction technique (XRD), thermogravimetric analysis (TGA), transmission electron microscopy (TEM) and Raman spectroscopy. Effects of concentration, pH and time for the functionalization of MWCNTs were investigated through photoluminescence (PL) studies. The resulting vinyl functionalized MWCNT will act as a promising adsorbent for organic pollutants like p-chlorobenzoic acid.","PeriodicalId":7271,"journal":{"name":"Advanced Materials Research","volume":"4 1","pages":"63 - 72"},"PeriodicalIF":0.0,"publicationDate":"2023-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82204755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：