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Biodegradation of Evercion Blue P-GR and Ostazin Black H-GRN in synthetic textile wastewater by membrane bioreactor system using Trametes versicolor 膜生物反应器系统降解合成纺织废水中的Evercion Blue P-GR和Ostazin Black H-GRN
Pub Date : 2020-06-01 DOI: 10.12989/AER.2020.9.2.085
Ü. Gül, C. Acıkgoz, Kadir Özan
In this study, the decolorization of Evercion Blue P-GR (EBP) and Ostazin Black H-GRN (OBH) was investigated using white-rot fungi named as Trametes versicolor (T. versicolor) by Membrane Bioreactor (MBR) system. This study involved experiments employing synthetic textile wastewater in Membrane Bioreactor (MBR) system (170 ml), initially inoculated with a pure culture of fungi, but operated, other than controlling pH (4.5±0.2) and temperature (25±1oC), under non-sterile conditions. The effect of dye concentrations on fungal biodegradation was also investigated. The decolorization efficiencies were 98%, 90%, and 87% respectively, for EBP when the initial dye concentration of 50, 100, and 200 mg L-1 were used. However, the decolorization percentages for OBH dye were obtained 95% for 50 mg L-1 dye solution in 2 days and 66% for 100 mg L-1 dye solution in 5 days. Possible interactions between dye molecules and the fungal surface were confirmed by SEM, EDX, and FTIR analyses.
本研究采用膜生物反应器(MBR)系统研究了白腐真菌Trametes versicolor (T. versicolor)对Evercion Blue P-GR (EBP)和Ostazin Black H-GRN (OBH)的脱色效果。本研究采用合成纺织废水在膜生物反应器(MBR)系统(170 ml)中进行实验,最初接种纯培养的真菌,但除了控制pH(4.5±0.2)和温度(25±1oC)外,在非无菌条件下进行操作。研究了染料浓度对真菌生物降解的影响。当初始染料浓度为50、100和200 mg L-1时,EBP的脱色效率分别为98%、90%和87%。50 mg L-1染料溶液2天脱色率为95%,100 mg L-1染料溶液5天脱色率为66%。通过SEM、EDX和FTIR分析证实了染料分子与真菌表面可能存在的相互作用。
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引用次数: 0
Methane emission from municipal solid waste dumpsites: A case study of Chennai city in India 城市固体废物倾倒场甲烷排放:以印度金奈市为例
Pub Date : 2020-06-01 DOI: 10.12989/AER.2020.9.2.097
Pavithrapriya Srinivasan, R. Andimuthu, S. Ibrahim, Prasannavenkatesh Ramachandran, Easwari Rajkumar, P. Kandasamy
The indiscriminate growth in global population poses a threat to the world in handling and disposal of Municipal solid waste. Rapid urban growth increases the production, consumption and generation of Municipal solid waste which leads to a drastic change in the environment. The methane produced from the Municipal Solid waste accounts for up to 11% global anthropogenic emissions, which is a major cause for global warming. This study reports the methane emission estimation using IPCC default, TNO, LandGEM, EPER and close flux chamber from open dump yards at Perungudi and Kodungaiyur in Chennai, India. The result reveals that the methane emission using close flux chamber was in the range of 8.8 Gg/yr-11.3 Gg/yr and 6.1Gg/yr to 9.1 Gg/yr at Kodungaiyur and Perungudi dump yard respectively. The per capita waste generation was estimated based on waste generation and population. The waste generation potential was projected using linear regression model for the period 2017-2050. The trend of CH4 emission in the actual field measurement were increased every year, similarly the emission trend also increased in IPCC default method (mass balance approach), EPER Germany (zero order decay model) where as TNO and Land GEM (first order decay model) were decreased. The present study reveals that Kodungaiyur dump yard is more vulnerable to methane emission compared to Perungudi dump yard and has more potential in waste to energy conversion mechanisms than compare to Perungudi dump yard.
全球人口的无差别增长对世界城市固体废物的处理和处置构成了威胁。快速的城市增长增加了城市固体废物的生产、消费和产生,从而导致环境的急剧变化。城市固体废物产生的甲烷占全球人为排放量的11%,这是全球变暖的主要原因。本研究报告了利用IPCC默认值、TNO、LandGEM、EPER和封闭通量室对印度金奈Perungudi和Kodungaiyur露天垃圾场的甲烷排放进行估算。结果表明:封闭通量室的甲烷排放量分别为8.8 ~ 11.3 Gg/yr和6.1 ~ 9.1 Gg/yr。人均废物产生量是根据废物产生量和人口来估计的。利用线性回归模型预测了2017-2050年期间的废物产生潜力。实测CH4排放趋势呈逐年增加趋势,IPCC默认方法(质量平衡法)、德国EPER(零阶衰减模型)的CH4排放趋势也呈逐年增加趋势,TNO和Land GEM(一阶衰减模型)呈下降趋势。本研究表明,与Perungudi堆场相比,Kodungaiyur堆场更容易产生甲烷排放,并且在废物转化为能源的机制方面比Perungudi堆场更有潜力。
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引用次数: 3
Water quality of an Indian tributary affected by various industrial effluents- a case study 受各种工业污水影响的印度支流水质-个案研究
Pub Date : 2020-03-01 DOI: 10.12989/AER.2020.9.1.041
Bharti, J. S. Jangwan, Amrish Kumar, Vivek Kumar
Industrialization and urbanization are modern need and trends. Such trends affect the natural ecosystem of rivers. Indian rivers face such problems in a high ratio. The aim of this study is to investigate the cause and amount of pollution in a tributary river Krishni. Pre-monsoon sampling of Krishni river water was performed as per APHA standard. Water samples were collected from different sites of Krishni river. Physiochemical parameters as well as trace elements concentrations have been analysed and results were compared with BIS-2012, WHO-2017 and EPA-2001 recommendations. The presence of high BOD, COD, TDS and others physiochemical parameters along with heavy metals reveals that tributary is highly polluted owing to industrial and domestic discharge either directly or through drains. High values of these parameters are harmful for the ecological health of the river because it makes survival of aquatic flora and fauna at risk. On the basis of the results obtained by the present study, it was concluded that level of the pollution in river Krishni is at alarming phase, where if strong action for the rejuvenation of river not takes place, river becomes a dead pool.
工业化和城市化是现代的需要和趋势。这种趋势影响着河流的自然生态系统。印度河流面临这类问题的比例很高。本研究的目的是调查克里希尼河支流污染的原因和数量。根据APHA标准对克里希尼河水进行季风前采样。从克里希尼河的不同地点采集了水样。分析了理化参数和微量元素浓度,并将结果与BIS-2012、WHO-2017和EPA-2001的建议进行了比较。高BOD、COD、TDS和其他物理化学参数以及重金属的存在表明,由于工业和家庭直接或通过排水沟排放,支流受到严重污染。这些参数的高值对河流的生态健康是有害的,因为它使水生动植物的生存受到威胁。根据本研究得出的结论,克里希尼河的污染水平处于警戒阶段,如果不采取强有力的行动来恢复河流,河流将成为一个死池。
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引用次数: 4
Digestate residues analysis under elevated heat regime by using DNS method 高温条件下消化残渣的DNS分析
Pub Date : 2020-03-01 DOI: 10.12989/AER.2020.9.1.055
M. H. Hanif, M. A. Kamaruddin, F. A. Norashiddin, M. Zawawi
The problems with unsorted municipal waste are always associated with disposal issues as it requires a large area for landfilling or high energy used for incineration. In recent years, an autoclaving technique has been considered a promising approach which could minimize the volume of organic waste from being directly disposed or incinerated. In this work, an attempt was done to study the saccharification potential of organic residues under elevated temperature Thermal treatment involving hot water bath was applied to treat the organic residue ranging from 60oC to 100oC for 30 and 60 minutes. The result obtained showed an increasing trend for the concentration of glucose and carbohydrate. However, the result for lignocellulose content which contains various component includes extractive, holocellulose, hemicellulose, cellulose and lignin show variation. Based on the thermal treatment carried out, the result indicated that the trend of glucose and carbohydrate content. The highest percentage of glucose that can be obtained 978.602 µg/ml which could be obtained at 90oC at 60 minutes. The carbohydrate also shows an increasing trend with 0.234 mg/ml as the highest peak achieved at 80oC for 30 minutes treatment. However, it was found that the lignocellulose content varies with temperature and time. The statistical analysis was carried out using two-ways ANOVA shows an interaction effect between the independent variables (temperature and contact time) and the saccharification effects on the food wastes. The result shows a variation in the significant effect of independent variables on the changes in the composition of food waste.
未分类的城市废物的问题总是与处置问题有关,因为它需要大面积的填埋或焚烧消耗大量的能源。近年来,高压灭菌技术被认为是一种很有前途的方法,可以最大限度地减少直接处理或焚烧有机废物的体积。采用热水浴法对60℃~ 100℃范围内的有机残渣进行热处理,处理时间分别为30和60分钟。结果表明,葡萄糖和碳水化合物浓度呈上升趋势。但是,不同组分的木质素纤维素含量,包括萃取物、全纤维素、半纤维素、纤维素和木质素的含量,结果有差异。通过对其进行热处理,结果表明了其葡萄糖和碳水化合物含量的变化趋势。在90℃、60分钟的条件下,葡萄糖的最高含量为978.602µg/ml。碳水化合物含量也呈增加趋势,在80℃处理30 min时达到峰值0.234 mg/ml。然而,我们发现木质纤维素含量随温度和时间的变化而变化。采用双因素方差分析进行统计分析,发现自变量(温度和接触时间)与食物垃圾的糖化效果之间存在交互作用。结果表明,自变量对食物垃圾组成变化的显著影响存在差异。
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引用次数: 0
Review of advanced oxidation processes (AOPs) for treatment of pharmaceutical wastewater 高级氧化法处理制药废水的研究进展
Pub Date : 2020-03-01 DOI: 10.12989/AER.2020.9.1.001
M. Verma, A. K. Haritash
Pharmaceutically active compounds (PhACs) have become an environmental havoc in last few decades with reported cases of antibiotic resistant bacteria (ARB) and antibiotic resistant genes (ARGs), lethal effects over aquatic organisms, interference in natural decomposition of organic matter, reduced diversity of microbial communities in different environmental compartments, inhibition of growth of microbes resulting in reduced rate of nutrient cycling, hormonal imbalance in exposed organisms etc. Owing to their potential towards bioaccumulation and persistent nature, these compounds have longer residence time and activity in environment. The conventional technologies of wastewater treatment have got poor efficiency towards removal/degradation of PhACs and therefore, modern techniques with efficient, cost-effective and environment-friendly operation need to be explored. Advanced oxidation processes (AOPs) like Photocatalysis, Fenton oxidation, Ozonation etc. are some of the promising, viable and sustainable options for degradation of PhACs. Although energy/chemical or both are essentially required for AOPs, these methods target complete degradation/mineralization of persistent pollutants resulting in no residual toxicity. Considering the high efficiency towards degradation, non-toxic nature, universal viability and acceptability, AOPs have become a promising option for effective treatment of chemicals with persistent nature.
在过去的几十年里,药物活性化合物(PhACs)已经成为一种环境破坏,对抗生素耐药细菌(ARB)和抗生素耐药基因(ARGs)的报道,对水生生物的致命影响,干扰有机物的自然分解,减少不同环境舱室中微生物群落的多样性,抑制微生物的生长导致营养循环速率降低,暴露生物体内激素失衡等。由于具有生物蓄积性和持久性,这些化合物在环境中具有较长的停留时间和活性。传统的废水处理技术对PhACs的去除/降解效果较差,因此需要探索高效、经济、环保的现代技术。先进的氧化工艺(AOPs),如光催化、Fenton氧化、臭氧化等,是一些有前途的、可行的和可持续的降解PhACs的选择。虽然AOPs基本上需要能源/化学或两者兼而有之,但这些方法的目标是完全降解/矿化持久性污染物,而不会产生残留毒性。由于降解效率高、无毒、普遍存在性和可接受性,AOPs已成为有效处理持久性化学品的一种很有前景的选择。
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引用次数: 15
Optimization of uranium biosorption in solutions by Sargassum boveanum using RSM method RSM法优化牛马尾藻对溶液中铀的生物吸附
Pub Date : 2020-03-01 DOI: 10.12989/AER.2020.9.1.065
N. Hashemi, R. Dabbagh, M. Noroozi, S. Baradaran
The potential use of Sargassum boveanum algae for the removal of uranium from aqueous solution has been studied by varying three independent parameters (pH, initial uranium ion concentration, S. boveanum dosage) using a central composite design (CCD) under response surface methodology (RSM). Batch mode experiments were performed in 20 experimental runs to determine the maximum metal adsorption capacity. In CCD design, the quantitative relationship between different levels of these parameters and heavy metal uptake (q) were used to work out the optimized levels of these parameters. The analysis of variance (ANOVA) of the proposed quadratic model revealed that this model was highly significant (R2 = 0.9940). The best set required 2.81 as initial pH(on the base of design of experiments method), 1.01 g/L S. boveanum and 418.92 mg/L uranium ion concentration within 180 min of contact time to show an optimum uranium uptake of 255 mg/g biomass. The biosorption process was also evaluated by Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models represented that the experimental data fitted to the Langmuir isotherm model of a suitable degree and showed the maximum uptake capacity of 500 mg/g. FTIR and scanning electron microscopy were used to characterize the biosorbent and implied that the functional groups (carboxyl, sulfate, carbonyl and amine) were responsible for the biosorption of uranium from aqueous solution. In conclusion, the present study showed that S. boveanum could be a promising biosorbent for the removal of uranium pollutants from aqueous solutions.
采用响应面法(RSM)下的中心复合设计(CCD),通过改变三个独立参数(pH、初始铀离子浓度、牛马尾藻投加量),研究了牛马尾藻对水溶液中铀的去除潜力。在20次实验中进行了批量实验,以确定最大金属吸附量。在CCD设计中,利用这些参数的不同水平与重金属吸收量(q)之间的定量关系,计算出这些参数的优化水平。对所提出的二次模型进行方差分析(ANOVA),发现该模型具有高度显著性(R2 = 0.9940)。最佳设置为初始pH为2.81(基于实验方法设计),接触时间为180 min的s - boveanum浓度为1.01 g/L,铀离子浓度为418.92 mg/L,可获得255 mg/g生物量的最佳铀吸收率。采用Langmuir、Freundlich、Temkin和Dubinin-Radushkevich等温线模型对吸附过程进行了评价,实验数据与Langmuir等温线模型拟合程度较好,最大吸附量为500 mg/g。利用红外光谱(FTIR)和扫描电镜对该生物吸附剂进行了表征,发现其对铀的生物吸附主要由羧基、硫酸盐基、羰基和胺基等官能团组成。综上所述,本研究表明牛乳杆菌是一种很有前途的去除水中铀污染物的生物吸附剂。
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引用次数: 2
Monitoring and spatio-temporal analysis of UHI effect for Mansa district of Punjab, India 印度旁遮普曼萨地区热岛效应监测与时空分析
Pub Date : 2020-03-01 DOI: 10.12989/AER.2020.9.1.019
R. Kaur, P. Pandey
Urban heat island (UHI) is one of the most important climatic implications of urbanization and thus a matter of key concern for environmentalists of the world in the twenty-first century. The relationship between climate and urbanization has been better understood with the introduction of thermal remote sensing. So, this study is an attempt to understand the influence of urbanization on local temperature for a small developing city. The study focuses on the investigation of intensity of atmospheric and surface urban heat island for a small urbanizing district of Punjab, India. Landsat 8 OLI/TIRS satellite data and field observations were used to examine the spatial pattern of surface and atmospheric UHI effect respectively, for the month of April, 2018. The satellite data has been used to cover the larger geographical area while field observations were taken for simultaneous and daily temperature measurements for different land use types. The significant influence of land use/land cover (LULC) patterns on UHI effect was analyzed using normalized built-up and vegetation indices (NDBI, NDVI) that were derived from remote sensing satellite data. The statistical analysis carried out for land surface temperature (LST) and LULC indicators displayed negative correlation for LST and NDVI while NDBI and LST exhibited positive correlation depicting attenuation in UHI effect by abundant vegetation. The comparison of remote sensing and in-situ observations were also carried out in the study. The research concluded in finding both nocturnal and daytime UHI effect based on diurnal air temperature observations. The study recommends the urgent need to explore and impose effective UHI mitigation measures for the sustainable urban growth.
城市热岛(UHI)是城市化最重要的气候影响之一,因此是21世纪世界环境学家关注的一个关键问题。随着热遥感的引入,人们对气候与城市化之间的关系有了更好的了解。因此,本研究试图了解城市化对发展中小城市当地温度的影响。本文对印度旁遮普省一个城市化小区的大气热岛强度和地表热岛强度进行了研究。利用Landsat 8 OLI/TIRS卫星资料和野外观测资料,分析了2018年4月地表和大气热岛效应的空间格局。卫星数据已用于覆盖较大的地理区域,同时对不同土地利用类型进行实地观测,以同时和每日测量温度。利用遥感卫星数据的归一化建筑和植被指数(NDBI、NDVI)分析了土地利用/土地覆盖(LULC)格局对热岛效应的显著影响。对地表温度(LST)和LULC指标的统计分析显示,LST与NDVI呈负相关,而NDBI与LST呈正相关,反映了丰富植被对热岛效应的衰减。在研究中还进行了遥感与原位观测的对比。这项研究的结论是,根据白天的气温观测,发现了夜间和白天的热岛效应。该研究建议,迫切需要探索和实施有效的缓解城市热岛问题的措施,以实现可持续的城市增长。
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引用次数: 3
Preparation of chitosan, sunflower and nano-iron based core shell and its use in dye removal 壳聚糖、葵花籽和纳米铁基核壳的制备及其在染料脱除中的应用
Pub Date : 2020-01-01 DOI: 10.12989/AER.2020.9.2.135
Esra Turgut, Azize Alayli, H. Nadaroğlu
. Many industries, such as textiles, chemical refineries, leather, plastics and paper, use different dyes in various process steps. At the same time, these industrial sectors are responsible for discharging contaminants that are harmful and toxic to humans and microorganisms by introducing synthetic dyes into wastewater. Of these dyes, methylene blue dye, which is classified as basic dyes, is accepted as a model dye. For this reason, methylene blue dye was selected in the study and its removal from the water was studied. In this study, two efficient biosorbents were developed from chitosan and sunflower waste, an agro-industrial waste and modified using iron nanoparticles. The biosorption efficiency was evaluated for methylene blue (MB) dye removal from aqueous solution under various parameters such as treating agent, solution pH, biosorbent dosage, contact time, initial dye concentration and temperature. We investigated the kinetic properties of dye removal from water for Chitosan-Sunflower (CS), Chitosan-Sunflower-Nanoiron (CSN). the wavelength scanned, the maximum absorbance was determined as 660 nm. For the core shell biosorbents we obtained, we found that the optimum time for removal of MB from wastewater was 60 min. The pH of the best pH was determined as 5 in the studied pH. The most suitable temperature for the experiment was determined as 30°C. SEM-EDAX, TEM, XRD, and FTIR techniques were used to characterize biosorbents produced and modified in the experimental stage and to monitor the change of biosorbent after dye removal. The interactions of the paint with the surface used for removal were explained by these techniques. It was calculated that 80% of CS and 88% of CSN removed MB in optimum conditions. Also, the absorption of MB dye onto the surface was investigated by Langmiur and Frendlinch isotherms and it was determined from the results that the removal was more compatible with Langmiur isotherm.
. 许多行业,如纺织、化学精炼厂、皮革、塑料和造纸,在不同的工艺步骤中使用不同的染料。与此同时,这些工业部门通过向废水中引入合成染料而排放对人类和微生物有害和有毒的污染物。在这些染料中,亚甲基蓝染料被归类为碱性染料,被认为是一种模型染料。为此,本研究选择亚甲基蓝染料,并对其从水中去除进行了研究。本研究以壳聚糖和向日葵废弃物为原料,制备了两种高效的生物吸附剂,并对其进行了纳米铁改性。考察了处理剂、溶液pH、生物吸附剂用量、接触时间、初始染料浓度和温度等参数对亚甲基蓝(MB)染料的生物吸附效果。研究了壳聚糖-葵花(CS)、壳聚糖-葵花-纳米铁(CSN)对水中染料的去除动力学性质。扫描波长,最大吸光度为660 nm。对于我们获得的核壳生物吸附剂,我们发现去除废水中MB的最佳时间为60 min,在研究的pH中确定最佳pH为5,实验的最合适温度为30℃。采用SEM-EDAX、TEM、XRD、FTIR等技术对实验阶段制备和改性的生物吸附剂进行表征,并监测生物吸附剂脱染后的变化。这些技术解释了用于去除的涂料与表面的相互作用。经计算,在最佳条件下,CS的去除率为80%,CSN的去除率为88%。通过Langmiur等温线和Frendlinch等温线研究了MB染料在表面的吸附,结果表明,去除过程更符合Langmiur等温线。
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引用次数: 4
Formulation of a novel bacterial consortium for the effective biodegradation of phenol 有效生物降解苯酚的新型细菌联合体的形成
Pub Date : 2020-01-01 DOI: 10.12989/AER.2020.9.2.109
V. Dhanya
Phenol is frequently present as the hazardous pollutant in petrochemical and pesticide industry wastewater. Because of its high toxicity and carcinogenic potential, a proper treatment is needed to reduce the hazards of phenol carrying effluent before being discharged into the environment. Phenol biodegradation with microbial consortium offers a very promising approach now a day’s. This study focused on the formulation of phenol degrading bacterial consortium with three bacterial isolates. The bacterial strains Bacillus cereus strain VCRC B540, Bacillus cereus strain BRL02-43 and Oxalobacteraceae strain CC11D were isolated from detergent contaminated soil by soil enrichment technique and was identified by 16s rDNA sequence analysis. Individual cultures were degrade 100 μl phenol in 72 hrs. The formulated bacterial consortium was very effective in degrading 250 μl of phenol at a pH 7 with in 48 hrs. The study further focused on the analysis of the products of biodegradation with Fourier Transform Infrared Spectroscopy (FT/IR) and Gas Chromatography-Mass Spectroscopy (GC-MS). The analysis showed the complete degradation of phenol and the production of Benzene di-carboxylic acid mono (2-ethylhexyl) ester and Ethane 1,2Diethoxyas metabolic intermediates. Biodegradation with the aid of microorganisms is a potential approach in terms of cost-effectiveness and elimination of secondary pollutions. The present study established the efficiency of bacterial consortium to degrade phenol. Optimization of biodegradation conditions and construction of a bioreactor can be further exploited for large scale industrial applications.
苯酚是石油化工和农药工业废水中常见的有害污染物。由于苯酚具有高毒性和致癌性,因此需要对其进行适当处理,以减少其排放到环境中的危害。微生物联合降解苯酚是一种非常有前途的方法。本研究以三株分离菌为原料,研究了苯酚降解菌群的组成。采用土壤富集技术从洗涤剂污染土壤中分离到蜡样芽孢杆菌VCRC B540、蜡样芽孢杆菌BRL02-43和草藻杆菌科菌株CC11D,并进行16s rDNA序列分析鉴定。单个培养物在72 h内降解100 μl苯酚。该菌群在pH为7的条件下,对250 μl苯酚的降解效果良好,降解时间为48 h。利用傅里叶变换红外光谱(FT/IR)和气相色谱-质谱(GC-MS)对生物降解产物进行了分析。分析表明苯酚完全降解,生成苯二羧酸单(2-乙基己基)酯和乙烷1,2二氧基代谢中间体。在成本效益和消除二次污染方面,微生物辅助生物降解是一种潜在的方法。本研究确定了细菌联合体降解苯酚的效率。生物降解条件的优化和生物反应器的构建可进一步用于大规模工业应用。
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引用次数: 0
Potential valorisation of ferrous slag in the treatment of water and wastewater: A review 铁渣在水和废水处理中的潜在增值研究进展
Pub Date : 2019-01-01 DOI: 10.12989/AER.2019.8.1.055
Anjali, S. Shrihari, B. Sunil
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引用次数: 0
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