Pub Date : 2018-09-01DOI: 10.12989/aer.2018.7.3.201
S. Aydın, M. Aydin, Arzu Ulvi, H. Kiliç
In this study, conditions of solid phase extraction (SPE) for determination of some antibiotics such as trimethoprim, oxytetracycline, erythromycin, clarithromycin, azythromycin, doxycycline, sulfamethazine, ciprofloxacin, chlortetracycline, sulfamethoxazole in wastewaters were optimized. After the optimum volume and pH of the sample were determined, the effect of the concentration of the compounds and matrix were investigated. The highest recovery rates for antibiotic compounds were determined between 82% and 105% in 200 mL sample volume and pH 2.5. Then, antibiotic compounds were investigated in influent and effluent samples taken from Konya Urban Wastewater Treatment Plant. The concentration of the antibiotics was detected range of 0.11-101 ng/L in influent waters and less than dl-288 ng/L in effluent samples in wastewater treatment plant. Hazard quotients (HQs) of antibiotic compounds determined in WWTP effluents to evaluate the risk towards different aquatic organisms (algae, Daphnia magna and fish) were determined. Azythromycin for fish and erythromycin, sulfamethoxazole, ciprofloxacin, clarithromycin for algae posed a moderate risk while azythromycin, ciprofloxacin, clarithromycin, oxytetracycline posed a high risk for algae in the receiving environment.
{"title":"Determination of antibiotics by SPE-LC-MS/MS in wastewater and risk assessment","authors":"S. Aydın, M. Aydin, Arzu Ulvi, H. Kiliç","doi":"10.12989/aer.2018.7.3.201","DOIUrl":"https://doi.org/10.12989/aer.2018.7.3.201","url":null,"abstract":"In this study, conditions of solid phase extraction (SPE) for determination of some antibiotics such as trimethoprim, oxytetracycline, erythromycin, clarithromycin, azythromycin, doxycycline, sulfamethazine, ciprofloxacin, chlortetracycline, sulfamethoxazole in wastewaters were optimized. After the optimum volume and pH of the sample were determined, the effect of the concentration of the compounds and matrix were investigated. The highest recovery rates for antibiotic compounds were determined between 82% and 105% in 200 mL sample volume and pH 2.5. Then, antibiotic compounds were investigated in influent and effluent samples taken from Konya Urban Wastewater Treatment Plant. The concentration of the antibiotics was detected range of 0.11-101 ng/L in influent waters and less than dl-288 ng/L in effluent samples in wastewater treatment plant. Hazard quotients (HQs) of antibiotic compounds determined in WWTP effluents to evaluate the risk towards different aquatic organisms (algae, Daphnia magna and fish) were determined. Azythromycin for fish and erythromycin, sulfamethoxazole, ciprofloxacin, clarithromycin for algae posed a moderate risk while azythromycin, ciprofloxacin, clarithromycin, oxytetracycline posed a high risk for algae in the receiving environment.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"1 1","pages":"201-212"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78187691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-09-01DOI: 10.12989/AER.2018.7.3.213
G. Lofrano, C. B. Özkal, M. Carotenuto, S. Meriç
Continuous input into the aquatic ecosystem and persistent structures have created concern of antibiotics, primarily due to the potential for the development of antimicrobial resistance. Degradation kinetics and mineralization of vancomycin B (VAN-B) by photocatalysis using TiO2 and ZnO nanoparticles was monitored at natural pH conditions. Photocatalysis (PC) efficiency was followed by means of UV absorbance, total organic carbon (TOC), and HPLC results to better monitor degradation of VAN-B itself. Experiments were run for two initial VAN-B concentrations (20–50 mgL-1) and using two catalysts TiO2 and ZnO at different concentrations (0.1 and 0.5 gL-1) in a multi-lamp batch reactor system (200 mL water volume). Furthermore, a set of toxicity tests with Daphnia magna was performed to evaluate the potential toxicity of oxidation by-products of VAN-B. Formation of intermediates such as chlorides and nitrates were monitored. A rapid VAN-B degradation was observed in ZnO-PC system (85 % to 70 % at 10 min), while total mineralization was observed to be relatively slower than TiO2-PC system (59 % to 73 % at 90min). Treatment efficiency and mechanism of degradation directly affected the rate of transformation and by-products formation that gave rise to toxicity in the treated samples.
{"title":"Comparison of TiO 2 and ZnO catalysts for heterogenous photocatalytic removal of vancomycin B","authors":"G. Lofrano, C. B. Özkal, M. Carotenuto, S. Meriç","doi":"10.12989/AER.2018.7.3.213","DOIUrl":"https://doi.org/10.12989/AER.2018.7.3.213","url":null,"abstract":"Continuous input into the aquatic ecosystem and persistent structures have created concern of antibiotics, primarily due to the potential for the development of antimicrobial resistance. Degradation kinetics and mineralization of vancomycin B (VAN-B) by photocatalysis using TiO2 and ZnO nanoparticles was monitored at natural pH conditions. Photocatalysis (PC) efficiency was followed by means of UV absorbance, total organic carbon (TOC), and HPLC results to better monitor degradation of VAN-B itself. Experiments were run for two initial VAN-B concentrations (20–50 mgL-1) and using two catalysts TiO2 and ZnO at different concentrations (0.1 and 0.5 gL-1) in a multi-lamp batch reactor system (200 mL water volume). Furthermore, a set of toxicity tests with Daphnia magna was performed to evaluate the potential toxicity of oxidation by-products of VAN-B. Formation of intermediates such as chlorides and nitrates were monitored. A rapid VAN-B degradation was observed in ZnO-PC system (85 % to 70 % at 10 min), while total mineralization was observed to be relatively slower than TiO2-PC system (59 % to 73 % at 90min). Treatment efficiency and mechanism of degradation directly affected the rate of transformation and by-products formation that gave rise to toxicity in the treated samples.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"48 1","pages":"213-223"},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86054377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-06-01DOI: 10.12989/AER.2018.7.2.139
H. Vempati, M. Vaitilingom, Zenghui Zhang, T. Liyana-Arachchi, C. Stevens, F. Hung, K. Valsaraj
Green Leaf Volatiles (GLVs) is a class of biogenically emitted oxygenated hydrocarbons that have been identified as a potential source of Secondary Organic Aerosols (SOA) via aqueous oxidation. The physico-chemical properties of GLVs are vital to understanding their fate and transport in the atmosphere via fog processing, but few experimental data are available. We studied the aqueous solubility, 1-octanol/water partition coefficient, and Henry's law constant (KH) of five GLVs at 25 C: methyl jasmonate, methyl salicylate, 2-methyl-3-buten-2-ol, cis-3-hexen-1-ol, and cis-3-hexenyl acetate. Henry's law constant was also measured at temperatures and ionic strengths typical of fog. Experimental values are compared to scarcely-available literature values, as well as estimations using group and bond contribution methods, property-specific correlations and molecular dynamics simulations. From these values, the partition coefficients to the air-water interface were also calculated. The large Henry's law constant of methyl jasmonate (8091+/-1121 Mxatm-1) made it the most significant GLV for aqueous phase photochemistry. The HENRYWIN program's bond contribution method from the Estimation Programs Interface Suite (EPI Suite) produced the best estimate of the Henry's constant for GLVs. Estimations of 1-octanol/water partition coefficient and solubility are best when correlating an experimental value of one to find the other. Finally, the scavenging efficiency was calculated for each GLV indicating aqueous phase processing will be most important for methyl jasmonate.
{"title":"Physico-chemical properties of green leaf volatiles (GLV) for ascertaining atmospheric fate and transport in fog","authors":"H. Vempati, M. Vaitilingom, Zenghui Zhang, T. Liyana-Arachchi, C. Stevens, F. Hung, K. Valsaraj","doi":"10.12989/AER.2018.7.2.139","DOIUrl":"https://doi.org/10.12989/AER.2018.7.2.139","url":null,"abstract":"Green Leaf Volatiles (GLVs) is a class of biogenically emitted oxygenated hydrocarbons that have been identified as a potential source of Secondary Organic Aerosols (SOA) via aqueous oxidation. The physico-chemical properties of GLVs are vital to understanding their fate and transport in the atmosphere via fog processing, but few experimental data are available. We studied the aqueous solubility, 1-octanol/water partition coefficient, and Henry's law constant (KH) of five GLVs at 25 C: methyl jasmonate, methyl salicylate, 2-methyl-3-buten-2-ol, cis-3-hexen-1-ol, and cis-3-hexenyl acetate. Henry's law constant was also measured at temperatures and ionic strengths typical of fog. Experimental values are compared to scarcely-available literature values, as well as estimations using group and bond contribution methods, property-specific correlations and molecular dynamics simulations. From these values, the partition coefficients to the air-water interface were also calculated. The large Henry's law constant of methyl jasmonate (8091+/-1121 Mxatm-1) made it the most significant GLV for aqueous phase photochemistry. The HENRYWIN program's bond contribution method from the Estimation Programs Interface Suite (EPI Suite) produced the best estimate of the Henry's constant for GLVs. Estimations of 1-octanol/water partition coefficient and solubility are best when correlating an experimental value of one to find the other. Finally, the scavenging efficiency was calculated for each GLV indicating aqueous phase processing will be most important for methyl jasmonate.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"16 1","pages":"139-159"},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87220272","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-06-01DOI: 10.12989/aer.2018.7.2.087
G. Asadollahfardi, N. Heidarzadeh, Atabak Mosalli, A. Sekhavati
Water quality monitoring network needs periodic evaluations based on environmental demands and financial constraints. We used a genetic algorithm to optimize the existing water quality monitoring stations on the Sefid-Rud River, which is located in the North of Iran. Our objective was to optimize the existing stations for drinking and irrigation purposes, separately. The technique includes two stages called data preparation and the optimization. On the data preparation stage, first the basin was divided into four sections and each section was consisted of some stations. Then, the score of each station was computed using the data provided by the water Research Institute of the Ministry of energy. After that, we applied a weighting method by providing questionnaires to ask the experts to define the significance of each parameter. In the next step, according to the scores, stations were prioritized cumulatively. Finally, the genetic algorithm was applied to identify the best combination. The results indicated that out of 21 existing monitoring stations, 14 stations should remain in the network for both irrigation and drinking purposes. The results also had a good compliance with the previous studies which used dynamic programming as the optimization technique.
{"title":"Optimization of water quality monitoring stations using genetic algorithm, a case study, Sefid-Rud River, Iran","authors":"G. Asadollahfardi, N. Heidarzadeh, Atabak Mosalli, A. Sekhavati","doi":"10.12989/aer.2018.7.2.087","DOIUrl":"https://doi.org/10.12989/aer.2018.7.2.087","url":null,"abstract":"Water quality monitoring network needs periodic evaluations based on environmental demands and financial constraints. We used a genetic algorithm to optimize the existing water quality monitoring stations on the Sefid-Rud River, which is located in the North of Iran. Our objective was to optimize the existing stations for drinking and irrigation purposes, separately. The technique includes two stages called data preparation and the optimization. On the data preparation stage, first the basin was divided into four sections and each section was consisted of some stations. Then, the score of each station was computed using the data provided by the water Research Institute of the Ministry of energy. After that, we applied a weighting method by providing questionnaires to ask the experts to define the significance of each parameter. In the next step, according to the scores, stations were prioritized cumulatively. Finally, the genetic algorithm was applied to identify the best combination. The results indicated that out of 21 existing monitoring stations, 14 stations should remain in the network for both irrigation and drinking purposes. The results also had a good compliance with the previous studies which used dynamic programming as the optimization technique.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"232 1","pages":"87"},"PeriodicalIF":0.0,"publicationDate":"2018-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78430823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-03-31DOI: 10.12989/AER.2018.7.1.000
Ali Bahadori-Jahromi, Radwa Salem, A. Mylona, P. Godfrey, Darren Cook
It is currently agreed upon that one of the major challenges in the construction industry is the energy efficiency of existing buildings. The World Meteorological Organisation (WMO) and United Nations (UN) have reported that the concentration of global atmospheric carbon dioxide has increased by an average of 50%, a record speed, from 2015 to 2016. The housing sector contributes to 45% of the UK’s carbon emissions. To help tackle some of those issues the recast Energy Performance Building Directive (EBPD) has introduced Nearly Zero Energy Buildings (NZEBs) in the coming years (including buildings that will undergo refurbishment/ renovations). This paper will explore the retrofitting of a UK residential dwelling using Thermal Analysis Simulation (TAS, EDSL) software by focusing on building fabric improvements and usage of on-site renewables. The CIBSE Test Reference Year (TRY) weather data has been selected to examine the performance of the building under current and future climate projections. The proposed design variables were finally implemented in the building altogether on TAS. The simulation results showed a reduction in the building’s annual energy consumption of 122.64kWh/m2 (90.24%). The greatest savings after this were achieved for the annual reduction in carbon emissions and avoided emissions, which were 84.59% and 816.47kg/CO2, respectively.
{"title":"Retrofit of a UK residential property to achieve nearly zero energy building standard","authors":"Ali Bahadori-Jahromi, Radwa Salem, A. Mylona, P. Godfrey, Darren Cook","doi":"10.12989/AER.2018.7.1.000","DOIUrl":"https://doi.org/10.12989/AER.2018.7.1.000","url":null,"abstract":"It is currently agreed upon that one of the major challenges in the construction industry is the energy efficiency of existing buildings. The World Meteorological Organisation (WMO) and United Nations (UN) have reported that the concentration of global atmospheric carbon dioxide has increased by an average of 50%, a record speed, from 2015 to 2016. The housing sector contributes to 45% of the UK’s carbon emissions. To help tackle some of those issues the recast Energy Performance Building Directive (EBPD) has introduced Nearly Zero Energy Buildings (NZEBs) in the coming years (including buildings that will undergo refurbishment/ renovations). This paper will explore the retrofitting of a UK residential dwelling using Thermal Analysis Simulation (TAS, EDSL) software by focusing on building fabric improvements and usage of on-site renewables. The CIBSE Test Reference Year (TRY) weather data has been selected to examine the performance of the building under current and future climate projections. The proposed design variables were finally implemented in the building altogether on TAS. The simulation results showed a reduction in the building’s annual energy consumption of 122.64kWh/m2 (90.24%). The greatest savings after this were achieved for the annual reduction in carbon emissions and avoided emissions, which were 84.59% and 816.47kg/CO2, respectively.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"10 1","pages":"13"},"PeriodicalIF":0.0,"publicationDate":"2018-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75260965","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2018-01-01DOI: 10.12989/aer.2018.7.3.225
N. Harish, P. Janardhan, S. Sangami
. The sorption of metal ions with low-cost adsorbents plays an important role in sustainable development. In the present study, the efficacy of sugarcane bagasse, rain tree fruits (samaneasaman), banana stem and their mixtures, used as bio-sorbents, in the removal of Cu(II) and Pb(II) ions from aqueous solution is evaluated. Batch studies are conducted, and residual ions were measured using Inductively Coupled Plasma (ICP)-atomic spectrometer. Effect of pH, initial metal ion concentration, reaction time and adsorbent dosage are studied. The Pb(II) removal efficiency was observed to be 97.88%, 98.60% and 91.74% for rain tree fruits, banana stem and a mixture of adsorbents respectively. The highest Cu(II) ion removal was observed for sugarcane bagasse sorbent with an efficiency of 82.10% with a pH of 4.5 and a reaction time of 90 min. Finally, desorption studies were carried out to study the leaching potential of adsorbent, and it was found that the adsorbent is stable in water than the other leaching agents such as HCl, ammonium acetate, Sodium EDTA. Hence, these adsorbents can be effectively used for the removal of these heavy metals.
{"title":"Effective adsorption of lead and copper from aqueous solution by samaneasaman and banana stem","authors":"N. Harish, P. Janardhan, S. Sangami","doi":"10.12989/aer.2018.7.3.225","DOIUrl":"https://doi.org/10.12989/aer.2018.7.3.225","url":null,"abstract":". The sorption of metal ions with low-cost adsorbents plays an important role in sustainable development. In the present study, the efficacy of sugarcane bagasse, rain tree fruits (samaneasaman), banana stem and their mixtures, used as bio-sorbents, in the removal of Cu(II) and Pb(II) ions from aqueous solution is evaluated. Batch studies are conducted, and residual ions were measured using Inductively Coupled Plasma (ICP)-atomic spectrometer. Effect of pH, initial metal ion concentration, reaction time and adsorbent dosage are studied. The Pb(II) removal efficiency was observed to be 97.88%, 98.60% and 91.74% for rain tree fruits, banana stem and a mixture of adsorbents respectively. The highest Cu(II) ion removal was observed for sugarcane bagasse sorbent with an efficiency of 82.10% with a pH of 4.5 and a reaction time of 90 min. Finally, desorption studies were carried out to study the leaching potential of adsorbent, and it was found that the adsorbent is stable in water than the other leaching agents such as HCl, ammonium acetate, Sodium EDTA. Hence, these adsorbents can be effectively used for the removal of these heavy metals.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"27 1","pages":"225-237"},"PeriodicalIF":0.0,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76227128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-06-01DOI: 10.12989/AER.2017.6.2.095
L. Gonsalvesh, G. Gryglewicz, R. Carleer, J. Yperman
The valorization of swine manure samples, i.e., de-watered cake (SMc) and solid digestate (SMd), in products with beneficial value, i.e., low cost activated carbons (ACs), is studied. For this purpose slow pyrolysis and steam activation at three different duration times are applied. Additionally, the obtained ACs are characterized and tested towards removal of Cr(VI) from aqueous solutions. It is revealed that BET surface area varies in the range of 236-267 m 2 /g for ACs prepared from SMc sample and in the range of 411432 m 2 /g for ACs prepared from SMd sample. Despite the low determined surface area of prepared ACs, a high total Cr removal capacity is observed occurring through a “coupled adsorption-reduction” mechanism. Higher Cr(VI) removal capacity is demonstrated for ACs having higher surface area (qm is 140.9 mg/g according Langmuir modelling). Cr(VI) removal is found to be pH dependent with a maximum at pH 1. However at that pH significant amounts of Cr remain in the solution as Cr(III). At pH 2 lower amount of Cr(VI) is removed compensated by a higher removal of Cr(III) resulting in a higher amount of adsorbed Crtot. Therefore adsorption at pH 2 is found to be appropriate. The removal capacity of the studied ACs towards Cr(VI) is almost independent of activation time.
{"title":"Valorization of swine manure into low cost activated carbons capable of Cr(VI) removal","authors":"L. Gonsalvesh, G. Gryglewicz, R. Carleer, J. Yperman","doi":"10.12989/AER.2017.6.2.095","DOIUrl":"https://doi.org/10.12989/AER.2017.6.2.095","url":null,"abstract":"The valorization of swine manure samples, i.e., de-watered cake (SMc) and solid digestate (SMd), in products with beneficial value, i.e., low cost activated carbons (ACs), is studied. For this purpose slow pyrolysis and steam activation at three different duration times are applied. Additionally, the obtained ACs are characterized and tested towards removal of Cr(VI) from aqueous solutions. It is revealed that BET surface area varies in the range of 236-267 m 2 /g for ACs prepared from SMc sample and in the range of 411432 m 2 /g for ACs prepared from SMd sample. Despite the low determined surface area of prepared ACs, a high total Cr removal capacity is observed occurring through a “coupled adsorption-reduction” mechanism. Higher Cr(VI) removal capacity is demonstrated for ACs having higher surface area (qm is 140.9 mg/g according Langmuir modelling). Cr(VI) removal is found to be pH dependent with a maximum at pH 1. However at that pH significant amounts of Cr remain in the solution as Cr(III). At pH 2 lower amount of Cr(VI) is removed compensated by a higher removal of Cr(III) resulting in a higher amount of adsorbed Crtot. Therefore adsorption at pH 2 is found to be appropriate. The removal capacity of the studied ACs towards Cr(VI) is almost independent of activation time.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"12 1","pages":"095"},"PeriodicalIF":0.0,"publicationDate":"2017-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81315320","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-06-01DOI: 10.12989/aer.2017.6.2.083
Shruti S. Tikhe, K. Khare, S. Londhe
Air quality planning and management requires accurate and consistent records of the air quality parameters. Limited number of monitoring stations and inconsistent measurements of the air quality parameters is a very serious problem in many parts of India. It becomes difficult for the authorities to plan proactive measures with such a limited data. Estimation models can be developed using soft computing techniques considering the physics behind pollution dispersion as they can work very well with limited data. They are more realistic and can present the complete picture about the air quality. In the present case study spatio-temporal models using Linear Genetic Programming (LGP) have been developed for estimation of air quality parameters. The air quality data from four monitoring stations of an Indian city has been used and LGP models have been developed to estimate pollutant concentration of the fifth station. Three types of models are developed. In the first type, models are developed considering only the pollutant concentrations at the neighboring stations without considering the effect of distance between the stations as well the significance of the prevailing wind direction. Second type of models are distance based models based on the hypothesis that there will be atmospheric interactions between the two stations under consideration and the effect increases with decrease in the distance between the two. In third type the effect of the prevailing wind direction is also considered in choosing the input stations in wind and distance based models. Models are evaluated using Band Error and it was observed that majority of the errors are in +/-1 band.
{"title":"Spatio-temporal estimation of air quality parameters using linear genetic programming","authors":"Shruti S. Tikhe, K. Khare, S. Londhe","doi":"10.12989/aer.2017.6.2.083","DOIUrl":"https://doi.org/10.12989/aer.2017.6.2.083","url":null,"abstract":"Air quality planning and management requires accurate and consistent records of the air quality parameters. Limited number of monitoring stations and inconsistent measurements of the air quality parameters is a very serious problem in many parts of India. It becomes difficult for the authorities to plan proactive measures with such a limited data. Estimation models can be developed using soft computing techniques considering the physics behind pollution dispersion as they can work very well with limited data. They are more realistic and can present the complete picture about the air quality. \u0000In the present case study spatio-temporal models using Linear Genetic Programming (LGP) have been developed for estimation of air quality parameters. The air quality data from four monitoring stations of an Indian city has been used and LGP models have been developed to estimate pollutant concentration of the fifth station. \u0000Three types of models are developed. In the first type, models are developed considering only the pollutant concentrations at the neighboring stations without considering the effect of distance between the stations as well the significance of the prevailing wind direction. Second type of models are distance based models based on the hypothesis that there will be atmospheric interactions between the two stations under consideration and the effect increases with decrease in the distance between the two. In third type the effect of the prevailing wind direction is also considered in choosing the input stations in wind and distance based models. Models are evaluated using Band Error and it was observed that majority of the errors are in +/-1 band.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"6 1","pages":"083"},"PeriodicalIF":0.0,"publicationDate":"2017-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87096041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-06-01DOI: 10.12989/aer.2017.6.2.113
R. Alizadeh, A. Zeidi
{"title":"Adsorption of methylene blue from an aqueous dyeing solution by use of santa barbara amorphous-15 nanostructure: Kinetic and isotherm studies","authors":"R. Alizadeh, A. Zeidi","doi":"10.12989/aer.2017.6.2.113","DOIUrl":"https://doi.org/10.12989/aer.2017.6.2.113","url":null,"abstract":"","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"30 1","pages":"113"},"PeriodicalIF":0.0,"publicationDate":"2017-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89376465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2017-06-01DOI: 10.12989/aer.2017.6.2.139
K. Mukwana, S. R. Samo, A. Q. Jakhrani, M. M. Tunio, A. R. Jatoi
The purpose of this study was to determine the present air pollutant concentrations and predicted levels for next 30 years in urban environment of Karachi city. For that, a total of fifty measurements were made for each twenty selected locations of the city. The locations were selected on the basis of land use pattern such as residential, commercial, industrial settlements, open areas, congested traffic and low traffic areas for investigation of air pollutants variability and intensity. The measurements were taken continuously for six months period using PM Meter, Model AEROCET 531 and Ambient Air Quality Meter, Model AAQ 7545. The concentration of air pollutants were found higher at Al Asif Square and Maripur Road due to higher intensity of traffic and at Korangi Crossing because of industrial areas. The level of pollutants was lower at Sea View owing to lower traffic congestion and transportation of pollutants by sea breezes.
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