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A comparative study of granular activated carbon and sand as water filtration media with estimation of model parameters 颗粒活性炭与砂作为水过滤介质的比较研究及模型参数的估计
Pub Date : 2017-03-25 DOI: 10.12989/AER.2017.6.1.035
J. Chatterjee, A. Shajahan, Shailendra Pratap, S. Gupta
The use of Granular Activated Carbon (GAC) and naturally occurring silica (Sand) as filtration media in water and waste water treatment systems is very common. While GAC offers the additional functionality of being an “adsorptive” filter for dissolved organics it is also more expensive. In this paper we present an experimental evaluation of the performance of a bed of GAC for colloid removal and compare the same with that from an equivalent bed of Sand. The experiments are performed in an “intermittent” manner over extended time, to “simulate” performance over the life of the filter bed. The experiments were continued till a significant drop in water flow rate through the bed was observed. A novel “deposition” and “detachment” rate based transient mathematical model is developed. It is observed that the data from the experiments can be explained by the above model, for different aqueous phase electrolyte concentrations. The model “parameters”, namely the “deposition” and “detachment” rates are evaluated for the 2 filter media studied. The model suggests that the significantly better performance of GAC in colloid filtration is probably due to significantly lower detachment of colloids from the same. While the “deposition” rates are higher for GAC, the “detachment” rates are significantly lower, which makes GAC more effective than sand for colloid removal by over an order of magnitude.
在水和废水处理系统中,使用颗粒活性炭(GAC)和天然二氧化硅(砂)作为过滤介质是非常常见的。虽然GAC提供了作为溶解有机物的“吸附”过滤器的额外功能,但它也更昂贵。在本文中,我们提出了一个实验评价的性能的GAC床的胶体去除,并比较了相同的性能,从一个等效的砂床。实验在延长的时间内以“间歇”的方式进行,以“模拟”过滤床的使用寿命。实验继续进行,直到观察到水流通过床层的速率显著下降。建立了一种新的基于“沉积”和“脱离”速率的瞬态数学模型。观察到,对于不同的水相电解质浓度,实验数据可以用上述模型解释。对所研究的两种滤料的模型“参数”,即“沉积”速率和“分离”速率进行了评估。该模型表明,GAC在胶体过滤中的性能显著提高可能是由于胶体从相同的胶体中分离明显降低。虽然GAC的“沉积”速率较高,但“脱离”速率明显较低,这使得GAC比砂更有效地去除胶体超过一个数量级。
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引用次数: 0
Evaluation of refused tea waste activated carbon for color removal: Equilibrium and kinetic studies 茶叶废渣活性炭去色的评价:平衡和动力学研究
Pub Date : 2017-03-25 DOI: 10.12989/aer.2017.6.1.001
S. Wijetunga, Chathurika Dfa Gunasekara
New technologies or improvement of the existing technologies are required to enhance the efficiency of removal of pollutants from wastewater. In this study we attempted to produce and test the activated carbon produced from the refused tea waste for the removal of dyes from wastewater. The objectives of this investigation were to produce activated carbon from refused tea waste by chemical activation, evaluate its performance for the removal of color produced from Acid Yellow 36, and the modeling of its dye removal with the kinetic study. The activation was performed in two steps namely carbonization at 375±25C and chemical activation with HCl at 800C under the absence of Oxygen. Adsorption isotherms and kinetic studies were performed with a textile dye, Acid Yellow 36, at different concentrations (20-80 mg/L). The maximum dye removal (~90%) observed at 80 mg/L dye concentration and it reduced at low dye concentrations. Maximum adsorption (71.97 mg/g) was recorded at 96 h at 29±1C. Low pH increased the dye adsorption (pH=2; 78.27 mg/g) while adsorption reduced at high pH levels indicating that the competition occurs in between OHions and AY36 molecules for the adsorption sites in RTAC. The Langmuir isotherm model clearly explained the dye adsorption, favorably, by RTAC. Moreover, kinetic studied performed showed that the pseudo second order kinetic model clearly describes the dye adsorption. Based on the results obtained in this study, it can be concluded that RTAC can be used for the removal of textile dyes.
为了提高废水中污染物的去除效率,需要采用新技术或改进现有技术。本研究以茶叶废渣为原料制备活性炭,并对活性炭去除废水中的染料进行了试验研究。本研究的目的是利用化学活化法制备茶叶废渣活性炭,评价其对酸性黄36脱色的性能,并通过动力学研究对其脱色过程进行建模。活化过程分为两个步骤,即375±25°C的碳化和800°C的HCl在缺氧条件下的化学活化。对不同浓度(20 ~ 80 mg/L)的纺织染料酸性黄36进行了等温线吸附和动力学研究。当染料浓度为80 mg/L时,染料去除率最高(约90%),较低时,染料去除率降低。在29±1℃下,96 h的最大吸附量为71.97 mg/g。低pH增加了染料吸附(pH=2;78.27 mg/g),而在高pH水平下,吸附减少,这表明OHions和AY36分子之间发生了对RTAC吸附位点的竞争。Langmuir等温线模型很好地解释了RTAC对染料的吸附。此外,动力学研究表明,准二级动力学模型可以很好地描述染料吸附。研究结果表明,RTAC可用于纺织品染料的脱除。
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引用次数: 5
Assessment of seasonal variations in water quality of Brahmani river using PCA 用主成分分析法评价婆罗门河水质的季节变化
Pub Date : 2017-03-25 DOI: 10.12989/AER.2017.6.1.053
C. R. Mohanty, S. Nayak
Assessment of seasonal changes in surface water quality is an important aspect for evaluating temporal variations of river pollution due to natural or anthropogenic inputs of point and non-point sources. In this study, surface water quality data for 15 physico-chemical parameters collected from 7 monitoring stations in a river during the years from 2014 to 2016 were analyzed. The principal component analysis technique was employed to evaluate the seasonal correlations of water quality parameters, while the principal factor analysis technique was used to extract the parameters that are most important in assessing seasonal variations of river water quality. Analysis shows that a parameter that is most important in contributing to water quality variation for one season may not be important for another season except alkalinity, which is always the most important parameters in contributing to water quality variations for all three seasons.
地表水质量的季节变化评价是评价自然或人为点源和非点源输入引起的河流污染时间变化的一个重要方面。本研究对2014 - 2016年某河流7个监测站采集的15个地表水理化参数数据进行了分析。采用主成分分析技术评价水质参数的季节相关性,采用主因子分析技术提取对评价河流水质季节变化最重要的参数。分析表明,除了碱度以外,对一个季节的水质变化最重要的参数可能对另一个季节不重要,碱度始终是对所有三个季节的水质变化最重要的参数。
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引用次数: 10
Marble wastes as amendments to stabilize heavy metals in Zn-Electroplating sludge 大理石废物作为稳定电镀锌污泥中重金属的改良剂
Pub Date : 2017-03-25 DOI: 10.12989/AER.2017.6.1.015
K. Riahi, S. Chaabane, B. B. Thayer
Powdered marble wastes (PMW) generated by Utique marble cutting industries (North of Tunisia) with abundant amounts were used in this study as low-cost materials to investigate the stabilization of heavy metals (Pb, Zn, Fe) in sludge generated from a local Zn-Electroplating factory. Powdered marble wastes were evaluated by means of chemical fractions of heavy metals in sludge and concentrations of heavy metals in leachate from columns to determine their ability to stabilize heavy metals in contaminated sludge. Results indicated that chemical fractions of heavy metals in sludge were affected by application of the PMW mineral materials and pH, however, the effects varied with heavy metals. Application of the powdered marble wastes mineral materials reduced exchangeable metals in the sequence of Pb (60.5%)>Fe (40.5%)>Zn (30.1%). X-ray diffraction and hydro-geochemical transport code PHREEQC analysis were successfully carried out to get a better understanding of the mechanisms of reactive mineral phases involved in reduced exchangeable heavy metals in sludge after PMW material amendments. Therefore, metal immobilization using powdered marble wastes materials is an effective stabilization technique for industrial metallic hydroxide sludge.
本研究利用乌蒂克大理石切割工业(突尼斯北部)产生的大量大理石粉末废料(PMW)作为低成本材料,研究了当地一家锌电镀厂产生的污泥中重金属(Pb, Zn, Fe)的稳定性。通过污泥中重金属的化学组分和柱状渗滤液中重金属的浓度来评估大理石粉末废物,以确定其稳定污染污泥中重金属的能力。结果表明,PMW矿物材料的施用和pH值对污泥中重金属的化学组分有影响,但对重金属的影响有所不同。应用大理岩废矿物材料后,可交换金属含量降低的顺序为Pb (60.5%)>Fe (40.5%)>Zn(30.1%)。通过x射线衍射和水文地球化学输运代码PHREEQC分析,成功地了解了PMW材料改性后污泥中可交换性重金属还原的反应性矿物相的机制。因此,粉末状大理石废弃物金属固定化是一种有效的工业氢氧化金属污泥稳定化技术。
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引用次数: 3
Mathematical model for reactive transport of heavy metals in soil column: Based on PHREEQC and HP1 simulators 重金属在土壤柱中反应性迁移的数学模型——基于PHREEQC和HP1模拟器
Pub Date : 2017-03-25 DOI: 10.12989/aer.2017.6.1.067
Fatemeh Izadi Tameh, G. Asadollahfardi, A. Darban
Mining activities play a significant role in environmental pollution by producing large amounts of tailings which comprise heavy metals. The impressive increase in mining activities in recent decades, due to their high influence on the industry of developing countries, duplicates the need for a substantial effort to develop and apply efficient measures of pollution control, mitigation, and abatement. In this study, our objective was to investigate the effect of simulation of the leachate, pH and inflow intensity of transport of Pb 2+ , Zn 2+ , and Cd 2+ through Lakan lead and zinc plant tailings, in Iran, and to evaluate the modeling efficiency by comparing the modeling results and the results obtained from previous column studies. We used the HP1 model and the PHREEQC database to simulate metals transport through a saturated soil column during a 15 day time period. The simulations assumed local equilibrium. As expected, a lower pH and inflow intensity increased metal transport. The retardation of heavy metals followed the order Zn 2+ >Pb 2+ >Cd 2+ and the removal concentrations of Cd, Pb, and Zn at the inflow intensity critical scenario, and Cd and Pb at inflow acidity critical scenario exceeded the allowable EPA and Iranian’s 1053 standard thresholds. However, although the simulation results generally agreed well with the results of the column study, improvements are expected by using multi-dimensional models and a kinetic modeling approach for the reactions involved. The results of such investigations will be highly useful for designing preventative strategies to control reactive transport of hazardous metals and minimize their environmental effects.
采矿活动产生大量含有重金属的尾矿,对环境造成严重污染。近几十年来,由于采矿活动对发展中国家的工业有很大的影响,采矿活动的增加令人印象深刻,因此需要作出大量努力,制定和实施控制、减轻和减少污染的有效措施。在本研究中,我们的目的是研究模拟伊朗拉坎铅锌厂尾矿中渗滤液、pH值和流入强度对Pb 2+、Zn 2+和Cd 2+迁移的影响,并通过将模拟结果与以往的柱状研究结果进行比较,评价模拟的效率。我们使用HP1模型和PHREEQC数据库模拟了15天时间内金属在饱和土柱中的运移。模拟假设局部平衡。正如预期的那样,较低的pH值和流入强度增加了金属的迁移。重金属的缓除率为Zn 2+ >Pb 2+ >Cd 2+,在流入强度临界情况下,Cd、Pb和Zn的去除率超过EPA和伊朗1053标准阈值。然而,尽管模拟结果与柱式研究的结果基本一致,但期望通过使用多维模型和所涉及的反应动力学建模方法进行改进。这种调查的结果将对设计预防战略以控制有害金属的反应性迁移和尽量减少其对环境的影响非常有用。
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引用次数: 1
Plurality of urban governance in Nigeria and its implications on delivery of environmental services 尼日利亚城市治理的多元化及其对提供环境服务的影响
Pub Date : 2017-03-25 DOI: 10.12989/AER.2017.6.1.025
O. Daramola, Oluwaseun Olowoporoku
This paper discussed plurality in urban governance in Nigeria and its implication on delivery of urban environmental services, with a focus on water supply, sanitation and solid waste disposal. Conceptually, it explained urban governance as the sum total of the ways of achieving an inclusive city and expressed the urban governance system of Nigeria based the legal framework set for them. The paper explored the environmental implications of urban governance in Nigeria. It concluded that urban governance has several implications on delivery of urban environmental services in Nigeria. The dualism in urban governance is a factor contributing towards inefficient delivery of environmental services such as water supply, sanitation and solid waste management in Nigeria. The paper recommended, among others, a constitutional reform that will guarantee efficient urban governance and delivery of environmental services in Nigeria.
本文讨论了尼日利亚城市治理的多元性及其对提供城市环境服务的影响,重点是供水、卫生和固体废物处理。从概念上讲,它将城市治理解释为实现包容性城市的方式的总和,并基于为其设定的法律框架表达了尼日利亚的城市治理体系。本文探讨了尼日利亚城市治理对环境的影响。报告的结论是,城市治理对尼日利亚提供城市环境服务有若干影响。城市管理的二元论是造成尼日利亚供水、卫生和固体废物管理等环境服务提供效率低下的一个因素。除其他外,该文件建议进行宪法改革,以保证尼日利亚有效的城市治理和提供环境服务。
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引用次数: 4
The review of municipal solid waste management in Nigeria: the current trends 审查尼日利亚的城市固体废物管理:目前的趋势
Pub Date : 2016-12-25 DOI: 10.12989/AER.2016.5.4.237
O. T. Iorhemen, M. Alfa, S. Onoja
{"title":"The review of municipal solid waste management in Nigeria: the current trends","authors":"O. T. Iorhemen, M. Alfa, S. Onoja","doi":"10.12989/AER.2016.5.4.237","DOIUrl":"https://doi.org/10.12989/AER.2016.5.4.237","url":null,"abstract":"","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"46 1","pages":"237-249"},"PeriodicalIF":0.0,"publicationDate":"2016-12-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86441565","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
Effects of ultrasound coupled with potassium permanganate pre-treatment of sludge on aerobic digestion 超声联合高锰酸钾预处理对污泥好氧消化的影响
Pub Date : 2016-12-25 DOI: 10.12989/AER.2016.5.4.251
O. Demir
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引用次数: 1
Development a numerical model of flow and contaminant transport in layered soils 建立层状土壤中流动和污染物运移的数值模型
Pub Date : 2016-12-25 DOI: 10.12989/AER.2016.5.4.263
F. Kilanehei, H. Ahmadi, M. Namin
{"title":"Development a numerical model of flow and contaminant transport in layered soils","authors":"F. Kilanehei, H. Ahmadi, M. Namin","doi":"10.12989/AER.2016.5.4.263","DOIUrl":"https://doi.org/10.12989/AER.2016.5.4.263","url":null,"abstract":"","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"1 1","pages":"263-282"},"PeriodicalIF":0.0,"publicationDate":"2016-12-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90118207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Mathematical simulation of surfactant flushing process to remediate diesel contaminated sand column 表面活性剂冲洗修复柴油污染砂柱过程的数学模拟
Pub Date : 2016-12-25 DOI: 10.12989/AER.2016.5.4.213
G. Asadollahfardi, A. Darban, Nazila Noorifar, M. Rezaee
This paper presents a numerical model based on a UTCHEM simulator to simulate surfactant flushing process to remediate diesel contaminated sand column. For this purpose, we modeled remediation process under 10000 and 20000 ppm initial concentrations of diesel. Various percent-mass sodium dodecyl sulfate (SDS) considered in our model. The model results indicated that 0.3 percent-mass of SDS at 10000 ppm and 0.1 percent-mass of SDS at 20000 ppm initial diesel concentration had maximum removal perdition which is in agreement with the experiment results. For 10000 ppm diesel concentrations, the coefficient of determination (R 2 ) and index of agreement (IA) between the model result and the experimental data were 0.9952 and 0.9695, respectively, and for 20000 ppm diesel concentrations, R 2 and IA were 0.9977 and 0.9935, respectively. The sensitivity analysis of permeability illustrated that in all diesel concentrations and SDS percent-mass with increasing permeability the model resulted in more removal efficiency.
本文建立了基于UTCHEM仿真器的表面活性剂冲洗修复柴油污染砂柱的数值模型。为此,我们模拟了柴油初始浓度为10000ppm和20000ppm下的修复过程。在我们的模型中考虑了各种百分比质量十二烷基硫酸钠(SDS)。模型结果表明,当柴油初始浓度为10000ppm时,0.1%质量的SDS和0.1%质量的SDS的去除率最大,与实验结果一致。当柴油浓度为10000 ppm时,模型结果与实验数据的决定系数(r2)和一致指数(IA)分别为0.9952和0.9695,当柴油浓度为20000 ppm时,r2和IA分别为0.9977和0.9935。渗透率的敏感性分析表明,在所有柴油浓度和SDS百分比质量下,随着渗透率的增加,该模型的去除效率更高。
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引用次数: 5
期刊
Advances in Environmental Research
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