Pub Date : 2020-12-01DOI: 10.12989/AER.2020.9.4.233
S. Aziz, Imad A. Omar, M. Bashir, A. Mojiri
To date, there is no central wastewater (WW) treatment plant in Erbil city, Kurdistan region, Iraq. Therefore, raw WW disposes to the environment and sometimes it used directly for irrigation in some areas of Erbil city. Disposal of the untreated WW to the natural environment and using for irrigation it causes problems for the people and the environment. The aims of the current work were to study the characteristics, design of primary and different secondary treatment units and reusing of produced WW. Raw WW samples from Ashty city-Erbil city were collected and analyzed for twenty three quality parameters such as Total Suspended Solids (TSS), total dissolved solids, total volatile and non-volatile solids, total acidity, total alkalinity, total hardness, five-day Biochemical Oxygen Demand (BOD5), Chemical Oxygen Demand (COD), biodegradability ratio (BOD5/COD), turbidity, etc. Results revealed that some parameters such as BOD5 and TSS were exceeded the standards for disposal of WW. Design and calculations for primary and secondary treatment (biological treatment) processes were presented. Primary treatment units such as screening, grit chamber, and flow equalization tank were designed and detailed calculation were illustrated. While, Conventional Activated Sludge (CAS), Sequencing Batch Reactor (SBR) and Moving Bed Biofilm Reactors (MBBR) were applied for the biological treatment of WW. Results revealed that MBBR was the best and economic technique for the biological treatment of WW. Treated WW is suitable for reusing and there is no restriction on use for irrigation of green areas inside Ashty city campus.
{"title":"Stage by stage design for primary, conventional activated sludge, SBR and MBBR units for residential wastewater treatment and reusing","authors":"S. Aziz, Imad A. Omar, M. Bashir, A. Mojiri","doi":"10.12989/AER.2020.9.4.233","DOIUrl":"https://doi.org/10.12989/AER.2020.9.4.233","url":null,"abstract":"To date, there is no central wastewater (WW) treatment plant in Erbil city, Kurdistan region, Iraq. Therefore, raw WW disposes to the environment and sometimes it used directly for irrigation in some areas of Erbil city. Disposal of the untreated WW to the natural environment and using for irrigation it causes problems for the people and the environment. The aims of the current work were to study the characteristics, design of primary and different secondary treatment units and reusing of produced WW. Raw WW samples from Ashty city-Erbil city were collected and analyzed for twenty three quality parameters such as Total Suspended Solids (TSS), total dissolved solids, total volatile and non-volatile solids, total acidity, total alkalinity, total hardness, five-day Biochemical Oxygen Demand (BOD5), Chemical Oxygen Demand (COD), biodegradability ratio (BOD5/COD), turbidity, etc. Results revealed that some parameters such as BOD5 and TSS were exceeded the standards for disposal of WW. Design and calculations for primary and secondary treatment (biological treatment) processes were presented. Primary treatment units such as screening, grit chamber, and flow equalization tank were designed and detailed calculation were illustrated. While, Conventional Activated Sludge (CAS), Sequencing Batch Reactor (SBR) and Moving Bed Biofilm Reactors (MBBR) were applied for the biological treatment of WW. Results revealed that MBBR was the best and economic technique for the biological treatment of WW. Treated WW is suitable for reusing and there is no restriction on use for irrigation of green areas inside Ashty city campus.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"212 1","pages":"233"},"PeriodicalIF":0.0,"publicationDate":"2020-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79421174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-01DOI: 10.12989/AER.2020.9.4.295
M. Asif, K. Zaman, Khan Burhan Khan
The earlier literature widely documented the role of natural resources in economic development and confined their findings either in support of resource blessing growth or resource curse hypothesis. The ample research on the stated theme has available in the relevant databases, supported with empirical data, while a few studies used a case study or mixed-method approach. The study identified plenty of room on a given topic by conducting a systematic literature review and synthesizing the literature in more meaningful inferences. After a thorough investigation of the literature review through systematic intervention, the study concludes that natural resource management is imperative for a country's sustained growth. Simultaneously, it is desirable to reduce resource conflicts, improve institutional performance, decrease corruption, and stabilize the political environment to get maximum natural resource management potential globally.
{"title":"Natural resource management: A systematic literature review","authors":"M. Asif, K. Zaman, Khan Burhan Khan","doi":"10.12989/AER.2020.9.4.295","DOIUrl":"https://doi.org/10.12989/AER.2020.9.4.295","url":null,"abstract":"The earlier literature widely documented the role of natural resources in economic development and confined their findings either in support of resource blessing growth or resource curse hypothesis. The ample research on the stated theme has available in the relevant databases, supported with empirical data, while a few studies used a case study or mixed-method approach. The study identified plenty of room on a given topic by conducting a systematic literature review and synthesizing the literature in more meaningful inferences. After a thorough investigation of the literature review through systematic intervention, the study concludes that natural resource management is imperative for a country's sustained growth. Simultaneously, it is desirable to reduce resource conflicts, improve institutional performance, decrease corruption, and stabilize the political environment to get maximum natural resource management potential globally.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"64 1","pages":"295"},"PeriodicalIF":0.0,"publicationDate":"2020-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83787609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-01DOI: 10.12989/AER.2020.9.4.275
Juhi Firdous, Y. K. Mathur, M. Jeelani, A. Aziz, Seema Azmat, Syeed Mudasir
We provide the first study on the occurrence of microplastics in Dal lake, Kashmir, India. Microplastics act as catastrophe that trigger many environmental problems. The key origins of microplastics are larger plastics, which split into smaller plastics after UV light disintegration. There is relatively little work carried out on the existence of microplastics. The present work has been undertaken on the occurrence of microplastics at four pre-selected sites (surface water) in Dal lake, Kashmir. The samples were taken to the laboratory to dissolve organic matter by using H2O2 (6%). To speed up the organic digestion; the treated mixture was heated on a hot plate at 70
{"title":"Preliminary studies on the microplastic pollution in Dal lake, Kashmir (first report)","authors":"Juhi Firdous, Y. K. Mathur, M. Jeelani, A. Aziz, Seema Azmat, Syeed Mudasir","doi":"10.12989/AER.2020.9.4.275","DOIUrl":"https://doi.org/10.12989/AER.2020.9.4.275","url":null,"abstract":"We provide the first study on the occurrence of microplastics in Dal lake, Kashmir, India. Microplastics act as catastrophe that trigger many environmental problems. The key origins of microplastics are larger plastics, which split into smaller plastics after UV light disintegration. There is relatively little work carried out on the existence of microplastics. The present work has been undertaken on the occurrence of microplastics at four pre-selected sites (surface water) in Dal lake, Kashmir. The samples were taken to the laboratory to dissolve organic matter by using H2O2 (6%). To speed up the organic digestion; the treated mixture was heated on a hot plate at 70","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"96 1","pages":"275"},"PeriodicalIF":0.0,"publicationDate":"2020-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80500479","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-12-01DOI: 10.12989/AER.2020.9.4.285
P. Velumani, P. Manikandan
Growth of any country rest in the consumption of industrial wastes for its infrastructure amenities. Countries like India positively desires a vital utilization of industrial waste resembling paper sludge in the construction industry to make various building materials. Also, it is the duty of all civil engineers or researchers to attach them in mounting new materials from the waste dumped as land fillings. In every construction project, about 70% of cost accounts for the procurement of materials. If this, can be minimized consequently the cost of construction will certainly be condensed. Research has established that the waste paper sludge can be reused in the construction field for a probable scope. The construction diligences munch through a massive quantity of non-renewable resources. On the additional dispense, more waste paper board sludge ends up in landfills or dumpsites than those recycled. Consequently, waste paper sludge for use as a construction material composes a step towards sustainable development. Keeping this in mind an endeavor has been made to utilize paper board sludge acquired from the paper board industry and used with several pozzolanic and cementitious materials for a specific purpose. The addition of paper sludge has been varied from 0% to 20% by weight of cement. The tests done with the samples expose that four samples showed significant outcomes with remarkable strength and durability properties which guide to move for the next phase of research for producing lightweight tiles.
{"title":"Contribution to the development of tiles made of paper board sludge","authors":"P. Velumani, P. Manikandan","doi":"10.12989/AER.2020.9.4.285","DOIUrl":"https://doi.org/10.12989/AER.2020.9.4.285","url":null,"abstract":"Growth of any country rest in the consumption of industrial wastes for its infrastructure amenities. Countries like India positively desires a vital utilization of industrial waste resembling paper sludge in the construction industry to make various building materials. Also, it is the duty of all civil engineers or researchers to attach them in mounting new materials from the waste dumped as land fillings. In every construction project, about 70% of cost accounts for the procurement of materials. If this, can be minimized consequently the cost of construction will certainly be condensed. Research has established that the waste paper sludge can be reused in the construction field for a probable scope. The construction diligences munch through a massive quantity of non-renewable resources. On the additional dispense, more waste paper board sludge ends up in landfills or dumpsites than those recycled. Consequently, waste paper sludge for use as a construction material composes a step towards sustainable development. Keeping this in mind an endeavor has been made to utilize paper board sludge acquired from the paper board industry and used with several pozzolanic and cementitious materials for a specific purpose. The addition of paper sludge has been varied from 0% to 20% by weight of cement. The tests done with the samples expose that four samples showed significant outcomes with remarkable strength and durability properties which guide to move for the next phase of research for producing lightweight tiles.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"115 1","pages":"285"},"PeriodicalIF":0.0,"publicationDate":"2020-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76932347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-09-01DOI: 10.12989/AER.2020.9.3.191
M. Hussain, M. S. Mahtab, I. Farooqi
The rise in population and industrialization accounts for the generation of a huge amount of wastewaters. The treatment of this wastewater is obligatory to safeguard the environment and various life forms. Conventional methods for high strength wastewater treatment coming out to be ineffective. Advanced oxidation processes (AOPs) for such wastewater treatment proved to be very effective particularly for the removal of various refractory compounds present in the wastewater. Ozone based AOPs with its high oxidizing power and excellent disinfectant properties is considered to be an attractive choice for the elimination of a large spectrum of refractory compounds. Furthermore, it enhances the biodegradability of wastewaters after treatment which favors subsequent biological treatments. In this review, a detailed overview of the AOPs (like the Fenton process, photocatalysis, Electrochemical oxidation, wet air oxidation, and Supercritical water oxidation process) has been discussed explicitly focusing on ozone-based AOPs (like O3, O3/H2O2, O3/UV, Ozone/Activated carbon process, Ozone/Ultrasound process, O3/UV/H2O2 process). This review also comprises the involved mechanisms and applications of various ozone-based AOPs for effective municipal/industrial wastewaters and landfill leachate treatment. Process limitations and rough economical analysis were also introduced. The conclusive remarks with future research directions also underlined. It was found that ozonation in combination with other effective AOPs and biological methods enhances treatment efficacies. This review will serve as a reference document for the researchers working in the AOPs field particularly focusing on ozone-based AOPs for wastewater treatment and management systems.
{"title":"The applications of ozone-based advanced oxidation processes for wastewater treatment: A review","authors":"M. Hussain, M. S. Mahtab, I. Farooqi","doi":"10.12989/AER.2020.9.3.191","DOIUrl":"https://doi.org/10.12989/AER.2020.9.3.191","url":null,"abstract":"The rise in population and industrialization accounts for the generation of a huge amount of wastewaters. The treatment of this wastewater is obligatory to safeguard the environment and various life forms. Conventional methods for high strength wastewater treatment coming out to be ineffective. Advanced oxidation processes (AOPs) for such wastewater treatment proved to be very effective particularly for the removal of various refractory compounds present in the wastewater. Ozone based AOPs with its high oxidizing power and excellent disinfectant properties is considered to be an attractive choice for the elimination of a large spectrum of refractory compounds. Furthermore, it enhances the biodegradability of wastewaters after treatment which favors subsequent biological treatments. In this review, a detailed overview of the AOPs (like the Fenton process, photocatalysis, Electrochemical oxidation, wet air oxidation, and Supercritical water oxidation process) has been discussed explicitly focusing on ozone-based AOPs (like O3, O3/H2O2, O3/UV, Ozone/Activated carbon process, Ozone/Ultrasound process, O3/UV/H2O2 process). This review also comprises the involved mechanisms and applications of various ozone-based AOPs for effective municipal/industrial wastewaters and landfill leachate treatment. Process limitations and rough economical analysis were also introduced. The conclusive remarks with future research directions also underlined. It was found that ozonation in combination with other effective AOPs and biological methods enhances treatment efficacies. This review will serve as a reference document for the researchers working in the AOPs field particularly focusing on ozone-based AOPs for wastewater treatment and management systems.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"2 1","pages":"191-214"},"PeriodicalIF":0.0,"publicationDate":"2020-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75200235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-09-01DOI: 10.12989/AER.2020.9.3.151
Giridhar M.V.S.S, S. Mohan, D. Kumar
Water quality demonstrates physical, chemical and biological characteristics of water. The quality of surface and groundwater is currently an important concern with population growth and industrialization. Over exploitation of water resources due to demand is causing the deterioration of surface water and ground water. Periodic water quality testing must be carried out to protect our water resources. The present research analyses the spatial variation of surface water and groundwater in and around the lakes of Hyderabad. Twenty-Seven lakes and their neighboring bore water samples are obtained for water quality monitoring. Samples are evaluated for specific physico-chemical parameters such as pH, Total Dissolved Solids (TDS), Cl, SO4, Na, K, Ca, Mg, and Total Hardness (TH). The spatial variation of water quality parameters for the 27 lakes and groundwater were analysed. Correlation and multiple regression analysis were carried out to determine comparative study of lake and ground water. The study found that most of the lakes were polluted and this had an impact on surrounding ground water.
{"title":"Comparative assessment of surface and ground water quality using geoinformatics","authors":"Giridhar M.V.S.S, S. Mohan, D. Kumar","doi":"10.12989/AER.2020.9.3.151","DOIUrl":"https://doi.org/10.12989/AER.2020.9.3.151","url":null,"abstract":"Water quality demonstrates physical, chemical and biological characteristics of water. The quality of surface and groundwater is currently an important concern with population growth and industrialization. Over exploitation of water resources due to demand is causing the deterioration of surface water and ground water. Periodic water quality testing must be carried out to protect our water resources. The present research analyses the spatial variation of surface water and groundwater in and around the lakes of Hyderabad. Twenty-Seven lakes and their neighboring bore water samples are obtained for water quality monitoring. Samples are evaluated for specific physico-chemical parameters such as pH, Total Dissolved Solids (TDS), Cl, SO4, Na, K, Ca, Mg, and Total Hardness (TH). The spatial variation of water quality parameters for the 27 lakes and groundwater were analysed. Correlation and multiple regression analysis were carried out to determine comparative study of lake and ground water. The study found that most of the lakes were polluted and this had an impact on surrounding ground water.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"35 1","pages":"151"},"PeriodicalIF":0.0,"publicationDate":"2020-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76971019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-09-01DOI: 10.12989/AER.2020.9.3.175
Aziz Azizpour, Mohammad Azarafza, H. Akgün
unicipal solid waste disposal is considered as one of the most important risks for environmental contamination which necessitates the development of strategies to reduce destructive consequences on the ecosystem as related especially to heavy metal accumulation. This study investigates heavy metal (i.e., As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn) accumulation in the Tonekabon region, NW of Iran that is related to city waste disposal and evaluates the environmental impact in the Caspian Sea coastal region. For this purpose, after performing field studies and collecting 50 soil specimens from 5 sites of the study area, geochemical tests (i.e., inductively coupled plasma mass spectrometry, atomic absorption spectroscopy and x-ray fluorescence) were conducted on the soil specimens collected from the 5 sites (named as Sites A1, A2, A3, A4 and A5) and the results were used to estimate the pollution indices (i.e., geo-accumulation index, normalized enrichment factor, contamination factor, and pollution load index). The obtained indices were utilized to assess the eco-toxicological risk level in the landfill site which indicated that the city has been severely contaminated by Cu, Mn, Ni, Pb and Zn. These levels have been developed along the stream towards the nearshore areas indicating uptake of soil degradation. The heavy metal contamination was classified to range from unpolluted to highly polluted, which indicated serious heavy metal pollution in the study area as related to municipal solid waste disposal in Tonekabon.
{"title":"The impact of municipal waste disposal of heavy metals on environmental pollution: A case study for Tonekabon, Iran","authors":"Aziz Azizpour, Mohammad Azarafza, H. Akgün","doi":"10.12989/AER.2020.9.3.175","DOIUrl":"https://doi.org/10.12989/AER.2020.9.3.175","url":null,"abstract":"unicipal solid waste disposal is considered as one of the most important risks for environmental contamination which necessitates the development of strategies to reduce destructive consequences on the ecosystem as related especially to heavy metal accumulation. This study investigates heavy metal (i.e., As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn) accumulation in the Tonekabon region, NW of Iran that is related to city waste disposal and evaluates the environmental impact in the Caspian Sea coastal region. For this purpose, after performing field studies and collecting 50 soil specimens from 5 sites of the study area, geochemical tests (i.e., inductively coupled plasma mass spectrometry, atomic absorption spectroscopy and x-ray fluorescence) were conducted on the soil specimens collected from the 5 sites (named as Sites A1, A2, A3, A4 and A5) and the results were used to estimate the pollution indices (i.e., geo-accumulation index, normalized enrichment factor, contamination factor, and pollution load index). The obtained indices were utilized to assess the eco-toxicological risk level in the landfill site which indicated that the city has been severely contaminated by Cu, Mn, Ni, Pb and Zn. These levels have been developed along the stream towards the nearshore areas indicating uptake of soil degradation. The heavy metal contamination was classified to range from unpolluted to highly polluted, which indicated serious heavy metal pollution in the study area as related to municipal solid waste disposal in Tonekabon.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"36 1","pages":"175"},"PeriodicalIF":0.0,"publicationDate":"2020-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91185498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-09-01DOI: 10.12989/AER.2020.9.3.215
Wasim S. Akthar, Mohamed Sheik Aadham, A. S. Nisha
Crude oils are essential source of energy. It is majorly found in geographical locations beneath the earth's surface and crude oil is the main factor for the economic developments in the world. Natural crude oil contains unrefined petroleum composed of hydrocarbons of various molecular weights and it contains other organic materials like aromatic compounds, sulphur compounds, and many other organic compounds. These hydrocarbons are rapidly getting degraded by biosurfactant producing microorganisms. The present study deals with the isolation, purification, and characterization of biosurfactant producing microorganism from oil-contaminated soil. The ability of the microorganism producing biosurfactant was investigated by well diffusion method, drop collapse test, emulsification test, oil displacement activity, and blue agar plate method. The isolate obtained from the oil contaminated soil was identified as Bacillus subtilis. The identification was done by microscopic examinations and further characterization was done by Biochemical tests and 16SrRNA gene sequencing. Purification of the biosurfactant was performed by simple liquid-liquid extraction, and characterization of extracted biosurfactants was done using Fourier transform infrared spectroscopy (FTIR). The degradation of crude oil upon treatment with the partially purified biosurfactant was analyzed by FTIR spectroscopy and Gas-chromatography mass spectroscopy (GC-MS).
{"title":"In situ isolation and characterization of the biosurfactants of B. Subtilis","authors":"Wasim S. Akthar, Mohamed Sheik Aadham, A. S. Nisha","doi":"10.12989/AER.2020.9.3.215","DOIUrl":"https://doi.org/10.12989/AER.2020.9.3.215","url":null,"abstract":"Crude oils are essential source of energy. It is majorly found in geographical locations beneath the earth's surface and crude oil is the main factor for the economic developments in the world. Natural crude oil contains unrefined petroleum composed of hydrocarbons of various molecular weights and it contains other organic materials like aromatic compounds, sulphur compounds, and many other organic compounds. These hydrocarbons are rapidly getting degraded by biosurfactant producing microorganisms. The present study deals with the isolation, purification, and characterization of biosurfactant producing microorganism from oil-contaminated soil. The ability of the microorganism producing biosurfactant was investigated by well diffusion method, drop collapse test, emulsification test, oil displacement activity, and blue agar plate method. The isolate obtained from the oil contaminated soil was identified as Bacillus subtilis. The identification was done by microscopic examinations and further characterization was done by Biochemical tests and 16SrRNA gene sequencing. Purification of the biosurfactant was performed by simple liquid-liquid extraction, and characterization of extracted biosurfactants was done using Fourier transform infrared spectroscopy (FTIR). The degradation of crude oil upon treatment with the partially purified biosurfactant was analyzed by FTIR spectroscopy and Gas-chromatography mass spectroscopy (GC-MS).","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"37 1","pages":"215-232"},"PeriodicalIF":0.0,"publicationDate":"2020-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80618588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-07-01DOI: 10.12989/AER.2020.9.3.161
D. Çifçi, Süreyya Meriça
The removal of two dyes, namely Methylene Blue (MB) and Reactive Brillant Red (RR) from aqueous solution was investigated using magnetite iron coated pumice (MIP) composite in the Fenton-like oxidation process. A weight ratio of 2.5 g (with the molar ratio of Fe3+ to Fe2+ to be 2) (5%) of iron to the total pumice (50 g) was enabled during synthesis of catalyst. Surface composition and characteristics of the catalyst were assessed by SEM-EDX, FT-IR, Raman spectral analysis. The effect of the amount of pumice solely used or MIP, H2O2 concentration, pH and initial concentration of MB or RR dyes on Fenton-like process efficiency was investigated. EDAX spectrums of pumice and MIP showed that oxygen and silisium are the major elements. The Fe content of MIP increased to 2.24%. SEM, FT-IR and Raman spectrums confirmed the impregnation of Fe on pumice surface. The experimental results revealed that high removal rates of dyes could be obtained using MIP that demonstrated a higher stability for removal of MB dye. pH affected the removal efficiency of both dyes and the degradation of both dyes was sharply dropped when pH was increased above 4. The removal of dyes did not significantly change with increasing H2O2 concentration. Degradation rates of both MB and RR dyes increased 3.3 and 2.8 times with the use of MIP compared to pumice alone, respectively. Furthermore, MIP enabled a good removal efficiency at higher dye concentrations. It can be emphasized that MIP composite can be used in the heterogeneous Fenton-like systems considering the economic and easily separation aspects.
研究了磁铁矿包覆浮石(MIP)复合材料在Fenton-like氧化过程中对水溶液中亚甲基蓝(MB)和活性艳红(RR)两种染料的去除效果。在催化剂的合成过程中，使总浮石(50 g)中铁的质量比为2.5 g (Fe3+与Fe2+的摩尔比为2)(5%)。通过SEM-EDX、FT-IR、拉曼光谱分析对催化剂的表面组成和性能进行了表征。考察了浮石用量、MIP、H2O2浓度、pH和MB、RR染料初始浓度对类芬顿工艺效率的影响。浮石的EDAX光谱和MIP光谱表明，氧和硅是主要元素。MIP的铁含量提高到2.24%。SEM、FT-IR和拉曼光谱证实了浮石表面铁的浸渍作用。实验结果表明，MIP对MB染料具有较高的去除率，对MB染料的去除率具有较高的稳定性。pH值对两种染料的去除率均有影响，当pH值大于4时，两种染料的降解均急剧下降。随着H2O2浓度的增加，染料去除率没有显著变化。与单独使用浮石相比，MIP对MB和RR染料的降解率分别提高了3.3倍和2.8倍。此外，MIP在较高的染料浓度下具有良好的去除效率。从经济、易分离等方面考虑，MIP复合材料可用于非均相类芬顿体系。
{"title":"Synthesis of magnetite iron pumice composite for heterogeneous Fenton-like oxidation of dyes","authors":"D. Çifçi, Süreyya Meriça","doi":"10.12989/AER.2020.9.3.161","DOIUrl":"https://doi.org/10.12989/AER.2020.9.3.161","url":null,"abstract":"The removal of two dyes, namely Methylene Blue (MB) and Reactive Brillant Red (RR) from aqueous solution was investigated using magnetite iron coated pumice (MIP) composite in the Fenton-like oxidation process. A weight ratio of 2.5 g (with the molar ratio of Fe3+ to Fe2+ to be 2) (5%) of iron to the total pumice (50 g) was enabled during synthesis of catalyst. Surface composition and characteristics of the catalyst were assessed by SEM-EDX, FT-IR, Raman spectral analysis. The effect of the amount of pumice solely used or MIP, H2O2 concentration, pH and initial concentration of MB or RR dyes on Fenton-like process efficiency was investigated. EDAX spectrums of pumice and MIP showed that oxygen and silisium are the major elements. The Fe content of MIP increased to 2.24%. SEM, FT-IR and Raman spectrums confirmed the impregnation of Fe on pumice surface. The experimental results revealed that high removal rates of dyes could be obtained using MIP that demonstrated a higher stability for removal of MB dye. pH affected the removal efficiency of both dyes and the degradation of both dyes was sharply dropped when pH was increased above 4. The removal of dyes did not significantly change with increasing H2O2 concentration. Degradation rates of both MB and RR dyes increased 3.3 and 2.8 times with the use of MIP compared to pumice alone, respectively. Furthermore, MIP enabled a good removal efficiency at higher dye concentrations. It can be emphasized that MIP composite can be used in the heterogeneous Fenton-like systems considering the economic and easily separation aspects.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"5 1","pages":"161-173"},"PeriodicalIF":0.0,"publicationDate":"2020-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87909622","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-06-01DOI: 10.12989/AER.2020.9.2.123
A. Nwachukwu, N. Nwachukwu
A time series dataset was conducted to ascertain the effect of water table on the variability in and emission of CH₄ and CO₂ concentrations at a closed landfill site. An in-situ data of methane/carbon dioxide concentrations and environmental parameters were collected by means of an in-borehole gas monitor, the Gasclam (Ion Science, UK). Linear regression analysis was used to determine the strength of the correlation between ground-gas concentration and water table. The result shows CH₄ and CO₂concentrations to be variable with strong negative correlations of approximately 0.5 each with water table over the entire monitoring period. The R² was slightly improved by considering their concentration over single periods of increasing and decreasing water table, single periods of increasing water table, and single periods of decreasing water table; their correlations increased significantly at 95% confidence level. The result revealed that fluctuations in groundwater level is the key driving force on the emission of and variability in ground-gas concentration and neither barometric pressure nor temperature. This finding further validates the earlier finding that atmospheric pressure – the acclaimed major control on the variability/migration of CH₄ and CO₂ concentrations on contaminated sites, is not always so.
{"title":"Water table: The dominant control on CH₄ and CO₂ emission from a closed landfill site","authors":"A. Nwachukwu, N. Nwachukwu","doi":"10.12989/AER.2020.9.2.123","DOIUrl":"https://doi.org/10.12989/AER.2020.9.2.123","url":null,"abstract":"A time series dataset was conducted to ascertain the effect of water table on the variability in and emission of CH₄ and CO₂ concentrations at a closed landfill site. An in-situ data of methane/carbon dioxide concentrations and environmental parameters were collected by means of an in-borehole gas monitor, the Gasclam (Ion Science, UK). Linear regression analysis was used to determine the strength of the correlation between ground-gas concentration and water table. The result shows CH₄ and CO₂concentrations to be variable with strong negative correlations of approximately 0.5 each with water table over the entire monitoring period. The R² was slightly improved by considering their concentration over single periods of increasing and decreasing water table, single periods of increasing water table, and single periods of decreasing water table; their correlations increased significantly at 95% confidence level. The result revealed that fluctuations in groundwater level is the key driving force on the emission of and variability in ground-gas concentration and neither barometric pressure nor temperature. This finding further validates the earlier finding that atmospheric pressure – the acclaimed major control on the variability/migration of CH₄ and CO₂ concentrations on contaminated sites, is not always so.","PeriodicalId":7287,"journal":{"name":"Advances in Environmental Research","volume":"03 1","pages":"123"},"PeriodicalIF":0.0,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79569804","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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